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21/04/2023 Code-B

Paper-2
Phase-III

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Time : 3 Hrs MM :180


FINAL TEST SERIES
for JEE (Advanced)-2023
Test – 2A (Paper - 2)_Actual Pattern-2021

Topics covered:
Physics : Mock Test on Complete Syllabus
Chemistry : Mock Test on Complete Syllabus
Mathematics : Mock Test on Complete Syllabus

General Instructions:
1. Read each question carefully.
2. It is mandatory to use blue/black ballpoint pen to darken the appropriate circle in the answer sheet.
3. Mark should be dark and should completely fill the circle.
4. Rough work must not be done on the answer sheet.
5. Do not use white-fluid or any other rubbing material on answer sheet.
6. Student cannot use log table and calculator or any other material in the examination hall.
7. Before attempting the question paper, student should ensure that the test paper contains all pages
and no page is missing.
8. Before handing over the answer sheet to the invigilator, candidate should check that Roll No., Centre
Code and Date of Birth have been filled and marked correctly.
9. Immediately after the prescribed examination time is over, the answer sheet is to be returned to the
invigilator.
10. Pattern of the questions are as under:
(i) The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has 4
sections.
(ii) Section-1: This section contains 6 multiple choice questions which have one or more correct
answer(s). Each question carries +4 marks for correct answer and –2 marks for wrong answer.
Partial +1 mark is given for darkening a bubble corresponding to each correct option,
Provided no incorrect option is darkened
(iii) Section-2: This section contains 3 questions stems. There are TWO (02) questions
corresponding to each question stem. The answer to each question is a NUMERICAL VALUE.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places. Each question carries +2 marks for correct answer and there is no negative
marking.
(iv) Section-3 : This section contains TWO (02) paragraphs. Based on each paragraph, there are
TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of
these four options is the correct answer. Each question carries +3 marks for correct answer and
–1 mark for wrong answer.
(V) Section-4: This section contains THREE (03) questions. The answer to each question is a
NON-NEGATIVE INTEGER. Each question carries +4 marks for correct answer and there is
no negative marking.

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Test-2A_Paper-2_(Code-B)_Phase-III FINAL TEST SERIES for JEE (Advanced)-2023

PART-I: PHYSICS
SECTION-1

One or More Options Correct Type


This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct.

1. A particle of mass 1 kg is subjected to a force which depends on position coordinate (x, y) as


 2y 2
F iˆ  4 y ln  x  jˆ . The speed of particle at (4, 10) is 24 m/s. The x = 1 line is equipotential line
x
having potential of 1 J/kg. At point (x, y), x and y are position coordinate (in m) in the path of particle.
(Use ln2 = 0.7)
(A) Potential energy varies with position coordinate (x, y) as U = 1 – 2y2 lnx
(B) Potential energy varies with position coordinate (x, y) as U = 1 + 2y2 lnx
(C) Mechanical energy at any point is 18 J
(D) Mechanical energy at any point is 9 J
2. In the given diagram, the circular wire circumscribe the equilateral triangular wire with side length l as
shown in figure. The line of input and output current (i0) seems to pass through the centre P. If resistance
per unit length of each wire is .(P is the centre of circle)

(A) The magnetic field at point P due to circular arc is zero


(B) The net magnetic field at point P due to all three sides of equilateral triangle is zero

 is 3 0 i 0
(C) The magnetic field at point P due to outer current carrying wire BAC
2 l

20 i 0
(D) Magnetic field at point P due to straight wire BC is
3 3  2 l 
     
3. A physical quantity is defined as F  v  Kx , where F, v and x are force, velocity and position vector


respectively, which of the following options has/have same dimension as of   ?
K 

Momentum
(A)
Force

Force
(B)
Momentum

Charge
(C)
Current × Resistance

Mass
(D)
Spring Constant

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m
4. In the given diagram, mass m is attached with other mass . The block of mass m is also attached with
2
ceiling at A with rope and with pulley Q with the help of a spring.

The spring has spring constant K, then at equilibrium [springs and pulleys used are ideal, PB is vertical]
3  mg   mg 
(A) Extension in spring is (B) Extension in spring is 
4  K  
 4K 
 3mg  mg 44 3
(C) Tension in string AB is 
 4  (D) Net force on pulley Q is 
  2 16 2

5. In a YDSE arrangement (, d, D), the maximum intensity is I0 and central maxima is at y = 0
D I D I
(A) Intensity at y  is 0 (B) Intensity at y  is 0
4d 2 3d 4
3 D I 5 D I
(C) Intensity at y  is 0 (D) Intensity at y  is 0
4d 2 2d 2
6. In a given circuit initially charge on the capacitor is Q0. At t = 0 the switch S is closed, which of the
following statement(s) is/are correct?

(A) Charge on the capacitor reduces from Q0 to saturation charge Q (not equal to zero) after long time
(B) Resistance R works as damper in the circuit
(C) Just after switch S is closed the current is zero
(D) Current in the circuit will follow equation I = I0 sin(t), where I0 and  are some constants

SECTION - 2

Numerical Value Type

This section contains 3 questions stems. There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE. If the numerical value has more than two decimal
places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 7 and 8

A water jet in the form of cylinder (with essentially flat ends) of length  = 9 cm and radius = 1 cm moves with

velocity v in gravity free space. Water jet minimizes its energy and splits into two equal drops of radius R. Both
drops are moving with speed v0 in same direction and are separated by distance d and loss in total energy is
E0. Surface tension, density and specific heat capacity of liquid is 0.4 J/cm2, 0.9 gm/cm3 and 10 J/gmºC
respectively (d is the distance between center of two drops)

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7. Find the numerical value of E0d (in Joule-cm).


X
8. Increase temperature of drops due to loss in energy is   ºC, find X .
 81
Question Stem for Question Nos. 9 and 10
A small rigid ball of mass m = 1 kg and speed v0 = 4 m/s, strikes a dumbell (two rigid equal mass m are joined
by a light rod of length 1 m) placed on a smooth plane surface as shown in figure. Ball is moving in the plane
of dumbell. The ball sticks to dumbell ball which is to be treated as particle.  is the angular velocity of
dumbell about centre of dumbell and heat energy produced in this process is H (in Joules), then (consider loss
in energy leads to heat generation)

9. Find  (in rad/sec).


10. Find H.
Question Stem for Question Nos. 11 and 12

In a certain region, uniform electric field E  –E0 kˆ and magnetic field B  B0 kˆ are present. If the particle is
q 4
projected from origin at t = 0 with velocity of v  v 0 ˆj  v 0 kˆ . If  1, v0 = 2, B0 = 1 and E0  then the
m 
magnitudes of X-component of velocity and Y - component of velocity are vx and vy when speed of particle is
minimum (consider all in SI unit).
11. Find vx.
12. Find vy.

SECTION-3

Paragraph Type
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.

Paragraph for Question Nos. 13 and 14


In the given figure reading of voltmeter V1 = 60 V, V2 = 80 V and V3 = 20 V.

13. The peak current and peak value of E.M.F. is I0A and V0 volt respectively then value of (I0, V0) is


(A) 15 2, 60 2  
(B) 15, 60 2 
(C) 15 2, 120  (D) (15, 20)

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FINAL TEST SERIES for JEE (Advanced)-2023 Test-2A_Paper-2_(Code-B)_Phase-III

14. P, Q, R, S are the points marked in figure, if potential difference between P and R is VPR and between Q
VPR
and S is VQS, then is
VQS

4 8
(A) (B)
3 3

6 5
(C) (D)
7 3

Paragraph for Question Nos. 15 and 16

In the shown figure piston A and B are made thermally insulated but electrically conducting. Piston A and B
are connected with the battery of potential V, which supply charge Q to the piston. All chambers are insulated
and gas between piston A and B has degree of freedom f. Initial separation of piston is d.
If potential of battery is increased so that it increases the charge on the piston by  times the initial value.
(Assume NO heat loss through battery and r for gas = 1)

15. If initial and final temperature of gas is T1 and T2 respectively, then find the distance between two pistons.

T1 T1
(A)  d (B) d
T2 2T2

T2 T2
(C) 2
d (D)  d
 T1 T1

16. If T1 and T2 are the initial and final temperature of gas, then choose the correct option.

T1 T1
(A) If  > 1 then 1 (B) If  < 1 then 1
T2 T2

T1 T1
(C) If  = 1 then 1 (D) If  > 1 then 1
T2 T2

SECTION-4

Non-Negative Integer Type

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

17. Consider the nuclear reaction in which -particle collides with stationary nitrogen nucleus in which

coming -particle has kinetic energy of 4 MeV and outgoing proton going at an angle of 60° from

incoming direction of -particle, has kinetic energy KP = 1.44 MeV. The kinetic energy of O17 is

12.64
MeV. Find x.
x
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Test-2A_Paper-2_(Code-B)_Phase-III FINAL TEST SERIES for JEE (Advanced)-2023

4 + N14  O17 + P1

18. A tube is filled with water and a water outlet tap is attached as shown in figure. Cross-sectional area of

tube and water outlet is 100 cm2 and 1 cm2 respectively. A tuning fork of frequency 1000 Hz is sounded
over resonance tube as shown. Speed of sound in air is 320 m/s.

If tap is opened up at t = 0 then the time between first two resonance is nearly x seconds. Find x, to the

nearest integer. (Use 10  3.2 , 19  4.36 and 23  4.8)

19. A thin uniform rod of mass m, length L is rotating about an axis passing through one end of the rod. At
t = 0 a wave pulse is generated at one end of the rod which is just close to the axis. Angular velocity of

  1
the rod is . The time taken by the wave pulse to reach other end is of the form T    . The value
 A 
 0 

of A0 will be

PART - II: CHEMISTRY

SECTION-1

One or More Options Correct Type


This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct

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FINAL TEST SERIES for JEE (Advanced)-2023 Test-2A_Paper-2_(Code-B)_Phase-III

20. The reaction sequence(s) that would lead to as the major product is/are

(A) (B)

(C) (D)

21. Consider the following sequence of reactions

The correct option(s) for the above sequence of reaction is/are

(A) (B)

(C) (D)

22. For the following reaction


d[C]
3A  B 
K
 C , the rate of reaction is  K[A] . Three moles of A are mixed with one mole of B to
dt
make 1.0 L of solution. At 50 s, 0.75 mole of A is left in the reaction mixture. The correct statement(s)
about the reaction is/are
(A) The rate constant K, of the reaction is 0.009 s–1 (B) Half-life of B is 50 s

d[A] d[B]
(C) At 25 s,  0.020 mol L–1 s–1 (D) At 50 s,  0.007 mol L–1 s–1
dt dt
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Test-2A_Paper-2_(Code-B)_Phase-III FINAL TEST SERIES for JEE (Advanced)-2023

23. Some standard electrode potential at 298 K are given below

EA2 / A  0.27 V

EB2 /B  0.38 V

EC2 /C  0.44 V

ED2 /C  0.48 V

To a solution containing 0.002 M of X2+ and 0.2 M of Y+2, the metal rods X and Y are inserted (at 298 K)
and connected by a conducting wire. This resulted in the dissolution of X. The correct combination of X
and Y, respectively is/are
(A) A and B (B) A and C
(C) B and D (D) D and C
24. The pair(s) of complexes wherein both are diamagnetic is/are
(A) [Fe(CN)6]3– and [Fe(CN)6]4– (B) [Fe(CN)6]4– and [Ni(CN)4]2–
(C) [Ni(CO)4] and [NiCI4]2– (D) [Co(H2O)6]3+ and [CoF6]3–

25. The correct statement(s) related to oxoacids of phosphorous is/are

(A) Upon heating, phosphinic acid does not disproportionate

(B) H4P2O6 has one oxylinkage and two ionizable hydrogens

(C) H4P2O5 has one oxylinkage and two non-ionizable hydrogens

(D) H4P2O7 is a tetrabasic acid

SECTION - 2
Numerical Value Type
This section contains 3 questions stems. There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE. If the numerical value has more than two decimal
places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 26 and 27

At 298 K, the limiting molar conductivity of a weak monobasic acid is 16 × 102 S cm2 mol–1. At 298 K, for an
aqueous solution of the acid, the degree of dissociation is  and molar conductivity is y × 102 S cm2 mol–1. At
298 K, the molar conductivity of a solution becomes 4y × 102 S cm2 mol–1 upon 20 times dilution with water.

26. The value of  is

27. The value of y is

Question Stem for Question Nos. 28 and 29


A sample (2.8 g) containing iron is completely dissolved in cold dil. HCI to prepare a 250 ml of solution.
Titration of 25.0 ml of this solution requires 25 ml of 0.01 M KMnO4 solution to reach the end point. Number of
moles of Fe2+ present in 250 ml solution is x × 10–2 (Consider complete dissolution of FeCI2.) The amount of
iron present in the sample is y% by weight. (Assume KMnO4 reacts only with Fe2+ in solution. Use: molar
mass of iron as 56 g mol–1)
28. The value of x is
29. The value of y is

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FINAL TEST SERIES for JEE (Advanced)-2023 Test-2A_Paper-2_(Code-B)_Phase-III

Question Stem for Question Nos. 30 and 31


Consider the following sequence of reactions
(1) C2H5MgBr Re d P Br2
CH3  C  N 
(2) H O
 P 
(i) NaOBr
(ii) H2 O
 Q 
Soluble in NaHCO3 (aq.)
R
3

x is the number of lone pair of electrons on R and y is the number of chiral carbons in R.
30. The value of x is
31. The value of y is

SECTION - 3

Paragraph Type
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question has
FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.

Paragraph for Question Nos. 32 and 33


Consider the following reaction sequence

32. The structures of compounds ‘P’ and ‘A’ respectively are


(A) (B)

(C) (D)

33. The structures of Q and R, respectively, are

(A)

(B)

(C)

(D)

Paragraph for Question Nos. 34 and 35

Cu2+ ion is treated with K4[Fe(CN)6] and SCN– to give compounds X and Y respectively. Also Cu 2+ is treated
with excess of KCN to give a complex of copper.
34. The colour of compounds X and Y respectively are
(A) Chocolate brown and yellow (B) Chocolate brown and black
(C) Yellow and black (D) Black and chocolate brown

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Test-2A_Paper-2_(Code-B)_Phase-III FINAL TEST SERIES for JEE (Advanced)-2023

35. The coordination number and oxidation state of copper in the complex formed by treatment of excess of
KCN respectively are

(A) 3 and +2 (B) 3 and +1

(C) 4 and +2 (D) 4 and +1

SECTION - 4

Non-Negative Integer Type

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

36. One mole of an ideal gas at 450 K, undergoes two reversible processes I followed by II, as shown below.
V 
If the work done by the gas in the two processes is same, then find the value of In  2  .
 V1 

37. Consider a helium (He) atom that absorbs a photon of wavelength 220 nm. The change in the velocity (in
cm s–1) of He atom after the photon absorption is (Assume: momentum is conserved when photon is
absorbed.)
Use: Planck’s constant = 6.6 × 10–34J.s, Avogadro number = 6 × 1023 mol–1, molar mass of He = 4 g mol–1.
38. When CI2 is treated with HgO at 300ºC a yellow brown gas X is released. The maximum number of
atoms in a plane in gas X is

PART - III: MATHEMATICS

SECTION-1

One or More Options Correct Type


This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct.

x2 y2
39. If P and Q are two points on the ellipse 2
  1, whose eccentric angles differ by 90°, then
a b2
x2 y2
(A) Locus of point of intersection of tangents at P and Q is 2
 2
a b2
x2 y2 1
(B) Locus of mid point of P and Q is 2
 
a b2 2

x2 y2 1
(C) Locus of point of intersection of tangents at P and Q is 2
 
a b2 2

x2 y2
(D) Locus of mid point of P and Q is 2
 2
a b2
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40. Let f : R  R, y = f(x), f(0) = 0, f(x) > 0 and f (x) > 0. If three points A(, f()), B(, f()), C(, f()) lie on
y = f(x) such that 0 <  <  < , then which of the following is/are true?

f (  )  f ( ) 
(A) f() > f() (B) f 
2  2 

f (  )  f ( ) 
(C) f( + – ) > ( +  – ) f() (D) f 
2  2 

 1  1
g  n   g  
 2 2
41. Let g(x) = ef(x) and f(x + 1) = x + f(x) x R. If n  N then –   is always equal to
 1  1
g n   g  
 2 2

 1 1 1  1 1 1 
(A) 2  1    ...   (B) 2  1    ... 
 2 3 n  3 5 2n – 1 

(C) n (D) 1
42. Consider equation z8 + z7 + z6 +…+ z2 + z + 1 = 0 has a non-real root . Then, choose the correct option(s).
8 4
1
(A) i 1
(2 –  i )  511 (B)  Re( )  – 2
i 1
i

 i
–  i 1 4
(C) i 0
4
2 (D)   i 9– i
4

i 0
2i
– 2 i 1 i 1

43. 5 boys and 5 girls sit in a row randomly, then


5!  6!
(A) Probability that 5 girls sit together =
10!
5! · 5!
(B) Probability that boys and girls sit alternately =
10!
1
(C) Probability that all boys are together and all girls are together given all girls are together =
3
(D) Probability that a particular boy and a particular girl sit together given that boys and girls sit
9
alternately =
25
1
44. Let y = f(x) be a differentiable function  x R and satisfy f ( x )  x  x 2 f (t )dt . Then choose correct

0

option(s) related to y = f(x).


1
(A) Minimum value of f(x) is –
3

  4  

(B) cos –1  f  –    cot –1 f  0  will be equal to 
  3  2

 1  3
(C) lim f ( x ) · f  2  
x  x  4

8
(D) Area bounded by curve y = f(x) and x-axis is
27

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Test-2A_Paper-2_(Code-B)_Phase-III FINAL TEST SERIES for JEE (Advanced)-2023

SECTION - 2
Numerical Value Type
This section contains 3 questions stems. There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE. If the numerical value has more than two decimal
places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 45 and 46

Let set A contain all the 3 × 3 matrices whose entries are 0, 1 and –1. Two of these entries are 1, two are –1
and five are 0.

On the basis of above information, answer the following questions.

45. Number of skew-symmetric matrices in set A is

46. Number of symmetric matrices in set A which is non-singular is

Question Stem for Question Nos. 47 and 48


x

 ( x – t  1)f (t )dt  x
4
A differentiable function y = f(x) satisfy  x 2  x  0.
0

On the basis of above information, answer the following questions.


47. If f(0) = 26, then minimum value of f(x) is equal to

48. If f(x) + fx= P(x), then area bounded by y = P–1(x), x-axis and x = 14 is equal to
Question Stem for Question Nos. 49 and 50

2 –1   
 sin  sin x  , 0  x  1
f (x)     2 
 2 2
(a – 1)  ( x – 1) , x 1

49. If x = 1 is point of local maximum of f(x), then sum of all integral values of |a| is
50. Maximum area of the region bounded by curve y = f(x), line y = 1 and x-axis is (given that such a bounded
region exists is)

SECTION – 3

Paragraph Type
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.

Paragraph for Question Nos. 51 and 52

Let f : R  R and g: R  R such that

f(x) = max {|x|, |x – 1|, |x – 2| … |x – 2018|}

g(x) = min {|x|, |x – 1|, |x – 2| … |x – 2018|} then:


2018
51. The value of

0
f ( x )dx is

(A) 1009 (B) (1009)2

(C) 3027 (D) 3(1009)2

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FINAL TEST SERIES for JEE (Advanced)-2023 Test-2A_Paper-2_(Code-B)_Phase-III
2018


0
f ( x )dx
52. The value of 2018
is

0
g ( x )dx

(A) 3027 (B) 1009

(C) 2018 (D) 6054

Paragraph for Question Nos. 53 and 54

Any matrix A = [aij]n×n is said to be symmetric if AT = A aij = aji. Also, trace of matrix A is the sum of elements
of principal diagonal of matrix A.
Let S be the set of all possible symmetric matrices of order 3, formed using four 1’s, three 2’s and two 0’s.
53. Number of elements in set S is
(A) 12 (B) 18
(C) 30 (D) 36
54. Sum of traces of all possible matrices in set S is

(A) 72 (B) 90

(C) 108 (D) 149

SECTION - 4

Non-Negative Integer Type


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

55. If a and b are randomly chosen from the set {1, 2, 3, 4, 5, 6, 7, 8, 9}, then the probability that the
p
expression ax4 + bx3 + (a + 1) x2 + bx + 1 has positive values for x  R is (p and q are co-prime
q
numbers), then q – p is

56. If Pn denotes the product of all the coefficient in the expansion of (1 + x)n and 9!Pn+1 = 109Pn, then n is
equal to (n  N)

57. x3 + 5x2 + px + q = 0 and x3 + 7x2 + px + r = 0, have two roots in common. If their third roots are 1 and 2
respectively, then |1 + 2 | is equal to



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