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Proj. Nuclear Chemistry
Proj. Nuclear Chemistry
Proj. Nuclear Chemistry
School
NUCLEAR CHEMISTRY
Submitted by Submitted to:-
ISHAN MURJHANI Ms. Veenu Murjhani
XII A PGT CHEMISTRY
ACKNOWLEDGEMENT
I would like to express my sincere gratitude towards
my mentor, Ms. Veenu Murjhani who blessed me
with this opportunity of exploring the deep secrets of
“Nuclear Chemistry” which also happens to be the
topic of my investigatory project.
__________ _________
Internal’s sign Principal’s Sign
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External’s sign School Seal
INDEX
1
fundamental constituent of any matter obviously holds the
energy. Researchers, by studying the structure of atom in
great detail, found that most of the energy of atom lies
within its nucleus. Hence it was important to unlock the
secret of nucleus.
2
generate heat and, subsequently, electricity. This process is
also one of the basics of nuclear weapons that were
developed in the U.S. during World War II and used against
Japan in 1945.
3
nucleus is less than the sum of the individual masses of the
free constituent protons and neutrons, according to
2
Einstein's equation E=mc . This 'missing mass' is known as
the mass defect, and represents the energy that was
released when the nucleus was formed.
The term "nuclear binding energy" may also refer to the
energy balance in processes in which the nucleus splits into
fragments composed of more than one nucleon. If new
binding energy is available when light nuclei fuse (nuclear
fusion), or when heavy nuclei split (nuclear fission), either
process can result in release of this binding energy. This
energy may be made available as nuclear energy and can be
used to produce electricity, as in nuclear power, or in a
nuclear weapon. When a large nucleus splits into pieces,
excess energy is emitted as photon (gamma rays) and as the
kinetic energy of a number of different ejected particles
(nuclear fission products).
These nuclear binding energies and forces are on the order
of a million times greater than the electron binding energies
of light atoms like hydrogen.
The mass defect of a nucleus represents the amount of mass
4
2
equivalent to the binding energy of the nucleus (E=mc ),
which is the difference between the mass of a nucleus and
the sum of the individual masses of the nucleons of which it
is composed.
5
Sometimes atoms aren’t happy just being themselves; they
suddenly change into completely different atoms, without
any warning. This mysterious transformation of one type of
element into another is the basis of nuclear reactions, which
cause one nucleus to change into a different nucleus. Just
like chemical reactions cause compounds to turn into other
compounds by swapping their electrons, nuclear reactions
happen when the number of protons and neutrons in the
nucleus of an atom change.
Some types of nuclear reactions can actually kick protons
out of the nucleus, or convert them into neutrons. Since we
know what to call an element by looking up its number on a
periodic table and then reading off its name, when the
atomic number (number of protons) changes, so does the
name of the element. This makes nuclear reactions look
somewhat like alchemy: an atom of potassium (atomic
number 19) can suddenly and unexpectedly transform into
an atom calcium (atomic number 20). The only sign that
anything has changed is the release of radiation, which we’ll
talk more about in a little bit.
Even more strangely, nuclear reactions often occur almost
entirely randomly. If you have a single nucleus that you are
6
certain will eventually decay into a different nucleus, you
still have only a rough idea how long it will take for you to
see it happen. You could be sitting watching the nucleus for
anywhere between a few seconds to your entire lifetime,
and at some point it would suddenly decay without any
warning! However, depending on the type of nucleus, you
can predict how long on average it would take to decay if
you watched many nuclei at once. So while the average
time to decay is a measurable number (for potassium it’s
over a billion years), the exact time of the decay is entirely
random.
There are three types of nuclear reaction, each of which
cause the nucleus to shoot out a different, fast-moving
particle (like a photon or electron). These released particles
are a side effect of the element changing its atomic number
or mass, and they are what scientists generally mean when
they warn about nuclear radiation, since fast-moving
particles can act like tiny bullets that poke holes in your
body. However, much nuclear radiation is actually harmless,
and it occasionally can be harnessed to provide new type of
medical or diagnostic tools.
7
Why do nuclear reactions happen?
a. ALPHA DECAY
During alpha decay, a nucleus actually breaks up into two
chunks: a pair of protons bound to a pair of neutrons (a
collection of four particles which is essentially a helium
nucleus, and is called an alpha particle), and another piece
constituting the original nucleus minus this chunk. So we
can actually write down a chemical reaction equation for
alpha decay:
Ra → Rn + He^{2+}
2+
The radium nucleus (Ra, atomic number 88) breaks up into
the helium nucleus (He^{2+}
2+
, the little chunk) and a daughter nucleus that corresponds
10
to the element radon (Rn, atomic number 86). The medical
risks
associated with radiation usually involve the fast
speeds at which the products of nuclear reactions
move.Think of the alpha particle released by this reaction as
a tiny bullet, which can puncture soft tissues like the lining
of the stomach and lungs. Fortunately, alpha decay tends to
release large, slow-moving decay products, and so it’s easy
to shield against this type of radiation.
The reaction shown above illustrates another, indirect
method by which alpha decay can pose a hazard. Radium,
the element on the left hand side of the reaction arrow, can
11
be found deep underground as a solid rock mixed in with
granite. However, when it undergoes alpha decay it turns
into radon, which naturally prefers to be a gas. The radon
then seeps out of the ground and into the basements of
people’s homes, where it can enter their lungs and then
decay again, releasing more alpha particles (or other types
of radiation) directly into the unprotected tissues. This
method of radon exposure represents a major lung cancer
risk factor in many parts of the world.
b. BETA DECAY
decay
into calcium-40 (Ca). Symbolically, this reaction looks
like:
K→ Ca + e^- + v
In addition to changing its atomic number, the nucleus
creates and releases an electron (e-) from the atom that
serves to counterbalance the positive charge it gained by
transforming a neutron to a proton. The other released
particle v is a mysterious particle called a neutrino, which
has no charge and barely any mass. The emitted, free
13
electrons are the “radiation” associated with beta decay
This means that if you were to go to the grocery store and
buy a jar of potassium-40 isotopes (which are prone to beta
decay) and then leave it sitting on your countertop for a
couple of years, you would end up having less potassium
than you started out with (calcium would take its place).
This process happens incredibly slowly and in miniscule
numbers for the potassium chloride available in the grocery
store, and so the actual health risk posed by this radiation is
nil.
A related type of beta decay actually decreases the atomic
number of the nucleus when a proton becomes a neutron.
Due to charge conservation, this type of beta decay involves
the release of a charged particle called a “positron” that
looks and acts like an electron but has a positive charge.
Because this particle’s interactions with other tissues are
easily identifiable, some medical imaging techniques involve
purposefully injecting a patient with an element that beta
decays into positrons, and then monitoring where the
positrons are emitted. When beta decay creates a positron
it’s called beta-plus decay, and when it creates an electron
it’s called beta-minus decay.
14
C. GAMMA DECAY
15
Recall that the electrons orbiting the nucleus have energy
levels, and that each time an electron moves from a high
energy level to a low energy level it emits a photon. The
same thing happens in the nucleus: when it rearranges into
a lower energy state, it shoots out a high-energy photon
known as a gamma ray.
Gamma rays are very high energy and are one of the most
dangerous sources of radiation because photons can pass
through most common shielding materials and cause DNA
damage in living tissues. But gamma radiation also has
practical uses; for example, the element technetium emits
relatively low-energy gamma decays that can be detected
16
using a specialized scanner, and so it has found use as a
tracer element for imaging the inside of patients’ bodies.
17
This means that any long-term space travel initiative (such
as a mission to mars) will have to invest considerable
resources in properly shielding the living areas of the
spaceship with materials that are impervious to cosmic
radiation. The development of materials that can shield
astronauts is an active area of research!
Half Life
18
shortened to half-life in the early 1950s.[1] Rutherford
applied the principle of a radioactive element's half-life to
studies of age determination of rocks by measuring the
decay period of radium to lead-206.
19
C) is constantly being created in the atmosphere by the
interaction of cosmic rays with atmospheric nitrogen. The
resulting 14
C combines with atmospheric oxygen to form radioactive
carbon dioxide, which is incorporated into plants by
photosynthesis; animals then acquire 14
C by eating the plants. When the animal or plant dies, it
stops exchanging carbon with its environment, and from
that point onwards the amount of 14
C it contains begins to decrease as the 14
C undergoes radioactive decay. Measuring the amount of 14
C in a sample from a dead plant or animal such as a piece of
wood or a fragment of bone provides information that can
be used to calculate when the animal or plant died. The
older a sample is, the less 14
C there is to be detected, and because the half-life of 14 C
(the period of time after which half of a given sample will
have decayed) is about 5,730 years, the oldest dates that
can be reliably measured by this process date to around
50,000 years ago, although special preparation methods
occasionally permit accurate analysis of older samples.
Research has been ongoing since the 1960s to determine
20
what the proportion of 14
C in the
atmosphere has
been over the
past fifty
thousand years.
The resulting
data, in the
form of a
calibration
curve, is now
used to convert a given measurement of radiocarbon in a
sample into an estimate of the sample's calendar age. Other
corrections must be made to account for the proportion of
14
C in different types of organisms (fractionation), and the
varying levels of 14
C throughout the biosphere (reservoir effects). Additional
complications come from the burning of fossil fuels such as
coal and oil, and from the above-ground nuclear tests done
in the 1950s and 1960s. Because the time it takes to convert
biological materials to fossil fuels is substantially longer than
21
the time it takes for its 14
C to decay below detectable levels, fossil fuels contain
almost no 14
C, and as a result there was a noticeable drop in the
proportion of 14
C in the atmosphere beginning in the late 19th century.
Conversely, nuclear testing increased the amount of 14 C in
the atmosphere, which attained a maximum in about 1965
of almost twice what it had been before the testing began.
23
Nuclear energy is the energy in the nucleus, or core, of an
atom. Atoms are tiny units that make up all matter in the
universe, and energy is what holds the nucleus together.
There is a huge amount of energy in an atom's dense
nucleus. In fact, the power that holds the nucleus together
is officially called the "strong force."
26
Because nuclear fuel can be used to create nuclear weapons
as well as nuclear reactors, only nations that are part of the
Nuclear Non-Proliferation Treaty (NPT) are allowed to
import uranium or plutonium, another nuclear fuel. The
treaty promotes the peaceful use of nuclear fuel, as well as
limiting the spread of nuclear weapons.
27
Building nuclear reactors requires a high level of technology,
and only the countries that have signed the Nuclear Non
Proliferation Treaty can get the uranium or plutonium that
is required. For these reasons, most nuclear power plants
are located in the developed world.
Chernobyl
31
Nuclear reactors use fission, or the splitting of atoms, to
produce energy. Nuclear energy can also be produced
through fusion, or joining (fusing) atoms together. The sun,
for instance, is constantly undergoing nuclear fusion as
hydrogen atoms fuse to form helium. Because all life on our
planet depends on the sun, you could say that nuclear
fusion makes life on Earth possible.
32
BIBLIOGRAPHY
The following sources have proven to be of
utmost importance in contribution to this
project:-
Google.co.in
Wikipedia.com
Physics hypertextbook
The fabric of cosmos by Brian Greene
Fourior by 3B1B Grant Sanderson
Khan Academy
Cengage Chemistry
GRB Chemistry