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Exercise 8-9 Chemical Formula Writing and Naming of Compounds
Exercise 8-9 Chemical Formula Writing and Naming of Compounds
ELEMENTS COMPOUNDS
IONIC MOLECULAR
COMPOUNDS COMPOUNDS
gain an lose an
- electron electron +
A A A
protons < electrons protons = electrons protons > electrons
negative charge (neutral) positive charge
(anion) (cation)
- +
A A
negative charge positive charge
(anion) (cation)
A negative ion A cat has paws
Anegativeion A cation has pawsitive
charge
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
NOTE: Atoms are electrically neutral because of the equal number of protons and electrons
- +
A B
anion cation
Ionic compounds
- +
A B are ultimately
electrically neutral
species.
anion cation
How do you write
the chemical
ionic compound formula for ionic
What is the charge of compounds?
an ionic compound?
Chemical Chemical
- + symbol for + symbol for
A B cation anion
1 1 1
ionic compound
NaCl FeCl3 MgCl2
2 2 2
What do the subscripts (encircled) mean? How do we know which number to write?
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
1A REMEMBER: Atoms gain
charge by either gaining or
8A
2A losing electrons 3A 4A 5A 6A 7A
So which elements want to gain electrons?
Which elements want to lose them?
K+ Ca2+
Rb+ Sr2+
Cs+ Ba2+
Fr+ Ra2+
K+ Ca2+ Kr
Rb+ Sr2+ Xe
Cs+ Ba2+ Rn
Fr+ Ra2+
K+ Ca2+ Br- Kr
Rb+ Sr2+ I- Xe
Fr+ Ra2+
Fr+ Ra2+
Fr+ Ra2+
Fr+ Ra2+
Fr+ Ra2+
Fr+ Ra2+
+ -
Na + Cl
If both cation and anion have the same charge, write the formula directly
NaCl
NOTE: cation is written The charges of the ions
first before anion must all add up to zero.
+ -
Na + Cl
NaCl The charges of the ions
must all add up to zero.
+ - 2+ 2-
K Br Mg S
KBr MgS
Total Charge = (+1) + (-1) Total Charge = (+2) + (-2)
=0 =0
3+ -
Fe + Cl
WE USE THE CRISS-CROSS METHOD!
How about for when the charges on the ions are not the same?
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
REMEMBER: ionic
Now how do we write the formulas for ionic compounds? compounds are neutral
3+ 1-
Fe + Cl
WE USE THE CRISS-CROSS METHOD!
How about for when the charges on the ions are not the same?
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
REMEMBER: ionic
Now how do we write the formulas for ionic compounds? compounds are neutral
Fe 1- + Cl3+
Fe1Cl3
WE USE THE CRISS-CROSS METHOD!
How about for when the charges on the ions are not the same?
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
REMEMBER: ionic
Now how do we write the formulas for ionic compounds? compounds are neutral
Fe 1- + Cl3+
FeCl3 Check that the charges
add up to zero!
+ 2-
Na O
2+ 3-
Na2- O+ Ca N
Na2O
Total Charge = 2(+1) + (-2)
= 2 + (-2)
=0
Na2- O+ Ca 3- N 2+
Na2O Ca3N2
Total Charge = 2(+1) + (-2) Total Charge = 3(+2) + 2(-3)
= 2 + (-2) = 6 + (-6)
=0 =0
+ -
Na NO3
1+ 1-
Na NO3
2+ -
Na 1- NO3 1+ Ca NO3
NaNO3
Total Charge = (+1) + (-1)
= 1 + (-1)
=0
Na 1- NO3 1+ Ca - NO3 2+
NaNO3 Ca(NO3)2
Total Charge = (+1) + (-1) Total Charge = (+2) + 2(-1)
= 1 + (-1) = 2 + (-2)
=0 =0
+ 2-
Li SO4
2+ 3-
Li 2- SO4 + Ca PO4
Li2SO4
Total Charge = 2(+1) + (-2)
= 2 + (-2)
=0
Li 2- SO4 + Ca 3- PO4 2+
Li2SO4 Ca3(PO4 )2
Total Charge = 2(+1) + (-2) Total Charge = 3(+2) + 2(-3)
= 2 + (-2) = 6 + (-6)
=0 =0
NH4 2- SO4 +
(NH4)2 SO4
Total Charge = 2(+1) + (-2)
= 2 + (-2)
=0
1 2
NaCl LiNO3
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Chemical Formulas – Ionic Compounds
Recognizing ionic compounds
Classify the following compounds as ionic or non-ionic:
SrCl2 IONIC
NH4Cl IONIC
Na +
sodium ion
Fr +
francium ion
1. COMMON SYSTEM
stem of element name + -ous
or
stem of element name + -ic
-ous is used for the ion with the lower charge
-ic is used for the ion with the higher charge
REMEMBER “OSLO” – “OUS LOW”
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Ionic Compounds
The Cations 1. Cations that can only have one charge.
2. Cations that have multiple stable ionic forms.
1. COMMON SYSTEM
Element: iron
Latin name: ferrum
Stem: ferr
Fe2+
ferrous ion
Fe3+
ferric ion
1. COMMON SYSTEM
Element: copper
Latin name: cuprum
Stem: cupr
Cu+
cuprous ion
Cu2+
cupric ion
Element: lead
Latin name: plumbum
Stem: plumb
Pb 2+
plumbous ion
Pb 4+
plumbic ion
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Ionic Compounds
The Cations 1. Cations that can only have one charge.
2. Cations that have multiple stable ionic forms.
Stock or IUPAC system used frequently in chemistry, while the common system is still used in medicine.
F - Cl- Br- I-
fluorine chlorine bromine iodine
fluoride ion chloride ion bromide ion iodide ion
+ +
name of anion name of anion
MgI2
What are the ions that make up this ionic compound? (reverse criss-cross)
2+ -
Can
magnesium
possess
Mg I
more than
one charge?
magnesium iodide
NO ion ion
MgI2
What are the ions that make up this ionic compound? (reverse criss-cross)
2+ -
Can
magnesium
possess
Mg I
more than
one charge?
magnesium iodide
NO
MgI2
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Ionic Compounds
Na2O
What are the ions that make up this ionic compound? (reverse criss-cross)
+ 2-
Can sodium
possess
Na
sodium
O
more than oxide
one charge?
ion ion
NO
Na2O
What are the ions that make up this ionic compound? (reverse criss-cross)
+ 2-
Can sodium
possess
Nasodium oxide O
more than
Na2O
one charge?
NO
FeCl3
What are the ions that make up this ionic compound? (reverse criss-cross)
3+ -
Can iron
possess
Fe Cl
more than
one charge?
iron (III) ion chloride
YES ferric ion ion
FeCl3
What are the ions that make up this ionic compound? (reverse criss-cross)
3+ -
Can iron
possess
Fe Cl
more than
one charge?
iron (III) chloride
YES ferric chloride
FeSO4
What are the ions that make up this ionic compound? (reverse criss-cross)
2+ 2-
Can iron
possess
Fe SO4
more than
one charge?
iron (II) ion sulfate
YES ferrous ion ion
FeSO4
What are the ions that make up this ionic compound? (reverse criss-cross)
2+ 2-
Can iron
possess
Fe SO4
more than
one charge?
iron (II) sulfate
YES ferrous sulfate
(NH4)2CO3
What are the ions that make up this ionic compound? (reverse criss-cross)
+ 2-
Can
ammonium
NH4 CO3
possess
more than
ammonium carbonate
one charge? ion ion
NO
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Ionic Compounds
(NH4)2CO3
What are the ions that make up this ionic compound? (reverse criss-cross)
+ 2-
Can
ammonium
possess
NH4 CO3
more than
one charge? ammonium carbonate
NO
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Ionic Compounds
Name the following ionic compounds:
- +
A B A B
anion cation
NO2
nitrogen oxygen
oxide
mononitrogen dioxide
nitrogen dioxide
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Molecular Compounds
NO
nitrogen oxygen
oxide
mononitrogen monooxide
nitrogen monoxide
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Molecular Compounds
PBr5
phosphorus bromine
bromide
monophosphorus pentrabromide
phosphorus pentabromide
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Molecular Compounds
Cl2O7
chlorine oxygen
oxide
dichlorine heptaoxide
dichlorine heptoxide
PhSc 105.1 – Inorganic Chemistry (Laboratory)
Naming Molecular Compounds
Name the following molecular compounds: