woo‘ouljuoprogdur mayan: http://www.mpboardonline.com Serial Number Roll Noy... Total Total Printed Time : Maximum Questions : 18 | Pages: 16 | 3 Hours | Marks : 70 Higher Secondary Examination (Regular) - 2019 THETA a] CHEMISTRY (Hindi & Engli h Versions) Pia: @ (ii) Gil) (iv) wv) (vi) (ii) wh wet aPrard e 1 wa wre 1a 4 aH argh vet ze 1 He sis 2071 we wri 5 A 7 ae, Tele WET 2 aH ar SI (sre AT 30 grea) Wet BAI 8 S 10 aa, els us 3 sie ar 1 (ex dT 75 ge) WaT wa 1 TS ce, wees wet 4 iw ar FI (gree MT 120 ate) WT wie 16S 18 TH, Tela GETS ies wt Bi (rex sr 150 ge) We wre 5 a 18 dH arate fae faq ag er Instructions : @ Gi) Gi) (iv) ) (vi) (vii) 220 All questions are compulsory. Question Nos. 1 to 4 are objective type. Carries total 20 marks. Question Nos. § to 7, each question carries 2 marks. (word limit 30 words) Question Nos. 8 to 10, each question carries 3 marks. (word limit 75 words) Question Nos. 11 to 15, each question carries 4 marks. (word limit 120 words) Question Nos. 16 to 18, each question carries 5 marks. (word limit 150 words) Internal choice is given in every question from Question Nos. § to 18: / B-235 1 (RNA PIL.O. http:/Avww.mpboardonline.com wos auljuopreoqdur mam //:dnywoo‘ouljuoprogdur mayan: 220 http://www.mpboardonline.com we freer gia: 1x5=5 @) iter args CsCl ¥ afk dias ora Cs Ht waG ae 8 a a adage orem Cheat wray wer ehh — @ 8 (bo) 4 © 6 @ 12 Gi) aia urate 4 oscar ara at atti yfar ¥ cfeea ona & - Gi (a) ofertas (>) arfergirer () sashes @ srasirer i) OT Tet aes wl TE oe Oe ods SeaTeRTES Fae Stet BI fat % ya wen at wed F (a) Rr (bo) sae were ©) Prenea @ wh Gv) orgdtarrngs weer tare — (@) 1° wit (ob) WRTa (©) 2 aha : @) aaah () qe F waked sgdtage t (@) are (bo) dada (©) ane (@) qe / B-235 2 {AKIO PT.O. http:/Avww.mpboardonline.com wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com Choose correct option : a If the coordination number of cesium ion Cs* in Cesium chloride is 8, then the coordination number of chloride ion will be - f@) 8 (b) 4 © 6 @ 12 (ii) In the adsorption process of acetic acid in activated charcoal, acetic acid is (a) adsorbent (b) adsorbate (©) absorbent (d) _absorbate (iii) Carbon dioxide is released on heating lime stone ore, in metallurgy. This is called (a) Smelting (b) Ore dressing (©) Calcination (4) Roasting (iv) The isocyanide test is given by - (a) 1° amine (6) phenol (©) 2° amine (@) triethylamine (v) The disaccharide present in milk is - (a) sucrose (b) lactose (©) maltose (d) cellulose 220 / E-235 3 http:/Avww.mpboardonline.com A PLO. wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com fert wrt afte: 1x5=5, (i) fleet oraen 4 dian acirags & fage or garte aa wr eT _ #1 (i) Som TG HT OTST ore 31 (ii) 9aa rena ae araren % (iv) [Co(NH,),ClICl tea ant at FY Ru ww ga awit AH sear et () after A were Fill in the blanks : (@) __ are the reason for the electrical conductance of sodium chloride in molten state. (ii) Calcopyrites is the main ore of ______ metal. (iii) White phosphorus possesses composition in vapour state. (iv) ‘The total number of ions provided by the complex [Co(NH3),CL]CI_ in water is (v) The monomer in orlon is _ 220] / -235 ANT PTO. http:/Avww.mpboardonline.com wos 'auljuopreoqdur mam) /:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com ad ote angy 1x§=5 gg va" @ wear aw @) a Gi) ext tem (a) eiiafen afew Gi) reset (1) surges (iv) wrepfere tax (a) caocl, (vy) Shenge () xaetdreatengs @ NaCl Match the pairs : "an npr @ Schottky defect (a) buna-rubber (i) gold number () thermosetting plastic (ii) bleaching powder (©) _ Isoprene (iv) natural rubber () Ca0Cl, (v) _ backelite (€) _lyophilic colloid (NaCl um se % oae faftan 1x5=5 @ aMEarata far ar fen anger ferfen) Gi) oréifrae wharcr fear) (ii) Ffeer & sie tg yaaa dA aad wea |r arr faftaqs 220] / £-235 {ANITA PTO. http:/Avww.mpboardonline.com wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan: http:/Awww.mpboardonline.com (iv) Her Prat & oheit & rq geared Fatt at epee ae re om #? () eR eget & wan aaa: Gi aa Fait? Answer in one word : (Write the radius ratio for tetrahedral void. Gi) Write the Arbennius equation, (iii) Write the name of the process used for refining of nickel. (iv) Which gas is filled in the balloons used for meteorological experiments ? (v) The salts of transition metals are generally coloured. Why ? aft aggiort fa Ny wi 293K UC aa A a vara Pear ae at ow ferex set 9 Peet Paste Np fe fata ehh? Ny ar otiftre are 0.987 ae Aa 293K TE Ny & fre Fre feria Ky BI A 76.48 ae BI If nitrogen gas No is passed in water at 293 K, then how many milli mole Np gas will be soluble in one litre water ? The partial pressure of No is 0.987 bar and the value of Henry's law constant Ky at 293K is 76.48 bar. amat / OR 298 K We CO, te at oa 4 fata & fe Be fete ar a 1.67 = 108 Pa 81 500 ml tet Ga 2.5 atm Ta Te ae fleur maT 298 K amy Ut Yet ee CO, Ht AT BH wT afc) Henry's law constant for CO, in water is 1.67 x 108 Pa at 298 K. Calculate the quantity of CO, in 500 ml of soda water when packed under 2.5 atm CO, pressure at 298 K. 220 http:/Avww.mpboardonline.com / E235 TANNA PTO. wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com aftgien a sravsitie ara an &? 2 What are Freundlich adsorption isotherms ? wat / OR wx tin & wai - @) wer fern oH ares fies aie F A vA Hea B? Gi) ata FS fga are wearer at ond? What happens when (i) Beam of light passes through a colloidal sol ? (ii) Electric current is passed through sol ? Prafatea dpa are ¥ dato og F deer car ge at aA anh 2 vat ar ara af — @ NCD, (i) [Fe(CN),)- Mention the hybridisation and the geometry attained in the central metal and complex ions - @ (NC, Gi) [Fe(CN)_P- aa / OR Preafefad srmedatstt drat % TUPAC am fefaq : @ — Ke{Zn(OH),] Gi) [Ag(NH5))] [Ag(CN)p] Write the IUPAC name of the following coordination compounds : (i) Ky[Zn(OH),} Gi) [Ag(NH3)9] [Ag(CN)o] 220] / E-235 © 7 NOAA PLO. http:/Avww.mpboardonline.com wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com Prafeftar ar aftr feta 3 (Ret wT Gi) AleTeraT (ii) eT Write the definition of the following : (i) mole fraction Gi) molality (ii) molarity seat / OR we tart & eA a adert CHC, at aa agtsal ag ant z, wt fe Sacre ordkics ad t1 gt ayheal ar War 15 ppm Fer a gfe @) am @ 8 wear vite A egies Gi) wa} ae TA A ater! A ere ae AT s are found including In a sample of drinking water, many imputi chloroform CHCl, which are carcinogenic. The level of these impurities was 15 ppm (according to mass) (i) Show it in_mass percentage (ii) Find the molality of chloroform in this sample of water. [220] / B-235 ANION PTO. http:/Avww.mpboardonline.com wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan): http://www.mpboardonline.com Praia afitraet a wt aie — 3 (i) RON + 4H _LAAINg | (ii) RCONH, + Br, + 4KOH ——> ee (iii) RNO, +H —SMHCH ge Complete the following reactions — () RON + 4H _LIAINg (ii), RCONH, + Bry + 4KOH ——> +t tL (iii) RNO, + H —SWHC!, + wat / OR eR WHAT — @) Gitta aati wi a omen ga area eat B1 Gi) Arr wh & fae F fear ates ye IT t1 ii) uRea tags & anita owed a ge TIN sat afer 31 Explain the reason - (i) Aniline is a weaker base than cyclohexyl amine (ii) Silver chloride dissolves in methyl amine solution (iii) It is difficult to prepare pure amine by ammonolysis of alkyl halide. 220] / #.235 9AM A BT.O. http:/Avww.mpboardonline.com wos'suljuopreoqdur mam //:dnywioo‘ouljuoprogdur mayan /:day http://www.mpboardonline.com 10) fraet orret cer wets farpftrecr ger Ba E? 3 What are Zwitter ion and protein denaturation 2 srt / OR Seam oigft emt at? seat nea Ril 3? What is DNA Fingerprinting ? Why it is important ? 1 frafefed aftfearai & a1 airet & gaat afifear ae aa a7 4 Revie dh goRai ara aif; @) 3NOwqy —> NO ; AT = k(NO? - - + - - Gi) 4207444) 4:31(qq) + 2H" > 2H 0, +15 5 91 = KHQO,) [7] (iii) CH;CHOg, > CHyg) + CO) 3 31 = k{CH,CHOP? Gv) CHsClig) ~ CoHayg + AChgy 5 84 = KCCI] Find the order of reaction and the unit of rate constant for the following reactions by their rate expressions — ()_ 3NOq) > N20) ; Velocity = k(NO}? o — + — aa ~) di) M201.) +30 (qq) + 2H” > 2H0(p) +15 5 Velocity = k[H02} [17] (iii) CHyCHOg) > CHyg) + COxy@) 5 Velocity = k[CH;CHOP? (iv) CzHsCliyy > CoHyigy + HCl) ; Velocity = k[CH Cl] svat / OR Ree aifiry at vert ate at offre ar ord anger attrac at pref viaat 1 Poke wet ae Prove that the half life period for a first order reaction does not depend on the initial concentration of reactants. 220] / E235 so |ARIURINEN PTO. http:/Avww.mpboardonline.com wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan /:day http://www.mpboardonline.com 120 weir ore & octamer F ats are onetaree I BY ware 4 wae ENT TARE! Explain with chemical equation any four oxidative properties of potassium permanganate in acidic medium, sea / OR wet aomrer aot a ced A Prater got a ufteda at Pde sie — @ verde fra Gi) aT Got (ii) ofan erat (iv) aratecor arent Discuss the changes in the following properties of the first transition series (i) Atomic radii (i) Ionisation energy (iii) Metallic character (iv) Oxidation states 13 ufc tongs A are Act when aftifear Ga eh 8? eat 4 Rafer dfs) How does nucleophilic substitution reaction occur in alkyl halide ? Give its reaction mechanism. wat / OR foster aftiear fet wet €? cea deftia date fom ar ote aif) What is Elimination reaction ? Mention Saytzeff's rule associated with it. il RTO. 220] / 8-235 11 http:/Avww.mpboardonline.com woos auljuopreoqdur mam //:dnywoo‘ouljuoprogdur mavay//:day 14 http://www.mpboardonline.com Uentet cer fair FY ote fafaq) Write the differences between alcohol and phenol. aya / OR enter der seats fax A ueaa ha wet? How to distinguish between alcohol and di-cthyl ether ? am fa & wale gana a omer for oe & — @ wie Gi) Grate Gi) LiAIM, aro wer (iv) Na-Hg/H,O art What happens when — Reduction of ethanal takes place — (i) Clemmensen (i) Wulf-Kishner (ii) By LiAIHy and (iv) by Na-Hg/H,0 awa / OR freafeted afairenstt & creratrs etercr faftrr — @ asta aftr Gi) Cer oiftifear (ii) ateta atrigs afifeat (Gv) tatert afar Write the chemical equations for the following reactions : ()— Sandmeyer reaction (ii) Stephens reaction [220] / 1-235 x2 [MITA http:/Avww.mpboardonline.com P.TL.O. wos 'suljuopreoqdur Mam //:dnywoo‘ouljuoprogdur mayan) /:day http://www.mpboardonline.com ii) Hoffmann Bromamide reaction {iv) Haloform reaction @) (b) @ () (a) (b) (@) (b) 220 ata & Pan a ofeaira afer 5 0.025 mol L~! ages ema at arma 46,15 Som? mol~! &, geet Peeaort wer ud frit Rete an ute afiee) Rar war & ut) = 349.6 Som? mol! wi i = 54,6 Sem? mot! ticoo"} Define Kohlransch's law. The conductance of 0.025 mol L~! methanoic acid is 46,15 Scm? mol-!. Calculate its degree of dissociation and dissociation constant. Given that http://www.mpboardonline.com 54.6 Sem? mol”! *ut) = 349.6 Sem? mol! and *ucoo"] aa / OR aa Perio fed met 8? fare cae a ae Reia & de ee weary se? 298 KW wm urea Gat fret 0.001 M KCI feerr & ar ofa 15002 %, af€ 0.001 M KCI freer at uremat 208 K Wz 0.146 x 103 Som"! & dt aa fertis aa 8? What is cell constant ? What is the ‘relation between speci ic conductivity and cell constant ? The resistance of a conductivity cell containing 0.001 M KCl, at.298 K is 1500.Q, if the conductance of 0.001 M KCI solution at 298 K is 0.146 x 10-3 Scm~!, what is the cell constant ? 1 E235 13 MINIT RTO. http:/Avww.mpboardonline.com wos auljuopreoqdur MMM //:dnywoo‘ouljuoprogdur mayan: http://www.mpboardonline.com 17 aerate oma %& Prat at aud fate or Prafetad eget F avy at 5 (@) avé fatty ar rarer Gi) daa or amifea faa, gas Ger art ae Rea ar racer Describe the contact method for the manufacturing of sulphuric acid under the following headings : (Principle of contact method (ii) Labelled diagram, its main components and description of the reactions. aa / OR aritfrer Prater at tax fat ¥ aftisast ar carafe eect aa ware A ow at at daa ar arise fea Afi Give the chemical equations for the reactions and the labelled diagram for the manufacture of ammonia by Haber's process. 18 (a) wre Ufttaat & a vereer a ys ferfac! 5 (&) afar Gi) geet cer Am — ateeha cet & afer weet & arr ae ate saan fafiagt (a) Write two examples and formula of food preservatives. (b) Write the names of active components and medicinal usage of (i) Aamta (i) Tulsi and (iii) Neem seat / OR http:/Avww.mpboardonline.com 220] / 0.235 + {ANN woos auljuopreoqdur mam) /:dnywoo‘ouljuoprogdur mayan): http://www.mpboardonline.com @ & dered fsa & ry pag ©) aes orrHisie FB? wate a scree ARC! @ Write name of two analgesic medicines. (b) What are synthetic detergents ? Give example of its each type 220 / E-235 httpy/www.mpboardonline.com Whatsapp @ 9300930012 Your old paper & get 10/- que dude tar athe 10 wd ard, Paytm or Google Pay & 15 [ANON PTO. http:/Awww.mpboardonline.com wos 'auljuopreoqdur mam //:dny< = 2 ea S g a ¢ B = g oe és 5 220 / E-235 http://www.mpboardonline.com BLANK PAGE x6 {ANNAN http:/Awww.mpboardonline.com wos 'suljuopreoqdur Mam //:dny