Class - 12th CBSE + JEE

Subject - Chemistry

Electrochemistry
24 May 2023

1) 2 2) 1 3) 2 4) 4 5) 4 6) 2 7) 2 8) 2 9) 1 10) 1 11) 3 12) 1 13) 3 14) 3

15) 2 16) 2 17) 1 18) 2 19) 1 20) 2 21) 2 22) 3 23) 1 24) 3 25) 3

Solution :- 6)
H
ERP = −0.059 × P
1)
+ −
AgN O3 → Ag + NO ERP = −0.059 × 4
3

E
= −0.236
M = × i × T
2 × F
108 × 0.5 × 10 × 60
M =
1 × 96500 (or)
54 × 600 324 0.0591 pH 2
M = = E = E
o
− log
96500 96500 n [H
+
]

M = 0.33 gm 0.0591 1

ON
= − log = −0.236 V
The mass of Ag deposited on cathode is 0.33 gms 1 −4
10

2) 7)
2+
0 0 0.0591 [Zn ]
ΔG = −nF E o
E = E − log
cell 2+
2 [Cu ]
We have
+2 −
slope = E o

cell
= 1.1 V
Cu + 2e → 10
o
Ecathode − Eanode = E
+2 − cell
Cu + e → 10
IZ
0.0591 0.1
0 Ecell = 1.1 − log = 1.070 V
ΔG = −2 × F × 0.337V 2 0.01
1

0
ΔG = −1 × F × 0.153V
2

ΔG
0
= ΔG
0
− ΔG
0 8)
1 2 0.059
o 2+
E = E + log[Cu ]
R
= F (2 × 0.337 − 0.153V ) n

ECu+ /Cu = [(2 × 0.337 − 0.153) V ] log values of 10 −1

, 10
−2
, 10
−3
and 10 −4
are all
ECu+ /Cu = 2 × 0.337 − 0.153V negative. So B > C > D > A
= 0.521V
HO

9)
3
K × 10
3) ∧M =
M
1
K = 3
∧M 10
R
=
K.1000 K M
∧m = 3
M ∧M 10
=
1 1000 K −2
10
= .
R M 5
= 10
1000
Molar conductivity=
MX

10)
+ −
2H2 O → O2 + 4H + 4e
4)
Conductivity always increase with increase in conc. 1) To separate oxygen, from 2 moles of water. The
of ionc required 4 × 96500 coulombs
Molar conductivity increase as dilution increase 2)While one mole of water required coulombs to
separate oxygen from water is
5) H2 O →
1
O2 + 2H
+
+ 2e
−

emf = E o

Cu
+2
/Cu
− E
Mg
o
+2
/M g
2

−
o 2e = 2F = 2 × 96500
2.7 = 0.34 V − E
M g +2 /M g

o = 193000
−2.36 = E +2
Mg /M g
5
= 1.93 × 10

11)
H
E = −0.06 × P

= −0.06 × 4

= −0.24 V
12) ++
19)
Ecell = E
o
−
0.059
log
(Zn ) Cell reaction is :
cell ++
2 (Cu ) +2 +2
Sn (s) + P b (aq) → Sn (aq) + P b (s)
0.059 0.1
= 1.10 −
2
log
0.1
= 1.10 V
Apply Nernst equation :
+2
0.06 [Sn ]
0
Ecell = E = log → (1)
cell
13)
+2
2 [P b ]

Sugar solution does not form ion; hence does not E

0
= −0.13 + 0.14 = 0.01 V
cell

conduct electricity in solution At equilibrium : E cell = 0

Substituting in (1)
14) 0.06 [Sn
+2
]
It is a electrochemical change 0 = 0.01 − log
+2
2 [P b ]
+2
1 [Sn ]
15) ⇒ = log
+2
+3 − 3 [P b ]
Fe + 3e → Fe
+2
[Sn ]
For 56gm deposited 3F current is required. but, 0.6F +2
= 2.15
[P b ]
required
how much grams of Fe deposit at electrodes 20)
0.059
0
56 → 3F Ecell = E − log Q
cell n
? ← 0.6F
At equilibrium
0.6 × 56
= 0.2 × 56 0.059
0 16
3 E = log 10
Cell
2

N
= 11.2 gm of Fe
= 0.059×8
11.2 gm of Fe required to deposit at electrodes 0.6F of = 0.472 V
electricity

16) ∞

∧ N H4 OH = 149.74 + 248.21 − 126.4

2 −1
ZO 21)
A

B
+

+
+ e

+ e
−

−
→ A

→ B
1.2V

0.6

= 271.44.S. cm . eq + −
C + e → C 0.85 V

+ −
D + e → D − 0.76 V

17)
Higher the value of E (reduction), higher the o

Option (1) is incorrect.

tendency to undergo reduction. A is reduced mos
RI
+

According to Kohlrausch's law correct expression is

0 0 0 0 easily and is deposited first at the cathode to A. D is +

(∧m ) − (∧m ) = (∧m ) − (∧m )

N aBr N aI KBr N aBr
reduced least easily and is deposited last. C and B + +

The other statements are correct.

are reduced C first followed by B . Hence the order
+ +

of ease of deposition is A + + +
and D .
+
HO

18) ,C ,B
− −
(A) P bSO4 (s) + 2OH → P bO2 + H2 SO4 + 2e
0.05F
0.05/2mole

+
22)
− ∧c 11.5
(C) P bSO4 (s) + 2e + 2H → P b (s) + H2 SO4
α = ,α = = 0.0424
0.05F
0.05/2mole ∧0 73.4 + 197.6

nT (P bSO4 ) = 0.05 mole

mP bSO = 0.05 × 303 = 15.2 gm 23)

4 + −
AgN O3 → Ag + NO
3

+ −
Ag + 1e → Ag

1e
−
= 1 Faraday

24)
∧BaSO = ∧BaCl + ∧H − ∧2H Cl
4 2 2 SO4

∧BaSO = x1 + x2 − 2x3
4

∧m x1 + x2 − 2x3
∧eq = =
2 2

25)
−1 2 −1
at 0.1 M → ∧m = 9.54 ohm cm mol

o −1 2 −1
∧ = 238 ohm cm mol
M

∧m 9.54
∝= o
= = 0.04008
∧ 238
M

t ∝ = 4.008 %