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SIMULATION No. 2
CONSTANT PRESSURE CALORIMETRY

I. Introduction

Heat flow between system and surroundings can be studied under


Calorimetry. When two bodies at different temperature are in contact the heat
energy normally moves from a hotter body to a colder body. If these two remain
in contact, the system of two bodies will eventually reach a thermal equilibrium.
In the energy from an exothermic chemical reaction is absorbed in a container of
water, the change in temperature of the water provides a measure of the amount
of heat absorbed and the amount of heat released by the reaction.
The heat capacity of a substance is the capacity of an object to give or
take up heat. The greater the heat capacity of an object the greater the energy
required to heat up the object.
C =mc where C= Heat Capacity of the substance, m =mass of the
substance, and c = specific heat of the substance
Specific heat is the amount of heat required raising the temperature of a1
gram substance to 1 o C. if the temperature is available you can calculate for the
heat evolve using;
q=mcΔT
Like enthalpy change, q is positive for endothermic reactions and negative
for exothermic reactions
In constant pressure calorimeter the heat evolved is absorbed by the
water. ΔH of reactions can be calculated using the formula below.
ΔH rxn = -qwater
qwater = mass of water x Specific heat of water x ΔTwater
ΔTwater = Final temp of water - Initial temp of water.
Specific heat of water = 4.184 J/g o C

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II. Learning Objectives

1. To use calorimetric data to calculate enthalpy changes.


2. To determine through the simulation experiment whether the materials
increase or decreases its temperature.
3. To determine the relationship among the variables: heat, mass, specific
heat and change in temperature

III. Principle of Method


Weighing - Weighing is a method to measure the heaviness of an object or a
substance. In the simulation, instead of measuring the mass of the substance,
there is a designated mass to be set for every substance that is used in the
experiment which is 30.5 grams for Copper (Cu), Silver (Ag), Tin (Sn) and the
unknown metal I. For the next simulation, the mass is set to 18.5 grams for
Sodium Chloride (NaCl), Sodium Hydroxide (NaOH), Ammonium Nitrate
(NH4NO3) and the unknown compound I. With the help of weighing and
setting the right mass for each substance helps to determine and observe the
changes in heat from different metals.

Dissolving - To dissolve means to move a solute into a solution in chemistry.


Dissolution is another word for dissolving. Dissolution often entails a solid
transitioning into a liquid phase, although it can also involve additional
changes. In the simulation, the Sodium Chloride (NaCl), Sodium Hydroxide
(NaOH) and the Ammonium Nitrate (NH4NO3) were dissolved when they
were placed together with water in the calorimeter. These compounds mixed
with water and they dissolve to help the simulation and the distribution to go
well in the calorimeter.

IV. Materials

Glassware Apparatus/Equipment Reagents


300mL Beaker Calorimeter 30.5g of copper
600mL Beaker Weighing Balance 30.5g of silver and tin
Thermometer 150g of water in
Stirring Rod 30.5g of unknown
metal 1
18.5g of Nacl
18.5g of NaOH
18.5g of NH4NO3
18.5g of unknown
compound 1

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V. Methodology

The simulation provides the ability to manipulate variables of mass or


volumes, temperature and type of substance and observe how change these
variables affect the initial and or final temperature and the amount of heat
exchanged in a constant pressure calorimeter.

https://media.pearsoncmg.com/bc/bc_0media_chem/chem_sim/calorimetry/C
alor.php

Please open the link to access the Virtual Calorimeter simulation. Once in the
website please choose Experiment tab and click Run Experiment.

Heat evolves from heated metals


A. Steps
1. In a beaker section click Solids tab. Choose Copper as your metal. Set the mass
of the Cu to 30.5 grams. While its temperature to 200 o C. Click next.

2. To set the calorimeter. Click the liquids tab and choose water as your substance.
Set the mass to 150 grams. Let the temperature of water fixed at 20 o C. Then

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click next.

3. To run the experiment, click the show graph view and show microscopic view
and click START.

4. Document your experiment and calculate for heat evolve in water and from the
metal.
5. Repeat the procedure 1 to 4 but instead of Cu choose Silver (Ag) and Tin (Sn).
For your fourth metal to test, Group 1,3,5 chose the unknown metal I and Group
2,4,6 chose the unknown metal II.

Heat evolves from dissolve substance


B. Steps
1. Reset the calorimeter and in beaker click solid tab and choose NaCl as your
substance and set the mass to 18.5 grams Temperature is fixed at 20 o C.
2. To set the calorimeter. Click the liquids tab and choose water as your substance.
Set the mass to 150 grams. Let the temperature of water fixed at 20 o C. Then
click next.
3. To run the experiment, click the show graph view and show microscopic view
and click START.
4. Document your experiment and calculate for heat evolve in water and from the
substance.

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5. Repeat the procedure 1 to 4 but instead of Sodium Hydroxide (NaOH) and


Ammonium Nitrate (NH4NO3). For your fourth Substance to test, Group 1,3,5
chose the unknown Compound I and Group 2,4,6 chose the unknown Compound
II.

VI. Data and Results

Table 1. Heat of evolve in heated metals

Initial Changes in
Masses
Temperature Temperature
Equilibrium
Metals Mass Mass Initial T Initial T
temperature ΔT
of of of of ΔT metal
Water
Metal Water Metal Water
Cu 30.5 g 150 g 200 o C 20 o C 23.31 o C -176.69 o C 3.31 o C
Ag 30.5 g 150 g 200 o C 20 o C 22.03 o C -177.97 o C 2.03 o C
Sn 30.5 g 150 g 200 o C 20 o C 21.88 o C -178.12 o C 1.88 o C
Unknown
30.5 g 150 g 200 o C 20 o C 23.33 o C -176.67 o C 3.33 o C
metal

Table 2. Heat evolves from dissolve substance


Initial Equilibrium Changes in
Masses
Temperature temperature Temperature
Metals Mass Initial T Initial T
Mass of Thermal ΔT ΔT
of of of
Water Temperature metal Water
Metal Metal Water
NaCl 18.5 g 150 g 20 o C. 20 o C. 18.26 o C -1.74 o C -1.74 o C
NaOH 18.5 g 150 g 20 o C. 20 o C. 49.20 o C 29.2 o C 29.2 o C
(NH4NO3) 18.5 g 150 g 20 o C. 20 o C. 11.58 o C -8.42 o C -8.42 o C
Unknown 18.5 g 150 g 20 o C. 20 o C. 32.52 o C 12.52 o C 12.52 o C
substance

Calculation:
For each given metals calculate the following.
qwater = (mass of water)(specific heat of water)(∆Twater)
qwater = (150 g)(4.184J/g o C)(3.31oC)

qwater = 2077.356 J

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ΔH rxn = qwater

ΔH rxn = -2077.356 J

Specific heat of metal (c)=


Copper (Cu)

c(Cu) = -0.39 J/(goC)


Specific heat of Cu =
𝑞
𝑐=
mΔT
+2077.36 𝐽
𝑐=
(30.5 g) (−176.69 °C)
−2077.36 𝐽
𝑐=
−5389.05 g °C

c(Cu) = -0.39 J/(goC)

Silver (Ag)

Specific heat of Ag =
𝑞
𝑐=
mΔT

+1274.03 𝐽 c(Ag) = -0.23 J/(goC)


𝑐=
(30.5 g) (−177.97 °C)
+1274.03 𝐽
𝑐=
−5428.085 g °C

c(Ag) = -0.23 J/(goC)

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Tin (Sn)

c(Sn) = -0.22J/(goC)
Specific heat of Sn=
𝑞
𝑐=
mΔT
+1179.89 𝐽
𝑐=
(30.5 g) (−178.12 °C)
+1179.89 𝐽
𝑐=
−5432.66 g °C

c(Sn) = -0.22J/(goC)

Unknown Metal I

c = -0.39 J/(goC)
Specific heat of Unknown Metal 1=
𝑞
𝑐=
mΔT
+2089.91 𝐽
𝑐=
(30.5 g) (−176.67 °C)
+2089.91 𝐽
𝑐=
−5388.435 g °C

c = -0.39 J/(goC)

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Heat capacity of metal (C) =


Copper (Cu)

Heat capacity of Cu = C = -11.90 J/oC


C = mc
C = (30.5 g) (-0.39 J/(goC)
C = - 11.743 J/oC

C = -11.90 J/oC

Silver (Ag)

Heat capacity of Ag = C = -7.015 J/oC


C = mc
C = (30.5 g) (-0.23 J/(goC)
C = - 7.015 8 J/oC

C = -7.015 J/oC

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Tin (Sn)

Heat capacity of Sn = C = -6.71 J/oC

C = mc
C = (30.5 g) (-0.22 J/(goC)
C = - 6.71 J/oC

C = -6.71 J/oC

Unknown Metal I

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For each given Substance calculate the following.


1. NaCl
qwater = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 ℎ𝑒𝑎𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 (𝑐) × ∆𝑇𝑤𝑎𝑡𝑒𝑟
= (150 𝑔 )(4.184 𝐽/𝑔℃)(−1.74℃)
𝒒𝒘𝒂𝒕𝒆𝒓 = −𝟏𝟎𝟗𝟐. 𝟎𝟐 𝑱

∆𝐻𝑟𝑥𝑛 = −𝑞𝑤𝑎𝑡𝑒𝑟
∆𝐻𝑟𝑥𝑛 = −(−1092.02 𝐽)
1
∆𝐻𝑟𝑥𝑛 = 1092.02 𝐽 × = 𝟏. 𝟎𝟗 𝒌𝑱
1000

ΔH rxn = KJ/mol
𝑁𝑎 = 23 𝑔
∆𝐻𝑟𝑥𝑛 = 1.09 𝑘𝐽 𝑓𝑜𝑟 18.5 𝑔 𝑜𝑓 𝑁𝑎𝐶𝑙
𝐶𝑙 = 35 𝑔
1.09 𝑘𝐽 58 𝑔 𝑁𝑎𝐶𝑙
∆𝐻𝑟𝑥𝑛 = × = 𝟑. 𝟒𝟐 𝒌𝑱/𝒎𝒐𝒍
18.5 𝑔 𝑁𝑎𝐶𝑙 1 𝑚𝑜𝑙 𝑁𝑎𝐶𝑙 𝑁𝑎𝐶𝑙 = 58 𝑔

Thermochemical equation

𝑵𝒂𝑪𝒍(𝒔) + 𝑯𝟐 𝑶(𝒍) → 𝑵𝒂+
(𝒂𝒒) + 𝑪𝒍(𝒂𝒒) ∆𝑯 = 𝟑. 𝟒𝟐 𝒌𝑱/𝒎𝒐𝒍

2. NaOH
qwater = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 ℎ𝑒𝑎𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 (𝑐) × ∆𝑇𝑤𝑎𝑡𝑒𝑟
= (150 𝑔 )(4.184 𝐽/𝑔℃)(29.2℃)
𝒒𝒘𝒂𝒕𝒆𝒓 = 𝟏𝟖𝟑𝟐𝟓. 𝟗𝟐 𝑱

∆𝐻𝑟𝑥𝑛 = −𝑞𝑤𝑎𝑡𝑒𝑟
∆𝐻𝑟𝑥𝑛 = −(18325.92 𝐽)
1
∆𝐻𝑟𝑥𝑛 = −18325.92 𝐽 × = −𝟏𝟖. 𝟑𝟑 𝒌𝑱
1000

ΔH rxn = KJ/mol
𝑁𝑎 = 23 𝑔
∆𝐻𝑟𝑥𝑛 = −18.33 𝑘𝐽 𝑓𝑜𝑟 18.5 𝑔 𝑜𝑓 𝑁𝑎𝑂𝐻
𝑂 = 16 𝑔
−18.33 𝑘𝐽 40 𝑔 𝑁𝑎𝑂𝐻
∆𝐻𝑟𝑥𝑛 = × = −𝟑𝟗. 𝟔𝟑 𝒌𝑱/𝒎𝒐𝒍 𝐻 =1𝑔
18.5 𝑔 𝑁𝑎𝑂𝐻 1 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
𝑁𝑎𝑂𝐻 = 40 𝑔

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Thermochemical Equation

𝑵𝒂𝑶𝑯(𝒔) + 𝑯𝟐 𝑶(𝒍) → 𝑵𝒂+
(𝒂𝒒) + 𝑶𝑯(𝒂𝒒) ∆𝑯 = −𝟑𝟗. 𝟔𝟑 𝒌𝑱/𝒎𝒐𝒍

3. NH4NO3
qwater = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 ℎ𝑒𝑎𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 (𝑐) × ∆𝑇𝑤𝑎𝑡𝑒𝑟
= (150 𝑔 )(4.184 𝐽/𝑔℃)(−8.42℃)
𝒒𝒘𝒂𝒕𝒆𝒓 = −𝟓𝟐𝟖𝟒. 𝟑𝟗 𝑱
∆𝐻𝑟𝑥𝑛 = −𝑞𝑤𝑎𝑡𝑒𝑟
∆𝐻𝑟𝑥𝑛 = −(−5284.39 𝐽)
1
∆𝐻𝑟𝑥𝑛 = 5284.39 𝐽 × = 𝟓. 𝟐𝟖 𝒌𝑱
1000

ΔH rxn = KJ/mol 𝑁 = 14 𝑔 = 2(14) = 28

∆𝐻𝑟𝑥𝑛 = 5.28 𝑘𝐽 𝑓𝑜𝑟 18.5 𝑔 𝑜𝑓 𝑁𝐻4 𝑁𝑂3 𝐻 = 1 𝑔 = 4(1) = 4

5.28𝑘𝐽 80 𝑔 𝑁𝐻4 𝑁𝑂3 𝑂 = 16 𝑔 = 3(16) = 48


∆𝐻𝑟𝑥𝑛 = × = 𝟐𝟐. 𝟖𝟑 𝒌𝑱/𝒎𝒐𝒍
18.5 𝑔 𝑁𝐻4 𝑁𝑂3 1 𝑚𝑜𝑙 𝑁𝐻4 𝑁𝑂3 𝑁𝐻4 𝑁𝑂3 = 80 𝑔

Thermochemical Equation
𝑵𝑯𝟒 𝑵𝑶𝟑 (𝒔) + 𝑯𝟐 𝑶(𝒍) → 𝑵𝑯+ −
𝟒 (𝒂𝒒) + 𝑵𝑶𝟑 (𝒂𝒒) ∆𝑯 = 𝟐𝟐. 𝟖𝟑 𝒌𝑱/𝒎𝒐𝒍

4. Unknown Substance I
𝑵𝑯𝟒 𝑵𝑶𝟑 (𝒔) + 𝑯𝟐 𝑶(𝒍) → 𝑵𝑯+ −
𝟒 (𝒂𝒒) + 𝑵𝑶𝟑 (𝒂𝒒) ∆𝑯 = 𝟐𝟐. 𝟖𝟑 𝒌𝑱/𝒎𝒐𝒍

qwater = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 × 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 ℎ𝑒𝑎𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 (𝑐) × ∆𝑇𝑤𝑎𝑡𝑒𝑟


= (150 𝑔 )(4.184 𝐽/𝑔℃)(12.52℃)
𝒒𝒘𝒂𝒕𝒆𝒓 = 𝟕𝟖𝟓𝟕. 𝟓𝟓 𝑱
∆𝐻𝑟𝑥𝑛 = −𝑞𝑤𝑎𝑡𝑒𝑟
∆𝐻𝑟𝑥𝑛 = −(7857.55 𝐽)
1
∆𝐻𝑟𝑥𝑛 = −7857.55 𝐽 × = −𝟕. 𝟖𝟔 𝒌𝑱
1000

ΔH rxn = KJ/mol
∆𝐻𝑟𝑥𝑛 = −7.86𝑘𝐽 𝑓𝑜𝑟 18.5 𝑔 𝑜𝑓 𝑈𝑛𝑘𝑛𝑜𝑤𝑛 𝑆𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒

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−7.86 𝑘𝐽 1 𝑔 𝑈𝑛𝑘𝑛𝑜𝑤𝑛 𝑆𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒


∆𝐻𝑟𝑥𝑛 = ×
18.5 𝑔 𝑈𝑛𝑘𝑛𝑜𝑤𝑛 𝑆𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 6.0221367 × 1023 𝑚𝑜𝑙
= −𝟕. 𝟎𝟓𝟐𝟖𝟓𝟐𝟕𝟐𝟑 × 𝟏𝟎−𝟐𝟓 𝒌𝑱/𝒎𝒐𝒍
Thermochemical Equation

VII. Interpretation
As you can see in the Table 1, the equilibrium temperature between water and
Cu is 23.31 which means that the Cu, lose heat of -176.69 °C, since it is at the higher
temperature initially. The water gains heat of 3.31 °C as it is at the lower temperature
initially. The Ag lose heat of -177.97 °C, and the water gains heat with 2.03 °C. The Sn
lose heat with -178.12°C, and the water gains heat of 2.03 °C. And lastly, the unknown
metal lose heat of -176.67 °C, and the water gains heat with 3.33 °C. That being said,
the heat lost by the metal is exothermic, and the heat gained by the water is
endothermic.
In table 2, the metal and water have the same initial temperature. The water and
Nacl have the same changes in temperature at -1.74 °C with equilibrium temperature at
18.26°C. Both of metal and water only lose heat. The water and NaOH have the same
changes in temperature at 29.2 °C with equilibrium temperature at 49.20°C. Both metal
and water only gain heat. The water and (NH4NO3) have the same changes in
temperature at -8.42 °C with equilibrium temperature at 11.58°C Both metal and water
only lose heat. Lastly, the water and unknown substance have the same changes in
temperature at 12.52 °C with equilibrium temperature at 32.52°C. Both metal and water
only gain heat. In this case, with the same initial temperature of water and metal, it will
either gain or
For the calculation, the exothermic reaction is energetically downhill, if ΔHrxn is
negative; thus, the enthalpy of the products is less than the enthalpy of the reactants.
On the other hand, an endothermic reaction is energetically uphill if ΔHrxn is positive,
which means that the enthalpy of the products is greater than the enthalpy of the
reactants.

VIII. Conclusion
For the overall simulation, we have observed and noticed that heat plays an
important role as we conduct the simulation. In this simulation, we have measured the
amount of heat that is absorbed or released during a reaction. The heat in the metal will
transfer to the water until it reaches thermal equilibrium. In the first experiment that
involves the different metals like Copper (Cu), Silver (Ag), and Tin (Sn), we have

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noticed that the water absorbs the heat from the metal and the metal loses heat and this
is where they will reach thermal equilibrium. On the other hand, when the water and
metal have the same initial temperature, it will either loss or gain heat. Another thing is
that, the form or kind of solid also affects the simulation because on the first simulation,
we use solid metals in which is requires higher temperature to be dissolved in the
calorimeter and on the other hand, the second simulation use powdered solids in which
it dissolves and the powdered solids are distributed well throughout the calorimeter that
is why it doesn’t require a higher temperature to dissolve and mix properly with water.

IX. Question Analysis

1. After putting the metals in the calorimeter, does the water inside the
container gained the same temperature as the initial temperature of the
metal? Yes or no, and why? Give a brief explanation regarding the concept
behind.
No, the water gained a temperature to attain thermal equilibrium, not the
metal's initial temperature. When a heated metal at 200 degrees Celsius and
a water at 20 degrees Celsius are placed on a calorimeter, the heat of the
metal will transfer from the metal to the water until the two substances attain
the same temperature or reach thermal equilibrium. The temperature of the
metal would decrease while the temperature of the water would increase until
they reached thermal equilibrium. With that, the metal loses heat since it is at
the higher temperature initially. The water gains heat as it is at the lower
temperature initially. The heat lost by the metal is exothermic, and the heat
gained by the water is endothermic.
2. Look for the literature specific heat of each given metals and calculate the
percent difference of your calculated specific heat and literature specific heat.
What might be the factor of not getting the exact literature specific heat in
conducting the experiment in real life?

The temperature change may be a factor in not obtaining the exact


literature specific heat when conducting the experiment in real life. When the
two bodies at different temperatures come into contact, the heat energy will
move and change. In this experiment, the temperature changes after mixing
each metal with water at different temperatures. As a result, when we
calculated the specific heat based on the temperature change in each metal,
we got a different result than the literature specific heat.

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3. After dissolving each compound in the calorimeter what type of heat of


reaction indicates the temperature change? Is it exothermic or endothermic?
Explained further your answer in molecular level.
After dissolving each compound in the calorimeter, the type of heat
reaction that indicates the temperature change is an exothermic reaction.
Which means more energy is released rather than absorbed when the bonds
are formed in the products. In which, in the shown microscopic view of the
simulation during the dissolving of compounds in the calorimeter, it is very
evident that as energy is released, the bonding of molecules is gradually
formed in the products. But as the simulators noticed, the speed of bonding of
molecules or particles is dependent on the types of metal and substances that
are being dissolved in 150 g of water (H2O)

X. Documentation

Picking and choosing the mass of Copper

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Setting the temperature

Selecting the mass of the liquid

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Let the fix temperature then press next

Click show graph view and microscopic


view, then click start

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Record the results

Picking and choosing the mass of Silver

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Setting the temperature

Selecting the mass of the liquid

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Let the fix temperature then press next

Check both boxes then press start.

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Choosing the mass of Tin

Setting the temperature of the solid

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Choosing the mass of the liquid

Selecting both boxes then starting

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Choosing mass for Unknown metal 1

Selecting the temperature

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Selecting the liquid mass

Check both boxes then press start

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Selecting mass for NaCl

Selecting the liquid mass

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Click both boxes then press start

Selecting mass for NaOH

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Selecting the liquid's mass

Checking both boxes then press start

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Selecting mass for NH4NO3

Selecting the water's mass

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Starting the experiment

Choosing Unknown compound 1's mass

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Choosing the liquid's mass

Enable both views before pressing start

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XI. References

Laboratory Simulation Guide


https://www.youtube.com/watch?v=iTqmFteomjU
Weighing. (n.d.). Systems Chemistry. Retrieved October 26, 2022, from
https://www.ru.nl/systemschemistry/equipment/analysis-
separation/weighing/

Dissolve Definition in Chemistry. (2019b, May 8). ThoughtCo.


https://www.thoughtco.com/definition-of-dissolve-604432

XII. Member’s Participation


Abejero, Jaila Marie S. • Data and Results
• Calculation (Substances)
• Question Analysis 1
Enriquez, Roi Christian F. • Data and Results
• Calculation (Metals)
Goot, John Carlo A. • Materials
• Data and Results
• Question Analysis 3
• Documentation
• Re-checking of calculations
Pampan, John Carlo A. • Data and Results
• Calculation (Metals)
• Question Analysis 3
Pellos, Jamile P. • Data and Results
• Calculation (Substances)
• Question Analysis 2
Rufo, John Lawrence L. • Principle of Method
• Data and Results
• Conclusion
• Question Analysis 2
Salitorno, Angela Maureen E. • Learning Objectives
• Data and Results
• Interpretation
• Question Analysis 1
• Re-checking of calculations

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