AQA Please write clearly in block capitals. aeeteg Bat Centre number Ganctdats natber “TOE PT cmena SHAKEEL cael Forename NAIMAH Candidate signature i A-level CHEMISTRY Paper 1 Inorganic and Physical Chemistry, ,. , Tuesday 4 June 2019 » Afternoon, 1+. Time allowed: 2 hours Materials ‘ 1 ope PT Re _ For this paper you must have: For Examine’s Use tthe Periodic Table/Data Sheet, provided as an insert (enciosed} => > Paueston] Mart 2 a ruler with milimetre measurements = TAT Sent calculator, which you are expected to use where ‘appropriate. 1 =e: Instructions ize black ink or black baf-point pen. Das Pirin the boxes atthe tp of tis page g 1 answer all questions. + Answmust answer the questions in the spaces provided. Do nat write outside the box around each page or on blank pages. «All working must be shown. 1 Ba a rough workin tis book. Cross through any work you do nat” want to be marked. j nqgne 2 oral | Information tthe marks for questions are shown in brackets. 1 The maximum mark for this paper is 105. *JUN197405101": s, ‘ . 7405/1 2 aaa Scanned with CamScanner~~ Ariswer.all questions in the spaces provided. Toure 1 shows an incomplete Bom—Haber cycle for the formation of caesium iodide. The diagram is not to scale. Figure 1 Cs(g) + Ko) Cst(g) +1i9) Csigh + 3hI8) ots) Table t'gives values of some standard enthalpy changes. Table 1 | DL Name of enthalpy change + | ator! ]* "| Enthalpy of atomisation of caesium 479 | First ionisation energy of caesium, ri: save tf te | Electron affinity of iodine z 314 Enthalpy of latice formation ofcaesiumiodide |< +585 | > ; | Enthalpy of formation of caesiumiodide ~ | ~ 337 i Pe Figure 1 and the data in Table to calculate the standard enthglpy of atomisation of lodine ; , including state symbols, of the appropriate : ayce | [2 marks]; {2 marks} Standard enthalpy of atomisation of iodine a a j Donat we ‘ounce Scanned with CamScanneree 3 ‘panatway——- > one ‘enthalpy of lattice formation for caesium iodide in Table 1 is a value obtained by experiment. ‘ “ 47) * . | ‘The value obtained by Calculation using the'perfect ionic model is -582 kJ mol. “+ | * Deduce what these values indicate about the bonding in caesium iodide. | | (1 mark] i | | (mab Use data from Table 2 to show that this reaction is not feasible at 298 K | fj | Csl(s) + Cs(s) +212(8)_ AH, = +337 kJ mort | | Table 2 ' Csi(s) Cs(s) la{s) | | | | S15! mort 130 828 117 | | [4 marks} } | | | } i | | | Turn over > *03" sreaniarsos Scanned with CamScannera ee ] ets 7 aed (TOF) mass spectrometry can be used to analyse large molecules such “tar | 3 in (P). "is ionised by electrospray ionisation and its mass spectrum is shown in Figure 2. | quun a i} n ¢ Figure 2 Abundance somple dissolved wo Youn govent Gnd intoed gh fue ny POILMALC Aaodle O72) { Y Describe the fog 0 556 2 five an equation to represent theiionisation of Pin this process. [4 marks] Descinion Hampe Gssowed ow voowe Soe ny meded faraugh ne WYPsdaME “AMA be Eerck gue Pe MISA - es Okradnad +o festa anne hgh e powers' OOS || “jonita QProron om savens- renin Naodve QrOdwtang pO WUN HH Chotge massor tl 04" recuumeransn Scanned with CamScannerSoot prior 8 2996 Ux ‘coo morn goaded 2 a Tick (Y) one box. [1 mark] relative molecular mass of 7 & Calculate the ete X66 12KIO KE = 12 nw 2where m= mass (kg) and v= speed (m s~*) ‘The Avogadro constar zt | 41000 46702218 3 smart) z ae KEzY, MV ved Vv =(a) | 2-0axto!s i . = /aym k (uss -s) | (2 BAO | . ws 2209 x10 Lem 2-25 1 Kk resiz9 vio" 2064 KIO sm ¥ 7436044976 M2 2+ 810632 Xo ww | X 1600 Worezexie ) | Nez 1696256289 | urzteq. 3 LON CBSE) Relaive molecuirmass _ WOBB 164 l= ae "05" ecantaracsn Scanned with CamScannera i i 3 cor ent [athena dente cnat prin no RERUN oop a3 State the meaning of te torypatessAT [1 mang | | | The paxtern vin ene change uv the | | rrovemes OF a remot ewmens, epeaied | im_the next row: 7 it highest electronegativity valle.” OTS JF] Identity the element in Patiog'4 with the’ ‘ ven Gromme | = a Aveng fencd a 3] Sipe een Peed wi eres RIC — number of prorons Explain your answer. neveases ¢* nuaearcnay INAASeS. —_ [BS marks} cmt enkassurn Oo OMLE raduur de cas _— Se ae ee ‘nos the least Number Totony weadic force Of axtraara werrreen nuceus Ousermosr eechon So More hardor energy (5 regaured Fo remcye oulermoast eauren . T]4_po equations or Wereadionsctarseicin exdeareshoin.? PrkONSHGLA SHagaad E— “AS20358 HCI 2ASC+3H20” RLACETONSHOMLS | strong OIE G— “As2024 6 NAOH 2NASASOT#S HAO casey bogs: Name the property 6 arsehic(l) oxidethal describes its ably to reac in th6S WS” | safe x U1 marig AmeNGRNC | | [ETEIET complete tne equaton othe rrmaton of aE IREERND | | [1 mark] | | as209+ O2n+ | ZHNos ast + 5 znione + 3 re | : eee eee ee el te - bag: Gay 6 84 6 ty 24 an. 26 Z2nk FS cosmmen axel? |g wizis \2 mye WIZ sre l2 Scanned with CamScannerpoe =o a ws [pra s stows some reactions of aqueous iron ions. © Figure 3 | | Reaction 2 . Reaction 1 Concentrated HCl(aq) ‘NazCO3(aq) ee epee Solution | «———. [Fe(H,0),)5* containing prown Complex ion L Reaction 3 © [Fe(HzO)g2* °: a3at Reaction 4 Concentrated NH3(aq) Give an equation O14) [Give the formula of Precipitate J and stataiseolour! [3 marks] Formula of J ZT Fe (HO) Prepay | Spur et Equation “2Efe(W oie) t 805 2 absebae)s ona} BHor xe, Grae] vid tn enn an) romiso.___ CF OCG mano Equation Le (Hys)ets ¢cr7 > Ceeciadng H,0 | [PTE}ET svocest a reagent or Roa 12.0 We W20 ‘Tum over > Scanned with CamScannereet ai Cond wie | me ‘pre | te ois of PR nana states calor / | fo [2 marks] OF) aot L Fe (4ad)q (GH) 25 | i Colour BEL 4 bug | jow how they lead to different” | | [ tr UE ois Hons ns IsoMerEM - I erauumarraosn Scanned with CamScanner{ = ——— NO,50q FBOy ‘Observation 1 oO C brown : Role» _.OXIGWINY agent. Chlorine reacts with Wot @qU86u8 SoUili HYEFEXIGS'@s shown in the equation. 10" 3 Clo +6 NaOH + NaCiO3 +5 NaCl +3 H2O Give th oxéation state chiorne inact NaClos vy +5 : 2 | Nact -1 . 3 | tcl | Nawdg =O* | TAG hae el ~2 tle -h =O . Ft Dont ute ‘a ae gros”: Saeeme tn fn NO Be, + Nys0g, > NOS0,, bE B | ail Scanned with CamScanner" a EA 1 | | : ———————————— cme CELE nie Meme ms mc omen [4 mark]) ow see unt ncn ane mtd ory lose} . ona 38 SS | [OTS7E Gomtion ¥ : | ate, s Beg wean Mag: | ‘The observations after each addition are recorded in Table 3. te Table 3 ee eee —— terrae skton ener ones excess dilute nitnc acid "cream precipitate D and bubbles of gas F A Son | NZCV= (AXLo ols 0g =7 2xto abnopcuets 2x10 2s CP | 3) n oF cote In 2s60m3 = 7-2 XLO PMI | 4) n= my mt 6)162K%107F = MI/E3°S *) m op cw = q2xtor3) RC 68S) | moss oF cv 5 0 S729 | ‘ a6 -F | 0+ 4572 1100 = 46-457 eS (64 abS a | one Scanned with CamScannerg ‘Shogest two ways that the student could reduce the percentage uncertainty in the ors) eared of the volume of sodium thiosulfate solution, using the same aratus as this experiment. = : [2 marks} 1_use a1arg? MASS OF SUD atoy 2 OSt_1ess CMeNWaed soduM Miosuiphoue - i | State the role of iodine in the reaction with sodium thiosulfate. | [1 mark] ! oye}4 Oridugng AGE y | ant POO’ Cy grees peprr o7e14 om ot, est exrognamet on °F ed - | [1 mark] 4s* 2st 2p" 35" gp ad 4 (oTe sa wis) gus is white, oor eyo DS Shexs i Beper( 1) todide hap a All d orn UV $0 CANNUT dvsarb UgHand emus BU Of it 50 18OKs unUe -erer (1) ded ve Hears OUCOLOUS oF Hho ColoY —Specmim of 4 Wavers gins and | AkLSAbS NO LAN - | | | Question 6 continues on the next page i | 13" Cy aron= 24 , Scanned with CamScanner42° eoneoreost * qeMol car 3 ys > ON cee [TTF] osine vaporises easily. v Zh Le 6 = Calculate the ncroorgeretin vapour Ko cases P x1000 ; : The gas constant R=831VK! mor Sg 166 + 273 = a6 7” Give your answer to 3 significant figures > [amar] ove ner T =~ 466K Re ye MAT = 90 8\ v “7 p= 100000 Az 003% Tz n: i q 10-0841 ~? Mm! 9-00 y= — m? yan® v= mt: (2669 x 0& (4sF) voune | 500. em: | 16- yz 0F039% X 33) x 455 —————— er 100 000 ye 1494s yior$ ye = 1499-598 Y = 1800 Scanned with CamScanner| [OTT]. “suite oxide decomposes of heating to fonrvan equilib miNUr@ containing | * 142 Me “sulfur dioxide-and oxygen. an, | | * RICE equate | “sample of sulfurtrioxide was heated and allowed to reach’ @quilibrium’at a | | | 4 given temperature. | The equilibrium mixture contained 6.08 gofsulturdioxide >» = Mi mf | | | { eS Calulate the mass, ing, of oxygen gas in the equilibrium mixture. eel 2 MUM, 5741 plelaget? ny nein 280g S 2502 + 0, me i { xt 2 22 : . 1 OG tae C . = +0449: 0° 0444'x0+ OF? . , 0 094% “40° 047¢ WE §2 5 ates 74 i i | i | I | | i | 12 +08 5 7 Lr oat mo 7K 0.047425 mat Question 7 continues on the next page \ “i Nrd2: 82 | Mr8On? 6 E- oes N 80,= 0+094%% nz | fn te | Mz 0-047425X 32. | oe none nneeneencnton t tgg “45° : Scanned with CamScannerA re = at 1050 K | is 29000)» 25040) Ona | . “The amounts of each substance in the equilibrium mixture are shown intebles.. | Table 4 i sulfur trioxide | sulfur dioxide | i oof KP | “| bo (4 marks} ps FYTP KP = (502) p(O2) | (3)? i | Mole fraction SOs 6 SL : TO) | a62¥IOT> Mole fraction S02 stb ae i Mole fraction O2 “a8 26S . 2 Toa K195 seston oa 2 ! 2 = P(SO (61) > CISTI) (soe) F z 7 +62x10%: 9. B2Oxz yG.2E2K PCS02) 9-OU2goty: x = LIU ESF. 7094 on +3622 0-3 20k 0+ 282 K 22 8 2egx 554294 .g817 | ea ano) 2it2 =0+1604 Orisi(sst) 803 = = 0-566 SOq = PAOLA Om” 14 2000 me 02 = 0-60 (212~ a 2¢3 _ C3s¢ ) i ol (BGuunta7408 Scanned with CamScanner7 | [PLTAEF§rthis reaction 7 ‘equilibrium constant, Kp wane | sae | For this reaction the equilibrium constan lowes Lorrie n can be used fo deduce ton HEMP, wus — [2 marks] | e A_lowey ie yo Casses CaUoNM ra oso" ov SALA QNd fayays ene tAdorn2m ie LANK - BO ME EMTAFds LAM NH MS be [ELT] Fhe data from late at 500K, forte equitorium vy ae [marks Aa aeuer P (80g) Ve % Pa +P ¥ ‘Tum over for the next question \ \ \ Tur over! 47" momen Scanned with CamScanner(0220-60 (212+ 0.23 CSsé) | a | Tea ——— of | include at hom pp pal ben I : | | eats I wed {8 marke] A Str | | a” § JON na OS yo | oN 2 4 | Lk fe ymer of ethanol | rea Metnoomet ‘Table 5 shows the boiling points of ethanol and methoxymethane. 1 ie en eh yygatt org se Tables ern 4) | \ H | compound Boiling point /*C | wa 1 c a point | , tt -4gm 7 -0 | HAG | metnoxymetnane 24 | || ukde Ear es ttn sabi)” | | a | Memor has _gevno. le AL, | pores uneve os eynandl nas nydtogen bOnaang — | “wir is senger han Pemantny deo __ | i etnanes | | Tw ere ear re over hydro. ou ch MIOLYelnane sO pOUNla POUNE 10 GANA Nel 18° ts sro 8 : Scanned with CamScannerSusoetavatetortebndereenCrs guna d | SRR shepeorciry © | ga Q ~ gu F Fo Sept a? 7 m™ avy baa & ca raw the shape of the \@ shape of the ClFa~fon,” PG Include (6-60) | = te 26¥L0 | tm \*¢2S _1+2%5¥lo_ 1o. oa | | ‘pe 1 §_Suggest which indicator is the most appropriate for the reactionin Question 09:25 i Tick (%) one box. [ | 1 marig| | i Indicator pHrange —_| Tick (v) one box ] | | b x methyl orange 31-44 v% | | bromothymol blue 6.0-7.6 , | cresolphthalein 82-98 VY \ x Ds | indigo carmine 11.6-13.0 | | Question 9 continues on the next page | | | \: , 4 | | ' | | | | 4 = Sens wR hs acc ee el hdl ay Tum over 29° : ccamarsonn Scanned with CamScanner | |yet 7 cyd-SOd 24 (4) A student prepared a buffer solution by ofa WA scion ‘and mixing thoroughly. — \ | of potassium hydroxide to the buffer solution. | | [6 marks} | 4) 0 OF Sadr = 0-016 mal 2) chD Ol Tarde 07 0l8k = 0-036 ol B)N RR = GotvoS=o-asmal 4) h of = 3 xto*mal ; s) NHB = AHP una —Ron added AHA = 60S ~ C3 not) =O -o¢e ATMA! nh “2 nh ~unal + Non ade 6 | ns 00136 + (sxL ont) 20-0184 ma! 7 )ka= tHt CA J 5 LATS HAD tr] ay TRAD 424 | *) mass tal shy *6 eqvrges) xo" 4) cutj. seis + 00) | eee'S\ yond ppt ERIS UBHLE®, we (Jeet to7S ) 40 +5 en a 0-134 EAPO = ph 24°24 28 Scanned with CamScannerCentre number Candidate number Sumame SHAKEEL Forename(s) NAIM AH A-level CHEMISTRY Paper 2 Organic and Physical Chemistry Tuesday 11 June 2019 Afternoon Materials For this paper you must have: + the Periodic Table/Data Sheet, provided as an insert (enclosed) + arulerwith milimetre measurements ‘a scientific calculator, which you are expected to use where appropriate. Instructions + Use black ink or black ballpoint pen. + Fill in the boxes at the top of this page. + Answer all questions. + You must answer the questions in the spaces provided. Do not write outside the box around each page or on blank pages. + All working must be shown. + Do all rough work in this book. Cross through any work you do not want to be marked, Information + The marks for questions are shown in brackets. ‘+ The maximum mark for this paper is 105. Time allowed: 2 hours For Examiner's Use ‘Question Mark [asics = SSIS *JUN197405201* Scanned with CamScanner 7405/2 Be bine aa esa nn we‘Answer all questions in the spaces provided. - ee 4 Tis qesten s les VORP 1a BC hun ag reaction of, *; j with ip braahesae wh ee UES. ia Ce Nib, TF4NN3> 2NH 2 (CHa) bNA2 t aNHa8r a = { [4 marks] 1 *o2* Scanned with CamScanner*JU * IN197405201 eounaer 7405/2 a Dont wie ‘eucone rks] | ¥ exes omand, . sate 1 reagent and condition | “Cx@s5 ehanoud amma repue” | aoe | “enandtonanwatcd HCl eRe ana ei | | OTT}42] Berlain why 3-ami alles maven Oe marta} | no-q-c-L- dd h WH 3-amus Ne is o We 5 lies fous, u an CUKY) 4 COUR eNBre fs e more Oe arn eee pea el HE becouse sno undiorie effed - | Sra ann aaa | {1 mana) | 6 ——— t | | & du aun \ gre a | akranod 49 conya} (ON. | | | Soo pranopttense Scanned with CamScannerppg: aa ATA) complete a" distil the 6yehexene fof the eecenm [2 marks] Scanned with CamScannergies, AoneX Ene sowh o | use" cear EER ‘Finis preparation, the student added Se as t _—tae4 g of cyclohexanol (Mr="100.0)——— m ‘The student Sn eeeeeeenel auvak ¥N 1-2: Dey teconemneostoger/—P OV aorencau or Soe ere a ag SE | 7 [Smart | / HgPoq + CERSOH —> Cerio — gna meorencat mats of cy aontye eee + $08 " a i von nevanot $2 ur 100 | 5 One 0. te | 5+ nog eyaonerene Not Cyaonex arat oe-ee. | =l4+€ =o144 Wass 20 KNMC | | 100 Mass of cyaonexene 3014452 Aceyay MASS OF CYACHEKLKS = Lneorencar fa0ss | | = Mass = Oensiny ¥ VALU? of cydone ere | “mass2 0+ $16 XQ-IS C3st) = 1 7808 | | Macs = 3+ 36154 wyed’__28+G a | Se yiad = avd) mass x10 i 323015100 aueston2coninueson ihe nxt hiGEYEFICHI MASS | (urSo Ly = age 4679875 285% Tum over > *05* ‘ eoumarese ee tof. 1 AYDON W.nen Scanned with CamScanner___-eacerapnule adduadi | [OTE IE] ‘ovetatiexene reacts witn bromine CQ | ‘Complete the mechanism for this reaction. cs A | _ sneverd 2@r | 1 a | ge | | | | ' *06* =... seamen | Scanned with CamScanner7 3s aa BR ow 7-3 | Ct ys ) tLe 6OSE Ge Gs + -02721+---- ae Molecular formula | ‘Structure HH i H# HW teow yy | | ! | i CSS ee or done: ond | sorewvere // 9-mernyl Buta-1,3-diene | | “_ Wigete = Mee t 1 t { H-c=>C— ca cH i a care Scanned with CamScanner —— §| ] Donctwete ‘acai ! N —c—c— We Ca. ' % H Scanned with CamScanner| Reason 9 ve FO vesmcred Toran Qocut Me | pranot =c Adsupie Ponds wigher Pr groves on Sarre or oP PO5Ue sides OF We cele ae Ta aE ene cn TSE PERL | pas | | mey dom 2 ON maromdas on | | non- PMA bonds $0 NorSvs@PNbIero | ® WWOLGPRLLE Outadc ‘Tum over for the next question Tum over > *09" Boumarona Scanned with CamScanner40 1) ee = | Ta ae (fle atirey®™ The 1 | if ert suring the change || | ‘The data obtained are shown in Table 1. i | : ) | Table 1 | \ | ‘ eee | | Time after Concentration / mot dm” 5” | | Experiment mana! 5 a | i - A soon? | azsew? 4 #4 | 50 X/|f/os2xio? | notmeasured_ XZ | . 0 KAooxs? [125107 4 3-216 { so ¢-/Asex10? | notmessuea | YQ | : 0 £0.50 * 107? 2.50.x 10°? | | | 50 034x102 | notmeasured | | | (144 ‘Complete Table 2 to show th ction oan | \ [ oto a n stl | Table 2 | | | | | | | Experiment Initial rate f mol dm3S + { | | 1 1.6 104 | = | ‘Oar 2 Be 2X F | 3 2644¢yig ft | | | Rate = wt 18) | as | } | Leklo * = IAD e00xle eV. 2sKb | 1 | | { 1 i L | J 40° ° ircuuna7 4052, Scanned with CamScannerWoe i \@ T} EDHemine the oer of eacon vith espe oP and he onder of reacon |= | y em | tual oa fe | \ | \ | | 1 | | | | Order with respect to P St ‘ ‘Order with respect to Q z, | gare = K Ce I £s7 | 1 " | ie sa ay CRT | Calculate a value for the rate con FScauwe | i Give the units for k Cae pris ee mridm=3 moran magn | r ‘ hop 7 be 20X10! | Rore | ; Kao | 7 ; 2: , vag et <2 | “* EegeCsd® |, Lr ooxrd* I(t 46x16 J [Ke (2 26 K10-F 1.2 1994 670 | Tee OOUSKIOS Zann 7 94 | sore en 2000 CSE) ey | gop 0006 + ‘um! ma Sante! [| mov Ps eer Scanned with CamScannerThe | in(3* 46 Ko [Sine rate -— ig sn win np shown by the sae | ; | ERT | ci eto > Sel | 1e gas.constant A= 8.310 K-mol-ip: | Calculate a value for the rr this reaction. Give the units for: | > ink+ inh - €4 2 | Doratw onset bat re | -_9 Sore nus [4 marks] i T= 25 +2732 2981 | aT 96 206 “y= In (®Y~ Cg ai yzas) un (32 6 10~F) SI (A) = Br 54700 ~ oT nag iets =ln(* ) A \n A A A Bs . 6674) 2s7!] 3648S -2-67x101(35f) 251X167 nm _¢ >! Scanned with CamScanner(tars This question is Bie 0 wt IO can 2 chy Caren ee C=C —I—shen n > 13 (Te 2 Salata stanton [3 marks] 47 town __aaduhed pani aneaae I Observation a lorcnarge fan | GUN CA . i 0 fo Gre ‘Observation wi itan-2-0l no ws an Question 6 continues on the next page | Scanned with CamScanner-0 H 14 ra | (fpr etiopeneisttainepenm | have te mole emu Cet 6 ate tinue Phang et iffertes oe earunman fama 10-70 g-tL ge: af ey By | | | < BY | 3s Le | Gs 7. | | | | | \ i : ” | \ | | Scanned with CamScanner43" “1 pected [ = caso cy 26 ie C-G O- RM OC O-n oO si “ q cry — cH 16° cH, —c% E erred Onpat € “ou : O—CHy Gs ¢M,-04 Wavenumber/ emt +45 Tum over » poanterove Scanned with CamScanner\ = 6 7 1 aS ee 26 | “ae ut om [ae Yh maou o ASB h ssomer X Isomer ¥ i sant Jeo KO dlawt gg Cee | ) GO —ap ~~ gee noma | agclopenra none | PE Explain how and why isomers X and ¥ can be distinguished by ae... each of ; Womer Y-hos anighor WANG Pan | thon isomer YX vecause Nnas O-Kvard | Seta waAucn reat fi nan eo Mant dvate dure tine ee | tara noe hegy feagincte | | Samet x Gabe aainawiieg am | | bea agp cn ar C26, wh ‘er 4 = Cs amen a ne Uo _Oles “6 Scanned with CamScanner\ BS aah a's | ond {Ne _pe phar Ot 1626 -1egacn | Qe £SC nn ho “YX hoes Ar a : | CHNR . isomer_X WS WO peaies th Lk?5 Spedaum One iMpler and OMe singer - Scanned with CamScanner“17° Tur over > racium97 4082 Scanned with CamScanner4-nitrophenol 4-aminophenol , (eet ee [1 mark] VOOTo Pn UL ¢ cama 5 VOStUAA a OH | fe OH | Oi = C)- 2H J4_] Complete the equation witinanaae eo | [1 mark] | Scanned with CamScanner19 ‘Question 8 continues on the next page “19° Tum over > | Scanned with CamScanner>| conc wre ro {1 mark | i i i | | { i | [OTR] Shei have recently developed a two-step process to produce paacetael rm ene. eoietiat step, phenol is oxidised to hydroquinone. | ~\ (a | { }) + Hy. ——* wo OH + Ho | hydroquinone 4 | enna = PF Complete the equation oy | ' oH Yr | | oa 65 SZ KA 1 HN, CHs + o~ i | ft { ° hydroquinone paracetamol i {1 mark] i - h 6 | | = Neut=G 1 | H-C-Cw# | it : aoe i babe H +20" ssotnnnarese Scanned with CamScanner_ Nok hy dro qua’ - e n= Mm n= l*6€S 142 n= ls “6S ° me 16S Ee ( Re NO N of PAFacora Ma) ~ | +@mol Mass VR 3s) ($2 ‘9 | n — ™M 280 Kg LEO ‘Tum over for the next question 280/icy 6087 \- és Scanned with CamScannera This question is min | and the plate placed vertically in a | | fs | 2 sed te 7 re ‘was: ‘smal lume of solvent 1. * Whe the solvent fentreachod nearly to the top ofthe lal the platlwasinis and to dry. 7 STD ancciise two" ace eine _ Volume of solvent 2. . Wel vent front reached edly to the top Of he plate the plate was agin » removed and allowed to di | + Figure 2 shows the nal te pao, Figure 2 | Solvent 2 direction | i it i ost ve e Solvent 1 te direction Solvent front 2 | I i ; i i | © Spot seen after || / use of solvent 1) | ® Spot seen after || Position of use of solvent 2) riginal spot | dz" 4 ta dt adi ] Suggest a suitable reagent for the hydrolysis of protein. «s+, Ct mar H_ Scanned with CamScanner oman ot—_ —— Sy. “VV a | | [2 1912_] Suggest how the positions _—— on the fits Mag VV nghk \ — ee a | ; \ (OT214] Deduce nino. the original mixture. \ [1 mar 4 pn s re On| | (0 ]814_] Suggest why it was necessary 2 | (1 mark \ AWO GLAMRNS SOMME NAVE du fer | QPWINLS +0 ~* Strangiony | ut 1 ive era i * Tum over for the next question Scanned with CamScanneramore | Aid | Giaen “a “Ce [3 marks) | | 4s 4S K2 =40 -%0 | | C183 | - | ‘a | a = “ U4 marks) | 280 ‘et Neoit | 010 2 2): boon cor peer | [see | ~, \ not NaoK> NW 260 yO169= 2+BS44K10 101 06 nokaud = 2°35 44 x1o72 Mm In US cms 0 623544MdI oO cm$ = ; on ofaad in as | ne ™imr Ms 0+0235 K NS ZU TTBIVE 2: | | ' | 3 m 1 a“ Scanned with CamScanner25 ee = i es cia" le number }Own. H Hq & | | ark Ah Ha — C— CH) — CH, — C— CH AUN” oh | or’ OH oH | Deduce the number of peaks in the *H NMR spectrum ofthis diol. | [1 mark] or sete | [7T04[[] Draw the structure of a different diol also with molecular formula CsH1402 that has a HNMR im that consists ee Soe es mark] | bh We peg 18 dar : { t | u \ \ | — Ce ee | C + i NU | » adds 1 fo. The dicarboxylic acid ne mor ssamtey say ere aN B ee at Yih gd 8 EY timer} eguTos Pray ianisand adds ,H" iheeastry MOG by Che Hignor Preaiicn wos asus bexwee because Phay ve He corre OP TEE Noavesy | Wie nun’ Using 16W TESd WARE | eee mas 5 pe. arant! y 7 ae | Tu oe im over Scanned with CamScannereae ST a =a onan This question is nt RS oy Bh rg alee ee ee pow Eauaton (eng er, £0) 0 + CHgcit,dH > andl CH,CH, on * omoncon —> CH ACH COCK CH +|eH @ propanocue Name of ester — ounce . | Ina reaction a —— | to “ee en ester with so Tae toma [2 marks] Cig heer Scanned with CamScannera wt febe ‘Part of the structure of th s si | | ‘ | Complete 1 oo | Inyour a 3 D CHgCH2 COO Cg, t Cis C12 COOH | | : wa ki ong HOF i eo ' i Heck, (OOH 4 Poy 5 3 2] ; ha we: | ON NR OES | 7 i {2 re i |: 2 Coste | DEEPA) eine an equation for: of ! aun ay ... 4 h 9s | Ag _Srah3q02 + 0, > CO, ta ~ Question 11 continue’ on thé next page Scanned with CamScanner28 ir at on aaa 2] | [ELT] FSpmbustion of vf 0 | cause global war Part of the 100: Transmittance /% 50: © ee tore b- Ae "3000 2000 1000 ‘Wavenumber / cm=1 rm | a ‘eo t as infrared spectrum on dioxide jou = i ‘might precict from the data provide 100k | Cre (1 mari yor Thete sno Peaie @uSGrphcn at Lé%0 — \ \1$0 cm=\ For He C=O pod | | | the 1K SPEC a. ot | THe Eo id ing. \k en eno nua, Voss VF | pres The _€20 yondametes Infrared radian. o Apsorar Hic gNeqy and (rau ror j INGeoihge te Emperature of the gas. Scanned with CamScanner° Hos O=P—O0 Sw (Waas Draw all the nferogen bonds between the complemerityy strands shown in Figure 4. mt. H Use dashed Jines to show the hydrogen bonds. Wer You do net need to show lone pairs of electrons or partial charges. . . favmarks} eS ~ Draw'a ring avound'each of the component parts that make up the oytosine ndcleotide _ inthe section of DNA shown in Figure:4. oe - [2 marks] 12:9 Shien asin of the term complementary when it js used to refer { bem Cesta 2 weypi f [1 mark} Adenune 1S tOmpomaran to Thy mune and cyresune Compremanrerny Lo | guanwy- Ca Adenure nosey ano yee. Mowe 2 Wyd 10d en vonds an mover euvenuce ano. Guanuwe have Zhydroger *29* Sir S at Scanned with CamScannerwR ASH oman CEON POU $0 thenvaLEph Ue Cun | OXTOUC Wye PUYNELS pUSUVe LIOR - AYcere, Avemrnave * 6-0 grow co (sg nan~ Pay | | and CANNOT be OAded by NuUoOpnIe | a5 nee tenets ty Agubie bad ee ee <) srw Reagent | | ‘Observation I \ END OF QUESTIONS Scanned with CamScanner—AQA# lease wile clearly in BIOCK Capitals, Centre number Candidate number ‘Sumame Forename(s) Candidate signature A-level CHEMISTRY Paper 3 Wednesday 19 June 2019 = Morning Time allowed: 2 hours Material For this paper you must have: For Examines Use + the Periodic Table/Data Sheet, provided as an insert (enclosed) ‘custon [ESE + aruler with millimetre measurements + a scientific calculator, which you are expected to use where appropriate, 4 2 Instructions 3 + Use black ink or black ball-point pen. 7 + Fill in the boxes at the top of this page. + Answer all questions. 5 + You must answer the questions in the spaces provided. Do not write outside | Secton B the box around each page or on blank pages. TOIAE All working must be shown. + Doall rough work in this book. Cross through any work you do not ‘want to be marked. Information + The marks for questions are shown in brackets. + The maximum mark for this paper is 90. Advice Advice advised to spend about 70 minutes on Section A and 60 minutes on Section B, Lys *JUN197405301* ans 7405/3 2 3 . 4 pias ic OP 00 a a Scanned with CamScannerne, Answer all questions in this section. [ola] }~—"Sodium'thiosditate reacts with NaaSpQa(aq) + 2 HCl(aq) —+ 2 NaCl(aq) + SO2{a) + S(s) + #200) min create $203°7 +2 —» § +50,+ HO [ETT ons Balsa pots aude | ASNT \ shown. [1 mark] State the property of SO2 that.causes pollution when it enters rivers. Give an equation to show the reaction ees | i : | Property Quadro | 1 \ \ | Equation $0, tHjo 7 HysO 3 | \ | [2 marks] SO, + HO > HS04 F Scanned with CamScannerTAs : 6 Bond anglé wGr+S -- Explanation on jaurs ©! | CONtAL Oxygen axe and 21one paw of w20r, =v -sn | au and é ou eqn Pasi end yen din, paul 2 Os ema and OS fat apart os possvore= me bending Pou Lone pa repasion is Gleater than Ho Cu OY repvalun Moreh te “pacha te eas oat gee es cone pauireputstay LP LP repusior> Lpbe PMSA > 6 P GP repwia, Question 1 continues on the next page * Pusany b ond v0 cet revere: i Tum over > "03" aun Scanned with CamScanner0] 1] F The initial rate of the reaction between ws ar ie ror ‘ monitored by measur ca fh ul fae fe the eff \e init : inwaer b Include pee teow \ ; ti anne ee wore f sulfur to be formed i [8 marks} Add _sodum tniosuieque and HCl and | MIK Phen IAG in awidierboth > Mtosue | A _FANG* OE HRMPeIAIUES and the pve xouen for a A¥ed amourundt SulA tO le Pieduad: Paw the CONnUa AoxK ON FOP of AWACk Wass ANd USe o SWPWorMd¢d MeOSUR the FUN taicen lot tre Kass £6 Odsappear » CaLCWQe the inthal fate op reacnon 1) time . Pesenx rey wre “enagrath 4) rue agaivy emperane a 7 ae Scanned with CamScanner8 van: Qh ne grand Sh uncn Q 6 SE) cmeenevelseecsee es, x = Showa and wAbondi mao Ee (ima) q H- O-S-0-H “1 it ast ci q pos gon The 9 |) Remarks] “deudts - M2S0y : WIE Asa ploe Swegnug beat on 200 balang and pnd mass; feaconskintataricen | | (4 marks | sda NOHSOg desived mass +8 WeghUig pag Transfer to ond feweignt Weign GEN ont | QU_Nalic0g dussONed sTransfer tO Youu ¢ Binse pear - 4 Tum over > Scanned with CamScanner0 2rd U NS eset bebavngasa | _ Wr NQHS6¢ = 120-) : | NA Nawsog = S:66S z seagtees KIO” 120-1 3 we 5 +3768 HO = » = oe cn LWSe d= ——o., Vc usogd20-0S037 4g. ego7v i 3° 890" | io" ™ Cat] = 0-056 0- 06037 qeayos | | - jw 2 K10F ase) me mata | Ln ERED enone i EE ict: | en I TE al | \ | ‘Turn over for the next question 0 NOT WRITE ON THIS PAGE ANSWER IN THE SPACES PROVIDED Scanned with CamScanner0 " TEES” rioue + represents te caused to measure te standard elocode potter | "m= (emenermiomesor" =] rere aston . ar pais rs ero a | Tablet | | | 7 eentty | andtons | | | c | | | | ° x | a F | e | qegaue i (EIST Nhe epic ct apprtoaind viet) (Eee cent em camode Give the ionic equation for the overall reaction in the : ‘State the change that needs | tobe made to the a arin ge aut 0 ‘easton goto complcion es com = Cnet pesuw C ove a cred | | ho | Nonic equation | ‘crerae ot Name te substance used as elecvode Bin Figur t. ’ Bo mar) | — Graghue * | . "+r. ueton 3 ediinuas on tape * \ \ aa oo a — a or “10° econo Scanned with CamScannerTe 2 ; , § ao se EH) osm ar = a student sets up a cell as shown inthe call representation. ommne [SI lie how Ecel varies with concentration for this reaction, [2n2*] Zs)ea?*aapiew?"(aalouls) | ‘The student measures the cell EMF, Es, wih several diferent conceniraons of | = aan oer [Sd cans and 2 ons. ce eal text The rents re shown Table | siematon inte em tn equ os sri in. y= | i | | uct he cer four pt ine one graph in qvesion 036 | ‘You must show your working. 7 en «sn gbcdjoinibesid Experiment | 1 mol ars | | ve your gradient to calculate the temperature, 7, at ic he mdasuremeis 7 Ooi | | eat wore taken. 2 010 » Uepowerg unable fo calculate a gradient yo sould se the vali 0.018 (iis tent ine core vale) yd. 2 10 B < 10 010 i —s 10 ‘oo | 461 i CCompleie Table 2 1o show the vale missing from experiment 4. | Prot a graph of Eze aginst in (2a V1CuP* on the ri | | {3 marks) Gradient re th h | (then svat ent omncPeeena ¥ EmlV | Use data fom Table 2in question 09.6 calculate the electrode potential for the i 2n?*/2n electrode in expedient 2 | ive one reason why you calolated values ferent rom the standard locrode potental for 2n¥/2n elecrode Pat Scanned with CamScannerte] E | | AEB ere gnameorin niet _| se . mark) AdeOPHULE adduincn | a a a a ae | ‘condtons OIC | [ETE EMHe 2ryacxypopanentee ome by thereat n question Os a miure of FeEMOR dae bord * HrOSING, 2 CAG name ne | cote teeta eusamie ganar corms! (EEA craw a secon ofthe polymer ptyacryonii, showing three repeating unit, A oe Tt c oa Coy 1) b o | Name RaleMLe mivine equciy wm CC CRO OC Cy | none C=O equa AS | 1 tg eta : ben cn 3 = | ‘a EW HE PLANE caw : || | : —— t | et rte | On \ on | 1 | | \ \ \ ae * ©. \ . 7 UU EN xs dns | Hg hol 4 | | oa (eee | a rlrlrwrwC~™.—S—~—~—CCO ws = aoe Scanned with CamScanner7" Bet 6 a a ae sae ( a EEE vive 4 0 romney mara +aad asaite | [EIEIO ove te equation teh recten bees kon and stint 0 ei Fe + HrsOq > leone +Ha | Tables z z | =o Aaitial volume em? 0.00, | Titre fem* 22.90 | Cat meant, | ALTO + 22-66 | z | - oe ROS, mega es tim | [4] Namen pee tpn xr esd Ht ied oc a ie ‘contig was wed aye ma 0 on “Toking te 250 cm prions Piperre | aig be fetansum mangenatac) solton UY ELE sxbtraced tom yiusng ebeunes pee 0: 005 ¥fi00 | O-6% } feo ve = iS ator KWo am ot— 41 O-005X2 Cor | wnog 4) +e faa) + SFe faq) —pNn’ faa) ae YW a _ FS Feat fag) Scanned with CamScanneroven |S | Te eat meat repo ode ett aca ote aan Ney tte ‘Answer al questions inthis secon | | aie | ‘one answer per question i alowed Fr each answer completely iin te ccl alongsie the appropiate answer. you nano chara) anwar yu con ote nla town, Ityou wish toetum to an answor previously crossed out, ng the answer you now wish to selec | as sown. You may do int black spac round each queson bu hs wl abe marked Demot uae adifna sheets for ia wocig. | A=MIM oy ‘ao seg gg aren mama osesee | =m aul A 80 em? of 0.05 mal dn? NaoH(aq) 3) | 1B 100 cm of 0.50 mol dn NeOH(aa) a | © 100 cm? of 1.0 mol r® NeOH(aa) i} D100 em? of 2.0 mol der? NaOH(aq) i) ns LS NOE NoWK> 0-05 | - 160 > | hor Wea | | q 2 0-0$ #22 6 j | pa1198 tT ¢ NO, + 6H | 400 -US¥2 ALqOd Soul ve 704 (US 2 neers anile + 10, > Scanned with CamScannerree 00 centration of O2 diese conan * aioe | Clowerprossure [hs Duse of a catalyst | z (CE Thema teninstotonctne eaBibeicn Pn ae scons | ae Talal] — | —taiaal(G]—] Taal vate Experiment |_Imetdm | Jmol dor _| 1 mol am"? =~ | 1 0200 0500 0400 | Tobe 2 0600 | catvioted 0.800 | ‘aoser Bos93 coos Dost ke ($2400 i. 2 0-400 = K (0-20) (O-sa) 6-goos 8 ¥ LO6G60T3C ant aa Scanned with CamScanner| _ | Aose ag eons ie soo tS | ers eg) 6° Te bel fee ce oo +X IS | 1.200 ~% XE Ss \ oC . 26540 \ 22 Ee van ma hoa ‘Gy © Samar oe | Settee wise % bipeencbeaetmmnacisespiien SOP f= YK c Decrease he temperature [= Doorwee ew pee fs B-FOOs & FLW VYYUL SD 2 Oe os [EEE reer ver tre seracea sown aug 20° Fos) aay | | CuP*(aq) + 26° Cu(s) E= 40.34 | | Wats th EMF othe cot Fea acu iow? | | [1 mara) | | Asorev Ee | | B+010V = c-o10V Is p-078v [Is CHIE] web te retest itinsaton eng? | an fe | Be -_ | cu fs | oN - | | [CEE] wetter nent ac Atameaccowwimeioy! FH ge 18 Fomsaclourtesssouion and eferesces we | ‘CForms a wtite precipitate onty eS a i | | Forms awit prec nd etrvsces Se 7 _ oe) Scanned with CamScanner[ |es ar | I , \Wic could be te forma of tel | | ] | Ate NaOHeq) iw ABaC & | | B dite HeSO«(aq) TS i Se a) | a exet ira] | DNackea) Tei | vn 8 | | mae HOC ALO" | ea ae oo 2 Eaten nasal x ‘Te boing points decease. a ‘A Becoptic aden [= [prt bond sod ene of x doceases ea | | eiscphite wbsthtea lj © The polaiy of the H-X bond decreases. ow C Nuceophile addon f= | | | D Nueoie ssn Ie sk. D They are more easiy oxsised in aqueous solutions. - AD UNYH) (Ose eoorans mart) | | ‘AAcoloutess gas s evolved and a precipitate forms, [B.A colourless gas is evolved and no precipitate forms, © amcnua imagers eet 1D The solution changes colour and no precipitate forms. aaag Scanned with CamScanner{mana i ro ; sodium hydrogen [Aca Toten | eatbonate Echrommagy | ent | erent [aa] cre | XC [a [rower fete ferent [em | T= range suton | over | Tila |aeaxccwl eel {| | : no visble sher |S | | | [e=[repanone [ovis crnge [St aes Fropancie Sakae] = 8 | | 0 feu ctevescence [ange pre Ie | ano Cy | vv yund is forme acid | si |B) ia encima rece iam atone? 22 = | Dh "see = | | |. BostecHo = | i coassoocts tr | | | DeaHscoon le | | | |THE) Asienangindnayannss anos A | sin Barocas sit a TS | j B.cakiomsutte te Potassium hydroxide To Potassium carbonate, fe Tum over > Scanned with CamScanner2 Inthe UK industrial ethane! is now produced by the direct hycation of ethene, This =x process has largely replaced the fermentation method. Which is ely reason for this change of method? (mang) rect nycation route produces purr ehancl cana’ \\noeee | ‘A The direct nya produces purer = tends | B The direct hydration route employs milder conditions. fo =] A | adenine | guanine 2 a | | The drect hydration route does NOT use a catalyst l= B | oftosine | tying 2 a | wr | i reac | auarine | ofosi 3 i) | ZX, Pedinetierton rte resus eae by oer con [S | adenine | tnmin 3 a | ~ | ‘ AYE! a a nn ZA Cg 1 a, {man _A-T sodium ons in moten sodium chore io | { 1B The electrons between layers of carbon atoms in graphite iS Tbe serosa rt | | | en | Scanned with CamScannerRae | a ‘CH.COOH, 1 \ A H—C—NHy ; | coon Grc00H BH ol fay | boon | END OF QUESTIONS ‘Which is the main aspartic acid species present in an aqueous solution at pH = 142 Ut mark] cS a Scanned with CamScanner