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KGS - Geological Log Analysis - The Gamma Ray Log
KGS - Geological Log Analysis - The Gamma Ray Log
Radioactive isotopes of elements continuously decay to more stable forms and emit radiation of several types.
Gamma rays have longer penetrations than either alpha or beta rays, and can be measured by simple counter
devices, such as a Geiger counter.
Although many radioactive isotopes are known, only three types occur in any appreciable abundance in nature:
The uranium series consists of uranium isotopes which decay to radioactive daughter and granddaughter isotopes of
other elements. The rate of decay is used to date rocks by the uranium-lead method of geochronology. The thorium
series also has a spectrum of radioactive decay isotopes. Potassium-40 is a radioactive isotope of potassium and is
used for age dating of rocks by the potassium-argon method.
The photograph shows a Geiger counter on an outcrop of the Heebner Shale at the corner of 17th Street and Bob
White in Lawrence. The Heebner Shale is a "black shale," whose color is caused by organic matter content. Both
the organic content and phosphate nodules in the Heebner Shale are hosts for uranium. The high uranium content
causes relatively high readings on the Geiger counter. Because of its elevated uranium, the Heebner is more
radioactive than the overlying Kanwaka Shale and the underlying Lawrence Shale which are "gray shales."
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However, both black and gray shales have radioactive sources of thorium and potassium and contrast with low
radioactivity of the limestones between these shale units.
Because radioactive decay is a stochastic process, some degree of smoothing is made by an averaging (time
constant) circuit to cut down the statistical noise. The count rate is also smoothed by the logging speed of the tool as
it is raised through the borehole. The time constant and logging speed therefore influence both the bed resolution
and the amount of noise recorded on the gamma ray log.
Older tools were recorded in "counts" or as microgram equivalent weights of radium per ton. All modern logs are
scaled in terms of the API (American Petroleum Institute) gamma ray unit. The API test pit at the University of
Houston uses a concrete calibration standard with a value of 200 API units thought to be about double that of an
"average" mid-continent shale.
The gamma-ray curve is conventionally displayed in Track 1 on logs. It is common practice to see the scale range
of zero to 150 API units, with a wrapped scale of 150 to 300 API units, if the curve exceeds 150 API units.
However, this scaling is the conventional choice, but is under the control of the logging engineer. In the Niobrara
Chalk well, we have already seen that the logging engineer elected to use an expanded scale of zero to 400 API
units. He did this because the high uranium associated with the kerogen in the chalk would have created an
annoying tangle of wrapped curve on a zero to 150 API units scale.
The gamma-ray log is made on every run as a reference curve to help maintain good depth registration between
separate runs.
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Gamma-ray scans of core are also taken to reconcile core depths with log depths.
In most stratigraphic and petroleum geological applications, the gamma ray log is used as a "shale log," both to
discriminate shales from "clean" formations, and to estimate the relative shale proportions in shaly reservoir units.
The higher levels of radiation in shale are caused by absorption of thorium by clay minerals, the potassium content
of clay minerals (principally illite), and uranium fixed by associated organic material.
By contrast, sandstones, limestones and dolomites commonly have low levels of radioactivity, although numerous
exceptions occur. Sources of gamma radiation in sandstone can often be attributed to clay minerals, potassium
feldspars (in arkosic sandstones), micas (in micaceous sandstones) or heavy minerals (such as zircons).
In carbonates, radioactive zones are usually either shaly horizons or levels of uranium mineralization, typically
disseminated through the rock by diagenetic processes or precipitated within fracture systems.
The limestones have low radioactivity, with a value of about 20 API units.
A representative value for the gray shales is in the neighborhood of 120 API units.
The black shales are marked by much higher and variable radioactivity which is controlled by their uranium
content.
The succession consists of cyclothems that record repeated marine transgressions and regressions in response to
sea-level rise and fall, associated with pulses of glaciation in an "icehouse" world.
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The basic cyclothem is initiated by Lowstand terrestrial deposits of gray shales and sandstones with local
developments of coals, succeeded by a Transgressive systems tract limestone. Black shales occur in the Highstand
condensed section and interpreted to reflect deposition in the deepest water under reducing conditions which
preserve organic matter and concentrate uranium. The black shale shows an upward transition to a gray shale as the
depth shallowed and waters became more oxygenated. The succeeding Highstand regressive systems tract
limestones record progressive shallowing and the cyclothem is terminated by terrestrial sandstones and gray shales.
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The energy levels of the gamma rays are characteristic of their source isotope and form distinctive spikes on a
gamma-ray emission spectrum, although in practice these spikes are smeared into a diffuse train of peaks by
scattering events.
By subdividing the total energy range into restricted windows, estimates can be made of the separate contributions
of potassium-40, uranium and thorium through computer processing.
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The first commercial spectral gamma-ray logs were introduced by Dresser-Atlas. An initial successful application
was the detection of radioactive fractures in Austin Chalk wells (Fertl et al., 1980). These zones had originally been
interpreted as shale zones and not perforated. By running a spectral gamma-ray log, shales (moderate potassium and
thorium contents, but low uranium) could be differentiated from uranium-bearing fracture zones (low potassium
and thorium, but high uranium). Recompletion of the well using this information increased production seven-fold in
some cases.
Essentially, the uranium had been emplaced in the Austin Chalk through the precipitation of uranium salts by fluids
moving through fracture systems.
Not all fractures have increased uranium and there are a variety of mechanisms by which uranium can be
concentrated in a rock as we shall discuss shortly.
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4 for Th (ppm),
8 for U (ppm),
and 16 for the K (%) estimates.
This relationship provides a useful method to predict subsurface gamma-ray logging values of shale samples from
outcrop and core, based on laboratory geochemical measurements.
Analyses of the North American Shale Composite (NASC) reference standard for gray shales (Gromet et al., 1984)
reported values of
Th 12.3 ppm,
U 2.66 ppm.,
K 3.2%,
which converts to an equivalent SGR log reading of 121.7 API units, when applying the 4-8-16 multipliers.
The hypothetical log value of the NASC standard is a good match with the gray shales of most Midcontinent
Pennsylvanian successions.
Equivalent expectations of the gamma-ray log response of black shales can be predicted from core or outcrop
samples that have analyses of thorium, uranium, and potassium contents. So, for example, the Marine Sciences
Group Black Shale Composite (BSC) described by Quinby-Hunt et al. (1989) is characterized by values of
Th 11.6 ppm,
U 15.2 ppm,
K 2.99%,
As might be expected, the K and Th contents of this black shale composite is similar to the gray shale NASC
standard, because those sources are controlled by clay mineral and silt content.
However, the high variability of U contents among black shales results in a broader range about the BSC standard,
so that a maximum equivalent of about 3700 API units would be expected for the black shale with the most elevated
U content reported by Quinby-Hunt et al. (1989).
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Shales are the most common radioactive lithology that is seen on a gamma-ray log. However, other lithogies can
generate high gamma-ray readings and their expected API values can be computed by applying the 4-8-16
multipliers to analyses of thorium (ppm), uranium (ppm), and potassium (%), where these are available.
The gray Kinderhook Shale overlies the black Chattanooga Shale in the spectral gamma-ray log below, from a well
in southern Kansas.
Notice that the SGR (and potassium and thorium contents) are very similar in the two shale units, and that the
difference is in the uranium linked with the kerogen content.
The Oklahoma equivalent to the Kansas Chattanooga Shale is the Woodford Shale, which as been a major
play for shale gas.
Uranium in Limestones
Exceedingly high concentrations of uranium in limestones are unusual, so that the only limestone that qualifies as a
commercial source of uranium is the Jurassic Todilito Limestone of New Mexico. Although various theories have
been proposed for its origin, dating suggests emplacement shortly following deposition in a layer interpreted to be a
sabkha deposit. Rawson (1980) proposed that uranium-bearing groundwater was drawn upwards by evaporitic
pumping and precipitated by a decaying algal mat.
However, zones with anomalous concentrations of uranium in limestones are often seen on gamma-ray logs and
their origin can be attributed to a variety of mechanisms such as:
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Outcrop of the Stanton cyclothem near Kansas City showing the regressive Stoner Limestone, the Eudora Shale
(gray), the Eudora Shale (black), and the transgressive Captain Creek Limestone.
On the next page, we will see the logs for the Plattsburg and Stoner cyclothems in a well in Wabaunsee County.
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In the Stanton cyclothem above, notice:
the upper (gray) and lower (black) shale zones of the Eudora Shale, as shown by the differences between the
CGR and SGR logs in Track 1
that the Stoner Limestone is fairly shale-free as evidenced by the CGR curve, but shows a distinctive uranium
anomaly in a zone displaced slightly below the top of the limestone
that the regressive Springhill Limestone shows a similar uranium anomaly to the regressive Stoner Limestone.
Finally, an important lesson from this log is that any uranium anomalies will make a limestone appear to be shaly if
logging is restricted to a conventional gamma-ray log. This is a reason why companies will pay extra money to run
a spectral gamma-ray log, when carbonates in a section of interest are known to be "hot," such as occurs in the
Permian Chase Group of the Hugoton Gas Field.
How was the uranium emplaced in these regressive limestones? Maybe the answer is on the next page.
This is the mode of occurrence of uranium anomalies that have been measured in modern cays in the Bahamas
(Chung and Swart, 1990).
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If the modern analog can be demonstrated as applicable to these Pennsylvanian limestones, then gamma-ray logs
may provide a tool to map ancient water tables and interpret paleogeography.The Vilas and Rock Lake shales
commonly show paleosols and clastic zones indicative of deltaic deposits in outcrops that occur at a short distance
from this well location.
A major advantage of the gamma-ray log over other logs is that it is possible to make equivalent measurements on
an outcrop or cored section, using a geiger counter or scintillation detector. This commonality allows direct
comparison between subsurface logs and surface rock to link radioactivity patterns with visual properties and so
clarify geological interpretation.
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Wilke (2000) found a systematic uranium anomaly within the Pennsylvanian Bethany Falls Limestone in a quarry
in central Kansas. The anomaly was observed to be horizontal and cut across the cross-bedded oolitic limestones of
the Bethany Falls. The Bethany Falls is a regressive limestone which has mangal rootlets at the top which appear to
terminate at an ancient contact between vadose and phreatic zones. The uranium content shows a significant
increase immediately below this contact, suggesting emplacement by a paleogroundwater regime.
The problem is shown by the example of gamma-ray logging of the Towanda and Fort Riley limestones in a
Hugoton gas well. If a conventional gamma-ray tool was run, then the result would match the SGR curve and the
section would appear to have many shale beds. With the removal of the uranium component, the CGR curve shows
that the shale content is much more subdued within the two limestones.
Luczaj and Goldstein (2000) concluded from fluid-inclusion studies and U-Pb chronology that the uranium was
emplaced as one of several diagenetic events of dolomitization in the Late Permian in third-order cements. This
contrasts with syndepositional mechanisms such as evaporitic pumping or groundwater phenomena.
The potassium and thorium content of the CGR curve reflects clay content, which fluctuates within both the
Towanda and Fort Riley limestones. This section was cored and the texture of the carbonates described in terms of
the Dunham classification, ranging from packstone to mudstone. The textures described from core are
superimposed on the CGR curve and there is an excellent correspondence between the two profiles. Because the
Dunham texture scale is based on relative mud-to-grain proportion (see below), the correspondence with the clay
content mapped by the CGR curve is not surprising.
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The thorium, uranium, and potassium curves in Tracks 2 and 3 record the quantities of these elements, which can be
used in a more systematic analysis.
The application of the Th/K and Th/U ratios to geological interpretation is described with respect to a hydrologic
observation well KGS #1 Braun located near Hays, Kansas that drilled through a Cretaceous and Permian
succession.
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In most wells in the area it is easy to tell when the drill-bit penetrates the Permian Cedar Hill Sandstone, because
the sandstone is stained with hematite, which causes the mud pit to turn red. In this instance, there was no change in
mud color, but the well had clearly penetrated the Cedar Hills because of the drill-cutting returns of frosted grains
which were diagnostic of their eolian origin, and differentiated them from the deltaic sandstones of the overlying
Lower Cretaceous section. Another distinctive property of the Cedar Hills Sandstone is that it contains moderate
quantities of potassium felspar. The potassium curve of the spectral gamma-ray log should therefore be useful in
picking the Cretaceous-Permian unconformity. A casual inspection of the potassium curve might suggest that the
unconformity is located at about 790 feet depth. Wrong! It is actually found at 900 feet depth.
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The correct pick is made when considering the potassium in conjunction with the thorium as expressed by the
Th/K ratio discussed on the next page.
The lines that radiate from the origin of the plot have gradients matched with values of the Th/K ratio. The ratio
values are calculated using Thorium in ppm and potassium in percent (NOT decimal).
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Illite has higher potassium than mixed-layer clays or smectite, while kaolinite has little or none.
Generalized fields of expectations of mineral responses on a thorium-potassium crossplot are shown in the
crossplot. The crossplot should be used cautiously and intelligently, because clay minerals show wide variability in
composition and most shales contain mixtures of different clay mineral species.
This thorium-potassium crossplot shows the relationships between potassium and thorium for the entire logged
section in the Braun well.
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The cluster of points from the Cedar Hills Sandstone is clearly separated from Cretaceous zones and is readily
interpreted as a quartz-feldspar-illite system. This aspect conforms very well with the petrography of this unit. as
ranging from quartz arenite to lithic subarkose.
The Lower Cretaceous zones plot as a broader and more diffuse cloud, as would be expected for a mixed sequence
of sandstones, siltstones and shales. However, the cloud is coincides with the kaolinite-smectite-illite range of Th/K
ratios which, once again, shows good agreement with known petrography. The shales of the Lower Cretaceous are
mostly a mixture of illite and kaolinite with subsidiary amounts of chlorite, smectite, and mixed-layer clays.
Smectite becomes a major component in the overlying Graneros Shale.
Crossplot data from the Graneros Shale overlaps the Lower Cretaceous points. However, there is a distinctive bias
towards higher Th/K ratios, which probably reflects the increased importance of smectite as a significant
component. The source of much of the smectite can probably be attributed to bentonite (altered volcanic ash)
horizons observed in this borehole. Other Upper Cretaceous units show a common trend of a slightly more
potassium-rich ratio suggestive of a normal composition, dominated by illite.
In a pioneer paper, Adams and Weaver (1958), concluded that the Th/U ratio was often strongly linked with
depositional environment, based on their laboratory analysis of many samples of differing lithologies. They
suggested that when the ratio was computed to be less than two (i.e. uranium-rich), the depositional environment
had promoted uranium fixation under probable reducing conditions, and was most commonly marine. By contrast,
ratio values of greater than seven (uranium-poor), implied uranium mobilization through weathering and/or
leaching, and therefore indicated an oxidizing, possibly terrestrial environment.
The Th/K and Th/U ratios were also plotted as logs together with the gamma ray trace and a graphic lithology log
from the description of drill cuttings. The simultaneous consideration of these data throughout the sequence reveals
striking and readily interpretable patterns.
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An abrupt shift occurs at the Cretaceous-Permian contact and highlights clearly the major basal Cretaceous
unconformity. The illite-feldspar signature of the Cedar Hills Sandstone changes to a Lower Cretaceous trace which
oscillates between illitic and kaolinitic clay minerals facies, possibly linked with marine and deltaic fresh-water
environments, respectively.
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Kaolinitic clays are commonly found in the Dakota Formation and are of sufficient quality to be used in ceramics
(Plummer and Romary, 1947). Observations in Dakota Formation outcrop and core show that kaolinite-rich
horizons are often associated with seatearth developments.
The high amplitude variations in the Graneros Shale and Greenhorn Limestone may reflect the occurrence of
bentonites (observed in the drill cuttings) interbedded with normal illitic marine shales. These bentonites represent
altered ash deposits generated from explosive events from volcanoes in the Idaho-Montana and New Mexico-
Arizona regions.
The Th/U ratio log was indexed with the diagnostic values of 2 and 7 suggested by Adams and Weaver (1958) to
aid depositional environment interpretation through its use as an oxidation potential indicator.
The ratio indicates an oxidizing environment for much of the Cedar Hills Sandstone, which would be expected from
its postulated origin as eolian sands. Stacked repetitions of high and medium Th/U ratios characterize the Dakota
Formation. These probably reflect high lateral variability in clastic facies and interplay between mostly brackish
and fresh-water regimes of distributary channels, bays and marginal marine deposits, which would be expected to
typify a delta complex.
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The relatively smooth, long-term cyclic pattern of the Th/U ratio in the marine sequence of the Upper Cretaceous is
an excellent indicator of a large-scale transgression/regression couplet on an open marine shelf. The broad sine-
wave feature conforms precisely with the outcrop interpretation of the Greenhorn Cycle as a classic example of a
symmetric, third-order tectonoeustatic cycle (Glenister and Kauffman, 1985).
The transgressive phase of the cycle started in the uppermost part of the Dakota formation, continued through the
Graneros Shale, and reached maximum development in the Greenhorn Limestone. The regressive hemicyclothem
was initiated at the top of the Greenhorn and continued through the Fairport Chalk and Blue Hills Shale, to
terminate in the Codell Sandstone. There is an abrupt break in the Th/U ratio log at the boundary between the
Codell Sandstone and the overlying Fort Hays Limestone. This contact is thought to represent a long period of non-
deposition followed by a major transgression (Hattin and Siemers, 1978). The ratio log shows this transgression
clearly, but also indicates a distinctive regressive event at the top of the Fort Hays. This anomaly coincides closely
with a similar peak on a Th/U log from a Colorado well observed by Zelt (1985), who attributed it to a regional
warm water pulse or low salinity event suggested from oxygen isotope studies in the carbonate phase.
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The Smoky Hills Chalk at the top of the borehole succession is marked by a log ratio feature that indicates renewed
transgression.
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A cartoon representation of the K, U, and Th flux in different weathering systems of an idealized basin-wide scale
(Ruffel et al., 2003).
Fluxes of K, U, and Th may differ in both finer and grosser scale (e.g. the movement of Th in soil profiles or the
global cycling of K through sea-water and authigenesis).
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