JEE 11 - Advanced Test-1-Paper-2

Questions

1. For a particle moving along the x-axis, a scaled x-t graph is shown in figure. Mark the correct
statement(s):

(a)  Speed of the particle is greatest at C

(b)  Speed of the particle is greatest at B
(c)  Particle is speeding up in region marked CD
(d)  Particle is speeding up in the region marked AB

2. A particle has an initial velocity of 10 m/s. It moves under a constant retarding force along the line of
velocity which produces a retardation of 5 m/s2. Then
(a)  The maximum displacement in the direction of initial velocity is 10 m
(b)  The distance travelled in first 3 seconds is 7.5 m
(c)  The distance travelled in first 3 seconds is 12.5 m
(d)  The distance travelled in first 3 seconds is 17.5 m

3.
Which of the following unit vectors is/are not perpendicular to both and
?
(a)  

(b)  

(c)  

(d)  

4. A car accelerates from rest at a constant rate α for sometime, after which it decelerates at a constant
rate β to come to rest. If the total time elapsed is t seconds, then which of the following options is/are
correct
(a)  Maximum speed reached during the motion is

(b)  Total distance travelled is

(c)  Maximum speed reached during the motion is
(d)  Total distance travelled is
5. Velocity-displacement graph of a particle moving in a straight line is as shown in the figure

(a)  Magnitude of acceleration of particle is decreasing

(b)  Magnitude of acceleration of particle is increasing
(c)  Acceleration versus displacement graph is straight line
(d)  Acceleration versus displacement graph is parabola

6. A man wishes to throw two darts one by one at the target at B with same speed so that they arrive at the
same time.

Mark the correct statements about the two projections.

(a)  Projectile that travels along trajectory A was projected earlier
(b)  Projectile that travels along trajectory B was projected earlier
(c)  Second dart must be projected at angle such that
(d)  Second dart must be projected at angle

7. A particle thrown in the vertically upward direction passes three equally spaced windows of equal
heights. Then:

(a)  The average speed of the particle while passing the windows satisfy the relation vav1 > vav2 > vav3
(b)  The time taken by the particle to cross the windows satisfies the relation t1 < t2 < t3
The magnitude of the acceleration of the particle while crossing the windows, satisfies the relation
(c)  
a1 = a2 a3
The magnitude of change in the speed of the particle, while crossing the windows, would satisfy the
(d)  
relation v1 < v2 < v3
8. Velocity variations of an object moving along a straight line are plotted against time as shown.

(a)  The positive acceleration is maximum in first two seconds

(b)  The magnitude of acceleration is maximum during the ninth second
(c)  The object is the farthest from the starting point after 16 s
(d)  The displacement is the largest at 7 s

9. Two balls are dropped from same height at 1 second interval of time. The separation (in m) between the
two balls after 4 second of the drop of the 1st ball is: (take )

10. The area of the parabola bounded by the line is square units, where p and q do not
have any common factors. The value of p – q is:

11.
and are two such, vectors that and and . If the angle

between and is , then find the value of .

12. From a point on the ground at a distance, 3 m from the foot of a pole, a ball is thrown, at an angle of
45°. The ball just clears the top of the pole and strikes the ground at a distance of 9 m from the foot of
the pole, on the other side. Find the height of the pole (in metres, correct to two decimal places).

13. Airplanes A and B are flying with constant velocity in the same vertical plane at angles 30° and 60° with
respect to the horizontal respectively as shown in figure. The speed of A is ms-1. At time t = 0 s,
an observer in A finds B at a distance of 500 m. This observer sees B moving with a constant velocity
perpendicular to the line of motion of A. If at t = t0, A just escapes being hit by B, t0 in seconds is

14. A boy playing on the roof of a 10m high building throw a ball with a speed of at an angle of
with the horizontal. How far away (in meters) from the throwing point will the ball be, at the same
height of 10 m from the ground?
 
15. Trajectory of particle in a projectile motion is given as . Here, x and y are in meters. For this
projectile motion match the following with g = 10 m/s2

Column 1 Column 2
(a) Angle of Projection (p) 20
(b) Angle of velocity with horizontal after 4s (q) 80
(c) Maximum Hieght (r) 45o
(d) Horizontal Range (s)

(a)  (a) → (r), (b) → (s), (c) → (p), (d) → (q)

(b)  (a) → (p), (b) → (q), (c) → (r), (d) → (s)
(c)  (a) → (p), (b) → (p), (c) → (r), (d) → (r)
(d)  (a) → (r), (b) → (r), (c) → (p), (d) → (q)

16. Column I shows some vector equations. Match Column I with the value of angle between A and B given
in Column II.

Column I Column II
(a)
(p) Zero

(b)
(q)

(c) (r)

(d) and
(s)

(a)  (a) → (r), (s); (b) → (p); (c) → (q), (p); (d) → (p)
(b)  (a) → (r), (s); (b) → (p); (c) → (q); (d) → (p)
(c)  (a) → (r); (b) → (p); (c) → (q); (d) → (p), (s)
(d)  (a) → (r), (s); (b) → (p); (c) → (q); (d) → (r)
17. Match the following columns:

Column I Column II

(a) (p) Speed must be increasing

(b) (q) Speed must be decreasing

(c) (r) Speed may be increasing

(d) (s) Speed may be decreasing

(a)  (a) → (r), (s); (b) → (r), (s); (c) → (p); (d) → (q)
(b)  (a) → (r), (s); (b) → (r), (s); (c) → (q); (d) → (p)
(c)  (a) → (r); (b) → (p); (c) → (p), (q); (d) → (r), (s)
(d)  (a) → (r), (s); (b) → (s); (c) → (p); (d) → (q)

18. In projectile motion shown in figure (Figure not drawn to scale). 

(The usual assumptions apply)

Column I Column II
(a) Change in velocity between O and A (p)
(b) Average velocity between O and A (q)
(c) Change in velocity between O and B (r)
(d) Average velocity between O and B (s) None of the above

(a)  (a) → (q); (b) → (s); (c) → (p); (d) → (r)

(b)  (a) → (q); (b) → (s); (c) → (r); (d) → (p)
(c)  (a) → (s); (b) → (q); (c) → (r); (d) → (p)
(d)  (a) → (q); (b) → (r); (c) → (q); (d) → (r)
19. If satisfies the system of equations
and (where {.} and [.] denotes the fractional and integral parts
respectively), then match the following:

Column – I Column – II
(A) (P) 7.7
(B) (Q) 1.1
(C) (R) 1
(D) (S) 3
(T) 4

Which of the following is the only correct combination?

(a)  
(b)  
(c)  
(d)  

20. If satisfies the system of equations

and (where {.} and [.] denotes the fractional and integral parts
respectively), then match the following:

Column – I Column – II
(A) (P) 7.7
(B) (Q) 1.1
(C) (R) 1
(D) (S) 3
(T) 4

Which of the following is the only correct combination?

(a)  
(b)  
(c)  
(d)  
21. Let and be A.M’s and n G.M.’s respectively between
and 1 (where ) such that and . Then

Column -I Column-II

(I) is divisible by (P) 9

(II) is divisible by (Q) 8

(III) is divisible by (R) 6

(IV) is divisible by (S) 4

(T) 2

Which of the following is the only correct combination?

(a)  (II), (R), (S), (T)
(b)  (I), (R), (S), (T)
(c)  (II), (P), (R), (T)
(d)  (I), (Q), (S), (T)

22. Let and be A.M’s and n G.M.’s respectively between

and 1 (where ) such that and . Then

Column -I Column-II

(I) is divisible by (P) 9

(II) is divisible by (Q) 8

(III) is divisible by (R) 6

(IV) is divisible by (S) 4

(T) 2

Which of the following is the only correct combination?

(a)  (III), (R), (T)
(b)  (IV), (R), (T)
(c)  (IV), (S), (T)
(d)  (III), (P), (T)

23. If x is the arithmetic mean, and y and z are the two geometric means, between any two distinct positive
numbers, then the value of is

24. If AM, GM and HM of the first and last terms of series are the terms of
series itself, then value of is

25. If 8 harmonic means are inserted between two numbers and such that arithmetic mean of
and is times equal to geometric mean of and , then is equal to
26. If the sum of 20 terms of a series, of which every even term (second, fourth, sixth etc. terms) is 2 times
the term before it, and every odd term (third, fifth etc. terms) is 3 times the term before it, the first
term being unity, is equal to , then _____.

(where and )

27. The number of integral values of satisfying the inequation is

28. The natural numbers are grouped as , , , …. . The last but

one number of the tenth group is

29. If and the minimum value of is , where and are natural numbers, then _____.
(a)  
(b)  
(c)  
(d)  

30. If then
(a)  
(b)  
(c)  
(d)  

31. For the series

,
where each term in curly brackets is a term of sequence, whose:
(a)  7th term is 16
(b)  7th term is 18
(c)  sum of first 10 terms is
(d)  sum of first 10 terms is

32. Let be in GP. If the H.M. of and is 12 and that of and is 36, then
(a)  
(b)  
(c)  
(d)  

33. If for every , where is the term of the sequence,

, then
(a)  
(b)  
(c)  
(d)  
34. The value(s) of satisfying the equation is/are
(a)  
(b)  
(c)  
(d)  1

35. Let and be two positive real numbers. Suppose are two

Arithmetic means; are two Geometric means and are two Harmonic Means between
and , then
(a)  
(b)  
(c)  

(d)  

36. If , then which of the following is/are true?

(a)  
(b)  
(c)  
(d)  

37. Three different solutions of oxidising agents. K2Cr2O7, I2, and KMnO4 is titrated separately with 0.19 g of
K2S2O3. The molarity of each oxidising agent is 0.1 M and the reactions are:
i. Cr2O72– + S2O32– → Cr3+ + SO42–
ii. I2 + S2O32– → I⊝ + S4O62–
iii. MnO4⊝ + S2O32– → MnO2 + SO42–
(Molecular weight of K2S2O3 = 190, K2Cr2O7 = 294, KMnO4 = 158 and I2 = 254 g mol–1)
Which of the following statements is/are correct?
(a)  All three oxidising agents can act as self-indicators.
(b)  Volume of I2 used is minimum.
(c)  Volume of K2Cr2O7 used is maximum.
(d)  Weight of KMnO4 used in the titration is maximum.

38. 4 gm of NaOH can be neutralised by

(a)  100 ml of 1N HCI
(b)  200 ml of H2SO4
(c)  1000 ml of KOH
(d)  2000 ml of H3PO4

39. For the reaction:

The correct statement(s) in the balanced equation is/ are

(a)  Stoichiometric coefficient of is 6
(b)  Iodide is oxidized
(c)  Sulphur is reduced
(d)  H2O is one of the products.
40. Consider the following reaction,
Br2 + OH– BrO3– + Br– + H2O (unbalanced) select the correct statement.
(a)  Equivalent weight of Br2 when it is reduced to Br– is 80
(b)  Equivalent weight of Br2 when it is oxidized to BrO3– is 96
(c)  Net equivalent weight of Br2 is 96
(d)  It is a disproportionation reaction

41. Which of the following samples of reducing agents is/are chemically equivalent to 25 mL of 0.2 N KMnO4
to be reduced to Mn2+ and water:
(a)  25 mL of 0.2 M FeSO4 to be oxidized to Fe3+
(b)  50 mL of 0.1 M H3AsO3 to be oxidized to H3AsO4
(c)  25 mL of 0.1 M H2O2 to be oxidized to H+ and O2
(d)  25 mL of 0.1 M SnCl2 to be oxidized to Sn4+

42. Which of the following statements is/are true for titration?

(a)  Titrant is the standard solution and is generally taken in a burette.
(b)  At the equivalence point volume of titrant used must be equal to initial volume of analyte
(c)  Dichromate titrations do not require an external indicator for endpoint detection
(d)  In iodometric titrations, generally KI is used as an oxidising agent.

43. A 100 ml mixture of Na2CO3 and NaHCO3 is titrated against 1 M HCl. If V1 L and V2 L are consumed when
phenolphthalein and methyl orange are used as indicators, respectively, in two separate titrations,
which of the following is true for molarities in the original solution?
(a)  molarity of Na2CO3 = 10V1
(b)  molarity of NaHCO3 = 10 (V2 – 2V1)
(c)  molarity of Na2CO3 = 10 (V2 + V1)
(d)  molarity of NaHCO3 = 10 (V2 – V1)

44. Which of the following species can be oxidised completely by 0.1 mole of MnO4– in acidic medium?
(a)  0.5 mole Fe2+
(b)  0.16 mole FeC2O4
(c)  0.25 mole C2O42–
(d)  0.6 mole Fe3+

45. Among the following, what is the total number of compounds having a +3 oxidation state of the
underlined elements?
a. K4 P2O7
b. Na Au Cl4
c. Rb4Na[HV10O28]
d. ICl
e. Ba2 Xe O6
f. O F2
g. Ca(ClO2)2
h. NO2–

46. If the number of revolutions made by electron in 1 sec in H-atom in its nth orbit is one fourth (1/4) of
the number of revolutions made by electron in 1 sec in the 6th orbit of He+ ion, then value of n3 is
47. A 10 ml 0.1M aqueous solution of KxH(C2O4)y required 8 ml of a 0.1 M acidified KMnO4 solution. Hence
the value of x is __________.

48. n-factor for the following reaction is

FeS2 → Fe2O3 + SO2

49. 5.00 mL of 0.10 M oxalic acid solution taken in a conical flask is titrated NaOH from a burette using
phenolphthalein indicator. The volume of NaOH required for the appearance of permanent faint pink
colour is tabulated below for five experiments. What is the concentration, in molarity, of the NaOH
solution? (in nearest integer)

Exp. No. Vol. of NaOH (mL)

1 12.5
2 10.5
3 9.0
4 9.0
5 9.0

50. Find the basicity of H3PO4 for which equal weights of H2SO4 and H3PO4 neutralise the 100 mL of 0.1 N
NaOH separately. Given that basicity of H2SO4 is 2.

51. Some reactions are given in Column I and their n-factor and strength is given in Column II & III
respectively.

For 1.8 NA molecules of HCl given in column I, the only correct combination is
(a)  (III) (i) (P)
(b)  (III) (ii) (R)
(c)  (III) (iii) (Q)
(d)  (III) (ii) (S)

52. Some reactions are given in Column I and their n-factor and strength is given in Column II& III
respectively.

For 9.8% given in column I, the only correct combination is

(a)  (II) (i) (Q)
(b)  (II) (iii) (S)
(c)  (II) (ii) (P)
(d)  (II) (i) (R)
53. Match the following.

Column I Column II
(A) 4.5 m solution of CaCO3 density 1.45 gm/ml (p) Mole fraction of solute is 0.2
(B) 3 M 100 ml H2SO4 mixed with 1 M 300 ml H2SO4 solution (q) Mass of the solute is 360 gm
(C) 14.5 m solution of CaO (r) Molarity = 4.5
(D) in 2 litre solution of 4 M NaOH, 40 gm NaOH is added (s) Molarity =1.5
(t) 16.66 % (w/w) of NaOH in solution

(a)  A → p
(b)  A → q
(c)  A → r
(d)  A → s

54. Match the following.

Column I Column II
(A) 4.5 m solution of CaCO3 density 1.45 gm/ml (p) Mole fraction of solute is 0.2
(B) 3 M 100 ml H2SO4 mixed with 1 M 300 ml H2SO4 solution (q) Mass of the solute is 360 gm
(C) 14.5 m solution of Ca (r) Molarity = 4.5
(D) in 2 litre solution of 4 M NaOH, 40 gm NaOH is added (s) Molarity =1.5
(t) 16.66 % (w/w) of NaOH in solution

(a)  D → q, r
(b)  D → p, r
(c)  D → p, s
(d)  D → q, t
 Answer Key

1. B,C,D 2. A,C 3. B,C,D 4. A,B 5. A,C 6. B,C

7. A,B,D 8. A,B,D 9. 35.00 10. 1.00 11. 6.00 12. 2.25
13. 5 14. 8.65 15. C 16. B 17. A 18. B
19. A 20. D 21. B 22. C 23. 2.00 24. 40.00
25. 2.00 26. 10.00 27. 2.00 28. 109.00 29. A,B 30. A,B,C,D
31. A,C 32. A,B,C,D 33. A,D 34. A,D 35. A,B,C 36. C,D
37. B,D 38. A,B 39. A,B,D 40. A,C,D 41. A,C,D 42. A
43. A,B 44. A,B,C 45. 3.00 46. 216.00 47. 3.00 48. 11.00
49. 0 50. 2.00 51. B 52. A 53. C 54. A
 Solutions

1.  (B,C,D)
Point of the steepest slope corresponds to the maximum speed. Particle will speed up when the directions
of acceleration and velocity are the same. Acceleration is positive if slope of velocity is increasing and vice
versa. So for region AB, both the acceleration and velocity are positive while for CD, both are negative.
Therefore, the particle is speeding up in these regions.

2.  (A,C)
At t = 2 sec, the particle reverses its motion.
Maximum displacement in the direction of  initial velocity =  
= 10 m.
Distance travelled in first 3 seconds = Displacement from t = 0 to t = 2 added to magnitude of displacement
from t = 2 to t = 3
 = 12.5 m

3.  (B,C,D)
The perpendicular unit vector is given by

Now

Magnitude of 

Hence

4.  (A,B)
We have tanθ 1 = α and tanθ 2 = β
If the car accelerates for t1 and decelerates for t2, then t = t1 + t2
and

or

Distance covered in time t is the area under the curve.

5.  (A,C)

Here, v is decreasing but the slope (dv/ds) is constant. Hence magnitude of a is decreasing.
Further, v = -As + B and (dv/ds) = - A
Here A and B are positive constants.
Therefore, a = (- As + B)(- A) = A2s – AB
i.e. a – s graph is a straight line with positive slope and negative intercept.

6.  (B,C)

Both the darts have the same speed and arrive at B at the same time. So, we consider TA, TB :

, ie, projectile that travels along B was projected earlier, that is second dart is projected
at angle and

(As range is same)

7.  (A,B,D)

As the particle is going up, it is slowing down, i.e., speed is decreasing and hence we can say that time taken
by the particle to cover equal distances is increasing as the particle is going up.

Hence,  .

As 

Acceleration throughout the motion remains same from equation, 

So, 

8.  (A,B,D)
Four slopes are +2 ( for 0 - 2 s), -4/3 ( for 4 - 7s) , –3 (for 8 - 9s)  and  +3/2 (for 14 - 16s). 
For maximum positive acceleration, positive slope is to be maximum. Option a is correct.
For the maximum magnitude of acceleration, magnitude of slope is to be maximum. Option b is correct. 
For displacement from t = 0 to t = 7s, velocity is in the same direction. Displacement is maximum at t = 7 s.
Option d is also correct.

After t = 7s, the object rests for 1 s and then comes back (as velocity becomes negative)
9.  (35.00)
Motion of first ball
We have considered that ,
 is the distance covered by the first ball in 4 seconds 

Let 
   be the distance covered by the second ball in 3 second.

 
  

Separation between the two balls

10.  (1.00)
and line cut the parabola

and

Area

Here, the area is symmetric about the y-axis, we can find the area on one side and then multiply it by 2 , we
will get the area,

This area is between and the positive x-axis.

To get the area of the shaded region, we have to subtract this area from the area of square i.e.

Total Area square units.

As per question, p = 4 and q = 3. Therefore, p – q = 1.

11.  (6.00)

12.  (2.25)

( for angle of projection )

  (here, x = a, R = a + b,  = = 45o )

13.  (5)

For relative motion perpendicular to line of motion of A

14.  (8.65)
Here

15.  (C)
Comparing with the standard equation of projectile,

We get, and

Time period of this projectile is 4s. Hence after 4s velocity vector will again make 45o with horizontal

16.  (B)
(a) → (r), (s); (b) → (p); (c) → (q); (d) → (p)

17.  (A)
(a) → (r), (s); (b) → (r), (s); (c) → (p); (d) → (q)

18.  (B)
(a) → (q); (b) → (s); (c) → (r); (d) → (p)

19.  (A)

Adding all the three equations, we get

20.  (D)

Adding all the three equations, we get

21.  (B)

Now, are in A.P

Given,

22.  (C)

Now, are in A.P

Given,

Also, are in G.P

23.  (2.00)
Let the two distinct real positive numbers be a and b.
Then x =

Also a, y, z, b are in GP
If r is the common ration of the GP, then b =ar3 → r =

So,
24.  (40.00)

For A.M. to be natural number, n must be even

For G.M. to be natural number, n = 4k2

is the only solution

Hence,

25.  (2.00)

26.  (10.00)

Comparing, and , so .

27.  (2.00)

and

and

, which also satisfies

28.  (109.00)
The given sequence is , , , ….

The 1st group starts with the number .

The 2nd group starts with the number .

The 3rd group starts with the number .

The 4th group starts with the number .

So, the 11th group

starts with the number .

Thus, the required number is 109.

29.  (A,B)
Using , we have the following.

30.  (A,B,C,D)
Clearly, term of the given series is negative or positive accordingly as is even or odd, respectively.

Case I: When is even: In this case, the given series is

Case II: When is odd: In this case, the given series is

Also,
[Using (i)]

[Using (ii)]

31.  (A,C)

rth term,

And

32.  (A,B,C,D)
Let . Then,

From (1) and (2), we get

33.  (A,D)

34.  (A,D)

Let

35.  (A,B,C)

Similarly,

And

Now,

Thus,

36.  (C,D)

37.  (B,D)
Dichromate is not self indicator

38.  (A,B)

39.  (A,B,D)

Hence, I– is oxidised to I2
Coefficient of HSO4– = 6
and H2O is one of the products.

40.  (A,C,D)
(a) When Br2 is reduced to Br– total electrons gained per mole of Br2 is 2, i.e., n-factor = 2. Thus, equivalent
weight =

(b) When Br2 is oxidised to BrO3–, total electrons lost per mole of Br2 is 10, i.e., n-factor = 10. Thus,
equivalent weight =
(c) Net n-factor .

Thus, equivalent weight =

(d) Since Br2 is getting oxidised as well as reduced, the given reaction is disproportionation.
41.  (A,C,D)
For complete reaction, equivalents must be equal.
Equivalents of KMnO4 = 5 10–3

(a) n-factor of FeSO4 = 1

Equivalents of FeSO4 = 1 0.2 25 10–3

=5 10–3

(b) n-factor of H3AsO3 = 2

Equivalents of H3AsO3 = 2 0.1 50 10–3

= 10 10–3

(c) H2O2 2H+ + O2 + 2e–

n-factor of H2O2 = 2
equivalents of H2O2 = 2 0.1 25 10–3

=5 10–3

(d) Sn2+ Sn4+

n-factor of SnCl2 = 2
equivalents of SnCl2 = 2 0.1 25 10–3

=5 10–3

42.  (A)
(c) Dichromate titrations require an external indicator for endpoint detection (Diphenyl amine).
(d) In iodometric titrations, generally KI is used as a reducing agent.

43.  (A,B)
Let the molarities of Na2CO3 and NaHCO3 be M1 and M2 respectively.
With phenolphthalein, end point is obtained when Na2CO3 is half neutralised.
M1 × 0.1 × 1 = 1 × V1 …(1)
With methyl orange, end point is obtained when both Na2CO3 and NaHCO3 are completely neutralised.
M1 × 0.1 × 2 + M2 × 0.1 = 1 × V2 …(2)
Substituting value of (M1 × 0.1) from eq. (1)
2V1 + M2 × 0.1 = V2
M2 = 10 (V2 – 2V1)

44.  (A,B,C)
For complete reaction, the number of equivalents of the reacting species must be equal.
No. of equivalents = n-factor number of moles

For MnO4–, No. of equivalents = 5 0.1 = 0.5

For FeC2O4, No. of equivalents = 3 0.16 = 0.48

For C2O42–, No. of equivalents = 2   0.25 = 0.5

Fe3+ is already in the maximum oxidation state and thus can’t be oxidised further.

45.  (3.00)
The +3 oxidation state of the underlined element is in (b), (g) and (h).
a. +5     b. +3     c. +5     d. +1

e. +8     f. +2      g. +3     h. +3

46.  (216.00)
Number of revolutions made in 1 sec

Thus, number of revolutions made in 1 sec is proportional to

47.  (3.00)

n factor of

meq of salt = meq of KMnO4

10 × 0.1 × 2y = 8 × 0.1 × 5
y =2
again x + 1 = 2y

x = 4-1 = 3

48.  (11.00)

Total n factor = 10 + 1 = 11

49.  (0)
No. of eq. of oxalic acid = No. of eq. of NaOH
or

Molarity of NaOH solution

50.  (2.00)
Let basicity of

Given that:
Wt. of and are same = w gm

Eq. of NaOH = eq. of

mole × n.f.

w = 0.49 g
wt. of

eq. of NaOH = eq. of

51.  (B)
1.8 NA molecules = 1.8 mol of HCl in 500 mL = 1.8 Equiv.,
n-factor for HCl = 1 (only one replaceable H+)
52.  (A)
Molarity

n-factor for

53.  (C)
 A → r; B → s; C →s; D → q, r;
(A) 4.5 m, CaCO3 means
4.5-moles of CaCO3 is present in 1000 g solvent.
mass of solute = 4.5 × 100 = 450 g
mass of solution = 1450 g So, volume of solution = = 1000 ml

Hence molarity = 4.5 M

54.  (A)
 A → r; B → s; C →s; D → q, r;
(D) moles of NaOH in 2 ltr = 4 × 2 = 8 mole
moles of NaOH added = = 1 mole

∴ Molarity = = 4.5 M

mass of NaOH = 9 × 40 = 360 g