WORK BOOK

TH
11 CLASS
Chapter-1
Some Basic Concept of
Chemistry
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 CONTENTS

1. Atomic & Molecular Mass

2. Mole Concept
3. Percentage Composition & Empirical
Formula
4. Stoichiometry
5. Concentration Terms
6. Limiting Reagent

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CHAPTER : 01 (SOME BASIC CONCEPT OF CHEMISTRY)
Topic – 1 : ATOMIC AND MOLECULAR MASS (SHEET-1)
Find molecular mass of the following:

1. Glucose
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2. Sucrose
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3. Urea
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4. Crystalline oxalic acid
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5. Na2SO4
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6. CaCO3
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7. Acetic acid
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8. NaOH
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9. CaCl2
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10. H2SO4
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11. HNO3
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12. HCl
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13. Oxygen gas
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14. Nitrogen gas
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15. H2O

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16. NH3
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17. Sulphur Molecule
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18. H3PO4
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19. Ethylene glycol
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20. Octane
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21. Heptane
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22. Chloroform
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23. CH2Cl2
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24. CH4
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25. CH3-CH2-OH
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26. Benzene
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27. CCl4
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28. Mohrs Salt

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29. Magnesium carbonate
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30. Aluminium sulphate

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Topic – 2 : MOLECONCEPTS (SHEET-1)

1. Define 1 amu ?

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2. What is the mass of one proton in gm?

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3. What is the molecular mass of phosphorous and sulphur?

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4. What is the unit of atomic mass?

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5. How many protons will together weigh 1 gm ?

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6. Calculate the mass of one atom of carbon in gram?

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7. How much copper can be obtained from 100 g of copper sulphate (CuSO 4)?

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8. Prove that the volume of one mole of gas is 22.4 lit at STP?

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MOLE CONCEPT (SHEET-2)

1. Calculate the mass of one mole proton in gram?

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2. What is the charge of one mole electrons in coloumb?

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3. How many electrons are present in 1 ml of water?

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4. Calculate the number of oxygen atoms are present in 1.8 gram of Glucose?

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5. The volume of 11 gram of CO2 at STP is

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6. What is the mass of a molecule of carbon-14 dioxide (14CO2) in gm?

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7. How are 0.50 mol Na2CO3 and 0.50 M Na2CO3 different?

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8. How many number of atoms are present in 52 u of He?

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9. How many atoms of magnesium are present in 96 u of Mg?

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10. Calculate the number of carbon atoms in 34.2 g of Sucrose.

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11. How many atoms of magnesium are present in 144 g of Mg? [Molar mass of Mg = 24 g mo1 -1]

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12. Calculate the number of atoms present in 11.5 litres of H 2 at N.T.P.

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13. Calculate the mass of 1  1022 molecules of CuSO45H2O.

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14. If insulin contains 3.4% sulphur then, calculate the minimum molecular mass of the insulin.

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15. From 200 mg of CO2, 1021 molecules are removed. How many moles of CO2 are left?

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16. In three moles of ethane, calculate the following :

(i) no. of moles of carbon atom.

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(ii) no. of moles of hydrogen atoms.

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(iii) no. of molecules of ethane.

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17. Calculate the number of moles in each of the following amounts of materials :

(i) 10. 0 g of CaCO3

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(ii) 1  1023 molecules of CO2

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18. 6  1024 atoms of an element weigh 200 g. If this element form diatomic gas, then calculate the
molar mass of gas.

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19. How much copper can obtained from 100 g of copper sulphate? [At. mass of Cu = 635 u]

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20. Density of water at room temperature is 1.0 g/cc. How many molecules are there in one drop of
water if its volume is 0.1 cc?

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21. Calculate the number of atoms in each of the following :

(a) 52 g of He

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(b) 52 moles of Ar (gram atomic mass of He. = 4 g/mol, Ar = 39.95 g/mol)

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22. Calculate the number of hydrogen atoms present in 18 g of glucose.

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23. What will be the mass of one molecule of CO2 in gram?

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24. Calculate the number of Cl and Ca2+ ions in 222 g of anhydrous CaCl2.

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25. Calculate the number of atoms in each of the following :
(i) 1 g Au(s) (ii) 1 g Na(s)
(iii) 1 g Li(s) (iv) 1 g of C12(g)

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29. (a) Calculate the number of moles in the following :

(i) 11 g of CO2

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(ii) 3.01  1022 molecules of CO2

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(iii) 1.12 L of CO2 at STP

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(b) Calculate number of molecules in of the following :
(i) 14 g of nitrogen

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(ii) 3.4 g of H2S

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30. Calculate the number of moles in each of the following :
(i) 392 g of sulphuric acid

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(ii) 44.8 litres of sulphur dioxide at N.T.P.

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(iii) 6.022  1022 molecules of oxygen

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(iv) 8 g of calcium

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(v) 1 atom of magnesium.

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SHEET-3
1. Define unified mass (u).

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2. Calculate the number of atoms in 32.0 u of He.

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3. Define molar volume of a gas.

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4. What is the volume of 17 g of NH3 gas at STP (298 K, 1 atm)?

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5. Calculate the number of molecules present in 22.0 g of CO2.

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6. How many molecules of SO2 are present in 11.2 L at STP?

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7. Which has more number of atoms? 1.0 g Na or 1.0 g Mg.

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8. How many oxygen atoms are present in 16 g of ozone (O 3)?

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9. Calculate :

(i) Mass in gram of 5.8 mol N2O

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(ii) No of moles in 8.0 g of O2

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(iii) Molar mass if 11.2 L at STP weigh 8.5 g.

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10. 16 g of an ideal gas SOx occupies 5.6 L at STP. What is its molecular mass? What is the value of X?

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11. Calculate the number of atoms in each of the following :

(i) 52 moles of Ar.

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(ii) 52u of He

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(iii) 52g of He

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PERCENTAGE COMPOSITION & EMPERICAL FORMULA (SHEET-1)

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1. Write the relationship between empirical formula and molecular formula.

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2. A substance has molecular formula C6H12O6.What is its empirical formula.

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3. Empirical formula of a compound X(Molar mass = 78 mol-1) CH. Write its molecular formula.

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4. Calculate the present of carbon, hydrogen and oxygen in ethanol (C 2H5OH)

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5. How much copper can be obtained from 100 g of CuSO4?

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6. A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is 98.96
g. What are its empirical and molecular formulas?

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7. What is the % of Sulphur in Na2SO4?

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8. What is the % of H2O in Crystalline oxalic acid.

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9. What is the % of nitrogen in Urea?

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10. Write empirical & molecular formula of

(i) Glucose

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(ii) Acetic acid

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(iii) Oxalic acid

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(iv) Potassium permagnate

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(v) Benzene

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(vi) Ethene

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(vii) Acetylene

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(viii) Ethane

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(ix) Hydrogen peroxide

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 (x) Hydrazine

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PERCENTAGE COMPOSITION & EMPERICAL FORMULA (SHEET-2)

1. An inorganic salt on analysis gave the following percentage composition

Pb = 62.6, N= 8.4, 0 = 29

What is empirical formula of the compound ? Also name the compound.

(At. mass Pb = 207, N = 14, 0 = 16)

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2. An oxide of nitrogen has the percentage composition : N = 25.94 and O = 74.06

Calculate the empirical formula of the compound.

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3. A sample of a salt has the percentage composition : Fe = 36.76 ; S = 21.11 and 0 = 42.14 Calculate
the empirical formula of the compound. (At. mass Fe = 56, S = 32 and 0 = 16)

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4. A salt containing water of crystallization gave the following percentage composition :

Mg = 9.76 ; S = 13.01 ; O = 26.01 and H2O = 51.22.

Calculate the simplest formula. (At mass of Mg = 24)

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5. Calculate the empirical formula of gold chloride which contains 35.1% of chlorine. At. mass of Au =
197.

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6. Calculate the empirical formula of a mineral having the following composition :

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 CaO = 48.0% ; P2O5 = 41.3% ; CaCl2, = 10.7%

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7. A crystalline salt when heated becomes anhydrous and loses 51.2% of its weight. The anhydrous salt
on analysis gave the percentage composition as : Mg = 20.0% ; S = 26.66% and O = 53.33%

Calculate the molecular formula of the anhydrous salt and the crystalline salt. Molecular mass of the
anhydrous salt is 120.

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8. A compound containing carbon, hydrogen and oxygen gave the following analytical data : C =
40.0% and H = 6.67%

Calculate the molecular formula of the compound if its molecular mass is 180.

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9. On analysis, a substance was found to have the following percentage composition :

K= 31.84, Cl= 28.98 and O = 39.18

Calculate its molecules formula if its molecular mass is 122.5.

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10. An organic liquid having carbon, hydrogen, nitrogen and oxygen was found to contain
C = 41.37% ; H = 5.75% ; N = 16.09% and the rest oxygen. Calculate the molecular formula of the
liquid if its VD. is 43.3.

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11. A chemical compound is found to have the following composition :

C = 19.57% ; Fe = 15.2% ; N = 22.83%; K = 42.39%

Calculate the empirical formula of the compound. What will be its molecular formula if the
molecular mass of compound is 368? Name the compound.

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 STOICHIOMETERY (SHEET-1)

1. Calculate the amount of water (g) produced by the combustion of 16 g of methane.

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2. How many moles of methane are required to produce 22 g CO 2 (g) after combustion?

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3. How many grams of HCl react with 5.0 g of MnO2 according to the equation.

4HCl(aq) + MnO2(s)  2H2O(l) + MnCl2(aq) + Cl2(g)

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4. Pure oxygen is prepared by thermal decomposition of KClO3 according to the
equation :

Calculate the volume of oxygen gas librated at STP by heating 12.25 g KClO 3(s).

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5. Calcium carbonate reacts with aqueous HCl according to the reaction :

CaCO3(s) + 2 HCl (aq)  CaCl2(aq) + CO2(g) + H2O(l)

What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HC1?

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STOICHIOMETERY (SHEET-2)

1. In the commercial manufacture of the nitric acid, how many moles of NO2 Produce 7.33 mol of
HNO3 in the reaction :
3NO2 + H2O2HNO3(aq)+NO(g) ?

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2. How much of Fe can be theoretically obtained by the reduction of 1KG of Fe2O3?
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3. Calculation the mass of 60 % H2SO4 required to decompose 50g of chalk(calcium carbonate )?
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4. Excess of AgNO3 solution was added to 2.2g of commercial sample of common salt dissolved
in water.the mass of dreied precipitate of silver choride was 2.11g . calculate the precent of
common salt .?
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5. A sample of dolomite contained 45% of CaCO3,40% of MgCO3 and 15% clay. Calculate the
mass of sulphuric acid of 30% strength required of react completely with 10g of the sample?
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6. Calculate the mass of graphite thet must be burnt to produce 13.2g of CO2 ?
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7. What volume of oxygen at STP can be obtained from 10g of potassium chlorate ?
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8. 2.50g sample of sodium bicarbonate when strongly heated gave 300cm3 of CO2 Measured at
27o and 760 mm pressure . calculate the percentage purity of the sample ?
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9. The drain cleaner , drainex contains Small bits of aluminium which react with caustic soda
to produce dihydrogen . what volume of dihydrogen at 20oC and one bar will be released when
0.15 of aluminium react ?
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10. 5.6 liters methane (CH4)gas are ignited in oxygen gas .calculate the number of moles of CO 2
formed ?
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11. Find out the volume of C12 at STP produced by the action of 100cm3 of 0.2 N HC1 on
excess of MnO2 ?
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CONCENTRATION TERMS (SHEET-1)

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1. Calculate molarity of water if its density is 1.00 g mL -1.

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2. Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water to
form 250 mL of the solution.

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3. The density of 3 M solution of NaCl is 1.25 g mL -1 . Calculate molality of the solution.

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4. Calculate the mass of sodium acetate
(CH3COONa) required making 500 mL of 0.375 molar aqueous solution. (Molar mass of sodium
acetate is 82.0245 g mol-1).

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5. Calculate the concentration of nitric acid in moles per litre in a sample which has a density, 1.41 g
mL-1 and the mass per cent of nitric acid in it being 69%.

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6. What is the concentration of sugar(C12H22O11) in mol L-1 if its 20 g are dissolved in enough water to
make a final volume up to 2L?

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CONCENTRATION TERMS (SHEET-2)

1. 25 ml of 3.0 M HNO 3 are mixed with 75 ml of 4.0 M HNO3 . If the volumes are additive, the molarity of
the final mixture would be
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2. The amount of anhydrous Na 2 CO 3 present in 250 ml of 0.25 M solution is
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3. Dilute one litre 1 molar H 2 SO 4 solution by 5 litre water, the normality of that solution is

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4. If 5.85 gms of NaCl are dissolved in 90 gms of water, the mole fraction of NaCl is

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5. 9 .8 g of H 2 SO 4 is present in 2 litres of a solution. The molarity of the solution is

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6. How much of NaOH is required to neutralise 1500 cm 3 of 0.1 N HCl (At. wt. of Na =23)

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7. 3.0 molal NaOH solution has a density of 1.110 g/ml. The molarity of the solution is

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8. Two solutions of a substance (non electrolyte) are mixed in the following manner 480 ml of 1.5M
first solution + 520 mL of 1.2M second solution. What is the molarity of the final mixture

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9. What will be the molality of a solution having 18 g of glucose (mol. wt. = 180) dissolved in 500 g of
water.

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10. What volume of 0.8 M solution contains 0.1 mole of the solute
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11. Conc. H 2 SO 4 has a density of 1.98 gm/ml and is 98% H 2 SO 4 by weight. Its normality is
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N
12. With 63 gm of oxalic acid(mw=126 u) how many litres of solution can be prepared
10
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13. How many grams of dibasic acid (mol. wt. 200) should be present in 100 ml of its aqueous solution to
give decinormal strength

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14. The molarity of a solution of Na 2 CO 3 having 10 .6 g / 500 ml of solution is

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15. Molecular weight of glucose is 180. A solution of glucose which contains 18 gms per litre is

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16. The volume of water to be added to 100 cm 3 of 0.5 N H 2 SO 4 to get decinormal concentration is
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17. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is
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18. An aqueous solution of glucose is 10% in strength. The volume in which 1 gm mole of it is dissolved
will be
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19. 6 . 02  10 20 molecules of urea are present in 100 ml of its solution. The concentration of urea solution
is
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20. The weight of H2C2O4 . 2H2O required to prepare 500 ml of 0. 2 N solution is
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21. In a solution of 7.8 gm benzene C6 H 6 and 46 .0 gm toluene (C6 H 5 CH 3 ) , the mole fraction of benzene in
this solution is
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22. A solution contains 25 %H 2 O , 25%C2 H 5 OH and 50 % CH 3 COOH by mass. The mole fraction of H 2 O
would be
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23. Molarity of a solution containing 1g NaOH in 250ml of solution is
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24. A solution contains 1 . 2046  10 24 hydrochloric acid molecules in one dm 3 of the solution. The strength
of the solution is
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25. When 7.1gm Na 2 SO 4 (molecular mass 142) dissolves in 100 ml H 2 O , the molarity of the solution is
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26. If 5 . 0 gm of BaCl 2 is present in 10 6 gm solution, the concentration is
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27. How many grams of NaOH will be required to neutralize 12.2 grams of benzoic acid

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28. What is the molarity of H 2 SO 4 solution, that has a density 1.84 gm/cc at 35 o C and contains solute
98% by weight
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29. A certain aqueous solution of FeCl 3 (formula mass =162) has a density of 1.1 g / ml and contains
20 .0% FeCl 3 . Molar concentration of this solution is
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30. The molarity of pure water is
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LIMITING REAGENT (SHEET-1)

1. In the reaction 4A +2B +3C  A4B2C3, what will be the number moles of product formed, starting
from one mole of A, 0.6 moles of B and 0.72 moles of C?

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2. Zinc and hydrochloric acid react according to the following reaction :

Zn(s) +2HC1(aq.)  ZnCl2 (aq.) + H2 (g)

If 0.30 mole of Zn is added to 0.52 mole HCl, how many moles of H 2 is produced?

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3. A mixture of 1.0 mole of Al and 3.0 mole of Cl2 are allowed to react as:

2Al(s) + 3Cl2 (g)  2AlCl3 (g)

Then moles of excess reagent left unreacted is:

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4. If 30 mL of H2 and 20 mL of O2 react to form water, what is left at the end of the reaction?

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5. When 22.4 litres of H2 (g) is mixed with 11.2 litres of Cl2 (g), each at S.T.P., the moles of HCI (g)
formed is equal to :

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6. 1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel. Which reactant is left in excess and
how much? (At. wt. Mg = 24; 0 = 16)

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7. 2.4 g of pure Mg (at. mass = 24) is dropped in 100 mL of 1 M HCl. Which of the following
statement is wrong?

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8. 1.0 g of Mg is burnt with 0.28 g of O2 in a closed vessel. Which reactant is left in excess and how
much?

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9. If 0.3 mole Zn are added to HCl containing 0.52 mole of HCI, how many moles of H 2 are produced,
according to the reaction?

Zn(s) + 2HCl(a)  ZnCl2(a) + H2 (g)

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10. 3 g of H2 react with 29 g of O2 to form H2O. Find the amount of the reactant left unreacted?

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11. 1.2 L of hydrogen and 1.12 L of chlorine are reacted. The composition by volume of mixture is :

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LIMITING REAGENT (SHEET-2)

1. Consider the following balanced reaction:

2Ca(s) + O2(g) → 2CaO

Consider the reaction above. If 60g of Ca is placed in a reaction chamber with 32g of O2 which will
be the limiting reactant?

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2. Given the reaction

H2SO4 (aq) + 2 LiOH (aq) → Li2SO4 (aq) + 2 H2O (l)

If you have 100g of H2SO4 and 65g of LiOH. What is your limiting reactant?

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3. Consider the following reaction:

8Fe+S8→8FeS

If we begin with 293 g Fe and 17.2 g S8, how many grams of FeS will we create?

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4. Consider the following reaction:

2Na+2H2O→2NaOH+H2

If you have 36 grams of Na and 53 mL H2O, will you have any remaining sodium and/or water?
How much of each?

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5. Magnesium will combine with oxygen gas to form magnesium oxide according to the balanced
equation below.

2Mg+O2→2MgO

60 grams of magnesium metal and 30 grams of oxygen gas are allowed to react. If the reaction runs
to completion, which reactant will be depleted first?

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6. Consider the following balanced reaction.

If the reaction starts with 8 moles of chlorine gas and 10 moles of potassium iodide, how many
moles of the excess reagent will be left over after the reaction has run to completion?

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 _____________________________________________________________________

7. Consider the following balanced reaction.

If you start with 100 grams of chlorine gas and 500 grams of potassium iodide, how many grams of
the excess reagent will remain after the reaction has run to completion?

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8. The formation of ammonia is given by the following equation:

3H2+N2→2NH3

If you start the reaction with 12g of hydrogen gas and 64g of nitrogen gas, which will be the limiting
reagent?

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9. Consider the reaction of potassium carbonate with calcium nitrate to form potassium nitrate and
calcium carbonate:

K2CO3(aq)+Ca(NO3)2(aq)→CaCO3(s)+2KNO3(aq)

Suppose 50ml of a 0.250M potassium carbonate solution was mixed with 100ml of a 0.175M
calcium nitrate solution. What is the maximum amount of calcium carbonate that could be obtained?

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10. The following reaction is used to obtain small amounts of chlorine gas in the laboratory:

MnO2(s)+4HCl(g)→MnCl2(s)+Cl2(g)+2H2O(l)

If 28.0g of MnO2 are allowed to react with 42.0g of HCL, the limiting reactant will be:

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 ANSWERS
MOLE CONCEPT AND MOLAR MASSES (SHEET-2)
2. 8 4. 22.4 L 5. 3.011 × 1023 6. 3.011 × 1023

7. 1.0 g Na 8. 2.007 × 1023

9. (i) 255.2 g (ii) 0.25 mol (iii) 17 g mol-1 10. 64u, x = 2

11. (i) 3.13 × 1025 (ii) 13 (iii) 7.83 × 1024

PERCENTAGE COMPOSITION & EMPERICAL (SHEET-1)

4. 52.14%, 13.13%, 34.73% 5. 39.8g 6. CH2Cl, C2H4Cl2

PERCENTAGE COMPOSITION & EMPERICAL (SHEET-2)

1. PbN2O6.Pb(NO3)2, Lead nitrate 2. N2O5

3. FeSO4 4. MgSO4.7H2O 5. AuCl3

6. 9CaO.3P2O5.CaCl2 7. MgSO4.7 H2O 8. C6H12O6

9. KClO3 10. C3H5NO2 11. K4[Fe(CN)6]

STOICHIOMETERY (SHEET-1)

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1. 36g 2. 0.5 mol 3. 8.40 g 4. 3.36 L

5. 0.94 g

STOICHIOMETERY (SHEET-2)
1. 10.995moles
2. 700g
3. 81.67g
4. 39.10
5. 30.27g
6. 3.6g
7. 2.963 Litres
8. 81.9%
9. 203.0 Ml
10. 0.25 mole
11. 112 cm3
CONCENTRATION TERMS (SHEET-1)

1. 55.56 M 2. 0.4 M 3. 2.8m 4. 15.375 g

5. 15.44 M 6. 0.029 M

CONCENTRATION TERMS (SHEET-2)

1. 3.75 M 2. 6.625 g 3. 0.33 N 4. 0.0196
5. 0.05 M 6. 6 g 7. 2.9732 8. 1.344 M
9. 0.2 m 10. 125 ml 11. 39.6 N 12. 10 litre

13. 1g 14. 0.2 M 15. 0.1 molal 16. 400 cm3

17. 10 18. 1.8 litre 19. 0.01 M 20. 6 .3 g

21. 1/6 22. 0.503 23. 0.1M 24. 2N

25. 0.5 M 26. 5 ppm 27. 4 gms 28. 18.4 M

29. 1.27 30. 55.6

LIMITING REAGENT (SHEET-1)

1. 0.24 2. 0.26 3. 1.5 4. 5 mL of O2

5. 1 mol of HCl (g) 6. Mg, 0.16 g

7. 0.005 mol of magnesium is left behind 8. Mg, 0.58 g

9. 0.26 mole 10. 5.2 g O2

11. 0.08 L of H2 and 2.24 L of HCl

LIMITING REAGENT (SHEET-2)

1. Ca because there will need to be 2 moles if Ca for every mole of O 2 as defined by the balanced
equation.

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2. H2SO4 3. 47.1 g 4. 24.8mLH2O

5. Oxygen gas 6. 3 mol 7. 32g 8. Hydrogen

9. 1.25g 10. HCl

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