DPP-1

Thermodynamics
It is which type of system ?

A Open system

B Closed system

C Adiabatic system

D isolated system
It is which type of system ?

A Open system

B Closed system

C Adiabatic system

D isolated system
It is which type of system ?

Solution :
Neither energy nor matter is exchanged
∴ isolated system
Tea placed in thermos flask is an example of

A Open system

B Close system

C Isolated system

D It can’t act as system

Tea placed in thermos flask is an example of

A Open system

B Close system

C Isolated system

D It can’t act as system

Tea placed in thermos flask is an example of

Solution :
A thermos flask does not allow exchange of energy
and matter. Hence, it is an isolated system.
Which one of the following quantity is dependent on
path?

A molar internal energy

B volume

C w

D q+w
Which one of the following quantity is dependent on
path?

A molar internal energy

B volume

C w

D q+w
Which one of the following quantity is dependent on
path?

Solution :
Heat and work are path dependent, or indefinite
quantity.
Internal energy does not include

A vibrational energy

B rotational energy

C nuclear energy

D energy arising by gravitational pull

Internal energy does not include

A vibrational energy

B rotational energy

C nuclear energy

D energy arising by gravitational pull

Internal energy does not include

Solution :
The energy due to external field is not included in
internal energy like gravitational field, earth’s
magnetic field, etc.
What is the change in internal energy ΔU, for a system
that does 70 J of work as it absorbs 45 J of heat?

A 115 J

B 25 J

C –25 J

D –115 J
What is the change in internal energy ΔU, for a system
that does 70 J of work as it absorbs 45 J of heat?

A 115 J

B 25 J

C –25 J

D –115 J
What is the change in internal energy ΔU, for a system
that does 70 J of work as it absorbs 45 J of heat?

Solution :
ΔU = q + w
heat absorb (q) = 45 J
since w = –70 joule
Work done by the system.
ΔU = q + w = 45 – 70 = –25 J
If the internal energy of an ideal gas decreases by the
same amount as the work done by the system, the
process is

A cyclic

B isothermal

C adiabatic

D isolated
If the internal energy of an ideal gas decreases by the
same amount as the work done by the system, the
process is

A cyclic

B isothermal

C adiabatic

D isolated
If the internal energy of an ideal gas decreases by the
same amount as the work done by the system, the
process is

Solution :
Decrease in internal energy = –ΔU
Work done by the system = –w
–ΔU = –w⇒ΔU = w fi q = 0
The process is adiabatic.
In thermodynamics, a process is called reversible
when

A surroundings and system change into each other.

B there is no boundary between system and

surroundings.

C the surrounding are always in equilibrium with

the system.

D the system changes into the surroundings

spontaneously.
In thermodynamics, a process is called reversible
when

A surroundings and system change into each other.

B there is no boundary between system and

surroundings.

C the surrounding are always in equilibrium with

the system.

D the system changes into the surroundings

spontaneously.
In thermodynamics, a process is called reversible
when

Solution :
Reversible process-involve infinitesimally small
driving force. Hence system and surrounding
remains in equilibrium.
When 1 mol gas is heated at constant volume,
temperature is raised from 298 to 308 K. Heat supplied
to the gas is 500 J. Then which of the following
statements is correct?

A q = W = 500 J, ΔU = 0

B q = ΔU = 500 J, W = 0

C q = W = 500 J, ΔU = 0

D ΔU = 0, q = W = –500 J,
When 1 mol gas is heated at constant volume,
temperature is raised from 298 to 308 K. Heat supplied
to the gas is 500 J. Then which of the following
statements is correct?

A q = W = 500 J, ΔU = 0

B q = ΔU = 500 J, W = 0

C q = W = 500 J, ΔU = 0

D ΔU = 0, q = W = –500 J,
When 1 mol gas is heated at constant volume,
temperature is raised from 298 to 308 K. Heat supplied
to the gas is 500 J. Then which of the following
statements is correct?

Solution :
At constant volume ΔV = 0
∴ W = –Pext ΔV = 0
∴ ΔU = q first law
An ideal gas expands in volume from 10–3 m3 to 10–2
m3 at 300 K against a constant pressure of 105 N m–2.
The work done is

A 900 kJ

B –900 kJ

C 270 kJ

D –900 J
An ideal gas expands in volume from 10–3 m3 to 10–2
m3 at 300 K against a constant pressure of 105 N m–2.
The work done is

A 900 kJ

B –900 kJ

C 270 kJ

D –900 J
An ideal gas expands in volume from 10–3 m3 to 10–2
m3 at 300 K against a constant pressure of 105 N m–2.
The work done is

Solution :
Work done by a gas = –Pext × ΔV
= –105(10–2 – 10–3)
= –105(0.009) = –900 J
If 500 calorie of heat energy are added added to a system and
the system does 350 calorie of work on the surroundings, what
is the energy change of the system?
If 500 calorie of heat energy are added added to a system and
the system does 350 calorie of work on the surroundings, what
is the energy change of the system?

Solution

Heat absorbed, q = 500 cal

Work done by the system, w = -350 cal
Applying the first law of
thermodynamics,
ΔE = q + w = 500 + (-350) = 150 calorie
Which of the following is a state function?

A q

B w

C q+w

D All of these
Which of the following is a state function?

A q

B w

C q+w

D All of these
Which of the following is a state function?

Solution :

q (heat) and w (work done) are both path

functions.

● q + w = ΔU, which is change in internal energy,

which is a state function.
Any real gas is subjected to change in its state from 10
atm, 5l to 3 atm, 2l. ΔU = 20 l – atm. Calculate ΔH for
the process.
Any real gas is subjected to change in its state from 10
atm, 5l to 3 atm, 2l. ΔU = 20 l – atm. Calculate ΔH for
the process.

Solution :
ΔH = ΔU + (P2V2 – P1V1)
= 20 + (6 – 50)
= –24l atm
In a reaction, all reactant and products are liquid, then

A ΔH > ΔE

B ΔH < ΔE

C ΔH = ΔE

D Can’t predicted
In a reaction, all reactant and products are liquid, then

A ΔH > ΔE

B ΔH < ΔE

C ΔH = ΔE

D Can’t predicted
In a reaction, all reactant and products are liquid, then

Solution :

∵ All reactants and products are liquid,

hence, Δng = 0

Where, Δng signifies change in moles of gaseous substances.

∴ ΔH = ΔU + Δn RT or, ΔH = ΔU
For a gaseous reaction:
A(g) + 3B(g) ⟶ 3C(g) + 3D(g)
ΔE is 17 kcal at 27oC. Assuming R = 2 cal K-1 mol-1 the value of
ΔH for the above reaction will be

A 15.8 kcal

B 16.4 kcal

C 18.2 kcal

D 20.0 kcal
For a gaseous reaction:
A(g) + 3B(g) ⟶ 3C(g) + 3D(g)
ΔE is 17 kcal at 27oC. Assuming R = 2 cal K-1 mol-1 the value of
ΔH for the above reaction will be

A 15.8 kcal

B 16.4 kcal

C 18.2 kcal

D 20.0 kcal
For a gaseous reaction:
A(g) + 3B(g) ⟶ 3C(g) + 3D(g)
ΔE is 17 kcal at 27oC. Assuming R = 2 cal K-1 mol-1 the value of
ΔH for the above reaction will be

Solution
ΔH = ΔU + ΔngRT
Δng= (3+3) - (3+1) = 2
ΔH = 17 kcal + 2 × 2 cal K-1 mol-1 × 300 K × 10-3
ΔH = 17 kcal + 1.2 kcal = 18.2 kcal
One mole of ideal gas is allowed to expand reversibly
and adiabatically from a temperature of 27°C. If the
work done by the gas in the process is 3 kJ, the final
temperature will be equal to (CV = 20 J/K mol)

A 100 K

B 450 K

C 150K

D 400 K
One mole of ideal gas is allowed to expand reversibly
and adiabatically from a temperature of 27°C. If the
work done by the gas in the process is 3 kJ, the final
temperature will be equal to (CV = 20 J/K mol)

A 100 K

B 450 K

C 150K

D 400 K
One mole of ideal gas is allowed to expand reversibly
and adiabatically from a temperature of 27°C. If the
work done by the gas in the process is 3 kJ, the final
temperature will be equal to (CV = 20 J/K mol)

Solution :
When a monoatomic gas undergoes an adiabatic
process, its temperature and volume are related by the
equation TVn = constant, the value of n will be

A 1.33

B 0.33

C 2.33

D 1
When a monoatomic gas undergoes an adiabatic
process, its temperature and volume are related by the
equation TVn = constant, the value of n will be

A 1.33

B 0.33

C 2.33

D 1
When a monoatomic gas undergoes an adiabatic
process, its temperature and volume are related by the
equation TVn = constant, the value of n will be

Solution :
1 mole of CO2 gas at 300 K is expanded under reversible
adiabatic condition such that its volume becomes
27 times.
(a) What is final temperature?
(b) What is work done?
Given 𝛾 = 1.33 and CV = 25.08 J mol–1 K–1 for CO2.
Solution :
Molar heat capacity of water at constant pressure P is
75 J K–1. When 1 kJ of heat is supplied to 100 g of water
which is free to expand, the increasing temperature
of water is

A 1.2 K

B 2.4 K

C 4.4 K

D 6.6 K
Molar heat capacity of water at constant pressure P is
75 J K–1. When 1 kJ of heat is supplied to 100 g of water
which is free to expand, the increasing temperature
of water is

A 1.2 K

B 2.4 K

C 4.4 K

D 6.6 K
Molar heat capacity of water at constant pressure P is
75 J K–1. When 1 kJ of heat is supplied to 100 g of water
which is free to expand, the increasing temperature
of water is
Solution :
For a monatomic gas, the value of the ratio of Cp.m and
Cv.m is

A 5/7

B 7/5

C 9/7

D 9/11
For a monatomic gas, the value of the ratio of Cp.m and
Cv.m is

A 5/7

B 7/5

C 9/7

D 9/11
For a monatomic gas, the value of the ratio of Cp.m and
Cv.m is

Solution :
For monoatomic ideal gas total degree of freedom =
3
Three translational mode of motion
The specific heat of a gas is found to be 0.075 calories at
constant volume and its formula wt is 40. The atomicity of the
gas would be

A One

B Two

C Three

D Four
The specific heat of a gas is found to be 0.075 calories at
constant volume and its formula wt is 40. The atomicity of the
gas would be

A One

B Two

C Three

D Four
The specific heat of a gas is found to be 0.075 calories at
constant volume and its formula wt is 40. The atomicity of the
gas would be

Solution
Specific heat = 0.075 calories
∴ Molar specific heat capacity, CV = 0.075ｘ40 = 3 cal mol-1 k-1
∴ CP = CV + R = 3 cal mol-1 k-1 + 2 cal mol-1 k-1 = 5 cal mol-1 k-1

∴ ⇒ Monoatomic gas.
Two moles of an ideal gas initially at 27oC and one
atmospheric pressure are compressed isothermally and
reversibly till the final pressure of the gas is 10 atm. Calculate
q, w and ΔU for the process
 Two moles of an ideal gas initially at 27oC and one
atmospheric pressure are compressed isothermally and
reversibly till the final pressure of the gas is 10 atm. Calculate
q, w and ΔU for the process

Solution
Here, n = 2 moles,
T = 27oC = 300 K,
P1 = 1 atm, P2 = 10 atm

= 2.303 × 2 × 8.314JK-1mol-1 × 300 K × log 10 = 1148J

For isothermal compression of ideal gas,
ΔU = 0
Further, ΔU = q + w
∴ q = -w = -11488 J.
When one mole of a monoatomic ideal gas at initial
temperature T K expands adiabatically from 1 litre to 2 litre,
the final temperature in Kelvin would be

A T

D
When one mole of a monoatomic ideal gas at initial
temperature T K expands adiabatically from 1 litre to 2 litre,
the final temperature in Kelvin would be

A T

D
When one mole of a monoatomic ideal gas at initial
temperature T K expands adiabatically from 1 litre to 2 litre,
the final temperature in Kelvin would be

Solution
TV𝜸-1 = constant, i.e., T1V1𝜸-1 = T2V2𝜸-1
A monoatomic gas X and a diatomic gas Y, both initially
at the same temperature and pressure are compressed
adiabatically from a volume V to V/2, which gas will
be at higher temperature?

A X

B Y

C Both are same

D Cannot say
A monoatomic gas X and a diatomic gas Y, both initially
at the same temperature and pressure are compressed
adiabatically from a volume V to V/2, which gas will
be at higher temperature?

A X

B Y

C Both are same

D Cannot say
A monoatomic gas X and a diatomic gas Y, both initially
at the same temperature and pressure are compressed
adiabatically from a volume V to V/2, which gas will
be at higher temperature?
Solution :

Since 𝛾 is more for the gas X, the temperature will

also be more for it.
How much heat, in joules, must be added to 0.250 mol
of Ar(g) to raise its temperature from 20°C to 36.0°C at
constant pressure?

A 50.0

B 83.2

C 187

D 200
How much heat, in joules, must be added to 0.250 mol
of Ar(g) to raise its temperature from 20°C to 36.0°C at
constant pressure?

A 50.0

B 83.2

C 187

D 200
 How much heat, in joules, must be added to 0.250 mol
of Ar(g) to raise its temperature from 20°C to 36.0°C at
constant pressure?

Solution :
Q. 10 mole of ideal gas expand isothermally and
reversibly from a pressure of 10 atm to 1 atm at 300 K.
What is the largest mass which can lifted through a
height of 100 meter?

A 31842 kg

B 58.55 kg

C 342.58 kg

D None of these
Q. 10 mole of ideal gas expand isothermally and
reversibly from a pressure of 10 atm to 1 atm at 300 K.
What is the largest mass which can lifted through a
height of 100 meter?

A 31842 kg

B 58.55 kg

C 342.58 kg

D None of these
Q. 10 mole of ideal gas expand isothermally and
reversibly from a pressure of 10 atm to 1 atm at 300 K.
What is the largest mass which can lifted through a
height of 100 meter?

Solution:
Q. A heat engine carries one mole of an ideal
mono-atomic gas around the cycle as shown in the figure.
Select the correct option :

A qAB = 450 R and qCA = -450R

B qAB = 450 R and qCA = -225R

C qAB = 450 R and qCA = -375R

D qAB = 375 R and qCA = -450R

Q. A heat engine carries one mole of an ideal
mono-atomic gas around the cycle as shown in the figure.
Select the correct option :

A qAB = 450 R and qCA = -450R

B qAB = 450 R and qCA = -225R

C qAB = 450 R and qCA = -375R

D qAB = 375 R and qCA = -450R

Q. A heat engine carries one mole of an ideal
mono-atomic gas around the cycle as shown in the figure.
Select the correct option :

Solution:
Q. What is the final temperature of 0.10 mole
monoatomic ideal gas that performs 75 cal of work
adiabatically if the initial temperature is 227°C? (use R =
2 cal/K-mol)

A 250 K

B 300 K

C 350 K

D 750 K
Q. What is the final temperature of 0.10 mole
monoatomic ideal gas that performs 75 cal of work
adiabatically if the initial temperature is 227°C? (use R =
2 cal/K-mol)

A 250 K

B 300 K

C 350 K

D 750 K
Q. What is the final temperature of 0.10 mole
monoatomic ideal gas that performs 75 cal of work
adiabatically if the initial temperature is 227°C? (use R =
2 cal/K-mol)

Solution:
Q. During an adiabatic process, the pressure of gas is
found to be proportional to the cube of its absolute
temperature. The ratio of (Cp,m/Cv,m) for gas is :

A 3/2

B 5/3

C 7/3

D 4/3
Q. During an adiabatic process, the pressure of gas is
found to be proportional to the cube of its absolute
temperature. The ratio of (Cp,m/Cv,m) for gas is :

A 3/2

B 5/3

C 7/3

D 4/3
Q. During an adiabatic process, the pressure of gas is
found to be proportional to the cube of its absolute
temperature. The ratio of (Cp,m/Cv,m) for gas is :

Solution:
Q. Calculate the final temperature of a monoatomic
ideal gas that is compressed reversible and adiabatically
from 16L to 2L at 300 K :

A 600 K

B 1044.6 K

C 1200 K

D 2400 K
Q. Calculate the final temperature of a monoatomic
ideal gas that is compressed reversible and adiabatically
from 16L to 2L at 300 K :

A 600 K

B 1044.6 K

C 1200 K

D 2400 K
Q. Calculate the final temperature of a monoatomic
ideal gas that is compressed reversible and adiabatically
from 16L to 2L at 300 K :

Solution:
Q. 1 mole of an ideal gas A(Cv,m =3R) and 2 mole of an
ideal gas B are taken in a container and
expanded reversible and adiabatically from 1 litre to 4
litre starting from initial temperature of 320K. ΔE or Δu
for the process is

A -240 R

B 240 R

C 480 R

D -960 R
Q. 1 mole of an ideal gas A(Cv,m =3R) and 2 mole of an
ideal gas B are taken in a container and
expanded reversible and adiabatically from 1 litre to 4
litre starting from initial temperature of 320K. ΔE or Δu
for the process is

A -240 R

B 240 R

C 480 R

D -960 R
Solution:
A sample of a fluorocarbon was allowed to expand
reversibly and adiabatically to twice its volume. In the
expansion, the temperature dropped from 298.15 to
248.44 K. Assume the gas behaves perfectly. Estimate
the value of CV.
Solution :
Two moles of an ideal gas was compressed
adiabatically against constant pressure of 2 atm which
was initially at 350 K and 1 atm pressure. The work
involve in the process is equal to?

A 250 R

B 300 R

C 400 R

D 500 R
Two moles of an ideal gas was compressed
adiabatically against constant pressure of 2 atm which
was initially at 350 K and 1 atm pressure. The work
involve in the process is equal to?

A 250 R

B 300 R

C 400 R

D 500 R
Solution :
Solution :
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