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    Reaction of Ketone Complete

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    Joko Susilo
    This document summarizes several reactions of ketones: 1) Ketones can be oxidized to carboxylic acids using potassium permanganate or dichromate in dilute sulfuric acid with heat or reflux. 2) Ketones can be reduced to alcohols using sodium borohydride in aqueous solution at room temperature, or lithium aluminum hydride in dry ether. 3) Ketones react with iodine in the presence of sodium hydroxide to form a pale yellow precipitate of triiodomethane, known as the iodoform reaction.

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    Reaction of Ketone Complete

    Uploaded by

    Joko Susilo
    36 views1 page
    This document summarizes several reactions of ketones: 1) Ketones can be oxidized to carboxylic acids using potassium permanganate or dichromate in dilute sulfuric acid with heat or reflux. 2) Ketones can be reduced to alcohols using sodium borohydride in aqueous solution at room temperature, or lithium aluminum hydride in dry ether. 3) Ketones react with iodine in the presence of sodium hydroxide to form a pale yellow precipitate of triiodomethane, known as the iodoform reaction.

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    reaction ketones

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    This document summarizes several reactions of ketones: 1) Ketones can be oxidized to carboxylic acids using potassium permanganate or dichromate in dilute sulfuric acid with heat or reflux. 2) Ketones can be reduced to alcohols using sodium borohydride in aqueous solution at room temperature, or lithium aluminum hydride in dry ether. 3) Ketones react with iodine in the presence of sodium hydroxide to form a pale yellow precipitate of triiodomethane, known as the iodoform reaction.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    36 views1 page

    Reaction of Ketone Complete

    Uploaded by

    Joko Susilo
    This document summarizes several reactions of ketones: 1) Ketones can be oxidized to carboxylic acids using potassium permanganate or dichromate in dilute sulfuric acid with heat or reflux. 2) Ketones can be reduced to alcohols using sodium borohydride in aqueous solution at room temperature, or lithium aluminum hydride in dry ether. 3) Ketones react with iodine in the presence of sodium hydroxide to form a pale yellow precipitate of triiodomethane, known as the iodoform reaction.

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    Reaction of Ketones

    H3 H3
    C C
    OH OH
    H 3C C C CH3 reduction
    H 3C C CH3 H3C C CH3
    H KMnO4 or K2Cr2O7 H
    dil. H2SO4
    KMnO4
    Heat or reflux dil. H2SO4
    reduction heat NaBH4 (aq), r.t
    oxidation or 1. LiAlH4, dry ether
    2. H2O, r.t
    or H2 (g), Pt, heat
    O

    H 3C C CH3
    HCN
    trace NaOH or
    trace NaCN
    H2 10oC - 20oC
    C I2
    NaOH (aq) 2,4-DNPH
    H 3C C O – Na + warm r.t

    + CHI3 (s) OH

    (pale yellow ppt) H3C C CH3


    triiodomethane/ iodoform O2N
    reaction CN nucleophilic
    addition
    H 3C C N N NO2
    H
    H 3C condensation (orange ppt)

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