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MenAMI SodiumP 04
MenAMI SodiumP 04
Operator’s Manual
A-96.250.211 / 171011
Customer Support
SWAN and its representatives maintain a fully trained staff of technical specialists
around the world. For any technical question, contact your nearest
SWAN representative, or the manufacturer:
Internet: www.swan.ch
E-mail: support@swan.ch
Document Status
ID: A-96.250.211
Revision Issue
03 September 2005
04 Oct. 2011
1. Safety Instructions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.1. Warning Notices. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.2. General Safety Regulations . . . . . . . . . . . . . . . . . . . . . . . 7
1.3. Restrictions for use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2. Product Description. . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
2.1. Instrument Specification. . . . . . . . . . . . . . . . . . . . . . . . . . 12
2.2. Instrument Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
2.3. Display, Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.4. Software Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
2.5. Changing Parameters and Values . . . . . . . . . . . . . . . . . . 19
3. Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
3.1. Installation Check List . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
3.2. Mounting of Instrument Panel . . . . . . . . . . . . . . . . . . . . . 21
3.3. Connecting Sample and Waste . . . . . . . . . . . . . . . . . . . . 22
3.4. Electrical Connections . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
3.5. Connection Diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3.6. Power Supply. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
3.7. Signal Input . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
3.8. Connection of Sensors. . . . . . . . . . . . . . . . . . . . . . . . . . . 27
3.9. Relay Contacts. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
3.9.1 Alarm Relay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
3.9.2 Relay Contacts 1 and 2 . . . . . . . . . . . . . . . . . . . . . . . . 29
3.10. Signal Outputs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
3.10.1 Signal output 1 and 2 (current outputs) . . . . . . . . . . . . 30
3.10.2 Signal output 3 (optional) . . . . . . . . . . . . . . . . . . . . . . . 30
3.11. Interface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
3.12. Installation of Flow Cell and Sensors. . . . . . . . . . . . . . . . 32
3.13. Installation of Sodium Electrode . . . . . . . . . . . . . . . . . . . 33
3.14. Installation of Reference Electrode . . . . . . . . . . . . . . . . . 34
3.15. Installation of pH Electrode . . . . . . . . . . . . . . . . . . . . . . . 36
3.16. Installation of Reagent Bottle . . . . . . . . . . . . . . . . . . . . . . 37
3.17. Installation of Air Filter . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
3.18. Installation of 2nd Sample Stream (Option) . . . . . . . . . . . 39
A-96.250.211 / 171011 1
AMI Sodium P
4. Instrument Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.1. Power up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.2. Establish Sample Flow. . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.3. Switch on Power . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4.4. Programming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4.5. Prepare Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4.6. Check Outputs and Relays . . . . . . . . . . . . . . . . . . . . . . . 43
4.7. Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
4.7.1 pH Process Calibration. . . . . . . . . . . . . . . . . . . . . . . . . 44
4.7.2 1-Point-Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
4.7.3 2-Point-Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
5. Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
5.1. Grab Sample . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
6. Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
6.1. Maintenance Schedule. . . . . . . . . . . . . . . . . . . . . . . . . . . 48
6.2. Stop of Operation for Mainteneance . . . . . . . . . . . . . . . . 48
6.3. Maintenance of Sodium Electrode . . . . . . . . . . . . . . . . . . 49
6.4. Maintenance of Reference Electrode. . . . . . . . . . . . . . . . 50
6.5. Maintenance of pH Electrode. . . . . . . . . . . . . . . . . . . . . . 50
6.6. Maintenance of Solenoid Valve . . . . . . . . . . . . . . . . . . . . 51
6.7. Maintenance of Consatnt Head and Flow Cell. . . . . . . . . 53
6.7.1 Dismount Constant Head . . . . . . . . . . . . . . . . . . . . . . . 53
6.7.2 Replacement Parts for Constant Head. . . . . . . . . . . . . 54
6.7.3 Dismount Flow Cell . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
6.7.4 Replacement Parts for Flow Cell . . . . . . . . . . . . . . . . . 56
6.8. Tube Replacement. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
6.8.1 Tube Numbering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
6.9. Replacing Fuses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
6.10. Longer Stop of Operation. . . . . . . . . . . . . . . . . . . . . . . . . 59
7. Error List . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
8. Program Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
8.1. Messages (Main Menu 1). . . . . . . . . . . . . . . . . . . . . . . . . 64
8.2. Diagnostics (Main Menu 2) . . . . . . . . . . . . . . . . . . . . . . . 64
8.3. Maintenance (Main Menu 3) . . . . . . . . . . . . . . . . . . . . . . 65
8.4. Operation (Main Menu 4) . . . . . . . . . . . . . . . . . . . . . . . . . 66
8.5. Installation (Main Menu 5) . . . . . . . . . . . . . . . . . . . . . . . . 67
9. Program List and Explanations . . . . . . . . . . . . . . . . . . 69
1 Messages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
2 A-96.250.211 / 171011
AMI Sodium P
2 Diagnostics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
3 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
5 Installation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
10. Material Safety Data Sheets . . . . . . . . . . . . . . . . . . . . . 84
10.1. Etching Kit A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
10.2. Etching Kit B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
10.3. Sodium Standard Solution 1’000 [ppm] . . . . . . . . . . . . . . 91
10.4. Diisopropylamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
11. Default Values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
12. Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
13. Notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106
A-96.250.211 / 171011 3
AMI Sodium P
Safety Instructions
1. Safety Instructions
General The instructions included in this section explain the potential risks
associated with instrument operation and provide important safety
practices designed to minimize these risks.
If you carefully follow the information contained in this section, you
can protect yourself from hazards and create a safer work
environment.
More safety instructions are given throughout this manual, at the
respective locations where observation is most important.
Strictly follow all safety instructions in this publication.
Target Operator: Qualified person who uses the equipment
audience for its intended purpose.
Instrument operation requires thorough knowledge of applications,
instrument functions and software program as well as all applicable
safety rules and regulations.
OM Location The AMI Operator’s Manual shall be in proximity of the instrument.
Qualification, To be qualified for instrument installation and operation, you must:
Training read and understand the instructions in this manual as well
as the Material Safety Data Sheets.
know the relevant safety rules and regulations.
4 A-96.250.211 / 171011
AMI Sodium P
Safety Instructions
corrosive
harmful to health
flammable
Warning general
A-96.250.211 / 171011 5
AMI Sodium P
Safety Instructions
ATTENTION ATTENTION
Symbols
The attention symbol indicates the possibility of equipment
damage, malfunctions or incorrect process results if instructions
are not followed.
Attention general
Safety goggles
Safety gloves
6 A-96.250.211 / 171011
AMI Sodium P
Safety Instructions
Spare Parts Use only official SWAN spare parts and disposables. If other parts
and are used during the normal warranty period, the manufacturer’s
Disposables warranty is voided.
WARNING
A-96.250.211 / 171011 7
AMI Sodium P
Safety Instructions
WARNING
ATTENTION
8 A-96.250.211 / 171011
AMI Sodium P
Product Description
2. Product Description
Application Sodium measurement is used for quality control in high purity water
applications and to monitor break through of mixed bed ion ex-
changers, condenser leaks and the prevention of caustic corrosion
of turbines.
Measuring The sodium measurement used in this instrument is based on a po-
principle tentiometric measuring method. For this purpose a proven glass
ion sensitive electrode and a reference electrode is used. These
two electrodes produce a different electrical potential which is used
to calculate the sodium concentration of the sample. According to
Nernsts Law, the ion concentration depends on the temperature,
therefore a temperature sensor measures the sample temperature.
With the current temperature the measuring value is expressed for
the standard temperature of 25 °C by using programmed tempera-
ture compensation curves.
Sodium measurements below 1 ppb require a special glass formu-
lation for the sensing electrode response.
Ammonium and pH interferences from the unconditioned sample
are eliminated by a suitable reagent. The measuring limit of 0.1 ppb
sodium requires the conditioning of the sample to a minimum of
pH 10.5 while sample integrity has to be maintained. The best re-
sults are obtained with Diisopropylamine (DIPA)
Signal Two signal outputs programmable for measured values (freely scal-
Outputs able, linear or bilinear) or as continuous control output (control pa-
rameters programmable).
Current loop: 0/4 - 20 mA
Maximal burden: 510
Third signal output with the same specifications as option.
(Only possible if no communication interface is used.)
Relay Two potential-free contacts programmable as limit switches for
measuring values, controllers or timer for system cleaning with au-
tomatic hold function.
Maximum load: 1 A / 250 VAC
Consumables The filling of the 100 ml KCl Bottle is sufficient for one month.
A-96.250.211 / 171011 9
AMI Sodium P
Product Description
On-line The sample flows into the constant head [C] via the sample inlet [E]
Operation and the flow regulating valve [F]. Adjust the flow regulating valve so
that always a small part of the sample flows through the overflow
tube into the waste [L]. This adjustment ensures a sufficient sample
flow through the flow cell [K].
If the standard bottle holder [G] is completely turned down, the
sample flows from the constant head [C] into the reaction tube.
Due to different level of the constant head and the flow cell, a nega-
tive pressure is produced in the reaction tube. As a result, reagent
saturated air is aspirated into the reaction tube, raising the pH of
the sample to a value of 10.5, and forming a regular stream of air
bubbles.
The bubble stream is used to monitor the correct sample flow with
the bubble detector [I]. An inconsistent sample flow causes an in-
terruption of the bubble formation and produces a system error.
Calibration The standard bottle [D] is screwed in the standard bottle holder [G]
and turned upwards into the vertical position, thus switching the
sample flow from the flow cell to the standard bottle. Constant pres-
sure within the standard bottle is maintained by the pressure-equal-
izing tube inside the bottle.
1 liter standard is consumed in approx. 10 min. The sodium elec-
trode must reach constant readings within this time to obtain an ex-
act calibration.
For details, see Calibration, p. 42
10 A-96.250.211 / 171011
AMI Sodium P
Product Description
Fluidics
2 A
B
1
C D
E F G
H 3
H1 Na Ref Te pH
1
2
3 I
J
H2 H3
3 K
L L
A-96.250.211 / 171011 11
AMI Sodium P
Product Description
ATTENTION
12 A-96.250.211 / 171011
AMI Sodium P
Product Description
13 mm / ½”
280 mm / 11”
13 mm / ½” 254 mm / 10”
6 x dia. 6.5 mm / ¼”
Enter
412 mm / 16¼”
Exit
824 mm / 32 /16”
850 mm / 33½”
7
A-96.250.211 / 171011 13
AMI Sodium P
Product Description
13 mm / ½”
400 mm / 15¾”
13 mm / ½” 374 mm / 14¾”
4 x dia. 6.5 mm / ¼”
824 mm / 32 7/16”
850 mm / 33 ½”
14 A-96.250.211 / 171011
AMI Sodium P
Product Description
A Transmitter with
backlit LCD display
A
J B Panel
C Reference electrolyte bottle
D 2nd sample stream (option)
E Flow regulating valve
F Sample inlet (direct or via
2nd sample stream)
B K
G pH electrode
C L (behind sodium electrode)
H Sodium electrode
I Bubble detector
D
E M J Air filter
K Standard bottle/Grab sample
L Constant head
F M Standard bottle holder
G N N Reference electrode
H O Temperature sensor
O
I P Reagent bottle
P Q Waste nozzle
A-96.250.211 / 171011 15
AMI Sodium P
Product Description
RUN 15:20:18
R1
E
R2
21.5 ppm
H 10.88 pH 22.1°C
F
G
16 A-96.250.211 / 171011
AMI Sodium P
Product Description
Keys
A B C D
Exit Enter
Program
RUN 14:10:45 Main Menu 1
Access, Exit Enter
R1 Messages
0.42 ppb Diagnostics
R2
Maintenance
Exit Operation
10.84 pH 25.4°C Installation
A-96.250.211 / 171011 17
AMI Sodium P
Product Description
Main Menu 1
Messages
Diagnostics
Maintenance
Operation
Installation
Messages 1.1
Menu 1: Messages
Pending Errors
Reveals pending errors as well as an event history
Maintenance List
(time and state of events that have occurred at an
Message List earlier point of time) and maintenance requests.
It contains user relevant data.
Diagnostics 2.1
Menu 2: Diagnostics
Identification
Provides user relevant instrument and sample data.
Sensors
Sample
I/O State
Interface
Maintenance 3.1
Menu 3: Maintenance
Calibration
For instrument calibration, service, relay and signal
Simulation output simulation and to set the instrument time.
Set Time 01.01.05 16:30:00 It is used by the service personnel.
Operation 4.1
Menu 4: Operation
Sensors
Subset of menu 5 - installation, but process-related.
Relay Contacts User relevant parameters that might need to be
Logger modified during daily routine. Normally password
protected and used by the process-operator.
Installation 5.1
Menu 5: Installation
For initial instrument set up by SWAN authorized
Sensors
Signal Outputs persons, to set all instrument parameters. Can be
Relay Contacts protected by means of a password.
Miscellaneous
Interface
18 A-96.250.211 / 171011
AMI Sodium P
Product Description
Logger 4.3.1
The selected parameter is indicated
Log interval 1 Minute (but not saved yet).
Clear logger no
Exit
Press
Logger 4.3.1
Log interval event driven Yes highlighted, press Enter to save
Save ? the new parameter. The system
Clear logger no
Yes reboots, the new parameter is set.
No
Changing
value Sodium 5.3.1.1.1
Alarm High 20.00 ppm Select parameter and press Enter
Alarm Low 0.00 ppb
Hysteresis 0.10 ppb
Delay 5 Sec to set required value.
A-96.250.211 / 171011 19
AMI Sodium P
Installation
3. Installation
20 A-96.250.211 / 171011
AMI Sodium P
Installation
A-96.250.211 / 171011 21
AMI Sodium P
Installation
ATTENTION
Mounting of
SERTO fitting
A A Screw connection
B Compression ferrule
B C Knurled nut
C D Flexible tube
D
Waste Connect the 1/2” tubes to the nozzle of the waste funnels and place
them into an atmospheric drain of sufficient capacity.
WARNING
22 A-96.250.211 / 171011
AMI Sodium P
Installation
WARNING
A B C
Wire For Power and Relays: Use max. 1.5 mm2 / AWG 14
stranded wire with end sleeves.
For Signal Outputs and Input: Use 0.25 mm2 / AWG 23
stranded wire with end sleeves.
WARNING
A-96.250.211 / 171011 23
AMI Sodium P
Installation
WARNING
WARNING
24 A-96.250.211 / 171011
AMI Sodium P
Installation
WARNING
Use only the terminals shown in this diagram, and only for the
mentioned purpose. Use of any other terminals will cause short
circuits with possible corresponding consequences to material
and personnel.
A-96.250.211 / 171011 25
AMI Sodium P
Installation
B
C
ATTENTION
26 A-96.250.211 / 171011
AMI Sodium P
Installation
A-96.250.211 / 171011 27
AMI Sodium P
Installation
Terminals Description
a) usual use
28 A-96.250.211 / 171011
AMI Sodium P
Installation
ATTENTION
A-96.250.211 / 171011 29
AMI Sodium P
Installation
30 A-96.250.211 / 171011
AMI Sodium P
Installation
3.11. Interface
Interface Terminal 50, 52, 53
RS232 The AMI Interface RS232 PCB is used for Logger down load and
Firmware up load. For detailed information see the corresponding
manual “AMI RS232 Interface”
ON
PB-DPV1 V5.5
Profibus
81.420.020
A-96.250.211 / 171011 31
AMI Sodium P
Installation
B
C
D
Temperature Place the temperature sensor into the small opening in the cover of
sensor flow cell. Fasten the cable marked T.
WARNING
32 A-96.250.211 / 171011
AMI Sodium P
Installation
WARNING
ATTENTION
Once the fluoride salt is dissolved, the life time of the solu-
tion is limited to 6 months.
A-96.250.211 / 171011 33
AMI Sodium P
Installation
Mounting 1 Slip the black nut and then the washer onto the electrode.
2 Wet the O-ring and slip it carefully on the electrode.
3 Make sure no air bubbles are trapped between glass bulb
and glass tube by swinging the electrode with sensing bulb
downwards, like a clinical thermometer.
4 Insert the electrode into the measuring cell and push it down
completely.
5 Screw the black nut finger-tight.
6 Remove the protective cap from the connector and fasten
the cable marked S.
7 Make sure that only the sleeve is rotated.
8 Avoid twisting the cable.
1 Remove the stopper from the electrode tubing and cut off
1 cm of the nozzle of the electrolyte reservoir. Connect the
reservoir to the electrode tubing.
2 Fix the reservoir upside down in the holder to the right of the
transmitter. Puncture the top of the bottle to allow pressure
equilibration!
3 Remove the protection cap from the grounded glass sleeve
with a turning and pulling movement.
34 A-96.250.211 / 171011
AMI Sodium P
Installation
ATTENTION
F
F Push to close C
(slightly turning movement
D
Mounting 1 Slip first the black nut and then the washer on the electrode.
Wet the O-ring and slip carefully on the electrode. Make
sure that the grounded glass sleeve stays in place.
A-96.250.211 / 171011 35
AMI Sodium P
Installation
2 Insert the electrode into the measuring cell and push down
completely. Screw the nut finger-tight.
3 Remove the protective cap from the electrical connector and
fasten the cable marked R. Make certain the sleeve only is
rotated. Avoid twisting the cable. Store the protective caps
for later use.
ATTENTION
36 A-96.250.211 / 171011
AMI Sodium P
Installation
A
A Tube 2 to reaction tube
B (Flow cell)
B Tube 1 from air filter
C see figure next page
C G 45 nut
D D EPDM seal
E Reagent bottle
ATTENTION
ATTENTION
The tube inside the reagent bottle (tube 1) must connect to the
tube from the air filter.
ATTENTION
The red bottle nut fits on bottles with a G45 thread (Schott-thread).
If i.e. Merck reagent is used, a thread adapter is available.
A-96.250.211 / 171011 37
AMI Sodium P
Installation
B
C
A Filter holder
B Air filter
C Tube 1 from Air filter to Reagent bottle
38 A-96.250.211 / 171011
AMI Sodium P
Installation
C
D
I
E
F
G
H
A Solenoid valve
B Flow regulating valves for sample stream 1 and 2
C Fixing screw
D Block housing
E Pipe connection between block housing and flow cell
F Sample stream 1
G Waste funnel (drain)
H Sample stream 2
I Flow cell inlet
A-96.250.211 / 171011 39
AMI Sodium P
Installation
40 A-96.250.211 / 171011
AMI Sodium P
Instrument Setup
4. Instrument Setup
4.1. Power up
After the analyzer is installed according to the previous instructions,
connect the power cord.
WARNING
A B
WARNING
A-96.250.211 / 171011 41
AMI Sodium P
Instrument Setup
4.4. Programming
Program all parameters for external devices (interface, recorders,
etc.) Program all parameters for instrument operation (limits,
alarms). See Program Overview, p. 64 and for explanations, see
Program List and Explanations, p. 69
42 A-96.250.211 / 171011
AMI Sodium P
Instrument Setup
Maintenance 3.3
Calibration
Service
Simulation Enter Simulation 3.3.1
Set Time 01.06.04 16:30:00 Alarm Relay open/closed
Cleaning Relay 1 open/closed
Relay 2 open/closed
Signal Output 1 x mA
Signal Output 2 x mA
A-96.250.211 / 171011 43
AMI Sodium P
Instrument Setup
4.7. Calibration
When starting the calibration, you first have to perform the pH-Cali-
bration and then the Sodium calibration! The Sodium measurement
is dependent on the pH value.
ATTENTION
44 A-96.250.211 / 171011
AMI Sodium P
Instrument Setup
Example
ATTENTION
4.7.2 1-Point-Calibration
Electrode Go to Menu 3.1.1
Offset The instrument guides you through the complete calibration pro-
cess. If you have completed the required action press <Enter> to
proceed.
A-96.250.211 / 171011 45
AMI Sodium P
Instrument Setup
4.7.3 2-Point-Calibration
Electrode 1 Screw standard bottle 2 onto holder and swing bottle
Slope upwards.
2 Wait until the process has finished.
3 First, press <Enter> to save and then <Exit> to leave
calibration.
4 Calibration successful.
5 Swing bottle down and remove it from holder.
ATTENTION
46 A-96.250.211 / 171011
AMI Sodium P
Operation
5. Operation
ATTENTION
Screw the grab sample bottle into the standard bottle holder and
swing upwards.
ATTENTION
A-96.250.211 / 171011 47
AMI Sodium P
Maintenance
6. Maintenance
WARNING
48 A-96.250.211 / 171011
AMI Sodium P
Maintenance
WARNING
Replace the 1 Unscrew cable and protect the connector with the protective
sodium elec- cap.
trode 2 Loose the black nut completely and remove the electrode
together with nut, washer and O-ring from the measuring
cell.
3 Slip O-ring carefully over the glass sleeve and remove nut
and washer.
4 Install the O.ring to the new sodium electrode.
Install the See Installation of Sodium Electrode, p. 33
electrode
A-96.250.211 / 171011 49
AMI Sodium P
Maintenance
WARNING
Cleaning 1 Unscrew cable and protect the sensor connector with the
protective cap.
2 Loose the black nut completely and remove the electrode
together with nut and washer from the measuring cell.
3 Remove any iron deposits with a soft paper tissue.
4 Slip the grounded glass sleeve upwards with a turning and
pushing movement, let about 1 ml KCl flow out, and fix
sleeve finger tight with a gentle turning and pulling move-
ment.
5 Replace or refill KCl reservoir. Use only original SWAN KCl
Mount the See Installation of Reference Electrode, p. 34
electrode
WARNING
50 A-96.250.211 / 171011
AMI Sodium P
Maintenance
A-96.250.211 / 171011 51
AMI Sodium P
Maintenance
ATTENTION
Clean the white plate (G) and membrane (H) with clean water
only.
52 A-96.250.211 / 171011
AMI Sodium P
Maintenance
ATTENTION
ATTENTION
A-96.250.211 / 171011 53
AMI Sodium P
Maintenance
E
F
H I K J L M N O
A Constant head cover H SERTO fitting sample inlet
B Constant head tube; O-ring 55x4mm I O-ring 10x4 mm to constant head
C Tube 2 to reagent bottle; fitting; M6 J Locking screw
washer K 3 x O-ring 4.9x1.9 mm
D White flow restriction tube L 2 x O-ring 27x3 mm
E SERTO fitting reaction tube M Standard bottle holder
F Regulating valve with: N O-ring 34x3.5 mm in holder
O-ring 3.1x1.6 mm O Fixing screw M6 x 100
O-ring 4.9x1.9 mm
G Fixing screw M6
54 A-96.250.211 / 171011
AMI Sodium P
Maintenance
Note: After the maintenance work has been finished, run the
instrument in normal operation for at least 1 hour before doing a
calibration.
A-96.250.211 / 171011 55
AMI Sodium P
Maintenance
A
I
B
H
56 A-96.250.211 / 171011
AMI Sodium P
Maintenance
A
1
2 1
Tube Length
No [mm] from to
A-96.250.211 / 171011 57
AMI Sodium P
Maintenance
WARNING
Find and repair the cause for the short circuit before replacing the
fuse.
Use tweezers or needle-nosed pliers to remove the defective fuse.
Use original fuses provided by SWAN only.
A B C D
58 A-96.250.211 / 171011
AMI Sodium P
Maintenance
ATTENTION
A-96.250.211 / 171011 59
AMI Sodium P
Error List
7. Error List
Error
Non-fatal Error. Indicates an alarm if a programmed value is
exceeded.
Such Errors are marked E0xx (bold and black).
<Enter> to Acknowledge
60 A-96.250.211 / 171011
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Error List
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AMI Sodium P
Error List
62 A-96.250.211 / 171011
AMI Sodium P
Error List
A-96.250.211 / 171011 63
AMI Sodium P
Program Overview
8. Program Overview
For explanations about each parameter of the menus see Program
List and Explanations, p. 69
64 A-96.250.211 / 171011
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Program Overview
A-96.250.211 / 171011 65
AMI Sodium P
Program Overview
66 A-96.250.211 / 171011
AMI Sodium P
Program Overview
A-96.250.211 / 171011 67
AMI Sodium P
Program Overview
Delay 5.3.4.5*
Miscellaneous Language 5.4.1*
5.4* Set defaults 5.4.2*
Load Firmware 5.4.3*
Password Messages 5.4.4.1*
5.4.4* Maintenance 5.4.4.2*
Operation 5.4.4.3*
Installation 5.4.4.4*
Sample ID 5.4.5*
Interface Protocol 5.5.1* (only with RS485
5.5* Device Address 5.5.21* or RS232 interface)
Baud Rate 5.5.31*
Parity 5.5.41* * Menu numbers
68 A-96.250.211 / 171011
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Program List and Explanations
2.2.2 pH Electrode:
Current Value: Indicates the actually measured pH value pH.
Raw value: Read the actual electrode voltage mV.
A-96.250.211 / 171011 69
AMI Sodium P
Program List and Explanations
2.2.2.5 Cal. History: Read diagnostic values of the last pH electrode cali-
brations, offset in mV and slope in mV/pH
2.2.3 Miscellaneous:
2.2.3.1 Case Temp: Read actual temperature in °C inside the transmitter.
2.3 Sample
2.3.1 Sample ID: Review the programmed code. The code is defined by
the user to identify the sample point in the plant.
Temperature: Actual temperature in °C and in Ohm (NT5K)
Sample Flow:Read the actual sample flow B/s (bubbles per sec-
ond)
Raw value (Hz)
Sample flow must be above 5 B/s. Default Values; Sample Flow
Alarm Low 5 B/s
2.4 I/O State
Read actual status of all in- and outputs.
2.4.1/2.4.2 Alarm Relay: Open or closed.
Relay 1/2: Open or closed.
Input: Open or closed.
Signal Output 1/2: Actual current in mA (3 if option is installed)
2.5 Interface
Only available if optional interface is installed.
Review programmed communication settings.
3 Maintenance
3.1 Calibration
In this menu, you can correct measuring values, or calibrate offset
and slope of pH electrode.
3.1.1 Standard Sodium: Possibility to correct the sodium sensor value.
Follow the commands on the screen. Save the value with the <en-
ter> key. See Calibration, p. 44, for more details.
3.1.2 Process pH: Correction of pH electrode. See pH Process Calibra-
tion, p. 44, for details.
70 A-96.250.211 / 171011
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Program List and Explanations
3.2 Simulation
Test alarm relay, relay 1/2 or signal output 1/2 by selecting with the
<Enter> key and press the up/down key to change the value. After
confirming the setting with the Enter key, the value is simulated by
the relay/signal output.
Alarm Relay: Open or closed.
Relay 1/2: Open or closed.
Input: Open or closed.
Signal Output 1/2: Actual current in mA
Signal Output 3: Actual current in mA (if option is installed)
At the absence of any key activities, the instrument will switch back
to normal mode after 20 min. If you quit the menu, all simulated val-
ues will be reset.
3.4 Set Time
Adjust date and time.
4 Operation
4.1 Sensors
4.1.1 Filter Time Constant: Used to damp noisy signals. The higher the
filter time constant, the slower the system reacts to changes of the
measured value.
Range: 5–300 Sec
4.1.2 Hold after Cal: Delay permitting the instrument to stabilize again af-
ter calibration. During calibration- plus hold-time, the signal outputs
are frozen (held on last valid value), alarm values, limits are not ac-
tive.
Range: 0–6‘000 Sec
4.1.3 Interval: Only active, if a second sample streeam is installed and
the channel switch (menu 5.1.3) is set to automatic.
Range: 15 Min to 120 Min
4.2 Relay Contacts
See 5.3 Relay Contacts, p. 76
4.3 Logger
The instrument is equipped with an internal logger. The data can be
downloaded to a PC by Hyperterminal if option “HyperTerminal in-
terface” is installed.
The logger can save approx. 1500 data records. Records consists
of: Date, time, alarms, measured value, measured value uncom-
pensated, temperature, flow.
Range: 1 Second to 1 hour
A-96.250.211 / 171011 71
AMI Sodium P
Program List and Explanations
4.3.1 Log Interval: Select a convenient log interval. Consult the table be-
low to estimate the max logging time. When the login buffer is full,
the oldest data record is erased to make room for the newest one.
(circular buffer)
Time 25 min 2h 25 h 5d 10 d 31 d 62 d
4.3.2 Clear Logger: If confirmed with yes, the complete logger data is de-
leted. A new data series is started.
72 A-96.250.211 / 171011
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Program List and Explanations
5 Installation
5.1 Sensors
Sensor type: Display of the used sensor type.(e.g. Sodium)
Temperature: Display of the temperature sensor type. (e.g. NT5K)
Flow: Display of the actual sample flow B/s
5.1.4 Channel switch: For single sample stream select NONE.
If a second sample stream has been installed, select one of the fol-
lowing options, depending on your needs:
None: No channel switch
Auto: Automatic channel switch. The intervall can be defined in
4.1.3*
Input: Channel switch by input contact
Fielbus: Channel switch by fieldbus
5.1.5 Standards: Enter the concentration of the standard calibration.
5.1.5.1 Standard 1: Solution 1 (low concentration).
Do not select concentrations lower than 100 ppb
Range: 0.00 ppb–20 ppm
5.1.5.2 Standard 2: Solution 2 (high concentration).
Select concentration at least 10 times higher than solution 1.
Range: 0.00 ppb–20 ppm
5.2 Signal Outputs
5.2.1 - 5.2.2 Signal Output 1/2: Assign process value, the current loop range
and a function to each signal output.
5.2.1.1-5.2.2.1 Parameter: Assign one of the process values to the signal output.
Available values: Sodium 1/2, pH, Temperature and Sample flow.
5.2.1.2-5.2.2.2 Current Loop: Select the current range of the signal output.
Make sure the connected device works with the same current
range.
Available ranges: 0–20 mA or 4–20 mA
5.2.1.3-5.2.2.3 Function: Define if the signal output is used to transmit a process
value or to drive a control unit. Available functions are:
A-96.250.211 / 171011 73
AMI Sodium P
Program List and Explanations
20
(0 - 20 [mA])
(4 - 20 [mA])
A = linear
B A B = bilinear
10 12
C = Resol. 0.0002
X = Measured value
0/4 X
0.0 0.1 0.2 0.3 0.4 0.5
[mA]
20
(0 - 20 [mA])
(4 - 20 [mA])
10 12
X = Measured value
(logarithmic)
0/4 X
2 4 6
1 10 100 1’000 10’000
0 1 2 3 4
5.2.x.40 Scaling: Enter beginning and end point (Range low & high) of the
linear or logarithmic scale. In addition, the midpoint for the bilinear
scale.
Range: 0.00 ppb–20 ppm
74 A-96.250.211 / 171011
AMI Sodium P
Program List and Explanations
As control Signal outputs can be used for driving control units. We distinguish
output different kinds of controls:
P-controller: The controller action is proportional to the
deviation from the setpoint. The controller is
characterized by the P-Band. In the steady-state, the
setpoint will never be reached. The deviation is called
steady-state error.
Parameters: setpoint, P-Band
PI-controller: The combination of a P-controller with an
I-controller will minimize the steady-state error. If the
reset time is set to zero, the I-controller is switched off.
Parameters: setpoint, P-Band, reset time.
PD-controller: The combination of a P-controller with a
D-controller will minimize the response time to a fast
change of the process value. If the derivative time is set
to zero, the D-controller is switched off.
Parameters: setpoint, P-Band, derivative time.
PID-controller: The combination of a P-, an I - and a D-
controller allows a proper control of the process.
Parameters: setpoint, P-Band, reset time, derivative
time.
Ziegler-Nichols method for the optimization of a PID controller:
Y
A = Response to maximum
control output
B = Tangent on the inflec-
B A tion point.
Parameters:
Setpoint
P-Band
X
a Reset time
Derivative time
L
Xp = 1.2/a X = Time
Tn = 2L
Tv = L/2
The point of intersection of the tangent with the respective axis will
result in the parameters a and L.
Consult the manual of the control unit for connecting and program-
ming details. Choose control upwards or downwards.
A-96.250.211 / 171011 75
AMI Sodium P
Program List and Explanations
76 A-96.250.211 / 171011
AMI Sodium P
Program List and Explanations
A-96.250.211 / 171011 77
AMI Sodium P
Program List and Explanations
ATTENTION
78 A-96.250.211 / 171011
AMI Sodium P
Program List and Explanations
A-96.250.211 / 171011 79
AMI Sodium P
Program List and Explanations
80 A-96.250.211 / 171011
AMI Sodium P
Program List and Explanations
Fieldbus The relay will be switched via the Profibus input. No further param-
eters are needed.
5.3.4 Input: The functions of the relays and signal outputs can be de-
fined depending on the position of the input contact, i.e. no function,
closed or open.
5.3.4.1 Active: Define when the input should be active:
No: Input is never active
When closed: Input is active if the input relay is closed
When open: Input is active if the input relay is open
5.3.4.2 Signal Outputs: Select the operation mode of the signal outputs
when the relay is active:
Continuous: Signal outputs continue to issue the measured val-
ue.
Hold: Signal outputs issue the last valid measured value.
Measurement is interrupted. Errors, except fatal errors, are not is-
sued.
Off: Set to 0 or 4 mA respectively. Errors, except fatal er-
rors, are not issued.
5.3.4.3 Output/Control: (relay or signal output):
Continuous: Controller continues normally.
Hold: Controller continues on the last valid value.
Off: Controller is switched off.
5.3.4.4 Fault:
No: No message is issued and the alarm relay does not
close when input is active.
Yes: Message E024 is issued and alarm relay closes when
input is active.
5.3.4.5 Delay: Time which the instrument waits, after the input is deactivat-
ed, before returning to normal operation.
Range: 0–6‘000 sec
A-96.250.211 / 171011 81
AMI Sodium P
Program List and Explanations
5.4 Miscellaneous
5.4.1 Language: Set the desired language.
Available settings: German / English / French / Spanish / Italian
5.4.2 Set defaults: Reset the instrument to factory default values in three
different ways:
Calibration: Sets calibration values back to
default. All other values are kept in memory.
In parts: Communication parameters are kept in
memory. All other values are set back to default values.
Completely: Sets back all values including
communication parameters.
5.4.3 Load Firmware: Firmware updates should be done by instructed
service personnel only.
5.4.4 Password: Select a password different from 0000 to prevent unau-
thorized access to the menus “Messages”, “Maintenance”, “Opera-
tion” and “Installation”.
Each menu may be protected by a different password.
If you forgot the passwords, contact the closest SWAN representa-
tive.
5.4.5 Sample ID: Identify the process value with any meaning full text,
such as KKS number.
82 A-96.250.211 / 171011
AMI Sodium P
Program List and Explanations
5.5 Interface
Select one of the following communication protocols. Depending on
your selection, different parameters must be defined.
5.5.1 Protocol: Profibus
5.5.20 Device address: Range: 0–126
5.5.30 ID No.: Range: Analyzer; Manufacturer; Multivari-
able
5.5.40 Local operation: Range: Enabled, Disabled
5.5.1 Protocol: Modbus RTU
5.5.21 Device address: Range: 0–126
5.5.31 Baud Rate: Range: 2400–115’200 Baud
5.5.41 Parity: Range: none, even, odd
5.5.1 Protocol: Hyper Terminal
5.5.23 Baud Rate: Range: 2400–115’200 Baud
see separate RS232 Operation Manual for Logger download
5.5.1 Protocol: Webserver:
5.5.24 Device Address: Range: 0–126
see separate Webserver Manual.
A-96.250.211 / 171011 83
AMI Sodium P
Material Safety Data Sheets
Use of Product
Sodium Electrode Etching Solution; mix before use with Catalogue No. A-87.729.010B
Manufacturer/supplier identification
Company: SWAN Analytische Instrumente AG, CH-8340 Hinwil
Tel: +41 44 943 63 00 / Fax: +41 44 943 63 01
2 Hazard identification
Toxic if swallowed. Contact with acids liberates very toxic gas. Irritating to eyes and skin.
3 Composition/information on ingredients
Synonyms
Sodium fluoride: Less than 1g
CAS-No.: 7681-49-4
Molar mass: 41.99g/mol
Molecular formula: NaF
EINECS-No.: 231-667-8
5 Fire-fighting measures
Procedures for cleaning / absorption: Carefully take up dry. Forward for disposal. Clean up
affected area with water
84 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
Industrial hygiene
Immediately change contaminated clothing. Apply skin-protective barrier cream. Wash hands and
face after working with substance.
Form: Solid
Color: White
Odor: Odorless
A-96.250.211 / 171011 85
AMI Sodium P
Material Safety Data Sheets
11 Toxicological information
Acute toxicity
LD50 (oral, rat): 80 mg/kg (Merck results)
Further data
Further hazardous properties cannot be excluded.
12 Ecological information
Ecotoxic effects
The following applies to inorganic fluorides in general: Biological effects: Fish: L. idus LC50
660mg/l; bacteria: Ps. putida toxic as from 231mg/l; algea: Sc. quadricauda toxic as from 249mg/l;
protozoa:E. sulcatum toxic as from 101mg/l; U. parduczi toxic as from 71mg/l; (all values as NaF).
Hazard for drinking water. Daphnia toxicity: Daphnia magna EC50: 76mg/l / 24h
13 Disposal considerations
Product
There are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues
generally count as special waste. The disposal of the latter is regulated in the EC member
countries through corresponding laws and regulations, and in Switzerland also by the cantons. We
recommend that you contact either the authorities in charge or approved waste disposal
companies which will advise you on how to dispose of special waste.
Packaging
Disposal in compliance with official regulations. Handle contaminated packaging in the same way
as the substance itself. If not officially specified differently, non-contaminated packaging may be
treated like household waste or recycled.
86 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
14 Transport information
The transport regulations are cited according to international regulations and in the form applicable
in Germany (GGVS/GGVE). Possible national deviations in other countries are not considered.
15 Regulatory information
Symbol: T Toxic
R-phrases: 25-32-36/38 Toxic if swallowed. Contact with acid liberates
very toxic gas. Irritating to eyes and skin
S-phrases: 22-36-45 Do not breathe dust. Wear suitable protective
clothing In case of accident or if you feel unwell
seek medical advice immediately (show the label
where possible)
EWG-No: 231-667-8 EWG-Label
German regulations
Water pollution class: 1 (slightly polluting substance)
Storage class VCI: 6.1
Data sheet of the chemical
professional association: M005 hydrogen fluoride, hydrofluoric acid and inorganic fluorides
16 Other information
A-96.250.211 / 171011 87
AMI Sodium P
Material Safety Data Sheets
Use of product
Sodium Electrode Etching Solution; mix before use with Catalogue No. A-87.729.010A
Manufacturer/supplier identification
Company: SWAN Analytische Instrumente AG, CH-8340 Hinwil
Tel: +41 44 943 63 00 / Fax: +41 44 943 63 01
2 Hazard identification
3 Composition/information on ingredients
Synonyms
Ethanoic acid (acetic acid): 1%
CAS-No.: 64-19-7
Molar mass: --
Molecular formula: C2H4O2
EINECS-No.: 200-580-7
Hazardous ingredients
Name according to EC Directives: None
After inhalation: --
After skin contact: Wash off with plenty of water
After eye contact: Rinse out with plenty of water with the eyelid held wide open.
Summon eye specialist
After ingestion: Make victim drink a lot of water, summon doctor if feeling unwell
5 Fire-fighting measures
88 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
Procedures for cleaning / absorption: Dilute with water and take-up with liquid-absorbent
material
Environmental-protection measures: Undiluted solution should not be allowed to enter the
sewerage system in bigger quantities
Industrial hygiene
Contact with eye or skin: Wash with plenty of water
Form: Liquid
Color: Colorless
Odor: Like vinegar
Conditions to be avoided: --
Substances to be avoided: --
Hazardous decomposition products: None
A-96.250.211 / 171011 89
AMI Sodium P
Material Safety Data Sheets
11 Toxicological information
Acute toxicity
No toxicological data available.
12 Ecological information
Ecotoxic effects
--
13 Disposal considerations
Product
There are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues
generally count as special waste. The disposal of the latter is regulated in the EC member
countries through corresponding laws and regulations, and in Switzerland also by the cantons. We
recommend that you contact either the authorities in charge or approved waste disposal
companies which will advise you on how to dispose of special waste.
Packaging
Disposal in compliance with official regulations. Handle contaminated packaging in the same way
as the substance itself. If not officially specified differently, non-contaminated packaging may be
treated like household waste or recycled.
14 Transport information
15 Regulatory information
Symbol: --
R-phrases: --
S-phrases: 1 /2, 24/25 Keep locked up and out of the reach of children.
Avoid contact with skin and eyes.
16 Other information
90 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
Manufacturer/supplier identification
Company: SWAN Analytische Instrumente AG, CH-8340 Hinwil
Tel: +41 44 943 63 00 / Fax: +41 44 943 63 01
2 Hazard identification
3 Composition/information on ingredients
Synonyms
diluted sodium chloride solution
Hazardous ingredients
Name according to EC Directives: None
After inhalation: --
After skin contact: Wash off with plenty of water
After eye contact: Rinse out with plenty of water with the eyelid held wide open
After ingestion: --
5 Fire-fighting measures
A-96.250.211 / 171011 91
AMI Sodium P
Material Safety Data Sheets
Industrial hygiene
Contact with eye or skin: Wash with plenty of water
Form: Liquid
Color: Colorless
Odor: Odorless
Conditions to be avoided: --
Substances to be avoided: --
Hazardous decomposition products: None
11 Toxicological information
Acute toxicity
No toxicological data available
Page 2 of
92 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
12 Ecological information
Ecotoxic effects
--
13 Disposal considerations
Product
There are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues
generally count as special waste. The disposal of the latter is regulated in the EC member
countries through corresponding laws and regulations, and in Switzerland also by the cantons. We
recommend that you contact either the authorities in charge or approved waste disposal
companies which will advise you on how to dispose of special waste.
Packaging
Disposal in compliance with official regulations. Handle contaminated packaging in the same way
as the substance itself. If not officially specified differently, non-contaminated packaging may be
treated like household waste or recycled.
14 Transport information
15 Regulatory information
Symbol: --
R-phrases: --
S-phrases: --
16 Other information
A-96.250.211 / 171011 93
AMI Sodium P
Material Safety Data Sheets
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94 A-96.250.211 / 171011
AMI Sodium P
Material Safety Data Sheets
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12. Index
A M
Alarm pH 77 Maintenance Schedule 48
Alarm Relay 102 Message List 69
ATTENTION Symbols 6 Miscellaneous 68, 82, 103
C O
Cable thicknesses 23 On site requirements 20
Cal. History 69 Operating Time 69
Changing parameters 19
Changing value 19 P
Consumables 9 Password 82
Pending Errors 69
D pH Electrode 69
Default Values 102 Power Supply 12, 26
Diagnostics 69 Process pH 70
E Q
Electrical Connections 23 Qualification, Training 4
Electrical Wiring 20
R
I Relay 1/2 78
I/O State 70 Relay Contacts 28, 67
Identification 69
Input 103 S
Instrument Setup 20–21 Safety Data sheets 84
Interface 68, 70, 83 Sample 70
Interface RS232 31 Sample Flow 70, 77
Interface RS485 31 Sample ID 82
Sample inlet 22
L Sample requirements 12
Language 82 Sample Temperature 78
Load Firmware 82 Sensor 102
Logger 102 Sensors 67, 69, 102
Longer Stop of Operation 59 Set defaults 82
Signal Output 102
Signal Outputs 30, 67
Simulation . . . . . . ..... 71
Software Structure . ..... 18
T
Temperature ......... 70
W
WARNING Symbols . ..... 5
Wire . . . . . . . . . . .... 23
13. Notes
SWAN
is represented worldwide by subsidiary companies
and distributors.
SWAN Products
Analytical Instruments for:
Potable Water
Cooling Water
Made in Switzerland