Seawater Reverse Osmosis With Isobaric Energy Recovery Devices

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Seawater reverse osmosis with isobaric energy recovery devices

Article  in  Desalination · February 2007


DOI: 10.1016/j.desal.2006.03.528

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Desalination 203 (2007) 168–175

Seawater reverse osmosis with isobaric energy recovery devices


Richard L. Stover
Energy Recovery, Inc., San Leandro CA, USA
Tel. +1 (510) 483-7370; Fax: +1 (510) 483-7371; email: stover@energy-recovery.com

Received 21 March 2006; Accepted 28 March 2006

Abstract
The world increasingly depends on desalting seawater or brackish water for producing suitable and sustainable
supplies of potable water for local populations, tourism, agriculture and industry. The energy cost component of
desalinating seawater has historically been a large factor (up to 70%) of the total cost. There is a limit to the amount
of available energy and an environmental consequence associated with every kilowatt consumed. Along with the
older style centrifugal energy recovery devices (ERDs), there has been a recent proliferation of ERDs that employs
positive displacement mechanisms. These “pressure-equalizing” or isobaric ERDs transfer the energy from the
membrane reject stream directly to the membrane feed stream. This direct, positive displacement approach results
in a net transfer efficiency of up to 97%. This efficiency advantage makes it possible to dramatically improve the
performance of seawater reverse osmosis (SWRO) plants by reducing their energy consumption by as much as 60%
compared to systems operating without energy recovery. In addition to energy savings, isobaric ERDs offer
significant benefits to SWRO plant designers and operators. These include unlimited capacity, reduced high-pressure
pump costs, high efficiency and operational flexibility. The PX pressure exchanger isobaric ERD provides the
additional benefits of maintenance-free operation, fail-safe operation, corrosion avoidance, low vibration, ease of
control and long life. Although the author of this paper is directly associated with Energy Recovery, Inc., a leading
company in isobaric ERD technology, the principles and theories presented in this paper are applicable to all devices
that are based on the positive displacement, isobaric chamber approach.

Keywords: SWRO; Desalination; Pressure exchanger; Energy recovery device

Presented at the EuroMed 2006 conference on Desalination Strategies in South Mediterranean Countries: Cooperation
between Mediterranean Countries of Europe and the Southern Rim of the Mediterranean. Sponsored by the European
Desalination Society and the University of Montpellier II, Montpellier, France, 21–25 May 2006.

0011-9164/07/$– See front matter © 2007 Published by Elsevier B.V.


doi:10.1016/j.desal.2006.03.528
R.L. Stover / Desalination 203 (2007) 168–175 169

1. Introduction operating multiple units in parallel, similar to


membranes.
The desalination market has grown dramatic-
In addition, SWRO systems with centrifugal
ally in recent years, and seawater reverse osmosis
ERDs require high-pressure pumps sized to
(SWRO) technology is leading this growth.
handle the full membrane feed flow. In SWRO
SWRO plants have increased in both number and
systems with isobaric ERDs, the ERD provides
capacity. The largest SWRO plant in the world
only the brine portion of the feed, thus the high-
today is five times larger than the largest plant ten
pressure pump pressurizes only the quantity of
years ago, and another doubling is expected in the
water that results in permeate.
next two years. Several market factors have pro-
The following sections focus on the design
pelled this growth, and incremental improve-
and operation of SWRO systems equipped with
ments in membrane and pump technology have
isobaric ERDs. The reader is directed elsewhere
helped make plant operation more reliable and
for more detailed discussion of the relative merits
cost effective. But the technological breakthrough
of isobaric and centrifugal ERDs [2,3] or to the
most responsible for reducing SWRO energy
manufacturer’s literature for design and opera-
costs and enabling large-scale SWRO plants has
tional details of specific devices.
been the development of isobaric energy recovery
devices (ERDs).
The power required to drive the high-pressure
2. Design
pump(s) is typically the largest component of the
operating cost of SWRO systems. Most of the Optimum SWRO system design requires
pressure energy in the feedwater flowing to the consideration of many factors including system
SWRO membranes leaves the membranes with capacity, capital and operating costs, maintenance
the brine reject water. A number of devices have requirements and equipment reliability. This
been developed to recover pressure energy from section focuses on system capacity and operating
the brine reject stream [1]. These ERDs fall into cost calculations.
two general categories: centrifugal and isobaric
devices. Centrifugal ERDs, including Pelton
2.1. High-pressure pump capacity
wheels, turbochargers and reverse-running
pumps, are limited in capacity and have a maxi- In SWRO systems with isobaric ERDs, the
mum net transfer efficiency of approximately high-pressure pump must only be large enough to
82%. Furthermore, these devices are usually supply the combined flow rate of the permeate,
optimized for a narrow range of flow- and ERD leakage or lubrication, and other volumetric
pressure-operating conditions such that their loss at the operating pressure of the membranes.
efficiency declines with seasonal or operational The relationship between high-pressure pump
changes. Isobaric ERDs, including piston-type flow and permeate flow is illustrated in Fig. 1*.
work exchangers and the rotary PX Pressure In Fig. 1, a dashed-line box is drawn around
Exchanger™ device, provide unlimited capacity the high-pressure pump, the membrane array and
and a maximum operating efficiency of approxi- the high-pressure portion of the ERDs. Nearly all
mately 97%. The positive displacement pressure the water that enters the box to feed the high-
transfer mechanism used in these devices is
similar to that in reciprocating pumps and assures *Energy Recovery, Inc., ERI, PX, Pressure Exchanger,
high efficiency despite flow and pressure varia- PX Pressure Exchanger and the ERI logo are trademarks
tions. Higher ERD capacity is achieved by of Energy Recovery, Inc.
170 R.L. Stover / Desalination 203 (2007) 168–175

(
SE = ⎡QHP PHP − PF / ηHP
⎣ ) (2)
( )
+QBP PHP − PBPI / ηBP +QSP PF / ηSP / QP ⎤

where SE is the SWRO system specific energy,


EHP the high-pressure pump energy consumed,
EBP the booster pump energy consumed, ESP the
supply pump energy consumed, QP the permeate
Fig. 1. Schematic diagram of the SWRO system.
flow rate, QHP the high-pressure pump flow rate,
PHP the high-pressure pump outlet pressure, PF
the high-pressure pump feedwater pressure, ηHP
pressure pump leaves as permeate. A small
the high-pressure pump and motor efficiency, QBP
amount of water — typically less than 2% of the
the booster pump flow rate, PBPI the booster pump
permeate volume — passes through the seals of
inlet pressure, ηBP the booster pump and motor
the ERD. High-pressure pump flow and permeate
efficiency, QSP the booster pump flow rate,and ηSP
flow remain nearly equal regardless of membrane
the supply pump and motor efficiency.
pressure or booster pump flow rate.
Many published comparisons of SWRO ener-
In addition to reducing the required size of the
gy consumption with different ERDs present only
high-pressure pump, isobaric ERDs allow the
system designer to specify the capacity of the the energy consumed by the high-pressure and
ERDs independent of the capacity of the high- booster pumps. This is partly because of the
pressure pump. This decoupling has enabled significant variation in pretreatment and supply
several recent SWRO innovations such as pres- pumping requirements. However, it is important
sure center designs [4]. This decoupling also to consider supply pump energy consumption
allows the system designer and operator to vary when comparing devices because of potentially
membrane recovery and membrane flux rate significant differences in low-pressure water
independently as described below. Such flexi- consumption.
bility is important for obtaining optimal perfor- Between 1% and 2.5% of the brine flow to an
mance from each piece of equipment and for isobaric ERD is consumed as leakage or lubri-
maintaining design productivity throughout a cation flow. The exact lubrication flow rate
plant’s life. depends upon system pressure, temperature, sea-
water and brine flow rates, and device character-
istics. This flow is supplied by the high-pressure
2.2. Energy consumption pump and implicitly appears in the above
The energy required to desalinate with an equation as the difference between QHP and QP.
SWRO system can be expressed in terms of the
specific energy — the energy required per unit
2.3. Overflush
output of permeate — and calculated with the
following equivalent equations: In a piston-type isobaric ERD, the chambers
transition from high- to low- pressure as the
piston contained in the chamber moves back and
(
SE = E HP + E BP + ESP / QP ) (1) forth. A control system is used to manipulate
valves and coordinate the timing of the pressure
R.L. Stover / Desalination 203 (2007) 168–175 171

transitions and the piston movement in each ⎧


chamber with that in other chambers. Each cycle SI = ⎨ S FW × ⎡⎣1 − M × (1 − R − L ) ⎤⎦
of the piston can be thought of as a batch process. ⎩

⎥1−
The control system coordinates these batch pro- ⎡ R × M × (1 − R − L) ⎤
cesses to accommodate the continuous flow of −SP × ⎢
brine from the membranes. Often water must be ⎣ (1 − R ) ⎦
bypassed or dumped during each cycle to main- (4)
⎡ M × (1 − R − L) ⎤ ⎫⎪
tain coordination between all the chambers in an −⎢ ⎥⎬
array. This loss of pumped and treated water is ⎣ (1 − R ) ⎦ ⎪⎭
called overflush. The PX Pressure Exchanger
rotary ERD operates automatically and con- where SI is the salinity increase, R the membrane
tinuously with no overflush. recovery, L the ratio of the ERD lubrication flow
rate to the brine flow rate, and SP the permeate
salinity. Alternately, salinity increase can be very
2.4. Mixing closely approximated with the following empi-
rical equation:
In all commercially available isobaric ERDs,
some contact between the brine and seawater
streams occurs inside the device. As a result,
SI ≅ R × M × 1.025 (5)
these streams mix slightly. The ratio of the
Eqs. (4) and (5) are based on the simplifying
volume of brine that transfers into the seawater to
assumption that only one ionic couple is present,
the flow rate of the seawater, known as volu-
namely sodium chloride. Eqs. (3) through (5)
metric mixing, can be calculated with the follow-
apply at “balanced flow” when the high- and low-
ing equation:
pressure flows through the ERD are equal.

M = ( SHPout − SFW ) ( SHP in − SFW ) 2.5. Membrane performance


(3)
SWRO membrane performance is a function
of a number of variables including membrane
where M is the volumetric mixing, SHPout the type, feedwater temperature, salinity and dis-
salinity of the high-pressure water leaving the solved solids composition, permeate quality
ERD, SFW the salinity of the system feedwater, requirements, and membrane flux and membrane
and SHPin the salinity of the high-pressure brine. conversion or recovery rate. The composition of
Volumetric mixing is a function of the mixing the membrane feedwater is affected by mixing in
characteristics of the specific ERD and the ratio the ERD, and thus is a function of the compo-
of seawater and brine fed to the device but is sition of the brine reject flowing from the
independent of the membrane recovery rate. membranes. Because membrane selectivity varies
Mixing increases the membrane feed salinity to with membrane type, flux and ion type, the
slightly above the salinity of the system feed. The composition of the brine differs from the com-
ratio of the increase in membrane feedwater position of the feedwater, and those differences
salinity to the system feedwater salinity — the vary with system operating conditions. Therefore,
salinity increase — can be estimated by mass an accurate prediction of membrane performance
balance using the following equation: would require concurrent consideration of ERD
172 R.L. Stover / Desalination 203 (2007) 168–175

Fig. 3. Overall plant cost optimization diagram.

Fig. 2. Case Study: SWRO system specific energy vs.


tion and that an optimal minimum specific energy
membrane variables. occurs between approximately 35% and 45%
recovery.

mixing. Unfortunately, at the time of this writing,


no commercially available membrane projection 2.6. Overall cost
model allows the system designer to account for Although Fig. 2 suggests that lower energy
ERD mixing. consumption can be achieved with a greater num-
An approximate membrane design can be ber of membranes, the SWRO system designer
developed by ignoring individual ion selectivity must also consider capital costs. System capacity
and balancing and solving Eq. (4) to estimate the can be optimized by incorporating all capital and
bulk membrane feed salinity. The membrane pro- operating costs into an optimization diagram of
jection model can then be run to provide an the type illustrated in Fig. 3.
estimate of the membrane operating and dis-
charge pressures. These process parameters and
Eq. (2) can then be used to estimate energy 2.7. Isobaric ERD cost comparison
consumption. The relationship between SWRO Commercially available isobaric energy recov-
system specific energy consumption, membrane ery devices operate with different efficiencies,
recovery and membrane flux for a typical system lubrication flows and mixing rates. As described
is illustrated in Fig. 2. above, all these variables affect overall SWRO
In Fig. 2, specific energy is expressed in units operating costs. Different devices can be com-
of kilowatt hours per cubic meter of permeate pared by quantifying the pumping energy re-
(kWh/m3) and flux in units of liters of permeate quired to produce a given flow rate of desalinated
per square meter of membrane surface per hour permeate with an SWRO system equipped with
(lmh). The estimated specific energy data pre- the device. A comparison of a piston-type
sented in Fig. 2 were derived using a conven- isobaric ERD and the ERI PX-220 device is
tional membrane projection model, efficiency presented in Fig. 4.
data from commercially available pumps, Eq. (4) The piston-type ERD performance data pre-
and published operating data for the PX-220 sented in Fig. 4 are based recently published data
Pressure Exchanger device. Specific energy was for the DWEER* 1100 [5]. The differences
calculated with Eq. (2) above. These data indicate
that lower flux rates and lower recovery rates
generally result in lower system energy consump- *DWEER is a trademark of DWEER Technology Ltd.
R.L. Stover / Desalination 203 (2007) 168–175 173

Fig. 4. Isobaric energy recovery device performance


comparison.

between the performance of a piston-type ERD a piston ERD, and the result in the case illustrated
and the PX Pressure Exchanger rotary ERD are in Fig. 4 is a 1.4 bar increase in operating pres-
evident in the data in Fig. 4. No overflush is sure. The lubrication flow required by the two
required with the PX device, but a 3% overflush types of devices is almost identical and the high-
associated with flow bypass between cycles is and low-pressure differentials through the PX
typical with a piston ERD. The salinity increase device are lower. As a result, the efficiency of the
caused by the PX device is higher than caused by PX device is higher. When all these factors are
174 R.L. Stover / Desalination 203 (2007) 168–175

considered, the specific energy consumption of function of flow rate or operating pressure.
SWRO systems equipped with these two different Therefore, controls are required only for the
isobaric ERDs is the same despite differences in operation of the ERD itself and for keeping the
individual performance characteristics. flows and pressures within the capacity limits of
the ERD. A PX Pressure Exchanger device ope-
rates automatically such that only SWRO system
3. Operation flow and pressure controls are necessary. Speci-
fically, one high-pressure flow meter and pressure
Although the energy consumption is similar in gauge and one low-pressure flow meter and pres-
SWRO systems equipped with different ERD sure gauge are required to operate a PX device
technologies, there are significant operational array.
differences. Specifically, recovery variation, flux Piston-type ERDs require additional controls
variation, system control, maintenance and device to operate valves and to limit piston movement.
life differences should be considered. Each ERD in a piston-ERD array must be
operated individually and in conjunction with the
3.1. Recovery and flux variation other devices in the array to minimize overflush/
bypass and to prevent excessive pulsations.
Isobaric ERDs allow the SWRO system
operator to vary membrane flux and recovery
independently. This concept is illustrated with 3.3. Maintenance
reference to Fig. 1. If the flow rate of the booster ERD maintenance must be considered in
pump is set with a variable frequency drive to be SWRO system operation because of the direct
equal to the flow rate of the high-pressure pump, costs of the maintenance and because of the cost
the system will operate at 50% recovery. If the of the associated system downtime. The PX
flow rate of the booster pump is increased to device requires no periodic maintenance. If a PX
double the flow rate of the high-pressure pump, rotor stops spinning for any reason, water flows
the system will operate at 33% recovery. Neither through the device unimpeded because there are
of these operations significantly changes the no pistons or barriers in the flow paths through
high-pressure pump flow rate nor the permeate the device. Flow through a stopped rotor will
flow rate. Membrane flux can also be adjusted cause higher salinity at the membranes, however,
independent of recovery, although less easily, by large SWRO systems that employ multiple PX
directly manipulating high-pressure pump or devices can operate indefinitely and safely with
permeate flow or pressure using a control valve, one or more stopped rotors. This fail-safe design
variable frequency drive or an adjustable supply- feature provides plant operators the latitude to
booster pump. The decoupling of high-pressure- postpone or schedule maintenance when conven-
pump operation and ERD and booster-pump ient. The open flow channels through the PX
operation provides significant design and opera- device also facilitate easy startup and shutdown.
tional flexibility. Piston-type isobaric ERDs do require periodic
maintenance of the piston and the all the valves
and subsystems necessary for device operation.
3.2. SWRO system and ERD control
Piston ERDs, which have barriers in the flow
An SWRO system generally need not be paths, can require immediate emergency main-
manipulated to sustain peak ERD performance tenance in the event of device failure. Device
because isobaric ERD efficiency varies little as a failure can shutdown an SWRO system, and in
R.L. Stover / Desalination 203 (2007) 168–175 175

plants with pressure-center or collector designs, C minimal simple controls


an individual device shutdown can stop the entire C fail-safe operation
plant. Lost uptime, if it occurs, is a significant C maintenance free operation
cost. C corrosion avoidance
C low vibration
C long life
3.4. Device life
Factors that adversely affect the longevity of These design and operational advantages have
SWRO equipment include corrosion, vibration not only made isobaric ERDs the best choice for
and abrasion (wear). Pressure transfer in the PX energy recovery in SWRO systems, they have
device takes place in a ceramic rotor enclosed in also enabled the tremendous growth and success
ceramic components. This ceramic is the same of SWRO for desalination applications.
material used in bullet-proof sheathing. It is
approximately three times harder than steel and
never corrodes in seawater. Vibration and pul-
sation are negligible. The single moving part in Acknowledgements
the PX device — the rotor — floats on a hydro-
The author wishes to acknowledge ERI’s
dynamic bearing of seawater which prevents
Mr. Jeremy Martin and Mr. Ian Cameron for their
solid–solid contact and thereby avoids abrasion
assistance in developing the salinity-increase
wear. This combination of physical and dynamic
equations presented in this paper.
characteristics assures maximum device life.
Metal components in other ERDs corrode, wear
and fatigue which reduces performance and can
eventually result in device failure. Specifically, References
valve wear manifests as excess leakage and piston
[1] R.L. Stover, Development of a fourth generation
wear as excess mixing. To prevent unexpected
energy recovery device — A CTO’s notebook,
shutdowns, piston-type ERDs require periodic Desalination, 165 (2004) 313–321.
maintenance and component replacement. [2] R.L. Stover, Energy recovery device performance
analysis, Water Conditioning Purif. Internat.,
accepted for publication.
4. Conclusions [3] B. Schneider, Selection, operation and control of a
work exchanger energy recovery system based on the
Isobaric ERDs offer significant benefits to Singapore project, Desalination, 184 (2005) 177–
SWRO plant designers and operators. These 190.
include unlimited capacity, reduced high-pressure [4] B. Lieberman and M. Faigon, Flexible 3-centre setup
pump costs, high efficiency and operational saves costs in Ashkelon, Desalination Water Reuse,
flexibility. Among the commercially available 1414 (2005) 19–21.
isobaric ERDs, the PX Pressure Exchanger iso- [5] V. Verbeek, Presented at IDA Conference, Singa-
baric ERD provides the following advantages: pore, 2005.

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