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Powder Coatings Technical From Akzonobel
Powder Coatings Technical From Akzonobel
And
Trouble shooting Manual
Indian contact:
V. Narayanan
Business Service Manager,
Akzo Nobel Coatings India Pvt. Ltd.
Phone: + 91 9972590800
E mail: Venkataraman.Narayan@akzonobel.com
1
Introduction
2
Index
DESCRIPTION PAGE
3
Drying and Handling Parts after Pretreatment .............................. 25 - 26
Corona Charging.............................................................................. 31 - 34
External / Internal Electrodes
Current control and Ion collectors
Nozzles
Advantages and Disadvantages of Corona Charging
4
Spraying Powder Coatings Effectively .......................................... 39 - 40
Fluidising Powder
Powder Venturi Pump Operation and Adjustment
Applying the Appropriate Film Build
Adjusting Corona guns to control film build
Flow Rating guns
5
Curing Powder Coatings ................................................................. 51
Under Curing
Over Curing
Cure Schedules
Ovens ................................................................................................ 51 - 52
Types
Design and Sizing Considerations
Boost Ovens
Contamination .................................................................................. 60 - 61
Common Sources of Contamination
6
Powder Coating On Site Test ......................................................... 62
Pretreatment Tests
Powder Coated Parts Tests
Safety ................................................................................................ 67
7
The History of Powder Coating
Powder Coatings were developed in late 1940s and were initially applied by fluidised bed
method. Electrostatic spray was introduced in the 1960s and in the 1970s powder coatings
gained worldwide acceptance. Rapid growth throughout the world occurred in the 1980s.
The Powder Coatings industry today continues to expand and is widely recognised as an
environmental friendly, cost effective alternative to liquid paints, and a premium quality
finish.
8
About Powder Coatings
1. Weighing
2. Mixing / Blending
3. Extruder
4. Flat Bed Cooler & Nibbler
5. Grinding Mill
6. Sieving & Packing
7. Dust Filters
9
Raw materials such as - resin, cross linker, pigments, fillers, flow additives and matting
agents are weighed up and dry blended in high-speed mixers. The blended mixture is then
fed through an extruder that produces a homogeneous composite. This melted material is
flattened through chilled rollers and cooled on a flat belt conveyor. The sheet material is
then broken into chips and fed into a grinding mill that classifies powder into a specified
particle size distribution.
The final step is to sieve the powder through a very fine screen to remove any over sized
particles or contaminants.
At each stage of the production process the quality must be checked because once the
powder coating material has been produced, it cannot be changed or adjusted in any
significant way. The formulation and the manufacturing conditions are therefore critical.
Reworking of an ‘out of specification’ product is difficult and costly.
Higher temperatures and longer storage periods will result in absorption of moisture.
Most powder coatings have a shelf life of 12 months but if stored properly many
formulations will maintain their properties for far longer.
Some highly reactive powders (Fast / Low cure) formulations will have a more limited shelf
life.
Consult Product Data Sheets.
10
Powder Coating Chemistries
The most widely used Thermoset powder chemistries are:
TGIC Free Polyester
TGIC (triglycidyl isocyanurate) containing Polyester
Hybrid – Epoxy / Polyester
Epoxy
Epoxy polyester hybrid powders: are epoxy powders by origin containing a high
percentage of special polyester resin (sometimes exceeding 50%). These hybrids have
properties similar to those of epoxy powder. However, their additional advantage is that
they have improved resistance to over bake yellowing and improved weather ability.
Hybrid powders are now regarded as the main backbone of the powder coatings industry.
Epoxy powders: can be formulated to give high gloss and smooth coatings. Epoxy
Powder Coatings exhibit inherent toughness, corrosion resistance, chemical resistance,
flexibility, adhesion and abrasion resistance. Epoxy powder is normally used where a
tough durable film is required and the product will not be exposed to direct sunlight for long
periods of time. An epoxy coating will form a chalk like appearance on the surface with
lengthy exposure to sunlight.
11
Powder Coating Properties
12
The Powder Coating Process
Process Steps
13
Manual Batch System
14
Environments & Classifications
Reference – ISO 12944
In selecting the appropriate pre-treatment and powder coating (coating system) for a given
application, the atmospheric conditions must be considered.
Interior Environments
I1 – LOW HUMIDITY
Includes areas with low or average humidity < 20% RH.
I2 – HIGH HUMIDITY
Includes areas with high humidity >40% RH.
I3 – HARSH ENVIRONMENTS
Areas with harsh and polluted environments
Exterior Environments
E1 - MILD
Includes areas with low level pollution, mostly rural
E2 – MODERATE
Includes urban industrial area. Moderate SO2 levels in coastal areas with low salinity.
E3 – COASTAL
Includes industrial areas and coastal areas with moderate salinity and SO2
levels>30mg/m3
E4 – SEVERE
Includes industrial areas with Humid and aggressive atmospheres, with SO 2
levels>30mg/m3 coastal and offshore areas less than 1 km form coast with high UV, high
humidity and salt > 12 mg per litre rain water.
15
Metal Cleaning & Pre-treatment
The Purpose
Cleaning and pre-treatment of the substrate promotes better adhesion of the powder
coating and will improve the corrosion resistance of the substrate. It removes surface
contaminants Eg. Rust, Scale, Grease etc. & ensures uniform treated substrate.
Iron or Zinc Phosphate on steel, or the Chromate Conversion Coatings on aluminium are
critical components to the overall performance of the powder-coated part.
The Process
Depending on the performance and production requirements the process can be anything
from solvent wiping to a 9-stage in-line washer system.
The chemical concentration, temperature and exposure time will determine the cleanliness
and the level of conversion coating that is deposited onto the substrate accounts for the
performance. Parts should not be allowed to dry between the cleaning / pre-treatment
process as flash rust or deposits will form and this will adversely affect performance.
Stages of any Pre-Treatment system include:
1. Cleaning
2. Rinsing
3. Conversion Coating
4. Seal Rinsing
5. Drying
6. Cooling
The choice of pretreatment requires consideration of:
1. Substrate type (HDG, AZ, CRS, Al etc)
2. Surface condition – type of contaminants
3. Application method
4. Coating Performance – service life
5. Economics
6. Environmental Issues
16
Following types of Pre-treatment Systems are in practice:
Advantages Disadvantages
Advantages Disadvantages
17
Cleaning & Pre-Treatment Solutions
Solvent Wipe
Some smaller operations or those processing very large parts that cannot be dipped or
sprayed will solvent wipe to remove oil or lubricants. Chlorinated solvents are often used
but there are many health and safety concerns that must be taken into consideration.
Solvent wiping will generally improve adhesion and the finished appearance, but it offers
no corrosion protection to the metal substrate.
Alkaline Cleaner
Removes organic soils such as; oils, waxes, lubricants, drawing compounds and die
casting release agents.
Acid Cleaner
Removes inorganic soils such as: rust, smut, heat scale, oxides, stains and particulates
from sanding, blasting or deburring operations
Abrasive Blasting
Removes contaminants, and the rough surface will improve powder adhesion. As with
solvent wipe it offers no corrosion protection of the metal substrate. Parts should be free of
oils or other substances that may become impregnated into the parts. Shot blast material
can become contaminated if recycled. Excessive surface profile can cause pin holing with
some powder formulations.
Iron phosphate
The most common conversion coating used enhances the powder coating adhesion and
forms a protective barrier that retards corrosion creep.
Typical coating weight is 0.5 grams per square metre.
Salt Spray performance on steel between 150 and 400 hours.
Process is essentially pickling of steel in phosphoric acid.
Zinc Phosphate
Offers superior corrosion protection, but is considerably more expensive to maintain than
Iron Phosphate. Most commonly used in the Automotive and Appliance industries.
Typical coating weight is 2 grams per square metre.
Salt Spray on steel in the range of 1000 hours.
Accelerators (i.e. Oxidizers) are an important addition to Zinc Phosphating
solutions.
18
Conversion Coating Comparison:
Average Coating Weight 0.1 to 0.5 gms/m2 Average Coating Weight 0.5 to 4 gms/m2
1
Salt Spray resistance 500 hrs Salt Spray resistance 1000 hrs
3
Sealer Rinse
Final rinse stage (chrome or non-chrome). Further enhances conversion-coating
performance by removing residual chemicals and acting as a passivation treatment.
Improves adhesion and corrosion protection.
19
Pre-Treatment for Various Substrates
Cold Rolled Steel (CRS)
Alkaline cleaners are used to remove oils and greases. If rust is present an acid cleaner
will also be required. Conversion coatings such as Iron or Zinc Phosphate are most
commonly used to promote better adhesion of the powder coating and enhance corrosion
protection.
Aluminium
Alkaline and / or Acidic cleaners are used to clean and etch the substrate. Chromate
Phosphate (green) or Chromium Oxide (yellow) Conversion coatings enhance corrosion
protection.
20
Copper and Brass
Acid cleaner or abrasive blasting can be used to remove the oxide layer and improve
powder-coating adhesion. (Phosphate pre-treatment is not effective). Chromating may be
an option.
Stainless Steel and Chrome
Polished smooth surfaces will reduce powder adhesion; these substrates should be etched
or shot blasted. (Phosphate pre-treatment’s are not effective).
Note: Other pre-treatment may have temperature limitations, exceeding this limit may
adversely affect the performance of the pre-treatment. Consult the pre-treatment
chemical supplier.
21
Handling Pre-treated Parts
Pre-treated parts should never be handled without clean lint free gloves.
Once parts have been cleaned and pre-treated they should be powder-coated as soon as
possible for best coating performance and finished appearance.
The general rule is to have the space between parts twice the desired depth of
penetration.
Racks and hooks should be constructed of the smallest gauge material possible
so they will not rob powder away from the parts.
Racks should not to sway and twist during the pre-treatment spray process. Part
positioning for drainage must also be taken into account.
Hooks and racks should be designed to withstand the chemical or heat stripping
process.
22
Earthing / Grounding Parts
A good earth (Less than 1 Meg ohm) is recommended to maximise powder transfer
efficiency and for safety issues. A Meg Ohm meter with 500-volt output should be used to
test part earth.
Using a Meg Ohm Meter – Measure conductivity between a part on one hook and a part
on another hook, this will test conductivity path through hooks and conveyor. Measure
conductivity between load bars and between parts and building or electrical earth to check
complete circuit
Copper rub bars or brass bristle strips are often mounted above the conveyor slot opening
of a powder booth. As the hooks enter the powder booth they rub along the earthed bar or
bristles and this ensures the hooks are properly earthed.
A light coloured ash can remain on the hooks and racks after burning and this should be
removed by a high-pressure water wash. If it is not removed it can contaminate the washer
tanks and block washer spray nozzles.
23
Conveyor Design Considerations
Conveyors should be shielded or positioned with enough clearance over the top of the
powder booth so there is little chance of powder coming into contact with the rail, chain,
trolley assemblies or load bars. These components provide the electrical pathway to earth
and should they become insulated with powder they will require removal and stripping.
There can be a significant amount of fall off contamination from overhead conveyors that
will result in finish defects and reject parts. S hooks and sanitary pans are used in almost
every appliance or other Class A finish operation.
Load bars can provide greater flexibility and help maximise line density.
24
Air Compressors & Driers
All powder guns require compressed air to pump the powder from a hopper or box feeder
to the guns. Compressed air is also used to clean cartridge or bag filters in recovery
systems. The quality of the compressed air is critical and properly maintained air driers
and filters are required to produce air to an acceptable standard for powder coating
equipment. Contaminated air can cause equipment failures and adversely effect the
powder coating finish quality.
Compressed Air
It is essential that adequate and consistent compressed air pressure and volume be
maintained. Fluctuations in pressure and volume may cause inconsistent powder output
through the guns and inadequate filter cleaning in the recovery system.
Filters
Coalescer type filters should be used to remove water and oil before air enters air drier.
These can be fitted with automatic drains.
A filter to remove particulates is also recommended.
Air Driers
There are two suitable types:
Refrigerated
Desiccant – Twin tower
(It is recommended that the air drier be positioned within 30 meters of the powder coating
equipment).
25
Refrigerated Air Drier Principle of operation
air-
air-to-
to-air heat exchanger
(precooler/reheater)
precooler/reheater)
separator or
coalescing filter
drain
air-
air-to-
to-refrigerant
heat exchanger
refrigeration
equipment
A timer
Moisture-laden
circuit
compressed air
controls the
enters through
valves which
bottom of dryer
switch each
tower on-line
or off-line
26
Environment for Powder Coating
Environmental Rooms
In most factories there are many air-borne contaminants that can be drawn into the
powder booth and adversely affect the quality of the finished parts. If the highest quality
finish is required than the powder coating system must be contained in its own
environmental room.
These rooms are typically freestanding structures inside the factory with filtered air inlets.
A slight positive pressure prevents air borne contaminants from entering the room.
Any air conditioning or make-up air introduced into the environmental room should be
defused through ducting and vents to reduce its velocity and the air currents inside the
room. Excessive air velocity around powder booths will disrupt the booths airflows and
cause powder to escape into the environment.
Corona Charging
Theory of Operation
Corona Charging is the most widely used method to apply powder coatings. A high voltage
electrical source charges the surrounding air creating the corona electrical field, as the
powder particles pass through this field they pick up the charge and are attracted to the
earthed substrate.
27
Most corona guns produce a negative charge; it is claimed that the negative corona
charging offers superior transfer efficiency and produces less free-ions than a positive
corona charge.
28
Nozzles
Most gun models offer an optional selection of nozzles, typically a range of different size
conical or flat spray nozzles. The conical nozzles are more versatile and good for general
application. Flat spray nozzles are best suited for large flat surfaces such as appliance
panels or office furniture. Some gun models offer special nozzles that can be very effective
in certain applications.
29
Disadvantages of Corona Charging
Electrical field lines can make penetration into Faraday Cage areas difficult.
The free-ions generated by the corona field - It is claimed that only a small
percentage of the charged ions actually attach themselves to the powder
Particles as the pass through the Corona field. The excess free-ions can inhibit
penetration and cause “Back Ionisation” / “Starring” that may result in a rougher
surface finish or film defects.
Theory of Operation
Tribo guns work by exchanging ions between the powder particles and the friction material
in the gun. As the powder particles come into contact with a material that easily accepts a
charge such as PTFE or (Teflon), the Powder particles become positively charged. The
charged powder is than attracted to the earthed part. Not all powder coatings will Tribo
charge efficiently. Powder coatings are generally formulated and manufactured to more
efficiently accept a Tribo charge.
30
Disadvantages of Tribo charging
Powder coating should be specially formulated to enhance Tribo charge
performance.
Charge acceptance is very sensitive to excessive humidity in the environment.
Reclaim powder / finer particles of powder do not charge well.
Difficult to clean the guns for colour change
31
Automating Powder Spray Application
Automatic guns can either be in a fixed position, or be fitted to reciprocators, gun
positioners / movers or robots.
Reciprocators – allow guns to coat larger surface areas and can improve coverage and
uniformity.
Gun Positioners / Movers – are used to move guns in / out to maintain a consistent
distance from the parts. Multi axis movers can follow parts as they travel through the
powder booth.
Robots – Can be used to eliminate manual touch-up.
Part identification and gun triggering - can be beneficial in large production processes
by reducing the amount of over-sprayed powder, minimising film builds, and increasing the
overall process efficiency.
32
Powder Transfer Efficiency (TE) - Spraying
Part Earthing
Part line density
Part complexity
Powder formulation and particle size
Powder gun efficiency, positioning, pattern, and powder throughput
Booth air flow and design
Environment - temperature and humidity
33
Benefits of Maximising First Pass Transfer Efficiency
Generates less reclaim powder
Less wear on guns and filters
More consistent coverage and film build
Cleaner finish
Conserves powder
Gun Hoses
NOTE Hose length has a significant effect on powder output, the longer the hose the
less powder output at the same pump settings.
Example: For 2.4 metres per minute line speed with a vertical hanging length of 1.2
metres
2.4 X 1.2
0.8 = 3.6 or (4 guns per side)
34
Spraying Powder Coatings Effectively
Fluidising Powder
In most cases manual and automatic guns are fed powder from a fluidising hopper. Proper
fluidising is essential for a good consistent spray pattern. Powder hoppers, either round or
square are constructed with a porous membrane in the bottom, compressed air passes
through the membrane and suspends and separates the individual powder particles.
Properly fluidised powder should be completely aerated from top to bottom of the hopper,
and with only moderate bubbling on the surface.
The other air line is called (Atomising, Diffuser or Dosage) air; and it usually
enters the pump at 90 degrees and helps to even-out the powder delivery for a
more uniform spray pattern.
The Flow Rate air should be set first for the desired volume of powder output.
The Atomising air should then be adjusted just high enough to produce a good
spray pattern without any puffing and spitting.
As the Atomising air pressure is increased the volume output of powder is
reduced so the Flow-Rate may need to be adjusted up slightly.
35
Applying the Appropriate Film Build
Too thin a film build will allow the substrate to show through the coating and provide
inadequate protection. Too heavy a film-build is wasteful and can adversely effect the
coating appearance and mechanical performance.
Most standard powder coatings are formulated to be applied at a cured film-build
of between 40 and 80 microns.
When a warranty is offered by the powder-coating supplier, there will be a
specified cured film thickness range that must be adhered to.
Very bright colours such as Reds and Yellows will often require a heavier film-
build as compared to other colours to hide the substrate.
Some lighter shade colours can produce slightly different colour appearance at
lower and heavier film-builds.
Powder coatings with surface contours such as ripples, wrinkles and
hammertones usually require heavier average film-builds due to peaks and
valleys. The valleys can show through to the substrate at lower average film-
builds.
Controlling the applied film-build is one of the most important aspects of the
powder coating process. Thickness measurements should be taken regularly and
results immediately relayed to the operators so adjustments can be made.
36
Troubleshooting Powder Spray Problems
PROBLEM POSSIBLE CAUSE POSSIBLE SOLUTION
Poor Fluidisation A) Improper fluidising air A) Increase or decrease fluidising air supply
Or “Dusting” in adjustment to hopper
hopper B) Compacted or damp powder B) Stir Powder / Check for moisture in
compressed air supply
C) Plugged fluidising tile C) Replace tile
D) Powder too fine D) Reduce amount of reclaim powder, have
powder supplier check particle size
Guns Spitting or A) Poor fluidising A) See above
Surging B) Pump not adjusted properly B) Increase atomising / diffuser air
C) Supply air to pump leaking C) Check all air tube connections for leaks
D) Obstruction in pick-up tube or D) Clean pick-up tubes and hoses; ensure
hose there are no kinks or sharp bends in the
hoses.
E) Worn pump venturi throat E) Replace worn parts
F) Powder too fine F) Reduce amount of reclaim powder
Poor Penetration A) Insufficient powder A) Increase pump flow-rate pressure
B) Powder being blown out B) Lower pump atomising pressure
C) Parts spaced too close C) Increase space between parts
D) Poor earth D) Clean hooks or racks
E) Incorrect spray pattern E) Try different nozzles
F) Improper gun positioning F) Re-position guns
G) Voltage too high G) Reduce gun Kv output
H) Powder too fine H) Reduce the amount of reclaim powder
Poor Attraction of A) Gun voltage too low A) Increase Kv output, measure voltage
Powder to Parts output with Kv meter
B) Poor earthing B) Clean racks and hooks
C) Powder spray pressures too C) Decrease pump atomising / diffuser air
high
D) Moisture in compressed air D) Service compressed air drier
E) Hooks or racks robbing E) Redesign hooks and racks, allow more
powder from parts space between parts
Film Thickness too A) Powder output too low A) Increase pump pressures
Low B) Powder charge too low B) Increase gun Kv output
C) Poor earth C) Clean hooks and racks, measure earth
D) Hooks or racks robbing D) Redesign or reduce the size of the hooks
powder from parts or racks
E) Improper gun position E) Maintain 150mm to 300mm gun tip to
part distance
Film Thickness too A) Powder output too high A) Turn down pump pressures, move guns
High farther away from parts
B) Excessive coating time B) Increase conveyor speed, reduce gun
voltage as last resort
Powder “Staring” A) Excessive film build A) Reduce powder output from guns
Back Ionisation B) Poor earth B) Clean hooks and racks, check earth
C) (If re-coat) C) Reduce gun Kv output
37
Coating Appearance & Performance Problems
PROBLEM POSSIBLE CAUSE POSSIBLE SOLUTION
Gloss too High A) Cure temperature too low A) Increase oven temperature
B) Oven cycle too short B) Decrease line speed
Gloss too Low A) Oven temperature too high A) Reduce oven temperature
B) Time in oven too long B) Increase line speed
C) Contamination with C) Remove all contaminated powder,
incompatible powder thoroughly clean all equipment & re-
charge with virgin powder
38
Poor Hammer or A) Heat up rate too slow A) Ensure oven is up to temperature
Texture when parts enter oven, increase 1st
Development zone oven temperature
B) Too much reclaim powder B) Add more virgin powder
39
Foreign Matter in A) Inadequate substrate A) Check cleaning and pre-treatment
Cured Film cleaning B) Ensure powder spray environment is
B) Airborne contaminants clean
C) Sieve powder through appropriate
C) Lumpy or heat affected size screen
powder
40
Powder Gun Maintenance
Both Corona and Tribo guns require regular cleaning and maintenance to perform
optimally.
Recommended cleaning frequency is only a guideline; every system is unique and may
require more or less frequent cleaning and maintenance.
Cleaning and Impact Fusion
Impact fusion is heat-fused powder that has built-up onto the surfaces inside powder guns,
hoses and pumps. Heat generated by friction as the powder is conveyed through the
pumps hoses and guns causes the powder to melt. Higher pump operating pressures will
increase friction and generate more impact fusion.
If impact fused powder is not cleaned from the parts, it will continue to build and eventually
block passageways and reduce powder output from the guns. All powder pathways should
be cleaned regularly to remove impact-fused powder.
Some powder formulations are more prone to impact fusion than others, mainly those with
lower Glass Transition temperatures.
Compressed air and soft brushes should be used to clean impact fused powder. Avoid
using anything that will scratch or cut the parts as this will further promote impact fusion.
Corona Guns
Disassemble guns to clean and inspect internal parts for wear every 4 hours of
continuous operation.
Note: Compressed air should not be blown into the gun when feed hose is
connected, this can cause damage to the gun controller if powder enters
pneumatic components.
Replace any worn parts as recommended by the equipment manufacturer.
If gun controller has a Micro Amp display, this should be regularly monitored to
help identify potential problems with gun charging. A very high reading (90 plus)
indicates a short circuit, a very low reading (0 –10) indicates an open circuit.
Note: Read current with maximum Kv while gun tip is at least 250mm from parts
or booth wall.
Have actual gun voltage output measured every 6 months or at first sign of fault.
41
Tribo Guns
Disassemble guns to clean and inspect internal parts for wear every 4 hours of
continuous operation.
Replace any worn parts as recommended by the equipment manufacturer.
Some Tribo guns have reversible charge tubes; the life of these charge tubes can
be greatly increased if they are regularly reversed.
Most Tribo guns have a current feedback meter that measures Micro Amps; this
gives an indication of how well the powder is accepting a charge. This is the only
method to gauge the performance of the Tribo gun.
Hoses
Powder feed hoses should be cleared with compressed air every 4 hours of
continuous operation.
Powder feed hoses should be removed and (crushed) to break up impacted
powder every 30 days.
Hoses should be as short as possible with minimal bends.
42
Manual Powder Spray Touch-Up
Depending on the complexity of the parts and the feasibility of fully coating automatically,
manual operators may be required to reinforce certain areas of the parts. Manual touch –
up can be before or after the automatic guns.
Disadvantages
More difficult to apply powder into Faraday Cage areas.
Disadvantages
Part presentation and automatic gun operation must be precise and predictable.
Operators must be completely familiar with every part and its touch-up
requirements.
Many powder coatings are manufactured by blending a base powder with other materials
or additives to create a special effect. These powder coatings can be more difficult to apply
and to reclaim.
Metallic powders or other multi component powders may require unique application
techniques and special equipment to apply them effectively. Some of these powders can
not be reclaimed, or can only be reapplied when mixed in low concentrations with virgin
powder.
This is due the imbalance between the base powder and the metallic flakes or other post
blended materials that may have occurred during the initial spray application and / or by
processing through the recovery system.
43
Different brands and models of Corona guns charge the metallic flakes differently,
either laying the flakes down or standing them more on edge. This can produce
inconsistent finish appearance.
Preferential Charging
This occurs when one or more of the post blended components of the powder
charges more or less efficiently than another. For example: Metallic flakes
generally accept a charge and transfer to the earthed substrate more efficiently
than the base powder material. Therefore, the reclaim powder may have
substantially less metallic flake and if re-applied will look very different than the
virgin powder finish.
Reclaim Separation
Dry Spray
This occurs when the base powder does not cover the metallic flakes, the metallic flakes
flow to the surface and the result is a dull appearance and a rough texture. Reducing the
powder gun voltage may help. Consult powder supplier.
44
Exterior Exposure
Most Metallic and Special effect powders are not suitable, or may require a clear powder
coating over top for exterior use. Always refer to the product data sheet or consult the
powder supplier.
Specific Gravity
Specific Gravity (SG) is the density of the powder relative to water. The lower the SG the
greater the coverage (mileage) at the same applied thickness. The typical range for
powder coatings is between 1.3 SG and 1.7 SG depending on the levels of pigment and
extender.
Theoretical Coverage
To calculate the cost of the powder to cover one (1) square metre divide the cost per Kg of
the powder by the square metre coverage per Kg as calculated above.
Example: Cost is Rs150 per Kg of a powder applied at 50 microns that will coat 13.33
square metres.
150 / 13.33 = 11.27 rupees per square metre
45
Powder Losses
(Must be taken into consideration when calculating applied powder costs)
Average Range
Transfer Efficiency 10% to 75%
Booth Recovery System 1% to 15%
Hooks and Racks 2% to 25%
Spillage and Waste 1% to 5%
Rework <1% to 5%
46
Curing Powder Coatings
After the powder coating is applied the parts must be processed in a curing oven to reflow
and convert the powder particles into a continuous cured film. Different powder chemistries
and formulations require different curing cycles. It is essential that the specified cure
schedule be followed to ensure that the powder coating is fully cured and will perform
optimally.
Under-cure can sometimes be visually recognised by increased gloss level.
Over-cure can sometimes be recognised by lower gloss or discolouration.
Cure cycle – Example: 10 minutes at 200oC. This refers to the metal temperature.
Therefore, depending on the density of the substrate, shorter or longer oven dwell times
will be required in a conventional oven. Regular testing of cured film and periodic oven
recordings are recommended to ensure the powder coating is being properly cured.
Ovens
Oven Types
Direct and Indirect Gas Fired Convection
Electric Convection
Gas Infrared
Short and Medium Wave Electric Infrared
Induction
Direct fired gas convection ovens are the most commonly used for both dry off and curing.
Gas is typically less expansive to operate than electric, and convection heating is more
forgiving than infrared.
47
Boost Ovens
As businesses grow and production levels increase, often time’s line speeds are increased
and curing oven dwell times are reduced. To compensate the oven temperature is raised
to achieve an adequate cure. This can cause problems when the line stops and parts over-
cure, causing a reduction in gloss or coating discolouration.
A cost-effective solution can be installing an Infrared boost oven in front of the existing
convection oven. Infrared boost ovens can raise the part temperature quickly and allow the
undersized cure oven to operate at a lower more forgiving temperature.
Gas Infrared and Medium to Longer wave electric Infrared ovens are more suitable for
larger complex parts.
Short wave / High Intensity Infrared can be very effective for simple – flat, or very small
parts where all surfaces are within line of sight of the heating elements.
Boost ovens should always be interlocked with the conveyor to prevent parts from
discolouring / over curing should the line stop while parts are inside oven.
Oven Maintenance
All types of ovens need to be cleaned and maintained to ensure they consistently operate
efficiently.
Gas convection oven burners require periodic adjustment and cleaning, air circulation fans
may have belts that will require tightening and bearings that require lubrication.
Oven temperature recordings using a device that measures both air as well as part
temperature should be carried out regularly to ensure proper powder cure is achieved.
Gaps in convection oven panels can be sealed using Dow Corning 736 RTV. Local oven
builders have recommended this sealant.
Oven Cleaning
The interior of convection ovens can become dirty; the debris can loosen and contaminate
the powder coated parts as they pass through the oven.
Infrared oven reflectors will become dirty causing the oven to be less efficient. Depending
on the type of deflector they may require cleaning and polishing.
Oven interiors that have corroded and have loose scale can be cleaned with wire brushes
and coated with deodorised fish oil to seal the affected areas. Fish oil is available locally
from Blackwoods.
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Powder Booth Design Considerations
Over-sprayed powder that has not been attracted to the parts must be contained and
collected. An effective powder booth recovery system will contain all of the over-sprayed
powder within the booth canopy.
Excessive booth airflows will prevent the charged powder from depositing on the
parts and reduce transfer efficiency. Insufficient booth airflow will not contain the
over-sprayed powder inside the booth.
Australian standard requires a minium of .4 metres per second air velocity
through all openings in the powder booth.
The maximum concentration of powder within the booth should be 50% below the
LEL – Lower Explosion Limit of the powder. Most powder coatings have an LEL
of between 35 and 90 g/m3. Akzo Nobel recommends that a maximum of 10
g/m3 of air should not be exceeded. A general rule is not to exceed 1 gun per
cubic metre of booth interior.
If multiple powders are to be reclaimed in the same booth, design features for
fast and thorough cleaning should be incorporated.
Smooth seamless interior walls, rounded corners, seamless ducting, and non-
conductive booth walls will speed colour change times.
There should be adequate clearance between the overhead conveyor and the
conveyor slot in the top of the powder booth. This will prevent any over-sprayed
powder that may migrate out of the booth from coating the conveyor, chain and
load contact points. A minimum of 450mm clearance between the conveyor rail
and the top of booth is recommended.
A minimum clearance of 450mm from the top of the parts to the powder booth
ceiling is also recommended to prevent excessive over-sprayed powder from
collecting on booth ceiling, and from migrating out of the conveyor slot.
There should be adequate clearance between the manual operator openings and
the automatic gun slots to prevent over-sprayed powder from the automatic guns
coating the operators. Adequate space between the manual operators will
prevent them from coating each other.
The booth canopy should be wide enough to allow at least 250mm between the
automatic gun tips and booth wall behind the guns. This will prevent the powder
from being attracted away from parts and back to the walls of the powder booth.
The booth canopy should be wide enough to allow at least 250mm-gun tip to the
part distance.
Cyclone technology is more suitable for shorter colour runs where multiple
powders are to be reclaimed.
Cartridge technology is more suitable for larger colour runs where fewer colours
are to be reclaimed.
Cyclones systems are a good choice when there are many colours to reclaim.
Cartridge Filters systems are a good choice for larger production runs of fewer
colours.
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Cyclone Powder Booths
Air along with reclaimed powder is drawn into the cyclone a centrifugal force spins the air /
powder mixture around the interior of the cyclone. Heavier powder particles settle in the
bottom and are collected in a container and reused or discarded. Alternatively the powder
can be automatically pumped back to the gun feed hopper for re-application.
The smaller lighter particles along with the air are drawn up through the centre tube and
from there go to a water scrubber, cartridge filter collector or a bag house. This powder is
considered waste.
Efficiencies of cyclone systems will generally range from between 85% and 95%.
Multi Cyclones
Smaller cyclones (500 to 1000 CFM each) are built into a single module that can be
attached directly to the powder booth sidewall or remotely positioned and connected to the
powder booth base by ducting. A cartridge after filter collector is most commonly used.
The benefits of Multi Cyclones are faster / easier colour change due to the smaller size
and accessibility. The smaller cyclones are generally more efficient.
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Cyclone Recovery System Operation and Maintenance
Reclaim powder is collected at the bottom of the cyclone in a bucket or surge
hopper that automatically pumps the powder back to the feed hopper for re-
application, or to a scrap drum for disposal.
Powder that passes through the cyclone (powder fines) is collected by the after
collector – Cartridge Filter or Water Scrubber, and is considered waste.
Cyclones generally have no moving parts and require only cleaning for colour
changing. Interior surfaces that are impacted by high velocity powder can
develop a heavy build-up of impact fused powder. This impact-fused powder if
allowed to build heavy enough will break loose and cause contamination.
Some cyclones have a fan built into the top of the cyclone and these may require
regular cleaning and greasing of the bearings. Other systems have the fan
located in the after collector.
The ducting between the powder booth and cyclone may also develop heavy
impact fused powder build-up that will require removal to prevent potential
contamination.
It is common practise to spray to waste the first (10Kg Approx) of powder
collected by the cyclone before reclaiming to minimise the risk of contamination.
Advantages of Cyclones
Generally less expensive than cartridge systems.
Have capability of reclaiming infinite amount of colours.
Removes fine powder particles that can sometimes cause problems.
Disadvantages of Cyclones
Depending on cyclone efficiency as much as 15% of reclaimed powder can be
lost.
Colour changing can be time consuming and difficult because of ducting.
Although very rare, cyclones can explode.
Water Scrubbers
Most water scrubbers are installed after cyclones and are used to capture the ultra fine
particles that pass through the cyclones. Water scrubbers work by creating a series of
water curtains or umbrellas that the air and powder must pass through before exiting the
system. The water traps the powder and washes it down into a tank where it must be
manually removed as powder sludge. Water is continuously circulated from the sump to
the spray nozzles.
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Cartridge Filter Powder Booths
Cylindrical cellulose or synthetic filters separate over-sprayed powder particles from
processing air. Powder is pulsed from between the pleats and surface of the filters by a
compressed air pulse valve positioned over the interior of the filter. Re-claimed powder is
collected in fluidised beds under the filters and can then be pumped back to the gun feed
hopper or to a waste container. Filtered air is then processed through a secondary set of
filters.
Cartridge systems are typically over 99% efficient.
Advantages
Highest reclaim efficiency.
Quick colour changes with dedicated modules.
A single spray to waste module can be used for smaller non-reclaim colour runs.
No risk of explosion.
Disadvantages
A dedicated filter module is required for every reclaim colour and this is costly.
Extra colour modules take up floor space.
If not carefully managed, powder fines can build up and create problems.
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Cartridge Recovery System Operation and Maintenance
A fan draws air and over-sprayed powder through the cartridge filters, the
cartridges separate the air and the powder. The powder is pulsed from between
the pleats of the cartridges and recovered inside the filter module. The air is
generally passed through a secondary set of filters and returned to the factory.
Cartridge filters are reversed pulsed with dry compressed air during operation
and should not be cleaned in any other way.
The life expectancy of the cartridge filters should be at least 12 months if the
system is properly designed and maintained.
Filters can be easily damaged during installation, always follow manufactures
instructions.
Reverse compressed air pulsing valves can fail and should be inspected
regularly to ensure all cartridge filters are being properly cleaned.
Most systems have adjustable pulsing; there are (3) separate adjustments that
can affect the cleaning of the cartridge filters. The equipment supplier should be
consulted on most effective adjustment for each of the following:
1. Pulse Pressure 2. Pulse On-Time 3. Pulse Off-Time
It is recommended that all cartridge collector systems be fitted with a gauge to
measure differential pressure across the filters. This will give an indication of how
clean or blocked the cartridges are.
Motor and Fan bearings may require greasing.
Reclaiming Considerations
Virgin powder is manufactured to a specified particle size distribution and this varies
depending on the application and the manufactures production practices. When virgin
powder is applied through both Corona and Tribo guns, a higher proportion of the larger
particles are deposited onto the parts. This is due to the larger particles holding more
overall charge than the smaller particles, and the smaller particles being more likely to be
drawn away in the booths air currents.
Cyclone recovery system will classify (remove) a certain amount of the fine
particles depending on its design efficiency.
Cartridge recovery systems will recover virtually all over-sprayed powder
including the very fine particles. Reclaim powder will generally apply less
efficiently than virgin powder.
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Contamination
Colour, incompatible powders, dirt, fibres and other foreign particles can easily
contaminate the powder while it is being exposed to the equipment and environment.
Good housekeeping practices and operating procedures are essential to successfully
process reclaimed powder.
Particle Size
Reclaimed powder always has a shift in particle size distribution from virgin powder; this
can alter powder transfer efficiency, finish appearance and handling characteristics.
Fines Build-Up
Fine particles in higher concentrations can cause many handling and application problems.
Fines build-up is more common in Cartridge filter systems.
Specialty Powders
Powders such as metallic’s, spangles, and textures may be manufactured using a post dry
blending process and may be difficult to reclaim. This is primarily due to preferential
charging and recovery system classification. Consult the powder-coating supplier.
Vibratory Sieves
An electrical or pneumatic vibrator shakes a screen in an up / down motion to pass the
powder through the screen. Models range from very basic designs to complex high
efficiency large capacity models incorporating ultrasonics to help keep the screen clean.
Basic models will sieve through a 400 to 900 micron screen, upper end models to as small
as 100 microns.
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Rotary Sieves
An electric motor drives an auger that channels the powder into a cylindrical sieve screen
where paddles then push the powder through the screen. Any particles too large to pass
through the screen are deposited into a waste bucket. Rotary sieves are typically used
when sieving below 300 microns is desired.
Screen Sizes
Depending on the finish quality requirement commonly used screen opening sizes range
between 105 and 400 microns. For a Class A Finish, i.e. Appliance - a 140-micron or
smaller opening would be recommended.
Operating Recommendations
Maximise First Pass Transfer Efficiency – Line density, Part presentation,
Earthing, Gun Positioning, Gun settings.
Squeegee powder from booth interior as often as possible.
Maintain a minimal amount of reclaim powder in the system, always be
transferring reclaim powder back to the gun feed hopper.
Add Virgin powder in small regular doses to keep the gun feed hopper full.
Maintain transfer pumps, hoses and sieve screens to ensure consistent reliable
performance.
Colour Changing
Many powder-coating operations process any number of different colours. Some will
change colour many times per day and others every few days or weeks.
Changing colours can be very labour intensive, time consuming and costly.
Every effort should be made in scheduling production to allow for the longest colour runs
possible.
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Equipment to Reduce Colour Change Times
Tools such as squeegees, rags, air nozzles, vacuum cleaners
Dedicated gun feed hoses for dark and light colours or for every colour
Spare hoppers or dedicated hoppers for every colour
Extra set of gun feed pumps
Extra set of guns
Roll away booth canopies
2 complete roll away – on / off line systems (fastest colour change)
Contamination
Contamination is one of the most common and troubling problems in the powder coating
process; there are many potential sources of contamination in most powder coating plants.
Extreme care and good house keeping procedures must always be practised to minimise
the risk of contamination.
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Compressed Air Supply
Because all powder application equipment requires compressed air to operate, and the air
is directly exposed to the powder, any oil or moisture in the compressed air will
contaminate the coated parts.
Compressed air should be maintained to the standard detailed under compressors and
driers.
A second coating can usually be applied directly over the first coat; there are some
considerations and exceptions however.
First coat can act as an insulator to the earthed part and back ionisation can
occur (Staring). Reducing corona gun KV output will usually help overcome this
problem.
Some powders will not have good intercoat adhesion – (adhesion between
coats), re-coating may not be possible and parts may then require stripping. It is
essential to test adhesion any time parts are re-coated.
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Powder Coatings on Site Test
Depending on the coating specification, there are recommended on-site tests that should
be performed to help ensure the applied powder coating will meet the specified
performance requirements.
Listed below are some of the most common in-plant tests.
Water Break test – Visually inspect the parts as parts as they exit the final rinse
stage. Surface should be completely wetted out, water breaks or droplets indicate
that the parts are not properly cleaned.
White Rag test - Rub a white rag on dry pre-treated part to evaluate cleanliness.
Solvent cure test – Usually straight MEK or a less aggressive solvent is applied
to the powder coated part and resistance to the solvent is used to evaluate the
degree of cure.
Adhesion test – Cross Hatch tape pull test to evaluate the powder coating
adhesion to the substrate.
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Powder Coatings - Laboratory Tests
Descriptions of the most common laboratory tests used to evaluate powder-coating
performance on parts.
Humidity
Parts are scribed through the coating to the metal substrate and placed in the humidity
chamber exposing the part to 100% humidity at 38 oC for a predetermined time. Parts are
evaluated for loss of adhesion and blistering.
QUV
Powder coated panels are exposed to cycles of Ultra Violet at 50oC and condensation at
40 oC. Typically 4 hour cycles of each. Parts are then evaluated for Colour and Gloss
retention.
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Permeability
Part is placed in a pressure cooker with De-ionised water. Part is evaluated for loss of
adhesion.
Reverse Impact
Powder coated panel is subjected to impact from the UN-coated side and given a rating in
Joules that the coating will resist cracking.
Taber Abrasion
A pre-weighed powder coated panel is rotated under a weighted abrasive material for a
preset time. At completion of the test the panel is weighed to determine the amount of
coating loss.
Fluidising (R-Factor)
A pre weighed amount of powder is placed into a small fluidising test hopper. The height is
measured before and after applying fluidising air. While the powder is fluidising it is
allowed to flow through a small tube into a container for a preset amount of time. This
powder is weighed and a calculation is done to determine the R factor. The higher the
number the better the powder will fluidise.
Erichsen Cupping
A slow reverse impact test measures coating flexibility and a result is given in millimetres
just before the coating cracks.
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Differential Scanning Calorimeter (DSC)
Used to evaluate the degree of cure (not suitable for TGIC free polyester powders). A
small sample of cured powder film can be scraped from the part and placed in DSC. The
DSC measures thermal reactivity to determine if the powder sample was fully cured.
Production Throughput – Record conveyor line speed and the volume of parts
and or square metre of substrate processed per shift.
Pretreatment Chemicals – Record chemical concentrations, pH and heated
tank temperatures.
Maintain records on tank cleaning and purging.
Ovens - Record oven settings and document any maintenance performed, retain
all oven temperature recordings.
Powder Coating – Record powder product, batch, box numbers and the date
and time used.
Powder Application - Record gun positions, gun settings, reciprocator speeds,
and conveyor speed for different type parts.
Powder Booths - Record filter differential pressure, filter pulsing pressures,
transfer pump settings, fluidising pressures.
Film builds – Record low, high and average coating film-builds.
Quality Assurance – Maintain records on all coating performance testing, both
on-site and off-site.
Rejected Parts – Maintain a record of all rejected parts detailing the cause ie.
Light / heavy powder, gun spit, contamination, etc.
Equipment Maintenance – Document replacement spare parts usage and any
repairs performed.
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Test Standards & Associations
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Handling of Powder Coated Parts
Although properly applied and processed powder coated parts are generally quite durable,
they can still become damaged during handling and shipping transport. Cardboard as an
example is very abrasive and the vibration experienced during transportation on a truck
can scratch and mar the coated surface. Parts should never be handled or packaged while
still hot or warm after exiting the cure oven. Parts should be allowed sufficient time to cool
down to ambient temperature before being handled. Packing materials such as plastic
bags and wrapping, coated paper and padding are often used to protect coated parts
during handling and transport.
Safety
Many different processes take place in any powder coating plant and each has its own
safety concerns and requirements.
Powder coatings and chemical solutions should have both product data sheets and
Material Safety Data Sheets (MSDS). These documents should provide in detail the
recommended use and safe handling procedures and these should always be adhered to.
Equipment suppliers should be individually consulted for safety procedures involving the
use and maintenance of their equipment. Local government agencies can also provide
information on safety regulations and requirements for their regions.
Parts and all related powder equipment should be properly earthed to prevent charge
build-up and arching, which could potentially ignite powder coatings.
In the unlikely event that a fire occurs all associated equipment and compressed air supply
should immediately be switched off.
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Powder Coating in the Future
Much development work is being done to reduce powder temperature and dwell time
curing schedules. Ultra Violet curing powders are also being developed for the timber and
plastics markets that represent the greatest future growth for powder coating.
Thin and Ultra Thin Film products continue to be developed and should become more
widely used. These new technologies will significantly reduce the applied cost and make
coil and blank coating more feasible for powder coating.
New powder manufacturing technology will allow faster turnaround on special colours.
Powder application equipment suppliers will be introducing more efficient guns and faster
colour change recovery systems.
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