STEREO-ISOMERISM Isomers + Same motilar formula ae aa 4 Ditfer tn hate structure (on) Spuctal oventeion + Stctaval | Saka te oe a | Gow) Consbitutional temert teveomners nf cmationsh sy CAteanes) starter ste vatetion Gecrerttoal Uemers Se + Rescvickek Yatabion + Same molester frmale, e| : * deomind + planarthy. SpE Barcel, Hae y + Restricted netation Basted x Difference tn Spactal Orientation Cia Rep Aemerctatane '- Sts groups ave om Aion Sie ah Aulbvatd netation = cls Storia groups are om oppetite Side over Trend ve Pog, only we; Cy a ee petri Fat, = La if cnc thin bere She (Ode pts) ane Tran 22 Baka a © = Cnbagegen (opel) Ze Zameen (seme) Seo yA ons (oena+ 010s lpn ca sone MERI 2a 43h Se aspen Scape centers Mecsas Soe Pririty 14 poem bed Usp man 4 Cmfigaratfenad Umass ocala moa $n cate 4 moubtipln bends duplication ta deme > Previtg grouph ove m t 0 arti oo Grau ue (1e)4ehyraneaniine HaN—p Ht — rs pea HN SNH 8 Gan Agabrongebtiacn’ aioe t (26)-4,4.4-triamino-3-cyano-2-hydroxybut-2-enole acid so mol Yo eonwn wo. Ad Shee romeo Soe acid Sgn wrk -e Dati: URE =e 4 even number + old varies eladtwa akon Commuted ve "k-bendh deme tokbt G2 ¥ Geementricad Memerism Gat: és sean te odd mumbar Megs + mo G3 Sei cones eakibt Gor rica 7 oplicably foackive get Ky ve ey SOS - OO) oe Lee oe TaTer <8 mumbo qe sense Ying > opticany active weak 62 optic fn ee + ther of SERRE — eAtricked vatabinn ee Ustremetical i= — mumber f Gemmentvicel emer = 2 Spormetirteat » wna tven ) number fh Gummedtricat Hemert = + meodd Number J Crermertrical gomera = 2 4 2 CH, =e — Es — a — cm nes owkgrarnabrical we Gt=ge3 ekumber § Igemert = 6 Tyr Symes Bias h_Spemebeg =o fim Smegineny wets ts ped through Ge maleate + Rotate Cepia) the wabads over Ha ants for 368. H mamber Bp Lmes Aimnilay gemmentry 4 obterwed =n A A rmibeede have Cy ants Bp Syrmmnetige & * a ; Y BG acces lila tlie & 0 Derrar: eatin ok ee rae 388 sees some aa « tt _ tes ae ceqetepipne plane} Syroredy + fin tmagtoady plane colich cut the moleuds nto tae Squat halves and Hote ave rotvror fmega to gach other, if , (i (im oad Sassari conten Z = so saver pe peesContes Symmetry + tmneginary Point at Centon fh molaaibe + Deas tmaplnnry Mest tm opposite diveations abt thal pint Both Lines shout mest Akeley geomentry af Capial distances Ge for. . Aa a POM wea kK |. we Alternate ants 4 Syromebey er 4h ge ME iter oakrg kT oth " et cL 4 ee :B . at wo en 5 ethan ina plane perpendtodar to 4 ver an tmaginarg ants rotate the Grobe cube fav hak: os observe tha miner “oops mong © Af Ha whrver fonage ib bane. 4 original ral ean the roel 1h Sd be pesos Alternate att 4 Spromebry. % Molecule volich de net paises ang fh hate Agmmentvih <— Ariywmetvie malice | ey wb Metres itch do net pea plane dy Syrmmenbry < emepeemamememmtmama [4 opicauy Active medesserg 4 supfictent for opbleak mckivity plically- active Slersegenie. center sith four different grape mar caster 7 a foux diff) por ‘no plane Syprmetey” wd ts enanges . ee 73)= ol rere y er aig i im perGLD length tove Coe) . = plane polarized ight rane. potaans Ht A + dase fesse | ! ~ o Article wie etayeest o ee © bylenve G10) deste Cum dine vnlovor fmoyes te gach othey % Beted up Coop dubs, a a > Abdohube Configuration Can be entgned at chiral center Rectal ay Sinister (3) 0X | wp 8 £ © Nw is i sweet =e pionity on Serna pre ~ ae Tf prhenity. BF erm | groups Grant femerie. pal Se glarusite @) anbielck ite Ce Erantiewert Nen= Super tmpoasala.nalrver Images + fast prlevity proup mut be os copes pee SS Dlagtaresmers- Hen -Aupertmpofabte , "Ram mcrvor Emayes i} best priority group Cowerds the % @ Goropound Viewer GY &) sachorte preTedtien edge =< dea “Fikcher - preTection Bea horte —s wo ht te Ja gh ae as flicker Conventiso Amant ontdaad gremp on OP oa pavent” chain 14 Faken af Vertiele Une: Sith a oval centers om i 4 prespconationnss towords the viewer ave haigentat + ating frm Viewer ave reprenented Verdin wlio previty grap ¢ eine S > Hoists GY coo coo coor — " Oe | nantes j ow ae)cso en cue wo “ w % Undamenbrical & memes A chiral centers ma. dk optically active ows ma Coktemerte puns =" Le facie mixtese no dy momma = 2 1H opticatiy Inactive Plane hy Spmmentyy t Paternal Campenietion 1 Spometrical molese + eaters ow JF we oe) aoa oe din shevemnes TITY rake wcnduive Ay Enantiomas 4 Opticatny, nacre x Cxternal Compensation mis even mis old er wate A ely ote a a umes epay ative -(E°) LG) umber g mere form . marmber d mere form " Tobat nor stereonisemers » Seat Total now a stereoisomers 2) Yo. § Enantlererte pains = Retolution ¢- Seperoting Ga + face mic Mo. @ Erantiowete pains = gh a> 2? pee z Enantiomers frrm Racemie. mixture ee OAs + ones fs se Diagtevemners 4 opticamy oct Differ im thelr plgttea proportion prey ‘ nme, Bot ate x Thay Can be. Seperated Netes- Enant lemons ¢ * beret 1% Same phypteal ond chawceat wn Properkies # A Differ in than optionl activity Relghive Cenfiqueetien'- + D= Glyceratdebgds (5 taken os tefrance ol poop pilin evn bal chav oto * a Corson is obherved een nom mm ape Bk Ae finer) oy De) -Glycevatdahyd pratestion “4 + cal fe He ae fcr protect em + Nekwclly ceuuning Carbebydeates ada “D-forms cn Amino nets Lo Serine 14 tobe fob aference, Coot Le Serine % Nexesathy oceing Amine acids Be Le formsete ne : == ® ene D- theeose & ow ¥ ou cd " - ” a ° " * v . . 3 euyou cao" eyo A p-etbore D- Mrebinese Debye 7 a + S Ed ae Se ee ee nor a+ om one om on fo ” 2) oH 8H cs oH eH Co ee cone ens east one oot D = Militese D> Mlrode — D-Giacode nee D-Mtnctow. Beet Rebabive Configuvation over otk crab centers tema Lame) ed Configuration ever the first Codten changes = Epimet = Pome Pctscarqromnte Ciacanpinnase - 2 ons = “Woworth structures ty chased convent 4 re choral Cobbenh = 5 + Relabive Confiquiation over att chtral enters remain Sami Cacgt ang me conten Except the fivet Connon — Eptmars Gennes pAlb, Bike Gibacoke, Mawnan Cy-Epimers Gy apraaek Gutore, Ebene Galas, Tease Allote- Gbace Moke ~ Guede Atévabe- mannese Altra Tete Gulete ~ Cralactohe | Chicos - Galeckese Totote- Talote Monnet ~ Tatade ge soerespens J tonyTetose ~ Talone Momease ~ Tabode: aot L-form Blow acttyiey- 04 deform [mince oh ‘t fovm 4 Enankicmerte exces (ee) = a - me. Seree. homers, + Sheree Selecbiully Tm a suaction ; Amoung the Powtble praduats Yost atsis < One Ge Ue Stetotiomer daminates Meter Th there 14 a cCompebition Yoo be reacting my Than be ts Called cuno|rugfo- sebachriby, Stereo Specific 1 x In a tunstion; only me product ts formed predemintnty Kone Stereo-tbomer mag lund te me form & produck another Shereo-lomey may Lind to tha other form ay produsct Cotainud predachs sy be dap ferent en @2) as o- Rademis raiabore esejlemneae 12] rms an chm roel a ca a wn a ne, i wanda mean tee . + emma SL Samm —coonton FD Serene mart = Pct netgen be (ote woe ©) teen get cm bo “roma ectegcnonrinth—_)Gamanal em oe a enon tte rnin fenton? 83 ea mn O73 m3 28 12. Hawn recone oi eng cn? Speen ad pes OO ceatipmenntneed was Pew we "1, Spect ton oan ora Fue Eoroount fi +40. na eacton he compound ie bane og ‘tare of chanical reactona He ape ean of scien A wht wuld be ha pcre Inova tamer me itor? © om a am (dh yie 9 bed eso ores © 109% oe aig aerate asec ne (1) WX=H and =D, en compound sop ace @) X= DandY «7. hen cme pay ave 7 ecamenieiaomaal Conlrernstiont omer 4 Free notation our ¢-< bond 4 Difference tn Apadak onitatabion tems | groups fe a mothuabe wilich ate gentratad dun be ababin ove Megha bend ceo fligring 4 Wing Note: Confovrners | folames corratpmd to minimum potertial Crogy 4 Le trolake but ote detested spedrotcopicaly * + Taffnck Conformert pottsele a ae Set”Ug ° © WR a? eelpted sing hoo 2 oe eet a | = = nm A prereatieo ji B= Torhienal ong feet” Aled angle a cofecatios Bement in Ethane = =H sae 4 Ab too Sammperabaes ; AKA. wt &, ea ne seaggrk Echiphel + por free etation, abo han be over Come tha trey re beet. Steyqood Gauche Cabiptd gi OF ed 7 fon “ ~ Akl eww + Tokiond angle 0 —> L a Sy Gonfremabtenal sewers in__propone i= AA eB. we Tortie mgs > fy Gonfecmablons! Lpermers im _Butane 5 sot Anta ge AMAT —ae ae Paes Torkional mph em Bete rma f [= a mt vebrica! tomers Sos Sotrans a tr ee ster a be fete Be % Cefane ge aogsed ore Sele TN IN EY le a 12-Diftumecthane A gt & 7) Ae A ee ecbipted stogyoed Fag tind stays pntiad stagy piso ined stabs din to pobasity waht? Chinbedipet)“ne state in to pobealey a (Cdipte-dipole) astern te} Getiped > Gauss = sheqel oferty LenfernsQirad Uemetitm tn yelo-mlberes i 14" 2e'— bend angle = 1 Angle strain = ——+ - + Bond on Brow be og'ad. a COTA qictine 3 TH og egret Lt sein CHM va CY * ete Getepectane mo tw! CY % Angle strain = ae = aay Ggtlhenene @-aee) (ngs fo 0 polygon = + According to Buyer's Ring Strato thang ; cpste-perntane 14 rrme stable Bees Estate soulse fe , x oh ts ve: ih “the. fen Compose te Bheuble. Sig #40 —> StOrey 4 Sta, + Geto propane ay ' 7 agi = 201) 47 moi (ou) = 697 ke med! Oe * Cycle butane: = 686 KT mob % Ogchopentane = 3820 eT moi” -604 ETwl! + Cyclehwnane 3952 kTvvel! (3698-7 KT mmol rarer + Cyelohagtare 4687 kT anol! 062-4 kT met! * Gyeleortane ~ 5310 kT vmt! = 6688 kT mol! Y Yyebemerens. = 599) kT imal! ce it, Cyctentiors ade nok planer ; Thy Extst tn puckosd stractunesit, cgetenttons arr nok planed; They Exist tm puckaed structines . 4 * . " ta fru bbeg Mlring k ” , '. yo ON oo ¢ 4 Dany Ang flirting arteh bends comerted be dyucheriah ond Veeverse pod tft is + Skabihity orda of cctebanant Grnfremars Twined tg Mal hein > > Abuses Substituents prefer Sauiitoriah peuiliens 12 Dinabheegaliocane 13-Dt tine ih Le Am Trans Trap (ere stot) Simmtbarty = Diaby eycbebarcona eee fz = f Oy rhoeane =i dol _ a wt OY Indra mebodat,ge Crore: shania) Uh Diketbiarg butyegtehinens eH Test teed boat fev orere ate [Tautomerism and Stereoisomerism] 12, Funconal santo 90 () Bzme cy ete Bike 0) Btzare M80 300 yj nen en on 13. The yp of tamer defen yes flo a on ter fn pen tole ct compninds OHH OCHO rd ROC red oe UH Tetamersm (2) Textomerism (2) neon inc (Poston niin yc fe towing show ademeren? Hew, ° 0 Borer ad ° ° OL ot AL, 15. Polar solvent favours keto form while non-polar solvent favours enol form. Which has maximum enolic content inca? ° ° ° ° 1 1 be I I () cH —cH,— Cc, f cH, —C—cH,— CH i i @) ch, —C—cH,— coocH, ch, —C— chen, 16. Nunta of src omer postin C0 80 ys war 0 ahr as VN Le 4 ws NAA My 17. Compounds vith Cy, as leer oma can exit (1) Poston ncmeram @) Metamerm €@) Funetonal somes ATR ese 18. Which ofthe folowing does not show geometicllomertam? - ‘ - at18. Which of the folowing does not show geometrical isomerism? (1) 1.2 dichloro penttene Shed @) 1.8 Dichiowo pent 2-ene ww 1.4 Dichloro pent-t-ene at A) 14 Dito pent zene GD x AA 4 419. Newman projection for 22-dimethy\ butane x and y can respectively be () HEHX Lata cH, ©) Cae ony WATCH, BCH,