ISO-PROPYL

ALCOHOL

Basis
1 hr operation Molecular Weight
30 metric ton/day Isopropyl alcohol 60.1
1250 kg/hr Isopropyl ether 102.18
20.799 kmol/hr Water 18
propane 44.1
Propylene Reqired 20.799 kmol/hr propylene 42.08
Air 29
Reaction
C3H6 + H 2O ⇌ C₃H₈O
Mole balance between IPA & Propylene
1 : 1 : 1
20.80 : 20.8 : 20.80
Ratio
propylene : water
1 : 2.5
Propylene converted into IPA 20.80 kgmol/hr
IPA converted into IPE & water 0.416 kgmol/hr

conversion 0.6
Reaction
2C₃H₈O → C6H14O H 2O
2 : 1 1
1 : 0.5 0.5
0.416 : 0.208 0.208
0.208kgmol/hr 0.208kgmol/hr

Conversion 0.6
propylene to IPA 34.665 kgmol/hr
Total Propylene 35.081 kgmol/hr
1476.208 kg/hr
Feed
Propylene 0.95
Propane 0.05
Propylene Feed 1553.903 kg/hr
Propane 77.695 kg/hr
Water
Water in feed 53.0375 kgmol/hr
954.674 kg/hr
Product

propylene un-reacted 13.866 kgmol/hr

583.4813 kg/hr
Water un reacted 32.029 kgmol/hr
576.530 kg/hr
IPA produced 20.799 kgmol/hr
1250 kg/hr
Isopropyl ether 0.208 kgmol/hr
21.253 kg/hr
propane 77.695 kg/hr
3426.356 kmol/hr
Total 2508.96 kg/hr

REACTOR

stream1 36.84
Input Quantity (kmol/hr) Quantity(kg/hr) Mole fraction
Propylene 35.08 1476.21 0.390
Water 53.04 954.67 0.590
Propane 1.76 77.7 0.02
Total 89.88 2508.58 1.000

Output Quantity (kmol/hr) Quantity(kg/hr) Mole fraction

Isopropyl alcohol 20.799 1250 0.303
Isopropyl ether 0.208 21.253 0.003
propylene 13.866 583.481 0.202
propane 1.762 77.695 0.026
water 32.029 576.530 0.466
Total 68.664 2508.960 1.000
 Seperator

Input Quantity (kmol/hr) Quantity(kg/hr) Mole fraction

Isopropyl alcohol 20.799 1250 0.303
Isopropyl ether 0.208 21.253 0.0030
propylene 13.866 583.481 0.202
propane 1.762 77.695 0.026
water 32.029 576.530 0.466
Total 68.664 2508.960 1.000

Top Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 2.417 145.286 0.079
Isopropyl ether 0.092 9.380 0.003
propylene 13.005 547.250 0.425
propane 0.000 0.000 0.000
water 15.086 271.544 0.493
Total 30.600 973.461 1.000

Bottom Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 18.381 1104.714 0.483
Isopropyl ether 0.116 11.873 0.003
propylene 0.861 36.231 0.023
propane 1.762 77.704 0.046
water 16.944 304.986 0.445
Total 38.064 1535.509 1.000

Stripper
Bottom Flash chambr
Input Quantity (kmol/hr) Quantity(kg/hr) Mole fraction
Isopropyl alcohol 18.381 1104.714 0.483
Isopropyl ether 0.116 11.873 0.003
propylene 0.861 36.231 0.023
propane 1.762 77.704 0.046
water 16.944 304.986 0.445
Total 38.064 1535.509 1.000

Top
Output Quantity (kmol/hr) Quantity(kg/hr) Mole fraction
Isopropyl alcohol 18.381 1104.714 0.806
Isopropyl ether 0.116 11.873 0.005
propylene 0.861 36.231 0.038
propane 1.762 77.704 0.077
water 1.694 30.499 0.074
Total 22.815 1261.021 1.000

Bottom (recycle)
Bottom Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
water 15.249 274.487 1.000
Total 15.249 274.487 1.000

Drying column and water layer stripper

Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
 condenser

Input Quantity (kmol/hr) Quantity(kg/hr) Mole fraction

Isopropyl alcohol 18.381 1104.714 0.806
Isopropyl ether 0.116 11.873 0.005
propylene 0.861 36.231 0.038
propane 1.762 77.704 0.077
water 1.694 30.499 0.074
Total 22.815 1261.021 1.000

Top
Input Quantity (kmol/hr) Quantity(kg/hr) Mole fraction
propylene 0.861 36.231 0.328
propane 1.762 77.704 0.672
Total 2.623 113.935 1.000

Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 18.381 1104.714 0.910
Isopropyl ether 0.116 11.873 0.006
water 1.694 30.499 0.084
Total 20.192 1147.086 1.000

Scrubber

Top Separator
Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
Isopropyl alcohol 2.417 145.286 0.079
Isopropyl ether 0.092 9.380 0.003
propylene 13.005 547.250 0.425
propane 0.000 0.000 0.000
water 15.086 271.544 0.493
Total 30.600 973.461 1.000

Top Cooler
Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
propylene 0.861 36.231 0.328
propane 1.762 77.704 0.672
Total 2.623 113.935 1.000

scrubbing water 51.53211 kmol/hr 927.57798

Total Product INPUT
Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
Isopropyl alcohol 2.417 145.286 0.029
Isopropyl ether 0.092 9.380 0.0011
propylene 13.866 583.481 0.164
propane 1.762 77.704 0.021
water 66.618 1199.122 0.786
Total 84.755 2014.974 1.000

Top Product Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

propylene 13.866 583.481 0.887
propane 1.762 77.704 0.113
Total 15.628 661.185 1.000

Bottom product Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 2.4174 145.2857 0.0350
Isopropyl ether 0.0918 9.3801 0.0013
water 66.6179 1199.1224 0.9637
Total 69.1271 1353.7882 1.0000
 Propylene column
Total
Input Quantity (kmol/hr) kg/hr Mole fraction
Propylene 13.866 583.481 0.887
propane 1.762 77.704 0.113
Total 15.628 661.185 1.000

Top Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

propylene (recycle) 13.866 583.481 1
Total 13.866 583.481 1.000

bottom
Bottom Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
propane 1.762 77.7042 1
Total 1.762 77.704 1.000

Ether column

Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 20.799 1250.000 0.233
Isopropyl ether 0.208 21.253 0.002
water 68.312 1229.621 0.765
Total 89.319 2500.874 1.000

Top Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl ether 0.208 21.253 1.000
Total 0.208 21.253 1.000

Bottom Output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 20.799 1250.000 0.233
water 68.312 1229.621 0.767
Total 89.111 2479.621 1.000

Alcohol column
Input Quantity (kmol/hr) Quantity (kg/hr) Mole fraction
Isopropyl alcohol 20.799 1250.000 0.233
water 68.312 1229.621 0.767
Total 89.111 2479.621 1.000

Top output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

Isopropyl alcohol 20.799 1250.016 0.387
water 32.945 593.011 0.613
Total 53.744 1843.027 1.000

Bottom output Quantity (kmol/hr) Quantity (kg/hr) Mole fraction

water 35.367 636.610 1.000
Total 35.367 636.610 1.000
 SCRUBBER
REACTOR scrubbing water
Components F1(kg/hr) F2(kg/hr) R(kg/hr)
C3H8O …… …… 1250 Components
C6H14O …… …… 21.253 C3H8O
C3H6 1476.21 …… 583.481 C6H14O
C3H8 77.7 …… 77.695 C3H6
H2O …… 954.674 576.530 C3H8
Total 1553.90 954.67 2508.960 H2O
2508.58 2508.960 Total

SEPERATOR
Components R(kg/hr) S1(kg/hr) S2(kg/hr) Components
C3H8O 1250 145.286 1104.714 C3H8O
C6H14O 21.253 9.380 11.873 C6H14O
C3H6 583.481 547.250 36.231 H2O
C3H8 77.695 0.000 77.704 C3H6
H2O 576.530 271.544 304.986 C3H8
Total 2508.960 973.461 1535.509 Total
2508.960 2508.969

STRIPPER ETHER COLUMN

Components S2(kg/hr) S3(kg/hr) R1(kg/hr) Components
C3H8O 1104.714 1104.714 …… C3H8O
C6H14O 11.873 11.873 …… C6H14O
C3H6 36.231 36.231 …… C3H6
C3H8 77.704 77.704 …… C3H8
H2O 304.986 30.499 274.487 H2O
Total 1535.509 1261.021 274.487 Total (kg/hr)
1535.509 1535.509

COOLER Components
Components S3(kg/hr) C2(kg/hr) C1(kg/hr) C3H8O
C3H8O 1104.714 …… 1104.714 C6H14O
C6H14O 11.873 …… 11.873 C3H6
C3H6 36.231 36.231 …… C3H8
C3H8 77.704 77.704 …… H2O
H2O 30.499 …… 30.499 Total
Total 1261.021 113.935 1147.086
1261.021 1261.021
Drying column and water la
Components
 C3H8O
H2O
Total
bbing water 805.68 kmol/hr

S1(kg/hr) C2(kg/hr) S4(kg/hr) S5(kg/hr)

145.286 …… …… 145.28574
9.380 …… …… 9.380124
547.250 36.23088 583.481 ……
0.000 77.7042 77.704 ……
14773.680 …… …… 14773.7844
15475.596 113.935 661.185 14928.450
15589.531 15589.636

Propylene column
S4(kg/hr) R2(kg/hr) P1(kg/hr)
…… …… ……
…… …… ……
…… …… ……
583.481 …… 583.481
77.704 77.7042 ……
661.185 77.704 583.481
661.185 661.185

ER COLUMN
C1(kg/hr) S5(kg/hr) E1(kg/hr) E2(kg/hr)
1104.714 145.28574 …… 1250
11.873 9.380124 21.25344 ……
…… …… …… ……
…… …… …… ……
30.499 14773.7844 …… 14804.282988
1147.086 14928.450 21.253 16054.283
16075.536 16075.536

ALCOHOL COLUMN
E2(kg/hr) A1(kg/hr) W1(kg/hr)
1250 1250.0155728 ……
…… …… ……
…… …… ……
…… …… ……
14804.282988 593.011296 14211.271692
16054.283 1843.027 14211.272
16054.283 ;

ng column and water layer stripper

A1(kg/hr) P(kg/hr) W2(kg/hr)
1250.015573 1250.015573 0
593.01 0 593.01
1843.025573 1250.015573 593.01
 Reactor

componentflowrate Cp T(ref) T(in) delta H

0.303 IPA 20.799 138.9 298 543 707800.4
0.003 DIPE 0.208 245.21 298 543 12495.9
0.466 WATER 32.029 35.82 298 543 281083.3
0.026 PROPANE 1.762 114.25 298 543 49320.58
0.202 PROPYLEN 13.866 100.39 298 543 341041.9

Delta H 1391742
Preheater

Components Input Output

kmol/hr kmol/hr
H2O 53.04 53.04
C3H6 35.08 35.08
C3H8 1.76 1.76
89.88 89.88
Tin = 25 C
Tout = 270 C
P= 20.3 MPa
Q= mCp∆T

Inlet temperature 25 C
Outlet temperature 270 C
Tave 147.5 C
Cp at Tave = 99.92 kJ/kgmoleC

Q= 2200298.352 kJ/hr

Mass of steam required

Q= mλ
Tsteam = 290 C P 2500 kPa
λ= 27800 kJ/kgmol
m= 79.14742273381 kgmol/hr
m= 1424.653609209 kg/hr

Reactor

Components Input Output

kmol/hr kmol/hr
IPA 20.799
H2O 53.04 32.029
C3H6 35.08 13.866
C3H8 1.76 1.762
DIPE 0.208
Total 89.88 68.664

Inlet and Outlet temperature 270 C

specific heat of IPA 237.6 kJ/kgmoleC
specific heat of H2O 98.73 kJ/kgmoleC
specific heat of C3H6 126.5 kJ/kgmoleC
specific heat of C3H8 146.1 kJ/kgmoleC
specific heat of DIPE 292.6 kJ/kgmoleC

Tref 25 C
Treactants 270 C
Tproducts 270 C

∆HR1 -50000 kj/kmol -1754000 kJ/hr

∆HR2 -319030 kj/kmol -13271009.94 kJ/hr
Ʃ(mCp)R = 9931.3952 2433191.824
Ʃ(mCp)p = 10176.40357 2493218.8747
∆HR -369030 kj/kmol -15025009.94 kJ/hr
∆TR 245
∆TP 245 -14964982.9

Q = Ʃ(mCp∆T)p - Ʃ(mCp∆T)r +∆HR

Q -14964982.8894 kJ/hr -4156.9396915 kW

Water requirement for cooling

Q 14964982.89 KJ/hr P= 1 atm
Q= mCp∆T
Tin 25 C
Tout 60 C
Tave 42.5 C
Cp 75.376 kJ/kgmoleC
m= 5672.507690966 kgmole/hr
m= 102191.3605543 kg/hr

Condenser

component input output

IPA 18.381 kgmole/hr 18.381 kgmole/hr
DIPE 0.116 kgmole/hr 0.116 kgmole/hr
Propylene 0.861 kgmole/hr 0.861 kgmole/hr
propane 1.762 kgmole/hr 1.762 kgmole/hr
water 1.694 kgmole/hr 1.694 kgmole/hr
Total 22.814 kgmole/hr 22.814 kgmole/hr

Tin 250 C P= 20.3 Mpa

Tout 250 C P= 10.13 Mpa
Tref 25 C

Latent heat mλ Cp at 250C and 20.3MPa Cp at 250C and 10.13 MPa

IPA λ= 1830000 kJ/kg Cp 232.8 kJ/kmolC
DIPE λ= 3702000 kJ/kg Cp 286.3 kJ/kmolC
Propylene kJ/kg Cp 127.2 kJ/kmolC
 propane kJ/kg Cp 145.9 kJ/kmolC
water λ= 29331.97 kJ/kg Cp 93.6 kJ/kmolC
212.0626
Qin Qout
IPA Q = 962796.78 kJ/hr IPA Q = 34869676 kJ/hr
DIPE Q = 7472.43 kJ/hr DIPE Q = 437455.1 kJ/hr
Propylene Q = 24641.82 kJ/hr Propylene Q = 22762.69 kJ/hr
propane Q = 57842.055 kJ/hr propane Q = 51974.6 kJ/hr
water Q = 35675.64 kJ/hr water Q = 86541.75 kJ/hr
Total Q = 1088428.725 kJ/hr Total Q = 35468410 kJ/hr

Q= 34379981.49818 kJ/hr

Amount of cooling water requirement

Q= mCp∆T
Tin 25 C
Tout 60 C
Cpw 75.376 kJ/kgmoleC
m= 13031.80303628 kgmole/hr
234572.454653
Ether column
m of feed = 89.111 kgmole
m of distillate = 0.208 kgmole
m of bottom = 89.111 kgmole
Cpmix of feed = 165.4 kJ/kgmoleC
Cpmix of bottom = 64.52 kJ/kgmoleC
Cp of top = 221.9 kJ/kgmoleC
Tin 88.87 C 361.87 K P= 1 atm
Tout B 100 C 373 K P= 3.7 atm
Tout D 60 C 333 K
Tref 25 C 298 K
Enthalpy of feed
QF = mcp(T-Tref)
QF = 941377.336878 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 431208.129 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 3461.64 kJ/hr

Heat removed by condenser

Latent heat = Qc = mλ
λ= 3702000 kJ/kg Tin = 88.87 C 361.87 K
m= 0.202 kgmole Tout = 60 C 333 K
Qc = 747804 kJ/hr

Sensible heat = mCp(Tin-Tout)

Tave = 74.435 C
Cp = 78.33 kJ/kgmoleC
Qc = 456.8001942 kJ/hr
Total Qc = 748260.8001942 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 241553.2323162 kJ/hr

Water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
m= 404.4652974023 kgmol/hr
7280.375353241
Steam required for reboiler
QR = mλ
Treb 105 C
λ 2244.59 kJ/kg
m= 107.6157482285 kg/hr

Alcohol column

m of feed = 89.111 kgmole

m of distillate = 53.744 kgmole
m of bottom = 35.367 kgmole
Cpmix of feed = 106.6 kJ/kgmoleC
Cpmix of bottom = 79.33 kJ/kgmoleC
Cp of top = 73.02 kJ/kgmoleC

Tin 100 C 373 K P= 5 atm

Tout B 102.36 C 375.36 K P= 1 atm
Tout D 82.8 C 355.8 K P= 1.1 atm
Tref 25 C 298 K

Enthalpy of feed
QF = mcp(T-Tref)
 QF = 712442.445 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 217046.1755496 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 226829.561664 kJ/hr

Heat removed by condenser

Latent heat = Qc = mλ
λ= 708200 kJ/kgmole Tin = 100 C 373 K
m= 53.744 kgmole Tout = 82.8 C 355.8 K
Qc = 38061500.8 kJ/hr

Sensible heat = mCp(Tin-Tout)

Tave = 91.4 C
Cp = 78.88 kJ/kgmoleC
Qc = 387474.462208 kJ/hr
Total Qc = 38448975.26221 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 38180408.55442 kJ/hr

Water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
m= 20783.22987146 kgmol/hr
374098.1376863 kg/hr
Steam required for reboiler
QR = mλ
Treb 108 C
λ 2232.96 kJ/kg
m= 17098.56359022 kg/hr

Drying Column
m of feed = 53.744 kgmole
m of distillate = 32.754 kgmole
m of bottom = 20.99 kgmole
Cpmix of feed = 73.83 kJ/kgmoleC
Cpmix of bottom = 105.2 kJ/kgmoleC
Cp of top = 33.67 kJ/kgmoleC

Tin 82.73 C 355.73 K P= 1.1 atm

Tout B 84.83 C 357.83 K P= 1.1 atm
Tout D 40 C 313 K P= 1 atm
Tref 25 C 298 K

Enthalpy of feed
QF = mcp(T-Tref)
QF = 229067.9938896 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 132113.49484 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 16542.4077 kJ/hr

Heat removed by condenser

Latent heat = Qc = mλ
λ= 613700 kJ/kgmole Tin = 82.73 C 355.73 K
m= 32.754 kgmole Tout = 40 C 313 K
Qc = 20101129.8 kJ/hr

Sensible heat = mCp(Tin-Tout)

Tave = 61.365 C
Cp = 78.03 kJ/kgmoleC
Qc = 156836.3368563 kJ/hr
Total Qc = 20257966.13686 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 20177554.04551 kJ/hr

Water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
m= 10950.25196587 kgmol/hr
 197104.5353856
Steam required for reboiler
QR = mλ
Treb 100 C
λ 2256.92 kJ/kg
m= 8940.305392086 kg/hr

propylene column
m of feed = 15.628 kgmole
m of distillate = 13.866 kgmole
m of bottom = 1.762 kgmole
Cpmix of feed = 91.14 kJ/kgmoleC
Cpmix of bottom = 161.1 kJ/kgmoleC
Cp of top = 137.3 kJ/kgmoleC

Tin 52 C 325 K P= 2027 kPa

Tout B 57.9 C 330.9 K P= 2069 kPa
Tout D 46.5 C 319.5 K P= 1931 kPa
Tref 25 C 298 K

Enthalpy of feed
QF = mcp(T-Tref)
QF = 38457.06984 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 9338.93478 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 40931.7387 kJ/hr

Heat removed by condenser

Latent heat = Qc = mλ
λ= 1927000 kJ/kgmole Tin = 52 C 325 K
m= 13.866 kgmole Tout = 46.5 C 319.5 K
Qc = 26719782 kJ/hr

Sensible heat = mCp(Tin-Tout)

Tave = 49.25 C
Cp = 141.5 kJ/kgmoleC
 Qc = 96630.42075 kJ/hr
Total Qc = 26816412.42075 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 26828226.02439 kJ/hr

Water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
m= 14495.35806527 kgmol/hr
260916.4451749 kg/hr
Steam required for reboiler
QR = mλ
Treb 60 C
λ 2358.564 kJ/kg
m= 11374.81366814 kg/hr

Stripper

IPA 18.381 kmol/hr Tin = 250 C P= 10.13 MPa

DIPE 0.116 kmol/hr Tout = 270 C P= 20.3MPa
Propane 1.762 kmol/hr Tref = 25 C
propylene 0.861 kmol/hr
water 16.944 kmol/hr
total 38.064 kmol/hr

Cp at 250C and 10.13 Mpa Cp at 250C and 20.3 Mpa

IPA Cp = 298 kJ/kmolC 232.8 kJ/kgmoleC

DIPE Cp = 307.4 kJ/kmolC 286.3 kJ/kgmoleC
Propane Cp = 131.1 kJ/kmolC 145.9 kJ/kgmoleC
propylene Cp = 117.5 kJ/kmolC 127.2 kJ/kgmoleC
water Cp = 96.69 kJ/kmolC 93.6 kJ/kgmoleC
Cpw = 196.61635 kJ/kmolC 212.0626kJ/kgmoleC
Latent heat mλ
IPA λ= 1830000 kJ/kgmole
DIPE λ= 3702000 kJ/kgmole
Propylene λ= 1927000 kJ/kgmole
propane λ= 2045000 kJ/kgmole
water λ= 29331.97 kJ/kgmole
 Qin = mCp(Tin-Tref)
1683901.06794 kJ/hr
Qout top = 40467384.20646 kJ/hr
Qout b = 331745.80725 kJ/hr
Q= 39115228.94577 kJ/hr

Steam requirement for heating

Q= mλ T 270 C
λ 27885.34 Kj/kgmol
m 1402.716586772 kgmol/hr
25248.89856189 kg/hr
Cp at 250C and 10.13 MPa
298 kJ/kmolC
307.4 kJ/kmolC
117.5 kJ/kmolC
 131.1 kJ/kmolC
96.69 kJ/kmolC
263.4398
10.13 MPa
Ether column

m of feed = 89.111 kgmole

m of distillate = 0.208 kgmole
m of bottom = 89.111 kgmole
Cpmix of feed = 165.4 kJ/kgmoleC
Cpmix of bottom = 64.52 kJ/kgmoleC
Cp of top = 221.9 kJ/kgmoleC
Tin 88.87 C 361.87 K p= 1 atm
Tout B 100 C 373 K p= 3.7 atm
Tout D 60 C 333 K
Tref 25 C 298 K
Enthalpy of feed
QF = mcp(T-Tref)
QF = 941377.3 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 431208.1 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 3461.64 kJ/hr

Heat removed by condenser

latent heat = Qc = mλ
λ= 3702000 Tin = 88.87 C 361.87
m= 0.202 kgmole Tout = 60 C 333
Qc = 747804 kJ/hr

sensible heat = mCp(Tin-Tout)

Tave = 74.435 C
Cp = 78.33 kJ/kgmoleC
Qc = 456.8002 kJ/hr
Total Qc = 748260.8 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 241553.2 kJ/hr

water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
 m= 404.4653 kg/hr

steam required for reboiler

QR = mλ
Treb 105 C
λ 2244.59 kJ/kg
m= 107.6157 kg/hr

Alcohol column

m of feed = 89.111 kgmole

m of distillate = 53.744 kgmole
m of bottom = 35.367 kgmole
Cpmix of feed = 106.6 kJ/kgmoleC
Cpmix of bottom = 79.33 kJ/kgmoleC
Cp of top = 73.02 kJ/kgmoleC

Tin 100 C 373 K p= 5 atm

Tout B 102.36 C 375.36 K p= 1 atm
Tout D 82.8 C 355.8 K p= 1.1 atm
Tref 25 C 298 K

Enthalpy of feed
QF = mcp(T-Tref)
QF = 712442.4 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 217046.2 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 226829.6 kJ/hr

Heat removed by condenser

latent heat = Qc = mλ
λ= 708200 kJ/kgmole Tin = 100 C 373 K
m= 53.744 kgmole Tout = 82.8 C 355.8 K
Qc = 38061501 kJ/hr

sensible heat = mCp(Tin-Tout)

Tave = 91.4 C
Cp = 78.88 kJ/kgmoleC
Qc = 387474.5 kJ/hr
Total Qc = 38448975 kJ/hr
Overall Balance:
QR + QF = QC + QB + QD
QR = 38180409 kJ/hr

water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC

m= 20783.23 kg/hr

steam required for reboiler

QR = mλ
Treb 108 C
λ 2232.96 kJ/kg
m= 17098.56 kg/hr

Drying Column

m of feed = 53.744 kgmole

m of distillate = 32.754 kgmole
m of bottom = 20.99 kgmole
Cpmix of feed = 73.83 kJ/kgmoleC
Cpmix of bottom = 105.2 kJ/kgmoleC
Cp of top = 33.67 kJ/kgmoleC

Tin 82.73 C 355.73 K p= 1.1 atm

Tout B 84.83 C 357.83 K p= 1.1 atm
Tout D 40 C 313 K p= 1 atm
Tref 25 C 298 K

Enthalpy of feed
QF = mcp(T-Tref)
QF = 229068 kJ/hr

Enthalpy of bottom
QB = mcp(T-Tref)
QB = 132113.5 kJ/hr

Enthalpy of top

QD = mcp(T-Tref)
QD = 16542.41 kJ/hr

Heat removed by condenser

latent heat = Qc = mλ
λ= 613700 kJ/kgmole Tin = 82.73 C 355.73 K
m= 32.754 kgmole Tout = 40 C 313 K
Qc = 20101130 kJ/hr

sensible heat = mCp(Tin-Tout)

Tave = 61.365 C
Cp = 78.03 kJ/kgmoleC
Qc = 156836.3 kJ/hr
Total Qc = 20257966 kJ/hr

Overall Balance:
QR + QF = QC + QB + QD
QR = 20177554 kJ/hr

water required in condenser

Qc = mCp(Tin-Tout)
Tin = 25 C
Tout 50 C
Cp = 74 kJ/kgmoleC
m= 10950.25 kg/hr

steam required for reboiler

QR = mλ
Treb 100 C
λ 2256.92 kJ/kg
m= 8940.305 kg/hr