- -

2)Chan - Reacuon iMeohon

h

Inisiation P ¢oPhaaupnFi ermindtien

meaiate S 1pme i a!lsb reocion, i

Tne inter
calles cnain imitiaton ie
Som prosbe Ond
1 eComneS ouns
morenter medi QLe
teaetont tuo
nhe Chain popoa on SaRcSinGla ne
intermeiobeis desupyesnme cneal
erminati oosper htiabi on stepi
eaceans Pintermesictes)
(nbermeaiqtes enCacns ermpdigec)recuc
Poego tioo ep
|Coeceeiate s ¢oees Terinati on SteF

Mechanieim

Poocepo
Teroimacon
A
A
giel

1pas Aoter mesiotec

free radioale|
Freeabeme lor largerROmenuc oi Stoole.
e
mo olesbna conbain one or more onpoed
elecbo
omge
ipnen met relabively stcible).

Cunstoole ansionly reackie)

CLASSIFY
 ons.ard Polercuostancec
EecM call Croreed obomS,moleculecoriroement
o moleoule6
xamples

AC6 asaOtibe [inserme diates inreaeions

3Holecoles
rare itotion s eome molecsles o behg»
reacbive an oc agintermediate
Rs
L
R=
clonsider:A
ntermdiate

-o
acbie
become
Concen trabioo
oo ma
in
to
e
meOSUre
rreading mixtore Con

Kma nou e observed ond cOn oe coneu derea

bo pe inter Meaiaees
4Tronsoipncomplexes
y ostobletorms os molecoled oercoWsiens
betuween eadtcnts

6*mple iMechanisms
re radicolsChain Re.ccion Mechanicm

kaH/to
Mechanismg
+ a

Ha 6e 2
CLASSIFY
ho
 2Moledwlor obermediates,Nanehain Hednahism.
Pename oataly za Fernenecticn reactions

with expermnmeplalRAe

E E
kHndli enteneqotiob
MecnanismS
Anaym (A dnzgme)
Lenm *engme
5) ComplezNOO-Cnoin M¢cnaniem
Tronsition

Pepononesus decomposo d azoneunone

ARs
aCan oeekplknes py obolasjna ne ekisbence
oanener aized anduosteble Fordr
eackcn A
AAA Fomabion ofenesaizes molecle
AANtA Gorn bo sade for m oa Colsion
Pontomeosdecomgosi tion inpo
POdcAS

stepsioteetiog kinetuis modol

Posbblate p topose omecha nis
2)Petp rmine ne o erall rote g xpressionfor poduco
$ comare (E)oitn perimntdilderermined rate
pessiG

CLASSIFY
 in tesing kinetic Hosels
Ryles
The natake o eaceio nOcom ponn Encsvm s
otmenet reac lons o iin eacn step inte sexies o
elementa y reccbions
ne2
he netrate ot anintermediae or Sree radicale is
o2fo
Pseodo -stady etote ApProi nation (FsSA)|

n Testi nte corr OS pondencebetweenexpeime.ntod

Prposes mednanisms
ele mento zacicns,a
n atinielyesee.nce
pothesize
o
typesointer mediates

PO Anunseen and bamecsxaple |ntecmediotay

USuc greseneat euch Gmal Concentrations
bhatitc rae61 canaein temitore co

xi mall on
Srdadicate Apprekimatjon

.CLASSIFY.
 /

Tupei une rehomoaeneous preaent

cotuosoioitiaN
in aiorms
concentration Co iS
ebe as ieecotelust Crcom binedin

Qnappreciaole exteo fst interoed iate K.

an aceunti ne For one Catol vees

weosetme bat eitner

l

OK thoab the nterediate isineApil briom lwiibs

reactantltmye

(tecctane (iwar esiate)

wnete
 Ekample:
Tho raçtion 2AteEA2s has bcen studies Kioekically
Cn ee obe oi iormaiien o rodoce as
be ound
bope wal correlakes oA eolouoing te
votiOn
O1aCA C
pressionE eae
wnab reacklon mechesis is 9ugestebytis Tote
istn obe
bhat bne intermeaiotespooabl
eactin insjcotes.
onsissotan
association lofreactat molecules anottat the2
Chao reoCAi do does not ecc
Gieo Re popose omechanisa

|
A opAermino tne validit
O2Cce
echabism
So
Mose1 1
AtA

2) BE A2BKABA kEAKa2sJ-KA[|
KA

K**s

CLASSIFY
 Sol:Cconu)

2
otn mi

roposes mechanism ienot vols

Mosel2
syostiote (z)in
A
k&TKatKt-

SOme aisven lop Ka<i{

P Pose hedhanism iyaid 2

CLASSIFYY.
 zometmane: EHaN
ALO
Reaction Mecnojo em

Lcw)NJ He
Tegs:TN2
Soln

Azo A 20Aso+ 2o
AO A20 A2O A26
+ t

A zo
Ctg4N
A2o] ()
KAZS
Sons (2 in

KKAze3

CLASSIFY
Dasian HomoodrepOaasc eadpors
topic: louoduid n
tuo sot eugmen
)8 och raaeior

4aa sokias exten

Toloo Eneconcomuraton
omeoang in
o
a
reoctioa

aiveo compondn
pmysical popex
sokoel ue as
Fdilo

Volum
e
er mall concúcioittekracbiue jndes,euc
3) Chanae iniota preseure oia coastantt

olo tne nange in volao o Constantpressu re

SuStem

oitfereualmebned of oalsis
pi eenvioMethdd

diredk odwihoo6 Onintearot

n
tne
e
procecu
da beiore q pn

CLASSIFY
voluwne of reacLion minture not vou me oj
reaCLor
USa mean Constant densiiy eoction sy ste n

Reacuonro te 0 componen
oreal Gaces
d
C

(cive)-Ji
v c Gidv N
Or Gos reacuOn s ih Chngingnemsar molees
imple w ay {inding tne recction rate ic to
iollow thechanaein total ptescure, Toi me susem

CLASSIFY
A rolusicoft0tal pressure
FarlsOkhesmal ecctions

aAt3* S ines
Leb

No initial moeso
moeodu ConsUmee
oo iona)conversion inisial mberp moles
HENmoer okmoes otan te|
e otol bumser d moldspre en intne Ss s
At Onuime,b
Notsot inert
A eS nerUS

N Nso tsx

zNotxsn
xNeNo
o
ONANo a]1v
NA CA-C
 oal presBE
Tlo

P afial p¢esaurd
PioFintial pressore oi
e
iniial touo) pdessbte

he
con ponen
compon ens

CACpoj
SceC PA

P
a
An C-a-
Don)PodUd6 er
5 n acttay

P Ro mo)CRT
Ngte ne reciso stoichiownetnisno Kaon, tranope
socnoICeoation is neeADSuo cepesen
ectieo, bhen the buol presure Pocee duro
CannOb ce osed

.CLASSIFY
 Ocsipra) osnuersioo
FraCsioo oonyknd
ofeocbans Co veruo to sormetnin
--
Suppose
NAO Finitialamouavo
Aiabnereacbod abime
NAOmponb presenb| otbime

Thene cooersion ofA

N
|in the constantvolmDystem

1-NA NA Ca-C

Sampeproblem
Asiootm
On stariog
s reccuion320ac
doasonservessolbc
oporeisiod ndkat a tnedna ok omins
irs oqden

betotal pessor s\nGmm ansofteraongme 2ommi

iada)iniial pressore Thegsess orei
omins c)tneral ikeot the e ion?
act te nd
Civen

10is

CLASSIFY.
Sarople pobiem
9ow tion
A
OA6.

Recol Py Nt

N Nao2

2 P3PAe
Lae 3
2
NA PO
Pa t- omin
276m m NG_
P )2 (ao) -"
io mi ns Da 4 mm qPo90mnHa
n -K (1o mns)
/ao 36mins
CLASSIFY
 neara)AnalySs data
ussa particolar for no roueesoalonans oter
popiatue integsatioond maune mataedA nipulatien
PoO c hay the plOtoacertaim aonOentuta io
Sneaio vs eime snould|iel da raignu line

seps
oriteuha¢aue epreBsio n Ror telreoctioms
)orangeth eqpation DComeiniastne Kxa yariobiee
andotegrate the eations

A)bm

S
neceotion
e_eqatio onboineaate

Ksreghtiine is oBervecrom uneplot

,
2Tne condeotrationiepopoti ono to ime plo
toeinedratedeauation
oso

co
apc
o
meckagism eclectes is consistent iob, arotne r

.e onanismSnodi oeties

irreve rsioNe uninoleab)ar Tupe iret-order

ProdocsS
JCA

hot
CAG

A
In CO ke

CLASSIFY
 In -K
In C InCRo -K
CA nChotKt
D *m
nO
oecme oiSa

Ono
C
d Ca
Nad

Cho-C
-a
CAo (xa|
cti

CAO
dra)Conde rsion,

Pioe -
C -CAdd
CA
CAbd

Note
bop noamedade totris

Do- k Kine ok onausis. Thereior

no al Siret ordr reoctins

()1 -K|
|- a dove

In )--k t
3

.CLASSIFY
Ioterms of half- ik, °/a,
C in
-
Ca

KC
dA
CA

InCa

Sampleprodan
Civer
|
Kby

Regd:tya

a
Soln

Ko6s min I2 ,
2e28 min

.CLASSIFYY.
Irrevetsipie Bimolecular TuP ecnd -order eecions
aeeRA DccAs
oass2:AB PodoOes

Case 2A2RoducUs
e mK+o
A KO

Inbe ORFackiona Converbion,xa

C-Cho 1-A) dCA -chda

dca-kOK KCA t
-K Ca da

Cho (-XA
kdt
-KCaot kC
A dxA 1-

CLA SSIFY