21. WS on Modules 2.1 to 2.4 At.

Structure ( upto Bohrs model)

By Kishan Kumar Asokkumar
WS on Modules 2.1 to 2.4 Atomic Structure

1. List the postulates of Bohr’s Model of atom.

2. List the merits of Bohr’s Model over Rutherford’s model.
3. How the corpuscular theory does explain photoelectric effect?
4. The kinetic energy of an electron is 4.55 x 10-25 J. Calculate the wavelength.
5. Calculate the energy associated with the first orbit of He+. What is the radius of this orbit?
6. Calculate the wavelength of the first and the last line in the Balmer series of hydrogen spectrum.
7. What is the wavelength of the yellow sodium emission which has a frequency of 5.09 x 1014m/s?
8. The red spectral line of lithium occurs at 671 nm. Calculate the energy of one photon of this light.
9. Calculate the wave number for the shortest wavelength transition in the Balmer series of atomic hydrogen.
10. The wavelength of 1st spectral line in the Balmer series is 6561 . Calc. the wavelength of the 2nd line in Balmer
series.
11. The wavelength of a beam of light is 42.0 mm. What is (a) its wavelength in cm (b) its frequency (c) its wave number (d)
the energy of one of its photons
12. Calculate KE of the ejected electron when yellow light of frequency 5.2 x 1014 sec-1 falls on the potassium metal.
Threshold frequency of potassium is 5 x 10 14sec-1.
13. Applying Bohr’s model calculates the wavelength of the radiation emitted when an electron in a hydrogen atom makes a
transition from fourth energy level to first energy level.
14. What is the difference between the (i) continuous spectrum & line spectrum (ii) Balmer formula & Rydberg Formula (iii)
Emission spectrum & absorption spectrum (iv) molarity & molality (iv) cathode rays & anode rays
15. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes transition from the energy
level n=4 to the energy level with n=1? In which region of the electromagnetic spectrum does this radiation fall?

WS on Modules 2.1 to 2.4 Atomic Structure

16. List the postulates of Bohr’s Model of atom.

17. List the merits of Bohr’s Model over Rutherford’s model.
18. How the corpuscular theory does explain photoelectric effect?
19. The kinetic energy of an electron is 4.55 x 10-25 J. Calculate the wavelength.
20. Calculate the energy associated with the first orbit of He+. What is the radius of this orbit?
21. Calculate the wavelength of the first and the last line in the Balmer series of hydrogen spectrum.
22. What is the wavelength of the yellow sodium emission which has a frequency of 5.09 x 1014m/s?
23. The red spectral line of lithium occurs at 671 nm. Calculate the energy of one photon of this light.
24. Calculate the wave number for the shortest wavelength transition in the Balmer series of atomic hydrogen.
25. The wavelength of 1st spectral line in the Balmer series is 6561 . Calc. the wavelength of the 2nd line in Balmer
series.
26. The wavelength of a beam of light is 42.0 mm. What is (a) its wavelength in cm (b) its frequency (c) its wave number (d)
the energy of one of its photons
27. Calculate KE of the ejected electron when yellow light of frequency 5.2 x 1014 sec-1 falls on the potassium metal.
Threshold frequency of potassium is 5 x 10 14sec-1.
28. Applying Bohr’s model calculates the wavelength of the radiation emitted when an electron in a hydrogen atom makes a
transition from fourth energy level to first energy level.
29. What is the difference between the (i) continuous spectrum & line spectrum (ii) Balmer formula & Rydberg Formula (iii)
Emission spectrum & absorption spectrum (iv) molarity & molality (iv) cathode rays & anode rays
30. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes transition from the energy
level n=4 to the energy level with n=1? In which region of the electromagnetic spectrum does this radiation fall?

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 For Balmer series = 109677 n1= 2,n2= 109677 = 27419.25 cm-1
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Energy of electron in nth orbit is En = J atom -1

For first orbit of He+, Z =2, n=1 E1 = x (2)2 J atom -1

Radius of nth orbit is rn= nm r1= = 0.02645 nm

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Rydberg equation 🡪 =R

For first line in Balmer series, n1=2,n2 =3 =R =R ….(i)

For second line in Balmer series, n1 =2 ,n2=4 =R =R= ….(ii)

Dividing eq.(i) by (ii), = = = 4860

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For the first line in Balmer series n1 = 2 andn2 = 3

= 109677 x cm-1 =15232.9

cm-1 = 6.565 x 10-5 cm = 656.5 nm

For the last line in Balmer series n1= 2 and n2 = = 109677 =109677

= 109677 x cm -1 =27419.3 cm-1 = 3.647 x 10-5 cm = 364.7 nm.

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Energy of fourth energy level, E1 = - J/ atom

Energy of first energy level, E1 = - - J/atom

E4 – E1 = 2.18 x 10-18 J/atom = 2.04 x 10-18 J/atom

This energy is given out in the form of a single photon or quantum of radiation.

= hv or =
Substituting for h= 6.63 x 10-34 Js

and c = 3.00 x 108 ms-1 we get = = 9.7 x 10-8m =97 nm.

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