JEE Advanced 2023 Paper-1 & 2 Chemistry

PAPER-1 & 2
SUBJECT: CHEMISTRY
| JEE (ADVANCED) 2023 | DATE : 04-06-2023 | PAPER-1 & 2 | MEMORY BASED | CHEMISTRY
PART : CHEMISTRY
1 1
1. For a weak monobasic acid a curve is drawn between and Cm where is taken at y axis Cm is
m m
taken at x axis.
P
If P is intercept at y axis & S is slope find ratio of ?
S
( m = molar conductivity at  dilution
Cm = molar conductivity at concentration C
Ka = Ionisation constant of weak acid)
Ans. (P/S = m . Ka )
m C 2
Sol. = Ka =
m 1– 
2
   m 
Ka = C  m  1  
    
 m  m
C2m C m
=
m 
m  m  =
  
m  m  1
 
 m 
m C
–1 =  m
m  m .Ka
m C
=1+  m
m  m . Ka
1 1 C
=  +  2m
m m (  m ) . Ka
1 1
Intercept = = P, Slope = S = ,
m ( m )2 . Ka
P/S = m . Ka
2. Match the following :

Reactions Products
(I) P2O3 + H2O  (P) H3PO4
(II) P4 + NaOH + H2O  (Q) POCl3
(III) PCl5 + CH3COOH  (R) PH3
(IV) H3PO2 + H2O + AgNO3  (S) H3PO3
(A) (I)  (S) ; (II)  (R) ; (III)  (Q) ; (IV)  (P)

(B) (I)  (R) ; (II)  (S) ; (III)  (Q) ; (IV)  (P)
(C) (I)  (S) ; (II)  (R) ; (III)  (P) ; (IV)  (Q)
(D) (I)  (P) ; (II)  (R) ; (III)  (Q) ; (IV)  (S)
Ans. (A)
Sol. P2O3 + H2O H3PO3 
 P4 + NaOH + H2O PH3 + NaH2PO2 
 PCl5 + CH3COOH  CH3COCl + POCl3 + HCl 
 H3PO2 + H2O + AgNO3 H3PO4 + HNO3 + Ag
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3. Match the Column :

Reactions Products
(I) [Fe(H2O)6]+2 (P) t12,g1,1 e1g, 0
(II) [Co(H2O)6]+2 (Q) t 22,g1,1 e1g, 1
(III) [FeCl4]– (R) t 22,g2,1 e1g, 1
(IV) [Mn(H2O)6]+3 (S) t12,g1,1 e1g, 1

(A) (I)  (Q) ; (II)  (R) ; (III)  (S) ; (IV)  (P) (B) (I)  (R) ; (II)  (Q) ; (III)  (S) ; (IV)  (P)
(C) (I)  (Q) ; (II)  (S) ; (III)  (R) ; (IV)  (P) (D) (I)  (Q) ; (II)  (P) ; (III)  (R) ; (IV)  (S)
Ans. (A)
Sol. [Mn(H2O)6]+3  3d4 + weak legand t12,g1,1 e1g, 0
[Fe(H2O)6]+2  3d6 + weak legand t 22,g1,1 e1g, 1
[Co(H2O)6]+2  3d7 + weak legand t 22,g2,1 e1g, 1
[FeCl4]–  3d5 + weak legand e1g, 1 t12,g1,1
4. Select the correct option(s)


(A) Calamine  Zincite
(B) Impure Ag on treatment with NaCN in presence of O 2 forms a complex, which on reduction with Zn
forms Ag
(C) Copperpyrite on heating with silica in reverberatory furnace to remove Fe impurity
(D) Malachite green on roasting forms cuprite
Ans. (ABC)

Sol. (A) ZnCO3  ZnO + CO2
(B) O2 + H2O + Ag + NaCN  Na[Ag(CN)2]aq + NaOH

(C) CuFeS2 + O2  Cu2S + FeO + SO2
FeO + SiO2  FeSiO2

(D) CuCO3.Cu(OH)2  CuO + H2O + CO2
5. Compressibility factor of a gas is 0.5 at 800K and X-atm. If it behaves as ideal gas at the given pressure
X
and temperature its volume is Y. Find
Y
Ans. 100
PVm
Sol. Z=
RT
X.0.4
0.5 =
RT
X  0.4 = 0.5 RT
X  0.4 = 0.5 R x 800
X = R x 1000
PVm = RT
R x 1000 x Y = R x 800
Y = 0.8
X R x 1000 0.08 x 1000
= =
Y 0.8 0 .8
X
= 100
Y

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6. The complexes which can exhibit the type of isomerism as shown by [Pt(NH 3)2Br2] is/are :
[en = NH2CH2CH2NH2]
(A) [Zn(NH3)2Cl2] (B) [Cr(en)2(H2O)(SO4)]+
(C) [Pt(NH3)2Cl4] (D) [Pt(en)(SCN)2]
Ans. (BC)
Sol. [Pt(NH3)2Br2] exhibits cis-trans isomerism (Geometric isomerism)
(B) [M(AA)2ab] & [Ma2b4] can exhibit geometric isomerism.
7. H2S (5 mol) reacts completely with acidified aqueous KMnO4 solution. In this reaction the number of
moles of water produced is X, and the number of moles of electrons involved is Y. Determine the value
of (X + Y).
Ans. (18)
Sol. 2KMnO4 + 3H2SO4 + 5H2S K2SO4 + 2MnSO4 + 8H2O + 5S
X=8
Y = 10
8. For He+ ion a transition takes place from the orbit of radius 105.8 pm to the orbit of radius 26.45 pm. The
wavelength (in nm) of the emitted photon during the transition is
Use, Bohr radius (a0) = 52.9 pm
RH = 2.2 x 10–18J
h = 6.6 x 10–34 J sec
c = 3 x 108 m/sec
Ans. (30 nm)
n 22
Sol. 0.529 x = 1.058 n2 = 2
2
n12
0.529 x = .2645 n1 = 1
2
912
= = 304 Å = 30.4 nm  30 nm
1 1
22  2  2 
1 2 
9. Among [I3]+, [SiO4]–4, SO2Cl2, XeF2, SF4, Cl3, [Ni(CO)4], XeO2F2, [PtCl4] 2–, XeF4, SOCl2 the total number
of species having sp3 hybridized central atom.
Ans. (5)
[I3]+, [SiO4]–4, SO2Cl2, [Ni(CO)4], SOCl2
O– F
Cl
+
Si S—Cl Xe S Cl
I F
Sol. , , , , , ,
–O O– O F F F F
I I O – F F F
O
CO 2–
F Cl Cl
F F Cl
Ni Pt
Xe F
Xe S
CO CO , , Cl Cl , ,
CO O O F F O Cl

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10. 50 mL of 0.2 molal urea solution (density = 1.012 g ml–1 at 300 K) is mixed with 250 ml of a solution
containing 0.06 g of urea. Both the solutions were prepared in the same solvent. The osmotic pressure
(in torr) of the resulting solution M(urea) = 60 g mol–1 R = 62 L torr K–1 mol–1
Assume Hmixing = 0 Vmixing = 0
Ans. (682)
Sol. 50 ml × 1.012 = 50.6 g = xg urea + (50.6 – x)g H2O
x
molality = 0.2 = 60 x = 0.6 g urea  0.01 mol urea
50.6 – x
1000
Other solution has 0.06 g urea  0.001 mol urea
(0.01 0.001)
resulting = × 62 × 300 = 682 torr
0.3
11. Consider the following molecules Br3O8, OF2, H2S4O6, C3O2, and H2S5O6 . Count the number of atoms
existing in their zero oxidation state in each molecule.
Ans. (6)
O O
O O O O HO–S–S–S–S–S–OH
Sol. O=Br–Br–Br=O F F
O O
O O O 3 Sulphur
O O
HO–S–S–S–S–OH
O O O=C=C=C=O
2 Sulphur 1 Carbon
12. For F2 select the correct order of filling molecular orbitals:

(A) 2pz2, 2px2 = 2py2, *2px2 = *2py2
(B) 2px2 = 2py2, 2pz2, *2px2 = *2py2
(C) 2px2 = 2py2, *2px2 = *2py2, 2pz2
(D) *2px2 = *2py2, 2px2 = 2py2, 2pz2
Ans. (A)
Sol. Theory based
13. Atoms of metal x, y & z forms face centered cubic (fcc) unit cell of edge length L x, Body centered unit cell
(bcc) unit cell of edge length Ly and simple cubical unit cell (SC) of edge length L z respectively
3 8
It rz = r y , ry = rx
2 3
3
Mz = My, Mz = 3Mx
2
Given Mx, My, Mz are molar mass of metal x, y & z.
rx, ry, rz are atomic radii of x, y & z
Identify the correct statement(s)
(A) Packing efficiency x > y > z
(B) Density of x > Density of y
(C) Lx > Ly
(D) Ly > Lz
Ans. (AB)

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Sol. Packing efficiency

4  4 / 3rx3 4  4 / 3rx3
FCC PE = = 3
(L x )3  4rx 
 
 2
2  4 / 3ry3 2  4 / 3ry3
L y 3
BCC PE = = 3
 4ry 
 
 3 
 
1  4 / 3rz3 1  4 / 3rz3
S.C. PE = =
L z 3 2rz 3
PE FCC : BCC : SC
4  ( 2 )3 4  ( 3 )3 1
= 3
: 3
:
( 4) ( 4) ( 2) 3
2 2 23 3 1
= : :
16 16 8
= 8 2 : 6 3 :8
= 11.3 : 10.392 : 8
4r 4ry
Lx = x , Ly = , Lz = 2rz
2 3
Lx < Ly
Lx r 3 3 3 3
= x . = × =
Ly ry 2 8 2 8 2
4ry
Ly = , Lz = 2rz
3
Ly 2ry 2 3 1
= = × =
Lz rZ . 3 3 2 1
4M x 2My
(Density) = 3
, (Density)y =
N A (L x ) NA (L y )3
3
dx 2Mx  Ly 
= .  

dy My  Lx 
3
1 8 2 
=2× ×  
2  3 
 
SO: dx > dy
14. (P)   (Q)  (R)

NaOH
white ppt

(Q)  
PbO 2 & H
(S)
Pink coloured solution
(R)  (T)
MnO( OH )2
which produce blue dots on starch iodide paper (S) & (T) are respectively:
(A) KMnO4, Cl2 (B) K2MnO4, HCl (C) MnO2, ClO3– (D) K2MnO4, ClO2–
Ans. (A)

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Sol. Mn 2  Mn(OH)2 
NaOH
(P ) ( Q) white ppt
PbO2 + Mn+2 + H+  MnO 4  Pb 2  H2 O

(S)
Cl– + MnO(OH)2  Cl2

(T )
which gives starch iodide test.
15. NC CN
1. LiAlH4 (excess)
2. Acetophenone
(excess)
NC CN
Heterocyclic compound is not formed in final product then total number of sp 2 carbon atoms in the final
product is
Ans. 28
Sol.
NC CN NH2 NH2
1. LiAlH4
NC CN NH2 NH2
Acetophenone
Ph Ph
N N
Me Me
Ph Ph
N N
Me Me
X X
1. Mg/THF 1. Mg/THF
16. P ; Q
2. H3O 2. CO2
3. H3O
4. NaOH
X
X
1. KCN
1. Mg/THF S
R ; 2. LiAlH4
2. CH3COCl
3. CHCl3 / KOH
Which of the following is correct for above given reactions
(A) Q give Kolbe's electrolytic synthesis and its product has eight carbon atoms
(B) S is a primary amine
(C) R gives Cannizaro's reaction
(D) P is a primary alcohol
Ans. (A)

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X
1. Mg/THF
H3O
Sol. MgX
(P)
COOMgX
Mg/ThF CO2
X MgX
H3O
NaOH
KES COO–Na+ COOH
(Q)
O
Mg/ThF (i)
X MgX CH3COCl MgX
CH3
(ii) H3O
OH
CH3
Me
(R)
X CN NH2
KCN LiAlH4
CHCl3/KOH
+ –
N C
(S)
17. (I) KMnO4

P
H
O
COCl
(II) (i) aq NaOH
MeO
Q
(ii) H3O

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O O
OMe (1) NaOH (aq.)

(III) (R)
(2) H2CrO4 /
Br
(1) Mg/THF
(S)
(2) CO2
(IV) O (3) H3O /
(4) Tollen's reagent
O

Which of the following is/are correct
(A) Compound P and Q can be monomer of Dacron & Glyptal respectively
(B) Q & S are Dicarboxylic acids
(C) Q & R are same compound
(D) P, Q & R are structural isomers
Ans. (B)
Sol. KMnO4/H

COOH P
O O COOH
MeO Cl 1. NaOH(aq)
2. H3O+
COOH
(Q)

O O
COOH
OMe 1. NaOH(aq)
2. H2CrO4/
(R)

OH
Br COOH
(1) Mg/THF
(S) +
(2) CO2 OH
O (3) H3O / HOOC
(4) Tollen's reagent (S)
O


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Phenylalkyl HI 1. NaOH 1. Ac2O

Q 2. CO2
R S
ether 2. H3O
+
18. 3. H O+
P 3
4. NaOH
Compound S is ?
(1) O–Acetoxy benzoic acid (2) It inhibits prostaglandins
(3) It is a narcotic analgesic (4) It inhibits the enzyme which degrades noradrenaline
Ans. (1)
O
R
O OH OH O CH3
COOH 1.Ac2O
HI + COOH
Sol. 2.H3O
2.CO2
+
+ 3.H3O
R–I Aspirin
4.NaOH
Pain Killer
Paragraph/Comprehension
1,3,5 Tris (4-nitrophenyl) benzene is reacted with Sn/HCl, product is further reacted to NaNO 2 and HCl
at 0o-5oC tempreture that gives product 'P', product 'P' is heated with water at room temp. gives compound
Q, Q is brominated in aqueous medium, now compound 'P' is reacted with excess of Phenol in basic
medium giving 'S' molar mass difference of compound Q and R is 474.
19. Number of heteroatom in R is

Ans. 9
NO2
NH2
Sn, HCl
O2N NO2 H2N NH2

NaNO2/HCl (0o-5oC)
OH N2Cl
Sol.
H2O

HO OH ClN2 N2Cl
(Q) Br2/H2O (P)
OH
Br Br
Br
Br
HO OH
Br Br
(R)

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N2Cl OH
Ph-OH/OH–
excess N
ClN2 N2Cl
(P)
N
N
N
HO N
(S)
OH
20. If molar mass difference of S and P is 172.5 then sum of total carbon and hetroatoms in product 'S' is :
Ans. 51
OH
Sol.
N N
N N
(S)
HO OH

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PAPER-1 & 2

2. Match the following :

(A) (I)  (S) ; (II)  (R) ; (III)  (Q) ; (IV)  (P)

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3. Match the Column :

(II) [Co(H2O)6]+2 (Q) t 22,g1,1 e1g, 1

(III) [FeCl4]– (R) t 22,g2,1 e1g, 1

(IV) [Mn(H2O)6]+3 (S) t12,g1,1 e1g, 1

[Fe(H2O)6]+2  3d6 + weak legand t 22,g1,1 e1g, 1

[Co(H2O)6]+2  3d7 + weak legand t 22,g2,1 e1g, 1

[FeCl4]–  3d5 + weak legand e1g, 1 t12,g1,1

4. Select the correct option(s)

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12. For F2 select the correct order of filling molecular orbitals:

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Sol. Packing efficiency

14. (P)   (Q)  (R)

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PbO2 + Mn+2 + H+  MnO 4  Pb 2  H2 O

Cl– + MnO(OH)2  Cl2

which gives starch iodide test.

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17. (I) KMnO4

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OMe (1) NaOH (aq.)

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Phenylalkyl HI 1. NaOH 1. Ac2O

19. Number of heteroatom in R is

O2N NO2 H2N NH2

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JEE Advanced 2023 Paper-1 & 2 Chemistry

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