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Digital Pace (ADV) DT. 13-11-2022 - Answers & Solution
Digital Pace (ADV) DT. 13-11-2022 - Answers & Solution
Digital Pace (ADV) DT. 13-11-2022 - Answers & Solution
Answer Key
1. (A)
2. (B)
3. (B)
4. (D)
5. (D)
6. (A)
7. (C)
8. (D)
9. (D)
10. (A)
11. (A)
12. (B)
13. (B)
14. (B)
15. (D)
16. (A)
17. (A)
18. (B)
19. (D)
20. (C)
CENTERS: MUMBAI / DELHI / PUNE / NASHIK / AKOLA / GOA / JALGAON / BOKARO / AMARAVATI / DUBAI / DHULE # 3
MUMBAI / DELHI-NCR / PUNE / NASHIK / AKOLA / GOA / JALGOAN / BOKARO / AMRAVATI / DUBAI / DHULE
IIT – JEE: 2024 TW TEST (ADV) DATE: 13/11/22
TOPIC: MOLE CONCEPT
SOLUTION
21. (B)
3
No. of moles of atom
1
No. of atoms 3N A
1
No. of deuterium atom 3N A
6001
1
No. of neutron 3 6.02 1023
6001
3.011020
22. (B)
4.4
No. of moles of C2O42 0.05
88
No. of ions = 0.05 NA
No. of electrons in 1 ion = 12 + 32 + 2 = 46
No. of electrons in 0.05 NA ions = 46 0.05 NA = 2.3 NA
23. (D)
1
No. of moles of O2 in 1 gm dioxygen
32
1
No. of molecules of O2 NA
32
2N A N A
No. of atoms of O
32 16
1 gm atomic oxygen
1
moles of O atoms
16
N
A atoms of O
16
1 gm of Ozone
1
moles of O3
48
1
N A molecules of O3
48
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3 N
N A atoms of O = A
48 16
24. (A)
Volume of sea water 1.4 1021 L
1.4 1024 ml
Wt. of sea water 1.4 1024 gm
1.4 1021 kg
Wt. of chlorine 19 1.4 1021 gm
19 1.4 1021
No. of moles of chlorine atoms 7.5 1020
35.5
25. (A)
2KClO3 2KCl + 3O2
2 moles 3 moles
26. (D)
95
Wt. of pure NaCl 250 gm 237.5 gm
100
237.5
No. of moles of NaCl
58.5
2NaCl Na2SO4
237.5 237.5 1
mole mole
58.5 58.5 2
237.5 1
Wt. of Na2SO4 142 gm 288.24 gm
58.5 2
100
Wt. of impure sample 288.24 320.3 gm
90
27. (A)
CO & CO2
1 a moles a moles
2NaOH + CO2 Na2CO3 + H2O
2a moles a moles
20
2a
40
1
a moles
4
1 3
n CO 1 moles
4 4
2CO + O2 CO2
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3 3
mole mole
4 4
CO2 + 2NaOH Na2CO3 + H2O
3 3
mole 2mole
4 4
3
mole
2
3
40 gm
2
60 gm
28. (A)
[Cl ] 0.6 M
0.8 V 3 0.2 50 2
V 50
0.6V 30 2.4V 20
1.8V 10
100
V 5.56 ml
18
29. (A)
Wt. of HCl gas = x gm
x
100 40
50 x
100
x gm
3
100 250
Wt. of solution 50 gm
3 3
Volume of solution = 75 ml
250 3
Density 1.11 gm ml
75
30. (C)
Assume 100 gm solution
w
% 20
w
Wt. of glucose = 20 gm
w
% 25
v
20
100 25
v
v 80 ml
100
Density 1.25 gm ml
800
31. (C)
MnO & MnO2
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200 100
mole mole
3 3
200 100
No. of moles of Mn 100
3 3
100 55
%Mn 100 72.05
200 100
71 87
3 3
32. (D)
C3H8 + 5O2 3CO2 + 4H2O
0.15 mole
4
n H2O 0.15 0.2 mole
3
No. of molecules of H2O formed 0.2 6 1023
0.2 6 1023
No. of drops of water formed 70
1.7 1021
33. (D)
C H
Mass Ratio 8 : 1
8
Moles ratio : 1
12
2 : 3
EF C2 H3Ox
16x
10.6 100
24 3 16 x
x 0.2
EF C2 H3O0.2 or C10 H15O
34. (C)
A + 2B I
Initial 5 6 0
Final 5–3=2 6–6=0 3
I + C B + D
3 moles 3 moles 3 moles
Now 3 moles of B again react with unreacted A.
A + 2B I
Initial 2 3 0
Final 2 – 1.5 = 0.05 3–3=0 1.5
I + C B + D
1.5 moles 1.5 moles 1.5 moles
Now again B reacts with unreacted A.
A + 2B I
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Initial 0.5 1.5 0
Final 0.5 – 0.5 = 0 1.5 – 1 = 0.5 0.5
I + C B + D
0.5 moles 0.5 moles 0.5 moles
Total moles of D formed = 3 + 1.5 + 0.5 = 5 moles
35. (B)
98 98
Final volume V 10V 11V
100 100
2.2V 220 20
Molarity 0.204
98 11 98 98
11V
100
36. (D)
No. of moles of glucose = a
Wt. of glucose = 180a gm
Wt. of water = 1000 – 180a gm
a
1 1000
1000 180a
1000
1000 180a 1000a a
1180
Final wt. of water = 1000 – 180a + 4000 gm
1000
5000 180 gm
1100
4847 gm
4.847 kg
1000 1180
Final molality 0.175 m
4.847
37. (B)
Atomic mass of M = a
M + 3F2 MF6
0.250 gm 0.250
mole
0.250 a
moles
a
0.250
a 114 0.547
a
0.250a 114 0.250 0.547a
28.5
a 95.96
0.297
38. (B)
total mass
Average molecular mass
total moles
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100
2.10
90 10
2 4
39. (A)
CH4 & C2 H 6
a mole a mole
total no, of moles = 2a
total volume 22.4 2a
total wt. 16 a 30 a 46a
46a
density 1.03 gm
22.4 2a
40. (C)
2 103
Initial no. of moles of Ca atoms
40
1.2 1019
Moles of Ca atoms removed
6 1023
No. of moles of Ca atom left
2 103 1.2 1019
40 6 1023
0.5 104 0.2 104 3105
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MUMBAI / DELHI-NCR / PUNE / NASHIK / AKOLA / GOA / JALGOAN / BOKARO / AMRAVATI / DUBAI / DHULE
IIT – JEE: 2024 TW TEST (ADV) DATE: 13/11/22
TOPIC: QUADRATIC EQUATION
Solution
41. (C)
In order that the quadratic equation may have two roots with opposite signs, it must have real roots
with their product negative, i.e. if the discriminant,
4(a2 1)2 12(a2 3a 2) 0
1 2
and (a 3a 2) 0
3
Both of these conditions get satisfied if a2 3a 2 0
i.e., if (a 1)(a 2) 0 or if 1 a 2 .
42. (C)
If D is the discriminant of the equation x 2 4qx 2q 2 r 0 , then
D 16q 2 4(2q 2 r ) 8q 2 4r
822 4(4 4 ) 4(2 2 )2 0
Hence the equation x 2 4qx 2q 2 r 0 has always two real roots i.e. both real roots.
43. (C)
We know that ax2 bx c 0 if a 0 and b2 4ac 0 .
1 mx 2 x 1
mx 1 0 0
x x
mx2 x 1 0 and x 0
Now mx2 x 1 0 if m 0 and 1 4m 0
1
or if m 0 and m
4
1
Thus the minimum value of m is .
4
44. (A)
p p
Let roots of lx2 nx n 0 are and , given that .....(i)
q q
n n
and
l l
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p q n
Now
q p l
( ) ( )
0.
45. (D)
Let the correct equation be x2 px q 0 .....(i)
Roots found by the first student are 6 and 2.
Their sum 6 2 8 p
and the product 6 2 12 q
So, (i) reduces to x2 8x 12 0 .....(ii)
But he has committed mistake only in the coefficient of x i.e. in p. So q remains equal to 12 while p
in the actual equation has been taken wrongly by the first student.
Now roots found by the second student are 2 and –9.
Their sum 9 2 7 p and the product
= – 9×2 = –18 =q i.e., p =7 and q 18 in (i)
But he has committed mistake only in the constant term i.e. in q. So p remains equal to 7.
Hence correct equation from (i) is x2 7 x 12 0
( x 4)( x 3) 0 x 4, 3 .
46. (A)
p, q
If the given roots be A and B, then
A ( )2 ( )(2 2 )
( p 2 4q) p( p 2 q) p[ p 4 5 p 2q 4q 2 ]
B 22 ( ) q2 p
S A B p[ p4 5 p2q 5q 2 ]
P p 2 q 2 ( p 4 5 p 2 q 4q 2 )
The required equation is x2 Sx P 0 .
Trick : Check by putting p 3, q 2 so that 2, 1.
Now roots of required equation will be 21,12 .
Therefore S 33 and P 252 which is given by the option (A).
47. (D)
Let the correct equation be ax2 bx c 0 and the correct roots and .
Taking c wrong, the roots are 3 and 2.
3 2 5 .....(i)
Also a 1 and c 6
c / a 6 .....(ii)
Solving (i) and (ii), the correct roots are 6 and – 1.
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48. (A)
Let the roots are and
so, 3 3 ( )3 3( )
(a 2)3 3(a 3)(a 2)
a3 9a2 27a 26 (a 3)3 1
It assumes the least value, if (a 3)3 0 .
a 3.
49. (A)
As the coefficients are real and one root is 2 i, therefore, another root is 2 i (conjugate of 2 i ).
Let the third root be then sum of the roots 2 i 2 i
(5) 4 1
So, the other two roots are 2 i and 1.
50. (C)
We have x2 px (1 p) 0 …..(i)
(1 p)2 p(1 p) (1 p) 0
(1 p)[1 p p 1] 0 ; p 1
Put p 1 in equation (i),
x2 x 0 x( x 1) 0 i.e., x 0 1 .
51. (A)
( x 1)( x 3)
y
( x 2)
Here x cannot be 2.
Either both N r and D r are positive
x 1, x 3 and x 2 x 3 .....(i)
Or N r is negative and D r is negative
x 1 and x 2 1 x 2 …..(ii)
From (i) and (ii), 1 x 2 or x 3 .
52. (D)
Domain of definition of the function y x( x 3) is x( x 3) 0 i.e. x 0 or x 3 .....(i)
Given equation can be re-written as
9 | x |2 19 | x | 2 0
(9 | x | 1)(| x | 2) 0
| x | 2 or | x | 1/ 9
Solution of the given equation are 2, 1/ 9
In the domain (i), the required solutions are 2, 1/ 9 .
53. (C)
Given that x2 2ax a2 is a factor of
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x3 3 px 2q 0
Let x3 3 px 2q ( x2 2ax a 2 )( x ) ,
where is a constant.
Then equating the coefficients of like powers of x on both sides,
x3 3 px 2q x3 (2a ) x 2 (a 2 2a) x a 2
2a 0 2a ….. (i)
and 3 p a 2 2a …..(ii)
and 2q a2 …..(iii)
Put the value of in (iii),
2q 2a3 q a3 ..…(iv)
Put the value of in (ii),
3 p a 2 2a(2a) a 2 4a 2 3a 2
3 p 3a2 p a2 p (q)2/3 p3 q2 .
54. (A)
Roots , lie in the interval (0,1)( ) , so
(i) 0, (ii) f (0) 0, f (1) 0 , (iii) 0 2
Here 3 2 1 for every k
Hence no such k exist.
55. (A)
56. (A)
x2 x 1
From k 2
x x 1
We have x2 (k 1) x(k 1) k 1 0
As given, x is real (k 1)2 4(k 1)2 0
3k 2 10k 3 0
Which is possible only when the value of k lies between the roots of the equation 3k 2 10k 3 0
1 1
That is, when k 3 {Since roots are and 3}
3 3
57. (A)
x 1 1 1 ..... to
We have x 1 x
x2 1 x x2 x 1 0
1 1 4 1 5
x
2 2
1 5
As x 0 , we get x
2
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58. (C)
Given equations are 2x2 3x 5 0 and x2 2x 3 0 have a common root if
x2 x 1
x 2 , x or 1, 0 .
1
59. (A)
b c
As given, sin cos , sin cos
a a
To eliminate , we have
1 sin 2 cos2 (sin cos )2 2sin cos
b 2 2c
a 2 b 2 2ac 0
a2 a
60. (C)
Let 1 and the other root is , then product of roots 1.
c ( a b) c ( a b)
a(b c) a (b c)
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