Latihan Soal 1

Azas Teknik Kimia 2

1. A tank has a volume of 3 m3 and contains 1400 kg of liquid water in equilibrium with its
vapour, which fills the remainder of the tank. The temperature and pressure are 505 K and
2902 kPa respectively (The enthalpy of saturated vapour =2802 kJ/kg, the enthalpy of
saturated liquid = 1000 kJ/kg, the specific volume of saturated vapour = 1.213 × 10–3 m3/kg
and the specific volume of saturated liquid = 68.89 × 10–3 m3/kg). A quantity of 1000 kg
of water at 340 K (H = 280 kJ/kg) is to be pumped into the tank without removing any
steam. How much heat must be added during this process if the pressure and temperature
in the tank are to remain at their initial values?
2. (NIM genap) Sulphur dioxide is circulated as the refrigerant in a small refrigerator. SO 2
gas at a pressure of 5 bar and a temperature of 340 K is to be cooled at a constant volume
of 0.142 m3, to 293 K as part of the refrigeration cycle. Calculate
(a) The heat liberated
(b) The work done by the gas on cooling
(c) The final pressure attained on cooling
(d) The change in enthalpy
Sulphur dioxide may be treated as an ideal gas. The specific heat (J/mol K) is found to vary
with temperature (K) according to
𝐶𝑃 = 25,736 + 5,796 × 10−2 𝑇 − 3,8112 × 10−5 𝑇 2 + 8,612 × 10−9 𝑇 3
3. (NIM ganjil) 10 kg of an equimolar mixture of CO and H2 at 1500 K and 1 bar is cooled at
constant pressure to 350 K. Assuming that the gases are ideal determine the following:
(a) The heat given off during cooling,
(b) The change in internal energy,
(c) The work done on the gas
The specific heats in J/mol K are as follows:
𝐶𝑃,𝐻2 = 29,086 − 8,3694 × 10−4 𝑇 + 2,0130 × 10−6 𝑇 2
𝐶𝑃,𝐶𝑂 = 26,553 + 7,6882 × 10−3 𝑇 − 1,1727 × 10−6 𝑇 2
4. Ammonium sulphate is dried from 3.5% moisture to 0.2% moisture in a counter-current
rotary drier at a rate of 1000 kg/h of product. Atmospheric air at 298 K, 50% humidity will
be heated by passage over steam coils to 363 K before it is admitted into the drier. The air
leaves the drier at 305 K. The solids enter the drier at 298 K and is expected to be discharged
at 333 K. The heat loss from the drier is 40 X 103 kJ/h. Determine the following:
(a) The air circulation rate, kg/h
(b) The heat duty of the drier, kJ/h
The heat capacity of ammonium sulphate is 1.5 kJ/kg K, the heat capacity of dry air is 1.005
kJ/kg K, the specific heat of water vapour is 1.884 kJ/kg k and the latent heat of
vaporization of water at 273 K is 2502 kJ/kg.