w SREE RAYALASEEMA HI-STRENGTH HYPO LTD. GROUP MATERIAL SAFETY DATA SHEET Product ID: HSH1560 Product Name: CALCIUM HYPOCHLORITE 65% 1. IDENTIFICATION OF THE SUBSTANCE /PREPARATION AND THE COMPANY UNDERTAKING: Identification of the Substances / Preparation: Product Name Calcium Hypochlorite Hydrated, Granules & Tablets, Available Content: 65% Synonyms Calcium Oxychloride, Bleaching Powder, Chlorinated Lime,Granulated Chlorine Molecular Formula: Ca (OCL)2 Description : Sanitizer and Oxidizer Product Uses Disinfection is swimming pools and drinking water, ‘Treatment of industrial cooling water, slime control, Odor control, sewage and waster water treatment. Company/ Undertaking Identification : Manufactured by _: Sree Rayalaseema Hi-Strength Hypo Ltd., Gondiparla, Kurnool-518004, Andhra Pradesh, India. Emergency Telephone : +91-8518-280065/66/67 Email address + aquafit@sthhl.com 2. HAZARDS IDENTIFICATION: Classification : ORB, Xn R22, C R34, N RSO, R34 Contd.,2 Corp. Off. : # 216, KJ Complex Bhagya Nagar, Kurnool - 518 004 AP India Tel:+91-8518-226460, 220164 Ext: 382 Fax: +91-8518-223066, 226656, 226460 Grams: HISTRENGTH Web : www.srhhl.com Email logisties@sthhi.com /logstissotions@gmaicom 1S 9001,14001 & OHSAS 18001 CERTIFIED COMPANYSREE RAYALASEEMA HI-STRENGTH HYPO LTD. GROUP Product ID: HSH1S60 Product Name: CALCIUM HYPOCHLORITE 65% LRoute of Entry and Effect of short Acute) Exposure: Inhalation : Dust and mist irritate the nose and throat. When mixed with acids, chlorine gas is released. This gas causes irritation of the respiratory tract. Prolonged exposure to high concentrations of chlorine gas may result in severe lung damage. Eye Contact : Exposure to Calcium Hypochlorite can cause eye irritation. Concentrated solutions cause burns which may result in permanent eye damages if not promptly treated. Skin Contaet: Calcium Hypochlorite dust and solution can cause irritation and chemical burns. Ingestion: When ingestion, there will be burning in the mouth and throat, Calcium Hypochlorite can cause abdominal cramp and nausea which may lead to convulsion, coma and death. Long Term(Chronie) Exposure: Skin irritation may occur from repeated or prolonged skin contact. 3.COMPOTION/ INFORMATION OF INGREDIENTS: Ingredients : (by weight %) Available chlorine 65% Min, Moisture 10% Max, Inearts 25% Description CAS-No. Percentage | Classification Calcium Hypochlorite | 7778-54-3 >65% ORS Xn, R22, R31 C, R34N, RSO [Calcium Chlorate | 10137-74-3 2 Not applicable Calcium Carbonate | 471-34-1 2 Not applicable Calcium Hydroxide | 1305-62-0 2 Not applicable Sodium Chloride 7647-14-5 1000 mg/kg ( rabbit} | No Mortality at TT78-54-3 Moderate toxicity Slight to very low 3.Smg(rat) (Ihour)- toxicity. slight very low toxicity, Carcinogencity Toxicity : Not Available Reproductive Toxicity: Not Available Matagencity Not available 12.ECOLOGICAL INFORMATION: Ecotozicity: LC50: 0.088mg/L996hr bluegill sunfish) very toxic to aquatic organisms. Make sure not allow the material contaminate the ground water system. Environment fate: Mobility : Soluble Biodegradation _: Not available Bioaccumulation _: Not available Contd., 7 Corp. Off. : # 216, KJ.Complex Bhagya Nagar, Kurnool - 518 004 AP. India Tl:-+91-8518-226460, 220164 Ext: 382 Fax: +81-8518-223066, 226656, 226460 Grams: HLSTRENGTH Web : wwwvsrhhl.com Email: logistics@sehhl.com /logistcssolitons@gmeailcom $0 9001,14001 & OHSAS 1800) CERTIFIED COMPANYy SREE RAYALASEEMA HI-STRENGTH HYPO LTD. Product ID: HSH1560 Product Name: CALCIUM HYPOCHLORITE 65% Physical / Chemical: Hydrolysis : Not available Photolysis : Not available Additional information : Not available 13. DISPOSAL CONSIDERATIONS: Clean-up: Do not touch spilled material. Prevent material from entering sewers or confined place. Shovel into clean, dry, labeled containers. Flush area with water. Contaminated materials may be dissolved in water, then treated with a reducing agent such as sodium sulphite. Care should be taken while handling contaminated material due to fire risk. Waste Disposal: Consult appropriate Federal. State/Provincial and local regulatory authorities to ascertain proper disposal procedures. Care should be taken not to mix waste Calcium Hypochlorite with incompatible material. Calcium Hypochlorite should be dissolved in water and the available chlorine should be treated using a reducing agent such as Sodium Sulphite. 14. TRANSPORT INFORMATION: UN Numi : UN3487 Proper Shipping name a Calcium Hypochlorite, Hydrated Hazard Class : Su PACKING Group : 1 Sub Risk : 8 ICAOMAT. UN Number :UN3487 Proper Shipping name : Calcium Hypochlorite, Hydrated Hazard Class ee PACKING Group : 1 Sub Risk 5 8 Contd.,8 Corp. Off. : # 216, KJ.Complex Bhagya Nagar, Kurnool - 518.004 AP. India Tel:-+91-8518-226460, 220164 Ext: 382 Fax: +91-8518.223066, 226656, 226460 Grams: HLSTRENGTH Web : wwwschhl.com Email logistics@sehhl.com /logstcssokitons@gmiicom $0 9001,14001 & OHSAS 18001 CERTIFIED COMPANYy Product ID: HSH1560 Product Name: CALCIUM HYPOCHLORITE 65% PACKING Group Sub Risk UN Number Proper Shipping name Hazard Class Packing Group Sub Risk USA-RQ, Hazardous Substance and Quantity Marine Pollutant : 15. REGULATORY INFORMATIO! SREE RAYALASEEMA HI-STRENGTH HYPO LTD. UN3487 Calcium Hypochlorite, Hydrated 51 0 8 UN3487 Calcium Hypochlorite, Hydrated 5.1 Oxidizer) 1 8 10 Ibs. / 4.5 Kg. (Calcium Hypochlorite) Regular EC LABLING REQUIREMENTS: The product is classified and labeled in accordance with EC directives or respective national laws. Contains: Caleium hypochlorite (231-908-7) Danger Indications: 0- Oxidizing Fax: +91-8518- C= Corrosive 14001 & OHSAS 18001 CERTIFI N- Dangerous Environment Contd..9 91-8518-226460, 220164 Ext: 382 fv sth com Email: logistics @sthl.com /logistissoktions@gmaiicomTGV ‘F SREE RAYALASEEMA arate HI-STRENGTH HYPO LTD. Product ID: HSH1560 Product Name: CALCIUM HYPOCHLORITE 65%. R8_ - Contact with combustible material may cause fire. R22 - Harmful if swallowed R31_- Contact with acides liberates toxic gas R34 - Causes bums SO - Very toxic to aquatic organisms Safety Phrases: $26 — In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45_ - In case of accident or if you fell unwell, seek medical advice immediately (show label where possible) ‘S61 — avoid release to the environment. Refer to special instructions / Safety date sheets. '$36/37/39 — Wear suitable protective clothing, gloves and eye/face protection. $.1/2 - Keep locked-up and out of the reach of children. 16. OTHER INFORMATION: ‘Text of R Phrases Mentioned in Section 3:- R8_- Contact with combustible material may cause fire. R22 — Harmful if swallowed R31 Contact with aci R34 - Causes burns R50 Very toxic to aquatic organisms rates toxic gas Prepared by : ‘Chemical Safety Department, Sree Rayalaseema Hi-Strength Hypo Ltd., —End— Corp. Off. : # 216, KJ.Complex,thagya Nagar, Kurnool - 518 004 AP. India Tel:+91-8518-226460, 220164 Ext: 382 Fax: +91-8518-223066, 226656, 226460 Grams : HL-STRENGTH Web : wewusthhl.com Email logisties @sthh.com /logistissohatons@gmailcom 150 9001,14001 & OHSAS 18001 CERTIFIED COMPANY