Chemistry Test Examination Marks: 50 Duration: 2 hours

Answer any 25 Questions for 2 marks each: (25 x 2 = 50)

1. Combustion of 0.2000g of vitamin C gives 0.2998g of CO2 and 0.819g of H2O. What is the empirical formula of vitamin C?
2. What volume of 10M HCl and 3M HCl should be mixed to obtain 1L of 6M HCl solution?
3. 4 litres of water are added to 2L of 6 molar HCl solutions. What is the molarity of resulting solution?
4. Calculate the weight of lime (CaO) obtained by heating 2000kg of 95% pure lime stone (CaCO3)
5. What designations are given to the orbitals having (Answer of no (i) is given for example)

(i) n = 2, l = 1 (2p) (ii) n = 2, l = 0 (iii) n = 4, l = 3 (iv) n = 4, l = 2 (v) n = 4, l = 1?

6. Write the electronic configuration of (i) Mn4+, (ii) Fe3+ (iii) Cr2+ and Zn2+ Mention the no. of unpaired electrons.
7. Arrange the electrons represented by the following sets of quantum number in decreasing order of energy.

(a) n = 4, l = 0, m = 0, s = +1/2 (b) n = 3, l = 1, m = 1, s = -1/2 (c) n = 3, l = 2, m = 0, s = +1/2

8. Calculate the uncertainty in the momentum of an electron if it is confined to a linear region of length
9. Give the main features of d-block elements.
10. Explain why cations are smaller and anions are larger in radii than their parent atom?
11. Define ionization enthalpy and electron gain enthalpy?
12. Na+ has higher value of ionization enthalpy than Ne, though both have same electronic configuration.
13. How does electronegativity and non – metallic character related to each other?
14. Draw the resonating structure of NO3-
15. Give the main features of VSEPR Theory.
16. CO2 is linear whereas SO2 is bend – shaped. Give reason.
17. For the molecule,

Why is structure (b) more stable than structure (a)?

18. How would you attribute the structure of PH3 molecule using VSEPR model?
19. Give the relationship between for gases.
20. Show that for an ideal gas Cp- Cv = R
21. What is an extensive and intensive property?
22. With the help of first law of thermodynamics and H = U + pv, prove that, = Q (at constant p)
23. Define surroundings & First Law of Thermodynamics.
24. How many σ and π bonds are present in each of the following molecules? (a) HC≡CC≡CCH3 (b) CH2=C=CHCH3
25. What is the shape of the following molecules: (Any 2) (a) H2 C=O (b) CH3F (c) HC≡N.
26. Categories the following molecules or ions as nucleophile or electrophile: HS-, BF3, C2H5O-, (CH3)3N:, Cl-, CH3C+ = O
27. Write resonance structures of (a)CH3COO- (b) C6H5NH2
28. Draw the two geometrical isomers of, but – 2 – en – 1, 4 dioic acid.
29. How many isomers are possible for mono-substituted and di-substituted benzene?
30. Give the IUPAC of the following –