SUBJECT CHEMISTRY XII

UNIT 1 SOLUTIONS
TEST PAPER
SECTION A [1X10=10]
Q1(i) What is the boiling point of 0.2m solution of non-
electrolyte in water?[Kb H2O= 0.52Kkg/mol]
(ii) Define molal elevation boiling point constant.
(iii) Which of the following has the highest freezing
point at 1 atm 0.1M KCl , 0.1M urea, 0.1M CaCl2 ,0.1M
AlCl3 ?
(iv) Write the condition for reverse osmosis.
(v) Write the factors on which magnitude of Henry’s
constant depend.
(vi) Name one natural and one synthetic
semipermeable membrane.
(vii) If a solution of phenol in benzene shows 70%
trimerization then determine its degree of association.
 (viii) What happens if RBC is placed in aqueous NaCl
solution with concentration: a) greater than 0.91% and
b) less than 0.91%?
(ix) Define osmotic pressure.
(x) What kind of azeotropic mixture is formed by
68%nitric acid and 32% water?
SECTION B [2X 6=12]
Q2 What are colligative properties? Does increase in
interactive forces between solute and solvent affect
magnitude of colligative properties? Give reason.
Q3 Derive Raoult’s law for binary solutions containing
non volatile solute.
Q4 What mass of a non volatile solute with molar mass
40g/mol must be dissolved in 114g octane to reduce its
vapour pressure to 80%?
Q5 What is the amount of CaCl2 dissolved in 2.5L
solution so that its osmotic pressure at 300K is 0.75
atm?[formula mass CaCl2=111g/mol]
Q6 An aqueous solution of NaCl is 3M and its density is
1.25g/mL .Calculate its molality. [NaCl formula
mass=58.5]
SECTION C[3X6=18]
Q7 When 2.56g of sulphur was dissolved in 100g CS2 the
freezing point lowered by 0.383K.Calculate the
molecular formula of sulphur. [Kf for CS2 3.83 Kkg/mol]
Q8 What is the reason for abnormal molecular mass of
solute? Explain with suitable examples.
Q9 With help of a well labeled graph and example
explain positive deviation from ideal behavior.
Q10 Why osmotic pressure is considered a colligative
property? Justify. Why is it one of the best methods to
determine molar mass of solute amongst all the
colligative properties?
Q11 An aqueous solution of BaCl2 containing 12.48g of
it in 1.0kg of solvent boils at 373.083K.Calculate the
degree of dissociation of BaCl2.[Kb H2O is
0.52Kkg/mol][formula mass BaCl2 =208.34]
Q12 Give reasons:
 (i)nature of gas determines its solubility in
water.
(ii) mole fraction , molality are better methods
for finding concentration of solution than molarity .
(iii)Henry’s law is not applicable to gases like
ammonia and HCl.
SECTION D [5X2=10]
Q13 (i) Name the disease which is due to water
retention in the tissues.
(ii)What is anoxia?
(iii) Which condition is called Bends?
(iv)What is antifreeze?
(v)High B.P patients should consume less salt in diet.
Give reason.
Q14 (a) What is the magnitude of Vant Hoff factor for
benzoic acid if dissolved in water and if dissolved in
benzene? Why?
(b)Give one example of each kind of homogeneous
solution:
(i) solid in liquid (ii)liquid in gas (iii) solid in solid