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Wagner 2013
Wagner 2013
201300043
REVIEW
Ultrasonic Welding of Aluminum
Alloys to Fiber Reinforced Polymers**
By Guntram Wagner,* Frank Balle and Dietmar Eifler
To realize multi-material structures, e.g., out of light metals and fiber reinforced polymer (FRP)
composites suitable joining methods are required. The ultrasonic metal welding technology was applied
to produce high strength joints between different aluminum alloys and carbon fiber reinforced polymers
(CFRPs) in the framework of research unit 524 of the German Research Foundation. The bonding
mechanisms were characterized by light optical and scanning electron microscopy (SEM). The
performed analysis have shown a bonding zone with an intensive contact between the metallic surface
and the load bearing carbon fibers of the CFRP as a result of the ultrasonic welding process. Using
precipitation hardening aluminum alloy AA2024 tensile shear strengths of up to 58 MPa could be
achieved. In comparison to established joining techniques ultrasonic metal welding can be an interesting
alternative to realize dissimilar joints for the automotive or aircraft industry.
aluminum foils with glass but this findings were not further
REVIEW
REVIEW
may be the causal component for the joints.
But the results were unexpected. The inves-
tigations have shown that up to 50% better
results can be achieved for ultrasonic metal
welding (Figure 3).[31,32]
The reasons for this behavior can be found
in cross-sections (Figure 4). For ultrasonic
plastic welding only a bonding between the
metal and the polymer matrix occurred.
Moreover, the oscillation perpendicular to
the surface caused damages at the glass fibers
(Figure 4a). Using the ultrasonic metal
welding system the polymer matrix was
plasticized and displaced out of the joining
Fig. 2. Important welding parameters of ultrasonic metal welding.[42] area and as a result of this a direct contact
between the metal sheet and the glass fibers
was developed (Figure 4b). Consequently
the mechanical properties positive because the better deform- mechanical load on the joint can be directly transferred from
ability of the components enable a more distinctive contact the metal into the fibers. In addition no damage of the glass
between the welding partners. For higher pre-heating temper- fibers could be determined.[31]
atures the energy assumption in the upper component is such
intensive that a weld cannot be developed.[26]
5. Aluminum/Carbon Fiber Reinforced
Polymer (CFRP)-Joints
4. Metal/Glass Fiber Reinforced (GFRP)-Joints
5.1. AA5754/CF-PA66-Joints
At the WKK systematic investigations about the ultrasonic
weldability of metals with brittle materials like glass or ceramic
5.1.1. Specimen Geometry and Experimental Setup
were carried out for the first time. To develop a welding zone
between the metal part and the glass an Al-interlayer is Due to the successful results for Al/GFRP-joints the
necessary, because aluminum is the only material which weldability of Al/CFRP-joints were investigated. At first the
enables a weld with glass or ceramic in
standard ambient conditions. It was possible
to realize vacuum-tight welds which
achieved tensile shear strengths of up to
50 MPa for metal/glass-joints[27] and up to
120 MPa for metal/ceramic-joints.[28,29] To
understand the bonding mechanisms micro-
structural investigations were carried. In
high-resolution transmission electron micro-
graphs of the bonding zone it could be shown,
that the thickness of the developed joining Fig. 3. Comparison of achievable strengths using ultrasonic metal welding and ultrasonic plastic welding.[31]
zone lies in range from 2 nm up to 10 nm
and the changes in the surface structure
predominantly occurs in the metal compo-
nent.[30] The main bonding mechanism prob-
ably based on intermolecular interactions
because for a diffusion bonding the welding
time is too short.
Based on the knowledge of ultrasonic
metal welding of metals to glasses and
ceramics further investigations concerning
the ultrasonic weldability of glass FRPs
were carried out. In this case the ultrasonic
metal welding system was compared with
the plastic welding system, because it was Fig. 4. Bonding zone of an (a) ultrasonically metal welded and (b) ultrasonically plastic welded metal/GFRP –
assumed that the plastic matrix of the GFRP joint (SEM).[31]
Fig. 6. (a) Specimen geometry, (b) ultrasonic spot welding system for Al/FRP joints.[42]
REVIEW
the peak value a damage of the textile and thus a decrease of
the tensile shear strength occur. A variation of the welding
energy and the welding force shows nearly the same
tendencies (Figure 9b,c). These detailed investigations show
that the optimum parameter triple is FUS ¼ 160 N, u ¼ 40.5 mm,
and WUS ¼ 2160 Ws.
For a further optimization of the joint strength the surface
condition of the aluminum sheet was varied by mechanical
and/or chemical pre-treatments. Figure 10a shows a load–
displacement curve for an AA5754(R ¼ rolled, initial condi-
tion)/CF-PA66-joint. The hybrid weld fails without any
preliminary warning at a tensile shear load of FZ ¼ 3860 N.
Fig. 7. CCC-model for statistical analysis of ultrasonic metal welded joints.
The change of the electrical resistance DR in the joint was also
measured. The curve is characterized by a course of nearly zero
followed by an intensive increase due to a sudden fracture
of the welding area between aluminum and carbon fiber
composite.[43] By the application of a chemical surface pre-
treatment of the aluminum sheets using a pickling process in
nitric acid (acid pickled ¼ AP) the tensile shear strength of
the joints increases considerably.[39] Figure 10b illustrates a
characteristic load–displacement–curve for AA5754(AP)/CF-
PA66-joints. After reaching the yield point of the entire
hybrid joint at approximately FZ ¼ 4000 N, plastic deformation
occurs characterized by a flat discontinuous course. The shape
of the load–displacement–curve in this range can be traced
back to the PLC-effect in the AA5754 sheet, see detail in
Figure 10b.[40,41]
The change in the electrical resistance DR was also
measured. During elastic deformation of the weld no change
in DR could be observed. The first change of DR corresponds to
the yield point of the joint (first dashed line in Figure 10b).
Fig. 8. Contour plot (WUS ¼ 2160 Ws) for AA5754/CF-PA66-joints.[42] After a slow linear increase of DR due to plastic deformation as
a result of Al/C-fiber debonding a pronounced increase of the
electrical resistance was measured straight before final
a result of the higher wear in the welding
zone. In addition the number of oscillations
with the amplitude u decrease because of the
shorter welding time. Due to these effects
statistical-based investigations are necessary
to find the best parameter combinations.
The maximum tensile shear strength of
about 31.5 MPa can be determined for FUS
¼ 160 N and an oscillation amplitude
of u ¼ 40.5 mm. But in two-dimensional cuts
of the diagram the mutual dependence of
the process parameters can be discussed in
detail (Figure 9).[34] In every diagram two
process parameters are constant. In Figure 9a
the oscillation amplitude u varies between 38
and 42 mm. Besides the cours of the average
tensile shear strength the lower and upper
confidential interval for 95% is specified. With
increasing oscillation amplitude up to
40.5 mm an intensive displacement of the
matrix of the CFRP causes a better contact Fig. 9. Achievable tensile shear strength as function of (a) oscillation amplitude, (b) welding force, and (c)
between the metal sheet and the fibers. After welding energy for AA5754/CF-PA66-joints.[34]
Fig. 10. Load–displacement- (e_ ¼ 0,2 103 1/s) and load–resistance-curve for (a) AA5754(R)/CF-PA66- and (b) AA5754(AP)/CF-PA66-joint.[43]
failure of the hybrid weld occurs (second dashed line in the satin fabric structure (Atlas 1/4) the polyamide layer
Figure 10b). thickness near the surface depends on the position in the CFRP
Figure 11 shows a characteristic welding area of an AA5754/ sheet. The transition zone of the crimped fiber bundles is
CF-PA66-joint. It can be seen that the polymer matrix is characterized by periodically repeating layer thicknesses of
displaced out of the welding zone and the ductile aluminum about 250 mm (Figure 13). During the ultrasonic welding
flows around the carbon fibers. Based on this cross-section it process in the contact area of the sonotrode tip the fiber
can be assumed that an intermolecular contact as well as a reinforcement covering polymer layer is displaced by the
mechanical interlocking has been developed during the ultrasonic transversal waves. Digital image analysis clearly
ultrasonic metal welding process between the metal and the show the reduction of the PA66-layer thickness within the
fibers. Furthermore, no damage of the fibers was observed.[42,43] range of the crimped carbon fiber bundles by the ultrasonic
The assumption that a direct contact between metal surface welding process, but not a complete displacement in the entire
and carbon fibers is possible, were proven by additional welding area underneath the sonotrode tip.
welding experiments of Al sheets with a C-fiber textile without In Figure 14 cross-sections of corundum blasted (CB) joint
polymer matrix. A cross-section of the interfacial area of an are pictured. Especially at roughness peaks a direct contact
Al/C-fiber textile-joint is shown in Figure 12. Focused ion between the carbon fibers and the aluminum surface was
beam (FIB) preparation was used to investigate the interface generated (Figure 14a). However, in zones between warp and
between carbon fibers and Al bulk material in detail. It can be filling thread a polymer layer with a thickness of about 100 mm
seen, that after the ultrasonic welding process the carbon fibers remains because of the high layer thickness of about 250 mm in
are perfectly embedded by ductile aluminum due to the plastic the initial state before welding (Figure 14b). Instead of a direct
deformation of the metal sheet.[23,37] contact between carbon fibers and aluminum surface a pure
Furthermore the microstructure of ultrasonically welded adhesive bonding between the aluminum and polymer very
hybrid joints was studied by analyzing the polymer layer similar to the conventional plastic welding technique
before and after the ultrasonic welding process. According to occurs.[36]
In Figure 15 the different surface conditions are pictured. A
comparison of as rolled (R) surface (Figure 15a) with CB
surface (Figure 15b) show an intensive increase of the
macroscopic roughness for the CB surface. The surface
roughness Ra increases from 0.3 to 3.0 mm (Table 1). By acid
pickling (AP) (Figure 15c), the surface roughness is hardly
affected and only selected peaks were removed. So the
roughness profile Rt decreases from 1.7 to 1.2 mm. Continuative
investigations have shown that an open and porous oxide
structure of the Al sheet has been generated and leads to an
improved interface strength of AA5754(AP)/CF-PA66-joints.
Due to the positive effect of CB and AP pre-treatments both
processes were combined. The developing surface, which have
nearly the same Rt but as expected with a lower Ra is shown in
Figure 15d. But the combination of both pre-treatments led
only to a slight increase of tensile shear strength to 50 MPa in
comparison to 46 MPa for CB and 49 MPa for AP could be
Fig. 11. SEM micrograph of an AA5754/CF-PA66-joint (cross-section).[42] observed (Figure 15e).
REVIEW
Fig. 12. Metal/carbon fiber textile-joint: (a) specimen, (b) back view of a prepared joint, (c) FIB cut through the welding zone, (d) detail of the welding zone.[37]
Regarding the long-term stability for the differing pre- blasted Al sheets. So an easier and faster attack of the
treatments considerable differences can be determined interface occurs. Possible microstructural reasons were
(Figure 16). The hybrid joints were additionally tested investigated by fracture surface analysis and X-ray photo-
after aging of 1 and 4 weeks in an ambient temperature of electron spectroscopy (XPS) and are described in the
T ¼ 40°C and a humidity of 95%. For a mechanical and following communications in this journal.
a combined pre-treatment of the aluminum sheets (CB and
AP) nearly no decrease of the tensile shear strength was
5.1.3. Cyclic Behavior
measured. But for the only acids pickled joints the tensile
shear strength decreased 20%.[38] From a macroscopic point Fatigue tests were performed at ambient temperature on a
of view a main reason for the higher decrease of the tensile servo-hydraulic testing system with a frequency of 5 Hz. Force-
shear strength for these joints can be seen in the smoother controlled load-increase tests (LITs) and constant amplitude
surface of the acid pickled aluminum in comparison to tests were realized at a load ratio of R 0.
Figure 17 shows the experimental setup. The single overlap
samples were clamped by hydraulic grips. In addition, an
adjustable bending strut was used to minimize bending
stresses. PTFE-disks applied between the samples and the
struts reduce the friction in load direction. The cyclic
deformation behavior was measured with two strain gauges
positioned on the aluminum side and the CFRP side. To
characterize the cyclic deformation behavior with the strain
gauges, the total strain was determined. As described before,
one distinctive feature of the Al/CFRP-joints is a direct contact
between the aluminum sheets and the carbon fibers, which
allows the measurement of the change in electrical resistance
DR during monotonic and cyclic loading. A DC-power
supply enables reproducible long-term electrical resistance
measurements.
Fig. 13. Polymer layer thickness of the CF-PA66 sheet before and after ultrasonic
To estimate the endurance limit of the joints and to
welding.[46] determine appropriate stress amplitudes for constant
Fig. 14. Optical micrographs at different interface positions of AA5754 (CB)/CF-PA66-joints: (a) polymer poor area, (b) polymer rich area.[46]
Fig. 15. SEM micrographs of pre-treated AA5754 sheets: (a) initial state, as rolled (R); (b) CB; (c) acid pickled (AP); (d) combined pre-treatment, CB and AP, (e) increase of the tensile
shear strength.[46]
REVIEW
Fig. 18. (a) Displacement amplitude and change in electrical resistance in stepwise load-increase tests for AA5754(AP)/CF-PA66-joints, (b) Load–Woehler-Curve of ultrasonically
welded AA5754(AP)/CF-PA66-joints.[43]
well as the change in electrical resistance DR for a chemical CFRP (2 mm) eAl,m,t is more intensive. Afterwards both courses
pre-treated AA5754/CF-PA66-joint are shown. The courses are nearly constant. But the electrical resistance measurement
clarify that the total mean strains are not suitable as early shows that the cyclic loading leads to slow damage
indication of imminent fracture of the specimen. However, accumulation in the welding zone. The changes in the range
the electrical resistance is a stronger indicator for the of 0.5 V are caused by microstructural changes and minor
developing fatigue damage in the joining zone. A first slight plastic deformations in the aluminum. After 4 104 cycles a
increase of DR could be observed at about N ¼ 4 104 cycles, progressive increase of DR can be observed as a result of the
Figure 18a, point I. This first pronounced change in DR proceeding increasing damage of the welding zone followed
correlates with the endurance limit of these joints, compare by an abrupt final increase at failure of the joint
Woehler-Curve in Figure 18b.[43] After N ¼ 7 104 cycles the
course shows a pronounced increase, Figure 18a, point II,
5.2. Comparison with AA1050- and AA2024/CF-PA66-
until final failure occurs at N ¼ 9.5 104 cycles. The load
Joints
level of point II is equivalent to the yield point of the entire
AA5754(AP)/CF-PA66-joint. Thus the electrical resistance is a The previous results have shown that for a successful
well suited and high sensitive physical value to determine ultrasonic welding process of Al/CFRP-joints a sufficient
the actual fatigue state of Al/CFRP-joints. plastic deformation capability of the metal sheet is necessary.
In the following a constant amplitude tests (CAT) at Therefore the metal component was varied. Beside the
Fa ¼ 2250 N is shown (Figure 19). Again the total mean commercially pure and ductile Al alloy AA1050 the precipita-
strain eAl,m,t and eCFRP,m,t of the aluminum sheet and the change tion hardening aluminum alloy AA2024 were chosen. For
of DR for the entire AA5754(AP)/CF-PA66-joints were AA2024 a combined process of heat treatment and ultrasonic
measured welding was studied. To guarantee a sufficient ductility of the
During the first cycle total mean strains eAl,m,t and eCFRP,m,t AA2024 sheets a solution annealing at a temperature of 500 °C
increases fast as a result of the load. Because of the less for a period of 30 min of the Al sheet was realized before the
thickness of the aluminum sheet (1 mm) in comparison to the welding process. After water quenching, the ductile AA2024
sheet was immediately ultrasonic spot welded to the CFRP
within the next 15 min (Figure 20). This fast process is
necessary because of the rapid hardening of AlCuMg alloys.
Finally a post-weld heat treatment of the entire welded AA
2024/CF-PA66-joints was realized, which is characterized by
two consecutive procedures: artificial ageing for 20 h at the
temperature of T ¼ 180 °C and finally air-quenching or natural
ageing for 1 week at ambient temperature. Due to no
mechanical loading of the hybrid joint during aging at
T ¼ 180 °C no significant thermal impact of PA66 was
observed.[44]
The results of the tensile shear tests for Al/CF-PA66-joints
with three different Al are summarized in Figure 21. The
welding parameters for all hybrid joints were optimized
again by statistical test methods. For each Al/CFRP-
Fig. 19. Mean strain and change of electrical resistance during CAT of AA5754(AP)/
combination the best suitable process parameters are listed
CF-PA66-joints, Fa ¼ 2250 N. in Figure 21.
Fig. 20. Precipitation hardening of hybrid Al/CFRP-joints after ultrasonic welding: (a) solution annealing, ultrasonic welding, and natural ageing, (b) solution annealing, ultrasonic
welding and artificial ageing.[47]
Fig. 21. Tensile shear strength of different hybrid Al/CFRP-joints.[47] Fig. 22. Comparison of suitable methods to join metals with FRP.[45]
REVIEW
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