SRI VIGNESH VIDYALAYA

SENIOR SECONDARY SCHOOL,

KOOTHUR, TRICHY -621 216

CLASS XII(2023-2024)
CHEMISTRY PRACTICAL MATERIAL
S.NO. NAME OF THE EXPERIMENT PAGE
1 Preparation of M/20 solution of Mohr’s salt 1
2 Preparation of M/40 solution of Mohr’s salt 2
3 Preparation of M/50 solution of Mohr’s salt 3
4 Preparation of M/20 solution of oxalic acid 4
5 Preparation of M/40 solution of oxalic acid 5
6 Preparation of M/50 solution of oxalic acid 6
7 Estimation of amount of KMnO4 using FAS (M/20) 7
8 Estimation of amount of KMnO4 using FAS (M/40) 8
9 Estimation of amount of KMnO4 using FAS (M/50) 9
10 Estimation of amount of KMnO4 using oxalic acid(M/20) 10
11 Estimation of amount of KMnO4 using oxalic acid(M/40) 11
12 Estimation of amount of KMnO4 using oxalic acid(M/50) 12
Determination of weight of Ferrous Ammonium Sulphate EXP.NO.1 PREPARATION OF M/20 SOLUTION
(FAS)
OF MOHR’S SALT

Aim:-

To prepare 250 ml of M/20 solution of Mohr’s

Molarity = W x 1000/ M x V salt.
Weight of FAS = Molarity x Mol.mass x 250/1000

Weight of FAS = 0.05X 392X250/1000

Materials required:-
Weight of FAS = 4.9g
Ferrous Ammonium Sulphate crystals, weighing
balance, 250 ml standard flask, distilled water,
funnel, wash bottle and H2SO4.

Procedure:-

The calculated quantity of Ferrous Ammonium

Sulphate crystals were taken in weighing
balance accurately. The crystals were
transferred into 250 ml standard flask using
funnel. A small amount of distilled water was
added using a wash bottle to dissolve the
crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of FAS solution is found to be

0.05M

Page 1
 EXP.NO.2 PREPARATION OF M/40 SOLUTION
OF MOHR’S SALT

Determination of weight of Ferrous Ammonium Sulphate Aim:-

(FAS)
To prepare 250 ml of M/40 solution of Mohr’s
salt.

Materials required:-
Molarity = W x 1000/ M x V Ferrous Ammonium Sulphate crystals, weighing
Weight of FAS = Molarity x Mol.mass x 250/1000 balance, 250 ml standard flask, distilled water,
funnel, wash bottle and H2SO4.
Weight of FAS = 0.025X 392X250/1000
Procedure:-
Weight of FAS =2.45g
The calculated quantity of Ferrous Ammonium
Sulphate crystals were taken in weighing
balance accurately. The crystals were
transferred into 250 ml standard flask using
funnel. A small amount of distilled water was
added using a wash bottle to dissolve the
crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of FAS solution is found to be

0.025M

Page 2
Determination of weight of Ferrous Ammonium Sulphate EXP.NO.3 PREPARATION OF M/50 SOLUTION
(FAS) OF MOHR’S SALT

Aim:-

To prepare 250 ml of M/50 solution of Mohr’s

Molarity = W x 1000/ M x V salt.
Weight of FAS = Molarity x Mol.mass x 250/1000 Materials required:-
Weight of FAS = 0.02X 392X250/1000
Ferrous Ammonium Sulphate crystals, weighing
Weight of FAS =1.96g balance, 250 ml standard flask, distilled water,
funnel, wash bottle and H2SO4.

Procedure:-

The calculated quantity of Ferrous Ammonium

Sulphate crystals were taken in weighing
balance accurately. The crystals were
transferred into 250 ml standard flask using
funnel. A small amount of distilled water was
added using a wash bottle to dissolve the
crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of FAS solution is found to be

0.02M

Page 3
 Determination of weight of oxalic acid EXP.NO.4 PREPARATION OF M/20 SOLUTION
OF OXALIC ACID

Aim:-

Molarity = W x 1000/ M x V To prepare 250 ml of M/20 solution of Oxalic

acid.
Weight of oxalic acid = Molarity x Mol.mass x 250/1000

Weight of oxalic acid = 0.05X 126X250/1000

Materials required:-

Weight of oxalic acid =1.576g Oxalic acid crystals, weighing balance,

250 ml standard flask, distilled water, funnel,

wash bottle and H2SO4.

Procedure:-

The calculated quantity of oxalic acid crystals

were taken in weighing balance accurately. The
crystals were transferred into 250 ml standard
flask using funnel. A small amount of distilled
water was added using a wash bottle to
dissolve the crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of oxalic acid solution is found to

be 0.05M

Page 4
 EXP.NO.5 PREPARATION OF M/40 SOLUTION
OF OXALIC ACID

Determination of weight of oxalic acid Aim:-

To prepare 250 ml of M/40 solution of Oxalic

acid.
Molarity = W x 1000/ M x V

Weight of oxalic acid = Molarity x Mol.mass x 250/1000

Materials required:-

Weight of oxalic acid = 0.025X 126X250/1000 Oxalic acid crystals, weighing balance,

Weight of oxalic acid = 0.78g 250 ml standard flask, distilled water, funnel,
wash bottle and H2SO4.

Procedure:-

The calculated quantity of oxalic acid crystals

were taken in weighing balance accurately. The
crystals were transferred into 250 ml standard
flask using funnel. A small amount of distilled
water was added using a wash bottle to
dissolve the crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of oxalic acid solution is found to

be 0.025M

Page 5
 EXP.NO.6 PREPARATION OF M/50 SOLUTION
OF OXALIC ACID

Aim:-
Determination of weight of oxalic acid
To prepare 250 ml of M/50 solution of Oxalic
acid.

Materials required:-
Molarity = W x 1000/ M x V
Oxalic acid crystals, weighing balance,
Weight of oxalic acid = Molarity x Mol.mass x 250/1000
250 ml standard flask, distilled water, funnel,
Weight of oxalic acid = 0.02X 126X250/1000
wash bottle and H2SO4.
Weight of oxalic acid = 0.63g
Procedure:-

The calculated quantity of oxalic acid crystals

were taken in weighing balance accurately. The
crystals were transferred into 250 ml standard
flask using funnel. A small amount of distilled
water was added using a wash bottle to
dissolve the crystals.

20 ml of 2N H2SO4 acid was added to prevent

hydrolysis of ferrous ions. Sufficient amount of
distilled water was added to standard flask in
order to make up the volume of 250 ml.
Calculations were done to determine the actual
molarity of the solution prepared.

Result:-

The molarity of oxalic acid solution is found to

be 0.02M

Page 6
 EXP.NO.7 ESTIMATION OF AMOUNT OF
KMnO4 USING M/20 FAS

Aim:-
S.No Volume Burette Reading Volume Indicator
of FAS (ml) of KMnO4
(ml) Initial Final (ml) Self
To determine the molarity and strength of the
Indicator given solution of potassium permanganate with
1 20 0 (KMnO4)
standard solution.
2 20 0
Equation:-

2KMnO4 +8 H2SO4 + 10 FeSO4(NH4)2.6H2O 

Volume of FAS solution (V1) = 20ml K2SO4 +2MnSO4 +5Fe2(SO4)3 +10(NH4)2SO4 + 68H20

Normality of FAS solution (N1) = 0.05N

Materials required:-
Volume of KMnO4 solution (V2) = ------
Burette, Pipette, conical flask, 250 ml measuring
Normality of KMnO4 solution (N2) = flask, funnel, crystalline FAS, weighing balance.
V1N1= V2N2 Procedure:-
Normality of KMnO4 =20 x 0.05/V2
The Mohr’s salt solution of required
Normality of KMnO4 (N2) = ------ N concentration was prepared by weighing a
sample of mohr’s salt accurately and making up
Strength of KMnO4 = N x Eq.wt.
the solution to the mark in 250ml standard flask.
Strength of KMnO4 = ----- x 31.6 The burette was rinsed and filled with KMnO4
Strength of KMnO4 = ----- g/L solution. In a clean conical flask 20 ml of FAS
was pipette out and add 1 test tube full of
Molarity = Strength / Mol.wt sulphuric acid. Now run the KMnO4 solution
= ---- /158 from burette to the conical flask with
continuous shaking until the first permanent
Molarity of KMnO4 = ----- M
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 7
 EXP.NO.8 ESTIMATION OF AMOUNT OF
KMnO4 USING M/40 FAS
S.No Volume Burette Reading Volume Indicator
of FAS (ml) of KMnO4
(ml) Initial Final (ml) Self Aim:-
Indicator
1 20 0 (KMnO4) To determine the molarity and strength of the
2 20 0 given solution of potassium permanganate with
standard solution.
Volume of FAS solution (V1) = 20ml
Equation:-
Normality of FAS solution (N1) = 0.025N
2KMnO4 +8 H2SO4 + 10 FeSO4(NH4)2.6H2O 
Volume of KMnO4 solution (V2) = ------
K2SO4 +2MnSO4 +5Fe2(SO4)3 +10(NH4)2SO4 + 68H20
Normality of KMnO4 solution (N2) =
Materials required:-
V1N1= V2N2
Burette, Pipette, conical flask, 250 ml measuring
Normality of KMnO4 =20 x 0.025/V2 flask, funnel, crystalline FAS, weighing balance.
Normality of KMnO4 (N2) = ------ N
Procedure:-
Strength of KMnO4 = N x Eq.wt.
The Mohr’s salt solution of required
Strength of KMnO4 = ----- x 31.6 concentration was prepared by weighing a
Strength of KMnO4 = ----- g/L sample of mohr’s salt accurately and making up
the solution to the mark in 250ml standard flask.
Molarity = Strength / Mol.wt
The burette was rinsed and filled with KMnO4
= ---- /158 solution. In a clean conical flask 20 ml of FAS
was pipette out and add 1 test tube full of
Molarity of KMnO4 = ------- M
sulphuric acid. Now run the KMnO4 solution
from burette to the conical flask with
continuous shaking until the first permanent
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 8
S.No Volume Burette Reading Volume Indicator EXP.NO.9 ESTIMATION OF AMOUNT OF
of FAS (ml) of KMnO4
(ml) Initial Final (ml) Self KMnO4 USING M/50 FAS
Indicator
1 20 0 (KMnO4) Aim:-
2 20 0
To determine the molarity and strength of the
given solution of potassium permanganate with
standard solution.
Volume of FAS solution (V1) = 20ml
Equation:-
Normality of FAS solution (N1) = 0.02N
2KMnO4 +8 H2SO4 + 10 FeSO4(NH4)2.6H2O 
Volume of KMnO4 solution (V2) = ------
K2SO4 +2MnSO4 +5Fe2(SO4)3 +10(NH4)2SO4 + 68H20
Normality of KMnO4 solution (N2) =
Materials required:-
V1N1=V2N2
Burette, Pipette, conical flask, 250 ml measuring
Normality of KMnO4 =20 x 0.02/V2 flask, funnel, crystalline FAS, weighing balance.
Normality of KMnO4 (N2) = ------ N
Procedure:-
Strength of KMnO4 = N x Eq.wt.
The Mohr’s salt solution of required
Strength of KMnO4 = ----- x 31.6 concentration was prepared by weighing a
Strength of KMnO4 = ----- g/L sample of mohr’s salt accurately and making up
the solution to the mark in 250ml standard flask.
Molarity = Strength / Mol.wt
The burette was rinsed and filled with KMnO4
= ---- /158 solution. In a clean conical flask 20 ml of FAS
was pipette out and add 1 test tube full of
Molarity of KMnO4 = ----- M
sulphuric acid. Now run the KMnO4 solution
from burette to the conical flask with
continuous shaking until the first permanent
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 9
S.No Volume Burette Reading Volume Indicator EXP.NO.10 ESTIMATION OF AMOUNT OF
of (ml) of KMnO4
Oxalic Initial Final (ml) Self KMnO4 USING M/20 OXALIC ACID
acid Indicator
(ml) (KMnO4) Aim:-
1 20 0
2 20 0 To determine the molarity and strength of the
given solution of potassium permanganate with
Volume of oxalic acid solution (V1) = 20ml standard solution.

Normality of oxalic acid solution (N1) = 0.1N Equation:-

Volume of KMnO4 solution (V2) = ------ 2KMnO4 +3 H2SO4 +5 COOH-COOH. 2H2O 

Normality of KMnO4 solution (N2) = K2SO4 +2MnSO4 +5Fe2(SO4)3 +10CO2 + 8H20

V1N1 =V2N2 Materials required:-

Normality of KMnO4 = 20 x 0.1/V2
Burette, Pipette, conical flask, 250 ml measuring
Normality of KMnO4 (N2) = ------ N flask, funnel, crystalline oxalic acid, weighing
balance.
Strength of KMnO4 = N x Eq.wt.
Procedure:-
Strength of KMnO4 = ----- x 31.6

Strength of KMnO4 = ----- g/L Oxalic acid solution of required concentration

was prepared by weighing a sample of oxalic
Molarity = Strength / Mol.wt
acid crystals accurately and making up the
= ---- /158 solution to the mark in 250ml standard flask.
The burette was rinsed and filled with KMnO4
Molarity of KMnO4 = ----- M
solution. In a clean conical flask 20 ml of oxalic
acid was pipetted out and add 1 test tube full
of sulphuric acid was added ad heated to 60o -
70o C. Now run the KMnO4 solution from
burette slowly into the conical flask with
continuous shaking until the first permanent
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 10
S.No Volume Burette Reading Volume Indicator EXP.NO.11 ESTIMATION OF AMOUNT OF
of (ml) of KMnO4
Oxalic Initial Final (ml) Self KMnO4 USING M/40 OXALIC ACID
acid Indicator
(ml) (KMnO4) Aim:-
1 20 0
2 20 0 To determine the molarity and strength of the
given solution of potassium permanganate with
Volume of oxalic acid solution (V1) = 20ml standard solution.

Normality of oxalic acid solution (N1) = 0.05N Equation:-

Volume of KMnO4 solution (V2) = ------ 2KMnO4 +3 H2SO4 +5 COOH-COOH. 2H2O 

Normality of KMnO4 solution (N2) = K2SO4 +2MnSO4 +5Fe2(SO4)3 +10CO2 + 8H20

V1N1 =V2N2 Materials required:-

Normality of KMnO4 = 20 x 0.05/V2
Burette, Pipette, conical flask, 250 ml measuring
Normality of KMnO4 (N2) = ------ N flask, funnel, crystalline oxalic acid, weighing
balance.
Strength of KMnO4 = N x Eq.wt.
Procedure:-
Strength of KMnO4 = ----- x 31.6

Strength of KMnO4 = ----- g/L Oxalic acid solution of required concentration

was prepared by weighing a sample of oxalic
Molarity = Strength / Mol.wt
acid crystals accurately and making up the
= ---- /158 solution to the mark in 250ml standard flask.
The burette was rinsed and filled with KMnO4
Molarity of KMnO4 = ----- M
solution. In a clean conical flask 20 ml of oxalic
acid was pipetted out and add 1 test tube full
of sulphuric acid was added ad heated to 60o -
70o C. Now run the KMnO4 solution from
burette slowly into the conical flask with
continuous shaking until the first permanent
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 11
 EXP.NO.12 ESTIMATION OF AMOUNT OF
KMnO4 USING M/50 OXALIC ACID

Aim:-
S.No Volume Burette Reading Volume Indicator
of (ml) of KMnO4
Oxalic Initial Final (ml) Self
To determine the molarity and strength of the
acid Indicator given solution of potassium permanganate with
(ml) (KMnO4)
1 20 0 standard solution.
2 20 0
Equation:-

2KMnO4 +3 H2SO4 +5 COOH-COOH. 2H2O 

Volume of oxalic acid solution (V1) = 20ml
K2SO4 +2MnSO4 +5Fe2(SO4)3 +10CO2 + 8H20
Normality of oxalic acid solution (N1) = 0.04N

Volume of KMnO4 solution (V2) = ------ Materials required:-

Normality of KMnO4 solution (N2) = Burette, Pipette, conical flask, 250 ml measuring
flask, funnel, crystalline oxalic acid, weighing
V1N1 =V2N2
balance.
Normality of KMnO4 = 20 x 0.04/V2
Procedure:-
Normality of KMnO4 (N2) = ------ N
Oxalic acid solution of required concentration
Strength of KMnO4 = N x Eq.wt.
was prepared by weighing a sample of oxalic
Strength of KMnO4 = ----- x 31.6 acid crystals accurately and making up the
solution to the mark in 250ml standard flask.
Strength of KMnO4 = ----- g/L
The burette was rinsed and filled with KMnO4
Molarity = Strength / Mol.wt solution. In a clean conical flask 20 ml of oxalic
= ---- /158 acid was pipetted out and add 1 test tube full
of sulphuric acid was added ad heated to 60o -
Molarity of KMnO4 = ----- M
70o C. Now run the KMnO4 solution from
burette slowly into the conical flask with
continuous shaking until the first permanent
faint pink colour is obtained. Do the titration
until concordant value is reached and record
your observation.

Result:-

Strength of KMnO4 = -------- g/L

Molarity of KMnO4 = ----M

Page 12