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EE128 - Class 0
EE128 - Class 0
Source: Nagwa
Quantization of energy
How it started: thermodynamics going wrong How it started: thermodynamics going wrong
everything that has a temperature > 0K vibrates everything that has a temperature > 0K vibrates
like the atoms of a heating coil or lamp filament like the atoms of a heating coil or lamp filament
charges that vibrate emit light charges that vibrate emit light
like the charges in the vibrating atoms like the charges in the vibrating atoms
Source: Nagwa Source: Nagwa
How it started: thermodynamics going wrong How it’s going: a theory fix that not only worked,
but resulted in the most robust theory that explains our world
everything that has a temperature > 0K vibrates
like the atoms of a heating coil or lamp filament everything that has a temperature > 0K vibrates
like the atoms of a heating coil or lamp filament
charges that vibrate emit light
like the charges in the vibrating atoms charges that vibrate emit light
Source: Nagwa like the charges in the vibrating atoms
Source: Nagwa
one can model the atoms
one can model the atoms
as springs (a.k.a., harmonic oscillators)
as springs (a.k.a., harmonic oscillators)
that can only have specific energies
problem: theory disagrees with experiments and (thus• ) emit light at specific energies
and predicts bad-bad results (‘ultraviolet catastrophe’:
too much light emitted at large frequencies)
Source: Professor Dave Explains YouTube
How it’s going: a theory fix that not only worked, How it’s going: a theory fix that not only worked,
but resulted in the most robust theory that explains our world but resulted in the most robust theory that explains our world
start of XX century: the atom is in great danger! start of XX century: the atom is in great danger!
‘charges going in a circular orbit emit light, thereby losing energy’ says Maxwell∗
How it’s going: a theory fix that not only worked, How it’s going: a theory fix that not only worked,
but resulted in the most robust theory that explains our world but resulted in the most robust theory that explains our world
start of XX century: the atom is in great danger! start of XX century: the atom is in great danger!
‘charges going in a circular orbit emit light, thereby losing energy’ says Maxwell∗ ‘charges going in a circular orbit emit light, thereby losing energy’ says Maxwell∗
vs. vs.
‘atoms are composed of negatively charged particles (electrons) ‘atoms are composed of negatively charged particles (electrons)
orbiting around a positively charged nucleus’ says Rutherford∗ orbiting around a positively charged nucleus’ says Rutherford∗
Plank∗ saves the day again, and Bohr∗ models the atom! (∗ all ol’ white dudes btw)
‘charges going in a circular orbit emit light, thereby losing energy’ says Maxwell∗
vs.
‘atoms are composed of negatively charged particles (electrons)
orbiting around a positively charged nucleus’ says Rutherford∗
Wave-particle duality
Plank∗ saves the day again, and Bohr∗ models the atom! (∗ all ol’ white dudes btw)
Source: Wikipedia
Source: forgive me, author, but I can’t find it anymore Source: forgive me, author, but I can’t find it anymore
Light waves or beams of light are composed of particles (meet the photon!) Light waves or beams of light are composed of particles (meet the photon!)
Einstein explained the ‘photoelectric effect’ Einstein explained the ‘photoelectric effect’
Source: forgive me, author, but I can’t find it anymore Source: forgive me, author, but I can’t find it anymore
some colors of light don’t kick out some colors of light don’t kick out
electrons, even if beam very strong electrons, even if beam very strong
number of electrons kicked out, if any, number of electrons kicked out, if any,
depends on beam strength depends on beam strength
‘quanta of light’ are called photons ‘quanta of light’ are called photons
some colors of light don’t kick out some colors of light don’t kick out
electrons, even if beam very strong electrons, even if beam very strong
number of electrons kicked out, if any, number of electrons kicked out, if any,
depends on beam strength depends on beam strength
energy of electrons flying out does not energy of electrons flying out does not
change if light beam is weak or strong, change if light beam is weak or strong,
depends only on light color depends only on light color
Light waves or beams of light are composed of particles (meet the photon!) Light waves or beams of light are composed of particles (meet the photon!)
Einstein explained the ‘photoelectric effect’ Einstein explained the ‘photoelectric effect’
‘quanta of light’ are called photons ‘quanta of light’ are called photons
energy of electrons flying out does not energy of electrons flying out does not
change if light beam is weak or strong, change if light beam is weak or strong,
depends only on light color depends only on light color
Light waves or beams of light are composed of particles (meet the photon!) Light waves or beams of light are composed of particles (meet the photon!)
Einstein explained the ‘photoelectric effect’ Einstein explained the ‘photoelectric effect’
‘quanta of light’ are called photons ‘quanta of light’ are called photons
Tiny massive particles behave as waves Tiny massive particles behave as waves
Tiny massive particles behave as waves Tiny massive particles behave as waves
Source: Science 2.0 momentum of massive particle is p = m · v Source: Science 2.0 momentum of massive particle is p = m · v
cannon ball electrons (!) cannon ball electrons (!)
massive particle has quantized
wavelength λ = ph = m·v
h
, small
Tiny massive particles behave as waves Both matter and photons can be described in quantum mechanics
by wavefunctions
y is said to be a function of x
e.g., cost of chocolate as a function of demand
Source: AMSI
A wavefunction is a function with a weird notation A wavefunction is a function with a weird notation
y is said to be a function of x
e.g., temperature as a function of month
a wavefunction describes how the state of a quantum system depends,
e.g., on position, on time...
Source: AMSI
A wavefunction is a function with a weird notation A wavefunction lives in the space of complex numbers
a wavefunction describes how the state of a quantum system depends, a wavefunction, unlike regular functions and vectors IRL, obeys:
e.g., on position, on time... ◮ |z · Ai = z · |Ai = |Di, for z ∈ C
a wavefunction describing a quantum state is denoted by |Ai (read: ket A)
i is the imaginary number, i 2 ≡ −1
a wavefunction, like regular functions and vectors IRL, obeys:
◮ |Ai + |Bi = |C i z = x + iy, x and y ∈ R
◮ |Ai + |Bi = |Bi + |Ai
z has a complex conjugate z̄ = x − iy
◮ |Ai + | − Ai = 0
◮ |r · Ai = r · |Ai = |Di, for r ∈ R |z|2 = z̄ · z = r 2 = |x|2 + |y|2 is a real number
Source: TopPR Source: TikZ.net
A wavefunction can have different dimensions A wavefunction has a complex conjugate wavefunction
|Ai = A(x ) ∈ C
it could be that:
hA| = Ā(x ) ∈ C
|Ai = A(x ) ∈ C a1
|Ai = , a1 and a2 ∈ C
a2
hA| = ā1
a1 ā2 , ā1 and ā2 ∈ C
|Ai = , a1 and a2 ∈ C
a2 a1
a2
|Ai =
a3 , a1 , ..., a5 ∈ C
a1 hA| = ā1 ā2 ā3 ā4 ā5 ,
a2 a4 ā1 , ..., ā5 ∈ C
a5
|Ai =
a3 , a1 , ..., a5 ∈ C
a4
◮ |Ai + |Bi = |C i ◮ hA| + hB| = hC |
a5
◮ |Ai + |Bi = |Bi + |Ai ◮ hA| + hB| = hB| + hA|
◮ |Ai + | − Ai = 0 ◮ hA| + h−A| = 0
◮ |z · Ai = z · |Ai = |Di, for z ∈ C ◮ hz̄ · A| = z̄ · hA| = hD|, for z̄ ∈ C
A wavefunction and a complex conjugate combine A wavefunction and a complex conjugate combine
to give quantities that can be measured IRL to give quantities that can be measured IRL
a
hB|Ai = b̄1 b̄2 · 1 = b̄1 · a1 + b̄2 · a2 ∈ C
a2
dot product, similar to
dot product of vectors IRL:
a |hB|Ai|2 ∈ R
hB|Ai = b̄1 b̄2 · 1 = b̄1 · a1 + b̄2 · a2 ∈ C
a2 Source: TikZ.net
dot product, different from dot product of vectors IRL: wavefunctions |Ai cannot be measured or observed in IRL since they are complex
hB|Ai 6= hA|Bi
we can only measure real quantities such as |hA|Ai|2 or |hB|Ai|2
hB|Ai = hA|Bi, complex conjugates
if |Ai is normalized, |hA|Ai|2 = 1
(|hA|Ai|2 = 1 is usually used; |Ai is said to be normalized)
Source: CueMath |hB|Ai|2 is to be understood as the probability
(if hA|Bi = 0, |Ai and |Bi are said to be orthogonal)
that the quantum object |Ai is in quantum state |Bi
√ √
|Ai = 0.3|Bi + i 0.7|C i
|Bi, |C i normalized
√ and orthogonal
√ √ √ √
hB|Ai = hB|√ ( 0.3|Bi + i 0.7|C i) = 0.3hB|Bi √ + i 0.7hB|C i = 0.3
|hB|Ai|2 = | 0.3|2 = 0.3; similarly, |hC |Ai|2 = |i 0.7|2 = 0.7
Different waves have different mathematical equations
Evolution equation
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
h̄2 d 2 |Ai
− + V (x ) · |Ai = E · |Ai h̄2 d 2 |ψi
2m dx 2 − + V (x ) · |ψi = E · |ψi
2m dx 2
|ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |ψi is ψ (x )
V (x ) ∈ R: potential energy of tiny massive object
E ∈ R: total energy of tiny massive object
|hψ|ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance!
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
electron could be in |ψ1 i with energy E1 electron could be in |ψ2 i with energy E2 = 4E1
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
electron could be in |ψn i with energy En = n2 E1 (note: hψn |ψm i = 0 for n 6= m: solutions of Evolution equation are orthogonal!)
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
most generic state: a combination (or superposition) of |ψ1 i and |ψ2 i and... |ψn i, |ψi = a1 |ψ1 i + a2 |ψ2 i + ...an |ψn i, with |a1 |2 + |a2 |2 + ...|an |2 = 1
with a combination of the energies!
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
|ψi = a1 |ψ1 i + a2 |ψ2 i + ...an |ψn i, with |a1 |2 + |a2 |2 + ...|an |2 = 1 |ψi = a1 |ψ1 i + a2 |ψ2 i + ...an |ψn i, with |a1 |2 + |a2 |2 + ...|an |2 = 1
probability that |ψi is found in |ψn i is |hψn |ψi|2 = |an |2 probability that |ψi has energy En is |hψn |ψi|2 = |an |2
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
h̄2 d 2 |ψi
− + V (x ) · |ψi = E · |ψi h̄2 d 2 |ψi
2m dx 2 − + V (x ) · |ψi = E · |ψi
2m dx 2
|ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |ψi is ψ (x )
|ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |ψi is ψ (x )
V (x ) ∈ R: potential energy of tiny massive object
V (x ) ∈ R: potential energy of tiny massive object
E ∈ R: total energy of tiny massive object
E ∈ R: total energy of tiny massive object
|hψ|ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance!
|hψ|ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance!
one example: particle trapped in a box (V (x ) = 0 inside, V (x ) → ∞ outside)
another example: particle trapped in a ‘harmonic’ (parabolic) potential (V (x ) ∝ x 2 )
i.e., the quantum version of
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
allowed energies for the electron given by En = h̄ω2 (n + 1), E0 > 0!, equidistant
(non-zero probability that the particle explores position x not allowed classically!)
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
2
h̄ ∂2 |Ψi ∂|Ψi h̄2 ∂2 |Ψi ∂|Ψi
− + V (x ) · |Ψi = E · |Ψi= i h̄ − + V (x ) · |Ψi = E · |Ψi= i h̄
2m ∂x 2 ∂t 2m ∂x 2 ∂t
|Ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |Ψi is Ψ(x, t ) |Ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |Ψi is Ψ(x, t )
V (x ) ∈ R: potential energy of tiny massive object V (x ) ∈ R: potential energy of tiny massive object
E ∈ R: total energy of tiny massive object E ∈ R: total energy of tiny massive object
|hΨ|Ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance! |hΨ|Ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance!
E·t E·t
general solution can be shown to be |Ψ(x, t )i = |ψ (x )i · e−i h̄ general solution can be shown to be |Ψ(x, t )i = |ψ (x )i · e−i h̄
E·t E·t E·t
|hΨ|Ψi|2 = |hψ|ψi|2 · |e−i h̄ |2 = |hψ|ψi|2 · (e −i h̄ · e +i h̄ ) = |hψ|ψi|2 ,
independent of time!
Waves of tiny massive objects can be described by the Evolution equation Waves of tiny massive objects can be described by the Evolution equation
h̄2 ∂2 |Ψi ∂|Ψi h̄2 ∂2 |Ψi ∂|Ψi
− + V (x ) · |Ψi = E · |Ψi= i h̄ − + V (x ) · |Ψi = E · |Ψi= i h̄
2m ∂x 2 ∂t 2m ∂x 2 ∂t
|Ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |Ψi is Ψ(x, t ) |Ψi ∈ C: wavefunction of tiny massive object (e.g., electron); |Ψi is Ψ(x, t )
V (x ) ∈ R: potential energy of tiny massive object V (x ) ∈ R: potential energy of tiny massive object
E ∈ R: total energy of tiny massive object E ∈ R: total energy of tiny massive object
|hΨ|Ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance! |hΨ|Ψi|2 ∈ R, ≤ 1: quantity that is measurable and that has physical significance!
E·t E·t
general solution can be shown to be |Ψ(x, t )i = |ψ (x )i · e−i h̄ general solution can be shown to be |Ψ(x, t )i = |ψ (x )i · e−i h̄
E·t E·t E·t E·t E·t E·t
|hΨ|Ψi|2 = |hψ|ψi|2 · |e−i h̄ |2 = |hψ|ψi|2 · (e −i h̄ · e +i h̄ ) = |hψ|ψi|2 , |hΨ|Ψi|2 = |hψ|ψi|2 · |e−i h̄ |2 = |hψ|ψi|2 · (e −i h̄ · e +i h̄ ) = |hψ|ψi|2 ,
independent of time! independent of time!
(theory without noise as seen here cannot account for simple phenomena!
IRL: decoherence)
Superposition
Even if a quantum object can be in a superposition of states, when you Even if a quantum object can be in a superposition of states, when you
measure/observe it, you only see one ‘classical’ state and its exact energy measure/observe it, you only see one ‘classical’ state and its exact energy
Source: forgive me, author, I can’t find it anymore Source: forgive me, author, I can’t find it anymore
Source: forgive me, author, I can’t find it anymore measuring the electron orbit/energy, you measuring the electron orbit/energy, you
Source: forgive me, author, I can’t find it anymore
get: |ψ0 i/E0 with probability |a0 |2 , get: |ψ0 i/E0 with probability |a0 |2 ,
one electron in both orbits/energies, |ψ1 i/E1 with probability |a1 |2 (i.e., one electron in both orbits/energies, |ψ1 i/E1 with probability |a1 |2 (i.e.,
simultaneously: ‘probabilistic collapse to classical state’: simultaneously: ‘probabilistic collapse to classical state’:
E0 t E1 t E0 t E1 t
|Ψi = a0 |ψ0 i · e−i h̄ + a1 |ψ1 i · e−i h̄ involves decoherence) |Ψi = a0 |ψ0 i · e−i h̄ + a1 |ψ1 i · e−i h̄ involves decoherence)
to learn about the quantum state before observation,
you need to repeat the observation many times for statistics
(i.e., ‘prepare’ superposition state each time before measuring)!
Two quantum objects are entangled
if you ‘instantaneously’ learn about one by learning something about the other
Entanglement
Quantum concepts you can now qualitatively describe T’is end of the (quantum) world: measurement and decoherence
tiny ∼ quantum; but why don’t we see macroscopic quantum effects? (or do we... ?)
1. Quantization of energy
2. Wave-particle duality
3. Mathematical representation of wavefunctions
4. Evolution equation
5. Superposition
6. Measurement or observation of a quantum object
7. Entanglement measuring a quantum system yields a classical result: need probabilistic averaging