\ il Hydrocarbon ce iP § ee | 5108 OE FON Ne am eSaral.comwSaral Contents 1 Module Description 2 Homework Index 3 Exercise 1 4, Exercise 1A 5. Exercise 2 6 Exercise 2A 7 Answer Key Note Page - ii Page - ii Page - 1 Page - 5 Page - 7 Page - 12 Page - 14 Detailed solutions are available on the eSaral App. Hydrocarbon wSaral & at wa area SIwSa ral Hydrocarbon Module Description For mastering the concepts only learning is not sufficient. We have to practice and apply those concepts in problem solving. This sheet does just that. It contains a collection of problems segregated in the following exercises to help you master the concepts in a systematic and organized way, “Practice makes a man perfect” 1. Concept builder— 1 & 1A As soon as you have finished learning the concept do the problems from these exercises first. These exercises contains easy level questions to help you build your concepts. 1 —+» Contains Single Correct Type questions 1A —» Contains pattern based questions incorporating the latest JEE Advanced based patterns like more than one correct, matching list, match the column, ete. 2. Brain Booster— 2 & 2A Now that you have built your concepts it’s time to master them by solving Brain Boosting problems, Don’t hurry through these problems. Take time to solve & learn from them. These exercises contains Medium & Tough level problems. Do questions from 2 & 2A after attempting 1 & 1A 2 —+ Single Correct Type questions. 2A ——» Pattern Based questions. 3. Simulator — JM & JA Contains questions from previous year JEE Mains & JEE Advanced questions in exercise JM & exercise JA respectively. Get the real taste & feel of the type of questions being asked in JEE. It’s a great tool for simulating your mind with JEE problems. These exercises are not included in the module but are provided separately. JM —» JEE Mains previous years topic wise questions. JA —+ IEE Advance previous years topic wise questions. Eee scat (rodwSaral Hydrocarbon Home Work Index Problem solving is an integral part of learning, Find questions to solve after each video in the homework Index. Make sure that you attempt all the problems (in Ex 1 to 2A) after learning a topic from the videos. For example if you have finished topic 8, first attempt all the problems listed in the index corresponding to topic 8 before proceeding to the video of topic 9. Sr. No,| Topics Ex-l_| Ex-tA| Ex-2 | Ex-2A 1 Preparation Methods of 2 1 1 |Alkanes : Hydrogenation and Wurtz Reaction : hoo Desuteryton and Kobe's Reaction | *7 2 te 3. |Physical Properties of Alkanes 4 |Chemical Properties of Alkanes 8-16 5 9-12 5 een of AES by elimination a id 6 |Carbocation Rearrangement 7 [Preparation of Alkenes: Dehydrohalogenation | 20-21 6 16 8 |Alkenes: Other Methods of Preparation 9 [Physical Properties of Alkenes 10 __|Electrophylic Addition reactions on Alkene 22-25 7 17-19 i [Adon of Carb, Ozonobsis and Oxidation |, 57 30-22 D satin Free adel Substitution and a % 9 13. |Conjugited Diene, KCP ws TCP 4 Preparo: ‘Akkyne and Physieal Properties of/ [45.45 4 15. |Chemical Properties of Akyne 31-36 25-28 16 [Nuckeophilic Addition Reaction and Oxidation of |Alkyne 17 |Substitution and Cyelic Polymerisation of Akyne 18 |Introduction of Aromatic Hydrocarbons 19 _[Eketrophilc Substitution Reactions and Oxidation lof Aromatic Hydrocarbons 20 JACK 37-40 3-4,8 29-35, 1-8 wSaral & at wa area SIwSaral Hydrocarbon Exercise - 1 Concept Builder SINGLE CORRECT TYPE QS. — Which of the following alkanes cannot be produced by Kolbe electrolysis of sodium Each question has FOUR options for correct or potassium salts of carboxylic acids ? answer. ONLY ONE of these four options is correct (A) Methane (B) Ethane option. For each question, choose the correct option (© Butane (D) Hexane to answer the question. Q6. —_Decarboxylation of isobutyric acid yields :- Preparation Methods of Alkanes : (A) Isobutane Hydrogenation and Wurtz Reaction (B) Propane (©) 2-Methylpropane (D) None of the above a. Q UAL A is = D Q7. Rate of decarboxylation of following DB carboxylic acid with sodalime will be in order: (A) CH(CH)-CH,(B) PY if cH,coon S22 Dd cH,cH,coon "62 FP (D) D H OH CH, Q2. Which of the following hydrocarbon cannot CH,-CH-COOH "> be obtained by sabatier and Senderen’s (Arne ner | B)n>R>y reaction = On>n>r, (D)r>r>t, (A) CH, (B) CH, . . (CH, (D) All Preparation Methods of Alkanes: Decarboxylation and Kolbe's Reaction @. Anhydrous solution of the following compound on electrolysis gives ethane := (A) Acetic acid (B) Acetamide (©) Potassium acetate (D) Ethyl acetate Sodium propionate on decarboxylation with sodalime give (A) Propane (B) Ethane (C) Butane (D) Pentane Chemical Propet of Alkanes Q8. In the chlorination of methane, one of the chain propagating step is (A) CH, + Cl CHCl (B) CH + CLOCH,CI + Cr (A) CH, + CH,>CH,-CH, (D) Cle + Chl, Q9. The homolytic fission of hydrocarbon results in the formation of - (A) Free radicals (B) Carbocations (C) Carbanions (D) Carbenes wWSaral & at wae area SIwSaral Quo. qu. Qi2. Q13. qua. Qis. n-Heptane when heated to a temperature of about 800 K under high pressure in the pres- ence of Cr,0,/Al,0, catalyst gives - (A) I-heptene (B) 2-Methythexane (C) Toluene (D) Xylene Number of structural isomer which ean be theoretically obtained on monochlorination of 2-methylbutane is - A6 @2 O33 WMA The least reactive alkane towards free- radical substitution reactions is - (A) CH, (B) (CH (C) CH,CH, (D) CH,CH,CH, Arrange the following in correct order of reactivity towards Cl/hv - (a) CH, (b) CH,CH, CHs (©) CHCH,CH, — (d) CH bi CH, (Aa>b>e>d — (B)d>e>b>a (C)b>c>a>d — (Dyc>b>d>a caOYALO, are > The wrong title of the reaction would be :~ n-hexane Cyclic compound. (A) Aromatisation (©) Cyelisation (B) Hydroformation (D) Isomerisation Major product for the reaction is - OO “ OK . . ow Xx) Br Hydrocarbon SOAP, Major product : od ) AAA Q16. AAA CH, (A) oO oD Preparation of Alkenes: Dehydration of Alcohol by elimination QI7. Alkenes can be prepared by =~ (A) Dehydration of alcohols (B) Kolbe's electrolytic synthesis (C) Dehydrohalogen (D) All of these QI8. For the reaction Dy atc HS the major product is [eat (a) (B) [| Y-an, oC) oop QU9. The order of reactivity of alcohols with respect to acid catalysed elimination will be: (@) (CH,),C-OH (b) CH,CH,CH. .CH,OH (o) CH,CH-CH,-C 1H, OH Code is = (A)a>b>e (B)a>c>b (C)b>arec (D)b>c>a Preparation of Alkenes: Dehydrohalogenation Q20, An halide CH,,Br on treatment with ale, KOH give 2-pentene only. The halide willwSaral (A) CH.-CH,-CH,-CH,-CH,-Br (B) CH-CH,-CH,-CH-CH, Br (C) CH,-CH,-CH-CH,-CH Br CH, (D) cu, G-e-cH Br Qu. On On 1 1 Which one is most easily dehydrohalogenated ? “I (By (Cm (D) all with same case Op Electrophylic Addition Reactions On Alkene Q22, Which of the following will give positive test of unsaturation with Bromine water - (A) Oo (B) oO © O wo) “NZ Which one of the following will not give positive test with bromine water ? (A) OC (B) O (©) (©) CH, = CH, (D) CH = CH Q23. Qu, The test for unsaturation is confirmed by the decolourisation of which of the following :- (A) Iodine water (B) CuSO, solution (©) Bromine water (D) All of these Hydrocarbon Q25. Two jars A and B are filled with hydrocarbons. Br, in CCI, is added to these jars. Adoes not decolourise the Br, solution, but B decolourises. What are A and B respectively : (A) Alkane and alkene (B) Alkene and alkane (©) Both (D) None Addition of Carbene, Ozonolysis and Oxidation by Beayer's Reagent Q26. Dilute aqueous KMnO,, at room temperature reacts with R - CH =CH-R to give (A) R= CHO (B) R~ COOH (C) RCHOH ~ CHOHR (D) CO, + H,0 Qu7. In the following sequence of reactions, the alkene affords the compound 'B' CH, CH = CHCH, —°5A—%29B, The compound B is :- (A) CH,COCH, (B) CH,CH,COCH, (©) CH,CHO (D) CH,CH,CHO Oxidation, Free Radical Substitution and polymerisation of Alkene Q28. Propene when heated with chlorine at about 500°C forms:~ (A) CH, CLCH = CH, (B) CH,. CHCLCH,CI (C) CH,CLCHCLCH,CL (D) All the three wSaral & at wae area SIwSaral Preparation: All Physical Properties of Alkyne yne and R =e, R-C=C_R. 29, R-CH,-C The reagent is (A)Na (B) HCl in HO (C) KOH in CH,OH followed by (D) Zn in aleohol sodamian/ A Q30. The reagent(s) for the following conversion, BN eh He vate = (A) Alcoholic KOH (B) Alcoholic KOH followed by NaNH, (© aqueous KOH followed by NaNH, (D) ZvCH,OH Chemical Properties of Alkyne Qa. Propyne on reaction with aqueous chlorine gives - (A) 1, 1, 2, 2-Tetrachloropropane (B) 1, 2-Dichloropropene (©) 1, L-Dichloropropanone (D) 2, 2-Dichloropropanone 32. Mesitylene can be obtained by polymeriza- tion of - (A) Ethyne (C) Propene (B) Ethene (D) Propyne Q33. Product x is ~ (A) Cis-2-butene (B) Trans-2-butene -2-butene —_ (D) E-2-butene Q34, The product formed in the reaction Hydrocarbon ayn ow or oOO™ Acetylene gives - (A) White precipitate with AgNO, and red precipitate with Cu,Cl, (B) White precipitate with Cu,Cl, and red precipitate with AgNO, (C) White precipitate with both the re (D) Red precipitate with both the reagents Q35. nts cH, [A] Sse [B] [A] and [B (A) cis, trans-2-butene (B) Both trans (C) trans ci Q36. CH,-C= ] are respectively :- butene butene (D) Both cis -2- butene Q37. Which of the following reactions can be employed for getting odd carbon alkanes in good yield ? (A) Wurtz reaction (B) Corey-House reaction (C) Both (D) None of these Q38. The ease of formation of fr follows the order - radicals (A) 3°> 28> 18> CH, (B) CH, > 19> 293° (C) 19> 28> 3°> CH, (D) 2°> 19> 3°> CH,wSaral Hydrocarbon 39. Lindlar’s catalyst is = Q40. The reaction of toluene with Cl, in presence (A) Pt in ethanol of FeCl, gives predominantly :- (B) Pd + Cac (A) benzoyl chloride (© Niin ethanol (B) benzyl chloride (D) Na in liquid NH, (C) 0 and p-chlorotoluene (D) m-chlorotoluene Exercise - 1A Concept Builder ONE OR MORE THA’ QB. Match the column I with column Il. ONE CORRECT TYPE Column-t Column-I \Electrophilic subs |(A)] Wurtz reaction Oc, seuion Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question. QL. A mixture of ethyl iodide and n-propyl iodide is subjected to Wurtz reaction. The hydrocarbon that are formed is- (A) n-Butane (B) Propyne (C) n-Pentane (D) n-Hexane Q2. Aqueous solution of sodium acetate and sodium propionate on electrolysis yields :~ (A) Ethane (B) Butane (C) Propane (D) Pentane MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-I are labelled as A, B, C and D while the statements in Column-IT are labelled as (P), (Q), (R) and (8). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. |(B) [Hydration of alkenes |(q) |Free radical substitution [Ekectrophilic addition (c)}Nitraon ofabcane or [EKO [Reaction of alkene | ah NBS (8) |Nucleophile substitution MERICAL TY! The answer to each question is a NUMERICAL VALUE, For each question, find the correct ‘numerical value (in decimal notation, truncated/ rounded-off to the second decimal place; ¢.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) Q4. Number of compounds which have more activating power than benzene. OH SO.H wWSaral & at wer area SIwSa ral Hydrocarbon ASSERTION AND REASON (©) Statement-1 is true, statement-2 (D)Statement-1 is false, statement-2 is true. false. (A) Statement-1 is true, statement-2is true and statement-2 is correct explanation for | QS. Statement-I : Neopentane forms only one statement-1 monochlorinated product, (B) Statement-1 is true, statement-2 is true Statemen : Neopentane has four and statement-2 is NOT the correct identical methyl group attached to a explanation for statement-1 quaternary carbon, SUBJECTIVE TYPE mejor Give mechanism of this reaction. Q7. Propose mechanism : | J . B Be = HBr + Cr A [or Q8. Find out reagents involved in following conversions I p—&- — a. c-c-c, py a L__@__,q 1—CH,-CC-D a (rodwSaral Exercise - 2 Hydrocarbon Brain Booster SINGLE CORRECT TYPE Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question Qu. Q. Q@. If ethyl bromide and methyl bromide are mixed in equal proportions and the mixture is treated with sodium, predict the number of organic product formed :~ (A)3 (B)2 (C1 (D)4 Propane will be obtained by the decarboxylation of which of the following carboxylic acid :~ (A) CH,CH,CH,COOH @B) no-¢-cH,cHl-cH, ° (© capac, coon (D) All the above The number of Structure of monocarboxylic acids which on decarboxylation form isopentane is = (A)2 «3 (B) 1 (D)4 Choose the correct set showing the production of alkane by decarboxylation of the carboxylic acids :- 2,2-Dimethylpropanoie (A) jacid ((B)] Butanoic acid (b)] butane (a)Jisobutane} (C)]2-Methylpentanoie acid | (c)|pentane (D)}4-Methylpentanoie acid | (4) propane The answer is :~ (A) Aand C (C) Band D (B) A and B (D) C and D Q5. Qi. During electrolysis which anion migrates towards anode so as to produce 2, 3-dimethyl butane = coo (A) CH,-CH,-COO- (B) CH, CHK 60 (Cc) CH,-CH-COO CH, (D) CH,COO Which of the following carboxylic acids undergo decarboxylation easily - (A) C,H,CO-CH,COOH (B) C,H,COCOOH (C) C.H,CH.-COOH, on (0) CH.GH,-Coon NH. + eo TCH.COOK rCOOK Which of the ga of anode :- (A) CH, H, (B) CHyH, (©) CHACHsCO, (D) CH, + C\H,,+CO,7 es evolved on the surface Electrolysis and decarboxylation of CH,-CHCOONa respectively give :- Hy (A) 2,3-dimethylbutane and propane (B) Propane and 2,3-dimethylbutane (C) Isobutane and propane (D) n-butane and propane wSaral & at wa area SlwSaral wy. The major product obtained in the reaction, cH, OQ ee is CH.Br “O CH, Br (© Nitration of propane with nitric acid vapour at about 430°C is expected to yield :- (A) I-nitropropane (B) 2-nitropropane (C) Nitroethane and Nitromethane (D) A mixture of all the above CH, Br (B) CH (D) O Br Qi0. QI1. Consider the following reaction : cH. cn{O-cr1 sp. => Which of the following types of hydrogen atoms are most easily abstracted by the bromine radical to form HBr ? (A) Hydrogen atoms attached to a benzene ring, (B) Hydrogen atoms of the methyl group attached directly to benzene ring. (C) Hydrogen atoms of the methylene group of the ethyl substitutent. (D) None of these Qu. The most appropriate product. Qs. Qua. Hydrocarbon ‘oO oO © LY oD oS cH (CH,—C—CH,CH,CH,OH ++ Alkene oO The major alkene formed in the above reaction will be:- HC CH, — A) C=C M) We Neu, cu cH, (B) cr CHACH CH, cH, cH, (©) Ci '—CH,-CH=CH, cH, (D) none of the above OH OO “a “x (Major) Major productwSaral Hydrocarbon 15. CH.CH,-CH,-CH,-o1 —s=50 QI8,3-Methy!-2-pentene on reaction with HOC] Major Product (Y) is := gives: (A) cis-2-butene Clon (B) trans-2-butene (A) CH,-CH;-¢-CH-CH, (C) L-butene cH, (D) Iso-butene cHon (B) CH,-C -CH-CH, Q16. Consider the following reaction : CH, cn, CH, CH.CH, cl Cl cut crn, NCC cee L_¢ 1 cH H cH, , 0 a Which of the following base will give the on best yield of the alkene II as the major (D) CH,-cH,-C-CHCH, product cH (A) CH,O. (B) CHO (©) (CH)),cO a @)(CH),CO” QI. WOH HBr A QU7. What is 'A’ in the following reaction Product (A) is = CH.-CH=CH, be Bi bs) 5 “ ue : wd CH,-CH=CH, Br Br © O Oy CH-CH.-CH,-cl ° 6 Q20. Propanal and pentan -3-one are ozonolysis ) product of — (A) CHs ~ CH, CH =¢— CHa cH CH-CH-CH, CHy—CHs ‘1 (B) CHy — CH =C — CH —CH: © (B) CH ~CH-e— cH cls CHy—CHy ¢ (©) Cis Chie —G —Chs decn-cn, CH3 —C —CH3 ©) (D) Cts CH CH eH cy cts — CH CH wSaral & at wa area SIwSaral Q21-CH, CH CH CH, AN 9x tg 0) a Product (y) is - (A) CH ¢— CH, 8 mote o@ (B) cH,-¢-H & @ mole) (C)H-C-H § mote) (D) CH,-CH=CH-CH, Qn. x—F+cHo : X)is- CHO (2 mole) (A) Aromatic compound (B) Non-aromatic compound (© Anti-aromatic compound (D) All of these HBr / Peroxide, ‘At Q23. cH—c-cH CH, d Hy _—_______.. 'B" Product ‘A’ & 'B" are respectively a (A) cH—C— CH CH, & cn, CH —FH—CH— CH, CH, Br (B) cH, HCH CH. & CH, Br Qu. Q26. Q27. Q28. Hydrocarbon Br I (© Both are CH,—¢—CH,— CH, CH, br (D) Both are CH,—CH—CH 1 cH, Acetylene is obtained by the electrolysis of- (A) Soi (B) Potassium fumarate (C) Both (A) and (B) (D) None of these m succinate Consider the following reaction sequence CH,-C=CH #5 A 4, B The product (A) and (B) are, respectively (A) CH,CH,CHCI, and CH,CH,CHO (B) CH,CCI,CH, and CH,-C=CH (©) CH,CCI,CH, and CH,CO-CH, (D) CH,-CHCH-CH,CI and CH,CHOHCH,OH 1-Butyne and 2-Butyne can not be distinguished by reaction with the following except (A) [Ag(NH)),] (B) [Cu(NH,),] (C) Baeyer's reagent (D) Sodamide Hydration of or H,SO,/HgS0, giv 6 ay °C c=CH in presence of CH.CH, @) oy Propyne on polymerisation gives =~ (A) Mesitylene (©) Ethyl benzene (B) Benzene (D) Propyl benzeneHydrocarbon jum bromide reacts | Q33. The major product of the reaction, with t-butanol, the produet would be :- M (A) Benzene © (B) Phenol +cH,cocl YS jg (C) t-butyl benzene (D) t-butyl phenyl ether CHMe, Me Me 30. CH-CH —Mgc1GHLOH, 4 Chhv, 5 ie . , e COMe I - (A) (B) N ‘COMe Day ainehC What is C2 CHMe, CHMe, (A) -~< CH,COMe () >“ © (D) None of these CH CHMe, (© cae CH. CM, Q34. Compound 'A' on chlorination gives (D) cen compound'B, compound reacts with ale. KOH gives gas 'C’, which decolourise Bayer reagent. ozonolysis of compound NBS, , ale. KOH. gives only HCHO compound. ‘A’ is : Qa. ~ — aT orl CH, Identify 'B' product :- (cH, (cH Aaa (BR) Aa OH OAon OA - as Corp O) oven Le. (ee Q32. 2A > Major (X) A> Major (¥) ba ve pose < auc, Major (Z) ‘on Product (Z) is = A, Band C are : (A) simple hydration w Oo ® (B) hydroboronation, mercuration- Br demercuration, hydration (© hydration, hydroboronation, Br mercuration-demercuration © oO” (vy (D) mercuration-demercuration, hydration, hydroboronation wSaral & at wa area SlwSa ral Hydrocarbon Exercise - 2A Brain Booster PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions, Each question has FOUR options. ONLY ONE OR MORE THAN of these four options corresponds to the correct answer: For each question, choose the option corresponding to the correct answer: Paragraph for Q. 1 to 3 X(C,H,Br) "5 ¥Y 8247 (Dibromide) tt _, W (gas) —*X2> white ppt. X, Y and Z are: Qu. x Y Zz (A) CH,—CH,CH,CH,Br CH,—CH-CH—CH, aa Be Be (B) CH,—CH,CH,CH,Br CH,—CH,—CH=CH, aaa BB (C) CH—CH,—CH,—CH, CH, —CH=CH—CH, H-araray, Bo ©) a4-a4-aeat, CH,—CH-CH—CH, oh B BB Q2. Reductive ozonolysis of ¥ yields : Paragraph for Q. 4 to 5 (A) 2 moles of CH,CHO. wed hot F ed hot Fe (B) CH,CH,CHO & HCHO orCu tube . (C) aca, & HCHO u CH,CH,CH(CI), "254 (D) CH,CH,COOH & HCOOH 7 Ni/H. Q3. Which of the following statement (s) is/are | 4+ Ais - correct : (A) Propyne (B) Propene (A) Compound W has 2 DU (C) Propanal (D) Propanone (B) ¥ & W are functional isomers (C) Wean be converted into Y with Lindlar | 5+ © is ~ catalyst (A) Mesitylene (B)Benzene (D) W can be converted into Y with Ni/Pt (C) Cyclooctatetraene (D)Benzaldehyde Get Top Ranks in IIT-JEE/NEET/10"/9"/8" with eSaral APP Get it on (rodwSaral MATCHING LIST TYPE Hydrocarbon Each question has TWO (02) matching lists: LIST I and LIST I, FOUR options are given representing matching of elements from LIST I and LIST Il, ONLY ONE of these four options corresponds to a correct matching. For each question, choose the option corresponding to the correct matching. Q6. Match the List : List-I (> cH-cH.-cH,Br (i) HBr cH cucu B+ cH-CHBr-CH, (ii) HBr + peroxide +> CH-CHBr-CH.Br Gi) NBS Dy Brc-cH-cH, (iv) Br,, low temperature A BC OD @ dG) @ (vy ii) ®) (Gi) (iv) Gilt) © @ Gi) Gy Gi) © Gi) @ Gi) (iv) MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-t are labelled as A, B, Cand D while the statements in Column-II are labelled as (P), (O), (R) and (5). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-IT, Q7. Match the column I with column II. Column-1 Column-It (A) Dehydrohalogenation of alkyl halides (B) Electrolysis of sodium salt (©) Ozonolysis (D) Dichloro ethylene (B) Decarboxylation (p) Kolbe reaction (q) Alc. KOH () Addition product of ethylene (s) Sodalime (0 Alkene wSaral & at wa area SIwSaral NUMERICAL TYPE The answer to each question is a NUMERICAL VALUE. For each question, find the correct numerical value (in decimal notation, truncated! rounded-off to the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) Qs. How many of the following compounds will show higher rate of electrophilic substitution Hydrocarbon NMe. OH oO CN (g) Oo ASSERTION AND REASON reaction than benzene - (A) Statement-1 is true, statement-2 is true and ° statement-2 is correct explanation for cH, ti statement-1. @ o) oy ~o{O) (B) —Statement-1 is true, statement-2is true and statement-2 is NOT the correct explanation, for statement-1, cl (©) Statement-1 is true, statement-2 is false. NO, (D) — Statement-1 is false, statement-2 is true. © @ oy Q9.— Statement-I : |-Butene on reaction with HBr in the presence of a peroxide produces 1- bromobutane. OC Hy Statement-II : It involves the formation (e) oO ° of a primary radical Answer Key 2.4, B,C 5A 3.(A) 9 48;Bor;(C)>q;(D) >qwSaral Hydrocarbon Ex- 2A 1B 2.B 3.A,C 4A 5A 6A 7.(A)>9;(B)>p;(C) >t; D)>1;(E)>s 85 9.C wSaral & at wa area SIwSaral -: Important Notes & Formulas :-