Material Safety Data Sheet

BENZOIC ACID

Section 1 - Chemical Product and Company Identification

MSDS Name: BENZOIC ACID
Supplier:
Hubei Phoenix Chemical Company Limited
Address:Room 1101,Wan An International Building,226 Zhong Shan Ave.,Qiao Kou
District,Wuhan,Hubei,China (430030)
For information, call:0086 27 5135 0488 Fax:0086 27 5135 2088
For technical support, call: 0086 27 5135 0488

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent
65-85-0 BENZOIC ACID >99.0%

Emergency Overview：changed by Highly toxic.toluene ;but this goods do not have

hazards .

Section 3 - Hazards Identification

EMERGENCY OVERVIEW
Causes eye irritation; inhalation of dust may irritate the nose and throat; may cause skin
irritation; concentrated dust may be an explosion hazard; may be harmful if swallowed.
White to light tan chips, granules or powder.
Potential Health Effects :
EYES: Irritation.
SKIN: May cause irritation.
NHALATION: May irritate nose and throat.
INGESTION: Maybe harmful.
MEDICAL CONDITIONS AGGRAVATED: None known.
CHRONIC OVEREXPOSURE: Prolonged contact with skin may cause irritation.
ACUTE OVEREXPOSURE: See above.
CARCINOGENICITY: None.
Section 4 - First Aid Measures
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical aid immediately.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing
and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: 574°C (1065.2°F)
Flash Points: CLOSED CUP: 121°C (249.8°F).
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6 - Accidental Release Measures

Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Clean
up spills immediately, observing precautions in the Protective Equipment section. Avoid
generating dusty conditions. Provide ventilation. Cover with soda ash or sodium
bicarbonate and place in a closed container for disposal.

Section 7 - Handling and Storage

Handling: Wash hands before eating, drinking, or smoking or using toilet facilities.
Promptly remove contaminated clothing and wash thoroughly before reuse. Isolate,
vent, drain, wash and purge systems or equipment before maintenance or repair.
Remove all ignition sources. Check atmosphere for explosiveness and oxygen
deficiencies. Use adequate personal protective equipment. Comply with regulations
governing confined space entry.
Storage：Store in a cool, dry, well ventilated area away from sources of heat and
incompatible substances. Keep container tightly closed when not in use.
Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin.
Avoid inhaling dust.

Section 8 - Exposure Controls, Personal Protection

ENGINEERING CONTROLS: Use appropriate engineering control such as process
enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Where such systems are not effective wear
suitable personal protective equipment, which performs satisfactorily and meets OSHA
or other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
RESPIRATORY PROTECTION: A NIOSH approved air-purifying respirator with an
appropriate cartridge or canister may be permissible under certain circumstances
where airborne concentrations are expected to exceed exposure limits. Protection
provided by air purifying respirators is limited to airborne concentrations that are
typically within 10 times the exposure limit. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air-purifying respirators may not provide
adequate protection. A respiratory protection program that meets OSHAs 29 CFR
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirators use.
SKIN AND HAND PROTECTION: Wear suitable protective clothing to prevent contact
with skin.
EYE AND FACE PROTECTION: Wear appropriate protective glasses or splash
goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation,
or the European standard EN 166.
OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.

Section 9 - Physical and Chemical Properties

Physical State/Appearance: Solid

Color: White
Vapor Pressure: 1.3 mbar @ 96°C (204.8°F)
Vapor Density: 4.21
Flash Point: 121 °C (249.8°F)
Auto Ignition Temperature: 299°C (570.2°F)
Boiling Point: 249°C (480.2°F)
Melting Point: 122-123°C (251.6-253.4°F)
n-Octanol/water partition 1.87
Solubility in Water:
coefficient: 2.91 g/L @ 20°C (68°F)
Density: 1.316 (Ref:Sax)
Molecular Formula: C7H6O2
Molecular Weight: 122.12

Section 10 - Stability and Reactivity

Incompatibilities with Other Materials: Strong reducing agents. Bases.
Possible Decomposition Product: Carbon monoxide.

Section 11 - Toxicological Information

RTECS Number: DG0875000
Eye Effect:
Eye - rabbit: 100 mg; Severe irritation. (RTECS)
Skin - rabbit LD50: >1 0 gm/kg (RTECS).
Skin - Human TDLo: 6 mg/kg [Lungs, Thorax, or Respiration - dyspnea Skin and
Appendages - dermatitis, allergic (after systemic exposure)] (RTECS)
Inhalation Effects:
Oral - rat LD50: 1700 mg/kg (RTECS);
Oral - mouse LD50: 1940 mg/kg [Behavioral - somnolence (general depressed activity)
Lungs, Thorax, or Respiration - respiratory depression Gastrointestinal - other changes]
(RTECS);
Oral - rabbit LDLo: 2 gm/kg (RTECS);
Oral - guinea pig LDLo: 2 gm/kg (RTECS);
Oral - man LDLo: 500 mg/kg (RTECS)
Inhalation Effects: Inhalation - rat LC50: >26 mg/m3/1H [Sense Organs and
Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed
activity)]
(RTECS)
Chronic Inhalation Effects: Inhalation - rat TCLo: 1200 mg/m3/4W-I Lungs,
Thorax, or Respiration - fibrosis (interstitial) Related to Chronic Data - death (RTECS)
Mutagenicity: Human mutation data reported. (RTECS).
Other Toxicological Information:
Intraperitoneal - rat LD50: 1600 mg/kg;
Intraperitoneal- mouse LD50: 1460 mg/kg;
Intraperitoneal- guinea pig LDLo: 1400 mg/kg;
Intravenous - ratLD50:1700 mg/kg;
Subcutaneous - rabbit LDLo: 2 gm/kg

Section 12 - Ecological Information

Ecotoxicity: LC50 Gambusis affinis 180mg/l/96H.
Bioaccumulation: Bioaccumulation is observed to be high in invertebrates and low
in vertebrates. BCF Daphnia 1800. BCF Leuciscus idus <1 0.
Biodegredation: Completely biodegraded within 24 hours by adapted activated
sludge. Vapors are photodegradable in the atmosphere, half-life(estimated) 2 days.
Environmental: No information available.

Section 13 - Disposal Considerations

Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for
the classifications of hazardous waste prior to disposal. Furthermore, consult with your
state and local waste requirements or guidelines, if applicable, to ensure compliance.
Arrange disposal in accordance to the EPA and/or state and local guidelines, by a
licensed disposal company.
DOT Hazard Class: No data.

Section 14 - Transport Information

DOT Identification Number: No data
Suitable to be carried via IATA.

Section 15 - Regulatory Information

TSCA 8(b): Inventory Status: Listed on the TSCA inventory.
TSCA 12(b): Export Notification SARA: None of the chemicals are listed under
TSCA Section 12b. CAS # 65-85-0: acute.
Section 302 Extremely Hazardous Substances (RQ): CAS# 65-85-0: final RQ =
5000 pounds (2270 kg)
Section 116.4 part 117: Clean Water Act CAS# 65-85-0 is listed as a
Hazardous Substance under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are listed as
Toxic Pollutants under the CWA.
State: Benzoic acid can be found on the following state right to know lists: California,
New Jersey, Florida, Pennsylvania, Massachusetts. California No Significant Risk Level:
None of the chemicals in this product are listed.
Risk Phrases: R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrase: R36/37/38 Irritating to eyes, respiratory system and skin.
S22 Do not breathe dust.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

Section 16 - Additional Information

Disclaimer:
The information above is believed to be accurate and represents the best information
currently available to us. However, we make no warranty of merchantability or any other
warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event Hubei Phoenix
Chemical Company Limited be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Hubei Phoenix Chemical Company Limited has
been advised of the possibility of such damages.