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Project Report
CASE STUDY ON
“USE OF PLASTIC WASTE IN ROAD CONSTRUCTION”
This certify that the thesis entitled “USE OF PLASTIC WASTE IN ROAD
CONSTRUCTION” submitted by RISHABH DEV (2002860009005),
MUSKAN RAM (1902860000005), AMIT KUMAR (1902860000001),
PRESHIKA TAMANG (1902860000006) in the partial fulfilment of the
requirements for the award of bachelor degree in Civil Engineering at
“VISHVESHWARYA INSTITUTE OF TECHNOLOGY” is an authentic work
carried out by them under my supervision and guidance.
To the best of knowledge, the matter embodied in the thesis has not
been submitted to any other University/Institute for the award of
any degree or diploma.
Date: .................... Asst. Prof. MR. DEEPAK
DECLARATION
ACKNOWLEDGEMENT
The lack of proper water supply and sanitation services turns the surrounding
into polluted, unhealthy and undignified place to live in and degrades water
quality in lakes, rivers and seas. The poor suffer most as they often depend
directly on these water bodies for their needs. The provision of wastewater
treatment can take control on their lives and make real strides on the path to
sustainable development (SD). The need to improve these services is now
recognized as a critical component of poverty reduction, as well as being
necessary for progress in health, education and environmental sustainability.
Wastewater treatment, water conservation and hygiene play a vital role in
providing healthy living conditions for all in a sustainable way.
The paper presents the importance and the necessity to increase the efficiency
of cleaning process of the residual waste wate form waste industry. There
presented the methods of treatments of wastewaters, in order to find the best
conditions and parameters for treatment process.
LIST OF CONTENT
3. Methodology (21-71)
3.1 Preliminary treatment
3.1.1 Screening
3.1.2 Wastewater treatment through coarse solids reduction
3.1.3 Grit removal system
3.2 Primary treatment
3.2.1 Primary sanitation tank
3.3 Secondary treatment
3.3.1 Phases of secondary treatment (Aeration, Settling, Decanting)
3.3.2 Process of secondary treatment (Activated sludge, Tricking
filter, Rotating biological contractor)
3.4 Tertiary treatment
3.4.1 Need of tertiary treatment
3.4.2 Tertiary treatments (Nitrogen removal, Phosphorus removal,
chlorination)
5. Reference (75)
LIST OF FIGURES
4. Details of screens
9. Settling of sewage
11.Activated sludge
12.Tricking filter
13.Working of trickling filter
16.Working of RBC
CHAPTER 1
INTRODUCTION
1.1 BACKGROUND
Delhi being fast growing city is facing severe problem of untreated sewage.
Since the untreated sewage is discharged into the Yamuna River, the river is
severely polluted. Several efforts are made to depollute the Yamuna. In the
past Hon’ble Supreme Court issued several orders in this regard. As a result,
sewage treatment capacity in Delhi has been augmented. However, there is
always controversy on the utilization of sewage treatment capacity. In order to
get correct picture, a detailed study was conducted during November –
December 2003. The findings of the survey are presented in this report.
Delhi, the capital of India, has a population of over 13.9 million (approx. 14 m).
It has grown by more than 300% since 1971. The population density in the city
is also widely divergent, ranging from 1300 persons sq. km to 70,000 persons
per sq.km. The population growth pattern of Delhi is the single most important
factor that affects the level quantity of water supply and sewerage services
available to its habitants. Delhi Jal Board (DJB) is the authority responsible for
planning, designing and execution of water supply and wastewater
management facilities within its jurisdiction in the National Capital Territory of
Delhi. About 40% of the population of Delhi (J.J.Clusters, MCA area,
unauthorised colonies and rural villages) live in un-severed areas. Presently
about 650mgd (2955 mid) water is distributed by (DJB) in Delhi. Additional
90mgd water supply is estimated from ground water. In future the demand the
demand is projected by DJB as 845 mgd (3841 mid) by the year 2006 and 950
mgd (4319 mid) in 2011. In absence of any additional source of water, no
further significant increase excepted up to 2021. The population that has been
projected by Delhi Development Authority (DDA) by 2021 is 23 million.
Earth is the only planet where water exists in all its three phases solid, liquid
and gas. Availability and absence of water influence the distribution and
abundance of human society, plants vegetation’s animals as well as the
atmosphere of the earth. With the increasing population and development
activities the completing demand for water potable, domestic use, irrigation
power generation and industrial activities are exerting enormous pressure on
our water resources as utilization of water has also been consequently
increasing very fast.
97% sea is saline, 2% freezed in glaciers poles and high mountains only 1% is
available for the consumption of life forms in this earth. The precious balance
between growing demand and supplies can be overcome by recycling and
reuse of waste water as it can be used for multiple uses one after the other,
thereby reducing demand for fresh water. Treatment of domestic sewage and
subsequent utilization of treated sewage for irrigation can prevent pollution of
water bodies, reduce the demand for fresh water in irrigation, resulting huge
saving in terms of nutritional value of sewage in irrigation. From the irrigated
land surface, the percolation will also recharge the ground water by low T.D.S.
water and will also increase ground water level.
The waste water especially sewage water is rich source of organic
biodegradable pollution, bacteria, viruses, pathogens marshy gases inorganic
grit and floating material. We can provide total water management solution by
treating water for potable, waste water for reuse other than
domestic/drinking, swimming and recreational.
Wastewater treatment is closely related to the standards and expectations set
for the effluent quality. Wastewater treatment processes are designed to
achieve improvements in the quality of the wastewater. The various treatment
processes may reduce:
1. Suspended Solids (physical particles that can clog rivers or channels as
they settle under gravity).
2. Biodegradable organics (e.g., BOD) which can serve as food for
microorganisms in the receiving body. Microorganisms combine this
matter with oxygen from the water to yield the energy they need to
thrive and multiply; unfortunately, this oxygen is also needed by fish and
other organisms in the river. Heavy organic pollution can lead to dead
zones where no fish can be found sudden releases of heavy organic
loads can lead to dramatic fish skills.
It is really very strange that Delhi, which is India’s national capital, one of
the fastest growing metropolitan cities of the country, does not have a
proper sewage disposal and drainage system. Delhi is facing severe
problem of untreated sewage such that only about 55% homes in Delhi
are linked to a proper sewerage and the rest of the 45% wastes grows in
to the Yamuna River directly.
In fact, it is really very sad to say that the faces of the functional
commodes of the modern bathrooms in the urban Delhi are contributing
to the pollution of Yamuna. In spite of the fact that a number of plans
and programmes have been implemented by the government for
sewerage and wastewater treatment. These are not being able to keep
pace with the growing generation of wastewater. While there are
certain sections like developed and organised areas of Delhi which are
given wastewater treatment services to a certain extent. The slums or
the unorganised areas are not provided any sewage treatment, the
reason being they are not within the jurisdiction of the Delhi Jal Board
(DJB).
OTHER PROBLEMS
Lack of infrastructure
Weak financial base
Corruption
No co-ordinating body
Lack of political will
Lack of accountability etc.
1.3 OBJECTIVE
CHAPTER 2
LITERATURE REVIEW
The first wastewater treatment attempt was releasing the pollutants into
rivers, which where the sources of most water supplies. In 1971 this problem
drew the public attention to itself when the future king Edward VII caught
typhoid fever while staying at a house in Yorkshire. The reason was traced to
bad drainage and his illness resulted in immediate efforts to improve the
prevailing sanitary systems and so by the 19th century large cities realized that
they must reduce the water pollution which they release into the environment.
Sewage systems began to be designed and created after Louis Pasteur and its
colleagues proved that the bacteria which lived in sewers could cause
infectious diseases. From the early 1990s, sewer systems started to grow but
as cities started to develop, less spaces were available for disposal and
filtration, furthermore the amount of wastewater increased rapidly because of
the population growth. This all lead to the change in dimension of treatment
facilities today and former designs proved to be insufficient for today’s needs
in society. Overall (NIRAJAS and TOPARE) introduced three main objectives in
sewage/water treatment: ( i ) The evacuation of postponed particles and
floatable materials (ii) the treatment of organic elements in wastewater BOD
removal (iii) the removal of micro-organisms which may be the cause of
dangerous diseases. These objectives have been continued into the early
pollutant removal and reduction processes only in better systematic methods.
While the older treatment goals are still valid, new ways of treatment have
invented and developed significantly and more objectives have been into the
water treatment science.
Using Alum:
Using lime:
2.4 Disposal/Reuse
Disposal or reuse are the final procedures in sewage/wastewater treatment
which should be designed in a way which pleases economic and scientific goals
and procedures. There are two main groups of disposal systems which differ in
their use in terms of where they are situated and how they are to function; on-
site and off-site disposal/reuse systems.
On-site system is being used in an area which has minimal pollution production
and also where there are only a couple of houses in a wide geometric range. In
this case this disposal system is even more beneficial in terms of economics, in
comparison to using a system for collecting, transferring and treating the
wastewater.
In a public system, wastes are being collected in an area and then carried to
other locations through transporting systems for final disposal. In addition,
public disposal systems can be very useful in critical situations like flooding or
storms by containing the water in the of-site facilities or carrying out the huge
proportion of water.
CHAPTER 3
METHODOLOGY
Wastewater is not sewage. All the water used in the home that goes down the
drains or into the sewage collection system is wastewater. This includes water
from bath, sinks, dishwashers, toilet, and washing machine. Small businesses
and industries often contribute large amounts of wastewater to sewage
collection systems others operate their own wastewater treatment systems. In
combined municipal sewage systems water from storm drains is also added to
the municipal wastewater stream. The average American contributes 265-568
litres of wastewater each day. Wastewater is about 99% water by weight and is
generally referred to as influent as it enters the wastewater treatment facility.
Domestic wastewater is wastewater that comes primarily from individuals, and
does not generally include industrial or agricultural wastewater.
At wastewater treatment plants, this flow is treated before it is allowed to be
returned to the environment, lakes or streams. There are no holidays for
wastewater treatment and most plants operate 24 hours per day every day of
the week. Wastewater treatment plants operate at a critical point of the water
cycle, helping nature defend water from excessive pollution. Most treatment
plants have primary treatment and secondary treatment.
Wastewater treatment is a process to convert wastewater into an effluent that
can be either returned to the water cycle with minimal environment issues or
reused. The latter is called water reclamation and implies avoidance of disposal
by use of treated wastewater effluent for various purposes. Treatment means
removing impurities from water being treated; and some methods of
treatment are applicable to both water and wastewater. The physical
infrastructure used for wastewater treatment is called wastewater treatment
plant.
The treatment of wastewater belongs to the overarching field of public works
environmental with the management of human waste, solid waste, sewage
treatment, stormwater management and water treatment by products from
wastewater treatment plants such as screenings, grit and sewage sludge may
also be treated in a wastewater treatment plant. If the wastewater is
predominantly from municipal sources, it is called sewage and treatment is
called sewage treatment. Satisfactory disposal of wastewater whether by
surface, subsurface methods or dilution is dependent on its treatment prior to
disposal. Adequate treatment is necessary to prevent contamination of
receiving waters to a degree which might interfere with their best or intended
use whether it be for water supply, recreation or any other required purpose.
Wastewater treatment consists of applying known technology to improve or
upgrade the quality of wastewater. Usually, wastewater treatment will involve
collecting the wastewater in a central, segregated location and subjecting the
wastewater to treatment processes. Most often since large volumes of
wastewater are involved treatment processes are carried out on continuously
flowing wastewaters rather than as batch or a series of periodic treatment
processes in which treatment is carried out on parcels or batches of
wastewaters. While most wastewater treatment processes are continuous
flow, certain operations such as vacuum filtration, involving as it does, storage
of sludge, the addition of chemicals, filtration and removal or disposal of the
treated sludge, are routinely handled as periodic batch operations.
Wastewater treatment however can also be organised or categorized by the
nature of the treatment process operation being used; for example, physical,
chemical or biological. Examples of these treatment step are shown below. A
complete treatment system may consist of the application of a number of
physical, chemical and biological processes to the wastewater.
Some Physical, Chemical and Biological Wastewater treatment methods:
PHYSICAL
Sedimentation
Screening
Aeration
Filtration
Flotation and skimming
Degasification
Equalization
CHEMICAL
Chlorination
Ozonation
Neutralisation
Coagulation
Absorption
Ion exchange
BIOLOGICAL
AEROBIC
Activated sludge treatment methods
Trickling filtration
Oxidation ponds
Lagoons
Aerobic digestion
ANAEROIC
Anaerobic digestion
Septic tanks
Lagoons
Physical methods
Chemical treatment
It consists of using some chemical reactions to improve the water
quality. Probably the most commonly used chemical process is
chlorination, chlorine, a strong oxidizing chemical is used to kill bacteria
and to slow down the rate of decomposition of the wastewater.
Bacterial kill is achieved when vital biological processes are affected by
the chlorine. Another strong oxidizing agent that has also been used as
an oxidizing disinfectant is ozone.
A chemical process commonly used in many industrial wastewater
treatment operations is neutralization. Neutralization consists of
addition of acid or base to adjust pH levels back to neutrality. Since lime
is a base, it is sometimes used in neutralization of acid wastes.
Coagulation consists of the addition of a chemical that, through a
chemical reaction, forms an insoluble and product that serves to
Remove substances from the wastewater. Polyvalent metals are
commonly used as coagulating chemicals in wastewater treatment and
typical coagulants would include lime, certain iron containing
compounds and alum.
Certain process may actually be physical or chemical in nature. The use
of activated carbon to adsorb or remove organics, for example, involves
both chemical and physical process. Processes such as ion exchange
which involves exchanging certain ions for others are not used to any
great extent in wastewater treatment.
Coarse screens
Fine screens
Micro screens
3. Grinders:
Grinders consists of 2 sets of counter rotating, intermeshing cutters that trap
and shear wastewater solids into a consistent particle size, typically 6mm. The
cutters are mounted on a 2drive shaft with intermediate spacers. The shafts
counter rotates at different speeds to clean the cutters. The chopping action of
the grinder reduces the formation of rag balls and rag ropes. Wastewater that
contains large quantities of rags a solid, such as prison wastewater, utilize
grinder downstream from course screens to help prevent frequent jamming
and excessive wear. High speed grinders typically referred to as a fiammer
mills, receive screened materials from base screen. The material is pulverised
by a speed high rotation assembly that wets materials passing through the
unit.
the tank where a cross collector (also chain and flight) moves the sludge into a
deep hopper. From here, it is removed by new centrifugal pumps to a sludge
sump.
Scum, which rises to the surface of the tanks, is directed by fan-shaped water
jets to the inlet end of the tank. Here, it is lifted over a wall and into a trough
by rotating scum from collectors and carried into the sludge sump. The sludge
and scum from the primary sedimentation tanks are pump to the gravity
thickeners. After the sludge has been thickened in the gravity thickeners., it is
sent to the gravity belt thickeners for further thickening before being sent to
the digesters. At this stage, over 70 percent of the suspended solids have been
separated from the liquid waste stream with 40 percent of the BOD removed.
After separation in the primary sedimentation tanks, the liquid stream is
conveyed via the inter-stage pump station at a rate of up to nine cubic meters
per second to the reactor/clarifiers for secondary treatment.
. Zone-settling behaviour
As the concentration of particles in a suspension is increased, a point is
reached where particles are so close together that they no longer settle
independently of one another and the velocity fields of the fluid displaced by
adjacent particles, overlap. There is also a net upward flow of liquid displaced
by settled particles.
This results in a reduced particles-settling velocity and the effect is known as
hindered settling.
There is a common case for hindered settling occurs. The whole suspension
tends to settle as a ‘blanket’ due to its extremely high particle concentration.
This is known as zone settling because it is easy to make a distinction between
several different zones which separated by concentration discontinuities Fig 3
represents a typical batch-settled characteristics. There is a clear interface near
the top of the column would be formed to separating the settling sludge mass
from the clarified supernatant as long as leaving such as suspension to stand in
a settling column. As the suspension settles, this interface will move down at
the same speed. At the same time, there is an interface near the bottom
between that settled suspension is complete, the bottom interface would
move upwards and meet the top interface which moves downwards.
. Compression Settling
The settling particles can contact each other arise when approaching the
floor of the sedimentation tanks at very high particle concentration. So that
further settling will only occur in adjust matrix as the sedimentation rate
decreasing. This is can be illustrated by the lower region of the zone-settling
diagram (Figure 3). In compression zone, the settled solids are compressed by
gravity (the weight of solids), as the settled solids are compressed under the
weight of overlying solids, and water is squeezed out while the space gets
smaller.
There are most commonly used for primary sedimentation, since they
Careful design of the inlet stelling well is needed to active a stable radial
flow pattern without causing excessive turbulence in the vicinity of the
central sludge hopper.
The weir length aroid the perimeter of the tank is usually sufficient to
give a safes factory weir loading rate at maximum flow, but at low flows,
very low flow depths may result.
To overcome the sensitivity of these tanks to slight errors in weir level
and wind effects, it is common to provide v-much wares.
Sludge removal is affected by means of a rotary sludge scrapper who
moves the sludge into a central hopper, from which it is with drown.
Scum removal is carried out by surface skimming board attached to the
sludge scrapper mechanism and positioned so that scum is moved
towards a collecting hopper at the surface.
3. Up Flow Tanks:
Up flow tanks, usually square in plan and with deep hopper bottoms are
common in small treatment plants.
Their main advantages is that sludge removal is carried out entirely by
activity and no mechanical parts are required for cleaning them.
The steeply sloping sides usually to horizontal concentrate the sludge at
the bottom of the hopper.
Weir loading rate is a problem only at low flows. So that v-match weirs
are desirable.
The requires up flow pattern is maintained by weir troughs.
Any practical with a velocity lower than Vp = Q/A will not remove.
After settling, the clear wastewater is decanted from the tank into an
automatically lowered centrally located trough. This Secondary treated
effluent is piped into the Equalisation Basin for holding before its final tertiary
treatment. Secondary Alum dosing can be used at this point for removal of
phosphorus.
Once wastewater has gone through the Primary treatment stage. The Effluent
will undergo a secondary treatment in order to remove both small suspended
solids and BODs (five-day biochemical oxygen demand) that pass through the
primary treatment stage. All secondary treatments systems use a biological
process to break down organic matter. Microorganisms are introduced to the
wastewater and consume the organic matter, oxygen delivered to the system
ensuring microorganism survival. Oxygen delivery differs among the various
systems. This biological process occurs naturally in nature, but is accelerated in
secondary treatments system. Typically, 85% of BOD and suspended solids are
removed during
2.Settling
The Aerators switch off and the effluent becomes still. Having no oxygen
supply, the microorganisms use carbon in the organic matter as a food source,
converting nitrates to nitrogen gas which is released to the atmosphere (“De-
nitrification). During this phase the solids separate and settle from the liquid
giving clarification to the upper part of the tank.
Fig.9 settling of sewage
Some treatment processes, denitrification often impairs the settling of the floc
causing poor quality effluent in many suspended aeration plants. Overflow
from the activated sludge mixing chamber is sent to a secondary clarifier
where the suspended biological floc settles out while the treated water moves
into tertiary treatment or disinfection. Settled floc is returned to the mixing
basin to continue growing in primary effluent. Like most ecosystems,
population changes among activated sludge biota can reduce treatment
efficiency. Nocardia, a floating brown foam sometimes misidentified as sewage
fungus, is the best known of many different fungi and protists that can
overpopulates the floc and cause process upsets. Elevated concentrations of
toxic wastes including pesticides, industrial metal plating waste, or extreme
pH, can kill the biota of an activated sludge reactor ecosystem.
Fig.11 Activated sludge
Activated sludge
Trickling filter
Rotating Biological Contractor (RBC)
Oxidation ponds
Operational and initial costs along with space are their factors that will often
determine which technique is appropriate. Space is influenced by population
size and cost of land. For example, oxidation ponds require large areas of land
is costly or needed for housing oxidation ponds are not a likely option.
The activated sludge process is a process for treating sewage and industries
wastewater using air and a biological floc composed of bacteria and protozoa.
It is a common suspended-growth method of secondary treatment. Activated
sludge plants encompass a variety of mechanisms and processes using
dissolved oxygen to promote growth of biological floc that substantially
removes organic materials Biological floc is an ecosystem of living biota
subsisting on nutrient from the inflowing primary . Nitrogenous dissolved
solids are similarly converted to biological floc or oxidized by the floc to
nitrities, nitrates , and in some processes , to nitrogen gas through
denitrification. While denitrification is encouraged in
The bio-film develops in a trickling filter may become several millimetres thick
and is typically a gelatinous matrix that contains many species of bacteria,
cillates and amoeboid protozoa , annelids , round worms and insect larvae and
many other micro fauna. This is very different from many other bio-films which
may be less than 1 mm thick, Within the thickness of the bio-film both aerobic
and anaerobic zones can exist supporting both oxidative and reductive
biological processes. At certain times of year, especially in the spring rapid
growth of organisms in the film cause the film to be too thick and it may slough
off in patches leading to the ‘spring slough’.
Aeration tank where air (or oxygen) is injected in the mixed liquor.
Settling tank (usually referred to as “final clarifier” or ‘secondary settled
tank”) to allow the biological flocs (the sludge blanket) to settle thus
separating the biological sludge from the clear treated water.
The space required for a sewage treatment plant can be reduced by using a
membrane bioreactor to remove some wastewater from the mixed liquor prior
to treatment. This results in a more concentrated waste product that can then
be treated using the activated sludge process.
Many sewage treatment plants use axial flow pumps to transfer nitrified mixed
liquor from the aeration zone to the anoxic zone for denitrification. These
pumps are often referred to as internal mixed liquor recycle mixer in the
anoxic zones in order to achieve denitrification.
2.Sludge production
Activated sludge is also the name given to the active biological material
produced by activated sludge plants. Excess sludge is called “surplus activated
sludge” or “waste activated sludge” food supplied in the wastewater in
balance. This sewage sludge is usually mixed with primary Sludge from the
primary clarifies and undergoes further sludge treatment, for example by
anaerobic digestion, followed by thickening, dewatering, composting and land
application.
The amount of sewage sludge produced from the activated sludge process is
directly proportional to the amount of wastewater treated. The total sludge
production consists of the sum of primary sludge from the primary
sedimentation tanks as well as waste activated sludge from the bioreactors.
The activated sludge process produces about 70-100 kg/ML of waste activated
sludge (that is kg of dry solids produced per ML of wastewater treated; one
mega litre (ML) is 103m3 ). A value of 80 kg/ML is regarded as being typical. In
addition, about 110-170 kg/ML of primary sludge is produced in the primary
sedimentation tanks which most but not all of the activated sludge process
configurations use.
3.3.2.2. TRICKLING FILTER
The terms trickle filter, trickling bio filter, bio filter, biological filter and
biological trickling filter are often used to refer to a trickling filler. A trickling
filter is a type of wastewater treatment system first used by Dibben and
Clowes. It consists of a fixed bed of rocks, lava, coke, gravel, slag, polyurethane
foam, sphagnum peatmoss, ceramic, or plastic media over which sewage or
other wastewater flows downwards and causes a layer of microbial slime (bio-
film) to grow, covering the bed of media.
Aerobic
Conditions are maintained by splashing, diffusion, and either by forced air
flowing through the bed or natural convection of air if the filter medium is
porous. These systems have also been described as roughing filters,
intermittent filters, packed media bed filters, alternatives septic systems,
percolating filters, attached growth processes, and fixed film processes.
Typically, sewage flow enters at a high level and flows through the primary
settlement tank. The supernatant from the tank flows into a dosing device
Fig.13 Working trickling filter
often a tipping bucket which delivers flow to the arms of the filter. The lush of
water flows through the arms and exit through a series of holes pointing at an
angle downwards. This propels the arms around distributing the liquid evenly
over the surface of the filter media. Most are uncovered (unlike the
accompanying diagram) and freely ventilated to the atmosphere.
System can be configured for single pass use where the treated water is
applied to the trickling filter once before being disposed of, or for multi-pass
use where a portion of treated water is cycled back and retreated via a closed
loop. Multi-pass system results in higher quality and assist in removal of total
nitrogen (NT) levels by promoting nitrification in the aerobic media bed and
denitrification in the anaerobic septic tank. Some systems use the filters in two
banks operated in series so that the waste water has two passes through a
filter with sedimentation stage between the two passes. Every few days the
filters are switched round to balance the load. This method of treatment can
improve nitrification and de-nitrification since much of the carbonaceous
oxidative material is removed on the first pass through the filters.
The removal of pollutants from the wastewater streams involves both
absorption and adsorption of organic compounds and some inorganic species
such as nitrites and nitrates ion by the layer of microbial bio-film. The filter
media is typically chosen to provide a very high surface area to volume. Typical
material is often porous and have considerable internal surface area in
addition to the external surface of the medium. Passage of the wastewater
over the media provides dissolved oxygen which the bio-film requires for the
biochemical oxidation of the organic compounds and releases CO2 gas, Water
and other oxidised products. As the bio-film thickens, it eventually slough off
into liquid flow and subsequently forms part of secondary sludge. Typically, a
trickling filter is followed by a clarifier or sedimentation tank for the separation
and removal of the sloughed bio-film. Other filters utilising higher density
media such as sand, foam and forced air blowers and backwashing or an
enclosed anaerobic environment.
In acidic solution the major species are cl2 and hocl where as in alkaline
solution effectively only clo- is present. Very small concentration of
clo2-, clo3-,clo4- are also found.