Document No.

AT-HSSE-P-8-04/V0-2022

QHSE Management Department of Anton

Anton Oilfield Service Group Ltd. Prepared by:
Group

Issued on: August 4, 2022

Hazardous Chemicals Management Procedure Issued by: Li Qinggang

Hazardous Chemicals Management Procedure

1 Aims and objectives
This Procedure is prepared to identify the hazardous chemicals used in the Company, to help
employees know about the precautions and requirements during the handling, storage, transportation,
and use of hazardous chemicals, to provide reliable information about the operation of hazardous
chemicals, and to take effective control of hazards chemicals through the material safety data sheet
(MSDS), container labels, and training.

2 Scope
The Procedure is applicable to the Company and its wholly-owned subsidiaries, and the non-wholly
owned holding companies can use it as a reference. When working in the operating area of Party A, it is
necessary to consult Party A and implement the operation according to the highest standard.
Hazardous chemicals in this Procedure refer to substances listed in the national Catalog of Hazardous
Chemicals. When implementing this Procedure, relevant entities and personnel shall verify that the
items involved shall be indeed within the management scope of the above-mentioned standards and
this Procedure.

3 Terms and definitions

3.1 Hazardous chemicals
It refers to highly toxic chemicals and other chemicals that are toxic, corrosive, explosive, combustible,
and combustion-supporting, and are harmful to humans, facilities, and the environment.
3.2 Static electricity
Substances generate static electricity through physical contact and separation of electrical charges and
the different effects of positive and negative charge formation. When liquids are moved, such as
poured, mixed, pumped, filtered or mixed, static electricity will be generated as they come into contact
with other substances.
3.3 Equipotential bonding
It refers to the process of connecting two or more conductive objects using one conductor to reduce the
potential difference between two conductors. The connection equalizes the electrical potential between
objects.
3.4 Grounding
It refers to the process of connecting one or more conductors to the ground to reduce the potential
difference between an object and the ground. Grounding causes charge to flow into the ground.
3.5 Separated storage
It refers to that in the same room or the same area, different materials shall be separated from each
other by a certain distance, and non-taboo materials shall be stored by a passage to maintain a space.
3.6 Partitioned storage
It refers to the storage way of using partitions or walls to partition it from contraindicated materials in the
same building or in the same area.
3.7 Isolated storage
It refers to the way of storage in different buildings or in exterior zone away from all buildings.
3.8 Prohibited materials

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It refers to chemical materials that have conflicting chemical properties or different fire-fighting methods.

4 Responsibility and authority

4.1 Project leader
a) Ensure that this method is implemented within its management scope.
b) Provide resources and support systems if necessary to ensure that the handling, storage,
transportation and use of hazardous chemicals meet relevant requirements.
c) Be responsible for providing necessary personal protective equipment and training the staff to
use them correctly before carrying hazardous chemicals.
d) Use products with less risk as far as possible in actual work.
e) Provide necessary first aid equipment at the job site.
f) Be responsible for setting up the hazardous chemicals account of the entity.
g) Dispose waste properly.
4.2 Operators
a) Ensure that the job site is well prepared and operated as required.
b) Use personal protective equipment as required when handling hazardous chemicals.
c) Carry out work safely and keep the workplace clean and tidy before and after work.
d) Comply with the requirements for proper disposal of hazardous wastes.
e) When storing and handling flammable and combustible liquids, workers shall carefully read the
material safety data sheet (MSDS) and confirm its chemical properties and hazards.
4.3 QHSE Management Department
a) Be responsible for training, explaining, guiding and supervision over execution of these
measures.
b) Be responsible for the establishment of MSDS files within the entity.

5 Management content
5.1 Qualification management
5.1.1 The entity that produces final products or intermediate products listed in the Catalog of Hazardous
Chemicals shall obtain a permit to work for safety production of hazardous chemicals in accordance
with the Regulations on Safety Management of Hazardous Chemicals and other relevant regulations.
5.1.2 The entity engaged in the business (including storage business) of hazardous chemicals listed in
the Catalog of Hazardous Chemicals shall obtain a permit to work for business in hazardous chemicals
in accordance with the Regulations on Safety Management of Hazardous Chemicals and other relevant
regulations.
5.1.3 The entity that is listed in the applicable industry catalog for the safe use of hazardous chemicals,
uses hazardous chemicals for production and meets the quantitative standards for the use of
hazardous chemicals shall obtain the safe use permit to work of hazardous chemicals in accordance
with the Regulations on Safety Management of Hazardous Chemicals and other relevant regulations.
5.1.4 The entity producing, operating and using hazardous chemicals shall set up safety management
institutions in accordance with relevant regulations such as the Regulations on Safety Management of
Hazardous Chemicals, staffed with professional technical personnel and full-time safety management
personnel that meet the requirements;
5.1.5 The entity that produces, operates and uses hazardous chemicals shall, in accordance with the
Regulations on Safety Management of Hazardous Chemicals and other relevant regulations, conduct
professional technical training for employees and pass the examination.
5.2 Information management of hazardous chemicals
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5.2.1 Hazardous chemical hazard assessment

a) Purchasing, handling and transportation of hazardous chemicals in the production area shall
be combined with activities such as HSE hazard assessment, identification of major
hazard sources of hazardous chemicals and information provided by the MSDS. Hazard
identification and risk assessment shall be carried out for the whole process of storage, use,
disposal and other foreseeable emergencies such as leakage, and the assessment results
shall be applied to determine the risk control measures for specific hazardous chemicals.
When conducting a risk assessment, the following factors shall be considered (including but
not limited to):
 Physical and chemical properties of material;
 Any known hazard/toxic effects;
 The use and handling of on-site materials;
 Any volatilization, emission of hazardous chemicals (product, by-product or waste);
 Likelihood of personnel exposure, including duration of exposure;
 Exposure concentration (any applicable local regulatory standards, company
requirements or industry maximum limits);
 All possible measures needed to reduce exposure.
b) Based on the above information, control measures and precautions must be developed to
ensure that the exposure of personnel conforms to the standards.
5.2.2 Inventory of Hazardous Chemicals
Each entity shall check regularly the inventory of the hazardous chemicals used, grasp the quantity and
status of their storage, cargos moved into and out of warehouse, and establish an Inventory of
Hazardous Chemicals, the format of which is shown in Appendix 1.
5.2.3 Material safety data sheet (MSDS)
5.2.3.1 Basic requirements and guidelines
a) Hazardous chemicals used by companies or contractors must have the MSDS, and any
personnel making new application for hazardous chemicals shall ask the supply department
for MSDS.
b) For each batch of purchased hazardous chemicals, the supply department shall request the
latest hazardous MSDS from the manufacturer or supplier, and this requirement shall be
written into the terms of the purchase contract.
c) The MSDS must be stored with the goods in the place where chemicals are used, and be
easily accessible by employees.
d) The QHSE management department shall urge each entity to establish complete MSDS.
e) Employees or contractors who may be exposed to hazardous chemicals shall take the
initiative to obtain and read the MSDS from the user.
f) The contractor must establish an MSDS for the hazardous chemicals provide by him, and
ensure that it complies with relevant national specifications.
g) A key part of hazardous chemical information is to ensure that employees can use and
understand MSDS to obtain relevant safety and health information, and staff shall receive
relevant training and know how to use MSDS, the person in charge of the area shall provide
employees or contractors with copies of the MSDS, and more importantly, formulate and
implement on-site safety measures based on the information on hazardous chemicals.
5.2.3.2 See Appendix 2 for the Content of Material Safety Data Sheet
5.2.3.3 Chemical container labels
a) All the chemicals provided by suppliers and the chemicals produced by companies must be

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properly labeled and attached with MSDS in their packaging containers.

b) Chemical labels (see Appendix 3 for Package Labels of Common Hazardous Chemicals) must
be clearly and prominently marked on the container. Chemical labels provided by
manufacturers, suppliers or distributors must include the following:
 Name: Chemical or generic name in MSDS;
 Danger warning;
 Contact information – The name and address of the manufacturer or supplier for
emergency contact in the event of an incident.
5.2.4 Hazardous chemical response matrix
A reaction matrix of hazardous chemicals shall be formulated according to the reactivity of hazardous
chemicals, the types of on-site chemicals, and the substances that may be touched, so as to determine
the related substances that may have chemical reactions and their reaction phenomena, characteristics
and hazards. In order to prevent and control these hazards, if necessary, isolation and other preventive
measures shall be taken for the storage, handling, transportation, use, leakage disposal and other links
of related substances that may have chemical reactions. For example, strong acid and strong alkali
contact will cause severe reactions, so they shall be stored separately to prevent accidental contact.
Some chemicals will react with metals, and there shall be special regulations for packaging and use of
containers.
5.3 Management of hazardous chemicals
5.3.1 Apply to the relevant local government departments to obtain permission.
5.3.2 The storage regulations for hazardous chemicals shall be observed when storing hazardous
chemicals.
5.3.3 It is not allowed to purchase hazardous chemicals from enterprises engaged in the production and
operation of hazardous chemicals without permission, and shall not operate hazardous chemicals
without technical specifications for chemical safety or chemical safety labels.
5.4 Procurement of hazardous chemicals
5.4.1 When hazardous chemicals need to be used, the user shall put forward the purchase request,
stating their physical and chemical characteristics, toxicity level, use and dosage, etc. After the
purchase process is completed, the supply chain center shall be responsible for the purchase.
5.4.2 When using and purchasing hazardous chemicals, it is required to strictly control the purchasing
quantity according to the actual situation of use. Dangerous chemicals that are forbidden from being
purchased by the state shall not be purchased.
5.4.3 According to the approved procurement plan, the supply chain center shall select entities with
national production and operation qualifications and company access qualifications. When purchasing
hazardous chemicals, the safety labels on the packages (or containers) must be checked. Do not
purchase if the safety labels are detached or damaged.
5.4.4 After the arrival of hazardous chemicals, the planned purchasing entity shall check and accept
according to relevant national standards and product standards.
5.4.5 For the highly toxic chemicals (chemical reagents) needed by the Company' s production and
scientific research entity, the demand plan shall be put forward by the laboratory of the entity first, and
the purchase shall be approved after the process approval.
5.4.6 When preparing the demand plan for highly toxic chemicals (chemical reagents), the user shall
consider the actual needs of the workload, so that the highly toxic chemicals (chemical reagents) can
be used up within the shelf life, and the reagents) beyond the shelf life.
5.5 Storage, handling and use of hazardous chemicals
5.5.1 Basic requirements and guidelines
a) The use of hazardous chemicals shall be minimized, including reducing the variety, amount
and harm or concentration.
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b) All hazardous materials must be identified, classified and labelled in accordance with national
regulations.
c) The Company's supply department must obtain from the supplier and provide the on-site
management personnel with the MSDS of the hazardous chemicals stored and used.
d) According to the characteristics of hazardous chemicals, partition/classification/separate
storage shall be implemented, including separated storage, partitioned storage, and isolated
storage. The stacking shall not be too high, the quantity of storage shall not be excessive, and
the storage shall not be mixed with forbidden materials. Outdoor storage must have facilities
such as rainproof, moisture-proof, lightning protection, and sun protection. The storage of
highly toxic chemicals shall be kept in special counters and managed by two persons and
double locks. Hazardous chemicals must be kept in good condition, and shall be properly
handled when the packaging is damaged, deteriorated, decomposed, reacted, or expired in
storage to prevent injury to personnel and pollution to the environment.
(e) Storage, handling, and use of hazardous chemicals shall meet the requirements of safety and
fire-fighting; passages, entrances, and exits shall be kept open; electricity consumption shall
be in line with the norms; fire-fighting equipment shall be fully equipped; and various warning
signs shall be visible. When necessary, facilities such as isolation, ventilation, temperature and
humidity control, explosion-proof, gas leak detection, water spraying (confirm the water source
before loading and unloading operations) shall be equipped according to the characteristics
and storage requirements of hazardous chemicals, and regular inspection/testing/maintenance
shall be carried out as required.
f) Hazardous chemicals management entities shall establish an entry and exit ledger for
hazardous chemicals, establish and improve systems such as fire prevention, theft prevention,
and patrol duty, and regularly check to ensure that the accounts are consistent.
g) Personnel exposed to hazardous chemicals shall have received training and assessment of
relevant knowledge of hazardous chemicals and emergency response capabilities, and shall
be certified to work.
h) For containers of recycled hazardous chemicals:
 Correctly refill the same hazardous chemicals;
 Strictly clean and label before use for other substances;
 If it is not recovered or disposed of in time, clean the container and label the container
"Empty", and properly dispose of the residual liquid and waste water.
i) For hazardous chemicals that are flammable or may cause pollution, leak prevention devices
must be provided during storage and handling.
j) Employees are prohibited from bringing any hazardous chemicals for production into the living
area without approval.
5.5.2 Hygiene
All employees (personnel who are exposed to hazardous chemicals) shall develop the habit of washing
their faces and hands frequently, especially before smoking and eating, to prevent ingestion, irritation of
the skin or inhalation of toxic and harmful substances. Do not use organic solvents to wash the skin, to
avoid irritating the skin, or degreasing the skin.
5.5.3 Personal protective equipment
In order to protect the eyes, face and skin etc. from injury, the following measures can be taken:
ventilate to remove toxic or allergic vapors, avoid being injured by splashes and flying objects while
handling hazardous chemicals, follow the DSDS required to wear protective equipment such as
protective clothing, goggles and face shield.
5.5.4 Flammability and flammable liquid storage requirements
 Flammable or combustible liquid must be stored in tanks, barrels or movable tanks.
 Bottles or tanks containing flammable or combustible liquid must be marked with the chemical
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name and warning signs.

 All flammable or combustible liquid storage tanks shall be stored in storage cabinets or
storage rooms.
 The storage cabinets shall be marked with conspicuous signs "Flammable - No Ignition".
5.5.4.1 Tanks and drums are usually used for movable storage
a) Portable liquid storage shall be installed in storage tanks or indoor storage rooms. Tanks
found to be leaking must be moved to a safe area and contents transferred to undamaged
tanks.
b) Containers with a volume of more than 114 liters shall not be stacked on top of each other.
The transfer of liquids between containers requires the use of an approved pump.
5.3.4.2 Stored in buildings
a) It is prohibited to store flammable or combustible liquid in buildings such as offices,
apartments, etc., except when required for the maintenance and operation of the building or
equipment.
b) The storage of flammable or combustible liquid cannot interfere with exits, stairs or other
safety exits. Stacked containers shall be separated by spacer to ensure stability and prevent
crushing.
5.5.4.3 Stored outside buildings
a) When flammable or combustible liquid are stored close to the building, it shall be at least 3 m
away from the building.
b) There shall be no wood, garbage or other unnecessary combustible materials in the outdoor
storage area.
c) Class I flammable liquids must be stored in sealed containers, above-ground storage tanks, or
existing underground storage tanks. Class II and Class III flammable liquids must be stored in
containers, tanks in buildings, above ground tanks or underground tanks.
5.5.5 Handling requirements for flammable and combustible liquid
a) For requirements on personal protective equipment, see the MSDS.
b) Flammable liquid must be stored in airtight containers when not in use.
c) The minimum amount of flammable liquids required for the work shall be stored at the work
site to reduce fire hazards.
d) It is forbidden to use flammable liquids for cleaning without the permission of the person in
charge of the area.
e) When there is an open flame or source of ignition within 30 meters, flammable liquids cannot
be used.
f) When transferring flammable liquids into containers, both the nozzle and the container need to
be well grounded. This can be done in the following ways:
 Place the container on the metal floor while connecting the spout or line to the container
or floor.
 Equipotentially connect the container to be filled with the liquid to the filling system using
grounding cables.
g) Plastic containers shall not be used to collect, store or transport flammable liquids (e.g.,
sampling) unless the liquid will react with metal containers.
h) Waste flammable or combustible liquid cannot be poured directly into the sewer, and shall be
collected and disposed of safely.
i) In areas where flammable or combustible liquid is moved or operated, there shall be adequate
firefighting facilities.
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j) Leaks of flammable or combustible liquid need to be cleaned up immediately to prevent the

generation of volatile gases and fire sources. In the event of a leak, eliminate all sources of
ignition and turn off all electrical equipment (remotely if possible).
5.5.6 Oxidizing articles
a) Oxidizing materials shall not be transported or stored near combustible materials, which can
reduce fires caused by mixing, friction or influence.
b) Oxidants cannot be transported or stored near the acid to avoid violent explosions or the
release of toxic gases.
5.3.7 Poison
a) If there is a possibility of inhalation of toxic or irritating gases, vapor or dust, appropriate
ventilation or respiratory protection equipment shall be used.
b) Toxic substances cannot be transported or stored near the fire source to reduce the risk of fire
and the risk of toxic gas release due to decomposition.
5.5.8 Corrosive substances
a) When handling acid or other corrosive substances, select and use appropriate personal
protective equipment according to the requirements of the MSDS, and ensure that there is
sufficient water source at the use site.
b) When concentrated acid or alkali are used or heated, dense mists may be released and cause
serious hazards. Therefore, site ventilation or appropriate respirators shall be used.
c) When mixing concentrated acid and water, the acid must be poured into the water slowly, and
the water must not be poured into the acid.
5.5.9 Hazardous wastes
a) Different hazardous wastes must be separated and cannot be mixed to prevent the wastes
from producing hazardous reactions and releasing harmful gases.
b) Waste shall be loaded in appropriate containers, preferably in their original containers.
c) If drums are used, ensure that the waste does not react with the original product.
d) Containers containing hazardous waste need to be labelled in accordance with the standard.
e) Containers containing hazardous waste need to be properly sealed.
f) Ensure that hazardous waste is dumped to a licensed location, or entrust a qualified contractor
to dispose of the waste in a harmless manner.
5.5.10 Samples containing hazardous chemicals
a) Each container must be marked with the product name and related precautions, even if the
contents of the container are known to be non-hazardous.
b) Laboratory samples without MSDS shall be labeled with the following:
 Type of sample (name of hazardous chemical);
 Contains known hazardous chemicals;
 Sample number;
 Date:
 Place;
 Contact number;
 The signature of the person collecting the sample.
5.5.11 Emergency procedures
a) All employees shall know the location of emergency shower facilities and first aid tools in the

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operating area, and soda water and acid-proof labor insurance shall be provided for acid-
related operations.
b) If liquid or vapor enters the eyes, immediately rinse with water for at least 15 minutes; If acid
gets into eyes, rinse with soda water for at least 15 minutes.
c) If skin is burned by contaminants, rinse immediately with water and remove clothing to rinse
affected area.
d) Any skin erythema or irritation caused by exposure to hazardous chemicals shall seek
immediate medical attention.
e) Skin irritation may be due to exposure to chemicals or vapor, if this occurs, area managers
and safety personnel must be notified as soon as possible.
f) Area managers and safety personnel must be notified as soon as possible of any chemical
exposure.
g) In the event of leakage of hazardous chemicals, emergency personnel on site shall
immediately wear protective clothing and necessary monitoring and measuring instruments to
cut off the source of leakage; If unsuccessful, emergency personnel shall be organized to
repair the cofferdam and other measures shall be taken; If the cofferdam cannot be repaired
urgently, all personnel shall be evacuated immediately, relevant monitoring work shall be done
well, and reports shall be made to relevant departments or entities according to the accident
reporting procedure.
h) Any spilled chemicals must be cleaned up as soon as possible. If possible, immediately scrub
the spill area with water and a rag (do not flush liquids that do not mix well with water or
chemicals that may react with water to produce toxic gases), or use an appropriate neutralizer.
i) Do not scrub the leaked chemicals with hands and clothes, and do not do cleaning without
wearing protective equipment. Some chemicals may be highly corrosive, or cause severe
burns due to spontaneous combustion. In this case, only corresponding absorbing materials
shall be used.
j) Avoid inhalation of toxic gases from leaked chemicals. Respirators must be worn in the event
of a large-scale spill, and it shall be handled by professionals as much as possible.
k) Personnel training. Staff shall be trained and regularly drilled on emergency plans, personal
protective equipment, and emergency disposal methods, and records of training and drills
shall be made.
5.5.12 The person in charge of the area and the employees involved in the operation of hazardous
chemicals shall regularly read the regulations.
a) Before using new chemicals, read the safety technical specifications of hazardous chemicals
and relevant management and operation procedure.
b) The members designated as hazardous chemicals emergency response team shall receive
relevant training on a regular basis according to the requirements of on-site emergency
response procedures.
5.6 Transport and handling of hazardous chemicals
5.6.1 Only qualified and approved contractors can transport hazardous chemicals. During the
transportation of hazardous chemicals, the contractor must provide:
 The "Dangerous Goods Transport Permit" issued and valid by the competent government
department, and the person in charge of escorting shall have the "Transportation Permit";
 Qualified drivers, with extensive knowledge of handling hazardous chemicals;
 Motor vehicles in good safety condition must be equipped with fire extinguishing equipment
and anti-spill facilities.
5.6.2 Personnel engaged in the transportation and handling of hazardous chemicals must receive
training to understand the physical and chemical properties of hazardous chemicals and the emergency

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measures to be taken when danger occurs.

5.6.3 As far as transportation, loading and unloading facilities and places of hazardous chemicals are
concerned, safety protection facilities meeting standard shall be set up according to characteristics of
hazardous chemicals, such as lightning protection and electrostatic grounding facilities, and regular
check, test and maintenance shall be conducted to ensure their good condition.
5.6.4 Warning and isolation facilities shall be set up in the hazardous chemical loading and unloading
operation area, and irrelevant personnel are not allowed to enter the loading and unloading operation
area.
5.6.5 The loading and unloading of hazardous chemicals shall be carried out under the command of on-
site management personnel, who shall wear corresponding protective equipment according to the
characteristics of hazardous chemicals.
5.6.6 Before handling, the containers, packages and labels of hazardous chemicals shall be carefully
checked; In the process of handling, ensure that the containers and packages are in good condition,
load and unload gently, and it is strictly prohibited to drop, drag, weigh and rub. When loading and
unloading liquid chemicals, the flow rate shall be controlled, and the injection pipe must be as close to
the bottom of the tank as possible. Forbid overload and overbalance.
5.6.7 During the loading and unloading of hazardous chemicals, drivers, escorts and loading and
unloading personnel shall not leave the site, and the vehicles shall be turned off.
5.6.8 When loading and unloading flammable and explosive hazardous chemicals:
 It is forbidden for personnel to carry fire and engage in hot work;
 Turn off communication tools and electronic devices such as mobile phones;
 Smoking is strictly prohibited;
 Wear anti-static work clothes and work shoes without nails, and discharge static electricity
before entering the loading and unloading area;
 The vehicle shall adopt equipotential connection method for electrostatic grounding, where the
grounding cables, clamps, grounding piles, etc. shall remain intact, and the resistance shall be
less than 4 ohms. When loading and unloading in thunderstorm weather, it shall be confirmed
that lightning protection and moisture-proof measures are effective;
 It is forbidden to load and unload flammable and explosive hazardous chemicals by using
forklifts, scrapers, dump trucks, bicycles, etc.
5.6.9 All transport vehicles for transporting hazardous chemicals and their waste into/out of the site of
the operation shall be inspected, including but not limited to:
 Provide the necessary waybill or manifest;
 Licenses of contractors and drivers;
 Material safety data sheet (MSDS) and labels;
 Fire extinguishing equipment and anti-spill equipment;
 Motor vehicle and packaging container condition.

6 Reference documents
Regulations on Safety Management of Hazardous Chemicals (State Council Order No. 591)

7 Appendix
Appendix 1: Inventory of Hazardous Chemicals (HSSE-R-8-04.01)
Appendix 2: Contents of Material Safety Data Sheet
Appendix 3: Package Labels of Common Hazardous Chemicals

8 Version management
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Approved
Version Date Description (of change) Prepared by: Reviewed by:
by:
Zhao
V0 2022/8/4 New Zhang Liangfu Pengfeng Li Qinggang
Han Chunyu

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Appendix 1：
Inventory of Hazardous Chemicals
No.: HSSE-R-8-04.01

Job site location: ___________ Preparatory staff:

Material Safety Data Sheet

Maximum
Chemical Storage Current
Category safe Date of Leader
name area stock Number
storage establishment

Note: This list shall be updated monthly, and the specific operations are the responsibility of the person
in charge of each job site.
a) Chemical name: refers to the commercial name or main ingredient name used to identify the
chemical.
b) Category: according to the definition in Classification and Labels of Dangerous Chemical
Substances Commonly Used (GB13690), chemicals shall be mainly divided into eight categories
according to their dangerousness:
Explosive Compressed air and liquefied air
Flammable liquid flammable materials, Self-igniting materials, flammability of materials
due to wetting
Oxidants Toxic
Radioactive Corrosive
c) Storage area: indicates locations typically used to store chemicals.
d) Maximum safe storage amount: the maximum amount of a specified chemical that can be stored
on a facility.
e) Usual inventory: the usual amount of a given chemical held on the facility.
f) Person in charge: refers to the relevant personnel who use and manage these chemicals.

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Appendix 2：
Contents of Material Safety Data Sheet
According to the requirements of the General Rules for Preparation of Chemical Safety Data Sheet
(GB16483), the material safety data sheet shall include contents of the following 16 aspects:
a) Manufacturer name: list the manufacturer's company name, address and emergency contact
number.
b) Product Information: include product name, chemical category, hazard registration, and possible
designated shipping requirements or NFPA toxicity, flammability, and reactivity ratings.
c) Hazard description: indicate product hazard components and applicable exposure limits; and may
indicate the composition percentage of each ingredient (make sure not to contain commercial
ingredient).
d) First aid measures: indicate the first aid measures after skin contact, eye entry, inhalation and
ingestion of hazardous chemicals.
e) Fire-fighting measures: state the methods of extinguishing fire and relevant hazards, including
information on fire extinguishers and personal protective equipment that firefighters shall use.
f) Leakage emergency procedures: give treatment and cleaning precautions, and decontamination
requirements for personal protective equipment.
g) Operation, handling and storage: show the precautions for handling and storage.
h) Exposure controls and personal protective equipment: include information about the allowable
exposure concentrations, monitoring methods, engineering controls, respiratory protection, eye
protection, body and hand protection.
i) Physical and chemical properties: list the data, including boiling point, vapor concentration and PH
value. It may also include melting point, vapor pressure, water solubility, appearance/odor, and
evaporation rate. This information pertains to related clean-up, personal protective equipment and
product spill detection.
j) Reactivity: indicate the chemical reactivity of a substance when it comes into contact with other
items, which are important for its storage, spill cleanup and disposal (such as oxidants and fuel
gases).
k) Toxicity: include chronic toxicity, acute toxicity, and the possibility of carcinogenicity.
l) Biochemical data: give biotoxicity, biochemical and non-biochemical degradation and other
biochemical information.
m) Waste disposal: include information about waste characteristics, disposal methods and
precautions.
n) Shipping Information: include the labeling, classification, material requirements of the packaging,
and requirements during transport according to local legislation and international conventions.
o) Regulatory information: include local and international regulatory requirements and practices.
p) Other information: give the references, time and department that established this document, as
well as the approval authority and supplementary information.

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Appendix 3:
Package Labels of Common Hazardous Chemicals

Packing mark 4
Packing mark 1 Packing mark 2 Packing mark 3
Sign of explosives
Sign of explosives Sign of explosives Sign of explosives
(Symbol: black;
(Symbol: black; (Symbol: black; (Symbol: black; background color:
background color: background color: background color: orange-red)
orange-red) orange-red) orange-red)

Packing mark 5 Packing mark 6 Packing mark 8

Packing mark 7
Flammable gas sign Non-flammable and non- Flammable liquid sign
Toxic gas sign
toxic gas sign
(Symbol: black or white; (Symbol: black or white;
(Symbol: black; background color: true
background color: true (Symbol: black or white;
background color: white) red)
red) background color: green)

Packing mark 9 Packing mark 10 Packing mark 11 Packing mark 12

Flammable solid sign Mark of materials prone Mark of substances that Oxidizing substance sign
to spontaneously emit flammable gases in
(Symbol: black; combustion contact with water (Symbol: black;
background color: white (symbol: black or white; background color: lemon
with red bar) (Symbol: black; yellow)
background color: blue)
background color: top
white and bottom red)

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 Packing mark 16
Packing mark 13
Packing mark 14 Packing mark 15
Level I radioactive
Mark of organic peroxide
Toxic substance sign Infectious substance sign material sign
(Symbols: black or white;
(Symbol: black; (Symbol: black; (Symbol: black;
base colors: red and
background color: white) background color: white) background: white, with
lemon yellow)
a red vertical line)

Packing mark 17 Packing mark 20

Packing mark 18
Level 2 radioactive Packing mark 19 Mark of miscellaneous
Level 3 radioactive hazardous substances
material sign material sign Corrosive substance sign
and articles
(Symbol: black; (Symbol: black; (Symbol: black;
background color: top background color: top (Symbol: black;
background color: top background color: white)
yellow and lower white, yellow and bottom white, white and bottom black)
with two red vertical lines) with three red vertical
lines)

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