FERT18

FITOFARMACIE
E F+ F O C N T+ T XN X
9 pictogrammes de danger (SGH-CLP) : (SGH1 à SGH 9)
L'étiquetage et l'emballage des substances (Directive 67/548/EEC) et des melanges
(Directive1999/45/EEC)
GHS Pictograms and Hazard Categories

Authorisation of Plant Protection Products
Regulation (EC) No 1107/2009 is the legislation concerning the placing of plant protection products (PPPs) on the market
in the European Union.
PPPs (also referred to as 'pesticides') are products in the form in which they are supplied to the user, consisting of, or
containing active substances, safeners or synergists, and intended for one of the following uses:
(a) protecting plants or plant products against all harmful organisms or preventing the action of such organisms, unless the
main purpose of these products is considered to be for reasons of hygiene rather than for the protection of plants or plant
products (e.g. fungicides, insecticides);
(b) influencing the life processes of plants, such as substances influencing their growth, other than as a nutrient (e.g. plant
growth regulators, rooting hormones);
(c) preserving plant products, in so far as such substances or products are not subject to special Community provisions on
preservatives (e.g. extending the life of cut flowers);
(d) destroying undesired plants or parts of plants, except algae unless the products are applied on soil or water to protect
plants (e.g. herbicides/weedkillers to kill actively growing weeds);
(e) checking or preventing undesired growth of plants, except algae unless the products are applied on soil or water to
protect plants (e.g. herbicides/weedkillers preventing the growth of weeds).
PPPs contain at least one approved active substance (See the 'Approval of active substances' page for the approval
procedure); these may include micro-organisms, pheromones and botanical extracts.
Before any PPP can be placed on the market or used, it must be authorised in the Member State(s) concerned. Regulation
(EC) No 1107/2009 lays down the rules and procedures for authorisation of PPPs.
Information on the application procedure.
The controls of the use and placing on the market of PPPs are performed by Member States. For information about the
trade of illegal and counterfeit pesticides you can consult the study on this topic. A
abamectin
abamectin-aminomethyl
abscisic acid
ACC
acephate
acequinocyl
acetamiprid
acethion
acetochlor
acetofenate
acetophos
acetoprole
acibenzolar
acifluorfen
aclonifen
ACN
acrep
acrinathrin
acrolein
acrylonitrile
acynonapyr
acypetacs
afidopyropen
afoxolaner
alachlor
alanap
alanycarb
albendazole
aldicarb
aldicarb sulfone
aldimorph
aldoxycarb
aldrin
allethrin
d-trans-allethrin
allicin
allidochlor
allosamidin
alloxydim
allyl alcohol
allyxycarb
alorac
alpha-bromadiolone
alpha-cypermethrin
alpha-endosulfan
alphamethrin
altretamine
aluminium phosphide
aluminum phosphide
ametoctradin
ametridione
ametryn
ametryne
amibuzin
amicarbazone
amicarthiazol
amidithion
amidochlor
amidoflumet
amidosulfuron
aminocarb
aminocyclopyrachlor
aminopyralid
4-aminopyridine
aminopyrifen
aminotriazole
amiprofos-methyl
amiprophos
amiprophos-methyl
amisulbrom
amiton
amitraz
amitrole
ammonium sulfamate
amobam
amorphous silica gel
amorphous silicon dioxide

ampropylfos
AMS
anabasine
ancymidol
anilazine
anilofos
anisuron
anthraquinone
antu
apholate
aramite
arprocarb
arsenous oxide
asomate
aspirin
asulam
athidathion
atraton
atrazine
aureofungin
avermectin B1
AVG
aviglycine
azaconazole
azadirachtin
azafenidin
azamethiphos
azidithion
azimsulfuron
azinphos-ethyl
azinphosethyl
azinphos-methyl
azinphosmethyl
aziprotryn
aziprotryne
azithiram
azobenzene
azocyclotin
azothoate
azoxystrobin
bachmedesh
barban
barbanate
barium hexafluorosilicate
barium polysulfide
barium silicofluoride
barthrin
basic copper carbonate
basic copper chloride
basic copper sulfate
BCPC
beflubutamid
benalaxyl
benalaxyl-M
benazolin
bencarbazone
benclothiaz
bendaqingbingzhi
bendiocarb
bendioxide
benefin
benfluralin
benfuracarb
benfuresate
benmihuangcaoan
benodanil
benomyl
benoxacor
benoxafos
benquinox
bensulfuron
bensulide
bensultap
bentaluron
bentazon
bentazone
benthiavalicarb
benthiazole
benthiocarb
bentranil
benzadox
benzalkonium chloride
benzamacril
benzamizole
benzamorf
benzene hexachloride
benzfendizone
benzimine
benzipram
benzobicyclon
benzoepin
benzofenap
benzofluor
benzohydroxamic acid
benzomate
benzophosphate
benzothiadiazole
benzovindiflupyr
benzoximate
benzoylprop
benzpyrimoxan
benzthiazuron
benzuocaotong
benzyladenine
benzyl benzoate
berberine
beta-cyfluthrin
beta-cypermethrin
bethoxazin
BHC
gamma-BHC
bialaphos
bicyclopyrone
bifenazate
bifenox
bifenthrin
kappa-bifenthrin
bifujunzhi
bilanafos
binapacryl
bingqingxiao
bioallethrin
S-bioallethrin
bioethanomethrin
biopermethrin
bioresmethrin
biphenyl
bisazir
bismerthiazol
bismerthiazol-copper
bisphenylmercury methylenedi(x-naphthalene-y-sulphonate)
bispyribac
bistrifluron
bisultap
bitertanol
bithionol
bixafen
blasticidin-S
borax
Bordeaux mixture
boric acid
boscalid
BPCMS
BPPS
brassinolide
brassinolide-ethyl
brevicomin
brodifacoum
brofenprox
brofenvalerate
broflanilide
brofluthrinate
bromacil
bromadiolone
alpha-bromadiolone
bromchlophos
bromethalin
bromethrin
bromfenvinfos
bromoacetamide
bromobonil
bromobutide
bromociclen
bromocyclen
bromo-DDT
bromofenoxim
bromofos
bromomethane
bromophos
bromophos-ethyl
bromopropylate
bromothalonil
bromoxynil
brompyrazon
bromuconazole
bronopol
bropropdifacoum
BRP
BTH
bucarpolate
bufencarb
buminafos
bupirimate
buprofezin
Burgundy mixture
busulfan
busulphan
butacarb
butachlor
butafenacil
butam
butamifos
butane-fipronil
butathiofos
butenachlor
butene-fipronil
butethrin
buthidazole
buthiobate
buthiuron
butifos
butocarboxim
butonate
butopyronoxyl
butoxycarboxim
butralin
butrizol
butroxydim
buturon
butylamine
butylate
butylchlorophos
butylene-fipronil
cacodylic acid
cadusafos
cafenstrole
calciferol
calcium arsenate
calcium chlorate
calcium cyanamide
calcium cyanide
calcium polysulfide
calvinphos
cambendichlor
camphechlor
camphor
d-camphor
captafol
captan
carbam
carbamorph
carbanolate
carbaril
carbaryl
carbasulam
carbathion
carbendazim
carbendazol
carbetamide
carbofenotion
carbofuran
carbon disulfide
carbon tetrachloride
carbonyl sulfide
carbophenothion
carbophos
carbosulfan
carboxazole
carboxide
carboxin
carfentrazone
carpropamid
cartap
carvacrol
carvone
CAVP
CDAA
CDEA
CDEC
cellocidin
CEPC
ceralure
cerenox
cevadilla
Cheshunt mixture
chinalphos
chinalphos-méthyl
chinomethionat
chinomethionate
chiralaxyl
chitosan
chlobenthiazone
chlomethoxyfen
chlor-IPC
chloralose
chloramben
chloramine phosphorus
chloramizol
chloramphenicol
chloraniformethan
chloranil
chloranocryl
chlorantraniliprole
chlorazifop
chlorazine
chlorbenside
chlorbenzuron
chlorbicyclen
chlorbromuron
chlorbufam
chlordane
chlordecone
chlordimeform
chlorempenthrin
chloretazate
chlorethephon
chlorethoxyfos
chloreturon
chlorfenac
chlorfenapyr
chlorfenazole
chlorfenethol
chlorfenidim
chlorfenprop
chlorfenson
chlorfensulphide
chlorfenvinphos
chlorfenvinphos-methyl
chlorfluazuron
chlorflurazole
chlorflurecol
chlorfluren
chlorflurenol
chloridazon
chlorimuron
chlorinate
chlormephos
chlormequat
chlormesulone
chlormethoxynil
chlornidine
chlornitrofen
chloroacetic acid
chlorobenzilate
chlorodinitronaphthalenes
chlorofénizon
chloroform
α-chlorohydrin
chloromebuform
chloromethiuron
chloroneb
chlorophacinone
chlorophos
chlorophthalim
chloropicrin
chloropon
chloroprallethrin
chloropropylate
chlorothalonil
chlorotoluron
chloroxifenidim
chloroxuron
chloroxynil
chlorphonium
chlorphoxim
chlorphthalim
chlorprazophos
chlorprocarb
chlorpropham
chlorpyrifos
chlorpyrifos-methyl
chlorquinox
chlorsulfuron
chlorthal
chlorthiamid
chlorthiophos
chlortoluron
chlozolinate
chltosan
cholecalciferol
choline chloride
chromafenozide
cicloheximide
cimectacarb
cimetacarb
cinerin I
cinerin II
cinerins
cinidon-ethyl
cinmethylin
cinosulfuron
cintofen
ciobutide
cisanilide
cismethrin
clacyfos
clefoxydim
clenpirin
clenpyrin
clethodim
climbazole
cliodinate
clodinafop
cloethocarb
clofencet
clofenotane
clofentezine
clofenvinfos
clofibric acid
clofop
clomazone
clomeprop
clonitralid
cloprop
cloproxydim
clopyralid
cloquintocet
cloransulam
closantel
clothianidin
clotrimazole
cloxyfonac
cloxylacon
clozylacon
CMA
CMMP
CMP
CMU
codlelure
colecalciferol
colophonate
copper acetate
copper acetoarsenite
copper arsenate
copper carbonate, basic
copper hydroxide
copper naphthenate
copper oleate
copper oxychloride
copper 8-quinolinolate
copper silicate
copper sulfate
copper sulfate, basic
copper zinc chromate
coumachlor
coumafène
coumafos
coumafuryl
coumaphos
coumatetralyl
coumethoxystrobin
coumithoate
coumoxystrobin
4-CPA
4-CPB
CPMC
CPMF
4-CPP
CPPC
credazine
cresol
cresylic acid
crimidine
crotamiton
crotoxyfos
crotoxyphos
crufomate
cryolite
cue-lure
cufraneb
cumyleron
cumyluron
cuprobam
cuprous oxide
curcumenol
CVMP
cyanamide
cyanatryn
cyanazine
cyanofenphos
cyanogen
cyanophos
cyanthoate
cyantraniliprole
cyanuric acid
cyazofamid
cybutryne
cyclafuramid
cyclanilide
cyclaniliprole
cyclethrin
cycloate
cycloheximide
cycloprate
cycloprothrin
cyclopyranil
cyclopyrimorate
cyclosulfamuron
cycloxydim
cycluron
cyenopyrafen
cyflufenamid
cyflumetofen
cyfluthrin
beta-cyfluthrin
cyhalodiamide
cyhalofop
cyhalothrin
gamma-cyhalothrin
lambda-cyhalothrin
cyhexatin
cymiazole
cymoxanil
cyometrinil
cypendazole
cypermethrin
alpha-cypermethrin
beta-cypermethrin
theta-cypermethrin
zeta-cypermethrin
cyperquat
cyphenothrin
cyprazine
cyprazole
cyproconazole
cyprodinil
cyprofuram
cypromid
cyprosulfamide
cyromazine
cythioate
cytrex
1,3-D
2,4-D
3,4-DA
daimuron
dalapon
daminozide
dayoutong
dazomet
2,4-DB
3,4-DB
DBCP
d-camphor
DCB
DCD
DCIP
DCPA (USA)
DCPA (Japan)
DCPTA
DCU
DDD
DDPP
DDT
pp′-DDT
DDVP
2,4-DEB
debacarb
decafentin
decamethrin
decarbofuran
deet
dehydroacetic acid
deiquat
delachlor
delnav
deltamethrin
demephion
demephion-O
demephion-S
demeton
demeton-methyl
demeton-O
demeton-O-methyl
demeton-S
demeton-S-methyl
demeton-S-methylsulphon
demeton-S-methyl sulphone
DEP
2,4-DEP
depalléthrine
derris
2,4-DES
desmedipham
desmetryn
desmetryne
d-fanshiluquebingjuzhi
diafenthiuron
dialifor
dialifos
di-allate
diallate
diamidafos
dianat
diatomaceous earth
diatomite
diazinon
dibrom
1,2-dibromoethane
dibutyl phthalate
dibutyl succinate
dicamba
dicapthon
dichlobenil
dichlobentiazox
dichlofenthion
dichlofluanid
dichlone
dichloralurea
dichlorbenzuron
dichlorfenidim
dichlorflurecol
dichlorflurenol
dichlormate
dichlormid
o-dichlorobenzene
ortho-dichlorobenzene
p-dichlorobenzene
para-dichlorobenzene
1,2-dichloroethane
dichloromethane
dichlorophen
3,6-dichloropicolinic acid
1,2-dichloropropane
1,3-dichloropropene
dichlorprop
dichlorprop-P
dichlorvos
dichlozolin
dichlozoline
diclobutrazol
diclocymet
diclofop
diclomezine
dicloran
dicloromezotiaz
diclosulam
dicofol
dicophane
dicoumarol
dicresyl
dicrotophos
dicryl
dicumarol
dicyclanil
dicyclonon
dieldrin
dienochlor
diethamquat
diethatyl
diethion
diéthion
diethofencarb
dietholate
diéthon
diethyl pyrocarbonate
diethyltoluamide
difenacoum
difenoconazole
difenopenten
difenoxuron
difenzoquat
difethialone
diflovidazin
diflubenzuron
diflufenican
diflufenicanil
diflufenzopyr
diflumetorim
dikegulac
dilor
dimatif
dimefluthrin
dimefox
dimefuron
dimehypo
dimepiperate
dimetachlone
dimetan
dimethacarb
dimethachlone
dimethachlor
dimethametryn
dimethenamid
dimethenamid-P
dimethipin
dimethirimol
dimethoate
dimethomorph
dimethrin
dimethyl carbate
dimethyl disulfide
dimethyl phthalate
dimethylvinphos
dimetilan
dimexano
dimidazon
dimoxystrobin
dimpylate
dimuron
dinex
dingjunezuo
diniconazole
diniconazole-M
R-diniconazole
dinitramine
dinitrophenols
dinobuton
dinocap
dinocap-4
dinocap-6
dinocton
dinofenate
dinopenton
dinoprop
dinosam
dinoseb
dinosulfon
dinotefuran
dinoterb
dinoterbon
diofenolan
dioxabenzofos
dioxacarb
dioxathion
dioxation
diphacin
diphacinone
diphenadione
diphenamid
diphenamide
diphenylamine
diphenyl sulfone
diphenylsulphide
diprogulic acid
dipropalin
dipropetryn
dipterex
dipymetitrone
dipyrithione
diquat
disosultap
disparlure
disugran
disul
disulfiram
disulfoton
ditalimfos
dithianon
dithicrofos
dithioether
dithiométon
dithiopyr
diuron
dixanthogen
d-limonene
DMDS
DMPA
DNOC
dodemorph
dodicin
dodine
dofenapyn
doguadine
dominicalure
doramectin
2,4-DP
3,4-DP
DPC
drazoxolon
DSMA
d-trans-allethrin
d-trans-resmethrin
dufulin
dymron
EBEP
EBP
ebufos
α-ecdysone
β-ecdysone
ecdysterone
echlomezol
EDB
EDC
EDDP
edifenphos
eglinazine
emamectin
EMPC
empenthrin
enadenine
endosulfan
alpha-endosulfan
endothal
endothall
endothion
endrin
enestroburin
enilconazole
enoxastrobin
ephirsulfonate
EPN
epocholeone
epofenonane
epoxiconazole
eprinomectin
epronaz
epsilon-metofluthrin
epsilon-momfluorothrin
EPTC
erbon
ergocalciferol
erlujixiancaoan
esdépalléthrine
esfenvalerate
ESP
esprocarb
etacelasil
etaconazole
etaphos
etem
ethaboxam
ethachlor
ethalfluralin
ethametsulfuron
ethaprochlor
ethephon
ethidimuron
ethiofencarb
ethiolate
ethion
ethiozin
ethiprole
ethirimol
ethoate-methyl
ethobenzanid
ethofumesate
ethohexadiol
ethoprop
ethoprophos
ethoxyfen
(3-ethoxypropyl)mercury bromide
ethoxyquin
ethoxysulfuron
ethychlozate
ethylan
ethyl-DDD
ethylene
ethylene dibromide
ethylene dichloride
ethylene oxide
ethyl formate
ethylicin
ethylmercury acetate
ethylmercury bromide
ethylmercury chloride
ethylmercury 2,3-dihydroxypropyl mercaptide
ethylmercury phosphate
N-(ethylmercury)-p-toluenesulfonanilide
N-(ethylmercury)-p-toluenesulphonanilide
ethyl pyrophosphate
etinofen
ETM
etnipromid
etobenzanid
etofenprox
etoxazole
etridiazole
etrimfos
étrimphos
eugenol
EXD
famoxadone
famphur
d-fanshiluquebingjuzhi
fenac
fenamidone
fenaminosulf
fenaminstrobin
fenamiphos
fenapanil
fenarimol
fenasulam
fenazaflor
fenazaquin
fenbuconazole
fenbutatin oxide
fenchlorazole
fenchlorphos
fenclofos
fenclorim
fenethacarb
fenfluthrin
fenfuram
fenhexamid
fenidim
fenitropan
fenitrothion
fénizon
fenjuntong
fenobucarb
fenolovo
fenoprop
fenothiocarb
fenoxacrim
fenoxanil
fenoxaprop
fenoxaprop-P
fenoxasulfone
fenoxycarb
fenpiclonil
fenpicoxamid
fenpirithrin
fenpropathrin
fenpropidin
fenpropimorph
fenpyrazamine
fenpyroximate
fenquinotrione
fenridazon
fenson
fensulfothion
fenteracol
fenthiaprop
fenthion
fenthion-ethyl
fentiaprop
fentin
fentrazamide
fentrifanil
fenuron
fenuron-TCA
fenvalerate
ferbam
ferimzone
ferric phosphate
ferrous sulfate
fipronil
flamprop
flamprop-M
flazasulfuron
flocoumafen
flometoquin
flonicamid
florasulam
florpyrauxifen
florylpicoxamid
fluacrypyrim
fluazaindolizine
fluazifop
fluazifop-P
fluazinam
fluazolate
fluazuron
flubendiamide
flubenzimine
flubrocythrinate
flucarbazone
flucetosulfuron
fluchloralin
flucofuron
flucycloxuron
flucythrinate
fludioxonil
fluénéthyl
fluenetil
fluensulfone
flufenacet
flufenerim
flufenican
flufenoxuron
flufenoxystrobin
flufenprox
flufenpyr
flufenzine
flufiprole
fluhexafon
fluindapyr
flumethrin
flumetover
flumetralin
flumetsulam
flumezin
flumiclorac
flumioxazin
flumipropyn
flumorph
fluometuron
fluopicolide
fluopimomide
fluopyram
fluorbenside
fluoridamid
fluoroacetamide
fluoroacetic acid
fluorochloridone
fluorodifen
fluoroglycofen
fluoroimide
fluoromide
fluoromidine
fluoronitrofen
fluoroxypyr
fluothiuron
fluotrimazole
fluoxastrobin
flupoxam
flupropacil
flupropadine
flupropanate
flupyradifurone
flupyrimin
flupyrsulfuron
fluquinconazole
fluralaner
flurazole
flurecol
flurenol
fluridone
flurochloridone
fluromidine
fluroxypyr
flurprimidol
flursulamid
flurtamone
flusilazole
flusulfamide
flutenzine
fluthiacet
fluthiamide
flutianil
flutolanil
flutriafol
fluvalinate
tau-fluvalinate
fluxametamide
fluxapyroxad
fluxofenim
folpel
folpet
fomesafen
fonofos
foramsulfuron
forchlorfenuron
formaldehyde
formetanate
formothion
formparanate
fosamine
fosetyl
fosmethilan
fospirate
fosthiazate
fosthietan
frontalin
fthalide
fuberidazole
fucaojing
fucaomi
fujunmanzhi
fulumi
fumarin
funaihecaoling
fuphenthiourea
furalane
furalaxyl
furamethrin
furametpyr
furan tebufenozide
furathiocarb
furcarbanil
furconazole
furconazole-cis
furethrin
furfural
furilazole
furmecyclox
furophanate
furyloxyfen
gamma-BHC
gamma-cyhalothrin
gamma-HCH
genit
gibberellic acid
gibberellin A3
gibberellins
gliftor
glitor
glucochloralose
glufosinate
glufosinate-P
glyodin
glyoxime
glyphosate
glyphosine
gossyplure
grandlure
griseofulvin
guanoctine
guazatine
halacrinate
halauxifen
halfenprox
halofenozide
halosafen
halosulfuron
haloxydine
haloxyfop
haloxyfop-P
haloxyfop-R
HCA
HCB
HCH
gamma-HCH
hemel
hempa
HEOD
heptachlor
heptafluthrin
heptamaloxyloglucan
heptenophos
heptopargil
herbimycin
herbimycin A
heterophos
hexachlor
hexachloran
hexachloroacetone
hexachlorobenzene
hexachlorobutadiene
hexachlorophene
hexaconazole
hexaflumuron
hexafluoramin
hexaflurate
hexalure
hexamide
hexazinone
hexylthiofos
hexythiazox
HHDN
holosulf
homobrassinolide
huancaiwo
huanchongjing
huangcaoling
huanjunzuo
hydramethylnon
hydrargaphen
hydrated lime
hydrogen cyanamide
hydrogen cyanide
hydroprene
S-hydroprene
hydroxyisoxazole
4-hydroxyphenethyl alcohol
8-hydroxyquinoline sulfate
hymexazol
hyquincarb
IAA
IBA
IBP
icaridin
imazalil
imazamethabenz
imazamox
imazapic
imazapyr
imazaquin
imazethapyr
imazosulfuron
imibenconazole
imicyafos
imidacloprid
imidaclothiz
iminoctadine
imiprothrin
inabenfide
indanofan
indaziflam
indoxacarb
inezin
infusorial earth
inpyrfluxam
iodobonil
iodocarb
iodofenphos
iodomethane
iodosulfuron
iofensulfuron
ioxynil
ipazine
IPBC
IPC
ipconazole
ipfencarbazone
ipfentrifluconazole
ipflufenoquin
iprobenfos
iprodione
iprovalicarb
iprymidam
ipsdienol
ipsenol
IPSP
IPX
isamidofos
isazofos
isobenzan
isocarbamid
isocarbamide
isocarbophos
isocil
isodrin
isofenphos
isofenphos-methyl
isofetamid
isoflucypram
isolan
isomethiozin
isonoruron
isopamphos
isopolinate
isoprocarb
isoprocil
isopropalin
isopropazol
isoprothiolane
isoproturon
isopyrazam
isopyrimol
isothioate
isotianil
isouron
isovaledione
isoxaben
isoxachlortole
isoxadifen
isoxaflutole
isoxapyrifop
isoxathion
isuron
ivermectin
ixoxaben
izopamfos
izopamphos
japonilure
japothrins
jasmolin I
jasmolin II
jasmonic acid
jiahuangchongzong
jiajizengxiaolin
jiaxiangjunzhi
jiecaowan
jiecaoxi
Jinganmycin A
jodfenphos
juvenile hormone I
juvenile hormone II
juvenile hormone III
kadethrin
kappa-bifenthrin
kappa-tefluthrin
karbutilate
karetazan
kasugamycin
kejunlin
kelevan
ketospiradox
kieselguhr
kinetin
kinoprene
S-kinoprene
kiralaxyl
kresoxim-methyl
kuicaoxi
lactofen
lambda-cyhalothrin
lancotrione
latilure
lead arsenate
lenacil
lepimectin
leptophos
lianbenjingzhi
lime sulfur
d-limonene
lindane
lineatin
linuron
lirimfos
litlure
looplure
lotilaner
lufenuron
lüfuqingchongxianan
lüxiancaolin
lvdingjunzhi
lvfumijvzhi
lvxiancaolin
lythidathion
M-74
M-81
MAA
magnesium phosphide
malathion
maldison
maleic hydrazide
malonoben
maltodextrin
MAMA
mancopper
mancozeb
mandestrobin
mandipropamid
maneb
matrine
mazidox
MCC
MCP
1-MCP
MCPA
2,4-MCPA
MCPA-thioethyl
MCPB
2,4-MCPB
MCPP
mebenil
mecarbam
mecarbinzid
mecarphon
mecoprop
mecoprop-P
medimeform
medinoterb
medlure
mefenacet
mefenoxam
mefenpyr
mefentrifluconazole
mefluidide
megatomoic acid
melissyl alcohol
melitoxin
MEMC
menazon
MEP
mepanipyrim
meperfluthrin
mephenate
mephosfolan
mepiquat
mepronil
meptyldinocap
mercaptodimethur
mercaptophos
mercaptophos thiol
mercaptothion
mercuric chloride
mercuric oxide
mercurous chloride
merphos
merphos oxide
mesoprazine
mesosulfuron
mesotrione
mesulfen
mesulfenfos
mesulphen
metacresol
metaflumizone
metalaxyl
metalaxyl-M
R-metalaxyl
metaldehyde
metam
metamifop
metamitron
metaphos
metaxon
metazachlor
metazosulfuron
metazoxolon
metcamifen
metconazole
metepa
metflurazon
methabenzthiazuron
methacrifos
methalpropalin
metham
methamidophos
methasulfocarb
methazole
methfuroxam
methibenzuron
methidathion
methiobencarb
methiocarb
methiopyrisulfuron
methiotepa
methiozolin
methiuron
methocrotophos
métholcarb
methometon
methomyl
methoprene
S-methoprene
methoprotryn
methoprotryne
methoquin-butyl
methothrin
methoxychlor
2-methoxyethylmercury chloride
methoxyfenozide
methoxyphenone
methyl apholate
methyl bromide
methyl eugenol
methyl iodide
methyl-isofenphos
methyl isothiocyanate
methyl parathion
methylacetophos
methylchloroform
1-methylcyclopropene
methyldithiocarbamic acid
methyldymron
methylene chloride
methylmercaptophos
methylmercaptophos oxide
methylmercaptophos thiol
methylmercury benzoate
methylmercury dicyandiamide
methylmercury pentachlorophenoxide
methylneodecanamide
methylnitrophos
methyltriazothion
metiozolin
metiram
metiram-zinc
metobenzuron
metobromuron
metofluthrin
metolachlor
S-metolachlor
metolcarb
metometuron
metominostrobin
metosulam
metoxadiazone
metoxuron
metrafenone
metriam
metribuzin
metrifonate
metriphonate
metsulfovax
metsulfuron
metyltetraprole
mevinphos
mexacarbate
miechuwei
mieshuan
miewenjuzhi
milbemectin
milbemycin oxime
milneb
mimanan
mipafox
MIPC
mirex
MNAF
moguchun
molinate
molosultap
monalide
monalide
momfluorothrin
monisuron
monoamitraz
monochloroacetic acid
monocrotophos
monolinuron
monomehypo
monosulfiram
monosulfuron
monosultap
monuron
monuron-TCA
morfamquat
moroxydine
morphothion
morzid
moxidectin
MPMC
MSMA
MTMC
α-multistriatin
muscalure
myclobutanil
myclozolin
myricyl alcohol
NAA
NAAm
nabam
naftalofos
naled
naphthalene
naphthaleneacetamide
α-naphthaleneacetic acids
naphthalic anhydride
naphthalophos
1-naphthol
naphthoxyacetic acids
naphthylacetic acids
naphthylindane-1,3-diones
naphthyloxyacetic acids
naproanilide
napropamide
napropamide-M
naptalam
natamycin
NBPOS
neburea
neburon
nendrin
neonicotine
nichlorfos
niclofen
niclosamide
nicobifen
nicosulfuron
nicotine
nicotine sulfate
nifluridide
nikkomycins
NIP
nipyraclofen
nipyralofen
nitenpyram
nithiazine
nitralin
nitrapyrin
nitrilacarb
nitrofen
nitrofluorfen
nitrostyrene
nitrothal-isopropyl
nobormide
nonanol
norbormide
norea
norflurazon
nornicotine
noruron
novaluron
noviflumuron
NPA
nuarimol
nuranone
OCH
octachlorodipropyl ether
octhilinone
2-(octylthio)ethanol
o-dichlorobenzene
ofurace
omethoate
o-phenylphenol
orbencarb
orfralure
orthobencarb
ortho-dichlorobenzene
orthosulfamuron
oryctalure
orysastrobin
oryzalin
osthol
osthole
ostramone
ovatron
ovex
oxabetrinil
oxadiargyl
oxadiazon
oxadixyl
oxamate
oxamyl
oxapyrazon
oxapyrazone
oxasulfuron
oxathiapiprolin
oxaziclomefone
oxazosulfyl
oxine-copper
oxine-Cu
oxolinic acid
oxpoconazole
oxycarboxin
oxydemeton-methyl
oxydeprofos
oxydisulfoton
oxyenadenine
oxyfluorfen
oxymatrine
oxytetracycline
oxythioquinox
PAC
paclobutrazol
paichongding
palléthrine
PAP
para-dichlorobenzene
parafluron
paraquat
parathion
parathion-methyl
parinol
Paris green
PCNB
PCP
PCP-Na
p-dichlorobenzene
PDJ
pebulate
pédinex
pefurazoate
pelargonic acid
penconazole
pencycuron
pendimethalin
penfenate
penflufen
penfluron
penoxalin
penoxsulam
pentachlorophenol
pentachlorophenyl laurate
pentanochlor
penthiopyrad
pentmethrin
pentoxazone
perchlordecone
perfluidone
permethrin
pethoxamid
PHC
phenamacril
phenamacril-ethyl
phénaminosulf
phenazine oxide
phénétacarbe
phenisopham
phenkapton
phenmedipham
phenmedipham-ethyl
phenobenzuron
phenothiol
phenothrin
phenproxide
phenthoate
8-phenylmercurioxyquinoline
phenylmercuriurea
phenylmercury acetate
phenylmercury chloride
phenylmercury derivative of pyrocatechol
phenylmercury nitrate
phenylmercury salicylate
2-phenylphenol
phorate
phosacetim
phosalone
phosametine
phosazetim
phosazetin
phoscyclotin
phosdiphen
phosethyl
phosfolan
phosfolan-methyl
phosglycin
phosmet
phosnichlor
phosphamide
phosphamidon
phosphine
phosphinothricin
phosphocarb
phosphorus
phostin
phoxim
phoxim-methyl
phthalide
phthalophos
phthalthrin
picarbutrazox
picaridin
picloram
picolinafen
picoxystrobin
pimaricin
pindone
pinoxaden
piperalin
piperazine
piperonyl butoxide
piperonyl cyclonene
piperophos
piproctanly
piproctanyl
piprotal
pirimetaphos
pirimicarb
piriminil
pirimioxyphos
pirimiphos-ethyl
pirimiphos-methyl
pival
pivaldione
plifenate
PMA
PMP
polybutenes
polycarbamate
polychlorcamphene
polyethoxyquinoline
polyoxin D
polyoxins
polyoxorim
polythialan
potassium arsenite
potassium azide
potassium cyanate
potassium ethylxanthate
potassium naphthenate
potassium polysulfide
potassium thiocyanate
pp′-DDT
prallethrin
precocene I
precocene II
precocene III
pretilachlor
primidophos
primisulfuron
probenazole
prochloraz
proclonol
procyazine
procymidone
prodiamine
profenofos
profluazol
profluralin
profluthrin
profoxydim
profurite-aminium
proglinazine
prohexadione
prohydrojasmon
promacyl
promecarb
prometon
prometryn
prometryne
promurit
pronamide
propachlor
propafos
propamidine
propamocarb
propanil
propaphos
propaquizafop
propargite
proparthrin
propazine
propetamphos
propham
propiconazole
propidine
propineb
propisochlor
propoxur
propoxycarbazone
propyl isome
propyrisulfuron
propyzamide
proquinazid
prosuler
prosulfalin
prosulfocarb
prosulfuron
prothidathion
prothiocarb
prothioconazole
prothiofos
prothoate
protrifenbute
proxan
prymidophos
prynachlor
psoralen
psoralene
pydanon
pydiflumetofen
pyflubumide
pymetrozine
pyracarbolid
pyraclofos
pyraclonil
pyraclostrobin
pyraflufen
pyrafluprole
pyramat
pyrametostrobin
pyraoxystrobin
pyrapropoyne
pyrasulfotole
pyraziflumid
pyrazolate
pyrazolynate
pyrazon
pyrazophos
pyrazosulfuron
pyrazothion
pyrazoxyfen
pyresmethrin
pyrethrin I
pyrethrin II
pyrethrins
pyribambenz-isopropyl
pyribambenz-propyl
pyribencarb
pyribenzoxim
pyributicarb
pyriclor
pyridaben
pyridachlometyl
pyridafol
pyridalyl
pyridaphenthion
pyridaphenthione
pyridate
pyridinitril
pyrifenox
pyrifluquinazon
pyriftalid
pyrimétaphos
pyrimethanil
pyrimicarbe
pyrimidifen
pyriminobac
pyriminostrobin
pyrimiphos-éthyl
pyrimiphos-méthyl
pyrimisulfan
pyrimitate
pyrinuron
pyriofenone
pyriprole
pyripropanol
pyriproxyfen
pyrisoxazole
pyrithiobac
pyrolan
pyroquilon
pyroxasulfone
pyroxsulam
pyroxychlor
pyroxyfur
Q
qincaosuan
qingkuling
quassia
quinacetol
quinalphos
quinalphos-methyl
quinazamid
quinclorac
quinconazole
quinmerac
quinoclamine
quinofumelin
quinomethionate
quinonamid
quinothion
quinoxyfen
quintiofos
quintozene
quizalofop
quizalofop-P
quwenzhi
quyingding
rabenzazole
rafoxanide
R-diniconazole
rebemide
reglone
renofluthrin
renriduron
rescalure
resmethrin
d-trans-resmethrin
rhodethanil
rhodojaponin-III
ribavirin
rimsulfuron
rizazole
R-metalaxyl
rodéthanil
ronnel
rotenone
ryania
sabadilla
saflufenacil
saijunmao
saisentong
salicylanilide
salifluofen
sanguinarine
santonin
sarolaner
S-bioallethrin
schradan
scilliroside
sebuthylazine
secbumeton
sedaxane
selamectin
semiamitraz
sesamex
sesamolin
sesone
sethoxydim
sevin
S-hydroprene
shuangjiaancaolin
shuangjianancaolin
siduron
sifumijvzhi
siglure
silafluofen
silatrane
silica aerogel
silica gel
silthiofam
silthiopham
silthiophan
silvex
simazine
simeconazole
simeton
simetryn
simetryne
sintofen
S-kinoprene
slaked lime
SMA
S-methoprene
S-metolachlor
sodium arsenite
sodium azide
sodium chlorate
sodium cyanide
sodium fluoride
sodium fluoroacetate
sodium hexafluorosilicate
sodium naphthenate
sodium orthophenylphenoxide
sodium pentachlorophenate
sodium pentachlorophenoxide
sodium o-phenylphenoxide
sodium polysulfide
sodium silicofluoride
disodium tetraborate
sodium tetrathiocarbonate
sodium thiocyanate
solan
sophamide
spinetoram
spinosad
spirodiclofen
spiromesifen
spiropidion
spirotetramat
spiroxamine
stirofos
streptomycin
strychnine
sulcatol
sulcofuron
sulcotrione
sulfallate
sulfentrazone
sulfiram
sulfluramid
sulfodiazole
sulfometuron
sulfosate
sulfosulfuron
sulfotep
sulfotepp
sulfoxaflor
sulfoxide
sulfoxime
sulfur
sulfuric acid
sulfuryl fluoride
sulglycapin
sulphosate
sulprofos
sultropen
swep
2,4,5-T
tau-fluvalinate
tavron
tazimcarb
2,4,5-TB
2,3,6-TBA
TBTO
TBZ
TCA
TCBA
TCMTB
TCNB
TDE
tebuconazole
tebufenozide
tebufenpyrad
tebufloquin
tebupirimfos
tebutam
tebuthiuron
tecloftalam
tecnazene
tecoram
tedion
teflubenzuron
tefluthrin
kappa-tefluthrin
tefuryltrione
tembotrione
temefos
temephos
tepa
TEPP
tepraloxydim
teproloxydim
terallethrin
terbacil
terbucarb
terbuchlor
terbufos
terbumeton
terbuthylazine
terbutol
terbutryn
terbutryne
terraclor
terramicin
terramycin
tetcyclacis
tetrachlorantraniliprole
tetrachloroethane
tetrachlorvinphos
tetraconazole
tetradifon
tetradisul
tetrafluron
tetramethrin
tetramethylfluthrin
tetramine
tetranactin
tetraniliprole
tetrapion
tetrasul
thallium sulfate
thallous sulfate
thenylchlor
theta-cypermethrin
thiabendazole
thiacloprid
thiadiazine
thiadifluor
thiamethoxam
thiameturon
thiapronil
thiazafluron
thiazfluron
thiazone
thiazopyr
thicrofos
thicyofen
thidiazimin
thidiazuron
thiencarbazone
thifensulfuron
thifluzamide
thimerosal
thimet
thiobencarb
thiocarboxime
thiochlorfenphim
thiochlorphenphime
thiocyanatodinitrobenzenes
thiocyclam
thiodan
thiodiazole-copper
thiodicarb
thiofanocarb
thiofanox
thiofluoximate
thiohempa
thiomersal
thiometon
thionazin
thiophanate
thiophanate-ethyl
thiophanate-methyl
thiophos
thioquinox
thiosemicarbazide
thiosultap
thiotepa
thioxamyl
thiram
thiuram
thuringiensin
tiabendazole
tiadinil
tiafenacil
tiaojiean
TIBA
tifatol
tiocarbazil
tioclorim
tioxazafen
tioxymid
TMTD
tirpate
tolclofos-methyl
tolfenpyrad
tolprocarb
tolpyralate
tolyfluanid
tolylfluanid
tolylmercury acetate
tomarin
topramezone
toxaphene
2,4,5-TP
2,3,3-TPA
TPN
tralkoxydim
tralocythrin
tralomethrin
tralopyril
d-trans-allethrin
d-trans-resmethrin
transfluthrin
transpermethrin
tretamine
tri-allate
triacontanol
triadimefon
triadimenol
triafamone
triallate
triamiphos
triapenthenol
triarathene
triarimol
triasulfuron
triazamate
triazbutil
triaziflam
triazophos
triazothion
triazoxide
tribasic copper chloride
tribasic copper sulfate
tribenuron
tribufos
tributyltin oxide
tricamba
trichlamide
trichlopyr
trichlorfon
trichlormetaphos-3
trichloronat
trichloronate
trichlorotrinitrobenzenes
trichlorphon
triclopyr
triclopyricarb
tricresol
tricyclazole
tricyclohexyltin hydroxide
tridemorph
tridiphane
trietazine
trifenmorph
trifenofos
trifloxystrobin
trifloxysulfuron
trifludimoxazin
triflumezopyrim
triflumizole
triflumuron
trifluralin
triflusulfuron
trifop
trifopsime
triforine
trihydroxytriazine
2,3,5-tri-iodobenzoic acid
2,3,5-triiodobenzoic acid
trimedlure
trimethacarb
trimeturon
trinexapac
triphenyltin
triprene
tripropindan
triptolide
tritac
trithialan
triticonazole
tritosulfuron
trunc-call
tuoyelin
tyclopyrazoflor
uniconazole
uniconazole-P
urbacide
uredepa
valerate
validamycin
validamycin A
valifenalate
valone
vamidothion
vangard
vaniliprole
vernolate
vinclozolin
vitamin D3
warfarin
xiaochongliulin
xinjunan
xiwojunan
xiwojunzhi
XMC
xylachlor
xylenols
xylylcarb
xymiazole
yishijing
zarilamid
zeatin
zengxiaoan
zengxiaolin
zeta-cypermethrin
zinc naphthenate
zinc phosphide
zinc thiazole
zinc thiozole
zinc trichlorophenate
zinc trichlorophenoxide
zineb
ziram
zolaprofos
zoocoumarin
zoxamide
zuoanjunzhi
zuocaoan
zuojunzhi
zuomihuanglong
numerics
1-MCP
1-methylcyclopropene
1-naphthol
1,2-dichloropropane
1,3-D
1,3-dichloropropene
2iP
2-methoxyethylmercury chloride
2-(octylthio)ethanol
2-phenylphenol
2,2,3-TPA
2,3,5-triiodobenzoic acid
2,3,6-TBA
2,4-D
2,4-DB
2,4-DEB
2,4-DEP
2,4-DES
2,4-DP
2,4-MCPA
2,4-MCPB
2,4,5-T
2,4,5-TB
2,4,5-TP
(3-ethoxypropyl)mercury bromide
3,4-DA
3,4-DB
3,4-DP
3,6-dichloropicolinic acid
4-aminopyridine
4-CPA
4-CPB
4-CPP
4-hydroxyphenethyl alcohol
8-hydroxyquinoline sulfate
8-phenylmercurioxyquinoline
Biopesticide Paecilomyces lilacinus
-Pdeudozyma flocculosa -Susa benigna a virusului mozaicului galben
-Virusul poliedrozei nucleare la Spodoptera exigua
-Ampelomyces quisqualis
- Coniothyrim minitans
-Gliocladium catenulatum
Pseudomonas chlororaphis
-
-Paecilomyces fumosoroseum
March 2018
tetrachlorantraniliprole
November 2017
cyclopyranil
florylpicoxamid
fluopimomide
ipflufenoquin
metyltetraprole
oxazosulfyl
pyridachlometyl
September 2017
pyrapropoyne
July 2017
tyclopyrazoflor
June 2017
flupyrimin
May 2017
Spiropidion
April 2017
aminopyrifen
inpyrfluxam
March 2017
acynonapyr
benzpyrimoxan
alpha-bromadiolone
fluindapyr
isoflucypram
metcamifen
August 2016
fenpicoxamid
July 2016
dichlobentiazox
May 2016
lancotrione
April 2016
florpyrauxifen
ipfentrifluconazole
mefentrifluconazole
quinofumelin
April 2015
chloroprallethrin
cyhalodiamide
fluazaindolizine
fluxametamide
pydiflumetofen
October 2014
kappa-bifenthrin
broflanilide
dicloromezotiaz
dipymetitrone
pyraziflumid
kappa-tefluthrin
April 2014
fluhexafon
tetraniliprole
tolpyralate
trifludimoxazin
October 2013
tioxazafen
August 2013
napropamide-M
picarbutrazox
triflumezopyrim
April 2013
cyclaniliprole
fenquinotrione
mandestrobin
momfluorothrin
February 2013
tiafenacil
November 2012
cholecalciferol
cyclopyrimorate
halauxifen
July 2012
heptafluthrin
oxathiapiprolin
pyriminostrobin
rescalure
May 2012
coumoxystrobin
enoxastrobin
fenaminstrobin
flufenoxystrobin
pyrisoxazole
triclopyricarb
March 2012
afidopyropen
clacyfos
isofetamid
pyflubumide
tolprocarb
September 2011
benzovindiflupyr
June 2011
flometoquin
flupyradifurone
iofensulfuron
November 2010
flufiprole
triafamone
July 2010
fenpyrazamine
January 2010
fluensulfone
fluxapyroxad
meperfluthrin
pyriofenone
September 2009
tetramethylfluthrin
June 2009
ametoctradin
bicyclopyrone
fenoxasulfone
metazosulfuron
penflufen
pyrametostrobin
pyraoxystrobin
tebufloquin
valifenalate
December 2008
methiozolin (cancelled)
September 2008
cyantraniliprole
indaziflam
propyrisulfuron
sedaxane
sulfoxaflor
July 2008
flutianil
glufosinate-P
ipfencarbazone
May 2008
aminocyclopyrachlor
alpha-endosulfan
isopyrazam
December 2007
saflufenacil
December 2006
bixafen
fluopyram
October 2006
spinetoram
September 2006
chlorantraniliprole
August 2006
imicyafos
pyrifluquinazon
pyroxasulfone
June 2006
isotianil
pyroxsulam
tefuryltrione
tralopyril
February 2006
cyenopyrafen
cyprosulfamide
meptyldinocap
pyribencarb
tembotrione
thiencarbazone
May 2005
amisulbrom
bencarbazone
pyrasulfotole
spirotetramat
October 2004
cyflumetofen
flubendiamide
lepimectin
mandipropamid
metaflumizone
orthosulfamuron
pyrafluprole
pyrimisulfan
pyriprole
topramezone
May 2004
diflovidazin
fluopicolide
penthiopyrad
November 2003
dimefluthrin
pinoxaden
April 2003
flucetosulfuron
October 2002
aminopyralid
benalaxyl-M
boscalid
metofluthrin
profluthrin
April 2002
aviglycine
benclothiaz
benthiavalicarb
flumorph
fluoxastrobin
orysastrobin
proquinazid
prothioconazole
spiromesifen
October 2001
amidoflumet
flufenerim
metamifop
metrafenone
nicobifen
noviflumuron
May 2001
cyflufenamid
gamma-cyhalothrin
dimoxystrobin
flonicamid
pyridalyl
thiosultap
tiadinil
November 2000
bistrifluron
cyazofamid
cybutryne
profoxydim
propoxycarbazone
pyraclostrobin
spirodiclofen
May 2000
acetoprole
fenoxanil
fluacrypyrim
flufenpyr
mesosulfuron
methylneodecanamide
penoxsulam
picolinafen
December 1999
amicarbazone
epocholeone
ethaboxam
foramsulfuron
profluazol
pyraclonil
pyriftalid
silthiofam
simeconazole
trifloxysulfuron
zoxamide
July 1999
benzfendizone
butafenacil
dinotefuran
fentrazamide
florasulam
isoxadifen
pethoxamid
picoxystrobin
prohydrojasmon
protrifenbute
trifloxystrobin
tritosulfuron
October 1998
beflubutamid
benzobicyclon
clothianidin
dimethenamid-P
fenamidone
flufenacet
iprovalicarb
mesotrione
pyridafol
March 1998
epoxiconazole
ethiprole
fluazolate
flucarbazone
iodosulfuron
isoxachlortole
oxpoconazole
thiamethoxam
September 1997
acequinocyl
acibenzolar
bethoxazin
carpropamid
chromafenozide
cinidon-ethyl
diclocymet
ergocalciferol
fenhexamid
imazapic
indoxacarb
methoxyfenozide
metominostrobin
S-metolachlor
pyribenzoxim
spinosad
tepraloxydim
thiacloprid
tolfenpyrad
Entries below this point have been obtained from various sources and may be incomplete
April 1997
metalaxyl-M
pentoxazone
vaniliprole
October 1996
bifenazate
cloransulam
diclosulam
diflufenzopyr
diflumetorim
halofenozide
indanofan
oxaziclomefone
phosphocarb
pyraflufen
quinoxyfen
spiroxamine
sulfosulfuron
July 1996
butroxydim
dicyclonon
karetazan
sulcotrione
April 1996
azafenidin
azoxystrobin
carvone
chlorfenapyr
etoxazole
famoxadone
flupyrsulfuron
imazamox
isoxaflutole
kresoxim-methyl
mefenpyr
oxasulfuron
polyoxorim
triaziflam
February 1996
carfentrazone
bispyribac
ethoxysulfuron
flumetover
fluthiacet
pyriminobac
theta-cypermethrin
April 1995
acetamiprid
aldimorph
cafenstrole
clofencet
cyclanilide
cyclosulfamuron
cyhalofop
cyprodinil
dicyclanil
oxadiargyl
sintofen
tribufos
November 1994
azimsulfuron
flupropacil
furametpyr
tebupirimfos
thidiazimin
November 1993
diofenolan
halfenprox
prosulfuron
July 1993
nitenpyram
triazamate
June 1993
chlorethoxyfos
difenoconazole
hydroprene
novaluron
May 1993
clodinafop
cloquintocet
cumyluron
dimethenamid
emamectin
etobenzanid
fluazuron
fludioxonil
flumetsulam
flumiclorac
furilazole
halosulfuron
imiprothrin
karetazan
lufenuron
metosulam
nithiazine
pymetrozine
pyrimidifen
sulfentrazone
tebufenozide
thenylchlor
thiazopyr
thifluzamide
transfluthrin
triflusulfuron
trinexapac
triticonazole
zeta-cypermethrin
July 1992
amidosulfuron
silafluofen
May 1992
clethodim
mepronil
milbemectin
December 1991
debacarb
fenbuconazole
flumioxazin
fluquinconazole
pyrimethanil
pyrithiobac
rimsulfuron
July 1991
beta-cypermethrin
ethametsulfuron
fipronil
flufenprox
flumipropyn
flupoxam
ipconazole
metconazole
metobenzuron
tebufenpyrad
November 1990
bromuconazole
dichlorprop-P
imazosulfuron
quizalofop-P
October 1990
diniconazole-M
uniconazole-P
CONDIŢII DE ORGANIZARE ŞI FUNCŢIONARE A FITOFARMACIEI
În fitofarmacii comercianţii înregistraţi pe baza certificatului de activitate practică comerţul cu
amănuntul cu produse fitofarmaceutice nocive (Xn), iritante (Xi) sau fără clasificare de periculozitate. Localul
fitofarmaciei trebuie situat la parterul clădirilor având suprafaţa utilă ( suficientă şi adecvată) pentru derularea
activităţii. Încăperile fitofarmaciei (legate funcţional între ele în interiorul unei clădiri, nedispersate) sunt
amplasate doar în imobile cu fundaţie, cu pardoseala impermeabilă ( din ciment, gresie ), racordate la curent
electric, la instalaţia de apă curentă ( sursa de apa), canalizare ori fosă septică. Amplasarea fitofarmaciei nu este
indicată în spaţii improvizate (barăci, chioşcuri, contrucţii provizorii). Când fitofarmacia este la parterul imobilelor
accesul publicului se face direct din stradă, dar când este la parterul unui imobil (bloc) de locuinţe, accesul
cumpărătorilor va fi separat de accesul pentru locatarii imobilului.
Fitofarmacia trebuie obligatoriu compartimentată astfel :
1) încăpere unde se comercializează produsele pentru care au aprobare.
2) încăpere destinată depozitării produselor de protecţie fitosanitară în ambalajul original, sigilat ( încăperi
uscate, fără acţiunea directă a razelor solare şi a căldurii);
3) grup sanitar;
La sediul (legal) al fitofarmaciei trebuie să existe documentele:
a) acte de provenienţă şi de calitatea produselor (facturi, note de transfer, buletine de analiză, certificate de
conformitate);
b) lista furnizorilor;
c) documente care atestă efectuarea recepţiei calitative a produselor;
d) registrul unic de control.
Documentele se vor arhiva şi se păstrează într-un spaţiu special amenajat, pe perioada prevazută de legislaţia
în vigoare.
Personalul fitofarmaciei se compune din:

a) personal cu pregătire de specialitate, atestat prin certificat de atestare profesională pentru activităţi de
comercializare a produselor de protecţie a plantelor eliberat de unitatea fitosanitară a judeţului în raza căruia se
află şi-şi desfaşoară activitatea.
b) personal administrativ.
În situaţia fitofarmaciei aflate într-un imobil cu depozitul fitofarmaceutic (un tot unitar), proprietatea aceleiaşi
societăţi, nu se impun: doua grupuri sanitare; depozit separat pentru depozitarea produselor comercializate în
fitofarmacie
CONDIŢII DE ORGANIZARE ŞI FUNCŢIONARE A DEPOZITULUI FITOFARMACEUTIC

În depozitele fitofarmaceutice comercianţii înregistraţi pe baza certificatului de înregistrare au ca obiect comerţul
cu ridicata al produselor de protecţie a plantelor (achiziţia, stocarea, menţinerea calităţii, distribuţia produselor
fitosanitare.
Spaţiul destinat funcţionării depozitului fitofarmaceutic trebuie să asigure o suprafaţă utilă, suficientă şi adecvată
pentru desfăşurarea activităţii. Pentru depozitarea produselor de protecţie a plantelor clasificate ( foarte toxice
(T+) şi toxice (T) se delimitează o încăpere în cadrul depozitului, unde produsele foarte toxice (T+) şi toxice (T) sunt
separate de alte produse. Depozitul fitofarmaceutic va fi racordat obligatoriu la apă curentă ( o sursă de apă),
canalizare (fosă septică), la curent electric şi canalizare, cu grup sanitar, cu podea impermeabilă (ciment, gresie).
Depozitul fitofarmaceutic va fi organizat pe diviziuni, în funcţie de complexitatea activităţii ( recepţia / livrarea
produselor, depozitarea, stocarea produselor expirate, retrase sau returnate).
Depozitul fitofarmaceutic trebuie dotat cu:
1)rafturi metalice şi paleţi;
2) sistem pentru asigurarea condiţiilor optime de climatizare;
3) sisteme de prevenire şi stingere a incendiilor şi sisteme antiefracţie.
La sediul depozitului fitofarmaceutic trebuie să existe documentele:
a) acte de provenienţă şi calitate a produselor, facturi sau note de transfer, buletine de analiză şi certificate de
conformitate;
b) registru special de evidenta a distribuirii pentru produsele de protectie a plantelor clasificate ca foarte toxice
(T+) si toxice (T);
c) lista furnizorilor;
d) documentele care atestă efectuarea recepţiei calitative a produselor;
e) registrul unic de control.
Documentele se arhivează şi se păstrează în depozitul fitofarmaceutic în spaţiu amenajat, pentru perioada legală (
în vigoare).
http://www.alanwood.net/pesticides/******.html http://e-phy.agriculture.gouv.fr/spe/
Acetamiprid acetamiprid acétamipride ; ацетамиприд
STATUS: ISO 1750 (published)
IUPAC: (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine
CAS: (1E)-N-[(6-chloro-3-pyridinyl)methyl]-N′-cyano-N-methylethanimidamide
REG. NO.: 135410-20-7
FORMULA: C10H11ClN4
ACTIVITY: insecticides (pyridylmethylamine nicotinoid insecticides)
NOTES:
STRUCTURE:
ǎ-sǐ-tǎm-ǐ-prǐd
PRONUNCIATION: British pronunciation
INCHIKEY: WCXDHFDTOYPNIE-RIYZIHGNSA-N
INCHI: InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
-Acibenzolar-S-methyl acibenzolar acibenzolar ацибензолар

IUPAC: benzo[1,2,3]thiadiazole-7-carbothioic S-acid
CAS: 1,2,3-benzothiadiazole-7-carbothioic acid
REG. NO.: 126448-41-7
FORMULA: C7H4N2OS2
ACTIVITY: fungicides (unclassified fungicides) plant activators
When this substance is used as an ester or a salt, its identity should be stated, for
NOTES: example acibenzolar-S-methyl [135158-54-2].
STRUCTURE:
PRONUNCIATION: ǎ-sǐ-běn-zō-lar British pronunciation

INCHIKEY: CGIHPACLZJDCBQ-UHFFFAOYSA-N
INCHI: InChI=1S/C7H4N2OS2/c10-7(11)4-2-1-3-5-6(4)12-9-8-5/h1-3H,(H,10,11
–Acid benzoic
Alphametrin(Alphacypermethrin alpha-cypermethrin alpha-cyperméthrine альфа-циперметрин

IUPAC: racemate comprising (R)-α-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate or
racemate comprising (R)-α-cyano-3-phenoxybenzyl (1S)-cis-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
(R)-cyano(3-phenoxyphenyl)methyl (1S,3S)-rel-3-(2,2-dichloroethenyl)-2,2-
CAS: dimethylcyclopropanecarboxylate
REG. NO.: 67375-30-8
FORMULA: C22H19Cl2NO3
acaricides (pyrethroid ester acaricides)
ACTIVITY: insecticides (pyrethroid ester insecticides)
The name “alphamethrin” has been used in the literature, but it has no official status.
NOTES: The unresolved isomeric mixture of this substance has the ISO common name cypermethrin.
STRUCTURE:
PRONUNCIATION: ǎl-fa sī-per-mēth-rǐn British pronunciation

GUQZCTLEJXHSIH-RZAVTOELSA-N
identifier for no stereochemistry:
INCHIKEY: KAATUXNTWXVJKI-UHFFFAOYSA-N
InChI=1S/2C22H19Cl2NO3/c2*1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-
INCHI: 16(11-14)27-15-8-4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/t2*17-,18+,20-/m10/s1
- Aminotriazol (Amitrol) amitrole; amitrole ; амитрол

IUPAC: 1H-1,2,4-triazol-3-amine
CAS: 1H-1,2,4-triazol-3-amine
REG. NO.: 61-82-5
FORMULA: C2H4N4
ACTIVITY: herbicides (triazole herbicides)
NOTES: * The name “aminotriazole” is used in France.
STRUCTURE:
PRONUNCIATION: ǎ-mǐ-trōl British pronunciation

INCHIKEY: KLSJWNVTNUYHDU-UHFFFAOYSA-N
INCHI: InChI=1S/C2H4N4/c3-2-4-1-5-6-2/h1H,(H3,3,4,5,6
- Azimsulfuron azimsulfuron; azimsulfuron ; азимсульфуро

1-(4,6-dimethoxypyrimidin-2-yl)-3-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)pyrazol-5-
IUPAC: ylsulfonyl]urea
N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-
CAS: pyrazole-5-sulfonamide
REG. NO.: 120162-55-2
FORMULA: C13H16N10O5S
ACTIVITY: herbicides (pyrazole herbicides; pyrimidinylsulfonylurea herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ǎz-ǐm-sǔl-fūr-ǒn British pronunciation

INCHIKEY: MAHPNPYYQAIOJN-UHFFFAOYSA-N
InChI=1S/C13H16N10O5S/c1-22-11(7(6-14-22)10-18-21-23(2)19-10)29(25,26)20-13(24)17-12-
INCHI: 15-8(27-3)5-9(16-12)28-4/h5-6H,1-4H3,(H2,15,16,17,20,24)
- azoxystrobin azoxystrobine азоксистробин

IUPAC: methyl (2E)-2-{2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate
CAS: methyl (αE)-2-[[6-(2-cyanophenoxy)-4-pyrimidinyl]oxy]-α-(methoxymethylene)benzeneacetate
REG. NO.: 131860-33-8
FORMULA: C22H17N3O5
ACTIVITY: fungicides (methoxyacrylate strobilurin fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ǎz-ǒks-ē-strō-bǐn British pronunciation

INCHIKEY: WFDXOXNFNRHQEC-GHRIWEEISA-N
InChI=1S/C22H17N3O5/c1-27-13-17(22(26)28-2)16-8-4-6-10-19(16)30-21-11-20(24-14-25-
INCHI: 21)29-18-9-5-3-7-15(18)12-23/h3-11,13-14H,1-2H3/b17-13+
- Benalaxyl benalaxy bénalaxyl беналаксил

IUPAC: methyl N-(phenylacetyl)-N-(2,6-xylyl)-DL-alaninate
CAS: methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate
REG. NO.: 71626-11-4
FORMULA: C20H23NO3
ACTIVITY: fungicides (acylamino acid fungicides; anilide fungicides)
NOTES: The (−)-isomer of this substance has the ISO common name benalaxyl-M.
STRUCTURE:
PRONUNCIATION: běn-a-lǎks-ǐl British pronunciation

INCHIKEY: CJPQIRJHIZUAQP-UHFFFAOYSA-N
InChI=1S/C20H23NO3/c1-14-9-8-10-15(2)19(14)21(16(3)20(23)24-4)18(22)13-17-11-6-5-7-12-
INCHI: 17/h5-12,16H,13H2,1-4H3
- Bentazon bentazone bentazone бентазон

IUPAC: 3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide
CAS: 3-(1-methylethyl)-1H-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide
REG. NO.: 25057-89-0
ACTIVITY: herbicides (unclassified herbicides)
When this substance is used as a salt, its identity should be stated, for example bentazone-
sodium [50723-80-3].
The name “bendioxide” is used in South Africa, and the name “bentazon” is used in Canada and
NOTES: the USA.
STRUCTURE:
PRONUNCIATION: běn-ta-zōn British pronunciation

INCHIKEY: ZOMSMJKLGFBRBS-UHFFFAOYSA-N
INCHI: InChI=1S/C10H12N2O3S/c1-7(2)12-10(13)8-5-3-4-6-9(8)11-16(12,14)15/h3-7,11H,1-2H3
-
Beta-cyfluthrin beta-cyfluthrin bêta-cyfluthrin бета-цифлутрин
reaction mixture comprising the enantiomeric pair (R)-α-cyano-4-fluoro-3-phenoxybenzyl
(1S,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-4-fluoro-3-
phenoxybenzyl (1R,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate in ratio 1:2
with the enantiomeric pair (R)-α-cyano-4-fluoro-3-phenoxybenzyl (1S,3R)-3-(2,2-dichlorovinyl)-
2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-4-fluoro-3-phenoxybenzyl (1R,3S)-3-(2,2-
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate or
reaction mixture comprising the enantiomeric pair (R)-α-cyano-4-fluoro-3-phenoxybenzyl (1S)-
cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-4-fluoro-3-
phenoxybenzyl (1R)-cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate in ratio 1:2
with the enantiomeric pair (R)-α-cyano-4-fluoro-3-phenoxybenzyl (1S)-trans-3-(2,2-
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-4-fluoro-3-phenoxybenzyl
IUPAC: (1R)-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-
REG. NO.: 68359-37-5
FORMULA: C22H18Cl2FNO3
NOTES: The unresolved isomeric mixture of this substance has the ISO common name cyfluthrin.
STRUCTURE:
PRONUNCIATION: bē-ta sī-floo-thrǐn British pronunciation

(R)-alcohol (1S,3S)-acid plus (S)-alcohol (1R,3R)-acid enantiomeric pair:
OFHFONYRMVKULH-WNYJFNBPSA-N
(R)-alcohol (1S,3R)-acid plus (S)-alcohol (1R,3S)-acid enantiomeric pair:
OFHFONYRMVKULH-NIGOVZMWSA-N
INCHIKEY: QQODLKZGRKWIFG-UHFFFAOYSA-N
INCHI: (R)-alcohol (1S,3S)-acid plus (S)-alcohol (1R,3R)-acid enantiomeric pair:
InChI=1S/2C22H18Cl2FNO3/c2*1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-
16(25)17(10-13)28-14-6-4-3-5-7-14/h2*3-11,15,18,20H,1-2H3/t2*15-,18+,20-/m10/s1
(R)-alcohol (1S,3R)-acid plus (S)-alcohol (1R,3S)-acid enantiomeric pair:
InChI=1S/2C22H18Cl2FNO3/c2*1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-
16(25)17(10-13)28-14-6-4-3-5-7-14/h2*3-11,15,18,20H,1-2H3/t2*15-,18-,20+/m10/s1
-Bifenazat bifenazate bifénazate бифеназат

isopropyl 3-(4-methoxybiphenyl-3-yl)carbazate
or
IUPAC: isopropyl 2-(4-methoxybiphenyl-3-yl)hydrazinoformate
CAS: 1-methylethyl 2-(4-methoxy[1,1′-biphenyl]-3-yl)hydrazinecarboxylate
REG. NO.: 149877-41-8
FORMULA: C17H20N2O3
ACTIVITY: acaricides (carbazate acaricides)
NOTES: The name “lianbenjingzhi” (联苯肼酯) is approved in China.
STRUCTURE:
PRONUNCIATION: bī-fěn-a-zāt British pronunciation

INCHIKEY: VHLKTXFWDRXILV-UHFFFAOYSA-N
InChI=1S/C17H20N2O3/c1-12(2)22-17(20)19-18-15-11-14(9-10-16(15)21-3)13-7-5-4-6-8-13/h4-12,18H,1-3H3
INCHI: (H,19,20)
-Bromoxynil bromoxynil bromoxynil бромоксинил

IUPAC: 3,5-dibromo-4-hydroxybenzonitrile
CAS: 3,5-dibromo-4-hydroxybenzonitrile
REG. NO.: 1689-84-5
FORMULA: C7H3Br2NO
ACTIVITY: herbicides (nitrile herbicides)
When this substance is used as an ester or a salt, its identity should be stated, for example
bromoxynil butyrate [3861-41-4], bromoxynil heptanoate [56634-95-8], bromoxynil octanoate
NOTES: [1689-99-2], bromoxynil-potassium [2961-68-4].
STRUCTURE:
PRONUNCIATION: brō-mǒks-ǐ-nǐl British pronunciation
INCHIKEY: UPMXNNIRAGDFEH-UHFFFAOYSA-N
INCHI: InChI=1S/C7H3Br2NO/c8-5-1-4(3-10)2-6(9)7(5)11/h1-2,11H
-Carfentrazon –ethyl carfentrazone carfentrazone карфентразон

(RS)-2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-
IUPAC: yl]-4-fluorophenyl}propionic acid
α,2-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]-4-
CAS: fluorobenzenepropanoic acid
REG. NO.: 128621-72-7
FORMULA: C13H10Cl2F3N3O3
ACTIVITY: herbicides (triazolone herbicides)
NOTES: example carfentrazone-ethyl [128639-02-1].
STRUCTURE:
PRONUNCIATION: kar-fěn-tra-zōn British pronunciation

INCHIKEY: YHKBGVDUSSWOAB-UHFFFAOYSA-N
InChI=1S/C13H10Cl2F3N3O3/c1-5-19-21(13(24)20(5)12(17)18)10-3-6(2-8(15)11(22)23)7(14)4-
INCHI: 9(10)16/h3-4,8,12H,2H2,1H3,(H,22,23
-Chlorothalonil chlorothalonil chlorothalonil хлороталонил

IUPAC: tetrachloroisophthalonitrile
CAS: 2,4,5,6-tetrachloro-1,3-benzenedicarbonitrile
REG. NO.: 1897-45-6
FORMULA: C8Cl4N2
ACTIVITY: fungicides (aromatic fungicides)
NOTES: The name “TPN” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
STRUCTURE:
PRONUNCIATION: klor-ō-thǎl-ō-nǐl British pronunciation

INCHIKEY: CRQQGFGUEAVUIL-UHFFFAOYSA-N
INCHI: InChI=1S/C8Cl4N2/c9-5-3(1-13)6(10)8(12)7(11)4(5)2-14
-Chlorotoluron (chlortoluron) chlorotoluron chlortoluron хлоротолурон

IUPAC: 3-(3-chloro-p-tolyl)-1,1-dimethylurea
CAS: N′-(3-chloro-4-methylphenyl)-N,N-dimethylurea
REG. NO.: 15545-48-9
FORMULA: C10H13ClN2O
ACTIVITY: herbicides (phenylurea herbicides)
The name “chlortoluron” is approved by the Weed Science Society of America, and is also
NOTES: approved in China (绿麦隆).
STRUCTURE:
PRONUNCIATION: klor-ō-tǒl-ūr-ǒn British pronunciation

INCHIKEY: JXCGFZXSOMJFOA-UHFFFAOYSA-N
INCHI: InChI=1S/C10H13ClN2O/c1-7-4-5-8(6-9(7)11)12-10(14)13(2)3/h4-6H,1-3H3,(H,12,14)
-Chlorpropham chlorpropham chlorprophame хлорпрофам

IUPAC: isopropyl 3-chlorocarbanilate
CAS: 1-methylethyl N-(3-chlorophenyl)carbamate
REG. NO.: 101-21-3
FORMULA: C10H12ClNO2
herbicides (carbanilate herbicides)
ACTIVITY: plant growth regulators (growth inhibitors)
NOTES: The name “chlor-IPC” (хлор-ИФК) was used in the former USSR.
STRUCTURE:
PRONUNCIATION: klor-prō-fǎm British pronunciation

INCHIKEY: CWJSHJJYOPWUGX-UHFFFAOYSA-N
INCHI: InChI=1S/C10H12ClNO2/c1-7(2)14-10(13)12-9-5-3-4-8(11)6-9/h3-7H,1-2H3,(H,12,13)
–Chlorpyriphos (chlorpyriphos-ethyl) chlorpyriphos* хлорпирифос

IUPAC: O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate
CAS: O,O-diethyl O-(3,5,6-trichloro-2-pyridinyl) phosphorothioate
REG. NO.: 2921-88-2
FORMULA: C9H11Cl3NO3PS
acaricides (organothiophosphate acaricides)
insecticides (pyridine organothiophosphate insecticides)
ACTIVITY: nematicides (organothiophosphate nematicides)
* The name “chlorpyriphos-éthyl” (n.m.) is used in France.
NOTES: The analogous dimethyl ester has the ISO common name chlorpyrifos-methyl.
STRUCTURE:
PRONUNCIATION: klor-pǐr-ǐ-fǒs British pronunciation

INCHIKEY: SBPBAQFWLVIOKP-UHFFFAOYSA-N
–Chlorpyrifos methyl chlorpyrifos-methyl chlorpyriphos-méthyl хлорпирифос-метнл

IUPAC: O,O-dimethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate
CAS: O,O-dimethyl O-(3,5,6-trichloro-2-pyridinyl) phosphorothioate
REG. NO.: 5598-13-0
ACTIVITY: insecticides (pyridine organothiophosphate insecticides)
NOTES: The analogous diethyl ester has the ISO common name chlorpyrifos.
STRUCTURE:
PRONUNCIATION: klor-pǐr-ǐ-fǒs mē-thīl British pronunciation

INCHIKEY: HRBKVYFZANMGRE-UHFFFAOYSA-N
INCHI: InChI=1S/C7H7Cl3NO3PS/c1-12-15(16,13-2)14-7-5(9)3-4(8)6(10)11-7/h3H,1-2H3
- Cinidon-ethyl cinidon-ethyl cinidon-éthyl цинидон-этил

IUPAC: ethyl (Z)-2-chloro-3-[2-chloro-5-(cyclohex-1-ene-1,2-dicarboximido)phenyl]acrylate
ethyl (2Z)-2-chloro-3-[2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)phenyl]-2-
CAS: propenoate
REG. NO.: 142891-20-1
ACTIVITY: herbicides (dicarboximide herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: sī-nǐ-dǒn ē-thīl British pronunciation

INCHIKEY: NNKKTZOEKDFTBU-YBEGLDIGSA-N
InChI=1S/C19H17Cl2NO4/c1-2-26-19(25)16(21)10-11-9-12(7-8-15(11)20)22-17(23)13-5-3-4-6-
INCHI: 14(13)18(22)24/h7-10H,2-6H2,1H3/b16-10-
–Clodinafop clodinafop clodinafop клодинафоп

IUPAC: (R)-2-[4-(5-chloro-3-fluoro-2-pyridyloxy)phenoxy]propionic acid
CAS: (2R)-2-[4-[(5-chloro-3-fluoro-2-pyridinyl)oxy]phenoxy]propanoic acid
REG. NO.: 114420-56-3
FORMULA: C14H11ClFNO4
ACTIVITY: herbicides (aryloxyphenoxypropionic herbicides)
NOTES: clodinafop-propargyl [105512-06-9].
STRUCTURE:
PRONUNCIATION: klō-dīn-a-fǒp British pronunciation

INCHIKEY: YUIKUTLBPMDDNQ-MRVPVSSYSA-N
InChI=1S/C14H11ClFNO4/c1-8(14(18)19)20-10-2-4-11(5-3-10)21-13-12(16)6-9(15)7-17-13/h2-
INCHI: 8H,1H3,(H,18,19)/t8-/m1/s1
-Clopyralid clopyralid clopyralid клопиралид

3,6-dichloropyridine-2-carboxylic acid
or
IUPAC: 3,6-dichloropicolinic acid
CAS: 3,6-dichloro-2-pyridinecarboxylic acid
REG. NO.: 1702-17-6
FORMULA: C6H3Cl2NO2
ACTIVITY: herbicides (picolinic acid herbicides; pyridine herbicides)
clopyralid-methyl [1532-24-7], clopyralid-olamine [57754-85-5], clopyralid-potassium [58509-
83-4], clopyralid-tris(2-hydroxypropyl)ammonium.
NOTES: This compound is also included in Pesticides considered not to require common names (ISO 765-
1976), as 3,6-dichloropicolinic acid.
STRUCTURE:
PRONUNCIATION: klō-pīr-a-lǐd British pronunciation

INCHIKEY: HUBANNPOLNYSAD-UHFFFAOYSA-N
INCHI: InChI=1S/C6H3Cl2NO2/c7-3-1-2-4(8)9-5(3)6(10)11/h1-2H,(H,10,11)
-Clothianidin clothianidin clothianidine клотианидин

IUPAC: (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
CAS: [C(E)]-N-[(2-chloro-5-thiazolyl)methyl]-N′-methyl-N″-nitroguanidine
REG. NO.: 210880-92-5 (formerly 205510-53-8)
FORMULA: C6H8ClN5O2S
ACTIVITY: insecticides (nitroguanidine nicotinoid insecticides; thiazole insecticides)
NOTES: It is not possible to specify the (E)-isomer in a Standard InChI.
STRUCTURE:
PRONUNCIATION: klō-thī-ǎn-ǐd-ǐn British pronunciation

PGOOBECODWQEAB-PQKPOUEINA-N
Standard InChIKey (no stereo):
INCHIKEY: PGOOBECODWQEAB-UHFFFAOYSA-N
InChI=1/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/f/
h8,10H/b11-6+
INCHI: InChI=1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)
-Coumafen(Warfarine) warfarin warfarine варфарин

4-hydroxy-3-[(1RS)-3-oxo-1-phenylbutyl]coumarin
or
IUPAC: (RS)-3-(α-acetonylbenzyl)-4-hydroxycoumarin
CAS: 4-hydroxy-3-(3-oxo-1-phenylbutyl)-2H-1-benzopyran-2-one
REG. NO.: 81-81-2
FORMULA: C19H16O4
ACTIVITY: rodenticides (coumarin rodenticides)
* According to ISO 1750, the name “coumafène” (n.m.) is used in France, but the ISO common
name “warfarine” (n.f.) also appears to be used.
The name “warfarin” is approved by the World Health Organization; the Chinese version is “华
法林”.
The name “zoocoumarin” (зоокумарин) was used in the former USSR.
NOTES: warfarin-potassium [2610-86-8], warfarin-sodium [129-06-6].
STRUCTURE:
PRONUNCIATION: wor-fa-rǐn British pronunciation

INCHIKEY: PJVWKTKQMONHTI-UHFFFAOYSA-N
InChI=1S/C19H16O4/c1-12(20)11-15(13-7-3-2-4-8-13)17-18(21)14-9-5-6-10-16(14)23-
INCHI: 19(17)22/h2-10,15,21H,11H2,1H3
–Cyazofamid cyazofamid cyazofamide циазофамид

IUPAC: 4-chloro-2-cyano-N,N-dimethyl-5-p-tolylimidazole-1-sulfonamide
CAS: 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1H-imidazole-1-sulfonamide
REG. NO.: 120116-88-3
ACTIVITY: fungicides (imidazole fungicides; sulfonamide fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: sī-a-zō-fǎ-mǐd British pronunciation

INCHIKEY: YXKMMRDKEKCERS-UHFFFAOYSA-N
InChI=1S/C13H13ClN4O2S/c1-9-4-6-10(7-5-9)12-13(14)16-11(8-15)18(12)21(19,20)17(2)3/h4-
INCHI: 7H,1-3H3
-Cyclanilid cyclanilide cyclanilide цикланилид

IUPAC: 1-(2,4-dichloroanilinocarbonyl)cyclopropanecarboxylic acid
CAS: 1-[[(2,4-dichlorophenyl)amino]carbonyl]cyclopropanecarboxylic acid
REG. NO.: 113136-77-9
ACTIVITY: plant growth regulators (unclassified plant growth regulators)
NOTES:
STRUCTURE:
PRONUNCIATION: sī-klǎn-ǐ-līd British pronunciation

INCHIKEY: GLWWLNJJJCTFMZ-UHFFFAOYSA-N
InChI=1S/C11H9Cl2NO3/c12-6-1-2-8(7(13)5-6)14-9(15)11(3-4-11)10(16)17/h1-2,5H,3-4H2,
INCHI: (H,14,15)(H,16,17)
–Cyfluthrin cyfluthrin cyfluthrine цифлутрин

(RS)-α-cyano-4-fluoro-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate or
(RS)-α-cyano-4-fluoro-3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2-
IUPAC: dimethylcyclopropanecarboxylate
cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-
REG. NO.: 68359-37-5
One subset of isomers of this substance has its own ISO common name; see
NOTES: beta-cyfluthrin.
STRUCTURE:
PRONUNCIATION: sī-floo-thrǐn British pronunciation

InChI=1S/C22H18Cl2FNO3/c1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-
INCHI: 16(25)17(10-13)28-14-6-4-3-5-7-14/h3-11,15,18,20H,1-2H3
–Cyhalofop butyl cyhalofop-butyl

STATUS: modified ISO 1750 (published)
IUPAC: butyl (R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propionate
CAS: butyl (2R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propanoate
REG. NO.: 122008-85-9
FORMULA: C20H20FNO4
ACTIVITY: herbicides (aryloxyphenoxypropionic herbicides)
NOTES: This substance is a derivative of cyhalofop [122008-78-0].
STRUCTURE:
PRONUNCIATION: sī-hǎl-ō-fǒp bū-tīl British pronunciation

INCHIKEY: TYIYMOAHACZAMQ-CQSZACIVSA-N
InChI=1S/C20H20FNO4/c1-3-4-11-24-20(23)14(2)25-16-6-8-17(9-7-16)26-19-10-5-15(13-22)12-
INCHI: 18(19)21/h5-10,12,14H,3-4,11H2,1-2H3/t14-/m1/s1
–Cypermethrin cypermethrin cyperméthrine циперметрин

(RS)-α-cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate
or
(RS)-α-cyano-3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2-
CAS: cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 52315-07-8
Some subsets of isomers of this substance have their own ISO common names; see alpha-
NOTES: cypermethrin, beta-cypermethrin, theta-cypermethrin and zeta-cypermethrin.
STRUCTURE:
PRONUNCIATION: sī-per-mēth-rǐn British pronunciation

InChI=1S/C22H19Cl2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-
INCHI: 14)27-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3
–Cyprodinil cyprodinil cyprodinil ципродинил

IUPAC: 4-cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine
CAS: 4-cyclopropyl-6-methyl-N-phenyl-2-pyrimidinamine
REG. NO.: 121552-61-2
FORMULA: C14H15N3
ACTIVITY: fungicides (anilinopyrimidine fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: sī-prō-dī-nǐl British pronunciation

INCHIKEY: HAORKNGNJCEJBX-UHFFFAOYSA-N
InChI=1S/C14H15N3/c1-10-9-13(11-7-8-11)17-14(15-10)16-12-5-3-2-4-6-12/h2-6,9,11H,7-
INCHI: 8H2,1H3,(H,15,16,17)
-2,4 D 2,4-D 2,4-D 2,4-Д

IUPAC: (2,4-dichlorophenoxy)acetic acid
CAS: 2-(2,4-dichlorophenoxy)acetic acid
REG. NO.: 94-75-7
FORMULA: C8H6Cl2O3
herbicides (phenoxyacetic herbicides)
ACTIVITY: plant growth regulators (auxins)
When this substance is used as an ester or a salt, its identity should be stated, for example 2,4-
D-ammonium [2307-55-3], 2,4-D-butotyl [1929-73-3], 2,4-D-2-butoxypropyl [1320-18-9], 2,4-D-
3-butoxypropyl [1928-45-6], 2,4-D-butyl [94-80-4], 2,4-D-diethylammonium [20940-37-8], 2,4-
D-dimethylammonium [2008-39-1], 2,4-D-diolamine [5742-19-8], 2,4-D-dodecylammonium
[2212-54-6], 2,4-D-ethyl [533-23-3], 2,4-D-2-ethylhexyl [1928-43-4], 2,4-D-heptylammonium
[37102-63-9], 2,4-D-isobutyl [1713-15-1], 2,4-D-isoctyl [25168-26-7], 2,4-D-isopropyl [94-11-1],
2,4-D-isopropylammonium [5742-17-6], 2,4-D-lithium [3766-27-6], 2,4-D-meptyl [1917-97-1],
2,4-D-methyl [1928-38-7], 2,4-D-octyl [1928-44-5], 2,4-D-pentyl [1917-92-6], 2,4-D-propyl
[1928-61-6], 2,4-D-sodium [2702-72-9], 2,4-D-tefuryl [15146-99-3], 2,4-D-tetradecylammonium
[28685-18-9], 2,4-D-triethylammonium [2646-78-8], 2,4-D-tris(2-hydroxypropyl)ammonium
[18584-79-7], 2,4-D-trolamine [2569-01-9].
NOTES: One complex ester of 2,4-D has its own Chinese common name, lvxiancaolin .
STRUCTURE:
PRONUNCIATION: too for dē British pronunciation

INCHIKEY: OVSKIKFHRZPJSS-UHFFFAOYSA-N
INCHI: InChI=1S/C8H6Cl2O3/c9-5-1-2-7(6(10)3-5)13-4-8(11)12/h1-3H,4H2,(H,11,12)
-2,4 DB 2,4-DB 2,4-DB 2,4-ДБ

IUPAC: 4-(2,4-dichlorophenoxy)butyric acid
CAS: 4-(2,4-dichlorophenoxy)butanoic acid
REG. NO.: 94-82-6
FORMULA: C10H10Cl2O3
herbicides (phenoxybutyric herbicides)
ACTIVITY: plant growth regulators (auxins)
When this substance is used as an ester or a salt, its identity should be stated, for example 2,4-
DB-butyl, 2,4-DB-dimethylammonium [2758-42-1], 2,4-DB-isoctyl [1320-15-6], 2,4-DB-
NOTES: potassium [19480-40-1], 2,4-DB-sodium [10433-59-7].
STRUCTURE:
PRONUNCIATION: too for dē bē British pronunciation

INCHIKEY: YIVXMZJTEQBPQO-UHFFFAOYSA-N
INCHI: InChI=1S/C10H10Cl2O3/c11-7-3-4-9(8(12)6-7)15-5-1-2-10(13)14/h3-4,6H,1-2,5H2,(H,13,14)
–Daminozid daminozide daminozide даминозид

IUPAC: N-(dimethylamino)succinamic acid
CAS: butanedioic acid mono(2,2-dimethylhydrazide)
REG. NO.: 1596-84-5
FORMULA: C6H12N2O3
ACTIVITY: plant growth regulators (growth retardants)
NOTES:
STRUCTURE:
PRONUNCIATION: da-mēn-ō-zīd British pronunciation

INCHIKEY: NOQGZXFMHARMLW-UHFFFAOYSA-N
INCHI: InChI=1S/C6H12N2O3/c1-8(2)7-5(9)3-4-6(10)11/h3-4H2,1-2H3,(H,7,9)(H,10,11)
–Deltamethrin deltamethrin deltaméthrine дельтаметри

(S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-2,2-
dimethylcyclopropanecarboxylate or
(S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-dibromovinyl)-2,2-
(S)-cyano(3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-
REG. NO.: 52918-63-5
FORMULA: C22H19Br2NO3
The name “decamethrin” was originally proposed for this compound and was used in the
NOTES: literature, but was rejected because of a conflict with a trade mark.
STRUCTURE:
PRONUNCIATION: děl-ta-mēth-rǐn British pronunciation

INCHIKEY: OWZREIFADZCYQD-NSHGMRRFSA-N
InChI=1S/C22H19Br2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-
INCHI: 14)27-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3/t17-,18+,20-/m0/s1
–Desmedifam desmedipham desmédiphame десмедифам

IUPAC: ethyl 3-phenylcarbamoyloxycarbanilate
CAS: ethyl N-[3-[[(phenylamino)carbonyl]oxy]phenyl]carbamate
REG. NO.: 13684-56-5
FORMULA: C16H16N2O4
ACTIVITY: herbicides (carbanilate herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: děs-měd-ǐ-fǎm British pronunciation

INCHIKEY: WZJZMXBKUWKXTQ-UHFFFAOYSA-N
InChI=1S/C16H16N2O4/c1-2-21-15(19)18-13-9-6-10-14(11-13)22-16(20)17-12-7-4-3-5-8-12/h3-
INCHI: 11H,2H2,1H3,(H,17,20)(H,18,19)
–Dimethenamide-P(DMTA-P) dimethenamid-P diméthénamide-P диметенамид-

IUPAC: (S)-2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide
CAS: 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-[(1S)-2-methoxy-1-methylethyl]acetamide
REG. NO.: 163515-14-8
FORMULA: C12H18ClNO2S
ACTIVITY: herbicides (amide herbicides)
The Chinese name “精二甲吩草胺” has also been used in the literature, but it has no official
status.
NOTES: The unresolved isomeric mixture of this substance has the ISO common name dimethenamid.
STRUCTURE:
PRONUNCIATION: dī-mě-thēn-a-mǐd pē British pronunciation

INCHIKEY: JLYFCTQDENRSOL-VIFPVBQESA-N
InChI=1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3/
INCHI: t9-/m0/s1
–Dimoxystrobin dimoxystrobin dimoxystrobine димоксистробин

IUPAC: (E)-2-(methoxyimino)-N-methyl-2-[α-(2,5-xylyloxy)-o-tolyl]acetamide
CAS: (αE)-2-[(2,5-dimethylphenoxy)methyl]-α-(methoxyimino)-N-methylbenzeneacetamide
REG. NO.: 149961-52-4
FORMULA: C19H22N2O3
ACTIVITY: fungicides (amide fungicides; methoxyiminoacetamide strobilurin fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: dī-mǒks-ē-strō-bǐn British pronunciation

INCHIKEY: WXUZAHCNPWONDH-DYTRJAOYSA-N
InChI=1S/C19H22N2O3/c1-13-9-10-14(2)17(11-13)24-12-15-7-5-6-8-16(15)18(21-23-
INCHI: 4)19(22)20-3/h5-11H,12H2,1-4H3,(H,20,22)/b21-18+
–Diquat diquat diquat дикват

9,10-dihydro-8a,10a-diazoniaphenanthrene
or
6,7-dihydrodipyrido[1,2-a:2′,1′-c]pyrazine-5,8-diium
or
IUPAC: 1,1′-ethylene-2,2′-bipyridyldiylium
CAS: 6,7-dihydrodipyrido[1,2-a:2′,1′-c]pyrazinediium
REG. NO.: 2764-72-9
FORMULA: C12H12N2
ACTIVITY: herbicides (quaternary ammonium herbicides)
When this substance is used as a salt, its identity should be stated, for example diquat
NOTES: dibromide [85-00-7].
The name “deiquat” is used in Germany.
The name “reglone” (реглон) was used in the former USSR, but Reglone is a registered trade
mark in many countries.
The name “敌草快” is approved in China for diquat and for diquat dibromide.
STRUCTURE:
PRONUNCIATION: dī-kwǒt British pronunciation

INCHIKEY: SYJFEGQWDCRVNX-UHFFFAOYSA-N
INCHI: InChI=1S/C12H12N2/c1-3-7-13-9-10-14-8-4-2-6-12(14)11(13)5-1/h1-8H,9-10H2/q+2
–Esfenvalerat esfenvalerate esfenvalérate эсфенвалерат

IUPAC: (αS)-α-cyano-3-phenoxybenzyl (2S)-2-(4-chlorophenyl)-3-methylbutyrate
CAS: (S)-cyano(3-phenoxyphenyl)methyl (αS)-4-chloro-α-(1-methylethyl)benzeneacetate
REG. NO.: 66230-04-4
NOTES: The unresolved isomeric mixture of this substance has the common name fenvalerate.
STRUCTURE:
PRONUNCIATION: ěs-fěn-vǎl-er-āt British pronunciation

INCHIKEY: NYPJDWWKZLNGGM-RPWUZVMVSA-N
InChI=1S/C25H22ClNO3/c1-17(2)24(18-11-13-20(26)14-12-18)25(28)30-23(16-27)19-7-6-10-
INCHI: 22(15-19)29-21-8-4-3-5-9-21/h3-15,17,23-24H,1-2H3/t23-,24+/m1/
–Ethofumesat ethofumesate éthofumesate этофумезат

IUPAC: (RS)-2-ethoxy-2,3-dihydro-3,3-dimethylbenzofuran-5-yl methanesulfonate
CAS: 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl methanesulfonate
REG. NO.: 26225-79-6
FORMULA: C13H18O5S
ACTIVITY: herbicides (benzofuranyl alkylsulfonate herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ěth-ō-fū-mē-sāt British pronunciation

INCHIKEY: IRCMYGHHKLLGHV-UHFFFAOYSA-N
InChI=1S/C13H18O5S/c1-5-16-12-13(2,3)10-8-9(18-19(4,14)15)6-7-11(10)17-12/h6-
INCHI: 8,12H,5H2,1-4H3
–Ethoxysulfuron ethoxysulfuron éthoxysulfuron этоксисульфурон

IUPAC: 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethoxyphenoxysulfonyl)urea
CAS: 2-ethoxyphenyl [[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]sulfamate
REG. NO.: 126801-58-9
ACTIVITY: herbicides (pyrimidinylsulfonylurea herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ěth-ǒks-ē-sǔl-fūr-ǒn British pronunciation

INCHIKEY: UWVKRNOCDUPIDM-UHFFFAOYSA-N
InChI=1S/C15H18N4O7S/c1-4-25-10-7-5-6-8-11(10)26-27(21,22)19-15(20)18-14-16-12(23-2)9-
INCHI: 13(17-14)24-3/h5-9H,4H2,1-3H3,(H2,16,17,18,19,20)
Etoxazol etoxazole étoxazole этоксазол

IUPAC: (RS)-5-tert-butyl-2-[2-(2,6-difluorophenyl)-4,5-dihydro-1,3-oxazol-4-yl]phenetole
CAS: 2-(2,6-difluorophenyl)-4-[4-(1,1-dimethylethyl)-2-ethoxyphenyl]-4,5-dihydrooxazole
REG. NO.: 153233-91-1
FORMULA: C21H23F2NO2
ACTIVITY: acaricides (unclassified acaricides)
NOTES:
STRUCTURE:
PRONUNCIATION: ět-ǒks-a-zōl British pronunciation

INCHIKEY: IXSZQYVWNJNRAL-UHFFFAOYSA-N
InChI=1S/C21H23F2NO2/c1-5-25-18-11-13(21(2,3)4)9-10-14(18)17-12-26-20(24-17)19-15(22)7-
INCHI: 6-8-16(19)23/h6-11,17H,5,12H2,1-4H3
-Famoxadon famoxadone famoxadone фамоксадон
IUPAC: (RS)-3-anilino-5-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione
CAS: 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-2,4-oxazolidinedione
REG. NO.: 131807-57-3
FORMULA: C22H18N2O4
ACTIVITY: fungicides (dicarboximide fungicides; oxazole fungicides)
The orthodox Chinese form “噁唑菌酮” is used in GB 4839-2009 Chinese common names for
NOTES: pesticides, but the vulgar form “恶唑菌酮” is also used in the literature.
STRUCTURE:
PRONUNCIATION: fǎm-ǒks-a-dōn British pronunciation

INCHIKEY: PCCSBWNGDMYFCW-UHFFFAOYSA-N
InChI=1S/C22H18N2O4/c1-22(16-12-14-19(15-13-16)27-18-10-6-3-7-11-18)20(25)24(21(26)28-
INCHI: 22)23-17-8-4-2-5-9-17/h2-15,23H,1H3
-Fenamidon fenamidone fénamidone фенамидон

IUPAC: (S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one
CAS: (5S)-3,5-dihydro-5-methyl-2-(methylthio)-5-phenyl-3-(phenylamino)-4H-imidazol-4-one
REG. NO.: 161326-34-7
FORMULA: C17H17N3OS
ACTIVITY: fungicides (imidazole fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: fěn-ǎm-ǐ-dōn British pronunciation

INCHIKEY: LMVPQMGRYSRMIW-KRWDZBQOSA-N
InChI=1S/C17H17N3OS/c1-17(13-9-5-3-6-10-13)15(21)20(16(18-17)22-2)19-14-11-7-4-8-12-
INCHI: 14/h3-12,19H,1-2H3/t17-/m0/s1
–Fenhexamid fenhexamid fenhexamide фенгексами

IUPAC: 2′,3′-dichloro-4′-hydroxy-1-methylcyclohexanecarboxanilide
CAS: N-(2,3-dichloro-4-hydroxyphenyl)-1-methylcyclohexanecarboxamide
REG. NO.: 126833-17-8
ACTIVITY: fungicides (anilide fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: fěn-hěks-a-mǐd British pronunciation

INCHIKEY: VDLGAVXLJYLFDH-UHFFFAOYSA-N
InChI=1S/C14H17Cl2NO2/c1-14(7-3-2-4-8-14)13(19)17-9-5-6-10(18)12(16)11(9)15/h5-6,18H,2-
INCHI: 4,7-8H2,1H3,(H,17,19)
-Flazasulfuron flazasulfuron flazasulfuron флазасульфурон

IUPAC: 1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-trifluoromethyl-2-pyridylsulfonyl)urea
CAS: N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(trifluoromethyl)-2-pyridinesulfonamide
REG. NO.: 104040-78-0
FORMULA: C13H12F3N5O5S
NOTES:
STRUCTURE:
PRONUNCIATION: flā-za-sǔl-fūr-ǒn British pronunciation

INCHIKEY: HWATZEJQIXKWQS-UHFFFAOYSA-N
InChI=1S/C13H12F3N5O5S/c1-25-8-6-9(26-2)19-11(18-8)20-12(22)21-27(23,24)10-
INCHI: 7(13(14,15)16)4-3-5-17-10/h3-6H,1-2H3,(H2,18,19,20,21,22)
–Florasulam florasulam florasulame флорасулам

IUPAC: 2′,6′,8-trifluoro-5-methoxy[1,2,4]triazolo[1,5-c]pyrimidine-2-sulfonanilide
CAS: N-(2,6-difluorophenyl)-8-fluoro-5-methoxy[1,2,4]triazolo[1,5-c]pyrimidine-2-sulfonamide
REG. NO.: 145701-23-1
ACTIVITY: herbicides (sulfonanilide herbicides; triazolopyrimidine herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: flor-ǎs-ū-lǎm British pronunciation

INCHIKEY: QZXATCCPQKOEIH-UHFFFAOYSA-N
InChI=1S/C12H8F3N5O3S/c1-23-12-16-5-8(15)10-17-11(18-20(10)12)24(21,22)19-9-6(13)3-2-4-
INCHI: 7(9)14/h2-5,19H,1H3
–Flufenacet (Fluthiamid) flufenacet flufénacet флуфенацет

IUPAC: 4′-fluoro-N-isopropyl-2-[5-(trifluoromethyl)-1,3,4-thiadiazol-2-yloxy]acetanilide
N-(4-fluorophenyl)-N-(1-methylethyl)-2-[[5-(trifluoromethyl)-1,3,4-thiadiazol-2-
CAS: yl]oxy]acetamide
REG. NO.: 142459-58-3
ACTIVITY: herbicides (anilide herbicides)
NOTES: The name “fluthiamide” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: floo-fěn-a-sět British pronunciation

INCHIKEY: IANUJLZYFUDJIH-UHFFFAOYSA-N
InChI=1S/C14H13F4N3O2S/c1-8(2)21(10-5-3-9(15)4-6-10)11(22)7-23-13-20-19-12(24-
INCHI: 13)14(16,17)18/h3-6,8H,7H2,1-2H3
–Flumioxazin flumioxazin flumioxazine флумиоксазин

N-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene-1,2-
IUPAC: dicarboxamide
2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-
CAS: isoindole-1,3(2H)-dione
REG. NO.: 103361-09-7
FORMULA: C19H15FN2O4
ACTIVITY: herbicides (dicarboximide herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: floo-mē-ǒks-a-zǐn British pronunciation

INCHIKEY: FOUWCSDKDDHKQP-UHFFFAOYSA-N
InChI=1S/C19H15FN2O4/c1-2-7-21-15-9-14(13(20)8-16(15)26-10-17(21)23)22-18(24)11-5-3-4-
INCHI: 6-12(11)19(22)25/h1,8-9H,3-7,10H2
–Flupyrsulfuron-methyl flupyrsulfuron-methyl
IUPAC: methyl 2-[(4,6-dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-6-(trifluoromethyl)nicotinate
methyl 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-6-(trifluoromethyl)-
CAS: 3-pyridinecarboxylate
REG. NO.: 144740-53-4
This substance is a derivative of flupyrsulfuron [150315-10-9].
The name “flupyrsulfuron-methyl” has often been used incorrectly in the literature for the
NOTES: sodium salt, flupyrsulfuron-methyl-sodium.
STRUCTURE:
PRONUNCIATION: floo-pīr-sǔl-fūr-ǒn mē-thīl British pronunciation

INCHIKEY: DTVOKYWXACGVGO-UHFFFAOYSA-N
InChI=1S/C15H14F3N5O7S/c1-28-9-6-10(29-2)21-13(20-9)22-14(25)23-31(26,27)11-7(12(24)30-
INCHI: 3)4-5-8(19-11)15(16,17)18/h4-6H,1-3H3,(H2,20,21,22,23,25)
–Fluroxypyr fluroxypyr fluoroxypyr* флуроксипир

IUPAC: 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid
CAS: 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid
REG. NO.: 69377-81-7
FORMULA: C7H5Cl2FN2O3
ACTIVITY: herbicides (pyridine herbicides)
* The name “fluroxypyr” (n.m.) is also used in francophone countries.
NOTES: example fluroxypyr-butometyl [154486-27-8], fluroxypyr-meptyl [81406-37-3].
STRUCTURE:
PRONUNCIATION: flūr-ǒks-ē-pīr British pronunciation

INCHIKEY: MEFQWPUMEMWTJP-UHFFFAOYSA-N
INCHI: InChI=1S/C7H5Cl2FN2O3/c8-3-5(11)4(9)7(12-6(3)10)15-1-2(13)14/h1H2,(H2,11,12)(H,13,14)
-
Flurtamon flurtamone flurtamone флуртамон
IUPAC: (2RS)-5-methylamino-2-phenyl-4-(α,α,α-trifluoro-m-tolyl)furan-3(2H)-one
CAS: 5-(methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]-3(2H)-furanone
REG. NO.: 96525-23-4
ACTIVITY: herbicides (unclassified herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: fler-ta-mōn British pronunciation

INCHIKEY: NYRMIJKDBAQCHC-UHFFFAOYSA-N
InChI=1S/C18H14F3NO2/c1-22-17-14(12-8-5-9-13(10-12)18(19,20)21)15(23)16(24-17)11-6-3-2-
INCHI: 4-7-11/h2-10,16,22H,1H3
–
Foramsulfuron foramsulfuron foramsulfuron форамсульфурон

IUPAC: 1-(4,6-dimethoxypyrimidin-2-yl)-3-[2-(dimethylcarbamoyl)-5-formamidophenylsulfonyl]urea
2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-4-(formylamino)-N,N-
CAS: dimethylbenzamide
REG. NO.: 173159-57-4
NOTES:
STRUCTURE:
PRONUNCIATION: for-ǎm-sǔl-fūr-ǒn British pronunciation

INCHIKEY: PXDNXJSDGQBLKS-UHFFFAOYSA-N
InChI=1S/C17H20N6O7S/c1-23(2)15(25)11-6-5-10(18-9-24)7-12(11)31(27,28)22-17(26)21-16-
INCHI: 19-13(29-3)8-14(20-16)30-4/h5-9H,1-4H3,(H,18,24)(H2,19,20,21,22,26)
Forchlorfenuron forchlorfenuron forchlorfénuron форхлорфенурон

IUPAC: 1-(2-chloro-4-pyridyl)-3-phenylurea
CAS: N-(2-chloro-4-pyridinyl)-N′-phenylurea
REG. NO.: 68157-60-8
ACTIVITY: plant growth regulators (growth stimulators)
NOTES:
STRUCTURE:
PRONUNCIATION: for-klor-fěn-ūr-ǒn British pronunciation

INCHIKEY: GPXLRLUVLMHHIK-UHFFFAOYSA-N
InChI=1S/C12H10ClN3O/c13-11-8-10(6-7-14-11)16-12(17)15-9-4-2-1-3-5-9/h1-8H,
INCHI: (H2,14,15,16,17)
**
- Fosetyl (fosetyl-Al ) fosetyl-aluminium

IUPAC: aluminium tris(ethyl phosphonate)
CAS: aluminum tris[ethyl phosphonate]
REG. NO.: 39148-24-8
FORMULA: C6H18AlO9P3
ACTIVITY: fungicides (organophosphorus fungicides)
This substance is a derivative of fosetyl [15845-66-6].
NOTES: The name “fosetyl-aluminum” is used in the USA.
STRUCTURE:
PRONUNCIATION: fǒs-ē-tīl ǎl-ū-mǐn-ē-am British pronunciation

INCHIKEY: ZKZMJOFIHHZSRW-UHFFFAOYSA-K
INCHI: InChI=1S/3C2H7O3P.Al/c3*1-2-5-6(3)4;/h3*6H,2H2,1H3,(H,3,4);/q;;;+3/p-3
-Fosthiasat fosthiazate fosthiazate фостиазат

(RS)-[S-(RS)-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate]
or
IUPAC: (3RS)-3-[(RS)-sec-butylthio(ethoxy)phosphinoyl]-1,3-thiazolidin-2-one
CAS: O-ethyl S-(1-methylpropyl) P-(2-oxo-3-thiazolidinyl)phosphonothioate
REG. NO.: 98886-44-3
FORMULA: C9H18NO3PS2
NOTES:
STRUCTURE:
PRONUNCIATION: fǒs-thī-a-zāt British pronunciation

INCHIKEY: DUFVKSUJRWYZQP-UHFFFAOYSA-N
INCHI: InChI=1S/C9H18NO3PS2/c1-4-8(3)16-14(12,13-5-2)10-6-7-15-9(10)11/h8H,4-7H2,1-3H3
-Glyphosat glyphosate glyphosate глифосат

IUPAC: N-(phosphonomethyl)glycine
CAS: N-(phosphonomethyl)glycine
REG. NO.: 1071-83-6
FORMULA: C3H8NO5P
ACTIVITY: herbicides (organophosphorus herbicides)
example glyphosate-diammonium [69254-40-6], glyphosate-dimethylammonium [34494-04-7],
glyphosate-isopropylammonium [38641-94-0],glyphosate-monoammonium [40465-66-5], glyph
NOTES: osate-potassium [70901-20-1], glyphosate-sesquisodium [70393-85-0], glyphosate-trimesium [8
1591-81-3].
STRUCTURE:
PRONUNCIATION: glī-fō-sāt British pronunciation

INCHIKEY: XDDAORKBJWWYJS-UHFFFAOYSA-N
INCHI: InChI=1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)
-Hidrazida maleica
–Imazalil imazalil imazalil имазалил

(RS)-1-(β-allyloxy-2,4-dichlorophenethyl)imidazole
or
IUPAC: allyl (RS)-1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether
CAS: 1-[2-(2,4-dichlorophenyl)-2-(2-propen-1-yloxy)ethyl]-1H-imidazole
REG. NO.: 35554-44-0
FORMULA: C14H14Cl2N2O
ACTIVITY: fungicides (conazole fungicides)
When this substance is used as a salt, its identity should be stated, for example imazalil
nitrate [33586-66-2], imazalil sulfate [58594-72-2].
The name “enilconazole” is approved by the World Health Organization; the Chinese version is
NOTES: “恩康唑” and the Russian version is “энилконазол”.
STRUCTURE:
PRONUNCIATION: ǐm-āz-a-lǐl British pronunciation

INCHIKEY: PZBPKYOVPCNPJY-UHFFFAOYSA-N
InChI=1S/C14H14Cl2N2O/c1-2-7-19-14(9-18-6-5-17-10-18)12-4-3-11(15)8-13(12)16/h2-
INCHI: 6,8,10,14H,1,7,9H2
–Imazamox imazamox imazamox имазамокс

IUPAC: 2-[(RS)-4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl]-5-methoxymethylnicotinic acid
2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-(methoxymethyl)-3-
CAS: pyridinecarboxylic acid
REG. NO.: 114311-32-9
FORMULA: C15H19N3O4
ACTIVITY: herbicides (imidazolinone herbicides)
NOTES: example imazamox-ammonium.
STRUCTURE:
PRONUNCIATION: ǐm-āz-a-mǒks British pronunciation

INCHIKEY: NUPJIGQFXCQJBK-UHFFFAOYSA-N
InChI=1S/C15H19N3O4/c1-8(2)15(3)14(21)17-12(18-15)11-10(13(19)20)5-9(6-16-11)7-22-4/h5-
INCHI: 6,8H,7H2,1-4H3,(H,19,20)(H,17,18,21)
–Imazosulfuron imazosulfuron imazosulfuron имазосульфурон

IUPAC: 1-(2-chloroimidazo[1,2-a]pyridin-3-ylsulfonyl)-3-(4,6-dimethoxypyrimidin-2-yl)urea
2-chloro-N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]imidazo[1,2-a]pyridine-3-
CAS: sulfonamide
REG. NO.: 122548-33-8
NOTES:
STRUCTURE:
PRONUNCIATION: ǐm-āz-ō-sǔl-fūr-ǒn British pronunciation

INCHIKEY: NAGRVUXEKKZNHT-UHFFFAOYSA-N
InChI=1S/C14H13ClN6O5S/c1-25-9-7-10(26-2)18-13(17-9)19-14(22)20-27(23,24)12-11(15)16-8-
INCHI: 5-3-4-6-21(8)12/h3-7H,1-2H3,(H2,17,18,19,20,22)
–Indoxacarb indoxacarb indoxacarbe индоксакарб

methyl (S)-N-[7-chloro-2,3,4a,5-tetrahydro-4a-(methoxycarbonyl)indeno[1,2-e][1,3,4]oxadiazin-
2-ylcarbonyl]-4-(trifluoromethoxy)carbanilate
or
methyl (S)-7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-
IUPAC: trifluoromethoxyphenyl)carbamoyl]indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate
methyl (4aS)-7-chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4-
CAS: (trifluoromethoxy)phenyl]amino]carbonyl]indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate
REG. NO.: 173584-44-6
FORMULA: C22H17ClF3N3O7
ACTIVITY: insecticides (oxadiazine insecticides)
NOTES: Despite the “carb” ending, this substance is not related to the carbamate insecticides.
STRUCTURE:
PRONUNCIATION: ǐn-dǒks-a-karb British pronunciation

INCHIKEY: VBCVPMMZEGZULK-NRFANRHFSA-N
InChI=1S/C22H17ClF3N3O7/c1-33-18(30)21-10-12-9-13(23)3-8-16(12)17(21)27-28(11-35-
INCHI: 21)19(31)29(20(32)34-2)14-4-6-15(7-5-14)36-22(24,25)26/h3-9H,10-11H2,1-2H3/t21-/m0/s1
–Iodosulfuron(+iodosulfuron –methyl-sodiu) Iodosulfuron iodosulfuron иодосульфурон

IUPAC: 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid
CAS: 4-iodo-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid
REG. NO.: 185119-76-0
FORMULA: C13H12IN5O6S
ACTIVITY: herbicides (triazinylsulfonylurea herbicides)
example iodosulfuron-methyl [144550-06-1], iodosulfuron-methyl-sodium [144550-36-7]. The
methyl ester sodium salt has often been incorrectly referred to as “iodosulfuron-methyl” in the
NOTES: literature.
STRUCTURE:
PRONUNCIATION: ī-ō-dō-sǔl-fūr-ǒn British pronunciation

INCHIKEY: MBFHUWCOCCICOK-UHFFFAOYSA-N
InChI=1S/C13H12IN5O6S/c1-6-15-11(18-13(16-6)25-2)17-12(22)19-26(23,24)9-5-7(14)3-4-
INCHI: 8(9)10(20)21/h3-5H,1-2H3,(H,20,21)(H2,15,16,17,18,19,22)
-Ioxynil ioxynil ioxynil иоксинил

IUPAC: 4-hydroxy-3,5-diiodobenzonitrile
or
4-hydroxy-3,5-diiodophenyl cyanide
CAS: 4-hydroxy-3,5-diiodobenzonitrile
REG. NO.: 1689-83-4
FORMULA: C7H3I2NO
ACTIVITY: herbicides (nitrile herbicides)
NOTES: example ioxynil-lithium [2961-61-7], ioxynil octanoate [3861-47-0], ioxynil-sodium [2961-62-8].
STRUCTURE:
PRONUNCIATION: ī-ǒks-ǐ-nǐl British pronunciation

INCHIKEY: NRXQIUSYPAHGNM-UHFFFAOYSA-N
INCHI: InChI=1S/C7H3I2NO/c8-5-1-4(3-10)2-6(9)7(5)11/h1-2,11H
–
Iprodion iprodione iprodione ипродион

IUPAC: 3-(3,5-dichlorophenyl)-N-isopropyl-2,4-dioxoimidazolidine-1-carboxamide
CAS: 3-(3,5-dichlorophenyl)-N-(1-methylethyl)-2,4-dioxo-1-imidazolidinecarboxamide
REG. NO.: 36734-19-7
FORMULA: C13H13Cl2N3O3
ACTIVITY: fungicides (dichlorophenyl dicarboximide fungicides; imidazole fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ǐ-prō-dī-ōn British pronunciation

INCHIKEY: ONUFESLQCSAYKA-UHFFFAOYSA-N
InChI=1S/C13H13Cl2N3O3/c1-7(2)16-12(20)17-6-11(19)18(13(17)21)10-4-8(14)3-9(15)5-10/h3-
INCHI: 5,7H,6H2,1-2H3,(H,16,20)
–Iprovalicarb iprovalicarb iprovalicarbe ипроваликарб

IUPAC: isopropyl 2-methyl-1-{[(RS)-1-p-tolylethyl]carbamoyl}-(S)-propylcarbamate
CAS: 1-methylethyl N-[(1S)-2-methyl-1-[[[1-(4-methylphenyl)ethyl]amino]carbonyl]propyl]carbamate
REG. NO.: 140923-17-7
FORMULA: C18H28N2O3
ACTIVITY: fungicides (carbamate fungicides; valinamide fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: ī-prō-vǎl-ǐ-karb British pronunciation

INCHIKEY: NWUWYYSKZYIQAE-WMCAAGNKSA-N
InChI=1S/C18H28N2O3/c1-11(2)16(20-18(22)23-12(3)4)17(21)19-14(6)15-9-7-13(5)8-10-15/h7-
INCHI: 12,14,16H,1-6H3,(H,19,21)(H,20,22)/t14?,16-/m0/s1
–Isoproturon isoproturon isoproturon изопротурон

3-(4-isopropylphenyl)-1,1-dimethylurea
or
IUPAC: 3-p-cumenyl-1,1-dimethylurea
CAS: N,N-dimethyl-N′-[4-(1-methylethyl)phenyl]urea
REG. NO.: 34123-59-6
FORMULA: C12H18N2O
algicides
NOTES:
STRUCTURE:
PRONUNCIATION: ī-sō-prōt-ūr-ǒn British pronunciation

INCHIKEY: PUIYMUZLKQOUOZ-UHFFFAOYSA-N
INCHI: InChI=1S/C12H18N2O/c1-9(2)10-5-7-11(8-6-10)13-12(15)14(3)4/h5-9H,1-4H3,(H,13,15)
–
Isoxaflutol isoxaflutole isoxaflutole изоксафлутол
IUPAC: (5-cyclopropyl-1,2-oxazol-4-yl)(α,α,α-trifluoro-2-mesyl-p-tolyl)methanone
CAS: (5-cyclopropyl-4-isoxazolyl)[2-(methylsulfonyl)-4-(trifluoromethyl)phenyl]methanone
REG. NO.: 141112-29-0
FORMULA: C15H12F3NO4S
ACTIVITY: herbicides (cyclopropylisoxazole herbicides; oxazole herbicides)
The orthodox Chinese form “异噁唑草酮” is used in GB 4839-2009 Chinese common names for
NOTES: pesticides, but the vulgar form “异恶唑草酮” is also used in the literature.
STRUCTURE:
PRONUNCIATION: īs-ǒks-a-floo-tōl British pronunciation

INCHIKEY: OYIKARCXOQLFHF-UHFFFAOYSA-N
InChI=1S/C15H12F3NO4S/c1-24(21,22)12-6-9(15(16,17)18)4-5-10(12)13(20)11-7-19-23-
INCHI: 14(11)8-2-3-8/h4-8H,2-3H2,1H3
-Kresoxym methyl kresoxim-methyl krésoxime-méthyl крезоксим-метил

IUPAC: methyl (E)-methoxyimino[α-(o-tolyloxy)-o-tolyl]acetate
CAS: methyl (αE)-α-(methoxyimino)-2-[(2-methylphenoxy)methyl]benzeneacetate
REG. NO.: 143390-89-0
FORMULA: C18H19NO4
ACTIVITY: fungicides (methoxyiminoacetate strobilurin fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: krē-sǒks-ǐm mē-thīl British pronunciation

INCHIKEY: ZOTBXTZVPHCKPN-HTXNQAPBSA-N
InChI=1S/C18H19NO4/c1-13-8-4-7-11-16(13)23-12-14-9-5-6-10-15(14)17(19-22-3)18(20)21-2/
INCHI: h4-11H,12H2,1-3H3/b19-17
–Lambda-cyhalothrhrin lambda-cyhalothrin lambda-cyhalothrine лямбда-цигалотрин

reaction product comprising equal quantities of (R)-α-cyano-3-phenoxybenzyl (1S,3S)-3-[(Z)-2-
chloro-3,3,3-trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-3-
phenoxybenzyl (1R,3R)-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
dimethylcyclopropanecarboxylate or of
(R)-α-cyano-3-phenoxybenzyl (1S)-cis-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-[(Z)-2-chloro-
IUPAC: 3,3,3-trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate
CAS: (R)-cyano(3-phenoxyphenyl)methyl (1S,3S)-rel-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-
2,2-dimethylcyclopropanecarboxylate
REG. NO.: 91465-08-6
FORMULA: C23H19ClF3NO3
NOTES: The unresolved isomeric mixture of this substance has the ISO common name cyhalothrin.
STRUCTURE:
PRONUNCIATION: lǎm-da sī-hǎl-ō-thrǐn British pronunciation

BFPGVJIMBRLFIR-GUCBCRIZSA-N
INCHIKEY: ZXQYGBMAQZUVMI-UHFFFAOYSA-N
InChI=1S/2C23H19ClF3NO3/c2*1-22(2)17(12-19(24)23(25,26)27)20(22)21(29)31-18(13-28)14-
7-6-10-16(11-14)30-15-8-4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/b2*19-12-/t2*17-,18+,20-/
INCHI: m10/s1
-Laminarin Nodulation, which is considered the predominant defense reaction to infection in insects, is a
complex process influenced by various endogenous factors. However, the precise mechanisms underlying
nodulation remain largely unknown. In the present study, we examined the influence of the insect hormones 20-
hydroxyecdysone (20E) and juvenile hormone (JH) on
the laminarin-induced nodulation reaction in larvae of the flesh fly Neobellieria bullata. Treating third-instar
larvae of N. bullata with 20E prior to laminarin injection enhanced the nodulation response in a dose-dependent
manner. The ecdysone agonists RH2485, RH5849 and RH0345 similarly enhanced the nodulation reaction,
although they were less active than 20E. In contrast to ecdysone stimulation, supplying larvae with JH or the
juvenile hormone analogs (JHA), fenoxycarb and pyriproxyfen, significantly impaired their ability to form
nodules in response to laminarin. These findings demonstrate for the first time that 20E and JH play an
important regulatory role in the nodulation process.
–Linuron linuron linuron линурон

IUPAC: 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea
CAS: N′-(3,4-dichlorophenyl)-N-methoxy-N-methylurea
REG. NO.: 330-55-2
NOTES:
STRUCTURE:
PRONUNCIATION: lǐn-ūr-ǒn British pronunciation

INCHIKEY: XKJMBINCVNINCA-UHFFFAOYSA-N
INCHI: InChI=1S/C9H10Cl2N2O2/c1-13(15-2)9(14)12-6-3-4-7(10)8(11)5-6/h3-5H,1-2H3,(H,12,1
-
Mancozeb mancozeb mancozèbe маикозеб
IUPAC: manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt
[[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2−)-κS,κS′]manganese mixture with [[2-
CAS: [(dithiocarboxy)amino]ethyl]carbamodithioato(2−)-κS,κS′]zinc
REG. NO.: 8018-01-7
FORMULA:
ACTIVITY: fungicides (polymeric dithiocarbamate fungicides; zinc fungicides)
When this substance is used as a salt, its identity should be stated, for example mancozeb
NOTES: chloride.
STRUCTURE:
PRONUNCIATION: mǎn-kō-zěb British pronunciation

INCHIKEY:
INCHI:
–Maneb maneb manèbe манеб

IUPAC: manganese ethylenebis(dithiocarbamate) (polymeric)
CAS: [[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2−)-κS,κS′]manganese
REG. NO.: 12427-38-2
FORMULA: C4H6MnN2S4
ACTIVITY: fungicides (polymeric dithiocarbamate fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: mǎn-ěb British pronunc

–
MCPA (=2,4-MCPA) MCPA MCPA* МЦПА
IUPAC: 4-chloro-o-tolyloxyacetic acid
CAS: 2-(4-chloro-2-methylphenoxy)acetic acid
REG. NO.: 94-74-6
FORMULA: C9H9ClO3
ACTIVITY: herbicides (phenoxyacetic herbicides)
* The name 2,4-MCPA (n.m.) is also used in France.
The name “metaxon” (метаксон) was used in the former USSR.
example MCPA-butotyl [19480-43-4], MCPA-butyl [1713-12-8], MCPA-dimethylammonium [20
39-46-5], MCPA-diolamine [20405-19-0],MCPA-ethyl [2698-38-6], MCPA-2-ethylhexyl [29450-
45-1], MCPA-isobutyl [1713-11-7], MCPA-isoctyl [26544-20-7], MCPA-isopropyl [2698-40-0], M
CPA-methyl [2436-73-9], MCPA-olamine [6365-62-4], MCPA-potassium[5221-16-9], MCPA-
NOTES: sodium [3653-48-3], MCPA-trolamine [42459-68-7].
STRUCTURE:
PRONUNCIATION: ěm sē pē ā British pronunciation

INCHIKEY: WHKUVVPPKQRRBV-UHFFFAOYSA-N
INCHI: InChI=1S/C9H9ClO3/c1-6-4-7(10)2-3-8(6)13-5-9(11)12/h2-4H,5H2,1H3,(H,11,12)
–MCPB (=2,4-MCOB) MCPB MCPB* МЦПБ

IUPAC: 4-(4-chloro-o-tolyloxy)butyric acid
CAS: 4-(4-chloro-2-methylphenoxy)butanoic acid
REG. NO.: 94-81-5
FORMULA: C11H13ClO3
ACTIVITY: herbicides (phenoxybutyric herbicides)
* The name “2,4-MCPB” (n.m.) is used in France.
The name “2M-4CM” (2М-4ХМ) was used in the former USSR.
NOTES: example MCPB-ethyl [10443-70-6], MCPB-methyl [57153-18-1], MCPB-sodium [6062-26-6].
STRUCTURE:
PRONUNCIATION: ěm sē pē bē British pronunciation

INCHIKEY: LLWADFLAOKUBDR-UHFFFAOYSA-N
INCHI: InChI=1S/C11H13ClO3/c1-8-7-9(12)4-5-10(8)15-6-2-3-11(13)14/h4-5,7H,2-3,6H2,1H3,(H,13,14
-
Mecoprop mecoprop mécoprop мекопроп
IUPAC: (RS)-2-(4-chloro-o-tolyloxy)propionic acid
CAS: 2-(4-chloro-2-methylphenoxy)propanoic acid
REG. NO.: 7085-19-0
FORMULA: C10H11ClO3
ACTIVITY: herbicides (phenoxypropionic herbicides)
NOTES: When this substance is used as an ester or a salt, its identity should be stated, for
example mecoprop-dimethylammonium [32351-70-5], mecoprop-diolamine [1432-14-0], meco
prop-ethadyl, mecoprop-2-ethylhexyl [71526-69-7], mecoprop-isoctyl [28473-03-2], mecoprop-
methyl [2786-19-8], mecoprop-potassium [1929-86-8], mecoprop-sodium [19095-88-6], mecopr
op-trolamine [53404-61-8].
The name “MCPP” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
The (R)-isomer of this substance has the ISO common name mecoprop-P.
STRUCTURE:
PRONUNCIATION: měk-o-prǒp British pronunciation

INCHIKEY: WNTGYJSOUMFZEP-UHFFFAOYSA-N
INCHI: InChI=1S/C10H11ClO3/c1-6-5-8(11)3-4-9(6)14-7(2)10(12)13/h3-5,7H,1-2H3,(H,12,13)
-
Mecoprop-P mecoprop-P-2-ethylhexyl
IUPAC: (RS)-2-ethylhexyl (R)-2-(4-chloro-o-tolyloxy)propionate
CAS: 2-ethylhexyl (2R)-2-(4-chloro-2-methylphenoxy)propanoate
REG. NO.: 861229-15-4
FORMULA: C18H27ClO3
ACTIVITY: herbicides (phenoxypropionic herbicides)
This substance is a derivative of mecoprop-P [16484-77-8].
The unresolved isomeric mixture of this substance has the ISO common name mecoprop-2-
NOTES: ethylhexyl [71526-69-7].
STRUCTURE:
PRONUNCIATION: měk-o-prǒp pē too ē-thīl-hěks-īl British pronunciation

INCHIKEY: NWTKQOOQEPXMMW-GICMACPYSA-N
InChI=1S/C18H27ClO3/c1-5-7-8-15(6-2)12-21-18(20)14(4)22-17-10-9-16(19)11-13(17)3/h9-
INCHI: 11,14-15H,5-8,12H2,1-4H3/t14-,15?/m1/s1
-Mepanipyrim mepanipyrim mépanipyrime мепанипирим

IUPAC: N-(4-methyl-6-prop-1-ynylpyrimidin-2-yl)aniline
CAS: 4-methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine
REG. NO.: 110235-47-7
FORMULA: C14H13N3
NOTES:
STRUCTURE:
PRONUNCIATION: mě-pǎn-ǐ-pīr-ǐm British pronunciation

INCHIKEY: CIFWZNRJIBNXRE-UHFFFAOYSA-N
InChI=1S/C14H13N3/c1-3-7-13-10-11(2)15-14(17-13)16-12-8-5-4-6-9-12/h4-6,8-10H,1-2H3,
INCHI: (H,15,16,17)
-
Mesosulfuron mesosulfuron mésosulfuron мезосульфурон
IUPAC: 2-[(4,6-dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-α-(methanesulfonamido)-p-toluic acid
2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-4-
CAS: [[(methylsulfonyl)amino]methyl]benzoic acid
REG. NO.: 400852-66-6
FORMULA: C16H19N5O9S2
NOTES: mesosulfuron-methyl [208465-21-8].
STRUCTURE:
PRONUNCIATION: mě-sō-sǔl-fūr-ǒn British pronunciation

INCHIKEY: MAYMYMXYWIVVOK-UHFFFAOYSA-N
InChI=1S/C16H19N5O9S2/c1-29-12-7-13(30-2)19-15(18-12)20-16(24)21-32(27,28)11-6-9(8-17-
INCHI: 31(3,25)26)4-5-10(11)14(22)23/h4-7,17H,8H2,1-3H3,(H,22,23)(H2,18,19,20,21,24
–Mesothrion mesotrione mésotrione мезотрион

IUPAC: 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione
CAS: 2-[4-(methylsulfonyl)-2-nitrobenzoyl]-1,3-cyclohexanedione
REG. NO.: 104206-82-8
FORMULA: C14H13NO7S
ACTIVITY: herbicides (benzoylcyclohexanedione herbicides)
The Chinese name “甲基磺草酮” has also been used in the literature, but it has no official
NOTES: status.
STRUCTURE:
PRONUNCIATION: mě-sō-trī-ōn British pronunciation

INCHIKEY: KPUREKXXPHOJQT-UHFFFAOYSA-N
InChI=1S/C14H13NO7S/c1-23(21,22)8-5-6-9(10(7-8)15(19)20)14(18)13-11(16)3-2-4-12(13)17/
INCHI: h5-7,13H,2-4H2,1H3
-
Metalaxyl-M(=mefenoxam) metalaxyl métalaxyl металаксил
IUPAC: methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL-alaninate
CAS: methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-DL-alaninate
REG. NO.: 57837-19-1
FORMULA: C15H21NO4
ACTIVITY: fungicides (acylamino acid fungicides; anilide fungicides)
NOTES: The (−)-isomer of this substance has the ISO common name metalaxyl-M.
STRUCTURE:
PRONUNCIATION: mět-a-lǎks-ǐl British pronunciation

INCHIKEY: ZQEIXNIJLIKNTD-UHFFFAOYSA-N
InChI=1S/C15H21NO4/c1-10-7-6-8-11(2)14(10)16(13(17)9-19-4)12(3)15(18)20-5/h6-
INCHI: 8,12H,9H2,1-5H3
–Methoxyfenozide methoxyfenozide méthoxyfénozide метоксифенозид

IUPAC: N-tert-butyl-N′-(3-methoxy-o-toluoyl)-3,5-xylohydrazide
CAS: 3-methoxy-2-methylbenzoic acid 2-(3,5-dimethylbenzoyl)-2-(1,1-dimethylethyl)hydrazide
REG. NO.: 161050-58-4
FORMULA: C22H28N2O3
ACTIVITY: insecticides (moulting hormone agonists)
NOTES:
STRUCTURE:
PRONUNCIATION: měth-ǒk-sē-fěn-ō-zīd British pronunciation

INCHIKEY: QCAWEPFNJXQPAN-UHFFFAOYSA-N
InChI=1S/C22H28N2O3/c1-14-11-15(2)13-17(12-14)21(26)24(22(4,5)6)23-20(25)18-9-8-10-
INCHI: 19(27-7)16(18)3/h8-13H,1-7H3,(H,23,25)
- 1-methylcyclopropene 1-methylcyclopropene 1-méthylcyclopropène 1-метилциклопропен

STATUS: none
IUPAC: 1-methylcyclopropene
CAS: 1-methylcyclopropene
REG. NO.: 3100-04-7
FORMULA: C4H6
ACTIVITY: plant growth regulators (ethylene inhibitors)
There is no ISO common name for this substance; the name “1-methylcyclopropene” has been
used in the literature but it has no official status except as a systematic name. The names
NOTES: “MCP” and “1-MCP” have also been used in the literature, but they have no official status.
STRUCTURE:
PRONUNCIATION: wǔn mē-thīl-sī-klō-prō-pēn British pronunciation

INCHIKEY: SHDPRTQPPWIEJG-UHFFFAOYSA-N
INCHI: InChI=1S/C4H6/c1-4-2-3-4/h2H,3H2,1H3
- Metiram(+metiram-zinc) metiram métirame метирам

STATUS: JMAFF
IUPAC: zinc ammoniate ethylenebis(dithiocarbamate) - poly(ethylenethiuram disulfide)
CAS: metiram
REG. NO.: 9006-42-2
FORMULA:
ACTIVITY: fungicides (polymeric dithiocarbamate fungicides; zinc fungicides)
There is no ISO common name for this substance because it appears to be a mixture; the name
“metiram” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
The name “metiram” (代森联) is also approved in China, but is incorrectly spelled “metriam” in
GB 4839-2009 Chinese common names for pesticides.
NOTES: The name “metiram-zinc” has been used in the literature, but it has no official status.
PRONUNCIATION: mě-tī-rǎm British pronunciation
INCHIKEY:
INCHI:
-Metsulfuron methyl metsulfuron-methyl

IUPAC: methyl 2-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)benzoate
CAS: methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate
REG. NO.: 74223-64-6
This substance is a derivative of metsulfuron [79510-48-8].
NOTES: The name “甲磺隆” is approved in China for metsulfuron and for metsulfuron-methyl.
STRUCTURE:
PRONUNCIATION: mět-sǔl-fūr-ǒn mē-thīl British pronunciation

INCHIKEY: RSMUVYRMZCOLBH-UHFFFAOYSA-N
InChI=1S/C14H15N5O6S/c1-8-15-12(18-14(16-8)25-3)17-13(21)19-26(22,23)10-7-5-4-6-
INCHI: 9(10)11(20)24-2/h4-7H,1-3H3,(H2,15,16,17,18,19,21)
–Milbemectin milbemectin milbémectine милбемектин

extended von Baeyer nomenclature: mixture of 70% (10E,14E,16E)-
(1R,4S,5′S,6R,6′R,8R,13R,20R,21R,24S)-6′-ethyl-21,24-dihydroxy-5′,11,13,22-tetramethyl-
(3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene)-6-spiro-2′-
(tetrahydropyran)-2-one and 30% (10E,14E,16E)-(1R,4S,5′S,6R,6′R,8R,13R,20R,21R,24S)-21,24-
dihydroxy-5′,6′,11,13,22-pentamethyl-(3,7,19-trioxatetracyclo[15.6.1.1 4,8.020,24]pentacosa-
10,14,16,22-tetraene)-6-spiro-2′-(tetrahydropyran)-2-one or
bridged fused ring systems nomenclature: mixture of 70% (2aE,4E,8E)-
(5′S,6R,6′R,11R,13R,15S,17aR,20R,20aR,20bS)-6′-ethyl-
3′,4′,5′,6,6′,7,10,11,14,15,17a,20,20a,20b-tetradecahydro-20,20b-dihydroxy-5′,6,8,19-
tetramethylspiro[11,15-methano-2H,13H,17H-furo[4,3,2-pq][2,6]benzodioxacyclooctadecin-
13,2′-[2H]pyran]-17-one and 30% (2aE,4E,8E)-(5′S,6R,6′R,11R,13R,15S,17aR,20R,20aR,20bS)-
3′,4′,5′,6,6′,7,10,11,14,15,17a,20,20a,20b-tetradecahydro-20,20b-dihydroxy-5′,6,6′,8,19-
pentamethylspiro[11,15-methano-2H,13H,17H-furo[4,3,2-pq][2,6]benzodioxacyclooctadecin-
IUPAC: 13,2′-[2H]pyran]-17-one
(6R,25R)-5-O-demethyl-28-deoxy-6,28-epoxy-25-ethylmilbemycin B mixture with (6R,25R)-5-O-
CAS: demethyl-28-deoxy-6,28-epoxy-25-methylmilbemycin B
REG. NO.: 51596-10-2 (milbemycin A3) + 51596-11-3 (milbemycin A4)
FORMULA: C31H44O7 (milbemycin A3) + C32H46O7 (milbemycin A4)
acaricides (milbemycin acaricides)
ACTIVITY: insecticides (milbemycin insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: mǐl-bě-měk-tǐn British pronunciation

milbemycin A4 (6′-ethyl):
VOZIAWLUULBIPN-LRBNAKOISA-N
milbemycin A3 (6′-methyl):
ZLBGSRMUSVULIE-GSMJGMFJSA-N
identifier for mixture (not valid):
INCHIKEY: GYDJYANDMLXRJG-YVBHUIOZSA-N
milbemycin A4 (6′-ethyl):
InChI=1S/C32H46O7/c1-6-27-21(4)12-13-31(39-27)17-25-16-24(38-31)11-10-20(3)14-19(2)8-7-
9-23-18-36-29-28(33)22(5)15-26(30(34)37-25)32(23,29)35/h7-10,15,19,21,24-29,33,35H,6,11-
14,16-18H2,1-5H3/b8-7+,20-10+,23-9+/t19-,21-,24+,25-,26-,27+,28+,29+,31+,32+/m0/s1
milbemycin A3 (6′-methyl):
InChI=1S/C31H44O7/c1-18-7-6-8-23-17-35-28-27(32)21(4)14-26(31(23,28)34)29(33)36-25-15-
24(10-9-19(2)13-18)38-30(16-25)12-11-20(3)22(5)37-30/h6-9,14,18,20,22,24-28,32,34H,10-
INCHI: 13,15-17H2,1-5H3/b7-6+,19-9+,23-8+/t18-,20-,22+,24+,25-,26-,27+,28+,30-,31+/m0/s1
-Molinat molinate molinate молинат

S-ethyl azepane-1-carbothioate
or
S-ethyl perhydroazepine-1-carbothioate
or
IUPAC: S-ethyl perhydroazepine-1-thiocarboxylate
CAS: S-ethyl hexahydro-1H-azepine-1-carbothioate
REG. NO.: 2212-67-1
FORMULA: C9H17NOS
ACTIVITY: herbicides (thiocarbamate herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: mǒl-ǐn-āt British pronunciation

INCHIKEY: DEDOPGXGGQYYMW-UHFFFAOYSA-N
INCHI: InChI=1S/C9H17NOS/c1-2-12-9(11)10-7-5-3-4-6-8-10/h2-8H2,1H3
–Oxadiargyl Oxadiargyl oxadiargyl оксадиаргил

IUPAC: 5-tert-butyl-3-[2,4-dichloro-5-(prop-2-ynyloxy)phenyl]-1,3,4-oxadiazol-2(3H)-one
CAS: 3-[2,4-dichloro-5-(2-propynyloxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2(3H)-one
REG. NO.: 39807-15-3
ACTIVITY: herbicides (oxadiazolone herbicides)
The orthodox Chinese form “丙炔噁草酮” is used in GB 4839-2009 Chinese common names for
NOTES: pesticides, but the vulgar form “丙炔恶草酮” is also used in the literature.
STRUCTURE:
PRONUNCIATION: ǒks-a-dī-ar-jīl British pronunciation

INCHIKEY: DVOODWOZJVJKQR-UHFFFAOYSA-N
InChI=1S/C15H14Cl2N2O3/c1-5-6-21-12-8-11(9(16)7-10(12)17)19-14(20)22-13(18-
INCHI: 19)15(2,3)4/h1,7-8H,6H2,2-4H3
-Oxamyl oxamyl oxamyl оксамил

IUPAC: (EZ)-N,N-dimethyl-2-methylcarbamoyloxyimino-2-(methylthio)acetamide
CAS: methyl 2-(dimethylamino)-N-[[(methylamino)carbonyl]oxy]-2-oxoethanimidothioate
REG. NO.: 23135-22-0
FORMULA: C7H13N3O3S
acaricides (oxime carbamate acaricides)
insecticides (oxime carbamate insecticides)
ACTIVITY: nematicides (oxime carbamate nematicides)
NOTES: The name “thioxamyl” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: ǒks-a-mīl British pronunciation

INCHIKEY: KZAUOCCYDRDERY-UHFFFAOYSA-N
INCHI: InChI=1S/C7H13N3O3S/c1-8-7(12)13-9-5(14-4)6(11)10(2)3/h1-4H3,(H,8,12)
–Oxasulfuron oxasulfuron oxasulfuron оксасульфурон

IUPAC: oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate
CAS: 3-oxetanyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoate
REG. NO.: 144651-06-9
NOTES: This compound is the 3-oxetanyl ester of sulfometuron.
STRUCTURE:
PRONUNCIATION: ǒks-a-sǔl-fūr-ǒn British pronunciation

INCHIKEY: IOXAXYHXMLCCJJ-UHFFFAOYSA-N
InChI=1S/C17H18N4O6S/c1-10-7-11(2)19-16(18-10)20-17(23)21-28(24,25)14-6-4-3-5-
INCHI: 13(14)15(22)27-12-8-26-9-12/h3-7,12H,8-9H2,1-2H3,(H2,18,19,20,21,23)
-Paraquat paraquat paraquat паракват

IUPAC: 1,1′-dimethyl-4,4′-bipyridinium
CAS: 1,1′-dimethyl-4,4′-bipyridinium
REG. NO.: 4685-14-7
FORMULA: C12H14N2
ACTIVITY: herbicides (quaternary ammonium herbicides)
When this substance is used as a salt, its identity should be stated, for example paraquat
NOTES: dichloride [1910-42-5], paraquat dimetilsulfate [2074-50-2].
STRUCTURE:
PRONUNCIATION: pǎr-a-kwǒt British pronunciation

INCHIKEY: INFDPOAKFNIJBF-UHFFFAOYSA-N
INCHI: InChI=1S/C12H14N2/c1-13-7-3-11(4-8-13)12-5-9-14(2)10-6-12/h3-10H,1-2H3/q+2
–Pendimethalin pendimethalin pendiméthaline пендиметалин

IUPAC: N-(1-ethylpropyl)-2,6-dinitro-3,4-xylidine
CAS: N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine
REG. NO.: 40487-42-1
FORMULA: C13H19N3O4
ACTIVITY: herbicides (dinitroaniline herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: pěn-dī-měth-a-lǐn British pronunciation

INCHIKEY: CHIFOSRWCNZCFN-UHFFFAOYSA-N
InChI=1S/C13H19N3O4/c1-5-10(6-2)14-12-11(15(17)18)7-8(3)9(4)13(12)16(19)20/h7,10,14H,5-
INCHI: 6H2,1-4H3
–Penthoxamid
–Phenmedipham phenmedipham phenmédiphame фенмедифам

methyl 3-(3-methylcarbaniloyloxy)carbanilate
or
IUPAC: 3-methoxycarbonylaminophenyl 3-methylcarbanilate
CAS: 3-[(methoxycarbonyl)amino]phenyl N-(3-methylphenyl)carbamate
REG. NO.: 13684-63-4
FORMULA: C16H16N2O4
ACTIVITY: herbicides (carbanilate herbicides)
NOTES: The analogous ethyl ester has the ISO common name phenmedipham-ethyl.
STRUCTURE:
PRONUNCIATION: fěn-měd-ǐ-fǎm British pronunciation

INCHIKEY: IDOWTHOLJBTAFI-UHFFFAOYSA-N
InChI=1S/C16H16N2O4/c1-11-5-3-6-12(9-11)18-16(20)22-14-8-4-7-13(10-14)17-15(19)21-2/h3-
INCHI: 10H,1-2H3,(H,17,19)(H,18,20)
–Phosphat feric
-Picolinafen picolinafen picolinafène пиколинафен

IUPAC: 4′-fluoro-6-(α,α,α-trifluoro-m-tolyloxy)pyridine-2-carboxanilide
CAS: N-(4-fluorophenyl)-6-[3-(trifluoromethyl)phenoxy]-2-pyridinecarboxamide
REG. NO.: 137641-05-5
FORMULA: C19H12F4N2O2
ACTIVITY: herbicides (anilide herbicides; pyridine herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: pǐ-kō-lǐn-a-fěn British pronunciation

INCHIKEY: CWKFPEBMTGKLKX-UHFFFAOYSA-N
InChI=1S/C19H12F4N2O2/c20-13-7-9-14(10-8-13)24-18(26)16-5-2-6-17(25-16)27-15-4-1-3-
INCHI: 12(11-15)19(21,22)23/h1-11H,(H,24,26)
-Picoxystrobin picoxystrobin picoxystrobine пикоксистробин

IUPAC: methyl (2E)-3-methoxy-2-{2-[6-(trifluoromethyl)-2-pyridyloxymethyl]phenyl}acrylate
methyl (αE)-α-(methoxymethylene)-2-[[[6-(trifluoromethyl)-2-
CAS: pyridinyl]oxy]methyl]benzeneacetate
REG. NO.: 117428-22-5
ACTIVITY: fungicides (methoxyacrylate strobilurin fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: pǐk-ǒks-ē-strō-bǐn British pronunciation

INCHIKEY: IBSNKSODLGJUMQ-SDNWHVSQSA-N
InChI=1S/C18H16F3NO4/c1-24-11-14(17(23)25-2)13-7-4-3-6-12(13)10-26-16-9-5-8-15(22-
INCHI: 16)18(19,20)21/h3-9,11H,10H2,1-2H3/b14-11+
–Pirimicarb pirimicarb pirimicarbe* пиримикарб

IUPAC: 2-dimethylamino-5,6-dimethylpyrimidin-4-yl dimethylcarbamate
CAS: 2-(dimethylamino)-5,6-dimethyl-4-pyrimidinyl N,N-dimethylcarbamate
REG. NO.: 23103-98-2
FORMULA: C11H18N4O2
ACTIVITY: insecticides (dimethylcarbamate insecticides)
* According to ISO 1750, the name “pyrimicarbe” (n.m.) is used in France, but the ISO common
NOTES: name “pirimicarbe” (n.m.) also appears to be used.
STRUCTURE:
PRONUNCIATION: pǐ-rǐm-ǐ-karb British pronunciation

INCHIKEY: YFGYUFNIOHWBOB-UHFFFAOYSA-N
INCHI: InChI=1S/C11H18N4O2/c1-7-8(2)12-10(14(3)4)13-9(7)17-11(16)15(5)6/h1-6H3
Prohexadion-calciu prohexadione prohexadione прогексадион

IUPAC: 3,5-dioxo-4-propionylcyclohexanecarboxylic acid
CAS: 3,5-dioxo-4-(1-oxopropyl)cyclohexanecarboxylic acid
REG. NO.: 88805-35-0
FORMULA: C10H12O5
example prohexadione-calcium [127277-53-6].
NOTES: The name “调环酸” is approved in China for prohexadione and for prohexadione-calcium.
STRUCTURE:
PRONUNCIATION: prō-hěks-a-dī-ōn British pronunciation

INCHIKEY: BUCOQPHDYUOJSI-UHFFFAOYSA-N
INCHI: InChI=1S/C10H12O5/c1-2-6(11)9-7(12)3-5(10(14)15)4-8(9)13/h5,9H,2-4H2,1H3,(H,14,15)
-Propiconazol propiconazole propiconazole пропиконазол

IUPAC: (2RS,4RS;2RS,4SR)-1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole
CAS: 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole
REG. NO.: 60207-90-1
NOTES:
STRUCTURE:
PRONUNCIATION: prō-pǐ-kǒn-a-zōl British pronunciation

INCHIKEY: STJLVHWMYQXCPB-UHFFFAOYSA-N
InChI=1S/C15H17Cl2N3O2/c1-2-3-12-7-21-15(22-12,8-20-10-18-9-19-20)13-5-4-11(16)6-
INCHI: 14(13)17/h4-6,9-10,12H,2-3,7-8H2,1H3
-Propoxycarbazon (propoxycarbazon de sodium) propoxycarbazone propoxycarbazone пропоксикарбазон

methyl 2-[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazole-1-
IUPAC: carboxamido)sulfonyl]benzoate
methyl 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-
CAS: yl)carbonyl]amino]sulfonyl]benzoate
REG. NO.: 145026-81-9
ACTIVITY: herbicides (triazolone herbicides)
When this substance is used as a salt, its identity should be stated, for
NOTES: example propoxycarbazone-sodium [181274-15-7].
STRUCTURE:
PRONUNCIATION: prō-pǒk-sē-karb-a-zōn British pronunciation

INCHIKEY: JTHMVYBOQLDDIY-UHFFFAOYSA-N
InChI=1S/C15H18N4O7S/c1-4-9-26-14-16-19(15(22)18(14)2)13(21)17-27(23,24)11-8-6-5-7-
INCHI: 10(11)12(20)25-3/h5-8H,4,9H2,1-3H3,(H,17,21)
-Propyzamid propyzamide propyzamide проризамид

IUPAC: 3,5-dichloro-N-(1,1-dimethylprop-2-ynyl)benzamide
CAS: 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)benzamide
REG. NO.: 23950-58-5
FORMULA: C12H11Cl2NO
ACTIVITY: herbicides (amide herbicides)
NOTES: The name “pronamide” is approved by the Weed Science Society of America.
STRUCTURE:
PRONUNCIATION: prō-pīz-a-mīd British pronunciation

INCHIKEY: PHNUZKMIPFFYSO-UHFFFAOYSA-N
INCHI: InChI=1S/C12H11Cl2NO/c1-4-12(2,3)15-11(16)8-5-9(13)7-10(14)6-8/h1,5-7H,2-3H3,(H,15,16)
–
Prosulfuron prosulfuron prosulfuron просульфурон
STATUS:
IUPAC: 1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-3-[2-(3,3,3-trifluoropropyl)phenylsulfonyl]urea
N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]-2-(3,3,3-
CAS: trifluoropropyl)benzenesulfonamide
REG. NO.: 94125-34-5
NOTES:
STRUCTURE:
PRONUNCIATION: prō-sǔl-fūr-ǒn Guide to British pronunciation

INCHIKEY: LTUNNEGNEKBSEH-UHFFFAOYSA-N
InChI=1S/C15H16F3N5O4S/c1-9-19-12(22-14(20-9)27-2)21-13(24)23-28(25,26)11-6-4-3-5-
INCHI: 10(11)7-8-15(16,17)18/h3-6H,7-8H2,1-2H3,(H2,19,20,21,22,23,24)
–Pymetrozin pymetrozine pymétrozine пиметрозин

IUPAC: (E)-4,5-dihydro-6-methyl-4-(3-pyridylmethyleneamino)-1,2,4-triazin-3(2H)-one
CAS: 4,5-dihydro-6-methyl-4-[(E)-(3-pyridinylmethylene)amino]-1,2,4-triazin-3(2H)-one
REG. NO.: 123312-89-0
FORMULA: C10H11N5O
ACTIVITY: antifeedants
NOTES:
STRUCTURE:
PRONUNCIATION: pī-mět-tra-zēn British pronunciation

INCHIKEY: QHMTXANCGGJZRX-WUXMJOGZSA-N
InChI=1S/C10H11N5O/c1-8-7-15(10(16)14-13-8)12-6-9-3-2-4-11-5-9/h2-6H,7H2,1H3,
INCHI: (H,14,16)/b12-6+
-Pyraflufen-ethyl pyraflufen-ethyl
IUPAC: ethyl [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methylpyrazol-3-yl)-4-fluorophenoxy]acetate
ethyl 2-[2-chloro-5-[4-chloro-5-(difluoromethoxy)-1-methyl-1H-pyrazol-3-yl]-4-
CAS: fluorophenoxy]acetate
REG. NO.: 129630-19-9
FORMULA: C15H13Cl2F3N2O4
ACTIVITY: herbicides (phenylpyrazole herbicides)
NOTES: This substance is a derivative of pyraflufen [129630-17-7].
STRUCTURE:
PRONUNCIATION: pīr-a-floo-fěn ē-thīl British pronunciation

INCHIKEY: APTZNLHMIGJTEW-UHFFFAOYSA-N
InChI=1S/C15H13Cl2F3N2O4/c1-3-24-11(23)6-25-10-4-7(9(18)5-8(10)16)13-12(17)14(22(2)21-
INCHI: 13)26-15(19)20/h4-5,15H,3,6H2,1-2H3
–Pyradat pyridate pyridate пиридат

IUPAC: O-6-chloro-3-phenylpyridazin-4-yl S-octyl thiocarbonate
CAS: O-(6-chloro-3-phenyl-4-pyridazinyl) S-octyl carbonothioate
REG. NO.: 55512-33-9
ACTIVITY: herbicides (pyridazine herbicides)
NOTES:
STRUCTURE:
PRONUNCIATION: pǐr-ǐ-dāt British pronunciation

INCHIKEY: JTZCTMAVMHRNTR-UHFFFAOYSA-N
InChI=1S/C19H23ClN2O2S/c1-2-3-4-5-6-10-13-25-19(23)24-16-14-17(20)21-22-18(16)15-11-8-7-
INCHI: 9-12-15/h7-9,11-12,14H,2-6,10,13H2,1H3
-Pyrimethanil pyriméthanil риметанил

IUPAC: N-(4,6-dimethylpyrimidin-2-yl)aniline
CAS: 4,6-dimethyl-N-phenyl-2-pyrimidinamine
REG. NO.: 53112-28-0
FORMULA: C12H13N3
NOTES:
STRUCTURE:
PRONUNCIATION: pǐ-rǐ-měth-a-nǐl British pronunciation

INCHIKEY: ZLIBICFPKPWGIZ-UHFFFAOYSA-N
INCHI: InChI=1S/C12H13N3/c1-9-8-10(2)14-12(13-9)15-11-6-4-3-5-7-11/h3-8H,1-2H3,(H,13,14,15)
–Quinoxyfen quinoxyfen quinoxyfène квиноксифен

IUPAC: 5,7-dichloro-4-quinolyl 4-fluorophenyl ether
CAS: 5,7-dichloro-4-(4-fluorophenoxy)quinoline
REG. NO.: 124495-18-7
FORMULA: C15H8Cl2FNO
ACTIVITY: fungicides (quinoline fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: kwǐn-ǒk-sē-fěn British pronunciation

INCHIKEY: WRPIRSINYZBGPK-UHFFFAOYSA-N
INCHI: InChI=1S/C15H8Cl2FNO/c16-9-7-12(17)15-13(8-9)19-6-5-14(15)20-11-3-1-10(18)2-4-11/h1-8H
–Rimsulfuron rimsulfuron rimsulfuron римсульфурон

IUPAC: 1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)urea
CAS: N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(ethylsulfonyl)-2-pyridinesulfonamide
REG. NO.: 122931-48-0
NOTES: The name “renriduron” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: rǐm-sǔl-fūr-ǒn British pronunciation

INCHIKEY: MEFOUWRMVYJCQC-UHFFFAOYSA-N
InChI=1S/C14H17N5O7S2/c1-4-27(21,22)9-6-5-7-15-12(9)28(23,24)19-14(20)18-13-16-10(25-
INCHI: 2)8-11(17-13)26-3/h5-8H,4H2,1-3H3,(H2,16,17,18,19,20)
–Silthiofam silthiofam silthiofam силтиофам

IUPAC: N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide
CAS: 4,5-dimethyl-N-2-propenyl-2-(trimethylsilyl)-3-thiophenecarboxamide
REG. NO.: 175217-20-6
FORMULA: C13H21NOSSi
ACTIVITY: fungicides (amide fungicides; thiophene fungicides)
The name “silthiophan” (硅噻菌胺) is approved in China.
NOTES: The name “silthiopham” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: sǐl-thī-ō-fǎm British pronunciation

INCHIKEY: MXMXHPPIGKYTAR-UHFFFAOYSA-N
InChI=1S/C13H21NOSSi/c1-7-8-14-12(15)11-9(2)10(3)16-13(11)17(4,5)6/h7H,1,8H2,2-6H3,
INCHI: (H,14,15)
–S-metolachlore S-metolachlor S-métolachlore С-метолахлор

mixture of 80–100% 2-chloro-N-(6-ethyl-o-tolyl)-N-[(1S)-2-methoxy-1-methylethyl]acetamide
and 20–0% 2-chloro-N-(6-ethyl-o-tolyl)-N-[(1R)-2-methoxy-1-methylethyl]acetamide
or
mixture of 80–100% 2-chloro-6′-ethyl-N-[(1S)-2-methoxy-1-methylethyl]acet-o-toluidide and
IUPAC: 20–0% 2-chloro-6′-ethyl-N-[(1R)-2-methoxy-1-methylethyl]acet-o-toluidide
CAS: 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(1S)-2-methoxy-1-methylethyl]acetamide
REG. NO.: 87392-12-9
ACTIVITY: herbicides (chloroacetanilide herbicides)
NOTES: The unresolved substance has the ISO common name metolachlor.
STRUCTURE:
PRONUNCIATION: ěs mě-tǒl-a-klor British pronunciation

INCHIKEY: WVQBLGZPHOPPFO-LBPRGKRZSA-N
InChI=1S/C15H22ClNO2/c1-5-13-8-6-7-11(2)15(13)17(14(18)9-16)12(3)10-19-4/h6-8,12H,5,9-
INCHI: 10H2,1-4H3/t12-/m0/s1
-Spiroxamin spiroxamine spiroxamine спироксамин

IUPAC: 8-tert-butyl-1,4-dioxaspiro[4.5]decan-2-ylmethyl(ethyl)(propyl)amine
CAS: 8-(1,1-dimethylethyl)-N-ethyl-N-propyl-1,4-dioxaspiro[4.5]decane-2-methanamine
REG. NO.: 118134-30-8
FORMULA: C18H35NO2
ACTIVITY: fungicides (unclassified fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: spīr-ǒks-a-mēn Guide to British pronunciation

INCHIKEY: PUYXTUJWRLOUCW-UHFFFAOYSA-N
InChI=1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-
INCHI: 16H,6-14H2,1-5H3
-Sulfosulfuron sulfosulfuron sulfosulfuron сульфосульфурон

IUPAC: 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-ylsulfonyl)urea
N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-2-(ethylsulfonyl)imidazo[1,2-a]pyridine-3-
CAS: sulfonamide
REG. NO.: 141776-32-1
NOTES:
STRUCTURE:
PRONUNCIATION: sǔl-fō-sǔl-fūr-ǒn British pronunciation

INCHIKEY: RBSXHDIPCIWOMG-UHFFFAOYSA-N
InChI=1S/C16H18N6O7S2/c1-4-30(24,25)13-14(22-8-6-5-7-10(22)17-13)31(26,27)21-16(23)20-
INCHI: 15-18-11(28-2)9-12(19-15)29-3/h5-9H,4H2,1-3H3,(H2,18,19,20,21,23)
–Tepraloxydim tepraloxydim tépraloxydime тепралоксидим

(5RS)-2-{(EZ)-1-[(2E)-3-chloroallyloxyimino]propyl}-3-hydroxy-5-perhydropyran-4-ylcyclohex-2-
IUPAC: en-1-one
2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-
CAS: cyclohexen-1-one
REG. NO.: 149979-41-9
ACTIVITY: herbicides (cyclohexene oxime herbicides)
The name “tepraloxydim” (吡喃草酮) is approved in China, but is incorrectly spelled
NOTES: “teproloxydim” in GB 4839-2009 Chinese common names for pesticides.
STRUCTURE:
PRONUNCIATION: tě-prǎl-ǒk-sē-dǐm British pronunciation

INCHIKEY: IOYNQIMAUDJVEI-ZFNPBRLTSA-N
InChI=1S/C17H24ClNO4/c1-2-14(19-23-7-3-6-18)17-15(20)10-13(11-16(17)21)12-4-8-22-9-5-
INCHI: 12/h3,6,12-13,20H,2,4-5,7-11H2,1H3/b6-3+,19-14?
–Thiabendazol thiabendazole thiabendazole тиабендазол

2-(thiazol-4-yl)benzimidazole
or
IUPAC: 2-(1,3-thiazol-4-yl)benzimidazole
CAS: 2-(4-thiazolyl)-1H-benzimidazole
REG. NO.: 148-79-8
FORMULA: C10H7N3S
ACTIVITY: fungicides (benzimidazole fungicides; thiazole fungicides)
The name “tiabendazole” is approved by the World Health Organization; the Chinese version is
“噻苯达唑” and the Russian version is “тиабендазол”.
NOTES: The name “TBZ” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: thī-a-běn-da-zōl British pronunciation

INCHIKEY: WJCNZQLZVWNLKY-UHFFFAOYSA-N
INCHI: InChI=1S/C10H7N3S/c1-2-4-8-7(3-1)12-10(13-8)9-5-14-6-11-9/h1-6H,(H,12,13)
- Thiacloprid thiacloprid thiaclopride тиаклоприд

IUPAC: (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide
CAS: (Z)-[3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide
REG. NO.: 111988-49-9
FORMULA: C10H9ClN4S
insecticides (pyridylmethylamine nicotinoid insecticides; thiazolidine insecticides)
ACTIVITY: molluscicides
NOTES:
STRUCTURE:
PRONUNCIATION: thī-a-klō-prǐd Guide to British pronunciation

INCHIKEY: HOKKPVIRMVDYPB-UVTDQMKNSA-N
INCHI: InChI=1S/C10H9ClN4S/c11-9-2-1-8(5-13-9)6-15-3-4-16-10(15)14-7-12/h1-2,5H,3-4,6H2/b14-10-
-Thifensulfuron-methyl thifensulfuron-methyl
IUPAC: methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate
methyl 3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-2-
CAS: thiophenecarboxylate
REG. NO.: 79277-27-3
NOTES: This substance is a derivative of thifensulfuron [79277-67-1].
The name “噻吩磺隆” is approved in China for thifensulfuron and for thifensulfuron-methyl.
The name “thiameturon-methyl” was formerly approved by the Weed Science Society of
America.
STRUCTURE:
PRONUNCIATION: thī-fěn-sǔl-fūr-ǒn mē-thīl British pronunciation

INCHIKEY: AHTPATJNIAFOLR-UHFFFAOYSA-N
InChI=1S/C12H13N5O6S2/c1-6-13-10(16-12(14-6)23-3)15-11(19)17-25(20,21)7-4-5-24-
INCHI: 8(7)9(18)22-2/h4-5H,1-3H3,(H2,13,14,15,16,17,19)
-Thiophanat-methyl thiram thirame тирам

tetramethylthiuram disulfide
or
IUPAC: bis(dimethylthiocarbamoyl) disulfide
CAS: tetramethylthioperoxydicarbonic diamide ([[(CH 3)2N]C(S)]2S2)
REG. NO.: 137-26-8
FORMULA: C6H12N2S4
bird repellents
ACTIVITY: fungicides (dithiocarbamate fungicides)
The name “thiuram” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries,
NOTES: and the name “TMTD” (ТМТД) was used in the former USSR.
STRUCTURE:
PRONUNCIATION: thī-rǎm British pronunciation

INCHIKEY: KUAZQDVKQLNFPE-UHFFFAOYSA-N
INCHI: InChI=1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3
–Thiram thiram thirame тирам

tetramethylthiuram disulfide
or
IUPAC: bis(dimethylthiocarbamoyl) disulfide
CAS: tetramethylthioperoxydicarbonic diamide ([[(CH 3)2N]C(S)]2S2)
REG. NO.: 137-26-8
FORMULA: C6H12N2S4
bird repellents
ACTIVITY: fungicides (dithiocarbamate fungicides)
NOTES: The name “thiuram” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries,
and the name “TMTD” (ТМТД) was used in the former USSR.
STRUCTURE:
PRONUNCIATION: thī-rǎm British pronunciation

INCHIKEY: KUAZQDVKQLNFPE-UHFFFAOYSA-N
INCHI: InChI=1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3
-Tolclofos-methyl tolclofos-methyl tolclofos-méthyl толклофос-метил

IUPAC: O-2,6-dichloro-p-tolyl O,O-dimethyl phosphorothioate
CAS: O-(2,6-dichloro-4-methylphenyl) O,O-dimethyl phosphorothioate
REG. NO.: 57018-04-9
FORMULA: C9H11Cl2O3PS
ACTIVITY: fungicides (organophosphorus fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: tǒl-klō-fǒs mē-thīl British pronunciation

INCHIKEY: OBZIQQJJIKNWNO-UHFFFAOYSA-N
INCHI: InChI=1S/C9H11Cl2O3PS/c1-6-4-7(10)9(8(11)5-6)14-15(16,12-2)13-3/h4-5H,1-3H3
–Tolylfluanid tolylfluanid tolylfluanide толилфлуанид

IUPAC: N-dichlorofluoromethylthio-N′,N′-dimethyl-N-p-tolylsulfamide
CAS: 1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)methanesulfenamide
REG. NO.: 731-27-1
FORMULA: C10H13Cl2FN2O2S2
ACTIVITY: fungicides (phenylsulfamide fungicides)
The name “tolylfluanid” is also approved in China, but is incorrectly spelled “tolyfluanid” in GB
NOTES: 4839-2009 Chinese common names for pesticides.
STRUCTURE:
PRONUNCIATION: tǒl-īl-floo-a-nǐd British pronunciation

INCHIKEY: HYVWIQDYBVKITD-UHFFFAOYSA-N
InChI=1S/C10H13Cl2FN2O2S2/c1-8-4-6-9(7-5-8)15(18-10(11,12)13)19(16,17)14(2)3/h4-7H,1-
INCHI: 3H3
–Triasulfuron triasulfuron triasulfuron триасульфурон

IUPAC: 1-[2-(2-chloroethoxy)phenylsulfonyl]-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea
2-(2-chloroethoxy)-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-
CAS: yl)amino]carbonyl]benzenesulfonamide
REG. NO.: 82097-50-5
NOTES:
STRUCTURE:
PRONUNCIATION: trī-a-sǔl-fūr-ǒn British pronunciation

INCHIKEY: XOPFESVZMSQIKC-UHFFFAOYSA-N
InChI=1S/C14H16ClN5O5S/c1-9-16-12(19-14(17-9)24-2)18-13(21)20-26(22,23)11-6-4-3-5-
INCHI: 10(11)25-8-7-15/h3-6H,7-8H2,1-2H3,(H2,16,17,18,19,20,21)
-Tribenuron(+tribenuron-methyl) tribenuron tribénuron трибенурон

IUPAC: 2-[4-methoxy-6-methyl-1,3,5-triazin-2-yl(methyl)carbamoylsulfamoyl]benzoic acid
CAS: 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoic acid
REG. NO.: 106040-48-6
The name “metometuron” has been used in the literature, but it has no official status.
tribenuron-methyl [101200-48-0].
NOTES: The name “苯磺隆” is approved in China for tribenuron and for tribenuron-methyl.
STRUCTURE:
PRONUNCIATION: trī-běn-ūr-ǒn British pronunciation

INCHIKEY: BQZXUHDXIARLEO-UHFFFAOYSA-N
InChI=1S/C14H15N5O6S/c1-8-15-12(17-13(16-8)25-3)19(2)14(22)18-26(23,24)10-7-5-4-6-
INCHI: 9(10)11(20)21/h4-7H,1-3H3,(H,18,22)(H,20,21)
-Trifloxystrobin trifloxystrobin trifloxystrobine трифлоксистробин

IUPAC: methyl (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylideneaminooxy]-o-tolyl}acetate
methyl (αE)-α-(methoxyimino)-2-[[[[(1E)-1-[3-
CAS: (trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]benzeneacetate
REG. NO.: 141517-21-7
FORMULA: C20H19F3N2O4
ACTIVITY: fungicides (methoxyiminoacetate strobilurin fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: trī-flǒks-ē-strō-bǐn British pronunciation

INCHIKEY: ONCZDRURRATYFI-TVJDWZFNSA-N
InChI=1S/C20H19F3N2O4/c1-13(14-8-6-9-16(11-14)20(21,22)23)24-29-12-15-7-4-5-10-
INCHI: 17(15)18(25-28-3)19(26)27-2/h4-11H,12H2,1-3H3/b24-13+,25-18+
Trinexapac(+Trinexapac-ethyl) trinexapac trinéxapac тринексапак

IUPAC: (RS)-4-cyclopropyl(hydroxy)methylene-3,5-dioxocyclohexanecarboxylic acid
CAS: 4-(cyclopropylhydroxymethylene)-3,5-dioxocyclohexanecarboxylic acid
REG. NO.: 104273-73-6
FORMULA: C11H12O5
The names “cimectacarb” and “cimetacarb” have been used in the literature, but they have no
official status.
example trinexapac-ethyl [95266-40-3].
NOTES: The name “抗倒酯” is approved in China for trinexapac and for trinexapac-ethyl.
STRUCTURE:
PRONUNCIATION: trī-něks-a-pǎk British pronunciation

INCHIKEY: DFFWZNDCNBOKDI-UHFFFAOYSA-N
INCHI: InChI=1S/C11H12O5/c12-7-3-6(11(15)16)4-8(13)9(7)10(14)5-1-2-5/h5-6,14H,1-4H2,(H,15,16)
trinexapac-ethyl
IUPAC: ethyl (RS)-4-cyclopropyl(hydroxy)methylene-3,5-dioxocyclohexanecarboxylate
CAS: ethyl 4-(cyclopropylhydroxymethylene)-3,5-dioxocyclohexanecarboxylate
REG. NO.: 95266-40-3
FORMULA: C13H16O5
This substance is a derivative of trinexapac [104273-73-6].
NOTES: The name “抗倒酯” is approved in China for trinexapac and for trinexapac-ethyl.
STRUCTURE:
PRONUNCIATION: trī-něks-a-pǎk ē-thīl British pronunciation

INCHIKEY: RVKCCVTVZORVGD-UHFFFAOYSA-N
INCHI: InChI=1S/C13H16O5/c1-2-18-13(17)8-5-9(14)11(10(15)6-8)12(16)7-3-4-7/h7-8,16H,2-6H2,1H3
–Triticonazol triticonazole triticonazole тритиконазол

IUPAC: (RS)-(E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol
CAS: (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol
REG. NO.: 131983-72-7
NOTES:
STRUCTURE:
PRONUNCIATION: trī-tǐ-kǒn-a-zōl British pronunciation

INCHIKEY: PPDBOQMNKNNODG-NTEUORMPSA-N
InChI=1S/C17H20ClN3O/c1-16(2)8-7-14(9-13-3-5-15(18)6-4-13)17(16,22)10-21-12-19-11-20-
INCHI: 21/h3-6,9,11-12,22H,7-8,10H2,1-2H3/b14-9+
–Ziram ziram zirame цирам
IUPAC: zinc bis(dimethyldithiocarbamate)
CAS: (T-4)-bis(dimethylcarbamodithioato-κS,κS′)zinc
REG. NO.: 137-30-4
FORMULA: C6H12N2S4Zn
bird repellents
fungicides (dithiocarbamate fungicides; zinc fungicides)
ACTIVITY: mammal repellents
NOTES:
STRUCTURE:
PRONUNCIATION: zī-rǎm British pronunciation

INCHIKEY: DUBNHZYBDBBJHD-UHFFFAOYSA-L
INCHI: InChI=1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2
-
Zoxamid zoxamide zoxamide зоксамид
IUPAC: (RS)-3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-p-toluamide
CAS: 3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-4-methylbenzamide
REG. NO.: 156052-68-5
ACTIVITY: fungicides (benzamide fungicides)
NOTES:
STRUCTURE:
PRONUNCIATION: zǒks-a-mīd British pronunciation

INCHIKEY: SOUGWDPPRBKJEX-UHFFFAOYSA-N
InChI=1S/C14H16Cl3NO2/c1-4-14(3,12(19)7-15)18-13(20)9-5-10(16)8(2)11(17)6-9/h5-
INCHI: 6H,4,7H2,1-3H3,(H,18,20)
E F+ F O C N T+ T XN XI
Capitolul 1. Fitofarmacia şi Ecotoxicologia produselor fitofarmaceutice (produse fitofarmaceutice , proprietăţile
fizico-chimice , chimice , toxicologice ; formulare, etichetare , ambalare , marcare )
1.1 Scurt istoric
Invaziile organismelor animale care-i devastau culturile agricole şi proviziile de hrană, l- au determinat pe
om să-le cunoască , să-le monitorizeze limitându-le acţiunile distructive şi eventual să-i anihileze înaintea
semnalării de pierderi .
Organismele animale şi vegetale care intervin direct sau indirect în economia agroecosistemului determinând
pierderi calitative şi cantitative vegetalelor şi produselor agroalimentare sunt : dăunători [inamici animali ] ,
agenţi patogeni [microorganisme parazite ] şi buruieni [vegetale concurente, parazite].
În India se combăteau gărgăriţele care consumau boabele depozitate (2000 I Ch). Chinezii utilizau piretru
natural pentru combaterea insectelor sociale (1700 I Ch). În Grecia antică Aristotel ( 384 I Ch) menţionează
sulful ca fumigen la insecte. Scriitorul roman Pliniu menţionează distugerea insectelor sinantrope cu arsen.
Italianul Quintini în anul 1690 a extras din tutun nicotina , un alcaloid natural cu proprietăţi insecticide.
Abbe Roger Schabol în anul 1790 aplicând spumă de săpun pe frunzele plantei a observat bolile şi dăunătorii
care nu se mai instalau o vreme pe ” frunzele săpunite” . Elveţianul Prevost a tratat sămânţa de grâu cu
produse cuprice (1812) pentru combaterea mălurii la grâu. În anul 1824 englezul Herbst a folosit sulful pentru
combaterea făinării piersicului. Millardet (1885) a combătut mana viţei de vie stropind cu zeama bordeleză
reducând pierderile de struguri în Franţa . Fullant a folosit formalina pentru dezinfecţia fungică a seminţei.
Zeama californiană cunoscută din anul 1803 s-a aplicat pe suprafeţe extinse în pomicultură după anul 1880.
Primele aparate de stropit pentru protecţia plantelor au fost construite de firma germană Holder .
Fabricarea primelor insecticide de sinteză a început în anul 1892, odată cu fabricarea dinitroortocrezolului,
DNOC şi dinitro secundar butil fenol, DNBF, cloropicrina 1907, tiocianaţii, 1932, fenotiazina 1934.
Müller (1939) au descoperit că dimetil-difenil-triclor-etan, DDT (Zeidler,1874) are proprietăţi insecticide,
combătând vectorii tifosului exantematic (păduchii de corp). Insecticidele organoclorurate mai cunoscute au
fost:HCH(1825, Faraday), Tiodan, Heptaclor, Aldrin, Dieldrin, Toxafen, Endosulfan, Duplitox, Lindan, Hexacloran,
Clordan, Izodrin,Telodrin, Alodan, Stroban…
În1941 Schrader în Germania a sintetizat primul insecticid organofosforic TEPP (tetra-etil-pirofosfat) , care a
generat o nouă grupă chimică de produse fitofarmaceutice. Dintre substanţele organofosforice menţionăm:
parathion 1944, dimetoat 1951, malation1952, diazinon1953, azinfosmetil 1955, fenitrotion 1960 , fosmet1961,
clorfenvinfos 1962, fosalon 1963, metidation 1965, temefos 1965, clorpirifos-etil 1965, clorpirifos-metil 1966,
fenamifos1967, foxim1968, pirimifos-metil 1970,
În anul 1951 apare primul produs carbamic, cu efect nematocid-fungicid ” metam-sodiu”. Primul insecticid
carbamic carbaril a apărut în Franţa în anul 1957. Alte substanţe carbamice sunt propoxur 1959, metiocarb
1962 , carbofuran 1965, formetanat 1968, pirimicarb 1969, benfuracarb 1971, tiodicarb 1977 .
1.2 FITOFARMACIE , ECOTOXICOLOGIE ŞI RAŢIONALIZAREA TRATAMENTELOR
Fitiatria şi Fitofarmacia au fost incluse timp îndelungat în cursurile de Entomologie şi Fitopatologie .

Fitiatria are următoare semantică :paleogrecismele phyton-plantă şi yatron-suferinţă.
Fitofarmacia are etimologia:phyton-planta şi pharmacon-medicament, remediu, panaceu pentru protecţia
vegetalelor şi a produselor agroalimentare nemanufacturate.
Fitofarmacia studiază produsele fitofarmaceutice ( fizico-chimic, toxicologic, ecotoxicologic, modul de acţiune,
câmpul de activitate, eficacitate, selectivitate, compatibilitate, LMA, … ). În biosisteme produsele fitosanitare
suferă modificări diverse fizico-chimice, care diminuează eficacitatea, simptome de fitotoxicitate, schimbarea
raportului dintre specii, reducerea biodiversităţii, modificarea dominanţei…
Principalele obiective ale fitofarmaciei:
-cunoaşterea substanţelor fitofarmaceutice active avizate pentru utilizare în protecţia ecosistemelor din UE;
-cunoaşterea ingredientelor utilizate la formularea produselor fitofarmaceutice utilizate în UE ;
-cunoaşterea terminologiei utilizate în terminologia fitofarmaceutică eurocomunitară ;
- economia produselor fitofarmaceutice şi al tratamentelor fitosanitare;
- formularea, etichetarea, ambalarea şi utilizarea produselor fitosanitare ;
-reciclarea ambalajelor şi a produselor fitofarmaceutice inutilizabile.
1.3. TERMINOLOGIE FITOFARMACEUTICĂ EUROCOMUNITARĂ
Produs fitofarmaceutic-substanta activa sau formulata pentru :

a)protejarea vegetalelor sau produselor vegetale de organismele daunatoare, inclusiv prevenirea actiunea lor
b)dirijarea proceselor vitale la vegetale(hranire;crestere;fructificare; coacere)
c) franeaza si previne cresterea indezirabila a vegetalelor printr-o actiune chimica sau biologica;
d)distruge vegetalele indezirabile sau parti ale vegetalelor;
e)conservarea vegetalelor cu exceptia substantelor conservate speciale avizate; Termenul” produs
fitofarmaceutic” este sinonim cu” produs fitosanitar” , ”produs agrofarmaceutic” .Este preferat termenului
anterior ” pesticid”.
Produs biologic-substanta organica vegetala sau animala,biopreparat,organisme vii ,principii active ale
metabolismului lor utilizate in combaterea organismelor daunatoare vegetalelor.Sunt incluse si toxinele,suse
hipovirulente,antagonisti. Termenul “produs biologic” este preferat termenului “ biopesticid”.
Produs biocid - substanta sau preparat destinat combaterii organismelor daunatoare prin actiune chimica
sau biologica. Cuprinde insecticide de uz casnic si domestic , produse pentru tratamente la adaposturile de
animale domestic , mijloace de transport animale si hrana pentru animale .
Substanta activa –substanta sau microorganism (inclusive virusuri) care exercita o actiune generala ori
specifica asupra organismelor daunatoare , vegetalelor ori produselor vegetale. In cazul substantelor chimice
“substanta activa “se poate inlocui cu “ materie activa”.
Formulant-substanta sau preparat fara activitate biologica proprie inclusa la formularea unui preparat
fitofarmaceutic sau biocid, conferindu-le proprietatile necesare la utilizarea in practica.” Formulant
=coformulant,diferit de adjuvant.
Adjuvant-substanta sau preparat fara activitate biologica cunoscuta suficient in practica, dar care modifica
proprietatile fizice ,chimice sau biologice ale unui produs fitofarmaceutic facilitand amestecul instant in
momentul prepararii unui fluid fitosanitar (zeama de stropit). .Adjuvantul nu se confunda cu formulantul.
Fluid fitosanitar - amestec apos de produse fitofarmaceutice (solid , pasta , gel , relichid ,concentrat emulsionabil
, suspensie ..),cu adjuvanti ,aplicare prin udare,pulverizare ,umectare ,imbaiere.Fluid fitosanitar ~ zeama de
stropit. Camp de
activitate al unui produs fitofarmaceutic – sortimentul de daunatori , agenti patogeni , buruieni combatut .
Camp de activitate~spectru de eficacitate . Concentratia
de utilizare a produsului fitofarmaceutic-cantitatea (masa,volum) de produs fitofarmaceutic sau substanta
activa continuta in unitatea de volum de fluid fitosanitar .Pentru a
evita orice neclaritate: se exprima in kilograme sau litri de produs fitofarmaceutic in unitatea de volum de fluid
fitosanitar sau in grame de substanta active in unitatea de fluid fitosanitar.
Concentratia procentuala de utilizare- cantitatea de produs fitosanitar sau substanta activa continuta in 100
unitati (de volum,masa) de fluid fitosanitar Concentratia procentuala :substanta activa ( c% s.a.);produs
fitofarmaceutic(c%).
Concentratia produsului fitofarmaceutic –cantitatea de substanta activa continuta in kilogramul sau litrul de
produs fitofarmaceutic formulat.
Concentratia letala(CL)-concentratia de substanta activa din mediu , regim alimentar care produce,induce
moartea animalelor de laborator expuse.Concentratia letala se exprima in miligrame,micrograme pe unitatea
volum (apa , aer ) sau masa(sol,hrana).
Concentratia de inhibitie(CI)-concentratia de substanta activa din mediu , regim nutritional care produce
inhibitia microorganismelor, vegetalelor expuse actiunii .
Concentratia eficace(CE)- concentratia de substanta activa din mediu ,regim alimentar care produce efecte
(biologice,toxice) la organismele expuse actiunii.
CE,CI cuantifica alte efecte toxice sau biologice asupra organismelor [specii vegetale sau microorganisme (alge,
bacterii,riketsii,ciuperci)] expuse.
Concentratia fara efect(CFE)-concentratia maxima de substanta din regimul alimentar,mediu care nu produce
efecte toxice la animalele de laborator expuse. . Concentratia fara efect observabil (CFEO) ;
Concentratia fara efect observabil (CFENO ).
Doza (D)de utilizare - cantitatea ( masa , volum) de produs fitofarmaceutic sau substanta active administrata
pe unitate de tratament [ suprafata ( ha; m2) ,volum ( l ;hl ;m3..) ,masa ( Kg ;q ; t ), locatie(loc),
Doza de substanta activa se exprima in grame /unitate de tratament.
Doza de produs fitofarmaceutic se exprima in Kg , l / unitatea de tratament .
Doza de produs fitofarmaceutic se expliciteaza : [Kg / ha],[ g / m 2],[ Kg/ m3] , [ g / hl],[g / l], [Kg / t] ,[ g / q] ,[
g / Kg], [ l / ha],[ ml / m2],[ l / t],[ ml / Kg]
Doza de produs fitofarmaceutic formulat(l/ha;Kg/ha) =Doza de substanta activa
(g/ha) /concentratia ( substanta activa) produsului fitofarmaceutic( g / l ;g /Kg )
Doza letala,DL-cantitatea de substanta activa ce se administreaza animalelor de laborator cauzandu-le
moartea . Dintre doze DL50 prezinta mare importanta pentru toxicologie , ecotoxicologie , securitatea muncii si
protectia mediului. Doza letala cincizeci –cantitatea de substanta activa ( mg / Kg ) aplicata oral in doza unica
la sobolanii albi-Rattus norvegicus f. albino,masculi si female, de o zi nehraniti , antreneaza moartea a 50% din
efectivul testat, in perioada de 14 zile de observatii , la 3 ore dupa ingerarea produsului sunt hranite normal.
Doza fara efect- cantitatea maxima de substanta activa care este absorbita zilnic de animalele de laborator
fara sa le determine efecte toxice observabile .
DFE ,doza fara efect: -DFEO,doza fara efect observabil
- DFEN,doza fara efect nefast observabil
DZA, doza zilnica admisibila-cantitatea de substanta activa ce poate fi absorbita de om in cursul vietii , fara sa-
i produca efecte observabile pentru sanatate. DZA=DFE+Cs DFE-doza fara efect; Cs-coeficienti
securitate > 100 Cs ~ functie de riscul necunoscut ,dar nu mai mici de 100.DZA-mg /Kg /zi
Norma de stropit [ N]–cantitatea de fluid fitosanitar aplicata la hectar pentru a realiza eficacitatea scontata
prin tratament. N [ l/ha],[Kg/ha] ;Norma de stropit este sinonima cu norma de aplicare la culturile de camp .
N [l/ha] =600* Q / L* v ;Q-debitul masinii,utilajului [l /min;L-latimea de lucru a masinii ;
v –viteza de deplare a masinii [Km / h].
Timpul de pauza [Tp ]–durata minima de timp derulata de la administrarea ultimului tratament pana la
recoltare. Tp[zile] pe produs fitofarmaceutic si cultura se autorizeaza.
Timpul de soc [Ts]-timpul masurat de la administrarea unui tratament pana la aparitia efectului de knock-down.
Ts50 - timpul masurat de la administrarea unui tratament pana la aparitia efectului de knock-down la 50% din
efectivul supus actiunii toxicului. Ts este important in combaterea insectelor bune zburatoare migratoare pe
distante mari si la cele generatoare de disconfort[muste,tantari].
Timpul de expunere[T e] , expozitie,-timpul in care un organism supus unui tratament poate fi inactivat ,inhibat ,
anihilat .T e este important in cazul gazarii organismelor daunatoare la produsele depozitate, DDD la diverse
spatii inchise . Produsul fitosanitar indiferent de formulare actioneaza ca gaz toxic ,cu mare putere de penetrare
in sistemul respirator ,unde altereaza functia sau functiile vitale efemer sau definitive , antrenandu-i in final
moartea.
Timp de injumatatire [Ti]-timpul in care substanta activa aplicata se transforma in proportie de 50% intr- una
sau mai multe substante mai simple sau se disipa. Ti 50 difera de la cateva ore(DDVP) pana la zeci de
ani(cloroderivate:DDT….).
Autorizatia de punere pe piata [ APP] –actul eliberat de autoritatea competenta de stat membru UE , care
legalizeaza punerea pe piata (comercializarea) a unui produs fitofarmaceutic avizat , pe durata maxima de 10
ani,reinnoibila .
Autorizatie provizorie de punere pe piata [APPP ] actul eliberat de autoritatea competenta de stat
membruUE ,uneori are durata maxima de 3 ani ,reinnoibila .
~[BPA],bunele practici agricole- ansamblu de reguli de respectat la infiintarea si la managementul culturilor, a
modurilor de optimizare a productiilor agricole reducand riscurile pentru om si mediu, la cat e posibil, legate
de aceste practici .
[BPF],bunele practici fitofarmaceutice -ansamblu de reguli de respectat pentru asigurarea eficacitatii optime a
preparatelor fitofarmaceutice sau a altor mijloace de protectia plantelor pentru a reduce riscurile legate
utilizarea lor. Implica pritre altele : respectarea dozei,numarul de aplicari,timpului de pauza…
[BPE],bunele practice experimentale -ansamblu de reguli de respectat in modurile de realizare a incercarilor
biologice si conditiile in care aceste incercari sunt planificate,realizate ,controlate,inregistrate si exploatate in
vederea obtinerii de date comparabile si de calitate.
[BPL], bunele practici de laborator -ansamblu de proceduri raportate la la modul de organizare a studiilor de
laborator si conditiile in care aceste studii sunt planificate ,realizate,controlate,inregistrate si raportate.
Procedurile se refera la incercari in camp,sera,in particular pentru studii de reziduuri.
Persistenta - durata, in timpul careia reziduurile unui produs fitofarmaceutic sunt detectabile cu aparatura
existenta. Persistenta actiunii-durata actiunii in care un produs fitofarmaceutic protejeaza fitosanitar prin
actiunea biologica a substantei fitofarmaceutice a produsilor de degradare sau formulare .” Persistenta
actiunii” inlocuie “remanenta”.
Fitoprotector-substanta care protejeaza plantele cultivate de actiune fitotoxica a unui produs fitofarmaceutic.
Fitoprotectorii sunt inclusi la formularea, prepararea unor erbicide; Antidot
LMA-numita continut maxim in reziduuri ,concentratia maxima in reziduuri de produse fitofarmaceutice legal
fixate ,tolerate in produsele agroalimentare sau manufacturate destinate consumului uman sau hranirii
animalelor.Sin.LMR:MRL LMA se masoara mg / Kg ; ppm
Reziduu de produs fitofarmaceutic –substante susceptibile de a fi prezente in sau pe vegetale ,produse de
origine vegetala sau animala, in mediu [sol, aer,apa…]ca urmare a folosirii unui produs ,dupa terminarea
timpului de pauza. RPF -cuprinde substanta activa ,produsii de degradare sau conversie nocivi,care trebuie
analizati toxicologic si ecotoxicologic.
Rezistenta unui organism la actiunea unei substante active -[rezistenta naturala sau dobandita ] inhibarea
insesizabila sau minima a dezvoltarii unui organism daunator cand se aplica tratamente fitofarmaceutice
continand 1sau mai multe substante active.
-Rezistenta incrucisata - pozitiva sau -negativa
- Rezistenta multipla
1.4. Clasificarea substantelor si preparatele periculoase
Substantele periculoase - substante care altereaza , afecteaza stabilitatea functionalitatea si integritatea

componentelor sau intregului organism vegetal , animal sau pot fi riscante pentru mediu , componentele sale
(apa ,aer , sol). Substantele si preparatele periculoase sunt o amenintare potentiala , imediata sau de durata
pentru om ,fauna ,flora , mediu acvatic si non acvatic in timpul sau dupa manipularea , transportul ,
comercializarea , utilizarea , stocarea , inactivarea .
Directiva 99 / 45 C E clasifica substantele si preparatele periculoase in 15 categorii : explozive, foarte
inflamabile ,usor inflamabile , inflamabile , oxidanti , foarte toxice ,toxice ,nocive ,iritante, sensibilizante,
cancerogene , mutagene , toxice pentru reproducere , periculoase pentru mediu.
Produsele fitofarmaceutice se clasifica dupa proprietatile fizico-chimice in 5 categorii
explozive E,
foarte inflamabileF+,
usor inflamabile F,
oxidante O.
Produsele fitofarmaceutice se clasifica dupa proprietatile toxicologice in 6 categorii:
foarte toxice T+,
toxice T,
nocive X n ,
iritante, X i
corozive C ,
sensibilizante.
Clasificarea produselor fitofarmaceutice in categorii de toxicitate dupa DL 50 ( oral , cutanat)CL50 (aer)

Interval D L 50 oral mg/Kg DL50 cutanat mg/Kg CL50 inhalare mg/l aer
pericol Rattus norvegicus Rattus norvegicus Rattus norvegicus
formulare Lichid Solid Lichid Solid Gaz (asimilat .
Foarte toxic <25 <5 <50 <10 < 0,5 .
Toxic >25 <200 >5 <50 >50 <400 >10 <100 >0,5 <2 .
Nociv >200 <2000 >50 <500 >400 <4000 >100 <1000 >2,0 <20 .
Dupa efectele asupra sanatatii omului produsele fitosanitare se clasifica in 3 grupe
cancerogene C ,
mutagene M ,
reprotoxice R .
Pentru a prevenit nocivitatea substantelor periculoase se utilizeaza simboluri , pictograme , fraze de risc si
sfaturi de prudenta . Simbolul pentru marcarea proprietatilor periculoase majore este prima litera din
denumirea internationala a clasei ,a grupei de periculozitate ,de regula. Semnul conventional specific reda grafic
inteligibil , pericolul major esential pentru substanta sau preparatul fitofarmaceutic .
Fraza de risc exprima laconic natura ,particularitatile riscurilor acordate substantelor si preparatele
periculoase. Anexa III 20aprilie 1994 a redenumit “Lista frazelor de risc” (fraze R )in“ Natura riscurilor
particulare atribuite substantelor si preparatelor periculoase “- 20 aprilie 1994.
Lista cuprinde 68 fraze de risc si combinatii de fraze de risc( 57combinatii) .
R 33 Periculos ,efecte cumulative .
R 60 Poate altera fertilitatea .
Sfaturi de prudenta (fraze S ) cuprinse in” Lista sfaturilor de prudenta” ”Sfaturi de prudenta referitoare la
substantele si preparatele periculoase “ Anexa IV 20 aprilie 1994 ~64 fraze si 17 combinatii de fraze.
S 24 Evitati contactul cu pielea .
Un produs periculos poate avea maxim 3 simboluri ,cate unul din fiecare categorie de pericole ,cu
urmatoarele precizari:
- simbolul T determina utilizarea optionala a simbolurilor: C , X .
-simbolul E determina utilizarea optionala a simbolurilor : F, F+, O.
-simbolul Xn determina folosirea optionala a simbolului Xi.
-simbolul C determina utilizarea optionala a simbolului M.
1.5. Substante cu efecte nefaste pentru sanatatea omului
Substantele cu efecte nefaste pentru sanatatea omului sunt clasificate in 3 grupe: cancerogene C, mutagene
M si reprotoxice R ” . Fiecare dintre grupele , C ,M , R , are 3 categorii de risc 1, 2 , 3 .
Substantele reprotoxice R sunt substante care prin inhalare ,ingestie sau penetrare cutanata pot produce
sau majora frecventa efectelor nedorite asupra fertilitatii umane , fetusului inclusiv a dezvoltarii normale a
acestuia.
Substantele toxice pentru reproducerea umana , reprotoxice sau teratogene pot afecta functia de
reproducere la om , pot fi embriotoxice si / sau perturba dezvoltarea normala a progeniturii .
Substantele cancerogene C sunt substante care prin inhalare ,ingestie sau penetrare cutanata produc
cancer sau sporesc frecventa oncogenezei la om sau la animalele de laborator expuse actiunii toxicului.
Substante mutagene M sunt substante care prin inhalare ,ingestie sau penetrare cutanata pot induce ,
determina sau produce defecte ereditare, marind frecventa mutatiilor nefaste la om si animalele expuse actiunii
toxicului.
Detaliem efectele nefaste pe grupe C, M , R si pe categorii de risc 1 , 2, 3 .
Categoria 1de risc- substante cunoscute ca prin expunerea omului la actiunea lor determina o
epidemiologie,care este cauza producerii de mutatii,aparitia de cancer si efectele nefaste de teratogeneza.
-substante mutagene M1;T cu fraza R46 nu se cunosc
- substante cancerogene C 1;T cu frazeR45 ;R49 Arsenitul de sodiu
-substante reprotoxice R1; T cu fraze R60 si / sau R61 nu se cunosc
Categoria 2 de risc –substante asimilate, presupuse ca prin expunerea omului pot induce mutageneza ,
provoaca activarea oncogenelor , ca determina teratogeneza
M2 T cu fraza R46 ;
C2 T cu fraza R45 sau R49 ;
R2 T cu fraza R60 si / sau R61
Categoria 3de risc – substante nocive pentru om prin declansarea defectelor ereditare , initierea unor posibile
efecte cancerigene , afectarea posibila a fertilitatii omului si a dezvoltarii sale ulterioare .
M3 -Xn cu frazaR40
C3 -Xn cu fraza R40
R3 -Xn cu fraza R62 si / sau R63.
1.6. FORMULAREA SUBSTANTELOR FITOFARMACEUTICE
1.10.1. Necesitatea formularii substantelor fitofarmaceutice
Substantele active fitofarmaceutice sunt insolubile sau slab solubile in apa, dar peste 95% dintre tratamentele
fitosanitare sunt dilutii apoase (emulsii , suspensii , suspo-emulsii..) de substante fitofarmaceutice trebuie sa se
asigure un grad ridicat de hidrosolubilitate la majoritatea produselor fitofarmaceutice .
Moleculele de substante active putin solubile , insolubile in apa sunt dizolvate initial de un solvent nepolar /
polar,care le hidrosolubilizeaza bine si disperseaza mai uniform substanta activa in masa mixata .
Formularea este mixajul” substanta activa insolubila- solvent nepolar / polar, apa si alte ingrediente”
procesat fizico-chimic pentru asigurarea unui grad ridicat de solubilitate , o dispersie uniforma a substantei
active , imbunatatirea proprietatilor utile ale produsului fitofarmaceutic . I
n timpul formularii substanta activa fitofarmaceutica este mixata cu solvent nepolar /polar ,emulgatori,
muianti , sinergizanti,antioxidanti,substante tensioactive imbunatatindu-i proprietatile pentru a fi
administrata .
1.6.2. Obiectivele formulării produsului fitofarmaceutic
Prin formularea produsului fitofarmaceutic se ating obiectivele :

-miscibilitatea ridicata a substantei active in apa ; -
reducerea toxicitatii finale a produsului comercial(produsul pus pe piata);
-distributia mai uniforma a substantei active in produsul formulat; -
mentinerea campului de activitate initial al substantei active;
- etalarea adecvata a substantei active si pe suprafete netede glabre ceroase; -
tenacitate adecvata a depozitului de substanta activa depus pe frunze verticale
–marirea aderentei picaturilor de fluid fitosanitar pe vreme umeda ,ploioasa ;
- diminuarea dozei de utilizare fara micsorarea eficacitatii tratamentului ;
-impiedicarea atingerii punctului de scurgere “run-off”prin adaugarea tensidelor;
1.6.3.Substante utilizate la formularea produselor fitofarmaceutice
Formulant- coformulant –substanta sau un preparat fara activitate fitofarmaceutica proprie ,dar introdus intr-
un biocid sau produs fitofarmaceutic in timpul formularii ii asigura principalele proprietati de a fi utilizat .
substanta chimica folosita la prepararea emulsiilor (amestec neomogen de 2 lichide nemiscibile ,format din
dispersia fina a particulelor unui lichid insolubil .
Emulgator-substante chimice folosita la pregatirea emulsiilor (dispersia unui lichid in alt lichid , formand o faza
continua). Ex. Saponine , enzime, detergent
Diluanti-substante chimice polare sau nepolare care solubilizeaza substantele active fitofarmaceutice Pot fi
alcooli (a. etilic,a.metilic,a.butilic,a.amilic ) hidrocarburi (tetralina , decalina , xilen ),derivati halogenati
(tricloretan ). Diluantii sau solventii nu trebuie sa manifeste efecte nocive la plante ,la mediu .
Muiantii –substante care amelioreaza etalarea picaturilor de fluid fitosanitar pe suprafata tratata ,accelerand
evaporarea apei din picatura ,micsorandu-i volumul si suprafata ocupata pe frunza fiziologia decurge
normal .Ex: naftenati ,sulfonati.
Substante tensioactive (Tenside) –substante care asigura un impact adecvat, o mai buna acoperire la suprafete
lucioase,ceroase impiedicand atingerea RUN-OFF , punctual de scurgere , in timpul tratamentelor fitosanitare .
Tensidele nu se aplica cu produsele cuprice(oxid cupros,zeama bordeleza… ).
Adezivi-substante organice rareori anorganice care ajuta la fixarea picaturilor pe substrat ,impiedicand siroirea
si spalarea (RUN-RAIN). Ex.aracet,gelatina,caseina,melasa,dextrina .
Sinergizanti-substante cu actiune conjugata cu substantele active fitofarmaceutice majorandu-i eficacitatea
initial .Ex. K 264 pentru deltametrin ,limonen ,carvona . Utilizarea sinergizantilor diminueaza doza de utilizare la
aplicarea produsului fitofarmaceutic , dar mentin eficacitatea initiala a tratamentului fitosanitar.
Coloranti de marcaj- substante optic active ,usor de sesizat ,specifica unui produs
fitofarmaceutic ,personalizandu-l. Ex.safranina ,violet cristal .
Substante de avertizare olfactiva-odorizanti –substante cu mirosuri penetrante si persistente care se amesteca
cu substante gazoase toxice inodore sau putin mirositoare ,marcand prezenta gazelor toxice la concentratii
subacute pentru om . Ex. Cloracetona, cloropicrina pentru bromura de metil .
Antispumanti –substante care impiedica aerul sa patrunda si sa fie retinut in interiorul lichidului formand
spuma . Spumarea este nociva ,deoarece modifica vascozitatea,viteza de curgere …
Antidetonanti –substante care impiedica emisia gazelor foarte inflamabile care se pot autoaprinde .
Substantele suport –material care asigura distributia omogena s.a., in cantitate mica , la formularea unui
produs fitofarmaceutic.Pentru solide pulverulente , granule suportul este talcul, praful de creta ,tuful vulcanic…
.
1.6. 3 Codul internaţional al formulărilor de specialităţi fitofarmaceutice
AB - grain bait/ forma particulara de momeala
AE - aerosol dispenser/generator de aerosoli , disperseaza sub forma de aerosoli un produs formulat special cu un
gaz propulsor sub presiune , actionand o valva
AL –any other lichid/alte lichide nedefinite prin cod propriu , se aplica nediluate
AP –any other powder /pudra nedefinita prin cod propriu, se aplica nediluata
BB-block bait/forma particulara de momeala

BR-briquette/bricheta ,solid care elibereaza treptat s.a. in apa, mediu apos …
CB-bait concentrate/concentrat lichid sau solid care se amesteca cu …pentru prepararea unei momeliCF-capsule
suspension for seed treatment/suspensie de capsule care se aplica la seminte nediluate sau diluate
CG –encapsulated granule /granule incapsulate ,granule cu un invelis de protectie sau
CL-contact liquid or gel / lichid sau gel raticid sau insecticid aplicat nediluat sau se dilueaza inainte de folosire (gel)
,actionand prin contact .
CP-contact powder/ pudra de contact ,produs rodenticid sau insecticid de contact
CS-capsule suspension/suspensie de capsule care se dilueaza in apa inainte de aplicare,in particulele solide sunt
capsule cu s.a.
DC-dispersible concentrate /concentrat dispersabil ,concentat lichid omogen se aplica prin dispersie s.a. dupa
diluare in apa .
DP-dustable powder /pudra pentru pudrare , pulbere aplicata ca atare
DS-powder for dry seed treatment /pudra pentru tratamentul uscat al semintei , pulbere aplicata sec, ca atare,
pudrand semintele
DT-tablet for direct application /tableta pentru aplicare ca atare
EC-emulsifiable concentrate /concentrat emulsionabil ,lichid omogen concentrat , diluabil cu apa , se aplica ca
emulsie apoasa .
ED-electrochargeable liquid / lichid aplicabil electrostatic sau electrodinamic
EG-emulsifiable granule / granule emulsionabile,contin formulanti insolubili in apa,dupa dezagregare si dispersie

in apa formeaza emulsie apoasa care se aplica
EO-water in oil /emulsie apa in ulei,emulsie inversa, intr-o faza organica continua de picaturi de solutie apoasa
care contin produsul fitofarmaceutic
ES-emulsie for seed treatment /emulsie pentru tratamentul semintei , emulsie care se aplica la seminte , ca atare
sau dupa diluare .
EW-emulsion ,oil in water / emulsie ulei in apa ,emulsie intr-o faza apoasa continua de picaturi de solutie organica
a produsului , se aplica dupa dilutie.
FD-smoke tin /forma particulara(cutie) de fumigena
FK-fine granule / granule fine , granule mici o,3-2.5mm ,gata aplicabile .
FP-smoke cartridge /forma (cartus fumigen )particulara fumigena
FR - smoke rodlet / forma ( batonas fumigen )particulara de fumigena
FS- flowable concentrate for seed treatment / suspensie aplicabila la seminte ca atare sau dupa dilutie.
FT-smoke tablet /tableta fumigena , forma particulara fumigena .
FU-smoke generator / generator fumigen s.a. prin ardere , formulare solida care prin combustie , elibereaza s.a.
sub forma de fum .
FW-smoke pellet / pelete fumigene , forma particulara fumigena.
GA-gas /gaz , gaz sub presiune in butelie,rezervor,

GB-granular bait / momeala granulata, forma speciala de momeala.
GE - gas generating product / produs generator de gaz , prin reactie chimica elibereaza gaze.
GF-gel for seed treatment / gel de tratat seminte
GG-macrogranule /macrogranule ,granule mari , de2-6mm , gata de utilizat .
GL-emulsifiable gel /gel emulsionabil , gel care se aplica ca emulsie , rezultata prin diluarea gelului in apa .
GP-flo-dust /pudra pentru pulverizare pneumatica , pudra foarte fina ,aplicata prin curent de aer in incinte
inchise .
GR-granule /granule , granule cu dimensiuni de 0,1-6 mm ,gata de aplicare .
GS-grease /uleioasa , formulare vascoasa cu ulei sau substante grase.
GW- water soluble gel /gel solubil in apa , gel aplicabil ca solutie apoasa ,dupa diluare .
HN-hot fogging concentrate /produs pentru aerosoli calzi , formulare aplicabila cu un termo-nebulizator ,ca atare
sau dupa dilutie .
KK- combi-pack solid/lichid /pachet combinat solid /lichid
KL-combi-pack liquid/liquid / pachet combinat de 2 lichide
KN-cold foggingconcentrate /produs pentru aerosoli reci , formulare pentru produs aerosoli reci cu un
nebulizator ,nediluat sau diluat .
KP – combi-pack solid/solid / pachet combi solid/solid,2 solide asociate ambalate
LA-lacquer /lac , formulare filmogena pe baza de solvent .
LS - solution for seed treatment /solutie pentru tratamentul semintei , formulare lichida pentru tratat semintele ,
nediluata sau diluata .
ME-micro-emulsie /micro-emulsie ,emulsie apoasa in care picaturi foarte mici de solutie organica dau emulsiei o
aparenta omogena ,transparenta sau translucida , care se aplica dupa diluare .
MG-microgranule / microgranule , granule cu dimensiunea de 0,1-0,6mm .
OD-oil dispersible / dispersie in ulei,suspensie stabila de substante active in lichid nemiscibil cu apa , dar contine si
alte substante active dizolvate , produsul formulat se poate dilua cu apa .
OF-oil miscible flowable concentrate ,oil miscible suspension /suspensie miscibila in ulei ,suspensie diluabila in
lichid organic inainte de aplicare.
OL-oil miscible liquid / lichid miscibil in ulei(lichid organic) ,lichid care se dilueaza cu un lichid organic inainte de
aplicare .
OP-oil dispersible powder /pudra dispersabila in ulei(lichid organic) , pudra care se disperseaza in lichid organic
inaintea aplicarii .
PA-paste /pasta ,latex , formulare speciala cu un compus filmogen.
PB-plate bait /placheta momeala
PC-gel or paste concentrate /gel sau paste concentrate ,concentrate solide , gel sau pasta, care se dilueaza cu apa
inainte de aplicare.
PR-plan rodlet /bastonase , formulare solida cu lungime de cativa cm si diametru de cativa mm .
PS-seed coated with a pesticide /seminte tratate sau invelite in pelicule pesticide.
RB-bait (ready for use) /momeala pregatita .
SA - spot on / solutie pentru aplicare locala , solutie aplicata punctual pe pielea animalului ,cu volum extrem de
mic 100ml / animal.
SB-scrap bait /forma particulara de momeala
SC-suspension concentrate (flowable concentrate) / suspensie concentrata flow , suspensie de substante active in
lichid ,care contine uneori alte substante active dizolvate ,utilizata dupa diluarea cu apa .
SE-suspo-emulsion /suspo-emulsie , suspensie-emulsie, formulare fluida eterogena,alcatuita din dispersia stabila

de substante active sub forma de particule solide si din picaturi in faza apoasa continua.
SG-water soluble granule /granule solubile in apa, granule care se aplica sub forma de solutie apoasa a substantei
active si de ingrediente insolubile, inerte.
SL-soluble concentrate /concentrate solubile , lichid omogen solubil in apa = solutie adevarata a substantei
active , se aplica dupa diluarea in apa .
SO-spreading oil / ulei filmogen , formularea care diluata cu apa formeaza un film apos, ce se aplica acoperind ca
o pelicula ultrafina superficiala substratul.
SP- water soluble powder /pudra solubila in apa , pudra se aplica dupa dizolvare in apa , substanta activa da o
solutie adevarata ,dar contine formulanti insolubili.
SS- water soluble powder for seed treatment /pudra solubila pentru tratamentul semintei , pudra care se aplica
pe seminte dupa dizolvarea in apa .
ST-water soluble tablet /tablete solubile in apa , comprimatele dizolvate in apa dau solutii adevarate cu substanta
active dar pot sa contina formulanti insolubili.
SU- ultra-low volume( ULV) /suspensie nediluata aplicata cu aparat special ULV.
TB-tablet /tableta , formulare solida cilindrica cu inaltime mica /diametru mare .
TC-technical material / produs tehnic , produs direct din fabricatie , contine substante active + impuritati , aditivi ,
+ -decelabili .
TK-technical concentrate / concentrate tehnice,formulare intermediara solida sau lichida, de produs

tehnic,utilizata pentru fabricarea produselor formulate .
TP-tracking powder /pudra de pista , formulare de raticid si / sau insecticid care actioneaza prin contact , se
aplica ca atare .
UL-ultra-low volum ( ULV )-lichid omogen nediluat aplicat cu aparat tip ULV .
VP-vapour releasing product / substante volatile care elibereaza vapori in aer , in functie de substanta dar si de
dispozitivul de aplicare .
WG-water dispersible granule / granule dispersabile , granulele se aplica dupa dezagregarea si dispersia in apa .
WP-wettable powder / pudra care se aplica dupa dispersia in apa.
WS-tratamentul umed al semintelor , pudra care se aplica sub forma de zemuri concentrate apoase .
WT-water dispersible tablet /comprimate dispersabile ,comprimate care se aplica dupa dezagregarea si dispersia
in apa .
XX – others / toate formularile care nu au inca un cod specific .
Reformularea substantelor active fitofarmaceutice in noi specialitati pentru :
~mentinerea substantei active fitofarmaceutice in tari cu legislatii restrictive
~cresterea sigurantei, accesibilitatii cu reformulari mai eficace si putin toxice
~ utilizarea substantei active fitofarmaceutice pe vreme secetoasa sau ploioasa.
1.7. Marcarea proprietatilor fizico-chimice periculoase

E F+ F O C N T+ T XN XI
Substantele periculoase sunt substante care pot determina ,initia,produce pericole diverse:
explozii,incendii ,mutageneza ,cancer ,sterilitate ,fetotoxicitate…
Simbolurile standard utilizate pentru marcarea proprietatilor fizico-chimice periculoase sunt primele litere din
denumirea internationala data categoriei:
E -explozibil ,
O-oxidant ,
F -usor inflamabil ,
F+ -foarte inflamabil.
Semnul conventional specific reda grafic pericolul esential major al substantei .
E
EXPLOZIV E
Sub actiunea unui soc violent si/sau
scantei produsul poate exploda
OXIDANT O
Produsul in contact cu alte substante
cunoscute ca inflamabile degaja caldura in exces
USOR INFLAMABIL F
Produsul se poate aprinde usor de la flacara
FOARTE INFLAMABIL F+
Aprinderea produsului se produce foarte usor
chiar de la scantei , socuri , frictiuni , sarcini electrostatice F+
INFLAMABIL
Produsele periculoase sunt asociate cu fraze de risc ,care detaliaza natura riscului (explozie,incendiu) si
circumstantele in care se pot produce.
Produsele explozive se asociaza cu frazele R1 –R6 precizand circumstantele in care se pot produce
exploziile acestora. R1- Exploziv in stare uscata.
R2-Risc de explozie datorita socului,frictiunii,focului sau altor surse de ardere.
R3-Risc mare de explozie datorita socului,frictiunii,focului, altor surse de ardere.
Produsele oxidante sunt substante cu continut ridicat in elemente oxidante , dar initierea oxidarii, arderii,
degaja caldura in exces. Produsele oxidante care degaja multa caldura sunt numite produse calorigene .
Substantele inflamabile se asociaza cu frazele R 7 , R 8 ,R 9.
R7 - Poate provoca incendiu.
R8-Favorizeaza aprinderea materialelor oxidante (combustibile).
R 9-Poate exploda in amestec cu materialele combustibile (oxidante).
Produsele inflamabile - asociate cu fraza : R10 Inflamabil
Produsele usor inflamabile - asociate cu frazele R11 Inflamabil
R30 Poate deveni usor inflamabil in timpul utilizarii
Produsele foarte inflamabile se asociaza cu frazele R12 si R15.
R12 -Foarte inflamabile
R 15 - In contact cu apa degaja gaze foarte inflamabile .
1.8. Marcarea proprietatile toxicologice periculoase
Expunerea unor organisme animale de laborator la actiunea unui toxic poate produce efecte nefaste asupra
sanatatii ,care sunt clasificabile in diferite tipuri de toxicitate : subcronica, subacuta , acuta , cronica .
Toxicitatea acuta se manifesta la administrarea unei singure doze de substanta de studiat , efectele nefaste
observabile semnalandu-se in timp scurt .
Toxicitatea cronica este determinata de administrarea unei doze sau expunerea cotidiana , repetata la actiunea
unei substante studiate pe termen lung, 2 ani.
Toxicitatea subacuta este determinata de administrarea unei singure doze sau de expunerea zilnica la o
concentratie studiata in timp scurt ,o saptamana.
Toxicitatea subcronica se poate determina in urma aplicarii unei doze reduse sau
T+ F O A R T E T O X I C
Produsul care prin inhalare ,ingestie ,
penetrare cutanata poate antrena riscuri foarte
grave, acute sau cronice si chiar moartea . T +
T T O X I C
Produsul care prin inhalare, ingestie ,
penetrare cutanata poate antrena riscuri grave ,
acute sau cronice si chiar moartea T
Xn N O C I V
Produsul care prin inhalare, ingestie,penetrare Xn
cutanata poate antrena riscuri de o gravitate limitata .
Xi I R I T A N T
Produs necoroziv care prin contact momentan(imediat) ,
prelungit sau repetat cu pielea sau cu mucoasele
poate provoca o reactie inflamatorie. Xi
C COROZIV
Produs care in contact cu tesuturi vii poate exercita o
actiune distructiva asupra acestora . C
SENSIBILIZANT
Produs care prin inhalare , penetrare cutanata
poate determina local o reactie de hipersensibilitate ,
iar la expuneri ulterioare pot cauza unele efecte nedorite caracteristice.
X T T+
1.9..Marcarea substantelor periculoase pentru mediu
Mediu ,componentele sale (aer, apa , sol ) pot fi afectate imediat sau dupa o perioada de timp de unul sau
mai multe substante periculoase. Directiva 1999 / 45 C E din 31 mai 1999 a instituit clasamentul periculozitatii
pentru mediu al specialitatilor formulate in scopul comercializarii .
Simbolul N , Periculos pentru mediu si semnul conventional specific avertizeaza nocivitatea pentru mediu
si / sau componentele sale .
N PERICULOS PENTRU MEDIU

Substantele si produsele care prezinta sau pot prezenta risc imediat sau diferit pentru una sau mai multe
componente ale mediului .
Pericolele posibile pentru mediu pe care substantele formulate si specialitatile comerciale le produc ,sunt
explicitate cu frazele de risc R 50-R59.
Mediul este impartit in mediu acvatic ( apa dulce si apa sarata ) , non acvatic (sol , aer , partea terestra ).
Frazele de risc R 50 –R 57 detaliaza toxicitatea pentru componentele mediului :
R 54 Toxic pentru flora
R 55 Toxic pentru fauna
R 57 Toxic pentru albine
R 56 Toxic pentru organismele din sol
R 58 Poate antrena efecte nefaste pe termen lung pentru mediu.
R 59 Periculos pentru stratul de ozon .
Directiva 1999 / 45 C E prevede amplasarea mentiunilor de avertizare:

AQUA -periculos pentru organisme acvatice
DABE –periculos pentru albine si alte insecte polenizatoare
DAFT –periculos pentru fauna terestra
FASA - periculos pentru fauna salbatica
FAUN -periculos pentru fauna acvatica
GIBI -periculos pentru vanat ( fauna cinegetica)
OISO -periculos pentru pasari
POIS -periculos pentru pesti
CHIEN -periculos pentru caini
COUP –nu se foloseste la compost
C COROZIV E EXPLOZIV
F UŞOR F+ FOARTE
INFLAMABIL INFLAMABIL
N PERICULOS
PENTRU O COMBURANT
MEDIU
T TOXIC T+ FOARTE TOXIC
XI IRITANT XN NOCIV
1.10.. Eticheta produsului fitofarmaceutic
1.10.1. Eticheta produsului fitofarmaceutic -continut
Eticheta produsului fitofarmaceutic contine denumirea comerciala a produsului , denumirea si continutul in

substanta activa , simbolul si indicarea pericolului scris cu negru pe fond oranj , fraze de risc , fraze de prudenta ,
numarul autorizatiei de punere pe piata ,denumirea detinatorului autorizatiei de punere pe piata ,fabricant
importator , distribuitor (nume ,adresa ,telefon), numarul de eticheta CE ,elemente referitoare la utilitatea
produsului ,volumul ,termen de garantie ,data fabricatiei ,..
Produsul fitosanitar omologat , autorizat pentru punere pe piata in Romania, trebuie ambalat si etichetat ,
inscriptionat in limba romana aparent , lizibil pe orizontala , la produsul in ambalaj original asezat normal .
Semn conventional caracteristic-(simbol) reda grafic pericolul major al grupei de periculozitate in care este
clasificat produsul fitofarmaceutic formulat . Scrisul trebuie sa fie de dimensiuni vizibile , usor de citit si de
inteles de un utilizator cu nivel minimal referitor la produsele fitofarmaceutice .
ETICHETA CE
Denumirea comerciala a produsului
** Numarul autorizatiei de punere pe piata
Denumirea si continutul in substanta activa ***
** Denumirea detinatorului autorizatiei de
punere pe piata ***
** [ fabricant,importator,distribuitor]
( nume,adresa,telefon)
Simbolul si indicarea pericolului
(scris cu negru pe fond galben oranj)
** Fraze de risc *** NoCE<<etichetaCE >>
**Fraze de prudenta
** Eticheta produs
Pentru un produs caruia îi corespund multe simboluri de avertizare, se aleg primele doua [ în ordinea
descrescatoare a gradului de risc: dreapta etichetei –riscul cel mai mare; stânga, riscul mai redus).
- T face facultativa pe cea a semnelor grafice C, XN si XI;

- C face faculativa pe cea a semnelor grafice XN si XI ;
- E face facultativa pe cea a semnelor grafice F si O
Capitolul II Compatibilitatea , selectivitatea , toxicitatea , fitotoxicitatea , eficacitatea , transportul , stocarea şi

reciclarea produselor fitofarmaceutice
2..1. 1. Compatibilitatea produselor fitofarmaceutice
Compatibilitatea a 2 sau mai multe produse fitofarmaceutice -proprietatea determinata de interferenta

substantelor active amestecate pentru extinderea campului de activitate constand in cresterea eficacitatii
mixajului Es > Ee +Ei si lipsa efectelor negative observabile la cultura tratata .
Asocierea substantelor active fitofarmaceutice majoreaza eficacitatea mixajului Es > Ee+ Ei , sau diminueaza
eficacitatea amestecului Ea< Eo+ Eu
Sinergism -majorarea eficacitatii amestecului de produse fitofarmaceutice , superioara insumarii algebrice a
eficacitatilor individuale a componentelor . Sinergismul –fenomene prin care pesticidele in amestec isi
maresc eficacitatea , Baicu ,1979 . NF U 43 -000, 1987 defineste “ sinergismul –actiunea conjugata a 2 sau mai
multe produse asociate provoaca un efect superior, al superpozitiei , proprietatilor fiecarui constituent evaluat
izolat” . Sinergism - actiunea conjugata a 2, mai multe produse tradusa prin eficacitatea mixajului superioara
insumarii eficacitatilor individuale (CEB, 1990). Dupa reactualizare , sinergie a fost preferat sinergism.
“Sinergie –actiunea conjugata a 2 sau mai multe substante ce se traduce prin efect superior celui ce se poate
calcula prin insumarea efectelor individuale ”.
Sinergia-interferenta a 2 sau mai multe substante fitofarmaceutice asociate este maximum , eficacitatea
mixajului E s depaseste eficacitatea cumulata
Ee+Ei
Em = E e + E i
Es > E a + E i
Em - eficacitatea mixajului , cumulata , suma aritmetica.
Ee - eficacitatea substantei fitofarmaceutice “e”.
Ei - eficacitatea substantei fitofarmaceutice “i”.
Es - eficacitatea sinergiei .
E s= Ee + Ei+ d Ee Ei
2.1.2. Incompatibilitatea produselor fitofarmaceutice
Incompatibilitatea a 2 sau mai multe produse fitofarmaceutice este proprietatea determinata de interactiunile
opuse ale substantelor active manifestata prin : efecte negative fizico-chimice ,chimice,biologice,diminuarea
eficacitatii finale... Antagonismul in fitofarmacie este efectul de diminuare a eficacitatii amestecului de 2 sau
mai multe substante active fitofarmaceutice determinat sau generat de interactiunile contrare ale
componentelor fitofarmaceutice asociate Ea< Em
E a < E o+ E o
E a = E o+ E u – d E oE u
E m - eficacitatea amestecului , mixajului, suma aritmetica .
E o - eficacitatea substantei fitofarmaceutice “o” .
E u - eficacitatea substantei fitofarmaceutice “u” .
Ea - eficacitatea antagonismului .
Cand amestecul nu este stabil se recomanda sa fie facut de utilizator in ziua administrarii , respectand timpul
maxim de conservare , agitandu-l continuu pentru evitarea separarii pe faze si precipitarea .
Amestecul produselor fitofarmaceutice produce sau determina efecte negative. Incompatibilitatea consta in
aparitia efectelor negative biologice , chimice si fizico-chimice si in special diminuarea eficacitatii
amestecului de produse fitofarmaceutice . Incompatibilitatea este : fizico-chimica , chimica , biologica .
Incompatibilitate biologica consta in : -
antagonism -
efecte tisulare negative -
fitotoxicitate .
Incompatibilitatea chimica se poate manifesta prin : -
modificarea raportului dintre izomerii activi / inactivi
-reactii de schimb intre saruri -
formarea de combinatii complexe cu mobilitate redusa.
Incompatibilitatea fizico-chimica poate fi :
-precipitarea -depunerea -
separarea pe faze -spumarea -
modificarea vascozitatii -reducerea muiabilitatii -
reducerea tenacitatii -reducerea adezivitatii
2.1.3.Verificarea compatibilitatii emulsiilor si suspensiilor
Utilizarea pe scara larga in diverse conditii a schemelor de combatere integrata necesita studii laborioase
privind compatibilitatea fizico-chimica a emulsiilor si suspensiilor dupa amestecare .
In apa dura , 342 ppm , se studiaza amestecurile de substante fitofarmaceutice la concentratiile uzuale daca se
produc : virarea culorii , separari pe faze , spuma consistent , modificarea muiabilitatii , aglomerari , precipitare
Stabilitatea amestecului , variatia pH se verifica intr-un amestec de carbonat de calciu cu apa distilata si
monitorizand eliberarea de compusi de degradare si variatia valorii pH . Daca nu apar produsi de degradare
in libertate si variatia pH mica se considera ca amestecul contine produse compatibile . Mentinerea
eficacitatii biologice a amestecurilor de produse fitofarmaceutice se verifica in conditii de sera , laborator ,
camp. Mentinerea eficacitatii si lipsa semnelor vizibile de incompatibilitate denota ca amestecul de produse
fitofarmaceutice sunt compatibile si pot fi integrate in scheme de combatere.
2.1.4. Utilizarea compatibilitatii produselor in protectia agroecosistemelor
Majoritatea produselor fitofarmaceutice sunt incompatibile cu zemurile traditionale (bordeleza , burgunda ,

californiana , polisulfura de bariu ), produse cuprice(oxiclorura de cupru ,oxid cupros , carbonat bazic cupru).
Produsele fitofarmaceutice cu reactie alcalina se amesteca prudent cu produsele cu reactie acida pentru a
evita aparitia de efecte chimice negative . Amestecurile fitosanitare pot fi : binare -2 substante active
fitofarmaceutice ternare -3 substante active fitofarmaceutice ;cuaternare - 4 substante active fitofarmaceutice )
Substantele active fitofarmaceutice utilizate in amestecuri patentate sunt :
-insecticid + fungicid : Vitalin 85 PTS .
-insecticid + acaricid : Danirun 11EC
-2insecticide : Sumicombi 30 CE ;Tridim 25 VUR .
-2 fungicide : Prelude
-insecticid + ulei mineral : Oleodiazol ;Oleoekalux .
-insecticid + erbicid : Sinoratox 35 CE + SDMA
-fungicid + erbicid : Topsin M 70 + SDMA
-fungicid + regulatori de crestere : Sulf muiabil + Cycocel 40
Prin amestecul a 2 ,3,4 substante fitofarmaceutice campul de activitate al unui tratament fitosanitar se extinde ,
pentru combaterea simultana a organismelor daunatoare care depasesc pragul economic de daunare in
cultura agricola (anumita fenofaza sau perioada de timp) .
Frecvent in protectia agroecosistemelor folosim urmatoarele amestecuri :
binare ( 2 insecticide , 2 fungicide , 2erbicide , 1acaricid +1 insecticid ,
1insecticid+1 fungicid, 1insecticid +1 erbicid ,1 insecticid + 1 ulei mineral ,
1 fungicid + 1erbicid , 1fungicid + 1 regulator de crestere );
ternare ( 1fungicid + 1erbicid + 1 regulator de crestere , 2 fungicide+1insecticid,
1 insecticid + 1 fungicid + 1erbicid , 1insecticid + 1 acaricid + 1fungicid ).
cuaternare ( 1 insecticid+ 1 fungicid + 1acaricid + 1regulator de crestere ).
SITUAŢII ***c o m p a t i b i l <
>**c o m p a t i b i l fizic şi biologic <
>*c o m p a t i b i l chimic
^^^ încompatibil biologic <
>^încompatibil chimic <
>încompatibil fizic <
>^^încompatibil fizic şi chimic
2.2.. Selectivitatea substanţelor fitofarmaceutice
2.2.1.Selectivitatea- proprietatea substanţei fitofarmaceutice
Selectivitatea- proprietatea substanţei fitofarmaceutice de a acţiona diferenţiat cu componentele

agroecosistemului , afectând organismele vizate, neafectând organismele utile şi fiind indiferent faţă de restul
ecosistemului. În agroecosisteme producătorii primari sunt reprezentaţi de una,doua sau câteva specii vegetale
cultivate şi diferiţi consumatori( polenizatori, prădători , paraziţi). Pentru cultura agricolă interacţiunea produs
fitofarmaceutic cu plantele cultivate se manifestă prin diverse forme de fitotoxicitate (îngălbeniri ,ofiliri , necroze
fine). În acest caz nu se avizează produsul fitofarmaceutic pentru cultura respectivă . Exploatarea profitabilă a
unui agroecosistem necesită aplicarea unor tratamente fitosanitare pentru a preveni, limita sau anihila acţiunea
organismele dăunătoare (agenţi patogeni ,dăunătorI ,buruieni ), dar tratamentul fitosanitar poate deveni un
factor perturbator pe nivelele de organizare (celular,individual,populaţional) Acţiunea unei substanţe
fitofarmaceutice toxice cu diversele nivele de organizare a materiei vii a fost studiat detaliat de Baicu ,1981,
definind “selectivitatea pesticidelor –fenomen biologic de interacţiune a substanţelor chimice cu materia vie la
diverse niveluri de organizare prin care unele celule, specii, comunităţi etc. sunt afectate de substanţa chimică, iar
altele învecinate nu sunt supuse acţiunii
2..2.2. Aprecierea selectivităţii unui produs fitofarmaceutic

Selectivitatea produsului fitofarmaceutic este determinată de caractisticile intrinsece ale produsului
fitofarmaceutic , de tipul de formulare , de modul şi locul aplicării , de momentul interacţiunii “substanţă activă
fitofarmaceutică –constituenţii biotici “din agroecosistem , de etologia şi bioecologia speciilor cheie .
Cuantificarea selectivităţii produsului fitofarmaceutic se axează pe 3 categorii esenţiale :
Categoria A : om, cultură agricolă, mamifere domestice, vânat, păsări, peşti, zoofagi, polenizatori,
microorganisme antagoniste şi entomopatogene.
Categoria B:microorganisme utile din sol(simbionţi,micoritici), bacterii implicate în humificare şi mineralizare.
Categoria C : bacterii implicate în circuitul carbonului, azotului, fosforului .
Selectivitatea produsului fitofarmaceutic ( Baicu , adaptat Berchez )

Selectivitatea Supravieţuirea Mortalitatea :
produsului fitofarmaceutic organismelor utile organismelor utile
Neselectiv 0- 0,2 Foarte slabă< 20% Foarte mare>80%
Slab selective 0,2-0,37 Slabă 20-37% Mare 63-80%
Mediu selective 0,37-0,63 Medie 37-63% Medie 37-63%
Selectiv 0,63-0,8 Bună 63-80% Mică 20 - 37%
Foarte selectiv 0,8-1 Foarte bună >80% Foarte mică<20%
Selectivitatea produsului fitofarmaceutic - valori 0---1 s = v / 100
Supravieţuirea organismelor utile - procente 0-100% v% =100 –m %
Mortalitatea organismelor utile - procente 0-100% m% = 100 –v %
2.2.3. Tipuri de selectivitate a produselor fitofarmaceutice
Selectivitatea fiziologică- proprietatea substanţei active fitofarmaceutice de distrugere, inhibare,

inactivare a organismului sau grupei de organisme nedorite [ vizate, ţintă], de neafectare a organismelor utile
şi de neperturbare a celorlalte componente din agroecosistem .
Selectivitatea fiziologică a produsului fitofarmaceutic este determinată de natura substanţei active în special şi
în mica masura de tipul de formulare , momentul aplicarii tratamentului, modul si locul administrarii .
Substantele fitofarmaceutice cu camp de actiune ingust ,redus au selectivitati bune si foarte bune,deoarece
perturba slab restul organismelor nevizate,non tinta din agroecosistem . Biopreparatele pe baza de suse
nerezistenta sau tolerante la unele produse fitofarmaceutice pot manifesta selectivitati slabe sau medii. Ciuperca
Trichoderma viride-T d5 aplicata simultan cu fungicidulCaptan ,are o mortalitate de20-37%,in timp ce fungicidul
Perozin aplicat simultan cu Td5 produce o mortalitate mica ,<20%,avand o foarte buna selectivitate. Pentru fiecare
noua molecula cu actiune fitofarmaceutica principalul tel este selectivitatea fiziologica , de aceea multe molecule
cu potential fitofarmaceutic dar neselective sunt eliminate din faza de laborator .Produsele fitofarmaceutice
selective fiziologic nu vor prezenta fenomene de fitotoxicitate la specia vegetala indiferent de fenofaza,soi,
hibrid, tip de cultura, starea fiziologica ,stress hidric .
Selectivitatea tehnologica- selectivitatea conferita de tipul de formulare si modul de aplicare a unui produs
fitofarmaceutic , neselectiv fiziologic . Formularile, pulberi de prafuit (PP),pulberi umectabile( PU ,WP,WS,WT ) ,
suspensii (CS,DC,EG,FS,SC,SE ), concentratele emulsionabile( EC,CE ), granule dispersabile ( SG ,WG ) sunt slab
selective. Aplicarea prin mocirlire de substante fitofarmaceutice neselective fiziologic la rasadurile de
legume ,puieti manifesta o buna selectivitate tehnologica . Tratamentul semintei prin incrustare,drajare cu
produse fitofarmaceutice fara selectivitate fiziologica asigura o selectivitate tehnologica foarte buna.Raticidele
formulate sub forma de blocuri cerate sunt selective pentru pasari deoarece ceara este repelenta pentru
avifauna .Momelile cu substante fitofarmaceutice neselective fiziologic in concentratii subletale in amestec cu
preparate microbiologice pot sa manifeste o buna selectivitate tehnologica .
Selectivitarea de pozitie - selectivitatea datorata locului administrarii unui tratament cu un produs
fitofarmaceutic neselectiv (fiziologic,tehnologic)pentru combaterea daunatorului tinta (vizat) , dar inaccesibil
si/sau decalat in spatiu fata de alte organisme nevizate (non tinta) .
Nematocidele neselective fiziologic sau tehnologic incorporate in stratul arabil manifesta selectivitate fata de
polenizatori si pradatori harpactofagi care nu vin in contact cu toxicul administrat rarisim .Selectivitatea de pozitie
la aplicarea erbicidului Sencor –0,35 l/ha , incorporat la 2-3 cm in sol , nu afecteaza germinatia achenelor de
floarea soarelui aflate la adancimea de 7-9 cm .
Selectivitatea ecologica –selectivitatea unui produs fitofarmaceutic neselectiv ( fiziologic , tehnologic,de pozitie)
aplicat in functie de decalajul dintre cerintele ecologice ale daunatorului si cerintele ecologice ale
entomofagului specific . Pentru combaterea coccidelor( Qudraspidiotus perniciosi … ) in pomicultura se aplica
primavara timpuriu un tratament cu un insecticid organofosforic, malation , toxic pentru viespea parazita ,
Prospaltella perniciosi ,dar in perioada administrarii tratamentului,himenopterul gasindu-se in diapauza
hiemala,nu este afectat,deci tratamentul cu malation este considerat selectiv ecologic . Combaterea acarienilor
cu acaricide ovicide are selectivitate ecologica , nu afecteaza acarofagii Phytoseiulus persimilis,Typhlodromus sp.
Selectivitatea de comportament-selectivitatea determinata de comportamentul diferit la atractantii alimentari
si sexuali manifestata de daunatorii vizati. Feromonii sexuali sunt atractanti specifici care modifica
comportamentul masculilor unei specii, derutandu-i,capturandu-i , impiedicand imperecherea , diminueaza
prolicitatea si nivelul populational . Exista si alte substante biologic active precum alfa-farnesen ,care determina
depunerea pontei de femelele de Cidya pomonella pe tinerele fructe de mar,in timp ce pentru restul organismelor
daunatoare,utile,indiferente sunt inofensive.
2.9.4. Selectivitatea masurilor de combatere
Foarte selective (s>0,8) : metode genetice ,transgenice[ soiuri si hibrizi,soiuri transgenice],biologice [paraziti
specifici, microorganisme specifice ( entomopatogene ,micopatogene,bacteriofagi..)],atractanti specifici ,inhibitori
de nutritie, feromoni ,antisporulanti…
Mediu selective (s>0,37-0,63): pradatori polifagi,paraziti polifagi, antagonisti , hiperparaziti,atractanti
optici,atractanti alimentari si luminosi, antibiotice , fungicide,hormoni juvenili , inhibitori de metamorfoza ,
acaricide , raticide , moluscocide,algicide,erbicide,nematocide de vegetatie]… Neselective(s<0,2)
[desecari,drenaje,metode agrofitotehnice(aratura ,discuit ,cizel, fertilizare,amendamente,irigare,lucrari de
ingrijire,fertilizare faziala…..),nematocide de sol,dezinfectanti ai solului,insecticide cu camp de activitate
larg,erbicide totale ] Selectivitate buna fata de microorganisme
utile manifesta substantele active : a)Verticilium lecanii : triclorfon ,
carbaril , dimetoat , fention , endosulfan b)Beauveria bassiana :etion , propargit ,
tetraclorvinfos , triclorfon , carbaril.
c)Bacillus thuringiensis :permetrin ,cipermetrin ,fenvalerat ,paration ,diclorvos , triclorfon ,carbaril , lindan .
2.4.TOXICITATEA PRODUSELOR FITOFARMACEUTICE
2.4.1. Clasificarea tipurilor de toxicitate
Toxicitatea unei substante cu activitate fitofarmaceutica in stare pura sau mixata , formulata se manifesta prin
efecte nocive , periculoase , letale la animalele de laborator ,cu sange cald (sobolani albi , cobai ,iepuri ..)si cu
sange rece (dafnii , pesti ) dupa expunere scurta , prelungita , repetata ,corectata cu epidemiologia produsa
accidental la animale domestice , vanat si la om .
Toxicitatea acuta se manifesta la administrarea unei singure doze de substanta de studiat , efectele nefaste
semnalandu-se in timp scurt , o saptamana.
Toxicitatea cronica este determinata de administrarea unei doze sau expunerea cotidiana , repetata la
actiunea unei substante studiate pe termen lung , 2 ani.
Toxicitatea subacuta este determinata de administrarea unei singure doze sau de expunerea zilnica la o
concentratie studiata in timp scurt ,o saptamana.
Toxicitatea subcronica se poate determina in urma aplicarii unei doze reduse sau expunerea zilnica la o
concentratie studiata pe termen mediu , 3 luni.
2.4.2. Aprecierea toxicitatii

a) Scara logaritmica a toxicitatii - extrema inferioara, toxina botulinica 2 *10 – 4
-extrema superioara , bioresmetrin 104 mg/Kg.
SCALA TOXICITĂŢII
Doza letala medie- mamifere mg/Kg Doza letala medie-insecte
Bioresmetrin 104
Malation
Pirimifos
Permetrin
Carbaril 103
Rotenona Nicotina
Fenvalerat
Piretrina I
Dimetoat Diazinon
DDT 102
Deltametrin
Dieldrin DNOC Carbaril
Stricnina 10 Malation
Paration DDT , Aldicarb
Aldicarb 1 Diazinon,Rotenona
Dimetil mercur 0,1 Paration
Tetradotoxin 0,01 Piretrina I ,Fenvalerat
Sarin Bioresmetrin
Toxina botulinica 0.00002 mg/Kg Deltametrin
La mamifere deltametrin:- DL50 :- orala acuta -la sobolan = 135 - 5000mg /Kg;
- la caine > 300 mg /Kg;
-cutanee acuta –la sobolan>2000mg /Kg;
-inhalare acuta-la sobolan=0,6mg /Kg;
-DL50-orala acuta pe tip de formulare :EC(150g/l)-1080mg /Kg;
EC(250g/l)-535mg/Kg;
WP(25g/l)-16000mg/Kg;
SC(25g/l)-40000mg/Kg
b)Aprecierea toxicitatii produsului fitofarmaceutic prin compararea a

20 parametri toxicologici extrem de diversificati, de la bacterii simbionte la mamifere este mai fidela , fiind mai
apropiata de valoarea reala :
-toxicitatea orala de ingestie pentru mamifere -toxicitatea cutanee ( iepure )
-coeficientul de acumulare - actiune mutagena
-toxicitate pentru fazan -toxicitate pentru pesti ( pastrav )
-toxicitate pentru Daphnia magna -toxicitate pentru albine
-toxicitatea pentru rame (m<37%) -toxicitatea pentru Rhizobium(m<20%)
-toxicitatea fata de plantele cultivate (fasole,castraveti , DF = 3 DE 50 ) -
timpul de pauza (max 15zile)inainte de recoltare -
timpul de injumatatire (stabilitate medie , 120 zile ) -
influenta fata de mineralizarea materiei organice din sol(20% martor)
-influenta fata de respiratia solului (<20%) -influenta fata de nitrificare (<50%)
-migrarea pe verticala prin infiltrare in apa freatica (<10%) -coeficientul de acumulare in planta <35%
-persistenta,durata,actiunii biologice in apa (max 180 zile)
-toxicitatea pentru entomofagi,entomopatogeni,antagonisti
Toxicitatea pentru animale cu sange cald (sobolan , caine ,cobai, iepure , maimuta ..) pentru animale cu
sange rece( pesti , fazan , rata ), nevertebrate ( rame , dafnii , albine) .
Toxicitatea medie la principalele grupe chimice de produse fitofarmaceutice

Grupa chimică Toxicitatea[mg/Kg] Remanenţa[ani] Doza [Kg/ha]
Organoclorurate 230 1- 10 0,5 – 3 .
Organofosforice 67 ---- 0,6 .
Carbamaţi 45 ---- 0,7 .
Piretroizi 700 <o,1 0,01-0,02 .
2.4.3. Grupele de toxicitate
Doza letala cinci zeci [ DL 50 ]-cantitatea de substanta activa ( mg / Kg), aplicata oral in doza unica la sobolanii
albi Rattus norvegicus f. albino masculi si femele nehraniti de 24 ore , provoaca moartea unei jumatati (50%)
din efectivul supus testarii , in cursul perioadei de observatie de 14 zile calendaristice ,la 3ore din momentul
aplicarii substantei animalele sunt hranite normal .
Laboratorul de igiena publica si combaterea vectorilor din cadrul Ministerului Sanatatii
verifica ,determina ,reverifica DL50. Daca in practica epidemiologica se constata toxicitate marita la om decat la
animalele de laborator , necunoscuta la data avizarii se retrage avizul sanitar .
grupa I – produse extrem de toxice DL50 <50mg/Kg rosu >25%s.a . DL50mg /Kg cap de mort DL50<30mg/Kg
grupa II- produse puternic toxice 25%s.a.cu DL50= 50-200mg/Kg verde cap de mort
grupa III-produse moderat toxice 25%s.a.cu DL50=200-1000mg/Kg albastru X
grupa IV produse cu toxicitat DL50<1000mg/Kg negru X

Produsele cu continut sub 25% s.a. se incadreaza in clasa inferioara, exceptia fac produselor letale pentru om
prin otravire , desi se respecta normele de securitate ale grupei de toxicitate , se incadreaza in grupa Ide
toxicitate daca apartin toxicologic grupelor inferioare [ III,IV] ;( + epidemiologia -WHO ).
In cazul formularii produsului mixand substante fitofarmaceutice cu toxicitati diferite , grupa de toxicitate a
produsului este grupa substantei mai toxice .
2.5. Fitoxicitatea
2.5.1. Fitoxicitatea-terminologie
Fitoxicitatea –efectele nedorite atribuite activitatii unei substante active sau produs fitofarmaceutic care
altereaza efemer sau indelungat , reversibil sau ireversibil plantele de cultura determinand sau producand
cloroze , ofiliri , arsuri , basicari, gofrari .Fitotoxicitatea produsa de aplicarea produsului fitofarmaceutic la
culturi , in diferite fenofaze se poate compara utilizand scale calitative si cantitative: scala sensibilitatii
culturilor la aplicarea pesticidelor (produse fitofarmaceutice ); scala de afectare a suprafetei frunzei ;scala de
afectare a germinatiei semintei ;
2.5.2 Aprecierea fitotoxicităţii la plantele cultivate
2.5.2.1. **Scala de afectare a suprafeţei frunzei :
0~ nefitotoxic (nu afectează suprafaţa frunzei);
+ ~ slab fitotoxic( afectează 25% din suprafaţa frunzei);
++ ~ mediu fitotoxic(afectează 50%din suprafaţa frunzei);
+++ ~puternic fitotoxic (afectează75% din suprafaţa frunzei);
2.5.2.2.. Scala sensibilitatii culturilor la tratamentele cu produse fitofarmaceutice

1) salata
2) fasole
3 )tomate
4) patlagele vinete
5) ardei
6) porumb
7) grau
8) cartof
9) vita de vie
10) mar
11) par
12) cais
13) piersic
Scala sensibilitatii culturilor la tratamentele cu produse fitofarmaceutice este etalonata pe baza efectelor
sesizabile produse la plantele cultivate in Romania . Scala sensibilitatii culturilor la tratamentele cu produse
fitofarmaceutice contine 13 specii de plante superioare : 8specii erboase (1-8) si 5 specii lemnoase (9-12).
Structura scalei sensibilitatii culturilor agricole la tratamentele cu produse fitofarmaceutice din perspective
botanice cuprinde 13 specii vegetale, din care 11 specii dicotile (6 specii anuale , 5 specii perene ) si 2 specii
monocotile . Scala sensibilitatii vegetalelor la tratamente fitofarmaceutice pe culturi agricole: -legumicole
[1-5 plante erboase anuale dicotile ]; -culturi de camp [6–8 plante erboase anuale monocotile ( 6 ,7 ) si dicotile
( 8 )]; -culturi horticole[9-13plante lemnoase perene dicotile viticole(9)pomicole(10-13)
2..5.3. Determinarea fitotoxicitatii produselor fitofarmaceutice
Plantele de cultura se pot creste in conditii normale in sera , solar, fitotron vegetand pe parcursul anului
calendaristic . Culturile de plante anuale ,in special ,sunt posibile in camp ,in conditii de clima temperata numai
in sezonul agricol , care dureaza din luna aprilie pana in luna octombrie , ( 1 IV-31 X ).
DF =3DE50 , doza fitotoxica pentru cultura = triplu dozei eficace 50% .
Determinarea fitotoxicitatii se face in conditii meteorologice normale intr-o anumita fenofaza a plantei cultivate
dupa tehnologia standard . Concentratiile produsului fitofarmaceutic c 1, c2, c3, c4 sunt variante ( v1, v2 ,v3 , v4 ).
Concentratiile produsului fitofarmaceutic de testat sunt in progresie geometrica baza fiind concentratia de
utilizare pentru un daunator cheie al culturii pe care se testeaza fitotoxicitatea . Sunt 3 repetitii ( r1-r3 ) pe fiecare
varianta .Repetitia cuprinde o singura planta in ghiveci , cultivata in conditii de sera . In campul experimental
la speciile erbacee parcela are suprafata minima 2m2.
Variantele la speciile lemnoase pot fi la : vita de vie- 1 butuc ; pomi fructiferi - 1 pom
v = 3-4 r=3
n = ( v + 1 )* r
Pentru fiecare produs fitofarmaceutic sunt 3-4 variante de concentratii.
Concentratia start este concentratia de utilizare omologata pentru daunatorul cheie la cultura pe care se
testeaza fitotoxicitatea .
Valorile concentratiei sunt in progresie geometrica [0,1] [ 0,2] [ 0,4] [ 0,8].
Plantele se stropesc foarte bine , insistandu-se la portiunile tinere pana la aparitia’RUN-RAIN’,adica primele
scurgeri de produs fitofarmaceutic de pe frunze ,in special . Solutia se lasa un timp corespunzator pana la
uscarea pe fiecare planta. Notarile se fac la 1 , 3 , 7 , 14 zile de la aplicarea tratamentului . Martorul netrat face
parte obligatoriu din experienta .
Efectele fitotoxicitatii uneia sau mai multor substante active fitofarmaceutice la plantele dicotile se observa
pe marginea limbului foliar si in zona apicala , deoarece epiderma este fina , usor penetrabila .La plantele
monocotile efectele fitotoxicitatii substantei se sesiza in varful limbului foliar si in zona apicala .
Pentru testarea fitotoxicitatii produselor fitofarmaceutice folosite la dezinfectia solului din sere se recolteaza
probe din adancimea solului (10-25 - 50cm) , se pune 1/2l in borcan - 1l , se etanseaza cu inel de cauciuc si
capacul cu cleme . In restul liber al borcanului se introduc seminte de cresson- Lepidium sativum pe un tampon
de bumbac imbibat cu apa , montat deasupra solului . Borcanul se etanseaza , se mentine la 20-22 oC , unde
efectul emisiei de gaz fata de germinatia semintelor de cresson este vizibil . Semintele pot germina normal la
20-22oC ,daca solul nu mai emite gaz fitotoxic pentru germinatia cressonului .
Precizia buna a metodei rezulta comparand germinatia semintelor de cresson din borcanul cu sol tratat cu
produs fitofarmaceutic dezinfectant cu germinatia semintelor cressonului din borcan ……
2.6. EFICACITATEA PRODUSELOR FITOFARMACEUTICE
Eficacitatea produsului fitofarmaceutic – proprietatea prodului fitofarmaceutic manifestata prin inactivarea ,

inhibarea , distrugerea organimele daunatoare vizate datorate aplicarii tratamentului fitosanitar si a
persistentei actiunii .
Eficacitatea (E% ) dupa Abbott :
E % =[(1-Ta) / Ca ]*100
Ta - numarul de exemplare vii la varianta tratata dupa aplicarea produsului;

Ca - numarul de exemplare vii la variant martor dupa tratament .
Eficacitatea ( E% ) dupa Schneider-Orelli :
E % =[(T –C) /( 100 – C)] *100
T - % indivizi morti la varianta tratata dupa tratament

C - % indivizi morti la varianta martor dupa tratament
Eficacitatea ( E )dupa Henderson-Tilton ia in calcul migrarea sau inmultirea rapida a populatiilor daunatoare :
E % = 1 –[(Ta / Tb) *(Cb / Ca)]*100
Ta-numarul de indivizi vii la varianta tratata dupa tratament

Tb-numarul de indivizi vii la varianta tratata inainte de tratament
Ca –numarul de indivizi vii la varianta martor dupa tratament
Cb-numarul de indivizi vii la varianta tratata inainte de tratament
Eficacitatea ( E %) la populatiile de afide , unde cresterea si descresterea determina nivele extreme de

fluctuante , dupa Sun –Shepard :
E % =( Pt + -Pck ) / ( 100 +Pck )
unde Pt procentul de mortalitate la varianta tratata

: Pt = [(Tb-Ta) /Tb] *100
iar procentul de schimbare a numarului total de pe parcela martor :
Pck =[(Ca-Cb) /Cb]*100
Coeficientul de eficacitate
Ce = [ 1 –(X1 / X2 )]
X1 –numar organisme daunatoare dupa tratament ;

X2 –numar organisme daunatoare inaintea tratamentului.
Eficacitatea ( E % ) calculata in functie de mortalitatea omizilor :
E % =100 –[ 100 v /D]

v- numarul de omizi vii (densitatea de omizi vii) dupa tratament
D –numarul de omizi vii(densitateade omizi vii) inainte de tratament
Eficacitatea E % calculate in functie de procentul de mortalitate la omizi :
E % = 100 –[100v /( m +p)]
v-numarul de omizi vii dupa tratament p-procentul de mortalitate

p % = m /n *10 m –numarul de omizi moarte dupa tratament
n =m +v n-numarul de omizi vii si moarte
2.10. TRANSPORTUL PRODUSELOR FITOFARMACEUTICE
2.10.1 . Transporturi rutiere periculoase - A D R
Substantele si produsele fitofarmaceutice sunt considerate marfuri periculoase, care trebuie ambalate ,
marcate si transportate rutier conform ADR-30sept. 1957, de la Geneva , modificat la 1 iunie 2001. Romania a
aderat la A D R incluzand prevederile sale in Legea 31 / 1994 si Legea 6 / 2007.
Pricipalele obligatii la transportul rutier al marfurilor periculoase sunt:

-ambalarea , etichetarea si marcarea coletului ;
-semnalizarea si etichetarea vehiculului ( panouri oranj , fata si spate ) .
a)Panou orange 40 / 30
trusa de prim ajutor

–echipamente speciale pentru autovehicul ( instinctoare ,trusa de prim ajutor ) ;
-instruirea speciala a soferului ;
-documente de transport si sfaturi scrise pentru sofer ;
-destinatia , ruta , sfaturi de securitate .
Managementul situaţiilor de risc şi criză survenite la activităţi cu produsele fitofarmaceutice
In timpul activitatilor cu produse fitofarmaceutice din motive minore sau subestimarea voita a eventualelor
pericole pot fi determinate sau produse evenimente cu consecinte dezastroase pentru populatie sau mediu(sol,
aer, apa, componente biotice ( vegetale, animale).Pericolele aparute in timpul activitatilor cu pesticide pot
apare diverse accidente, care pot fi cauzate predominant din cauze mecanice, fizice, chimice sau
complexe( fizico-chimice, mecano-chimice, mecano-fizico-chimice…..).
Situaţiile de urgenţă
sunt manageriate şi gestionate prin aplicaţii punctuale de ISU cu:
- inspectoratele teritoriale pentru situaţii de urgenţă
Pompierii
SMURD
Poliţia rutieră şi teritorială

Jandarmeria
Protecţia civilă
Ambulanţa
2.10.2. Clasificarea ADR a marfurilor periculoase
Mărfurilor periculoase se clasifică: explozivi , gaze, lichide inflamabile, solide inflamabile , oxidanti, toxice ,
radioactive , corozive , materiale si obiecte periculoase diverse .
1. Explozibili
2. Gaze
3. Lichide inflamabile
4. Solide inflamabile
5 Oxidanti
6. Toxice
7. Radioactive
8. Corozive
9. Materiale si obiecte periculoase diverse .
Majoritatea produselor fitofarmaceutice periculoase sunt clasificate in

clasa 3 Lichide
3.1 lichide inflamabile la 18o C

3.2 lichide inflamabile la 18-23oC
3.3 lichide inflamabile la 61o C
clasa 4 Solide inflamabile
clasa 5 Oxidanti
clasa 6 Toxice (otrăvitoare)
Ambalarea marfurilor ( materialelor):

* I- foarte periculoase
* II – moderat periculoase
*III- putin periculoase
2.10.3 Semnalizarea transporturilor speciale A D R
Autovehicul trebuie sa corespunda exigentelor codului rutier referitoare la transportul marfurilor periculoase .
Echipamentul obligatoriu care doteaza vehiculul se compune: extinctoare , unu destinat stingerii incendiilor
motorului si un extinctor pentru incarcatura , 2 lampi portabile ( de buzunar , de fixat pe cap) pentru fiecare
membru al echipajului , vesta fluorescenta , banderola . Semnalizarea vehiculului se face cu 2 panouri fixe
sau mobile oranj , fixate in fata si spatele vehiculului si placa-avertizare de pericol fixat pe lateralele si in
spatele vehiculului cu masa neta transportata de peste 3 tone
a)Panou orange 40 / 30
b) Etichetele
claselor de
pericol
b) Indicatoare (etichete ) de pericol
Pericol de foc N lichid inflamabil

flacara neagra sau alba pe fond rosu , No3
cifra 3 in coltul inferior .
Pericol de foc N solid inflamabil

flacara neagra pe fond rosu, No4.1
cu 7bare verticale rosii,
cifra 4 in coltul inferior .
Materiale predispuse la
aprindere spontana
flacara neagra pe fond alb, No4.2
in jumatatea superioara si
cifra 4 in coltul inferior ,
a jumatatii inferioare rosii .
Pericol de emanare
de gaz inflamabil N o4.3
in contact cu apa
Negru sau alb pe fond bleu ,
cifra 4 in coltul inferior
Materiale calorigene (comburante~combustibile)
Flacara deasupra unui No5.1
cerc ,negru pe fond galben ,
cifra5.1 in coltul inferior
Materiale toxice
Cap de mort pe 2 tibii No6.1
negru pe fond alb ,
cifra 6 in coltul inferior
Materiale corozive
2 eprubete deverseaza lichide , No8
care ataca o mana sau un metal
negru pe fond alb in jumatatea superioara
si negru cu bordura alba in cea inferioara
cifra 8 alb in coltul inferior
Materiale si obiecte periculoase diverse

7linii verticale negre in partea superioara
pe fond alb 9 (cifra 9sublineat ) N o9
A.-Etichete de pericol
a.-in funcţie de clasa substanţei periculoase
CLASA 1
ETICHETA 1
In legătură cu explozia – diviziunile 1.1, 1.2 şi

1.3
ETICHETA 1.4
In legătură cu explozia – diviziunea 1.4
ETICHETA 1.5
ETICHETA 2
ETICHETA 1.6
Gaz inflamabil
CLASA 2
Gaz neinflamabil şi netoxic
Gaz toxic
CLASA 3
ETICHETA 3
Pericol de incendiu (substanţe
lichide inflamabile)
CLASA 4
ETICHETA 4.1
Substanţă solidă inflamabilă
ETICHETA 4.2
Substanţă predispusă la aprindere spontană
ETICHETA 4.3
Pericol de emanaţie de gaz
inflamabil în contact cu apa
CLASA 5
ETICHETA 5.1
Substanţă comburantă
ETICHETA 5.2
Peroxid organic: pericol de incendiu
CLASA 6
ETICHETA 6.1
Substanţă toxică (se ţine izolată de articole
alimentare sau de alte obiecte destinate
consumului in vehicule, precum şi de locuri de
descărcare sau transbordare)
ETICHETA 6.2
Substanţă infecţioasă (se ţine izolată de articole
alimentare sau alte obiecte de consum şi alimente
pentru animale in vehicule, precum şi de locuri de
încărcare, descărcare sau transbordare)
CLASA 7
ETICHETA 7A
Substanţă radioactivă în ambalaje
(in caz de avarie a ambalajelor, pericol pentru
sănătate în caz de ingerare, inhalare sau contact cu
substanţa împrăştiată)
ETICHETA 7B
Substanţă radioactivă în ambalaje
(In caz de avarie a ambalajelor, pericol pentru
sănătate prin ingerare, inhalare sau contact cu
substanţa împrăştiată, inclusiv riscuri de iradiere la
distanţă)
ETICHETA 7C
Substanţă radioactivă în ambalaje (În caz de avarie a
ambalajelor, pericol pentru sănătate prin ingerare,
inhalare sau contact cu substanţa împrăştiată,
inclusiv riscuri de iradiere la distanţă)
ETICHETA 7
Substanţă radioactivă, prezentînd pericol de fisiune
CLASA 8
ETICHETA 8
Substanţă corozivă
CLASA 9
ETICHETA 9
Substanţe şi obiecte diverse, care în cursul
transportului prezintă un pericol, altul decât cele pe
care le prezintă celelalte clase
b.- în funcţie de grupa de risc
Substanţă explozivă
Produs chimic susceptibil să explodeze în anumite
condiţii ( şocuri, frecări, scântei căldură)
se evită şocurile, zgâlţâielile, frecările producerea de
scântei şi a căldurii
E. Exploziv
Substanţă comburantă
Produs ce poate produce un incendiu prin aprinderea
unui produs combustibil
C. Comburant
Substanţă uşor inflamabilă F

substanţe inflamabile în contact cu scântei, căldura,
apa, alte substanţe
Evitaţi sursele susceptibile flacări, scîntei, ţigări,
F Uşor inflamabil rezistenţe electrice, inflamabile spontan, gazoase
F+
Substanţă foarte inflamabilă F+
gaze inflamabile spontan (autoaprindere), substanţe
care emit gaze inflamabile în contact cu scântei,
căldura, apa, şocuri, fricţiuni, alte substanţe
Evitaţi sursele susceptibile să producă şocuri, fricţiuni,
căldură, scîntei, ţigări, rezistenţe electrice,
F+. Foarte inflamabil
Substanţă toxică T Produse chimice ce pot provoca: o

intoxicare acută(afectează grav sănătatea), moartea
prin inhalare, ingestie sau contact dermal, topic)
Evitati inhlalarea, ingestia sau contactul cutanat
T. Toxic
Substanţă forte toxică T +
Produse chimice ce produc: intoxicare acută, moartea
( afectează grav sănătatea , produc moartea) prin
inhalare, ingestie ( per os) sau contact dermal (topic)
Evitati inhlalarea, ingestia sau contactul cutanat
T+ . Foarte toxic
Substanţă nocivă (Xn)
Crucea Sf. Andrei urmată de indicele Xn: substanţă
nocivă (Afectarea pe termen lung a sănătăţii datorită
utilizării repetate a unor cantităţi reduse de produse
chimice)
Xn. Nociv
Substanţă iritantă (Xi)

Crucea Sf. Andrei urmată de indicele Xi: substanţă
iritantă (Substanţă iritantă pentru piele, ochi şi căile
respiratorii)
Xi. Iritant
Substanţă corozivă
Produs chimic care distruge ţesuturile vii
C. Coroziv
Substanţă periculoasă pentru mediu
N. Periculos pentru mediu
B.-Etichete de manipulare
ETICHETA 10
Substanţa trebuie protejată de umezeală
ETICHETA 11
Manevrare pe verticală
ETICHETA 12
Colet cu mărfuri fragile
Dispense de la aplicarea Acordului European A
Dispensa pentru toate persoanele Maxim 50 Kg de produs fitofarmaceutic periculos se pot transporta cu un
vehicul rutier, de o persoana, la un transport .
Dispensa pentu agricultori transportul efectuat cu un tractor agricol de un agricultor sau un angajat al sau , cu
varsta de 18 ani , pentru necesarul propriei exploatatii agricole , nu poate depasi 1000 Kg de produse
fitofarmaceutice periculoase pe transport , ambalat in bidoane cu capacitate maxima de 20 litri
Dispensa partiala Pentru incarcaturile in majoritate marfuri periculoase masa totala a coletelor nu poate
depasi 1000 Kg , fara a excede cantitatea maxima autorizata 20-1000 Kg dupa clasament , transport ,
specialitate .
Transportul are urmatoarele prescriptii :

-incarcatura sa nu fie majoritara ;
-obligatiile partilor la operatiunile de incarcare si descarcare;
-dotarea cu cel putin un extinctor si o lanterna de buzunar;
- emiterea unui document de transport ;
2.11 . DEPOZITAREA PRODUSELOR FITOFARMACEUTICE
2.11.1. Depozitul de produse fitofarmaceutice
Constructie cu fundatie si pardoseala betonata , ventilata natural sau fortat in care produsele fitofarmaceutice
ambalate se stocheaza pe grupe de periculozitate , toxicitate si flamabilitate - depozitul fitofarmaceutic.
Evidenta produselor se face cu ajutorul fiselor de magazie , registre contabile si registre speciale
Fiecare specialitate comerciala are fisa de magazie pe care tinem contabilitatea.
Registrul special contine :data intrarii , cantitatea , tip ambalaj , numarul de unitati de ambalaj , nume delegat ,
mijloc de transport , data iesirii , cantitatea , tip ambalaj , numarul de unitati de ambalaj, nume delegat , mijloc
de transport. Depozitul de produse fitofarmaceutice va fi situate la distanta de 50 m fata de birouri, surse de
apa , depozite de furaje , depozite de alimente , medicamente , locuinte , depozite de combustibili, adaposturi de
animale . La intrarea in depozit se monteaza panouri cu inscriptii de avertizare:
Fumatul interzis ! Pericol de moarte! Purtati obligatoriu manusi !
Substantele fitofarmaceutice periculoase din categoriile nocive , corozive , iritante se depoziteaza separat .
Substantele toxice , cancerogene, mutagene, teratogene , explozive se stocheaza separate pe categorii , in
incaperi cu acces restrictionat , sub cheie permanent . Stocarea de substante fitofarmaceutice este reglementata
de legislatiile de sanatate publica , de mediu, de securitaritatea muncii .
In functie de cantitatile stocate sunt dispuse si obligatiile de indeplinit.
Cultivatorii care detin cantitati mici de produse necesare tratamentelor fitosanitare , echipament de protective
vor destina un local special: aerat sau ventilat , inchis cu lacat , fara surse de foc , podea betonata , extinctor
carosabil cu praf , amplasat exterior.
Exploatatiile agricole stocheaza produse fitofarmaceutice in cantitati mici nepericuloase pentru om , mediu si
sanatatea publica , pe durata scurta :
a) maximum 1000 Kg de produse foarte toxice pe durata tratamentului ;
b) durata maxima a tratamentului nu va depasi 10 zile ; c)
oricare produs fitofarmaceutic in ambalaj , nu va depasi cantitatea maxima : lichide foarte toxice - 50 Kg ;
solide foarte toxice -200 Kg ;
Depozitul ( capacitatea > 15 t ) de produse agrofarmaceutice va indeplini :
1)amplasare la minim 15 m de limita proprietatii ;
2) nu va fi corp comun cu imobile pentru locuit ;
3)rezistenta minima la foc 2 ore ( pereti , plafon );
4) sistem antifum cu comanda manuala ;
5) instalatiile electrice autorizate , controlate periodic , bine intretinute.
6) incinta depozitului bine ventilate va evita aparitia gazelor explozive(aer +gaze);
7) existenta unui bazin colector de ape de la stingerea incendiilor :5m 3 / t produs;
8) podeaua va fi etansa ,din material ignifug , inpermeabil la lichide(apa ,produs).
Clasificarea depozitelor fitofarmaceutice Neclasificat Declaratie Autorizatie SEVESO

1111.1 Stocuri de produse 200Kg 1t 20t
solide foarte toxice T+
1111.2 Stocuri de produse
lichide foarte toxice T+ 50Kg 250Kg 20 t
foarte toxice T+
1172 Stocuri de produse periculoase 20t 100t 200t
pentru mediu –A-Foarte toxice
pentru organismele acvatice
R50sau R50/53
1173 Stocuri de produse periculoase
pentru mediu –B-Toxice pentru 100 t 200 t 500 t
organisme acvatice R51/53
1155 Depozit de produse agrofarmaceutice 15t 100 t 500t pf(200t pfT)
2.11.2.Managementul riscurilor la stocarea produselor fitofarmaceutice
Pe durata operatiunilor legate de aprovizionare , stocare , livrare apar situatii nedorite ca rasturnari de
recipiente , ciocniri , fisurari , socuri , frictiuni care pot produce sau determina alunecari , caderi , arsuri ,
accidente , incendii , explozii si victime.
Aceste evenimente se pot evita prin :
instruire generala si individuala a fiecarui angajat ,
purtarea echipamentului de protectie specific categoriei de pericol ,
respectarea normelor de securitatea muncii la stocarea , manipularea de produse periculoase si PSI.
PLANUL DE ALARMARE
-telefon de urgenta 112 -

telefon Director + sef de depozit -
planul de evacuare
-traseele de deplasare
-tabele nominale cu personalul de interventie / tura / zi .
DOTAREA P S I
-lada cu nisip uscat cernut -100 l -extinctoare carosabile cu praf

-extinctor portabil cu praf -unelte de interventie (tarnacop , lopata , furca , galeti)
-furtune -hidranti
-punct de alimentare cu apa . -masca de gaze
-combinezoane -material absorbante
-bazin de stocat apa -bazin colector pentru ape uzate .
-instalatie de detectare si de avertizare a incendiilor
TRUSA DE PRIM AJUTOR
-comprese sterile -
pansamente -vata
-fese -PAM o,5g
-sulfat de sodiu -bicarbonat de sodiu
-atropina -carbune medicinal
-Magnezia USTA -pense
-foarfece -pahare
-lingurite
2.12. SECURITATEA MUNCII CU PRODUSE FITOFARMACEUTICE
2.12.1..Protectia personalului la lucrarile cu produse fitofarmaceutice
Personalul care utilizeaza ,manipuleaza ,stocheaza,inactiveaza substante si produse fitofarmaceutice trebuie sa fie
major,sanatos ,fara vicii (fumatori inraiti , alcoolici , narcomani ) controlat medical,fara boli cronice si respiratorii
Femeile gravide sau care alapteaza minorii sau persoanele cu rani deschise nu pot fi admise la orice lucrare
fitosanitara . Instruirea colectiva si individuala de protectia muncii va fi , insusita si verificata si inscrisa obligatoriu
in fisa individuala de protectia muncii .Echipamentul de protectia muncii va fi purtat in timpul lucrului ,nu si in
timpul pauzei de masa si la odihna. Denocivizarea echipamentului de protectia muncii se face dupa fiecare utilizare
,in nici un caz la domiciliul muncitorului . Stationarea personalului in depozit , inclusiv a paznicilor va restrictionat
la minim ,doar in timpul activitatilor necesare .Grupul social va fi obligatoriu cu apa curenta ,sapun.
Pregatirea fluidelor fitosanitare se face fie in statii de pregatire amenajate special in
pomicultura ,viticultura ,legumicultura ,sere sau in statii provizorii de tratat seminte si pregatire a zemurilor de
stropit . Amplasarea statiei provizorii de pregatit fluide fitosanitare va fi departe de
surse de apa ,naturale ,artificiale, depozite de furaje,locuinte . Statia va fi delimitata de un sant adanc de 25-
30cm,care poate prelua scurgerile de ape la nivelul solului , pentru a limita poluarea mediului .Dupa terminarea
lucrului la statia provizorie stratul superficial de sol va fi razuit cu sapa ,strans si ingropat la adancime ,acoperindu-l
cu sol necontaminat . In locul unde se pregatesc fluide
fitosanitare se interzice accesul copiilor, altor persoane , animale , servitul mesei fumatul , odihna .
Locul de masa se alege cu 150 m amonte fata de statia provizorie ,pe directia vantului dominant al zilei .
La lucrarile de deratizare ,lucrari cu risc pentru om si animale cu sange cald ,se iau masuri de protectie deosebite si
se vor populariza cu mult timp de inceperea lor . In timpul lucrarilor de dezinsectie ,dezinfectie din sere nu se
folosesc persoane care nu sunt bine instruite si nu au aviz medical recent . La gazarile din magazii , silozuri , mori,
depozite agroalimentare se foloseste numai personal bine instruit autorizat pentru aceste lucrari , cu detectoare
de gaz si dozatoare de PH3, masca de gaz .
In cazul aviotratamentelor personalul care balizeaza traseele de tratament fitosanitar la culturile de camp vor
purta echipament de protectie :cizme ,manusi , masca , combinezon .Muncitorii ce deservesc avionul vor purta
echipamentul corespunzator activitatilor cu substante periculoase.
Suprafetele tratate vor fi marcate cu indicatoare de avertizare cu texte :
PASUNATUL INTERZIS !
TEREN OTRAVIT !
Cap. III Substanţe active fitofarmaceutice si ingredientele utilizate la formularea produselor fitofarmaceutice ;
aprofundarea poluării agroecosistemelor şi mediului înconjurător
3.1. Produsul fitofarmaceutic-definitie
Etimologia termenului produs fitofarmaceutic provine de la cuvintele grecesti phyton=planta si

pharmacon=panaceu , medicament,remediu , corectiv .
Normativele franceze NF U 43-000 - Produse utilizate in Agricultura –Agrofarmacie-Vocabular ,1978 , clarifica
terminologia agrofarmaceutica :
Produsul agrofarmaceutic - substanta sau preparatul destinat protectiei sau ameliorarii productiei
agricole ,( se deduce lipsa fertilizantilor si alimentelor ) .
Produsul fitofarmaceutic –substanta sau preparatul ( - fertilizanti ) destinat protectiei sau ameliorarii productiei
vegetale si la produsele recoltate . Pesticid –substanta sau preparatul care permite lupta contra inamicilor
culturilor sau produselor recoltate .
Specialitate –preparat de compozitie definita prezentat in ambalaj propriu destinat comercializarii .
Pesticide –substante chimice ,destinate luptei impotriva daunatorilor ,agentilor patogeni si a vegetalelor
nedorite in agricultura ,silvicultura ,in gopodarii piscicole si gospodarirea apelor cat si substante chimice
destinate defolierii si desicarii culturilor ,Baicu ,1979 .
Regulamentul privind organizarea si functionarea Comisiei interministeriale de omologare a produselor de uz
fitosanitar si procedura de omologare a acestora in vederea fabricarii ,comercializarii si utilizarii lor in
agricultura si silvicultura defineste “Sub denumirea de produse de uz fitosanitar sunt cuprinse toate produsele
de natura chimica ,biologica sau biotehnica ,destinate prevenirii pagubelor cauzate de agenti
patogeni ,daunatori ,buruieni si alte organisme daunatoare culturilor agricole si vegetatiei forestiere , precum si
produselor depozitate .Sub aceeasi denumire sunt cuprinse si alte produse ,precum cele cu efect
desicant ,repellent, adjuvant ,sinergic , inclusiv capcanele feromonale , chromo-atractive sau fago-atractive ,
alte produse a caror utilizare are ca scop imbunatatirea starii fitosanitare a culturilor agricole , vegetatiei
forestiere si a produselor depozitate”,Codexul produselor de uz fitosanitar omologate pentru a fi utilizate in
Romania ,1999 .
Produsul fitofarmaceutic – substanta activa sau preparatul destinat :
-protejarii vegetalelor sau produselor vegetale de toate organismele daunatoare sau pentru prevenirea
actiunii lor; -
exercitarii unei actiuni fata de procesele vitale ale vegetalelor, sunt excluse substantele nutritive.
–conservarii produselor vegetale ,cu exceptia agentilor de conservare cuprinsi in dispozitiile particulare CCE .
–distrug buruienile sau portiuni ale vegetalelor;
-tempereaza sau inhiba cresterea nedorita a vegetalelor printr-o actiune chimica sau biologica “.
Directiva 91 / 414 /CEE 1990. Produsul fitofarmaceutic este preferat sinonimelor: produs agrofarmaceutic ,
produs fitosanitar , produs de uz fitosanitar, produs antiparazitar , pesticid .
Produs fitofarmaceutic -molecule de origini diverse care previn , combat sau franeaza actiunea
organismelor daunatoare plantelor sau produselor vegetale, stimuleaza sau inhiba procesele vitale ale
vegetalelor , modereaza sau franeaza biochimic cresterea plantelor cultivate , distrug buruienile sau portiuni
de planta sau pot conserva produsele vegetale.
3.2. Clasificarea produselor fitofarmaceutice
Principalele criterii de clasificare a produselor fitofarmaceutice sunt :

-grupele de organisme daunatoare pe care le combate ;
-modul de patrundere in organismul daunator tinta ; -
provenienta ,origine ; -
modul de actiune .
Dupa grupele de organisme combatute produsele fitosanitare se clasifica in : -
antivirale -bactericide -
fungicide -insecticide
-acaricide -nematocide
-moluscocide -raticide
-corbifuge -iepurifuge
-algicide -erbicide
-fitoprotectori -regulatori de crestere
-substante de crestere .
Dupa modul de patrundere in organismul daunator tinta si prezenta substantei in sau pe substratul de protejat
produsele fitofarmaceutice pot fi :
-de contact , topice - de ingestie ,per oral .
–de respiratie ,asfixiante , fumigante .
-sistemice . -nesistemice .
Dupa provenienta ,origine produsele fitosanitare sunt :
-anorganice -organice
-vegetale -biologice
-biotehnologice
Dupa modul de actiune produsele fitofarmaceutice pot (fi) :
-inhibitori ai transmisiei neurale -inhibitori metamorfozei
-inhibitori ai respiratiei -inhibitori ai germinatiei sporilor
-inhibitori ai complexului mitocondrial -afecteaza metabolismul glucidelor si polioli
--afecteaza biosinteza lipidelor (steroli ) -afecteaza biosinteza aminoacizilor si proteinelor
-afecteaza biosinteza acizilor nucleic -afecteaza diviziunea celulara si microtubuli
-inhibitori ai sintezei aminoacizilor in plaste si cloroplaste -inhibitori enzimatici
-blocanti ai proteinei D1 in fotosinteza -perturbatori ai cresterii prin inhibarea transportului auxinelor
-regulatori de crestere -substante de crestere
-feromoni de agregare -feromoni sexuali
-atractanti alimentari - atractanti cromatici
-entomofagi -acarofagi
-preparate virale -preparate bacteriene
3.3. Microorganisme cu dosare conforme dar care necesita examinari detaliate pentru a fi inscrise Anexa I -
Directiva n*91/414/CE
-Paecilomyces lilacinus
-Pdeudozyma flocculosa -Susa benigna a virusului mozaicului galben
-Virusul poliedrozei nucleare la Spodoptera exigua
3.4 Microorganisme inscrise si autorizate -Anexa I - Directiva n*91/414/CE
-Ampelomyces quisqualis - Coniothyrim minitans

-Gliocladium catenulatum -Paecilomyces fumosoroseum
- Pseudomonas chlororaphis
3.5. Substantele active inscrise si autorizate ~ Anexa I- Dir. n* 91 /414 /CE - 1991
-Acetamiprid -
Acibenzolar-S-methyl –Acid benzoic
–Alphametrin(Alphacypermethrin) - Aminotriazol (Amitrol)
- Azimsulfuron - Azoxystrobine
- Benalaxyl - Bentazon
- Beta-cyfluthrin -Bifenazat
-Bromoxynil -Carfentrazon -ethyl
-Chlorothalonil -Chlorotoluron (chlortoluron)
-Chlorpropham –Chlorpyriphos (chlorpyriphos-ethyl)
–Chlorpyrifos methyl -Cinidon-ethyl
–Clodinafop -Clopyralid
-Clothianidin -Coumafen(Warfarine)
–Cyazofamid -Cyclanilid
–Cyfluthrin -Cyhalofop butyl
–Cypermethrin –Cyprodinil
-2,4 D -2,4 DB
–Daminozid –Deltamethrin
–Desmedifam –Dimethenamide-P(DMTA-P)
–Dimoxystrobin –Diquat
–Esfenvalerat –Ethofumesat
–Ethoxysulfuron –Etoxazol
-Famoxad -Fenamidon
–Fenhexamid -Flazasulfuron
–Florasulam –Flufenacet (Fluthiamid)
–Flumioxazin –Flupyrsulfuron-methyl
–Fluroxypyr -Flurtamon
–Foramsulfuron -Forchlorfenuron
-Fosetyl(fosetyl-Al ) -Fosthiasat
-Glyphosat -Hidrazida maleica
–Imazalil –Imazamox
–Imazosulfuron –Indoxacarb
–Iodosulfuron(+iodosulfuron –methyl-sodiu) -Ioxynil
–Iprodion –Iprovalicarb
–Isoproturon –Isoxaflutol
-Kresoxym methyl –Lambda-cyhalothrhrin
-Laminarin –Linuron
- Mancozeb –Maneb
–MCPA (=2,4-MCPA) –MCPB (=2,4-MCOB)
-Mecoprop -Mecoprop-P
-Mepanipyrim -Mesosulfuron
–Mesothrion -Metalaxyl-M(=mefenoxam)
–Methoxyfenozide -1-methylcyclopropene
- Metiram(+metiram-zinc) -Metsulfuron methyl
–Milbemectin -Molinat
–Oxadiargyl -Oxamyl
–Oxasulfuron -Paraquat
–Pendimethalin –Penthoxamid
–Phenmedipham –Phosphat feric
-Picolinafen -Picoxystrobin
–Pirimicarb -Prohexadion-calciu
-Propiconazol -Propoxycarbazon(=propoxycarbazon de sodium)
-Propyzamid –Prosulfuron
–Pymetrozin -Pyraclostrobin
-Pyraflufen-ethyl –Pyradat
–Quinoxyfen –Rimsulfuron
–Silthiofam –S-metolachlore
-Spiroxamin -Sulfosulfuron
–Tepraloxydim –Thiabendazol
– Thiacloprid -Thifensulfuron-methyl
–Thiophanat-methyl –Thiram
–Tolclofos-methyl –Tolylfluanid
–Triasulfuron -Tribenuron(+tribenuron-methyl)
-Trifloxystrobin -Trinexapac(+Trinexapac-ethyl)
–Triticonazol –Ziram
-Zoxamid
3.6. Substante cu dosare conforme dar care necesita examinari

detaliate pentru a fi inscrise in Anexa I –Directiva n*91/414/CE
-Acequinocyl -Acid ascorbic
- Aminopyralid -Aviglycine HCl
–Bas 670 H –Beflubutamid
–Benalaxyl-M -Benthiavalicarb
-Bispyribac sodium -Carvone
-Chromafenozide -Clefoxydim
-Clothianidin -Cyflufenamid
–Dimoxystrobin -Ethaboxam
–Fen 56 -Flonicamide (IKI-220)
–Fluazolate -Fluopicolide
–Florura de sulfuril –Fluoxastrobin
-Gamma-cyhalothrin -Halosulfuron
–Iodura de potasiu -Mandipropamid
–Meptyldinocap –Mesosulfuron-methyl
-Metaflumizon -Methoxyfenozid(RH2485)
-Metrafenone -Nicobifene
-Novaluron -Penoxsulam
-Pethoxamide -Phosphite de potasiu
-Pinoxaden -Proquinazid
– Prothioconazole -Spinosad
–Spirodiclofene -Spiromesifene
–Tembotione -Thimethoxam
-Thiocyanat de potasiu -Tritosulfuron
-Valiphenal
3.7. Clasificarea substanţelor fitofarmaceutice după principalele grupe de organisme combătute
Erbicide Fungicide Insecticide Raticide
-Chlorotoluron (chlortoluron)
-Chlorpropham
–Chlorpyriphos (chlorpyriphos-ethyl)
–Chlorpyrifos methyl
- Cinidon-ethyl
–Clodinafop
-Clopyralid
-Clothianidin
-Coumafen(Warfarine)
–Cyazofamid
-Cyclanilid
–Cyfluthrin
–Cyhalofop butyl
–Cypermethrin
–Cyprodinil
-2,4 D
-2,4 DB
–Daminozid
–Deltamethrin
–Desmedifam
–Dimethenamide-P(DMTA-P)
–Dimoxystrobin
–Diquat
–Esfenvalerat
–Ethofumesat
–Ethoxysulfuron
–Etoxazol
-Famoxadon
-Fenamidon
–Fenhexamid
-Flazasulfuron
–Florasulam
–Flufenacet (Fluthiamid)
–Flumioxazin
–Flupyrsulfuron-methyl
–Fluroxypyr
-Flurtamon
–Foramsulfuron
-Forchlorfenuron
- Fosetyl(fosetyl-Al )
-Fosthiasat
-Glyphosat
-Hidrazida maleica
–Imazalil
–Imazamox
–Imazosulfuron
–Indoxacarb
–Iodosulfuron(+iodosulfuron –methyl-sodiu)
-Ioxynil
–Iprodion
–Iprovalicarb
–Isoproturon
–Isoxaflutol
-Kresoxym methyl
–Lambda-cyhalothrhrin
-Laminarin
–Linuron
- Mancozeb
–Maneb
–MCPA (=2,4-MCPA)
–MCPB (=2,4-MCOB)
-Mecoprop
-Mecoprop-P
-Mepanipyrim
-Mesosulfuron
–Mesothrion
-Metalaxyl-M(=mefenoxam)
–Methoxyfenozide
- 1-methylcyclopropene
- Metiram(+metiram-zinc)
-Metsulfuron methyl
–Milbemectin
-Molinat
–Oxadiargyl
–Oxamyl
–Oxasulfuron
-Paraquat
–Pendimethalin
–Penthoxamid
–Phenmedipham
–Phosphat feric
-Picolinafen
-Picoxystrobin
–Pirimicarb
–Prohexadion-calciu
-Propiconazol
-Propoxycarbazon(=propoxycarbazon de sodium)
-Propyzamid
–Prosulfuron
–Pymetrozin
- Pyraflufen-ethyl
–Pyradat
–Quinoxyfen
–Rimsulfuron
–Silthiofam
–S-metolachlore
-Spiroxamin
-Sulfosulfuron
–Tepraloxydim
–Thiabendazol
– Thiacloprid
-Thifensulfuron-methyl
–Thiophanat-methyl
–Thiram
–Tolclofos-methyl
–Tolylfluanid
–Triasulfuron
-Tribenuron(+tribenuron-methyl) -
Trifloxystrobin
-Trinexapac(+Trinexapac-ethyl)
–Triticonazol
–Ziram
-Zoxamid
Erbicide Fungicide Insecticide Raticide

Cap. IV Produse fitofarmaceutice : fungicide, bactericide,, insecticide, acaricide, nematocide,
moluscocide , rodenticide , erbicide , regulatori de creştere
4. 3. Insecticide
4. 3..1. Clasificarea insecticidelor
Insecticid-molecule de diferite proveniente care inhiba , inactiveaza , omoara insectele sau previn
actiunea distructiva la vegetale , a partilor de planta sau produselor vegetale stocate .
Etimologia termenului provine de la cuvintele latinesti : insectum= insecta si caedo ,-ere ,-avi, -atum= a tranti
jos , a face inofensiv , a distruge , adica substanta care ucide insectele.
Clasificarea insecticidelor se face in special dupa :
-modul de patrundere in organismele daunatoare tinta;
–modul de actiune in organismele daunatoare ;
-grupa sau clasa chimica din care provin moleculele ;
-modul de deplasare , curgere ,in planta ,sol ,alte substraturi de protejat ;
-dupa principalul stadiu pe care-l inhiba ,inactiveaza ,distruge .
1)Dupa modul de patrundere in corpul insectei insecticidele pot fi :
a)-topice,de contact;-strabat , penetreaza tegumentul ,le preia hemolimfa;
b)-perorale,de ingestie;-preluate cu hrana,ajung in tubul digestiv ;
c)-de respiratie ,asfixiante;prin respiratie simultan cu aerul intra in stigme .
2)Dupa modul de actiune in corpul insectelor insecticidele se clasifica:
a)-insecticide care afecteaza sistemul nervos, aprox. 90% dintre ele ;
b)-insecticide care afecteaza procesul respirator ;
c)-insecticide care afecteaza biosinteza chitinei ;
d)-regulatori de crestere a insectelor , perturbatori ai metamorfozei .
3)Dupa mecanismele de actiune asupra sistemului nervos al insectei pot :
A) actiona la nivelul sinapselor si neuromediatorilor;
a)receptorul glutamic
b)sinapse GABA
c)sinapse colinergice :
c1)- antagonisti de ACH * ;
c2 ) inhibitor de ACH-esteraza
B)actioneaza la nivelul transmisiei axonale a) asupra canalului de sodium
C) inhiba hranirea
4)Insecticidele care afecteaza respiratia prin:
a)inhibitori ai transportului de electroni in mitocondrie
b)inhibitori ai fosforilazei oxidative
5)Regulatori de crestere a insectelor :
a)perturbatori de ecdyson
b)blocarea hidroxilarii ecdysonului
c)mimetic ale hormonului juvenile
6)Dupa compozitia si clasa chimica insecticidele formulate se clasifica:
a)-minerale:ulei ,polisulfura de bariu ,polisulfura de calciu…
b)-vegetale :nicotina ,anabasina ,piretru natural
c)-organoclorurate :endosulfan ,lindan…..
d)-organofosforice :malation .diazinon ,fenitrotion ,cadusafos ,clorpirifos –etil
e)-carbamice :carbaril ,metomil , pirimicarb , tiocarb ,carbosulfan ,carbofuran
f)-piretroizi de sinteza :deltametrin ,bioresmetrin ,ciflutrin .betaciflutrin ,…
g)-carbinoli :dicofol , brompropilat… ….
h)–sulfone +sulfonati :fenizon ,tetradif ,tetrasul…
i)-carbamil triazoli :triazamat
j)-cloronicotinilice :acetamiprid ,imidacloprid ,tiacloprid …
k)-tiadiazine :buprofezin …
l)-amidinohidrazone :hidrametilon
m)-fenil-pirazoli :fipronil
n)-spinosoizi :spinosad
o)-avermectine :abamectin
p)-milbemycine :milbemectin
q)-oxadiazine :indoxacarb
7)Dupa caracteristicile reologice ,a curgerii ,deplasarii substantei active formulate in substratul de protejat
insecticidele pot fi :
a)nesistemice (exoterapice)-actioneaza adiacent locului de patrundere in insecta.
b)sistemice(endoterapice)-actioneaza in intreaga planta ,circuland cu seva bruta,elaborate sau in insecta prin
intermediul hemolimfei :
b1)ascendent sistemice –circula cu seva bruta spre aparatul foliar ;
b2)descendent sistemice-circula cu seva elaborate
b3)ambimobile sistemice-circula cu seva bruta si elaborata in sus si jos in planta.
c) translaminare –penetreaza frunza sau alt organ aerian al plantei ,actionand pe o parte sau alta a punctului
de patrundere combatand daunatorii existenti .
8)Dupa stadiile biociclului combatute insecticidele sunt:
a)-ovicide ; b)-adulticide ;
c)-larvicide ; d)- ovicide, larvicide si adulticide ;
e)-larvicide si adulticide.
4.3..2. Determinarea eficacitatii insecticidelor
Pentru determinarea eficacitatii insecticidelor se deruleaza testari in laborator si in camp In laborator

determinarea eficacitatii insecticidelor utilizeaza curent:
a)metoda peliculei toxice
b)metoda topica
Metoda peliculei toxice are caracteriticile : -
insecta test –Tribolium confusum,gandacelul fainii ; -conditii termo-higro: t o~27o ±1oC ; Ur % ~70 -80 % .
–reactivi : acetona -20 l ;bicromat de potasiu -1Kg ;acid sulfuric -5 Kg .
-materiale :para de cauciuc-5buc ;trompa metalica pentru apa -1buc ;creion dermatograf -10buc ;vata de bumbac -
10 pachete ;balanta analitica- 1buc ;vase Petri D/10 - 2*100buc ;pipete gradate 1 , 2 , 10 ,25 –
(20buc ,20buc ,15buc , 10buc );pahare Erlanmayer 50 ,100ml –(10buc ,100buc ).
Derularea testului
Pregatirea solutiei start--produsul tehnic, formulat--concentratie start ~(c s % ): -insecticide organofosforice -0,1%;
-insecticide cloroderivate-0,5% ; -insecticide carbamice-0,2% ;
Concentratiile se calculeaza gram / gram , acetona 100g = 126 ml . Cantarirea produsului solid de testat se face pe
hartie celofan ,cu dimensiunea egala cu dimensiunea platanului balantei , iar in cazul lichidelor cantarirea se face
in fiole speciale , scazand masa fiolei .
Pregatirea solutiei start =mama=baza=initiala se face in pahar Erlanmayer de 100ml cu dop rodat.
Dilutiile 4 ,5 se pregatesc in pahar de50 ml , 5ml acetona +dilutia ,astupate cu un dop de vata .
Dilutiile se pregatesc prin metoda injumatatirii ,concentratiile obtinute sunt in progresie geometrica .
Numarul vaselor Petri se calculeaza prin triplarea numarului de dilutii plus 3 vase pentru martor.
Sintetizand [3*(n+1)] n –numarul dilutiilor + martorul(1) .
Insectele se distribuie la inceput in vase Petri curate pentru transfer facil .
Transferarea in vasele cu pelicule toxice insecticide se face prin basculare , se acopera cu capacul si se introduc in
termostat ,unde se mentin timp de 2 ore la temperatura de 27 oC +/- 1 si Ur -70-80% .
Dupa 2ore se scot insectele in vase Petri inscriptionate identic cu vasele cu pelicule toxice inse ,unde stau 24 ore .
Dupa o zi se fac”citirile”,notandu-se
numarul de insecte vii -v ;
numarul de insecte “knock down”, rasturnate -i ;
numarul de insecte moarte - m
. m+v+i=n n=50
m % =( m +i)2 /100
DL50 se calculeaza prin metoda probit mortalitate-logDoza .
Daca DL50 nu apartine intervalul “serie dilutii testate “ se reduc dilutiile,iar daca insectele nu mor la
concentratia initiala produsul nu este bun.
Metoda topica are urmatoarele caracteristici:
-insectele test au dimensiuni medii- mari , usor de manevrat .
-speciile testate sunt comune , robuste .
- usor de procurat in tot cursul anului .
-insecte utilizate : Leptinotarsa decemlineata , Bothynoderes punctiventris .
Prin metoda injumatatirii concentratiei se realizeaza o progresie geometrica .
Aplicarea toxicului Se prinde insecta in zona humerala ,se roteste cu 180 o , astfel ca mezosternul sa poata veni in
contact cu picatura de insecticide ,eliberata prin rotirea capului micrometric al microseringii .Cand insectele sunt
dinamice nu pot fi mentinute in pozitia standard , atunci se introduc 3 ore la temperatura redusa in frigider .
Microdozarea insecticidului incepe cu dilutia cea mai mica , astfel microseringa este utilizata la microdoza
superioara succesiva . Deci microseringa nu trebuie spalata pentru fiecare microdoza administrata .
Calculul DL50 se face dupa metoda probit mortalitate –log D .
DL90 se calculeaza tot dupa metoda probit mortalitate –log D .
Alegerea produsului etalon se face dupa trei criterii:
-sa apartina aceleeasi clase chimice cu produsul de analizat;
-sa posede acelasi mecanism de actiune cu al produsului de analizat ;
-sa fie utilizat in tehnologiile moderne pe suprafete extinse .
4. 3..3 . Insecticide minerale
Primele insecticide pe care omul le-a preluat din regnul mineral au fost sulful , arseniatii , arsenatii. Mentionati
de romanul Pliniu la culturile antice agricole compusii arseniului au fost utilizati pana in a doua jumatate a
secolului X IX . Fitotoxicitatea mare , toxicitatea foarte mare , solubilitatea redusa in apa , concentratiile de
utilizare mari si remanenta indelungata au limitat folosirea in vegetatie , exceptand: silvicultura , pomicultura ,
viticultura si terenuri virane .
Compusi ai arseniului :
-Arsenatul de calciu - Ca( AsO4)2 -
aceto-arsenitul de cupru , Verde de Paris - (CH3COO)2 Cu * 3Cu(AsO2)2 sau Verde de Schweinfurt
-arsenatul de plumb- [PbHAsO4 +( AsO4)2Pb3]
Sulful mentionat de Aristotel actioneaza ca gaz sufocant, SO 2 incolor , iritant , neinflamabil , hidrosolubil ,
puternic toxic pentru om si animale cu sange cald . 1 g S+O 2 =2 g SO2; prin arderea sulfului degaja bioxid de
sulf , cu miros iritant . Dezinsectia spatiilor de depozitat fructe , legume , inventar vinificatie si apicol .
Polisulfura de bariu contine: S-20-25% ; Ba—40-45% ;
tratamente de iarna –6-8% pentru coccide; tratamente in vegetatie—0,8-1% ;
nematocid ,imbaiere 2-3 ore la 0,4% + svantare
Polisulfura Ba contine si monosulfura de Ba , tiosulfat , sulfura de carbon .
Polisulfura de calciu (1803) contine 2,8Kg S macinat + 1,5 Kg var CaO+3 l de apa fierbinte(formula ICAR), se
stinge varul , triturat ca nuca , plus7-8 l apa , in vas smaltuit , cu V = 12-15 l , se fierbe 45minute , galben-oranj-
rosu sangeriu , zeama atinge 28-30 o Beaume ( 1,24-1,25 g / l), cu mentinerea volumului initial prin completare
cu apa fierbinte , pH - usor alcalin . Conservare limitata , in sticle bine astupate , la intuneric .
3Ca(OH)2 + 12 S =2 Cas2 + CaS2O3+ 3H2O S -80% , sulfuri + pentasulfuri Ca ; - 20% tiosulfat Ca
Tratamente de iarna—polisulfura de calciu ( zeama sulfocalcica )- 20 %.
Tratamente in vegetatie—2% pentru acarieni , coccide ,antioidium ;
nematocid, imbaierea bulbilor de usturoi timp de 2-3 ore in 0,8% ,+ svantare
Dilutia : ZC / ZF =100 * X ; 32 / 8 =100 / x ; x=100*8 /32 ; x =100/4 =25 % .
4. 3..4. . Uleiuri horticole
Uleiuri minerale sunt mixaje de hidrocarburi naftenice , parafinice , aromatice , si emulgatori formand emulsii
apoase , cu actiune ovicida , adulticida , sufocand pontele si coccidele de pe pomi la momentul aplicarii .
Emulsia de ulei mineral formeaza o pelicula filmogena , care se etaleaza pe scoarta pomului , sufoca (oua ,
acarieni , nimfe, coccide prezente pe pom la aplicare ), obtureaza lenticele si stomata , reduce osmoza normala
(O2 - CO2 ), produce oboseala pomilor si favorizeaza atacul de carii pomilor , determinand disparitia pomilor .Au
efecte erbicide pentru umbelifere . DL50 - acuta la sobolan >4300 mg Actipron / Kg .
Uleiurile minerale crude distilate la to=335 oC dau sorturile : light(67-79%); medium(40-49%); heavy (10-25%) .
Densitatea 0,92 -0,86g/cu la 15oC; punct de inflamabilitate- toC >204oC
Uleiurile minerale crude distilate la to=335oC se separa in 3 sorturi :

light(67-79%) usoare medium(40-49%)medii heavy (10-25%) grele .
Petroleum oils,Ulei alb-1922 marca Volck(Chevron)-primul Ulei horticol
US1 (ulei mineral -92% )~1,5% (30l / ha ) tratamente de iarna in pomicultura Quadraspidiotus
perniciosus=paduchele din San Jose;acarieni-Tetranychidae.
OleoekaluxRV(30 g quinalfos/ l); pomicultura , tratamente de iarna -1,25% (18,75l in 1500l apa/ha) mar,(12,5 l
in 1000l apa /ha)prun -Quadraspidiotus perniciosus( larve hibernante) , Panonychus ulmi (ou iarna) .
Oleoecalux (30g quinalfos /l + ulei mineral); tratamente de iarna in pomicultura 1,0-1,5% (mar, prun) -paduchele
din San Jose= Quadraspidiotus perniciosus .
Oleodiazol 3CE (32 g diazinon / l); tratamente de iarna in pomicultura 1,5%(15 / 1000 l apa / ha)-
Quadraspidiotus perniciosus (larve hibernante), Panonychus ulmi (oua de iarna )- mar, par , prun ,cires , visin .
Oleocarbetox 12CE ( malation12%+40% ulei mineral) ;tratamente de iarna la Quadraspidiotus perniciosus ( larve
hibernante) , Panonychusulmi (ou iarna)-1,5%(15 l /1000 l apa /ha) prun ;1,5%(22,5l /1500l /ha) mar .
Oleocarbetox plus (9%malation+65% ulei mineral);tratamente de iarna 1,5% (22,5 l /1500l /ha mar)
(15l/1000l /ha prun)Quadraspidiotus perniciosus(larve hibernante) , Panonychus ulmi ( ou iarna)
Oleocarbetox super (18% malation+30% ulei mineral);tratamente iarna 1%(15l / 1500 l /ha mar;10 l /1000 l /ha
prun )Quadraspidiotus perniciosus (larve hibernante) , Panonychus ulmi (ou iarna) .
Actipron +Fyzol-adjuvant Paroil E Oleo-Bladan
4.3..5. Primele insecticide de sinteza
DNOC -1892 , dinitro orto cresol Fomula bruta C7H6N2O5 metil - 2 dinitro - 4,6 fenol ; familia chimica : fenoli. Solid
cristalin galben , insolubil in apa(sarea DNOC-130g / l la 15 oC) , solubil in solventi organici ;
DL50 orala la sobolan =25-40mg/Kg ;T+ R27/28-33-36-40-44 ; Penetreaza usor pielea; Toxic pentru vanat , albine ,
pesti ; insecticid , ovicid , erbicid (grau , orz , ovaz , secara-3720g / ha;mar , par ,cais , piersic -5000g /ha
1932 ,Franta , fungicid formulari:PU , CE , PA , mixturi cu ulei minerale , saruri de sodiu(DNOC-Na), saruri de
amoniu( DNOC-NH4 ) mai active , combate coccide , afide .specialitati comerciale : Selinon , Sandolin , Sinox ,
Herbogil , Nicyl , Nitro-Mop
CHINESE: 二硝酚; FRENCH: DNOC (n.m.); RUSSIAN: ДНОК

IUPAC: 4,6-dinitro-o-cresol
CAS: 2-methyl-4,6-dinitrophenol
REG. NO.: 534-52-1
FORMULA: C7H6N2O5
acaricides (dinitrophenol acaricides)
fungicides (dinitrophenol fungicides)
herbicides (dinitrophenol herbicides)
ACTIVITY: insecticides (dinitrophenol insecticides)
When this substance is used as an ester or a salt, its identity should be stated, for example DNOC-ammonium
NOTES: [2980-64-5], DNOC-potassium [5787-96-2], DNOC-sodium [2312-76-7].
STRUCTURE:
PRONUNCIATION: dē ěn ō sē Guide to British pronunciation

INCHIKEY: ZXVONLUNISGICL-UHFFFAOYSA-N
INCHI: InChI=1S/C7H6N2O5/c1-4-2-5(8(11)12)3-6(7(4)10)9(13)14/h2-3,10H,1H3
DNBF –dinitro secundar butil fenol C10H12O5N2 ~ DL50=50-60mg/Kg

Ulei brun , inflamabil , insolubil in apa , solubil in produse petroliere
Cloropicrina -1907, denumirea comuna : chloropicrin (BSI , E-ISO ,ESA) denumirea
chimica:trichloronitromethane Formula chimica:CCl 3NO2 ; Cl3CNO2 Lichid colorat ;
neinflamabil ,lacrimogen ,iritant pentru mucoase , punct de topire -64 o C ;punct de fierbere 112,3 oC ; presiunea
de vapori 3,2kPa; solubilitate 0oC 2,27g/l apa; solubil in acetona, ,benzen , tetraclorura de carbon , dietil eter ,
methanol foarte toxic (CL=0,8 mg /l aer, timp= 20 min
pisica , cobai , iepure –letal foarte fitotoxic ,nu in vegetatie ,
cloropicrina + metil bromide avertizor olfactiv pentru operatori ;
Insecticid , nematocid , dezinfectant de sol in sere, intre cicluri ,combate( fungi , exc-Scerotinia..), fumigant la
produse stocate formulari:mixturi ; Di-Trapex CP (cloropicrin+1,2-diclorpropan+1,3-diclorpropen+metal
isotiocyanat) ; Telone C17( 215g clorpicrin+937g (E) +(Z)-1,3-dicloropropen/l);Nor-Am ( 150g
cloropicrin+340g(E)+(E)-1,3-dicloropropen +170g metal isotiocyant/Kg)
Tiocianati 1932 Murphy
Fenotiazina 1934
4 .3.6 . Insecticide vegetale
Piretrul a fost primul insecticid mentionat in scrierile chineze ( 2000 ICh ).

In anul 1690 Quintini a extras din frunzele de tutun nicotina ,un alcaloid . Nicotiana tabacum si N .rustica contin
nicotina , un lichid incolor , cu miros neplacut , la aer devine bruna , foarte solubila in apa si solventi organici ,
forma levogira se gaseste in natura , iar sub forma de sare este dextrogira .
Nicotina- densitatea 1,009g/l ;punctul de fierbere 247 oC ; miros iritant , gust acru ; punctul de topire-80 oC;
tensiunea de vapori 5,65 Pa la 25oC In frunzele de tutun si mahorca nicotina se gaseste sub forma de citrat si
saruri ale acidului malic. Nicotina , C10 H14 N2 ,1-metil-2-piridin-pirolidina , cu nucleu pirolic hidrogenat metilata
la atomul N , un nucleu piridinic , legat la C3 cu nucleul pirolic hidrogenat , pirolidinic .
Aplicata in doze mici nicotina este excitanta , in doze mari este toxica , izomerul levogir , paralizand sistemul
nervos . Proprietatile cumulative sunt slabe , toxicitatea cutanee –50g / Kg, toxicitatea respiratorie- foarte
ridicata “0,1mg/m3, timpul de pauza =20 zile . combate afidele , este selectiva pentru coccinelide ,
himenoptere . Formulari : Nicotina pura -950g / Kg ; Sulfatul de nicotina -400g nicotina / l ;
Anabazina-alcaloid , lichid brun , puternic toxic pentru animale cu sange cald , extrasa din Anabasis aphylla .
Combate afide , tripsi .
Rotenona –radacina de Derris era cunoscuta in China ca otrava la pesti si insecticid . In anul 1895 Geoffrey a
izolat rotenona -C23H22O6 ,iar La Forge a stabilit structura (2R, 6aS)-1,2,6,6a,12,12a-hexahydro-2-isopropenyl-8,9-
=dimetoxycromenol[3,4-b]furo[2,3-h]cromen-6-one ,-alcaloid din radacinile de - Derris eliptica , Lonchocarpus
utilis , L. urucu , L. nicou numite Tuba-root , aker-tuba , barbasco , cube , timbo , haiari , nekoe .
cristale colorate(CCl4 ) ;punct de topire 163oC ;f. dimorph-181oC ;f. c.- 231oC ; solubilitate (100oC )- 15 mg /l apa ,
slab solubil in tetraclorura de carbon , ulei de petrol , solubil in solventi organici polari ; nefitotoxic ; toxicitate
mica fata de om ;LD50-orala acuta sobolan alb 132-1500mg/Kg ; soarece alb -350mg/Kg; toxic pentru porc ;
foarte toxic pentru pesti .
Insecticid nesistemic , actioneaza prin contact , ingestie , respiratie inhiband transportul electronilor in
mitocondrie , proprietati acaricide , persistenta redusa timp de injumatatire= 1-3 zile in apa , sol .
Formulari: Phytrol EC -80g/l -Leptinotarsa decemlineata ~200g / ha ; afide legume , cicade~ vita de vie -200g /
ha ;afide pomi cires , par , piersic 20g / hl. Rotenobiol SC -66,6g/l ~Leptinotarsa decemlineata -256g/ha ;
Pyretol 8EC (rotenona + piretrine + piperonil butoxid )–10g/l ;P -5g/l ;P-15g/l . Biophytox L 2(rotenona +
piretrine + piperonil butoxid ) -30g/l ;15g/l ;150g/l . Bio Back to Nature Spray(rotenone+quassia); Bio Back to
Nature Pest and Disease Duster DP (rotenone + sulf );
Piretrinele naturale au fost studiate de Staudinger si Ruzicka ,identificand in pulberea de flori de
Pyrethrum=Chrysanthemum cinerariefolium ,C. roseum esterii acidului chrysantemic 1,3-3% substanta activa .
(acidului ciclopropan carboxylic) : piretrine(I , II) , cinerine(I , II ) , jasmoline(I , II ) .
Raportul piretrine / cinerine / jasmoline =71 /21 /7. Piretrinele au catena nesaturata fiind instabile se oxideaza
in prezenta aerului si luminii polimerizand . La pH alcalin piretrinele hidrolizeaza rapid trecand in izomeri fara
proprietati insecticide . Adaugand antioxidanti efectul insecticid al piretrinelor se mentine .
Piretrul are actiune de contact , ingestie ,cu actiune de soc , perturband electrofiziologic sistemul nervos al
insectelor . Piretru de Persia , Piretru de China
Tomatina –extract din partea supraterana a tomatelor-Lycopersicon esculentum are actiune aficida –Aphis pomi
.
Alcaloizi quinolizidinei sunt metaboliti secundari , biosintetizati de genurile
Lupinus ,Sophora ,Ormosia ,Thermopsis au actiune insecticida / repelenta pentru afide , diptere , lepidoptere ,
coleoptere , himenoptere .
Speciile vegetale Sambucus ebulus , Euphorbia amygdalorides , decoct , combat afidele , paduchii de pasari ,raia
Amaranthus ascendens , A.retroflexus , Capsicum annum , Convulvulus arvensis , Mentha piperita , Glycine
max , Phaseolus vulgaris , Artemisia vulgaris combat Leptinotarsa decemlineata .
Rumex obtusifolium –acaricid ,insecticid
Achillea millefolium –antibiotic ,insecticide ;
Juglans nigra-insecticid ,antiviral ,nematocid ;
Anethum graveolens –fungicid ,acaricid ,insecticid
Cannabis sativa –insecticid ,acaricid ,fungicid
4. 3.6. Insecticide cloroderivate
In anul 1939 Muller a descoperit proprietatile insecticide ale DDT, produs in anul 1874 de Zeidel prin
condensarea clorbenzenului cu tricloroacetaldehida .
J.R. Geigy in anul 1942 in Elvetia il pune pe piata pentru combaterea insectelor vectoare : paduchii -vectorii
tifosului exantematic si tantarii -vectorii malariei . Muller a primit premiul Nobel pentru medicina deoarece a
rezolvat terapia tifosului exantematic european intrerupand lantul epidemiologic , combatand vectorii ,
paduchii de corp - insecte hematofage transmitatoarele bolii de la om la om .
Cloroderivatele actioneaza prin contact ,ingestie , iar mecanismul de actiune este hiperexcitatia sistemului
nervos ,vizibila prin miscari dezordonate , paralizia si in final moartea insectei . Cercetarile moderne au
evidentiat actiuni la nivelul sinapselor , neuromediatorilor,GABA in cazul endosulfanului si dienoclorului.
Toxicitatea este cronica, efectul cumulativ se deruleaza in organisme vegetale si animale , dar si in sol . DL 50
mediu al clasei organocloruratelor este 230 mg/Kg. Timpul de injumatatire este de ordinul anilor .Timpul de
pauza este mediu ,7- 21 zile la endosulfan .Stabilitatea la caldura ( termostabilitatea ) este ridicata ; stabilitatea
la lumina ( fotostabilitatea ) este buna ;stabilitatea la pH acid este foarte buna (191 zile-la pH=7,endosulfan ),
la pH bazic este mica (11ore –endosulfan la pH=9). Din familia cloroderivatelor DDT, cel mai utilizat insectid a
salvat viata a 25 000 000 de oameni supusi atacului tantarilor .
Cloroderivate :DDT , HCH , lindan , toxafen , aldrin , dieldrin , endrin , heptaclor , tiodan , clordan , izodrin ,
stroban , alodan , telodrin ,…
DDT -formula bruta C14H9Cl5 ; denumirea comuna : DDT ( ISO ) , zeidane (F), dicophane (BPC ) , cloropheothane
(USA);denumirea chimica:1,1,1-triclor-2.2bis –(4-clorfenil)-etan; p,p’-diclor-difenil-tricloretan.
pp’-DDT- cristale incolore ; punctul de topire =108,5 oC ; tensiunea de vapori la 20o C=1.9*10 -7 mm Hg
solubil in solventi polari organici ; insolubil in apa ; foarte solubili in solventi clorurati , aromatici ; stabilitatea
la stocare;bazele si fierul favorizeaza DL50 (oral)=113-118mg /Kg ; DL50(dermal) =2510mg/Kg ;DZA -
0,02mg/Kg . Modul de actiune :contact , ingestie , slaba actiune de soc , persistenta ..x luni.
Specialitati comerciale :Anofex , Arkotine , Dedelo , Diamekta , Neocid , Gesarol ,Guesarol , Detoxan -igiena
publica; Detox 25% , Detox 5% , Detox 10% , Duplitox3+5 ~contine: 3% HCH + 5% DDT –protectia plantelor .
Formulari:EC ,WP, DP ; mixturi: Supracide Combi 40EC ,Ultracide Combi40 EC , EC (250gDDT +150g metidation /l)
DDT
CHINESE: 滴滴涕; FRENCH: DDT (n.m.); RUSSIAN: ДДТ

IUPAC: 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane
CAS: 1,1′-(2,2,2-trichloroethylidene)bis[4-chlorobenzene]
REG. NO.: 50-29-3
FORMULA: C14H9Cl5
acaricides (bridged diphenyl acaricides; organochlorine acaricides)
ACTIVITY: insecticides (organochlorine insecticides)
DDT is the common name for the technical product; the pure compound has the ISO common name pp′-DDT.
The acronym is derived from an old and imprecise name, DichloroDiphenylTrichloroethane.
The name “clofenotane” is approved by the World Health Organization; the Chinese version is 滴滴涕 and the
Russian version is клофенотан.
NOTES: The name “dicophane” is approved by the British Pharmacopoeia Commission.
STRUCTURE:
PRONUNCIATION: dē dē tē Guide to British pronunciation

INCHIKEY: YVGGHNCTFXOJCH-UHFFFAOYSA-N
INCHI: InChI=1S/C14H9Cl5/c15-11-5-1-9(2-6-11)13(14(17,18)19)10-3-7-12(16)8-4-10/h1-8,13H
LIMERICK: According to Adam Bernard (adamb@bgumail.bgu.ac.il)
A mosquito cried out in pain:

“A chemist has poisoned my brain!”
The cause of his sorrow
Was para-dichloro
Diphenyltrichloroethane
Another version:
A mosquito was heard to complain

“I fear they have addled my brain!
The cause of my sorrow
Is para-dichloro-
Diphenyltrichloroethane”
HCH- Formula bruta chimica: C6H6Cl6 , hexaclor-ciclohexan -1825 ,Faraday ; insecticid descris de Racourt si
Dupire ,1942- Franta ; Slade , 1945- Anglia. HCH are 5 izomeri : alpha , beta , delta , epsilon , gamma .
Formulari :Hexacloran , Heclotox 1,5 PP , Heclotox 3PP , HCH
CHINESE: 六六六; FRENCH: HCH (n.m.); RUSSIAN: ГХЦГ

IUPAC: 1,2,3,4,5,6-hexachlorocyclohexane
CAS: 1,2,3,4,5,6-hexachlorocyclohexane
REG. NO.: 608-73-1
FORMULA: C6H6Cl6
insecticides (organochlorine insecticides)
ACTIVITY: rodenticides (organochlorine rodenticides)
The common name “BHC” is also approved by ISO.
The name “benzene hexachloride” is used in the USA; the name “hexachlor” is used in Sweden; the name
“hexachloran” (гексахлоран) was used in the former USSR.
NOTES: The ISO common name for the gamma-isomer is gamma-HCH.
STRUCTURE:
PRONUNCIATION: āch sē āch Guide to British pronunciation

INCHIKEY: JLYXXMFPNIAWKQ-UHFFFAOYSA-N
INCHI: InChI=1S/C6H6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-6H
Gamma HCH = Lindan denumirea comuna:HCH sau BHC ,
benzen hexaclorid (USA , BPC), gamma benzene hexacloride(ESA,USA,EPA,BPC ),hexaklor (Sweden ), linden ( ISO
), lindane(OMS);1,2,3,4,5,6-hexachlorocyclohexane (IUPAC);(1,2,4/3,4,6)-alpha; (1,3,5/2,4,6)-beta ;
(1,2,4,5/3,6)-gamma ;(1,2,3,5/3,6)-delta;(1,2,3/3,5,6)-epsilon; Descoperit in 1941- Franta , 1942 –Anglia , pe
piata a fost comercializat de ICI Plant Protection Ltd. sub marca inregistrata Gammexane . formula bruta: C 6H6
Cl6 denumirea chimica: Γ-hexaclorciclohexan ; 1,2,3,4,5,6-
hexaclorciclohexan . DL 50(oral)=88-91 mg / Kg ; DL50 (dermal) = 1000 mg /Kg; cristale albe ; punct de
topire=112,9o C ;presiunea de vapori la 20 o C = 9,4*10 -6mm Hg Solubilitatea in apa -7 mg/l ,>50 g/l acetona ,
benzen , etanol , toluen , dietil eter, etil acetat , greu solubil in ulei mineral ; stabil la lumina , caldura < 180 o, in
aer , in mediu puternic acid , instabil in mediu bazic (191 zile la pH 7; 11ore la pH 9) , fiind declorurat ; Mod de
actiune :contact , ingestie , respiratie unde sunt insecte sensibile
Specialitati comerciale :Lindatox 3PP,Lindan 20CE, Lintox , Lindafor , Silvanol ,Gallogama , Gammex,
Exagama ,Gammahexane ,Gammexane -igiena publica F B-7 , PEB +Lindan –protectia plantelor . gamma-HCH
CHINESE: 林丹; FRENCH: gamma-HCH (n.m.); RUSSIAN: гамма-ГХЦГ

IUPAC: 1α,2α,3β,4α,5α,6β-hexachlorocyclohexane
CAS: (1α,2α,3β,4α,5α,6β)-1,2,3,4,5,6-hexachlorocyclohexane
REG. NO.: 58-89-9
FORMULA: C6H6Cl6
acaricides (organochlorine acaricides)
insecticides (organochlorine insecticides)
ACTIVITY: rodenticides (organochlorine rodenticides)
The common name “gamma-BHC” is also approved by ISO.
The ISO common name for grades of gamma-HCH containing not less than 99% of the pure compound is
lindane.
The name “林丹” is approved in China for gamma-HCH and for lindane.
NOTES: The ISO common name for mixed isomers of hexachlorocyclohexane is HCH.
STRUCTURE:
PRONUNCIATION: gǎm-a āch sē āch Guide to British pronunciation

INCHIKEY: JLYXXMFPNIAWKQ-GNIYUCBRSA-N
INCHI: InChI=1S/C6H6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-6H/t1-,2-,3-,4+,5+,6+
Endosulfan -amestec de 2 izomeri:alpha / beta - endosulfan + endosulfan ;sinonimii : thiodan (Iran , URSS),
benzoepin ( Japonia ), exception (Italia). denumirea chimica: CC’-dimetil sulfit
6,7,8,9,10,10-hexacloro-1,5,5a,6,9,9a-hexahydro-6-9-metano-2,4 benzodioxatiepin 3-oxide ;
1,4,5,6,7,7-hexacloro-5-norbornene-2,3-dimetylciclic sulfit
(1,4,5,6,7,7-hexacloro-8,9,10-trinorborn-5=en-2,3-ylenbismetilen)sulfit ;
–cristale brune , miros deSO2 ( pucioasa); punct de topire 70 – 100 o C ; presiunea de vapori 1,2Pa ;
solubilitate alpha-endosulfan (22 o) - 0,32 mg / l apa; beta-endosulfan-0,33 mg / l apa ; 200g s.a. / l
diclorometan acetat de etil , toluen ; 65 g / l etanol ; 24 g /l hexan ;
Mod de actiune : contact , ingestie , nesistemic ;insecticid , acaricid Formulari:EC (161 ,357 , 480 g /l ), WP
(164 ,329 ,470 g/Kg ), DP (30-47g/Kg), GR (10 ,30 ,40 ,50 g/Kg), UL(242 ,497 ,604 g/l)
mixturi :(endosulfan +dimetoat , endosulfan+paration ), Quinolate MG’ , FS , (endosulfan + antrachinona + gHCH +
oxina de Cupru) , Quinolate MG SOPRA ,Total ,Ceregram ,
Specialitati comerciale :introdus de Hoechst AG ;Thiodan ,Cyclodan , Beosit , Malix ,Thimul endosulfan
CHINESE: 硫丹; FRENCH: endosulfan; RUSSIAN: эндосульфан

1,4,5,6,7,7-hexachloro-8,9,10-trinorborn-5-en-2,3-ylenebismethylene sulfite
or
IUPAC: 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepine 3-oxide
CAS: 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin 3-oxide
REG. NO.: 115-29-7
FORMULA: C9H6Cl6O3S
acaricides (organochlorine acaricides)
ACTIVITY: insecticides (cyclodiene insecticides)
Commercial endosulfan consists of 2 components, alpha-endosulfan (which is an ISO common name) and
beta-endosulfan.
The name “thiodan” is used in Iran and was used in the former USSR (тиодан), but Thiodan is a registered
trade mark in many countries. The name “benzoepin” is approved by the Japanese Ministry of Agriculture,
NOTES: Forestry and Fisheries.
STRUCTURE:
PRONUNCIATION: ěn-dō-sǔl-fǎn Guide to British pronunciation

INCHIKEY: RDYMFSUJUZBWLH-UHFFFAOYSA-N
INCHI: InChI=1S/C9H6Cl6O3S/c10-5-6(11)8(13)4-2-18-19(16)17-1-3(4)7(5,12)9(8,14)15/h3-4H,1-2H2
4.3.7. I n s e c t i c i d e o r g a n o f o s f o r i c e
Chimistii Schrader G. si Kukenthal H. in anul 1938 au descoperit proprietatile aficide ale TEPP . In anul 1943 in
Germania I.G. Farbenindustrie a sintetizat HETP-hexaetil tetraphosphat , nou principiu activ. TEPP, HETP sunt
substante organofosforice considerate promotorii principalei grupe chimice de insecticide .
Insecticidele organofosforice sunt esteri sau derivati ai acizilor fosforici , fiind fosfati , tiofosfati , ditiofosfati ,
fosfonati halogenati sau nu , alchili , heteroclici, alifatici (malation , dimetoat , terbufos ), vinilici ( mevinfos ,
diclorvos ), aromatice (diazinon , pirimifos) .
Insecticidele organofosforice penetreaza corpul prin contact , ingestie , stigme , actionand la nivelul sinapselor
si neuromediatorilor prin blocarea acetilcolinei.
Enzima acetilcolinesteraza este inactivata prin formarea de compusi fosforilati , hidroliza acetilcolinei se
blocheaza , concentratiile acetilcolinei la nivelul terminatiilor nervoase ale ganglionilor creste rapid , ireversibil
. Simptomatologia intoxicatiei cu insecticide organofosforice la insecte consta in hiperexcitatie , exteriorizata
prin tremuratul picioarelor si al aripilor , knock-down (caderea pe spate a insectei , paralizie generala si in
final moartea .
Toxicitatea este acuta ,osciland de la redusa la foarte toxice .
Timpul de pauza este variabil (7 -21 zile~majoritatea ) ,exista produse cu Tp , (DDVP ~2- 3 ore) ,chiar o luna
( vamidothion ).
Timpul de injumatatire este mic , iar persistenta in mediu este o luna.
Reologia(stiinta curgerii formelor) insecticidelor organofosforice este diferita :
-substantele nesistemice , exoterapice actioneaza in proximitatea locului de patrundere in organimul vegetal ,
animal , substrate …
-substante sistemice , endoterapice actioneaza in organismul animal sau vegetal oriunde este transportat de
seva bruta si /sau elaborata , hemolimfa , singe .
Solubilitatea insecticidelor organofosforice in apa si solventi organici este buna.
Corozivitatea pentru metale este variabila .
Substante active sistemice organofosforice : dimetoat , disulfoton , endotion , metamidofos , mevinfos ,
monocrotofos , oxydemeton –metil , forat , fosfamidon ,
terbufos , tiometon , vamidotion , acefat , heptenefos , dimefox , azametifos ,…
Substante active nesistemice (non sistemice )organofosforice : azinfos-etil , azinfos-metil , bromofos ,
clorfenvinfos , clorpirifos-etil , clorpirifos-metil , diazinon , diclorvos , etoprofos ,fenitrotion , fention , malation ,
parathion –etil , parathion –metil , fosalon , fosmet , pirimifos-etil , pirimifos –metil , quinalfos , tetraclorvinfos ,
triclorfon , temefos ,…
Substante active sistemice organofosforice perorale : dimetoat , endotion , metamidofos , mevinfos ,
monocrotofos , oxydemeton –metil , forat , fosfamidon ,
terbufos , tiometon , vamidotion , acefat , heptenefos , dimefox , azametifos ,…
Substante active nesistemice organofosforice perorale : azinfos-etil , azinfos-metil , bromofos , clorfenvinfos ,
clorpirifos-etil , clrorpirifos-metil , diazinon , diclorvos , fenitrotion , fention , malation , parathion –etil ,
parathion –metil , fosalon , fosmet , pirimifos-etil , pirimifos –metil , quinalfos , tetraclorvinfos , triclorfon ,
temefos ,…
Substante active sistemice organofosforice topice : dimetoat , metamidofos , mevinfos , monocrotofos ,
oxydemeton –metil , forat , fosfamidon , terbufos , acefat , heptenefos , dimefox , azametifos , metacrifos ,
vamidation ,omethoat .
Substante active nesistemice organofosforice topice : azinfos-etil , azinfos-metil, bromofos , clorfenvinfos ,
clorpirifos-etil , clorpirifos-metil , diazinon , diclorvos, etoprofos , fenitrotion , fention , malation , parathion –etil
, parathion –metil , fosalon , fosmet , pirimifos-etil , pirimifos –metil , quinalfos , tetraclorvinfos , triclorfon ,
temefos…..
Substante active sistemice organofosforice de respiratie :metacrifos , mevinfos , oxydemeton –metil , dimefox ….
Substante active nesistemice organofosforice de respiratie : clorpirifos-metil , diazinon , diclorvos , fention ,
malation , parathion –etil , parathion –metil , fentoat , fosmet , triclorfon , metidation
Termostabilitatea este buna .Fotostabilitatea este foarte buna.
Stabilitatea la pH < 6 este foarte buna(2-4 luni) ; buna la pH=7 (30-40 zile) , slaba la pH <7 (3 zile-pH=9 ;
1,4ore… ore-pH=11).
Selectivitatea este medie (mica~~foarte buna)
Compatibilitatea cu produse cu pH neutru , acid , exceptii : zemurile clasice (zeama bordeleza ,zeama burgunda,
zeama californiana , polisulfura de bariu).
TEPP-
formula chimica bruta :C8 H20H7P2 denumire comuna: TEPP (BSI , E-ISO ,F-ISO , ESA ), etil-pirofosfat (BPC ) , tetra
etil pirofosfat ( I ), tetraetil difosfat (9CI ) -primul organofosforic cu proprietati insecticide aficide
-descoperit de G. Schrader si H. Kukenthal . - inclus de I .G .Farbenindustrie in hexaetil tetrafosfat , HETP , in
anul 1943, iar dupa al doilea razboi mondial a fost inclus in produse noi: Nifos T- Monsanto si in Vapone –
Chevron Chemical .
TEPP-lichid colorat higroscopic , punct de fierbere 124 oC /1mm Hg ;presiunea de vapori-21 mPa (20oC);
analiza :produs-hidroliza selectiva ; reziduu-glc (gas-liquid chromatography) .
solubilitatea-miscibil in apa si solventii organici importanti ; hidrolizeaza rapid in apa ,Ti 50 ~(50 % TEPP
descompus in) 6-8 ore la pH=7 si 25oC La 170 oC se descompune in etilena .Este coroziv pentru principalele
metale . TEPP- nesistemic , aficid , acaricid . DL50 orala acuta pentru sobolan -1,12 mg /Kg ;DL50-cutanat la
sobolan mascul2,4mg /Kg; metabolizare rapida de animale.
Formulari: AE-solutie in metil clor
TEPP
CHINESE: 特普; FRENCH: TEPP (n.m.); RUSSIAN: ТЕПП

IUPAC: tetraethyl pyrophosphate
CAS: tetraethyl diphosphate
REG. NO.: 107-49-3
FORMULA: C8H20O7P2
acaricides (organophosphate acaricides)
ACTIVITY: insecticides (organophosphate insecticides)
NOTES: The name “ethyl pyrophosphate” is approved by the British Pharmacopoeia Commission.
STRUCTURE:
PRONUNCIATION: tē ē pē pē Guide to British pronunciation

INCHIKEY: IDCBOTIENDVCBQ-UHFFFAOYSA-N
INCHI: InChI=1S/C8H20O7P2/c1-5-11-16(9,12-6-2)15-17(10,13-7-3)14-8-4/h5-8H2,1-4H3
Paration
- parathion-ethyl - descoperit de Schrader in Germania , citat in anul 1946 , Martin H., Shaw H...
pus pe piata deAmerican Cyanamid , Bayer, ICI Plant Protection , Monsanto …
Formula chimica bruta :C10H14NO5PS denumirea comuna :parathion(E-ISO , ESA ,BSI ), thiophos (URSS) ,
denumirea chimica :O,O-diethyl O-(4-nitrophenyl ) phosphorothioate;
analiza: produs-hplc , glc ; titrare redox …;reziduu - glc ;
lichid galben pal ; punct de fierbere-157-162oC / 0,6mmHg ; tensiunea de vapori=5mPa(20oC ) ; densitatea =
1,265g/l ; solubilitatea -24mg /l apa (25oC);in ulei de petrol –putin solubil ; produsul tehnic- lichid brun ,
cu miros de usturoi; in mediu alcalin hidrolizeaza. Actiune nesistemica de contact , insectida , acaricida , ~
fumigant; nefitotoxic, cu mici exceptii la unele plante ornamentale .Eficace la combaterea insectelor tericole. DL 50
acuta orala:sobolan(13 mg/Kg masculi;3,6mg/Kg femele);2,5mg/Kg porc.DL 50 acuta cutanata :sobolan (21mg /Kg
masculi;6,8/Kg femele);LC50 (96ore) pastrav curcubeu -1,5mg/l ; DZA om-0,005mg/Kg .
Formulari :WP , EC , DP , AE ,GR , CS , FU mixturi:-cu ulei( Paratoil E EC , Oleo-Bladan ); -cu substante active
insecticide 100g parathion + 200g malation +270g metoxiclor/Kg~ Saitofos ; 90g parathion+120g gamma-HCH/l ~
Sopragam.-paration+tiometon~Thilonan;Ekatin WF,UL (60g parathion+150g thiometon/l) parathion
CHINESE: 对硫磷; FRENCH: parathion (n.m.); RUSSIAN: паратион

IUPAC: O,O-diethyl O-4-nitrophenyl phosphorothioate
CAS: O,O-diethyl O-(4-nitrophenyl) phosphorothioate
REG. NO.: 56-38-2
FORMULA: C10H14NO5PS
ACTIVITY: insecticides (phenyl organothiophosphate insecticides)
The name “thiophos” (тиофос) was used in the former USSR.
NOTES: The analogous dimethyl ester has the ISO common name parathion-methyl.
STRUCTURE:
PRONUNCIATION: pǎr-a-thī-ǒn Guide to British pronunciation

INCHIKEY: LCCNCVORNKJIRZ-UHFFFAOYSA-N
INCHI: InChI=1S/C10H14NO5PS/c1-3-14-17(18,15-4-2)16-10-7-5-9(6-8-10)11(12)13/h5-8H,3-4H2,1-2H3
Parathion-methyl
descris de Schrader G. ,1952. Bayer AG il pune pe piata sub denumirea Folidol-M , Metacide M , Nitrox 80 .
Formula bruta :C8H10NO5PS Denumirea comuna :Parathion-methyl (BSI ,E-ISO) , methyl parathion (ESA , JMAF ),
metaphos (USSR) .
analiza: produs – hplc , glc , hidrolizare + colorimetrie ; reziduu - glc
Denumirea chimica :O,O-dimethyl O-(4-nitrophenyl) O-4-nitrophenyl phosphorothioate(9CI) ;O,O-dimethyl O-(p-
nitrophenyl )phosphorothioate(8CI). pur -cristal colorant; punct de topire 35-36 oC; presiunea de
vapori-1,3mPa/20oC. produsul tehnic-80% este lichid colorat deschis~inchis; densitatea 1,2-1,22 ; hidrolizeaza in
mediu alcalin in izomeri O,S-dimethyl. Insecticid nesistemic ,de contact , ingestie, ~àctiune fumiganta , nu
cumuleaza . concentratia utilizare ~15-20 g s a/100l . DL50 orala acuta la sobolan:~ mascul -14 mg/Kg , ~femela-24
mg/Kg ; DL50 acuta cutanata la sobolan -67 mg/Kg+ NEL –mg /Kg hrana;DZA om -0,02mg/Kg .
Formulari EC , WP , DP : Fostox Metil ; Penncap-M; Penntox MS ; Methyl-bladan 40EC (200, 400 g /l ) ;Methyl-
bladan 2 DP (20 g /l ); amestecuri paration-metil:150g/l +250g dicofol/l =Kelthane Mixte ; 12,5 g +20 g dicofol +700
g sulf / Kg= Kriss M Soufre; + diverse cloroderivate(lindan ,endosulfan ), organofosforice (fosalon , fenson )...
parathion-methyl
CHINESE: 甲基对硫磷; FRENCH: parathion-méthyl (n.m.); RUSSIAN: паратион-метил

IUPAC: O,O-dimethyl O-4-nitrophenyl phosphorothioate
CAS: O,O-dimethyl O-(4-nitrophenyl) phosphorothioate
REG. NO.: 298-00-0
FORMULA: C8H10NO5PS
The name “metaphos” (метафос) was used in the former USSR.
The name “methyl parathion” is used in the USA and is approved by the Japanese Ministry of Agriculture,
Forestry and Fisheries.
NOTES: The analogous diethyl ester has the ISO common name parathion.
STRUCTURE:
PRONUNCIATION: pǎr-a-thī-ǒn mē-thīl Guide to British pronunciation

INCHIKEY: RLBIQVVOMOPOHC-UHFFFAOYSA-N
INCHI: InChI=1S/C8H10NO5PS/c1-12-15(16,13-2)14-8-5-3-7(4-6-8)9(10)11/h3-6H,1-2H3
Diazinon
descris de Gasser H., 1953; Introdus de Geygi J. R. S A Basudin , Diazitol , Neocitol , Nucidol
formula chimica:C12 H21 N2 O3 P S;denumirea comuna :diazinon ( BSI , ESA , BPC , JMAF ) , dimpylate ( BPC)
analiza :produs –glc ;reziduu –glc prin TID ( termo ionic detection ) , MCD .
denumirea chimica :O,O-diethylO-[6-methyl-2-(1-methylethyl)-4-pyrimidinyl]phosphorothioate(9CI);
O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphoroththioate (C.A.).
–lichid clar colorant;punct de fierbere 83 -84 oC/0,0002mmHg ; presiune de vapori 0,097mPa (20oC);
densitatea 1,11 g/cu. cm ; solubilitatea 40 g/l apa ;miscibil in acetona , benzen , cyclohexan , diclormetan , dietil
eter , etanol , toluen , octan-1-ol ;stabilitatea la 20 oC hidrolizeaza: ~12 ore la pH=3,1 ;185 zile la pH=7,4 ;6 zile la
pH=10,4 ; se descompune >120 oC ; insecticid nesistemic la culturi de camp (porumb, cartof ,orez , tutun , trestie de
zahar ), horticole ,vita de vie , culturi protejate , medicina veterinara .
DL50 acuta orala sobolan ~300 -400 mg/p.tehnic ;DL50 acuta cutanata sobolan > 2150mg /Kg; slab iritant cutanat si
ocular la iepure . LC50 inhalare (4 ore) ~ 3,5 mg /l aer NEL: 1) sobolan (90zile)~0,1mg/Kg /zi; 2)caine~o,o2mg/Kg/zi;
LC50 (96ore) pastrav ~2,6mg/Kg ;crap~7,6-23,4mg/l ; 16mg/l. Nu e toxic pentru albine si pasari .
DZA(ADI)=0,002mg/Kg/zi; Formulari :Basudin 10(100g/Kg)GR ;Basudin40WP(400g/Kg); Diazostar(60%); Knox Out
flowable microcapsule(230g/l);Basudin 60 EC (600g/l );Fyfanol 50EC (500g/l) ; Pallas50 EC(500 g/l ); Basudin 20
Mushroom Aerosol . Mixari: piretrin+diazinon;Ethidimethon 6, Ethimeton 6(30gdiazinon+ 30g disulfoton);
Oleodiazol3CE(32g diazinon+ulei mineral ). diazinon
CHINESE: 二嗪磷; FRENCH: diazinon (n.m.); RUSSIAN: диазинон

IUPAC: O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphorothioate
CAS: O,O-diethyl O-[6-methyl-2-(1-methylethyl)-4-pyrimidinyl] phosphorothioate
REG. NO.: 333-41-5
FORMULA: C12H21N2O3PS
bird repellents
ACTIVITY: insecticides (pyrimidine organothiophosphate insecticides)
The name “dimpylate” is approved by the World Health Organization; the Chinese version is “敌匹硫磷” and the
NOTES: Russian version is “димпилат”.
STRUCTURE:
PRONUNCIATION: dī-ǎz-ǐn-ǒn Guide to British pronunciation

INCHIKEY: FHIVAFMUCKRCQO-UHFFFAOYSA-N
INCHI: InChI=1S/C12H21N2O3PS/c1-6-15-18(19,16-7-2)17-11-8-10(5)13-12(14-11)9(3)4/h8-9H,6-7H2,1-5H3
Dimethoate
descris de Hoegberg E.I .,1951 Introdus de American Cyanamid , BASF AG. ,
denumirea comuna :dimethoate (BSI , E-ISO , ESA ,JMAF ); fosfamid (USSR)
denumirea chimica :2-dimethoxyphosphinothioylthio-N-methilacetamide( C.A )
O,O-dimethyl S-methylcarbamoylmethyl phosphorodithioate ; formula chimica bruta :C 5H17NO3PS2
analiza :produs –glc ;tlc(thin-layer chromatography)~P[spot apr];reziduu –glc .
dimetoat pur-cristale colorate ; punct de topire ~51-52 oC ; presiunea de vapori :1,1 mPa (25oC)
densitatea 1,281; produsul tehnic~cristale alb-gri ; punct de topire 45 -47oC ; solubilitate apa 25g/l >300 g /Kg
alcool , benzen , cloroform , diclormetan , toluen , cetone. . >50g/Kg tetraclorura de carbon , hidrocarburi
saturate . Stabilitatea buna in mediu apos cu valori pH=2 -7. La pH 9 este incompatibil cu produse alcaline , se
descompune in O,S-dimethyl . Insecticid , acaricid , cu actiune sistemica , la doze 300-700 g s a / ha culturi
diverse si daunatori , nefitotoxic (citrus , smochin , maslin , alun ) .DL50 oral acut sobolan: mascul 500 -600
mg /Kg , femela 570 -680 mg / Kg; fazan -15 mg /Kg ; rata -40 mg /Kg ;DL50 acuta cutanata la sobolan
>800mg/kg. La iepure 130 mg s a /20 cm2 -- . DL50 albina 0,0009mg /ex .LC50 aplicat pentru tantari (96h)~ pesti
40 -60 mg /Kg . NEL om in timp <57 zile ~15 mg /zi ; DZA om 0,002 mg / Kg .
Formulari :Bio Systemic Insecticide , Vitex (EC 200,400,600 g /l ); RogorAS UL(300 g /l) ;Turbair Systemic Insecticide
UL ,WP (200g/Kg) ; GR(20g/Kg). Roxion ,Cygon , Sinoratox 35CE , Perfektion , Devignon , Dimevur ,Trimetion,
Sintogryll 5G , Sinoratox 35CE ;Sinoratox 5G ,10G . Diazostar (diazinon 60%); Dimetox (diazinon 350 g/l );Dimezyl 40
EC (dimetoat 400g/l ; Novadim 40EC ( dimetoat 400 g/l ) .
Amestec :Bio Long Last(dimetoat+permetrin) ;Sinoratox Plus (dimetoat 300 g/l +cipermetrin
5g/l ) ;Mikant(dimetoat +fenvalerat) ;dimetoat +endosulfan . dimethoate
CHINESE: 乐果; FRENCH: diméthoate (n.m.); RUSSIAN: диметоат*

O,O-dimethyl S-methylcarbamoylmethyl phosphorodithioate
or
IUPAC: 2-dimethoxyphosphinothioylthio-N-methylacetamide
CAS: O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] phosphorodithioate
REG. NO.: 60-51-5
FORMULA: C5H12NO3PS2
insecticides (aliphatic amide organothiophosphate insecticides)
NOTES: * The name “phosphamide” (фосфамид) was used in the former USSR.
STRUCTURE:
PRONUNCIATION: dī-měth-ō-āt Guide to British pronunciation

INCHIKEY: MCWXGJITAZMZEV-UHFFFAOYSA-N
INCHI: InChI=1S/C5H12NO3PS2/c1-6-5(7)4-12-10(11,8-2)9-3/h4H2,1-3H3,(H,6,7)
Malation
formula bruta C10H19O6PS2 ; denumire comuna :malathion (BPC , ESA , E-ISO ); maldison (Australia , Noua
Zeenlanda );malathon (JMAF); mercaptothion (Republica Sud Africana ); carbofos ( URSS );
analiza:produs –glc ;reziduu –glc .
denumirea chimica :diethyl(dimethoxyphosphinothioylthio) succinate ; introdus de American Cyanamid Co. sub
denumirea Cythion .malathion 95% -lichid limpede ambra (chilimbar = galben /oranj). punct de topire 2,85 oC ;
punct de fierbere 156-157oC ;presiunea de vapori 5.3 mPa (30oC); densitatea 1,23.
Solubilitate 145 g/l apa ;miscibil in majoritatea solventilor organic (ulei de petrol 350 g in 1 l malathion );
Utilizare: insecticid nesistemic , acaricid , nefitotoxic (exceptand castravetii , fasolea verde , dovleceii - in
sera),horticultura , ectoparaziti veterinari si umani ( paduchi de cap , paduchi de corp , purici), tantari .
DL50 acuta orala sobolan -2800mg/Kg; DL50 acuta cutanata (24 ore ) iepure -4100mg/Kg ;
LC50 prepelita 3497 mg/Kg dieta; fazan 4320 mg/Kg ; LC50 (96ore) biban-0,285mg/Kg ;
LD50 albine*****-710 ng / insecta ***** Toxicitate extrema***** DZA om - 0,02mg/Kg .
Formulari :CE (25-1000gs.a. / l )Fyfanol 50CE (500g/l ) ; Pallas 50CE(500g/l; UL(920g/l) – Malatox ,Fyfanon
Mixturi:Gryllosin 5G (4,8% fenitrotion + 0,3% malation); Saitofos EC (200g malation +270 gmetoxychlor +100 g
parathion / Kg ); Malatox P(475g malation +196 g parathion /Kg);Combat Vegetable Insecticide(malathion
+bioresmethrin) malathion
CHINESE: 马拉硫磷; FRENCH: malathion (n.m.); RUSSIAN: малатион*

diethyl (dimethoxyphosphinothioylthio)succinate
or
IUPAC: S-1,2-bis(ethoxycarbonyl)ethyl O,O-dimethyl phosphorodithioate
CAS: diethyl 2-[(dimethoxyphosphinothioyl)thio]butanedioate
REG. NO.: 121-75-5
FORMULA: C10H19O6PS2
ACTIVITY: insecticides (aliphatic organothiophosphate insecticides)
NOTES: * The name “carbophos” (карбофос) was used in the former USSR.
The name “maldison” is used in Australia and New Zealand, and the name “mercaptothion” is used in South
Africa.
STRUCTURE:
PRONUNCIATION: mǎl-a-thī-ǒn Guide to British pronunciation

INCHIKEY: JXSJBGJIGXNWCI-UHFFFAOYSA-N
INCHI: InChI=1S/C10H19O6PS2/c1-5-15-9(11)7-8(10(12)16-6-2)19-17(18,13-3)14-4/h8H,5-7H2,1-4H3
Chlorpyrifos
formula bruta C9H11Cl3NO3PS
analiza: produs hplc , uv detectie ; reziduuri – glc .
descris de Kenaga E.E. 1965 ; introdus de Dow Chemical Co.sub denumirea de Dursban , Lorsban .
denumire comuna :chlorpyrifos (BSI , E-ISO , ESA ,F-ISO , JMAF ) ; chlorpyriphos-ethyl (Franta) ;
denumirea chimica:O,O-diethyl O-3,5,6-tricloro-2-pyridyl phosphorothioate(CA)
O,O-diethyl O-(3,5,6-trichloro-2-pyridyl )phosphothioate (8 CI)
Cristale colorate , cu miros mediu de mercaptan ; punct de topire 42-43, oC ;presiunea de vapori -2,5 mPa (25oC)
solubilitate : -apa (25oC )2mg / l ;-acetona 6,5Kg/l ; -benzen 7,9 Kg /Kg ;-cloroform 6,3 Kg /Kg ; N-metanol 450
g/Kg ;coroziv pentru cupru , alama; hidroliza ~pH , t oC , prezenta cuprului , bronzului formand chelati ;la pH=8 ,
toC=25oC,stabilitate = 1,5 zile ;la pH=7 , toC=15oC , stabilitate=100zile .
Utilizari :insecticid nesistemic cu actiune de contact , ingestie , prin vapori . la om paduchi , tantari ,ectoparazitii
de oi , bovine; in vegetatie , foliar , la sol , nefitotoxic in concentratii uzuale ; Se degradeaza in sol in 3,5,6-
tricloropyridin-2-ol , …in compusi cloroderivati si dioxid de carbon .persistenta in sol ~60-120 zile .
DL50 oral acut:- sobolan ~135-163mg/Kg ;-porci de Guinea~500mg/Kg;-pui ~ 32mg/Kg;-iepuri~1000-2000mg/Kg ;
DL50 acuta cutanata~iepuri 2000mg/Kg ;NEL –sobolan ~0,03mg/Kg zi;caine~0,01mg/Kg zi ;
LC50(96h)pastrav curcubeu-0,003mg/Kg ; DZA om 0,01 mg/Kg .
Formulari:Dursban , Lorsban ,EC (240 ,480 g/Kg ); UL(240g/l);GR (50,75 ,100g/Kg);GR (50 ,75 , 100g/Kg );Spannit EC
(480g/l ); Clorifos 48 EC (clorpirifos 48% );Magic 20 EC (200 g clorpirifos /l) ; Sonata(480 g clorpirifos / l ) ;
Amestecuri :Nurelle 50/500EC (50 g cipermetrin + 500 g clorpirifos /l ;Pyrinex Quick(250 gclorpirifos + 6 g
deltametrin /l ); Twin Span GR (40g clorpirifos+60 g disulfoton /Kg );
chlorpyrifos
CHINESE: 毒死蜱; FRENCH: chlorpyriphos* (n.m.); RUSSIAN: хлорпирифос

IUPAC: O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate
CAS: O,O-diethyl O-(3,5,6-trichloro-2-pyridinyl) phosphorothioate
REG. NO.: 2921-88-2
insecticides (pyridine organothiophosphate insecticides)
* The name “chlorpyriphos-éthyl” (n.m.) is used in France.
NOTES: The analogous dimethyl ester has the ISO common name chlorpyrifos-methyl.
STRUCTURE:
PRONUNCIATION: klor-pǐr-ǐ-fǒs Guide to British pronunciation

INCHIKEY: SBPBAQFWLVIOKP-UHFFFAOYSA-N
INCHI: InChI=1S/C9H11Cl3NO3PS/c1-3-14-17(18,15-4-2)16-9-7(11)5-6(10)8(12)13-9/h5H,3-4H2,1-2H3
Chlorpyrifos –methyl
formula bruta : C7H7Cl3NO3PS
analiza : produs -hplc ; reziduuri -glc
descris de Rigterink R .H . si Kenaga E. E. 1966 ; introdus de Dow Chemical Co. sub denumirea de Reldan .
denumirea comuna chlorpyriphos-methyl (BSI , E-ISO , ANSI, F-ISO , JMAF ) denumirea chimica O,O-dimethyl O-
3,5,6-trichloro-2-pyridyl phosphorothioate (CA);O,O-dimethyl O-( 3,5,6-trichloro-2-pyridyl ) phosphothhioate (9CI )
cristale colorate ;miros slab de mercaptan ;punct de topire 45,5 -46,5 oC ;
presiunea de vapori 5,6mPa (25oC); solubilitatea : -apa~4 mg/ l ;-acetona~ 6,4 Kg / Kg;-benzen~5,2 Kg /Kg ;
-hexan~230 g /Kg ;-cloroform~3,5 Kg /Kg ;-metanol~300 g /l ;stabil la pH neutru ; hidrolizeaza in mediu acid ( pH 4
-6 ); hidrolizeaza rapid in mediu bazic (pH 8-10).
Utilizari :insecticid de contact , ingestie , prin vapori ; combaterea larvelor in apa , purici , tantari adulti , insecte de
depozit , daunatori foliari si de sol ,… degradare initial in 3,5,6-trichloropyridin-2-ol , compusi organoclorurati ,
dioxid de carbon .
DL50 acuta orala:- la sobolan ~1630-2140 mg /Kg ;-iepure~2000 g /Kg ;-pui 7950mg /Kg(aplicare capsule); NEL 0,1
mg /Kg zi la caine ,sobolan .LC50 (36ore) la rac -0,004mg /Kg ;
LC50 (36 ore ) –pastrav curcubeu 0,3 mg/l . DZA om 0,01mg /Kg .
Formulari :Reldan EC (240 , 500 g s.a./ l ) ,UL (25 g s.a./ l ); Reldan 40 EC (400g/l) tratamentul daunatorilor de
depozit . chlorpyrifos-methyl
CHINESE: 甲基毒死蜱; FRENCH: chlorpyriphos-méthyl (n.m.); RUSSIAN: хлорпирифос-метнл

IUPAC: O,O-dimethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate
CAS: O,O-dimethyl O-(3,5,6-trichloro-2-pyridinyl) phosphorothioate
REG. NO.: 5598-13-0
ACTIVITY: insecticides (pyridine organothiophosphate insecticides)
NOTES: The analogous diethyl ester has the ISO common name chlorpyrifos.
STRUCTURE:
PRONUNCIATION: klor-pǐr-ǐ-fǒs mē-thīl Guide to British pronunciation

INCHIKEY: HRBKVYFZANMGRE-UHFFFAOYSA-N
INCHI: InChI=1S/C7H7Cl3NO3PS/c1-12-15(16,13-2)14-7-5(9)3-4(8)6(10)11-7/h3H,1-2H3
Fenitrotion
formula bruta :C9H12NO5PS; denumirea comuna:fenitrothion (BSI ,E-ISO, F-ISO , ESA,BPC);MEP(JMAF). descris de
Nishizawa Y. ,1961; introdus de Sumitomo Chemical Co. si de Bayer AG., American Cyanamid Co.
denumirea chimica :O,O-dimethyl O-4-nitro-m-tolyl phosphorothioate (C.A.);
O,O-dimethyl O-(4-nitro-m-tolyl)phosphorothioate (9CI ).
analiza:produs –glc ; reziduu –glc .
fenitrotion tehnic- lichid galben-brun , punct de fierbere 140-145 oC /0,1 mm Hg. densitatea 1,32 -1,34 .
solubilitatea : -apa (30oC) 14mg /l ;-diclormetan , methanol , xylen >1Kg /Kg ; -hexan 42g / Kg ;-propan-2– ol 0,1-1
Kg / Kg . hidrolizeaza 50% in alcalin 30oC in 4,5 ore (10M hidroxid de sodiu ).
Utilizare : insecticid de contact , insecte care rod , mineaza si sug , insecte vectoare la malarie (tantari ) ,
ectoparaziti umani cuprinsi pe listele WHO , lacuste( FAO , USAID ,OCLALAV ).
DL50 acuta orala sobolan femele 800 mg /Kg ; DL50 cutanata acuta sobolan –mascul 890mg /Kg , femela 1200mg
/Kg .NEL-sobolan 5mg / Kg dieta . LC50 (48ore)-crap 4,1mg /l . DZA om 0,003mg /Kg .
Formulari :EC ( Dicofen 500g /l );WP (400 g /Kg );DP (20 ,30,50g /Kg );UL (1,25Kg /l) ;AE (Novathion )
Amestecuri : Gryllosin 5G (4,8% fenitrotion + 0,3% malation ) ; Danitol S , Sumimix EC ( fenpropatrin + fenitrotion ) ;
Dicontal Fort WP (200g triclorfon +200 g fenitrotion ) ; Pesguard NT , Sumithion L 40S , Sumithion NP EC , Sumithion
Plus EC, SL , AE ( fenitrotion + tetrametrin ) ; Sumibas , Sumibassa UL , SL , AE (450 g fenitrotion + 300 g
fenobucarb / l ); Sumicombi EC ,UL (fenitrotion + fenvalerat ); Sumithion M 1000 E EC
(fenitrothrotion + malathion ) . fenitrothion
CHINESE: 杀螟硫磷; FRENCH: fénitrothion (n.m.); RUSSIAN: фенутротион

IUPAC: O,O-dimethyl O-4-nitro-m-tolyl phosphorothioate
CAS: O,O-dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate
REG. NO.: 122-14-5
FORMULA: C9H12NO5PS
The name “MEP” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
NOTES: The name “methylnitrophos” (метилнитрофос) was used in the former USSR.
STRUCTURE:
PRONUNCIATION: fě-nī-trō-thī-ǒn Guide to British pronunciation

INCHIKEY: ZNOLGFHPUIJIMJ-UHFFFAOYSA-N
INCHI: InChI=1S/C9H12NO5PS/c1-7-6-8(4-5-9(7)10(11)12)15-16(17,13-2)14-3/h4-6H,1-3H3
Triclorfon
formula bruta:C4H8Cl3O4P ; descris de Unterstenhofer G. , 1957 ; Preparat de Lorenz W.
Introdus pe piata de Bayer AG sub denumirea Dipterex , Neguvon , Dylox(USA);denumirea comuna:trichlorfon (E-
ISO , F-ISO ), chlorophos ( USSR ) ; metriphonate ( BPC ) , dipterex (excep. Turcia ). denumirea chimica dimethyl
2,2,2-trichloro-1-hydroxyethylphosphonate (CA);dimethyl 2,2,2-trichloro1hydroxyethylphosphonate(C
analiza:produs –polarograf ; titrarea ionilor clorati obtinuti prin hidroliza ; reziduu – glc .
-pudra cristalina colorata , solid.punct de topire 83-84 oC ;presiunea de vapori 1,0 mPa(20 oC );densitatea 1,73;
solubilitatea (25oC) :-apa 154 g /l ;-benzen , etanol , etanol , hidrocarburi clorurate , insolubil in ulei de petrol ; putin
solubil in tetraclorura de carbon , dietil eter; stabil la temperatura camerei ;la pH <5,5 in apa calda se descompune
in diclorvos .
Utilizari:insecticide de contact , ingestie , cu actiune penetranta( larve de fluturi, muste la fructe) , insecte parazite ,
ectoparaziti la animale domestice . DL 50
orala acuta sobolan:- mascul 560 mg /Kg ;-femela 630 mg /Kg ;DL 50 cutanata acuta sobolan >2000mg/ Kg .
LC50 (48ore):-crap 6,2 mg /Kg/ l ;-goldfish >2000mg /Kg .
DZA 0,01mg /Kg .
Formulari :WP (500 g s.a./Kg );SP (500 , 800 ,950g /Kg ); SC (500 g /l );UL(250, 500,750 g /l ); GR(25 ,50 g /Kg)
Mixaje :WP (200g triclorfon + 200g fenitrotion /Kg ) trichlorfon
CHINESE: 敌百虫; FRENCH: trichlorfon (n.m.); RUSSIAN: трихлорфон*

dimethyl (RS)-2,2,2-trichloro-1-hydroxyethylphosphonate
or
IUPAC: (RS)-2,2,2-trichloro-1-(dimethoxyphosphinoyl)ethanol
CAS: dimethyl (P)-(2,2,2-trichloro-1-hydroxyethyl)phosphonate
REG. NO.: 52-68-6
FORMULA: C4H8Cl3O4P
acaricides (phosphonate acaricides)
ACTIVITY: insecticides (phosphonate insecticides)
The name “metrifonate” is approved by the World Health Organization; the Chinese version is “美曲膦酯” and
the Russian version is “метрифонат”.
* The name “chlorophos” (хлорофос) was used in the former USSR.
The name “DEP” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries. The name
“dipterex” was formerly used in Turkey, but Dipterex is a registered trade mark in many countries. The name
“metriphonate” was formerly approved by the British Pharmacopoeia Commission. The name “trichlorphon” was
formerly approved by the British Standards Institution.
NOTES: The butyrate ester has its own ISO common name, butonate.
STRUCTURE:
PRONUNCIATION: trī-klor-fǒn Guide to British pronunciation

INCHIKEY: NFACJZMKEDPNKN-UHFFFAOYSA-N
INCHI: InChI=1S/C4H8Cl3O4P/c1-10-12(9,11-2)3(8)4(5,6)7/h3,8H,1-2H3
Dichlorvos
descris de Ciba AG , nume DDVP , cu structura componentelor incorecta ; Marston A.M. ,1955 , raporteaza
impuritate in triclorfon . introdus pe piata de Ciba-Geigy ( Nuvan) , Shell (Vapona) , Bayer ( Apavap , Dedevap)
formula bruta :C4H7Cl2O4P ;denumirea comuna:dichlorvos (E-ISO , ESA ,F-ISO , BSI ); DDVP(JMAF); dichlorfos
( USSR );DDVF (exceptie USSR ).
analiza :produs - spectrometrie i.r. si ~ titrare cu iod(exces); reziduu-glc .
lichid colorant , galben ambra ;miros aromatic; punct de fierbere 35 oC /0,05 mm Hg;presiunea de vapori 1,6 Pa
densitatea 1,415; solubilitate in :-apa (20 oC) 10g /l ;-kerosen 2-3g/ Kg miscibil cu majoritatea solventilor organici
; stabil la caldura ;hidrolizeaza in apa , in solutie apoasa saturata ---dimethyl hydrogen, dicloroacetaldehida
3% /zi , rapid la pH alcalin . coroziv pentru fier si otel .
Utilizare: insecticid de contact , ingestie , cu actiune fumiganta si penetranta . combate :insecte igiena publica si
vectoare (diptere , tantari ); insecte la produse stocate~ 0,5 -1,0 g s a /100m 3;in vegetatie la insecte care
inteapa , sug si la insecte care rod~ 300 -1000 g / ha . nefitotoxic ,(-crizantema), nepersistent
antihelmintic in hrana animalelor DL50 orala acuta:- sobolan 56 -108mg /Kg;DL50 cutanata acuta:-sobolan 75-210
mg/Kg ; in a 90 zi sobolanul hranit cu 1000 mg / Kg dieta nu este intoxicat vizibil .LC 50 (24ore)1mg / l apa
caras !; soarece > 0,22 mg /l ;sobolan >0,20 mg /l aer ;
******Albine *****Foarte toxic****** pasari ****toxic DZA om 0,004 mg /Kg .

Formulari: EC Nogos ( 50 ,100 ); EC Nuvan(50 ,100 ); AE ( 4-10 g/l ); OL(1000 g /l ); GR ( 5g/Kg ).
Amestecuri :Baygon Spray (dichlorvos + cyfluthrin + propoxur ); Safrotin Liquid (5 g dichlorvos + 10 g
propetamophos / Kg); Safrotin Aerosol ( 5g dichlorvos + 20 g propetamophos /Kg );…
dichlorvos
CHINESE: 敌敌畏; FRENCH: dichlorvos (n.m.); RUSSIAN: дихлорвос

IUPAC: 2,2-dichlorovinyl dimethyl phosphate
CAS: 2,2-dichloroethenyl dimethyl phosphate
REG. NO.: 62-73-7
FORMULA: C4H7Cl2O4P
acaricides (organophosphate acaricides)
ACTIVITY: insecticides (organophosphate insecticides)
The name “DDVP” (ДДВФ) was used in the former USSR.
Mis-spelled versions of “dichlorvos” are common in the literature, including dichlorfos, dichlorofos, dichlorophos,
dichlorovos and dichlorphos.
NOTES: This substance is a component of another pesticide, calvinphos.
STRUCTURE:
PRONUNCIATION: dī-klor-vǒs Guide to British pronunciation

INCHIKEY: OEBRKCOSUFCWJD-UHFFFAOYSA-N
INCHI: InChI=1S/C4H7Cl2O4P/c1-8-11(7,9-2)10-3-4(5)6/h3H,1-2H3
4. 3.8. I n s e c t i c i d e c a r b a m i c e
Primul produs fitosanitar carbamic , metam de sodium , care a apărut în anul 1951, avea acţiune
fumigantă nematocidă. Prima substanţa carbamică cu proprietăţi insecticide a fost carbaril , descris de Haynes
H. L. în anul 1957, fiind pus pe piaţă de Union Carbide , marca Sevin .Semnalarea rezistenţei populaţiilor de
insecte la cloroderivate , organofosforice a impulsionat sinteza de noi molecule de carbamaţi . Grupa
carbamatilor cuprinde substante cu acţiune insecticidă , acaricidă , moluscocidă , nematocidă, fungicidă
erbicidă . Insecticidele carbamice sunt derivaţi ai acidului carbamic (monoamida acidului carbonic , HO-CO-NH 2 ,
instabilă în stare liberă , descompunându-se rapid în CO 2 şi NH3) .
Insecticidele carbamice pătrund în corpul insectelor prin contact , ingestie , respiraţie , unde acţionează la nivelul
sinapselor colinergice inhibând acţiunea enzimei colinesteraza prin formarea” carbamil-derivat” . Compusul
format va bloca hidroliza acetilcolinei în colinesteraza şi gruparea acetil , reacţia fiind reversibilă în cazul
intoxicării cu carbamaţi . Toxicitatea este acută :- foarte mare la produse de tratat sămânţa , carbofuran DL50
orală acută în ulei porumb la şobolan = 8 -14 mgs.a. / Kg , la câine 19 mg s.a. pudră uscată / Kg - medie la
majoritatea produse utilizate , carbaril -DL50 orală acută =850 mg /Kg , -mică la produsele mai noi , fenoxicarb
DL50% - 10 000 mg /Kg . Persistenţa este mică , de la câteva zile la câteva săptămâni .
Stabilitatea termică Stabilitatea la pH Selectivitatea Compatibilitatea
Substanţe carbamice cu acţiune insecticidă sunt :aldicarb , bendiocarb , benfuracarb , bensultap , carbaril ,
carbofuran , carbosulfan , dioxicarb , ethyophenacarb , fenoxycarb , formetanat , furathiocarb , isolan ,
mercaptodimethur , metham de sodiu , methomyl , promecarb , thiocarb , thiofanox , pyrimicarb .
Carbaril . carbaryl
CHINESE: 甲萘威; FRENCH: carbaryl (n.m.); RUSSIAN: карбарил

IUPAC: 1-naphthyl methylcarbamate
CAS: 1-naphthalenyl N-methylcarbamate
REG. NO.: 63-25-2
FORMULA: C12H11NO2
acaricides (carbamate acaricides)
insecticides (carbamate insecticides)
ACTIVITY: plant growth regulators (growth inhibitors)
The name “carbaril” is approved by the World Health Organization; the Chinese version is “卡巴立” and the
Russian version is “карбарил”.
The name “sevin” (цевин) was used in the former USSR, but Sevin is a registered trade mark in many
NOTES: countries.
STRUCTURE:
PRONUNCIATION: kar-ba-rīl Guide to British pronunciation

INCHIKEY: CVXBEEMKQHEXEN-UHFFFAOYSA-N
INCHI: InChI=1S/C12H11NO2/c1-13-12(14)15-11-8-4-6-9-5-2-3-7-10(9)11/h2-8H,1H3,(H,13,14)
descris de Haynes H.L. ,1957 ;

introdus de Union Carbide Corp.
formula brută :C12H11NO2
denumirea comună:carbaryl ( E-ISO , F-ISO , ANSI, ESA , BPC , BSI ); sevin (URSS); NAC ( JMAF );
denumirea chimică :1-naphtyl methylcarbamate (I ); 1-naphthalenyl methylcarbamate (9CI);
analiză:produs–i.r. spectroscopie ;reziduu -glc .
produs solid cristalizat colorat ;
punctul de topire 142oC ;
presiunea de vapori <665 mPa (26oC);
Densitatea 1,232
solubilitatea (30oC) 120 g / l apă ;400 -450 mg/Kg dimethylformamide (25 oC) , dimetil sulfoxid ; stabilitatea
<70oC , la lumină ;hidrolizează la 1-naphtol -pH>9
incompatibil cu produse cu pH puternic alcaline ;
utilizări :insecticid de contact , ingestie , cu slabe proprietăţi sistemice ,0,25-2,0Kg s.a. /ha bumbac , legume ,
fructe , alte culturi. Toxicitatea acută orală DL 50 şobolan mascul 850 mg /Kg ;la şobolan în anul 2
după aplicarea 200 mg/Kg dietă nu au fost efecte nefaste; toxic pentru albine ; CL 50 peşti -5-13 mg/l ;
DZA om = 0,01 mg /Kg
Formulări: WP (500 , 800 ,850 g s.a. /Kg ;GR (50g s.a./Kg ); DP (50-100 g /Kg);SC ,OF ( 220 , 300 , 400 , 440 , 480
g/l ; Mixaje:Naftil acaricide , WP (carbaril + clorfenson)
Aldicarb aldicarb
CHINESE: 涕灭威; FRENCH: aldicarbe (n.m.); RUSSIAN: альдикарб

IUPAC: (EZ)-2-methyl-2-(methylthio)propionaldehyde O-methylcarbamoyloxime
CAS: 2-methyl-2-(methylthio)propanal O-[(methylamino)carbonyl]oxime
REG. NO.: 116-06-3
FORMULA: C7H14N2O2S
NOTES:
STRUCTURE:
PRONUNCIATION: ǎl-dǐ-karb Guide to British pronunciation

INCHIKEY: QGLZXHRNAYXIBU-UHFFFAOYSA-N
INCHI: InChI=1S/C7H14N2O2S/c1-7(2,12-4)5-9-11-6(10)8-3/h5H,1-4H3,(H,8,10
proprietăţi insecticide descrise de Weiden M. H. J. , 1965 .

introdus de Union Carbide Corp. sub numele Temik
denumirea comună :aldicarb (BSI , ESA , ANSI , E-ISO);aldicarbe (F-ISO ); denumirea chimică: (C A ) 2-methyl-2-
(methylthio)propanal O-[(methylamino ) carbonyl]oxime ;
(IUPAC)2-methyl-2-(methylthio)propionaldehyde O-methylcarbamoyloxime ;
formula brută :C7H14N2O2 S
aldicarb-cristale colorate ;
analiză: spectrometrie i.r. spectrofotometrie ; reziduu –hplc ; glc cu FPD dupa oxidare la aldoxicarb .
punctul de topire 98-100oC;
presiunea de vapori 13 mPa (25oC);
solubilitatea 6 mg /l apă;
insolubil practic în heptan ;solubil în majoritatea solvenţilor organici ;
stabil , exceptând pH puternic alcalin ;
necoroziv pentru metale si echipamente; neinflamabil ;
inhibitor de colinesterază formând O-acetilcolina Atomul S din aldicarb este oxidat rapid în SO 2(330g/l)- sulfone-
aldoxycarb. utilizări: insecticid sistemic , nematocid , acaricid , aplicare simultan cu semănatul , pre-, post-
emergent , în brazdă sau în bandă la doza= 0,34-1,125 Kg s.a./Kg granule + irigaţie , ploaie abundentă
percolează rapid zona radiculară protejând-o câteva săptămâni ;
toxicitatea orală acută –şobolan mascul 0,93 mg produs tehnic / Kg ;
toxicitatea cutanată acută – iepure mascul 5,0 mg/Kg ;
CL şobolan 0,2 mg/l aer =5 min ;
toxicitatea cronică: în anul 2 sobolan -0,3 mg/Kg zi şobolanul este neafectat ;
CL50 (7---56 zile )prepeliţă 2400 mg/Kg;
CL50 (96 ore) –păstrăv curcubeu 0,56-0,88 mg /l ;
Formulări:GR ,SC
Aldoxycarb aldoxycarb
CHINESE: 涕灭砜威; FRENCH: aldoxycarbe (n.m.); RUSSIAN: альдоксикарб

IUPAC: (EZ)-2-mesyl-2-methylpropionaldehyde O-methylcarbamoyloxime
CAS: 2-methyl-2-(methylsulfonyl)propanal O-[(methylamino)carbonyl]oxime
REG. NO.: 1646-88-4
FORMULA: C7H14N2O4S
Prior to the approval of the common name, this substance was widely known as aldicarb sulfone.
The orthodox Chinese form “涕灭砜威” is used in GB 4839-2009 Chinese common names for pesticides, but
NOTES: the vulgar form “涕灭威砜” is also used in the literature.
STRUCTURE:
PRONUNCIATION: ǎl-dǒks-ǐ-karb Guide to British pronunciation

INCHIKEY: YRRKLBAKDXSTNC-UHFFFAOYSA-N
INCHI: InChI=1S/C7H14N2O4S/c1-7(2,14(4,11)12)5-9-13-6(10)8-3/h5H,1-4H3,(H,8,10)
proprietăţile insecticide şi nematocide descrise de Weiden M. H.J. ,1965 ;

introdus de Union Carbide sub marca ‘Standak ‘;
formula brută :C7H14O4S
Solid cristalin colorat ;
solubil 9 mg/l apă;50g/l acetonă ;75g/l acetonitril ;41g/l diclormetan ;
Se descompune în prezenţa bazelor concentrate
Stabil la lumină , căldură;
coroziv pentru aliaje dure ;
utilizări : aplicare la sol (stropire , benzi ) -2,0-11,25 Kg/s.a./Kg ;afide , tripşi coleoptere la bumbac ,
tutun ;tratament la sămânţă 0,5-2,0 Kg /q
Bendiocarb bendiocarb
CHINESE: 噁虫威; FRENCH: bendiocarbe (n.m.); RUSSIAN: бендиокарб

IUPAC: 2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate
CAS: 2,2-dimethyl-1,3-benzodioxol-4-yl N-methylcarbamate
REG. NO.: 22781-23-3
FORMULA: C11H13NO4
ACTIVITY: insecticides (carbamate insecticides)
The orthodox Chinese form “噁虫威” is used in GB 4839-2009 Chinese common names for pesticides, but the
NOTES: vulgar form “恶虫威” is also used in the literature.
STRUCTURE:
PRONUNCIATION: běn-dī-ō-karb Guide to British pronunciation

INCHIKEY: XEGGRYVFLWGFHI-UHFFFAOYSA-N
INCHI: InChI=1S/C11H13NO4/c1-11(2)15-8-6-4-5-7(9(8)16-11)14-10(13)12-3/h4-6H,1-3H3,(H,12,13)
insecticid descris de Lemon R.W. ,1971 ;

introdus de Fisons Ltd. (FBC , subs. Schering ), Ficam -igiena publică , Garvox , Seedox , Tatoo , uz agricol .
formula brută: C11H13NO4
denumirea comună: bendiocarb (BSI ,ESA , E-ISO );bendiocarbe (F-ISO)
denumirea chimică : 2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate(I) (IUPAC); 2,3-
isopropylidenedioxyphenyl methylcarbamate(II)(CA) ;
analiză:produs-hplc , glc ;reziduuri-hidroliza 2,3-isopropylidenedioxyohenol , derivate măsurabile prin glc cu
ECD bendiocarb-solid colorat ; punct de topire 129-130 oC ;
o
presiunea de vapori 0,66mPa (25 C);
solubilitate (25oC):40 mg/l apă ;200g/Kg acetonă , cloroform , dioxan ;40g/Kg benzen ,etanol ;350mg/Kg
hexan ;< 1g /Kg kerosen deodorizat ; raţia partiţiei (20 oC) apa/kerosene =1/9
stabilitatea în apă la pH =5; în 4 zile ,la25 oC hidrolizează 50% (EDA ghid) la pH=7, descompunându-se în 2,3-
isopropylidenedioxyphenol , methylamine ,CO2. Utilizări: insecticid de contact , ingestie , sistemic în
plante ;letalitatea- inhibitor de colinesterază ;igiena publică (muşte , ţânţari , blatide) , uz fitosanitar porumb
sfecla ,alte culturi prin tratamente (sămânţă ,sol ,vegetaţie ); reziduu detectabil 0,02 mg/Kg
Toxicologie: toxicitate acută orală , şobolan DL50 40-156 mg/Kg ; toxicitate acută cutanată , şobolan DL50 566-
600 mg /K; toxicitatea cronică :NEL şobolan 10mg/Kg dietă zi în 2ani ;în 90 zile şobolanul hrănit cu 250g/Kg
dietă zi nu au manifestat efecte vizibile ; CL50(96ore)-păstrăv curcubeu -1,55 mg/l;
toxic pentru albine DL50 0,001mg/ex. DZA om = 0,004 mg/Kg
Formulări:DP( 10 , 32 g ),WP(760g/Kg) , WP , AE(184g/Kg) , SC (500 ,800g/Kg) Mixări: WS ( ) , WP (
Benfuracarb benfuracarb
CHINESE: 丙硫克百威; FRENCH: benfuracarbe (n.m.); RUSSIAN: бенфуракарб

IUPAC: ethyl N-[2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl(methyl)aminothio]-N-isopropyl-β-alaninate
2,3-dihydro-2,2-dimethyl-7-benzofuranyl 2-methyl-4-(1-methylethyl)-7-oxo-8-oxa-3-thia-2,4-diazadecanoate
(formerly ethyl N-[[[[(2,3-dihydro-2,2-dimethyl-7-benzofuranyl)oxy]carbonyl]methylamino]thio]-N-(1-methylethyl)-
CAS: β-alaninate)
REG. NO.: 82560-54-1
ACTIVITY: insecticides (benzofuranyl methylcarbamate insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: běn-fūr-a-karb Guide to British pronunciation

INCHIKEY: FYZBOYWSHKHDMT-UHFFFAOYSA-N
InChI=1S/C20H30N2O5S/c1-7-25-17(23)11-12-22(14(2)3)28-21(6)19(24)26-16-10-8-9-15-13-20(4,5)27-
INCHI: 18(15)16/h8-10,14H,7,11-13H2,1-6H3
Insecticid descris de Goto T. , 1983

introdus de Otsuka Chemical Co. sub numele Oncol
formula brută:C20H30N2O5 S
Denumirea comună:benfucarb
denumirea chimică :^( IUPAC) N-[2,3-dihidro-2,2-dimetylbenzofuran-7 yloxycarbonyl(methyl)aminothio-=N-
isopropyl-β-alaninate ; ^^(CA)2,3-dihydro-2,2-dimethyl-7-benzofuranyl 2-methyl-4-(1methylethyl)-7-oxo-8-oxa-
3-thia-2,4diazadecanoate ;
analiza: produs- ;reziduu - ;
lichid roşcat-brun ;
solubilitate (20oC) în apă -8mg/ l apă ;solubil în solvenţi organici (majoritatea); la sol cu granulate pentru
Diabrotica , Agriotes ;sistemic actiune foliara aficidă în tratamente la cartof -Leptinotarsa decemlineata , la
măr-Cydia pomonella .
Toxicitatea orală acută :DL50 şobolan -138 mg/Kg ;şoarece -175mg/Kg ; câine -300mg/Kg .
Toxicitatea acută cutanată DL50 şobolan >2000mg/Kg ; nemutagen ; piele – neiritant ;ochi-neiritant ;
Formulări:GR (100gs.a. /Kg ) Oncol
Bensultap bensultap
CHINESE: 杀虫磺; FRENCH: bensultap (n.m.); RUSSIAN: бенсултап

IUPAC: S,S′-2-dimethylaminotrimethylene di(benzenethiosulfonate)
CAS: S,S′-[2-(dimethylamino)-1,3-propanediyl] di(benzenesulfonothioate)
REG. NO.: 17606-31-4
FORMULA: C17H21NO4S4
ACTIVITY: insecticides (nereistoxin analogue insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: běn-sǔl-tǎp Guide to British pronunciation

INCHIKEY: YFXPPSKYMBTNAV-UHFFFAOYSA-N
InChI=1S/C17H21NO4S4/c1-18(2)15(13-23-25(19,20)16-9-5-3-6-10-16)14-24-26(21,22)17-11-7-4-8-12-17/h3-
INCHI: 12,15H,13-14H2,1-2H3
1983
denumirea comuna:bensultap
introdus de Takeda Chemical sub denumiri: Bancol ,Victenon , Doricide ;
denumirea chimică:^S,S’-2-dimethylaminotrimethylene di(benzenethiosulfonate (IUPAC);^^S,S’-
2dimethylaminotrimethylene di(benzenethiosulfonate (CA); formula brută:C 17H21NO4S4
analiză:reziduu-glc cu FPD
Bensultap-pudră cristalină galbenă
punct de fierbere :82-83oC ;punct descompunere ~150oC ;
presiunea de vapori ~0mPa ;
solubilitatea (25oC)0,7-0,8 mg/Kg apă ; >1Kg/ Kg acetonă , acetonitril , cloroform , dimetilformamide ; 13g/Kg
etanol ;170g/Kg hexan ;25g/Kg metanol . Stabil în acid , hidrolizează în mediu neutru , alcalin .
utilizări: combate coleoptere , lepidoptere 300-750g s.a./ha ; la cartof aplicaţii foliare -Leptinotarsa
decemlineata
Toxicitatea acută orală şobolan 1105 mg/Kg ;şoarece 484-516 mg/Kg ;prepeliţa japoneză -60mg/Kg ;pui găină
- 103 mg/Kg ; toxicitatea acută cutanată DL50 iepure >2000mg/Kg ;NEL(90zile)-şobolan 250mg/Kg ;- mascul
şoarece 40mg/Kg ;-femela şoarece 40mg/Kg dietă ; Neteratogen la şobolan ; CL 50 (48 ore)crap-15mg/l ;caras
auriu 5,1mg granule/l ; CL50 (6 ore)-Daphnia 40mg/ l ; DL50 –albine 0,0147 mg/ex.
Formulări:WP (500g/Kg);EC , DP ,GR .
Carbofuran carbofuran
CHINESE: 克百威; FRENCH: carbofuran (n.m.); RUSSIAN: карбофуран

IUPAC: 2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate
CAS: 2,3-dihydro-2,2-dimethyl-7-benzofuranyl N-methylcarbamate
REG. NO.: 1563-66-2
FORMULA: C12H15NO3
insecticides (benzofuranyl methylcarbamate insecticides)
ACTIVITY: nematicides (carbamate nematicides)
NOTES:
STRUCTURE:
PRONUNCIATION: kar-bō-fūr-ǎn Guide to British pronunciation

INCHIKEY: DUEPRVBVGDRKAG-UHFFFAOYSA-N
INCHI: InChI=1S/C12H15NO3/c1-12(2)7-8-5-4-6-9(10(8)16-12)15-11(14)13-3/h4-6H,7H2,1-3H3,(H,13,14)
descris de Mc Ewen F.L. & Davis A.C., E .J. Armburst &G.C. Grisco 1965
denumirea comună :carbofuran
denumirea chimică:2,3-dihydro-2,2-dimethyibenzofuran-7-yl methylcarbamate (IUPAC ; 2,3-dihydro-2,2-
dimethyl-7-benzofuranyl methylcarbamate (CA);
Introdus de FMC(Agricultural Chemical )-Furadan şi Bayer -Curaterr, Yaltox.
formula brută: C12H15NO3
analiză :produs – hplc , spectrometrie i.r. ;reziduuri-glc .
Carbofuran-solid cristalin ;
punct de topire -150-152oC ;
presiunea de vapori-2,7 mPa(33oC);
densitatea 1,180 ;
solubilitatea (25oC) 700mg/l apă ;150g/Kg acetonă ;140g/Kg acetonitril ; 40g/Kg benzen ;90 g/Kg
cyclohexanonă ; 270g/Kg dimetilformamidă ; 250g/Kg dimetil sulfoxid ;300g/Kg 1-metil -2 -pirolidone;
insolubil în solvenţii de la formulările utilizate în agricultura ;instabil în mediu alcalin ;
utilizări:insecticid sistemic , acaricid , nematocid , aplicări foliare 0,25-1,0 Kg s.a. /ha insecte de sol şi ale
foliajului ;nematozi 6 -10 Kg /ha la porumb , orez ,..
toxicitatea acută orală şobolan 8-14 mg s.a.în ulei pb/ Kg ;câine-19 mg s.a. /Kg; toxicitatea acută cutanată
iepure 2550 g s.a.(WP)/ Kg ; toxicitatea cronică în 2ani la 25mg/Kg dietă , 10mg/Kg dietă pe 3 generaţii sau
50mg/Kg dietă /1 generaţie nu au fost observate efecte vizibile ;DL 50 -fazan 960mg s.a. (10%GR)/Kg dietă ;
CL50(96ore) păstrăv -0,28mg/Kg . În organismul animal este metabolizat şi excretat prin urină, 50% în 6-12 ore ;
în sol carbofuranul se înjumătăţeşte (50%) în 30-60 zile ; DZA om = 0,01 mg/Kg
Formulări:WP(750g s.a./Kg); flowable paste (480g/l) ; ST (350 , 500g /Kg ); GR ( 20 , 30 , 50 , 100g/Kg);
Carbosulfan carbosulfan
CHINESE: 丁硫克百威; FRENCH: carbosulfan (n.m.); RUSSIAN: карбосульфан

IUPAC: 2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylaminothio)methylcarbamate
CAS: 2,3-dihydro-2,2-dimethyl-7-benzofuranyl N-[(dibutylamino)thio]-N-methylcarbamate
REG. NO.: 55285-14-8
insecticides (benzofuranyl methylcarbamate insecticides)
ACTIVITY: nematicides (carbamate nematicides)
NOTES:
STRUCTURE:
PRONUNCIATION: kar-bō-sǔl-fǎn Guide to British pronunciation

INCHIKEY: JLQUFIHWVLZVTJ-UHFFFAOYSA-N
InChI=1S/C20H32N2O3S/c1-6-8-13-22(14-9-7-2)26-21(5)19(23)24-17-12-10-11-16-15-20(3,4)25-18(16)17/
INCHI: h10-12H,6-9,13-15H2,1-5H3
insecticid raportat de E.C.Maitlen & N.A. Sladen 1979

introdus de FMC Corp. sub numele Marshal
denumirea comună:carbosulfan
denumirea chimică:2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylaminothio)methylcarbamate(IUPAC) ;
formula brută: C20H32N2O3S
analiză: produs - ;reziduu - ;
carbosulfan-lichid vâscos brun ;
presiunea de vapori -0,041 mPa ;
solubilitatea (25oC)-0,03 mg/l;
insecticid sistemic tratamente foliare(afide ,coleoptere ), la sol(milipede,insecte) la porumb , sfeclăde zahăr ,
cartof (afide , Leptinotarsa decemlineata)
toxicitate acută orală DL50 :şobolan mascul 250 mg s.a. / Kg ;femelă 185 mg/Kg; fazan 26 mg /Kg ;răţoi 8,1
mg /Kg ;prepeliţa 82 mg/Kg ;
toxicitatea acută cutanată DL50 iepuri > 2000 mg /Kg ;
CL50 (96 ore)bluegill 0,015 mg/ l ; păstrăv 0,042 mg/l ;
DZA’ om = 0,005 mg/Kg
Formulări: GR (50g s.a./Kg );ED (150 g/l );
Dioxicarb
insecticid descris de F. Bachmann & J.B. Legge ,
introdus de Ciba AG , mărcile Elocron , Famid .
denumirea comună: dioxicarb (BSI , ESA , E-ISO ) , dioxicarbe (F-ISO) denumirea chimică:(IUPAC) 2-(1,3-dioxolan-
2-yl )phenyl methylcarbamate (I)(C.A.);0-1,3-dioxolan-2-ylphenyl methylcarbamate (8CI) ;
formula brută:C11H13NO4
analiză:produs titrare acidimetrică ;reziduu –glc cu ECD ;
dioxicarb-cristale colorate ;
punct de topire 114-115oC ;
presiunea de vapori 0,04 mPa (20oC) ;
densitatea 1,46 g/cm3 ;
solubilitatea (20oC): 6g / l apă ;280 g/l acetonă ;235 g/l ciclohexanonă ;
550g/l dimetilformamidă ;80g/l etanol ; < 1g/ l kerosen ;9g/l xilen ;
În mediu apos la 20oC înjumătăţire (50% reducere) la pH=5 ~85 ore , la pH=9~ 15 ore ; pH=7~ 24,6 ore; în sol se
descompune rapid . Utilizări:insecticid de contact , ingestie , la insecte rezistente la cloroderivate ,
organofosforice (gândaci de bucătărie ), insecte generatoare de discomfort + produse depozitate , la doza de
0,5-2,0g s.a. / m2 ; insecte sugătoare (afide rezistente la insecticide organofosforice ), lăcuste , Leptinotarsa
decemlineata -250-500 g /ha , 500-750g/ha -efect de şoc , persistenţa 5-7 zile pe plantă , 0,5 zile pe suprafeţe
diverse . toxicitatea acută orală DL50 –şobolan 72 mg/Kg ; toxicitatea acută cutanată DL50 –şobolan 3000mg/K ;
la iepure- iritant pentru piele şi ochi; NEL în 90 zile –şobolanul -10 mg/ Kg dietă zi ;câine -2mg/Kg zi marginal ;
CL50(96 ore)- păstrăv curcubeu -29 mg/ l ;crap -32 mg/l ; în laborator Netoxic la albine şi păsări ;
Formulări: WP (500g /Kg ), Elecron ;EC (400 g/l ), Elecron 40 SCW
Ethyophencarb ethiofencarb
CHINESE: 乙硫苯威; FRENCH: éthiophencarbe (n.m.); RUSSIAN: этиофенкарб

IUPAC: α-ethylthio-o-tolyl methylcarbamate
CAS: 2-[(ethylthio)methyl]phenyl N-methylcarbamate
REG. NO.: 29973-13-5
FORMULA: C11H15NO2S
ACTIVITY: insecticides (phenyl methylcarbamate insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: ě-thī-ō-fěn-karb Guide to British pronunciation

INCHIKEY: HEZNVIYQEUHLNI-UHFFFAOYSA-N
INCHI: InChI=1S/C11H15NO2S/c1-3-15-8-9-6-4-5-7-10(9)14-11(13)12-2/h4-7H,3,8H2,1-2H3,(H,12,13)
insecticid descris de Hammann J. & Hoffmann

introdus de Bayer AG , sub marca Croneton
denumirea comună:ethyophencarb (BSI , E-ISO ) ; ethyophenocarbe (F-ISO) denumirea chimică : α –ethylthio-o-
tolyl methylcarbamate (I) : 2–ethylthiomethylphenyl metylcarbamate
formula brută:C11H13NO4
analiză :produs –m. Bayer ;reziduuri- glc .
produs - ulei galben ;
punct de fierbere 33,4 oC ;
presiunea de vapori :13 mPa;
densitatea -1,147
solubilitatea -1,82 g/Kg apă ; >600 g/Kg diclormetan , propan-1-ol , toluen ; utilizări: insecticid sistemic , aficid ,
aplicabil la sol , foliar – 5g s.a./10 l apă , la porumb , cartof , cereale , bumbac , plante ornamentale , pomi
fructiferi (pomacee , drupacee ) , sfeclă de zahăr , legume , tutun . toxicitate acută orală şobolan mascul 411-
499 mg/Kg ;şoarece 224-256 mg/Kg ; prepeliţă japoneză -155 mg / Kg ; canari ~100 mg/Kg ;găini~1000 mg/Kg ;
toxicitatea acută cutanată DL 50 şobolan –mascul >1150 mg/Kg ; NEL în anul 2 –şobolan 330mg/Kg dietă ;
CL50(96 ore) crap -10-20 mg/ l ; caras auriu -20-40g/Kg ;golden orfe 8-10g/l ; DZA om = 0,1 mg /Kg ;
Formulări: EC (500 g /Kg ) ;Mixaje:( ethiofencarb 250 g + oxydemeton-methyl 50g /l )
Fenoxycarb fenoxycarb
CHINESE: 苯氧威; FRENCH: fénoxycarbe (n.m.); RUSSIAN: феноксикарб

IUPAC: ethyl 2-(4-phenoxyphenoxy)ethylcarbamate
CAS: ethyl N-[2-(4-phenoxyphenoxy)ethyl]carbamate
REG. NO.: 79127-80-3
FORMULA: C17H19NO4
ACTIVITY: insecticides (juvenile hormone mimics)
NOTES:
STRUCTURE:
PRONUNCIATION: fěn-ǒk-sē-karb Guide to British pronunciation

INCHIKEY: HJUFTIJOISQSKQ-UHFFFAOYSA-N
InChI=1S/C17H19NO4/c1-2-20-17(19)18-12-13-21-14-8-10-16(11-9-14)22-15-6-4-3-5-7-15/h3-11H,2,12-
INCHI: 13H2,1H3,(H,18,19
insecticid descris de Dorn S. &.. , 1981

introdus de R. Maag AG sub marca Insegar
denumirea comună :fenoxicarb
denumirea chimică :ethyl [2-(4-phenoxyphenoxy)ethyl]carbamate
produsul pur –cristale colorate ;
presiunea de vapori 0,0017mPa(25oC) ;
punct de aprindere 224 oC ;
solubilitate 6 mg/Kg apă ; 5g/Kg hexan ;> 250 g/Kg în majoritatea solvenţilor organici ; stabil > 2 ani în
container închis la to< 40oC ;
utilizări :lepidoptere la pomi fructiferi , coleoptere , lepidoptere la produse depozitate , gândaci de bucătărie ,
purici , larve de ţânţari . toxicitatea acută orală DL 50 pentru şobolan > 10 000 mg/Kg ;
toxicitatea acută cutanată DL50 > 2000 mg/ Kg ; nu
Formetanat formetanate
CHINESE: 伐虫脒; FRENCH: formétanate (n.m.); RUSSIAN: форметанат

IUPAC: 3-[(EZ)-dimethylaminomethyleneamino]phenyl methylcarbamate
CAS: N,N-dimethyl-N′-[3-[[(methylamino)carbonyl]oxy]phenyl]methanimidamide
REG. NO.: 22259-30-9
FORMULA: C11H15N3O2
acaricides (formamidine acaricides)
ACTIVITY: insecticides (formamidine insecticides)
When this substance is used as a salt, its identity should be stated, for example formetanate hydrochloride
[23422-53-9].
NOTES: The name “伐虫脒” is approved in China for formetanate and for formetanate hydrochloride.
STRUCTURE:
PRONUNCIATION: for-mět-a-nāt Guide to British pronunciation

INCHIKEY: RMFNNCGOSPBBAD-UHFFFAOYSA-N
INCHI: InChI=1S/C11H15N3O2/c1-12-11(15)16-10-6-4-5-9(7-10)13-8-14(2)3/h4-8H,1-3H3,(H,12,15)
Furathiocarb furathiocarb
CHINESE: 呋线威; FRENCH: furathiocarbe (n.m.); RUSSIAN: фуратиокарб

IUPAC: butyl 2,3-dihydro-2,2-dimethylbenzofuran-7-yl N,N′-dimethyl-N,N′-thiodicarbamate
CAS: 2,3-dihydro-2,2-dimethyl-7-benzofuranyl 2,4-dimethyl-5-oxo-6-oxa-3-thia-2,4-diazadecanoate
REG. NO.: 65907-30-4
NOTES:
STRUCTURE:
PRONUNCIATION: fūr-a-thī-ō-karb Guide to British pronunciation

INCHIKEY: HAWJXYBZNNRMNO-UHFFFAOYSA-N
InChI=1S/C18H26N2O5S/c1-6-7-11-23-16(21)19(4)26-20(5)17(22)24-14-10-8-9-13-12-18(2,3)25-15(13)14/h8-
INCHI: 10H,6-7,11-12H2,1-5H3
Isolan furathiocarb
CHINESE: 呋线威; FRENCH: furathiocarbe (n.m.); RUSSIAN: фуратиокарб

IUPAC: butyl 2,3-dihydro-2,2-dimethylbenzofuran-7-yl N,N′-dimethyl-N,N′-thiodicarbamate
CAS: 2,3-dihydro-2,2-dimethyl-7-benzofuranyl 2,4-dimethyl-5-oxo-6-oxa-3-thia-2,4-diazadecanoate
REG. NO.: 65907-30-4
NOTES:
STRUCTURE:
PRONUNCIATION: fūr-a-thī-ō-karb Guide to British pronunciation

INCHIKEY: HAWJXYBZNNRMNO-UHFFFAOYSA-N
InChI=1S/C18H26N2O5S/c1-6-7-11-23-16(21)19(4)26-20(5)17(22)24-14-10-8-9-13-12-18(2,3)25-15(13)14/h8-
INCHI: 10H,6-7,11-12H2,1-5H3
Mercaptodimethur methiocarb
CHINESE: 甲硫威; FRENCH: méthiocarbe (n.m.); RUSSIAN: метиокарб

IUPAC: 4-methylthio-3,5-xylyl methylcarbamate
CAS: 3,5-dimethyl-4-(methylthio)phenyl N-methylcarbamate
REG. NO.: 2032-65-7
FORMULA: C11H15NO2S
bird repellents
insecticides (phenyl methylcarbamate insecticides)
NOTES: The common name “mercaptodimethur” is also approved by ISO.
STRUCTURE:
PRONUNCIATION: mě-thī-ō-karb Guide to British pronunciation

INCHIKEY: YFBPRJGDJKVWAH-UHFFFAOYSA-N
INCHI: InChI=1S/C11H15NO2S/c1-7-5-9(14-11(13)12-3)6-8(2)10(7)15-4/h5-6H,1-4H3,(H,12,13)
Mercaptodimethur
Identification
Name Mercaptodimethur
3,5-Dimethyl-4-(methylthio)phenol methylcarbamate; 3,5-Dimethyl-4-
Synonyms (methylthio)phenyl methylcarbamate; Methylcarbamic acid 4-(methylthio)-3,5-xylyl
ester
Molecular Structure
Molecular Formula C11H15NO2S

Molecular Weight 225.30
CAS Registry Number 2032-65-7
EINECS 217-991-2
Properties
Melting point 119 ºC

Water solubility Insoluble
Safety Data
Hazard Symbols
T;N Details
Risk Codes R25;R50/53 Details
Safety Description S22;S37;S45;S60;S61 Details
Transport Information UN 2811/2757
Metham de sodiu 1951 metam-sodium
CHINESE: 威百亩

IUPAC: sodium methyldithiocarbamate
CAS: sodium N-methylcarbamodithioate
REG. NO.: 137-42-8
FORMULA: C2H4NNaS2
fungicides (dithiocarbamate fungicides)
herbicides (dithiocarbamate herbicides)
ACTIVITY: nematicides (unclassified nematicides)
This substance is a derivative of metam [144-54-7].
The name “metham-sodium” is approved by the British Standards Institution and the Weed Science Society of
America.
The name “sodium methyldithiocarbamate” is used in Canada and New Zealand.
The name “carbam-sodium” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
The name “carbathion” (карбатион) was used in the former USSR.
The name “metam-sodium” was formerly approved by ISO for the sodium salt, but this was replaced by the
NOTES: name “metam” for the acid as part of a rationalisation exercise in 1989.
STRUCTURE:
PRONUNCIATION: mē-tǎm sō-dē-am Guide to British pronunciation

INCHIKEY: AFCCDDWKHLHPDF-UHFFFAOYSA-M
INCHI: InChI=1S/C2H5NS2.Na/c1-3-2(4)5;/h1H3,(H2,3,4,5);/q;+1/p-1
Methiocarb 196 methiocarb
CHINESE: 甲硫威; FRENCH: méthiocarbe (n.m.); RUSSIAN: метиокарб

IUPAC: 4-methylthio-3,5-xylyl methylcarbamate
CAS: 3,5-dimethyl-4-(methylthio)phenyl N-methylcarbamate
REG. NO.: 2032-65-7
FORMULA: C11H15NO2S
bird repellents
insecticides (phenyl methylcarbamate insecticides)
NOTES: The common name “mercaptodimethur” is also approved by ISO.
STRUCTURE:
PRONUNCIATION: mě-thī-ō-karb Guide to British pronunciation

INCHIKEY: YFBPRJGDJKVWAH-UHFFFAOYSA-N
INCHI: InChI=1S/C11H15NO2S/c1-7-5-9(14-11(13)12-3)6-8(2)10(7)15-4/h5-6H,1-4H3,(H,12,13)
Methomyl 1968 methomyl
CHINESE: 灭多威; FRENCH: méthomyl (n.m.); RUSSIAN: метомил

IUPAC: S-methyl (EZ)-N-(methylcarbamoyloxy)thioacetimidate
CAS: methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate
REG. NO.: 16752-77-5
FORMULA: C5H10N2O2S
ACTIVITY: insecticides (oxime carbamate insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: měth-ō-mīl Guide to British pronunciation

INCHIKEY: UHXUZOCRWCRNSJ-UHFFFAOYSA-N
INCHI: InChI=1S/C5H10N2O2S/c1-4(10-3)7-9-5(8)6-2/h1-3H3,(H,6,8)
Promecarb promecarb
CHINESE: 猛杀威; FRENCH: promécarbe (n.m.); RUSSIAN: промекарб

IUPAC: 5-methyl-m-cumenyl methylcarbamate
or
3-isopropyl-5-methylphenyl methylcarbamate
CAS: 3-methyl-5-(1-methylethyl)phenyl N-methylcarbamate
REG. NO.: 2631-37-0
FORMULA: C12H17NO2
ACTIVITY: insecticides (phenyl methylcarbamate insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: prō-mě-karb Guide to British pronunciation

INCHIKEY: DTAPQAJKAFRNJB-UHFFFAOYSA-N
INCHI: InChI=1S/C12H17NO2/c1-8(2)10-5-9(3)6-11(7-10)15-12(14)13-4/h5-8H,1-4H3,(H,13,14)
Thiocarb 1977
Thiofanox thiofanox
CHINESE: 久效威; FRENCH: thiofanox (n.m.); RUSSIAN: тиофанокс

(EZ)-3,3-dimethyl-1-methylthiobutanone O-methylcarbamoyloxime
or
IUPAC: (EZ)-1-(2,2-dimethyl-1-methylthiomethylpropylideneaminooxy)-N-methylformamide
CAS: 3,3-dimethyl-1-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime
REG. NO.: 39196-18-4
FORMULA: C9H18N2O2S
ACTIVITY: insecticides (oxime carbamate insecticides)
NOTES: The name “thiofanocarb” is used in South Africa.
STRUCTURE:
PRONUNCIATION: thī-ō-fǎn-ǒks Guide to British pronunciation

INCHIKEY: FZSVSABTBYGOQH-UHFFFAOYSA-N
INCHI: InChI=1S/C9H18N2O2S/c1-9(2,3)7(6-14-5)11-13-8(12)10-4/h6H2,1-5H3,(H,10,12)
Pyrimicarb 1977 pirimicarb
CHINESE: 抗蚜威; FRENCH: pirimicarbe* (n.m.); RUSSIAN: пиримикарб

IUPAC: 2-dimethylamino-5,6-dimethylpyrimidin-4-yl dimethylcarbamate
CAS: 2-(dimethylamino)-5,6-dimethyl-4-pyrimidinyl N,N-dimethylcarbamate
REG. NO.: 23103-98-2
FORMULA: C11H18N4O2
ACTIVITY: insecticides (dimethylcarbamate insecticides)
* According to ISO 1750, the name “pyrimicarbe” (n.m.) is used in France, but the ISO common name
NOTES: “pirimicarbe” (n.m.) also appears to be used.
STRUCTURE:
PRONUNCIATION: pǐ-rǐm-ǐ-karb Guide to British pronunciation

INCHIKEY: YFGYUFNIOHWBOB-UHFFFAOYSA-N
INCHI: InChI=1S/C11H18N4O2/c1-7-8(2)12-10(14(3)4)13-9(7)17-11(16)15(5)6/h1-6H3
4. 3.9. Piretroizi de sinteza
Analogii chimici de sinteză ai piretrinelor naturale ,‘‘piretroizii de sinteză’’ provin din esterificarea
aletrolonei , analogul de sinteză al cetoalcoolului natural retrolona cu acid crizantemic , Schechter 1949 .
Aletrinele (aletrin -8 stereoizomeri , bioaletrin -2 stereoizimeri , S-bioaletrin – 1 stereoizomer ) preparate prin
esterificarea alletrolonei cu acidul crizantemic sunt primii piretroizi de sinteză .Esterificarea alcoolului 5-benzil-
3-furil metanol cu stereoizomerii cis şi trans ai acidului crizantemic modificând structura moleculei a potenţat
activitatea insecticidă ( tetrametrin – 4 stereoizomeri , resmetrin - 4 stereoizomeri , bioresmetrin -1
stereoizomer), dar fotostabilitatea produşilor se menţinea relativ modestă .
Eliott , 1973 a modificat 2 zone fotolabile din structura resmetrinului sintetizând ‘permetrin’ (4stereoizomeri ),
primul piretroid de sinteză bun de ‘utilizat şi în agricultură‘ . În Japonia Ohno, 1973 a introdus grupa cyano în
poziţia benzil sintetizând un nou piretroid ‘fenvalerat’ (amestec de 4 stereoizomeri ).
Eliott , în anul 1974, înlocuie gruparea ‘diclor’cu gruparea‘dibrom’ sintetizând α cyano phenoxybenzyl
dibromvinil dimethyl cyclopropane carboxylate , un stereoisomer fotostabil şi foarte eficace numit iniţial
‘decametrin ‘1974 , iar ulterior (OMS ,1998) ‘ deltametrin’ .
Insecticidele piretroide acţionează prin contact , ingestie , nesistemice care perturbă transmisia axonală a
impulsurilor prin blocarea canalului de sodiu .
Toxicitatea pentru animalele cu sânge cald este de la medie la mică , iar pentru animale cu sânge rece este
mare în special la peşti (foarte mare) .
Timpul de pauză este mic (1 -3 zile) la majoritatea piretroizilor şi medie (14 zile) la multi piretroizi de sinteză .
Selectivitatea piretroizilor de sinteză este mică ( ), dar se cunosc şi piretroizi mediu selectivi ( Mavric
Persistenţa mică (7-14 zile ) mare (100 zile )
Câmpul de actiune este în general mare .
Alte acţiuni : piretroizi sinteză şi cu acţiune acaricidă (acrinatrin , bifentrin ).
Substanţele active piretroide de sinteză moderne utilizate în protecţia agroecosistemelor şi sanogeneză sunt
: acrinatrin , alfametrin , betacyflutrin , bioresmetrin , cyflutrin , cypermetrin , deltametrin , esfenvalerat,
etofenprox , fenpropatrin , fenvalerat , lambda -cyhalotrin , permetrin , tau-fluvalinat , teflutrin , tralometrin ,
zetacypermetrin .
Allethrin allethrin
CHINESE: 烯丙菊酯; FRENCH: alléthrine (n.f.); RUSSIAN: аллетрин

IUPAC: (RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-
enyl)cyclopropanecarboxylate
or
(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-
or
(±)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (±)-cis-trans-chrysanthemate
2-methyl-4-oxo-3-(2-propen-1-yl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propen-1-
CAS: yl)cyclopropanecarboxylate
REG. NO.: 584-79-2
FORMULA: C19H26O3
The name “palléthrine” is approved by the Association Française de Normalisation.
One pair of stereoisomers of this substance has it own BSI common name; see bioallethrin. One stereoisomer
NOTES: from this pair has its own AFNOR common name; see esdépalléthrine [28434-00-6].
STRUCTURE:
PRONUNCIATION: ǎl-lēth-rǐn Guide to British pronunciation

INCHIKEY: ZCVAOQKBXKSDMS-UHFFFAOYSA-N
InChI=1S/C19H26O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h7,9,14,16-
INCHI: 17H,1,8,10H2,2-6H3
insecticid descris de Schechter M.S., 1949 , Barthel W.,1967 detalii+ dezvoltare.

Formula brută :C19H26O3 analiză:produs –
glc ; nmr ;raportul izomerilor glc ;reziduuri-glc
denumire comună :allethrine(F-ISO) ;pallethrine( F );allethrin (BSI , ESA , JMAF, E-ISO); introdus pe piaţă de
Sumitomo Chem. sub marca Pinamin;
denumirea chimică :( RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS , 2RS ; 1RS ,2SR )-2,2-dimethyl-3-(2-
methylprop-1-enyl)-=cyclopropanecarboxylate ;
(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl(1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-
enyl)=cyclopropanecarboxylate ;(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl( ± )-cis-trans-chrysanthemates
(IUPAC);
2-methyl-4-oxo-3-( 2-propenyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propenyl)
cyclopropanecarboxylate ( CA ).
Produsul tehnic –lichid galben pal la galben brun ;
punct de fierbere 140oC ;
densitatea 1,005 -1,015 ;
presiunea de vapori 16 mPa(30oC);
solubilitatea >1Kg /Kg hexan , metanol , xilen ;
utilizări:insecticid de contact eficace (ţânţari , muşte );mixarea sinergică cu piretroizi naturali majorează
eficacitatea .
DL 50 şobolan -mascul 1100mg /Kg ,-femelă 685 mg/Kg ; prepeliţă -2030 mg/Kg; CL 50 păstrăv -17,5 mg/Kg; drac
de mare-30,1 mg /Kg ;
Formulare : AE (1-6 g allethrin /l ; DP ;EC (810 g/Kg ) ; mixări: allethrin + chlorpirifos; allethrin + piperonil
butoxid ; AE ,
Bioallethrin bioallethrin
CHINESE: 生物烯丙菊酯; FRENCH: bioalléthrine* (n.f.); RUSSIAN: биоаллетрин
STATUS: BSI
(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-
or
(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-trans-2,2-dimethyl-3-(2-methylprop-1-
IUPAC: enyl)cyclopropanecarboxylate
2-methyl-4-oxo-3-(2-propen-1-yl)-2-cyclopenten-1-yl (1R,3R)-2,2-dimethyl-3-(2-methyl-1-propen-1-
REG. NO.:
FORMULA: C19H26O3
There is no ISO common name for this substance; the name “bioallethrin” is approved by the British Standards
Institution, and is also approved in China (生物烯丙菊酯).
The name “d-trans-allethrin” is approved by the Entomological Society of America, and is also approved in
China (右旋反式烯丙菊酯).
* The name “dépalléthrine” (n.f.) is approved by the Association Française de Normalisation.
The unresolved mixture of stereoisomers has the ISO common name allethrin [584-79-2].
NOTES: The (S)-alcohol stereoisomer has the AFNOR common name esdépalléthrine [28434-00-6].
STRUCTURE:
PRONUNCIATION: bī-ō-ǎl-lēth-rǐn Guide to British pronunciation

INCHIKEY: ZCVAOQKBXKSDMS-AQYZNVCMSA-N
InChI=1S/C19H26O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h7,9,14,16-
INCHI: 17H,1,8,10H2,2-6H3/t14-,16?,17+/m1/s1
descris parţial (ester 1R trans) de Lhoste J. , 1967 ;

introdus pe piaţă: Roussell Uclaf ‘Bioallethrine’ şi McLaughlin Gormley King Co. ‘D-Trans’;Sumitomo Chemical
Co.‘Pinamin’=80:20 bioallethrin /d-alletrin denumirea comună:bioallethrin( BSI , N.
Zeelanda);depallethrin(Franta) ; d-trans-allethrin (ESA) ;
formula brută :C19H26O3
denumirea chimică :(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R , 3R )-2,2=dimethyl-3-(2-methylprop-1-
enyl)cyclopropanecarboxylate ; (RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-trans-2,2-dimethyl-3-(2-
methylprop-1-enyl= cyclopropanecarboxylate ;(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (+)-trans-
chrysanthemate ( IUPAC ). 2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl 2,2dimethyl-3-(2-methyl-1-
propenyl )cyclopropanecarboxylate (C A );dl-2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester d-trans-2,2-
dimethyl-3-(2-methylpropenyl )cyclopropanecarboxylic acid .
analiză:produs -glc ; nmr;reziduu -glc .
D-Trans ~lichid –vâscos ambră ; densitatea 0,997;
90% bioalletrin punct de aprindere 65,6oC ;
insolubil în apă ;>1Kg/ Kg hexan , metanol , xilen .
Utilizări: insecticid de contact , nesistemic , cu efect de şoc (knock-down), insecte vectoare , discomfort .
Toxicitatea orală acută DL50 D-trans şobolan :femelă 845-875 mg/Kg; - mascul 425-575 mg / Kg ; DL 50 Pinamin
Forte şobolan femelă 310mg /Kg ;-mascul 1320 mg /Kg ; NEL (90 zile)şobolan 750 mg /Kg dietă ;
CL 50 (8zile ) raţă , prepeliţă 5620 mg Pinamin Forte / Kg ;
Toxicitatea cutanată acută şobolan DL50 >2500 mg Pinamin Forte / Kg Formulări:AE , DP , OL
S-bioallethrin esdépalléthrine
CHINESE: S-生物烯丙菊酯; FRENCH: esdépalléthrine (n.f.); RUSSIAN: эсдепаллетрин
STATUS: AFNOR
(S)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-
or
(S)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-trans-2,2-dimethyl-3-(2-methylprop-1-
IUPAC: enyl)cyclopropanecarboxylate
(1S)-2-methyl-4-oxo-3-(2-propen-1-yl)-2-cyclopenten-1-yl (1R,3R)-2,2-dimethyl-3-(2-methyl-1-propen-1-
REG. NO.: 28434-00-6
FORMULA: C19H26O3
There is no ISO common name for this substance; the name “esdépalléthrine” is approved by the Association
Française de Normalisation.
The name “S-bioallethrin” (S-生物烯丙菊酯) is approved in China.
The unresolved mixture of stereoisomers has the ISO common name allethrin [584-79-2], and one partially
NOTES: resolved mixture of stereoisomers has the BSI comon name bioallethrin [28057-48-9].
STRUCTURE:
PRONUNCIATION:
INCHIKEY: ZCVAOQKBXKSDMS-PVAVHDDUSA-N
InChI=1S/C19H26O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h7,9,14,16-
INCHI: 17H,1,8,10H2,2-6H3/t14-,16+,17+/m1/s1
descris de Rauch F. , 1972 .

denumirea comună :esdepallethrine (F) , S-bioallethrin (BSI), analog chimic –racemicul cyclopentenyl , neoficial .
introdus de Roussel Uclaf: Esbiothrin , Esbiol >72% esdepaletrin , >21% alletrin
denumirea chimică: (S)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R , 3R)-2,2-dimethyl-3-(2-methylprop-1-
enyl)cyclopropanecarboxylate . (S)-3-allyl-3-methyl-4-oxocyclopent-2-enyl (1R)-trans-2,2-dimethyl-3-(2-
methylprop-1-enyl)= cyclopropanecarboxylate ; (S)-3-allyl-3-meyhyl-4-oxocyclopent-2-enyl(+)-trans-
chrysanthemate .
formula brută: C19H26O3 ;
analiză: produs glc ; mnr ; reziduuri –glc ;
depallethrine >90% -lichid vâscos galben
densitatea 1,000 -1,020 ;
[ α ]D > -47oC ;
punct de inflamabilitate ~120oC ;
solubilitate ~apă ; 100g / Kg hexan ;
utilizări :muşte , ţânţari , insecte zburătoare şi mergătoare
toxicitate orală acută , DL50 şobolan mascul 784 mg esdepalletrin / Kg , femelă 1545 mg /Kg ; pui >5000 mg
/Kg; toxicitatea cutanată acută DL50 –iepuri 1545 mg /Kg .;CL50 inhalare:-şoarece- 1,5 mg/l aer , -şobolan -1,65
mg / l aer ; NEL -0,5 zile ~1000 mg /Kg dietă şobolan ; CL 50(8zile)- raţă , prepeliţă >5000 mg/Kg dietă ;
CL50 (96ore) păstrăv curcubeu -0,01 mg/l ; Formulări :AE , DP , SL ,TC + sinergizanţi …
Tetramethrin tetramethrin
CHINESE: 胺菊酯; FRENCH: tétraméthrine (n.f.); RUSSIAN: тетраметрин

cyclohex-1-ene-1,2-dicarboximidomethyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-
or
cyclohex-1-ene-1,2-dicarboximidomethyl (1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-
or
IUPAC: cyclohex-1-ene-1,2-dicarboximidomethyl (±)-cis-trans-chrysanthemate
(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl 2,2-dimethyl-3-(2-methyl-1-propen-1-
REG. NO.: 7696-12-0
FORMULA: C19H25NO4
ACTIVITY: insecticides (phthalimide insecticides; pyrethroid ester insecticides)
NOTES: The name “phthalthrin” is approved by the Japanese Ministry of Agriculture, Forestry and Fisheries.
STRUCTURE:
PRONUNCIATION: tě-tra-mēth-rǐn Guide to British pronunciation

INCHIKEY: CXBMCYHAMVGWJQ-UHFFFAOYSA-N
InChI=1S/C19H25NO4/c1-11(2)9-14-15(19(14,3)4)18(23)24-10-20-16(21)12-7-5-6-8-13(12)17(20)22/h9,14-
INCHI: 15H,5-8,10H2,1-4H3
Insecticid introdus de Sumitomo Chem. , FMC Corp mărci : Neo-Pinamin Forte , FMC …
formula chimică brută :C19H25NO4
denumirea comună:tetramethrin (BSI, E-ISO ,ANSI) , tetramethrine (F-ISO) , phthalthrin (JMAF);
analiză:produs –glc ; spectroscopie u.v.
denumirea chimică :cyclohex-1-ene-1,2-dicarboximidome (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-
enyl)=cyclopropanecarboxylate ;cyclohex-1-ene-1,2-dicarboximidomethyl (1RS)-cis-trans-2,2-dimethyl-3-(2-
methylprop-1-enyl)=cyclopropanecarboxylate;3,4,5,6,-tetrahydrophthalimidomethyl( ± )-cis-trans-
chrysanthemate ;
tetrametrin tehnic solid uşor galben-brun ;
punct de topire :60-80oC ;
presiunea de vapori: 0,944 mPa(30oC);
densitatea 1,11;
solubilitatea (30oC) 4,6 mg /l apă ;20 g /Kg hexan ;53 g /Kg metanol ;
1 Kg /Kg xilen ;stabil în condiţii normale ; utilizări:
insecticid de contact , cu efect de şoc (knock-down) la blatelide ,muşte, ţânţari , igiena publică .
mixarea cu sinergizanţi majorează eficacitatea , asigură siguranţa .
toxicitatea acută orală DL50 şobolan >5000 mg/Kg; raţă , prepeliţă >1000 mg/Kg;LD50 acută cutanată şobolan
>5000 mg /Kg ; CL50 (96 ore) bluegill 0,021 mg/Kg ;
Formulări :DP , UL , HN , EC , KN ,
Resmethrin resmethrin
CHINESE: 苄呋菊酯; FRENCH: resméthrine (n.f.); RUSSIAN: ресметрин

5-benzyl-3-furylmethyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
or
5-benzyl-3-furylmethyl (1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
or
IUPAC: 5-benzyl-3-furylmethyl (±)-cis-trans-chrysanthemate
CAS: [5-(phenylmethyl)-3-furanyl]methyl 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)cyclopropanecarboxylate
REG. NO.: 10453-86-8
FORMULA: C22H26O3
Some subsets of isomers of this substance have their own ISO common names; see bioresmethrin and
NOTES: cismethrin.
STRUCTURE:
PRONUNCIATION: rěz-mēth-rǐn Guide to British pronunciation

INCHIKEY: VEMKTZHHVJILDY-UHFFFAOYSA-N
InChI=1S/C22H26O3/c1-15(2)10-19-20(22(19,3)4)21(23)25-14-17-12-18(24-13-17)11-16-8-6-5-7-9-16/h5-
INCHI: 10,12-13,19-20H,11,14H2,1-4H3
Insecticid descris de Eliott M., 1967

denumirea comună:resmethrin (BSI , E-ISO , ANSI, ESA , JMAF);resmethrine (F-ISO).
analiză:produs-glc cu FID ; estimarea ‘cis / trans’ – hplc , glc ; reziduu –glc .
introdus de FMC Corp. , Sumitomo Chem. , Penick Corp., Mitchell Cotts Chem. sub denumirile Benzofyroline ,
Chryson … formula
chimică brută : C22H26O3 denumirea chimică
:5-benzyl-3-furylmethyl (1RS , 3 RS ;1RS, 3SR )-2,2-dimethyl-3-(2-methylprop-1-enyl)=cyclopropanecarboxylate ;
5-benzyl-3-furylmethyl (1RS)-cis-trans-2,2-dimthyl-3-(2-methylprop-1-enyl)=cyclopropanecarboxylate;5-benzyl-3-
furylmerhyl( ± )-cis-trans-chrysanthemate (IUPAC).
Resmetrin –solid ceros colorat ;
presiunea de vapori 0,0015 mPa(30oC) ;
solubilitatea (30oC) < 1mg / l apă , 220g /Kg hexan ;81 g /Kg metanol ; >1Kg /Kg xilen .
se descompune în aer şi lumina solară ; în mediu alcalin este instabil .
utilizări: insecticid de contact , cu câmp de activitate larg ;
toxicitatea de 20 ori mai mare la Musca domestica decât piretroizii naturali ;
nu sunt sinergici cu piretroizii naturali .
Fitotoxicitatea este redusă ;
utizat în agricultură , horticultură , igiena publică , în amestec cu alte insecticide .
Toxicitatea orală acută : -şobolan >2500 mg /Kg ; toxicitatea acută cutanată :-şobolan >3000 mg / Kg ; şobolan
–efecte vizibile de teratogeneză absente (90 zile)-25 mg/Kg zi ;~şoarece-50 mg/ Kg zi .
Formulări:AE , EC , WP ,UL , ULV :Pynosect 30, Mixări :resmetrin+malation ; resmetrin + tetrametrin ;
Bioresmethrin bioresmethrin
CHINESE: 生物苄呋菊酯; FRENCH: bioresméthrine (n.f.); RUSSIAN: биоресметрин

5-benzyl-3-furylmethyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
or
IUPAC: 5-benzyl-3-furylmethyl (1R)-trans-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
CAS: [5-(phenylmethyl)-3-furanyl]methyl (1R,3R)-2,2-dimethyl-3-(2-methyl-1-propen-1-yl)cyclopropanecarboxylate
REG. NO.: 28434-01-7
FORMULA: C22H26O3
The name “d-trans-resmethrin” (右旋反式苄呋菊酯) has been used in the literature, but it has no official status.
NOTES: The unresolved isomeric mixture of this substance has the ISO common name resmethrin.
STRUCTURE:
PRONUNCIATION: bī-ō-rěz-mēth-rǐn Guide to British pronunciation

INCHIKEY: VEMKTZHHVJILDY-UXHICEINSA-N
InChI=1S/C22H26O3/c1-15(2)10-19-20(22(19,3)4)21(23)25-14-17-12-18(24-13-17)11-16-8-6-5-7-9-16/h5-
INCHI: 10,12-13,19-20H,11,14H2,1-4H3/t19-,20+/m1/s1
Proprietăţi insecticide descrise de Eliott M.,1967 ;

denumire comună :bioresmethrine ( F-ISO );bioresmethrin (BSI, E-ISO); d-trans-resmethrin (ESA) ;
dezvoltare deFisons , FMC , Roussel Uclaf , Sumitomo Chem. , Wellcome Foundation , mărci (Combat White Fly ,
Insecticide , Chryson , Resbutrin..
bioresmetrin +cismetrin (80:20)~cismthrine .
analiză : produs-glc cu FID ; hplc ; reziduu- glc .
lichid vâscos galben –roşcat-brun parţial solidificat ;
punct de fierbere 181oC / 0,01 mm Hg;
pelicula- film de bioresmetrin expusă la lumina solară se descompune (Eliott M. 1973); hidrolizare rapidă în
mediu alcalin . mixajul bioresmetrin /cismetrin (80/20) –lichid galben parţial cristalizat uneori ; densitatea
1,527-1,530; presiunea de vapori :0,45 mPa(20 oC); solubilitatea (30oC) 1,2 mg/ l apă ; >1Kg /Kg hexan ,
metanol , xilen ;
utilizări:insecticid de contact , pentru muşte , ţânţari , gândaci de bucătărie , plante şi stocuri (Musca domestica
= eficacitatea 50 x E-piretroizii naturali) . fitotoxicitatea –mică ;
mai mic sinergimul –methylenenedioxyphenyl ca la piretroizi ;
toxicitatea acută orală –DL50 şobolan 7070-8000 mg/Kg ; păsări >10 000mg/Kg;
şobolan femelă DL50 >10 000 mg /Kg = toxicitatea acută cutanată ; NEL şobolan - 1200mg /Kg ;câine >500 mg/Kg
; neteratogen moartea fetusului 40 mg/Kg;CL 50 (96ore)-gupi 0,5-1,0 mg/l , peştele arlechin 0,014mg/Kg
<><><>albine DL50 oral 3ng/ex <><><>DL50 topică 6,2 ng/ex.<><><>.
Formulare :AE(1g/ l) , SL(2,5g/l ) ;
mixaje: Combat Insecticide Vegetable(bioresmetrin + malation
!5-Benzyl-3-furylmethyl(E)-(1R)-cis-2,2-dimethyl-=
3-(2-oxothiolan-3-ylidenemethyl)-cyclopropanecarboxylate
descris de Martel J. & Buendia J ,1974 ;
introdus de Roussel Uclaf Kadethrin . denumirea chimică: 5-benzyl-3-furylmethyl (E)-(1R , 3S)-2,2-dimethyl-3-(2-
oxothiolan-3-ylidenemethyl)=cyclopropanecarboxylate(IUPAC) .
[1R-[1α ,3α(E)]]-[5phenylmethyl)-furanyl]methyl 3-[(dihidro-2-oxo-3(2H)-thienylidene)methyl]-2,2-
=dimethylcyclopropanecarboxylate (CA)
formula brută :C23H24O4S
analiză:produs –glc sau hplc ;
Utilizări: efect de şoc (knock-down) la muşte , ţânţari , gândaci de bucătărie ;
Toxicitate orală acută DL50 şobolan mascul 1320 mg /Kg , femela 650 mg /Kg ; câine >1000 mg/Kg ;
toxicitatea acută cutanată LD50 femelă >3200 mg/Kg; toxicitatea respiratorie –tolerata perfect ;NEL (90 zile)-
şobolan 25 mg /Kg zi ;-câine15 mg /Kg zi ; neteratogen (iepure , şobolan , şoarece );şobolan ~metabolizat rapid
+ excretat ; Formulări: TK ,…. Mixaje:AE
Bifenthrin bifenthrin
CHINESE: 联苯菊酯; FRENCH: bifenthrine (n.f.); RUSSIAN: бифентрин

IUPAC: 2-methylbiphenyl-3-ylmethyl (1RS,3RS)-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-
or
2-methylbiphenyl-3-ylmethyl (1RS)-cis-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-
(2-methyl[1,1′-biphenyl]-3-yl)methyl (1R,3R)-rel-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-2,2-
REG. NO.: 82657-04-3
FORMULA: C23H22ClF3O2
NOTES:
STRUCTURE:
PRONUNCIATION: bī-fěn-thrǐn Guide to British pronunciation

OXCDWLBJSLVWHB-LKRLXIKPSA-N
INCHIKEY: OMFRMAHOUUJSGP-UHFFFAOYSA-N
InChI=1S/2C23H22ClF3O2/c2*1-14-16(10-7-11-17(14)15-8-5-4-6-9-15)13-29-21(28)20-18(22(20,2)3)12-
INCHI: 19(24)23(25,26)27/h2*4-12,18,20H,13H2,1-3H3/b2*19-12-/t2*18-,20-/m10/s1
descris de Joel H.J.H.,1984 si A.R. Crossman

introdus de FMC sub marca Talstar , Brigade
formula chimică brută : C23H22ClF3O3
denumirea comună :bifenthrine (F-ISO);
denumirea chimică :2-methylbiphenyl-3-ylmethyl (Z)-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-
=dimethylcyclopropanecarboxylate (IUPAC);
[1α ,3 α (Z)]-( ± )-(2-methyl[1,1’-biphenyl]-3-yl)methyl 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-
=dimethylcyclopropanecarboxylate (CA);
[1α , 3α(Z)]-(± )-(2-methyl[1,1’-bifenyl]-3-yl) methyl 3-(2chloro-3,3,3-trifluoro-1-propenyl)-
=dimethylcyclopropanecarboxylate (C A ).
produs solid ;
punct de inflamabilitate 165oC;
densitatea 1,21g/ cm3(25oC);
presiunea de vapori 0,024 mPa ;
solubilitatea 0,1 mg /l apa; solubil în acetona , cloroform , diclormetan , dietyl eter, toluen ; usor solubil in
heptan , metanol ; produsul tehnic –punct de topire 51-66 oC ; stabil >1 la 25oC ;
utilizări : insecticid cu câmp larg de acţiune (coleoptere , diptere , heteroptere, homoptere , lepidoptere ,
ortoptere , acarieni) .
DL50 orală acută : şobolan 54 ,5 mg produs tehnic / Kg ; prepeliţă 1800 mg /Kg ; raţă > 4450 mg/ Kg ;
DL50 acută cutanată -iepure >2000 mg/Kg ;nu irită pielea , practic nu irită ochii; nu sensibilizează pielea la
porcuşorii de Guinea ; CL50 prepeliţa -4450 mg /Kg dietă ; raţă-1280 mg/Kg dietă ; administrat < 2mg /Kg dietă
zi la şobolan nu este teratogen ; CL50 (96ore )0,00015mg/l la păstrăv; Daphnia -0,00016 mg/l ;bluegill -0,00035
mg/Kg ;slab impact asupra mediului acvatic datorită slabei solubilităţi în apă şi a marii afinităţi la sol .
Betacyflutrin
Cyflutrin cyfluthrin
CHINESE: 氟氯氰菊酯; FRENCH: cyfluthrine (n.f.); RUSSIAN: цифлутрин

(RS)-α-cyano-4-fluoro-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
or
(RS)-α-cyano-4-fluoro-3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2-
CAS: cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 68359-37-5
NOTES: One subset of isomers of this substance has its own ISO common name; see beta-cyfluthrin.
STRUCTURE:
PRONUNCIATION: sī-floo-thrǐn Guide to British pronunciation

InChI=1S/C22H18Cl2FNO3/c1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-16(25)17(10-13)28-14-6-
INCHI: 4-3-5-7-14/h3-11,15,18,20H,1-2H3
denumirea comună :cyflutrin ( BSI , E- ISO ) ; cyflutrine ( F-ISO )

denumirea chimica: ( RS )-α-cyano-4-floro-3-phenoxybenzyl (1RS,3RS ;1RS, 3SR )-3-(2.2-dichlorovinyl)-2,2-
=dimethylcyclopropanecarboxylate ( IUPAC ); cyano-( 4-fluoro-3-phenoxyphenyl) methyl 3-(2,2-dichloroethenyl)-
2,2-dimethylcyclopronecarboxylate( 9CI) ;
Proprietăţile insecticide raportate de Hamman I. &Fuchs R. , 1981
Introdus de Bayer AG . , ca mărci înregistrate ‘Baytroid , Baytroid H’
formula brută: C22 H18 Cl2 FNO3 analiză:produs
– ; reziduuri - metoda Bayer . produsul tehnic –
masă galbenă cleioasă ; punct de topire
60 oC ; enantiomerul I -64oC presiunea de vapori <
1 mPa (20oC); densitatea -1,27 -1,28 g
/cm3 ; solubilitatea 2 mg / Kg apa ;>1
Kg /l diclormetan , toluen ;10-20 g / l hexan ;10 -100 g /l propan-2-ol ;
produsul tehnic conţine:23-26% (S 1R )-cis- + (S 1S )-cis- p.t. 57 oC ;
16 -19% (S 1R )-cis - p.t. 74 oC ;
33 -36% (R 1R )-trans-+(S 1S )trans- p.t. 66 oC ;
22 -25 %(S 1R )-trans-+(R 1S )tras- p.t.102 oC
Utilizări :eficace –Musca domestica , Culicidae , Blatellidae , igienă publică , produse stocate , biocid , efect de
şoc , rezidual pe termen lung la doze mici , DL50 orală acută şobolan mascul 500 -800 mg produs tehnic /Kg ,400
mg în dimetil sulfoxid /Kg ;şobolan femelă 1200mg /Kg ; iepure >1000 mg /Kg ; oi -1000 mg /Kg ; >5000 mg /Kg
prepeliţă ; 5000 mg / Kg găină ; 250 -1000 mg / Kg;DL 50 cutanată DL50 (24 ore) >5000 mg /Kg ;om –
pielea facială iritare subiectiv perceptibilă ; la porci de Guinea –neiritabilă ;
NEL şobolan 50 mg / Kg dietă ; şoarece 200 mg /Kg ; CL50 (96ore) păstrăv curcubeu -0,0006 mg /l ;
periculos pentru albine Formulare :EC (25 ,50 g /l );UL (100 g /Kg ), insectipen (200 mg );
Amestecuri :Baygon Spray AE ,OL
Cyhalotrin cyhalothrin
CHINESE: 氯氟氰菊酯; FRENCH: cyhalothrine (n.f.); RUSSIAN: цигалотрин

(RS)-α-cyano-3-phenoxybenzyl (1RS,3RS)-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
or
(RS)-α-cyano-3-phenoxybenzyl (1RS)-cis-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
cyano(3-phenoxyphenyl)methyl (1R,3R)-rel-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-2,2-
REG. NO.: 68085-85-8
Some subsets of isomers of this substance have their own ISO common name; see gamma-cyhalothrin and
NOTES: lambda-cyhalothrin.
STRUCTURE:
PRONUNCIATION: sī-hǎl-ō-thrǐn Guide to British pronunciation

BFPGVJIMBRLFIR-OWGBZRAASA-N
InChI=1S/2C23H19ClF3NO3/c2*1-22(2)17(12-19(24)23(25,26)27)20(22)21(29)31-18(13-28)14-7-6-10-16(11-
INCHI: 14)30-15-8-4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/b2*19-12-/t2*17-,18?,20-/m10/s1
denumirea comună : cyhalothrin (BSI , BPC , E-ISO) ; cyhalothrine (F-ISO)

denumirea chimică :(RS)-α –cyano-3-phenoxybenzyl (Z)-(1 RS , 3RS )-(2 -chloro-3,3,3-trifluoropropenyl )-2,2-
=dimethylcyclopropanecarboxylate(IUPAC).
(RS)-α-cyano-3-phenoxybenzyl(Z)-(1 RS)-cis-3-(2-chloro-3,3,3-trifluoropropenyl)-2,2-
=dimethylcyclopropanecarboxylate (C A).
formula brută :C23 H19 Cl F3NO3
analiză :produs –hplc ;reziduuri –glc cu ECD(electron-capture detection)
insecticid descris de Bentley P.D. ,1980;
acaricid descris de Stubbs V. K.
introdus de ICI în Australia ‘Grenade’ .
cihalotrin cu puritate 90% din care 95% izomeri cis –ulei vâscos galben –brun ;
punctul de fierbere -187-190 oC / 0,2 mm Hg ;
densitatea -1,25 g /cm3 (25oC) ;
presiunea de vapori -0,001 mPa (20oC)
solubilitatea :0,003 mg /l apă (20oC);>500 g /l acetona , diclormetan , dietil eter, etil acetat , hexan , metanol ,
toluen; stabilitate : t =50 oC , la întuneric , în 4 ani nu se schimbă’ cis /trans’; la lumină < 10% -1,67 ani ;
la 275oC se descompune ; hidroliza :- slabă la pH 7 -9 ;-rapid la pH >9 .
Utilizări : ectoparaziţi –Boophilus microplus , Haematobia irritans la bovine , deparazitari la oi spray 21 zile cu
70 mg /l adăposturi ;
DL50 oral mascul şobolan 243 mg prod. tehnic / Kg ;femela şobolan144 mg/Kg; porcuşori Guinea >5000 mg / Kg;
iepure > 1000 mg /Kg ; raţă > 5000 mg /Kg ; iritabilitate moderată pentru ochi ; irită mediu pielea iepurelui .
Efecte toxicologice nesemnificative la şobolan după 2 zile , de la administrarea 2,5 mg /Kg dietă zi ;
administrat oral la sobolan se elimină rapid (urină , fecale); CL 50 pentru păstrăv curcubeu –0,00054 mg/ l ;
DZA om -0,02 mg/Kg Formulări: EC , Grenade .
Cyhalothrin ((S)(Z)-(1 R)-cis-si (R) (Z)-(1S)-cis-izomeri gamma-cyhalothrin
CHINESE: 精高效氯氟氰菊酯; FRENCH: gamma-cyhalothrine (n.f.); RUSSIAN: гамма-цигалотрин

(S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
or
(S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
(S)-cyano(3-phenoxyphenyl)methyl (1R,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-2,2-
REG. NO.: 76703-62-3
STRUCTURE:
PRONUNCIATION: gǎm-a sī-hǎl-ō-thrǐn Guide to British pronunciation

INCHIKEY: ZXQYGBMAQZUVMI-GCMPRSNUSA-N
InChI=1S/C23H19ClF3NO3/c1-22(2)17(12-19(24)23(25,26)27)20(22)21(29)31-18(13-28)14-7-6-10-16(11-
INCHI: 14)30-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3/b19-12-/t17-,18+,20-/m0/s1
formula brută:C23H19ClF3NO3
reacţie mixaj 1:1 (S)-α-cyano-3-phenoxybenzyl (Z)-(1R, 3R)-3-(2-chloro-3,3,3-trifluoropropenyl )-2,2-
=dimethylcyclopropanecarboxylate + (R)-α-cyano -3-phenoxybenzyl (Z)-(1S , 3S )-3-(2-chloro-3,3,3-
trifluoropropenyl)-2,2-=dimethylcyclocarboxylate ( IUPAC) ;
mixaj 1:1 (S) –α-cyano-3-phenoxybenzyl (Z)-(1R)-cis-3-(2chloro-3,3,3-trifluoropropenyl) -2,2-
=dimethylcyclopropanecarboxylate + (R )-α-cyano-3-phenoxybenzyl (Z)-(1S)-cis-3-(2-chloro-3,3,3-
trifluoropropenyl)-2,2-=dimethylcyclopropanecarboxylate(CA)
Insecticid descris de Jutsum A .R.,1984 .
introdus de ICI Plant Protection Div. ca marcă înregistrată’ Karate’
solid colorat ;
punct de topire 49,2 ;
presiunea de vapori 200 nPa;
solubilitatea 0,005 mg / l apă purificată (pH=6,5 ) , 0,004mg / l apă tamponată (pH=5,0)(20 oC);solubil în
solvenţi organici
stabil > 0,5ani (15-25oC );
fotostabil ;
utilizare: Lepidoptera , Coleoptera , Hemiptera la culturi de câmp (orz ..) , vărzoase , bumbac , cartof .
DL50 acută orală şobolan mascul 79 mg produs tehnic în ulei de porumb/Kg ; femelă şobolan 56mg /Kg ; ambele
sexe 233-477 mg s.a. (EC-500 g /l )/ Kg sau 230-482 mg s.a.(EC 250g / l) /Kg; m . raţă >3950 mg /Kg .
DL50 acută cutanată şobolan - mascul 632 mg p. t. în propan -1,2-diol / Kg ;
-femela 696 mg /Kg .
nu este iritant pentru piele ;
este iritant ocular mediu ;
nu este mutagen ;
Formulări: EC (25 , 50 g s.a. /l ) , L (8 g /l)
!Lambda -cyhalotrin lambda-cyhalothrin
CHINESE: 高效氯氟氰菊酯; FRENCH: lambda-cyhalothrine (n.f.); RUSSIAN: лямбда-цигалотрин

reaction product comprising equal quantities of (R)-α-cyano-3-phenoxybenzyl (1S,3S)-3-[(Z)-2-chloro-3,3,3-
trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-[(Z)-2-
chloro-3,3,3-trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate
or of
(R)-α-cyano-3-phenoxybenzyl (1S)-cis-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-[(Z)-2-chloro-3,3,3-
IUPAC: trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate
(R)-cyano(3-phenoxyphenyl)methyl (1S,3S)-rel-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-2,2-
REG. NO.: 91465-08-6
STRUCTURE:
PRONUNCIATION: lǎm-da sī-hǎl-ō-thrǐn Guide to British pronunciation

BFPGVJIMBRLFIR-GUCBCRIZSA-N
InChI=1S/2C23H19ClF3NO3/c2*1-22(2)17(12-19(24)23(25,26)27)20(22)21(29)31-18(13-28)14-7-6-10-16(11-
INCHI: 14)30-15-8-4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/b2*19-12-/t2*17-,18+,20-/m10/s1
Cypermetrin cypermethrin
CHINESE: 氯氰菊酯; FRENCH: cyperméthrine (n.f.); RUSSIAN: циперметрин

(RS)-α-cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
or
IUPAC: (RS)-α-cyano-3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
CAS: cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 52315-07-8
Some subsets of isomers of this substance have their own ISO common names; see alpha-cypermethrin, beta-
NOTES: cypermethrin, theta-cypermethrin and zeta-cypermethrin.
STRUCTURE:
PRONUNCIATION: sī-per-mēth-rǐn Guide to British pronunciation

InChI=1S/C22H19Cl2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-
INCHI: 5-9-15/h3-12,17-18,20H,1-2H3
formula brută :C22 H19 Cl2 NO3

denumirea comună; cypermethrin(BSI , E-ISO , ANSI);cypermethryne (F-ISO).
denumirea chimica:(RS)- α-cyano-3-phenoxybenzyl (1RS ,3RS;1RS ,3SR)-3-(2,2-dichlorovinyl )-
=dimethylcyclocarboxylate (IUPAC);
(RS)-α-cyano-3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorvinyl)-1,1 -=dimethylcyclopropanecarboxylate (C
cyano-(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate(9CI).
descoperit de Eliott M. 1975
raportat de Breese M.H. & Highwood D.P. ,1977
pus pe piaţă de Ciba –Geygi , ICI Plant Protection Division , Mitchell Cotts , Shell International Chemical
Co.:Ambush ,Cymbush , Ripcord , Folcord …
analiză : produs-glc prin FID (flame-ionisation detection ) , hplc ;reziduu –glc prin ECD (electron capture
detection ).
Produs tehnic-masa semi-solidă gălbui brună vâscoasă , devine lichidă la 60 oC ; presiunea de vapori-190 nPa ;
solubilitatea(21oC)0,01-0,2 mg produs tehnic /l apă ;450 g /l acetonă , cloroform, ciclohexanona , xilen ;337 g /l
etanol ;103 g /l hexan
termostabil până la 220oC ;
descompunere fotochimică în laborator , dar în câmp nu se cunoaşte suficient.. stabilitate mai bună la pH acid
decât alcalin , la pH=4 optimul stabilităţii .. degradarea în sol –Roberts T.R. , Standen M.E.
utilizare: insecticide de contact , ingestie pentru Lepidoptera , Hemiptera , la culturi de câmp , pomi , viţa de vie ,
ectoparaziţi (Boophilus micropus la bovine , 150mg /l ; scabia -Psoroptes spp. , Melophagus ovinus 10mg /l
tratament unic), insecte vectoare (ţânţari ,..)50-75 mg /m2 , persistenţă 42-72 ore .
DL50 acută orală :şobolan 251-4123 mg /Kg ;şoarece-138 mg/Kg ;păsări > 2000 mg /Kg ; iepure >2400 mg /Kg;
slab iritant pentru piele , mediu iritant ocular ; şobolan -100 mg/Kg dietă în al 2-lea an efecte toxice ;câine
300mg/Kg dietă; DL50(96 ore) păstrăv brun -0,0020-0,0028 mg/l ;
Formulări:EC ( 25-400 g s.a. /l )agricultură ;UL (10-50/l )Barricade , Stockade; EC ( 25-200 g/l )uz veterinar;
Flectron , Folcord - igiena publică , …. raportul între izomerii cis /trans = 45/55+/-10% m / m .
Amestecuri: EC ( Polytrin ….)
Alfametrin = Alfacypermethrin = Alfoxylate = Cypermethrin(S1R-cis-+R1S-cis * alpha-cypermethrin
CHINESE: 顺式氯氰菊酯; FRENCH: alpha-cyperméthrine (n.f.); RUSSIAN: альфа-циперметрин

racemate comprising (R)-α-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dichlorovinyl)-2,2-
or
racemate comprising (R)-α-cyano-3-phenoxybenzyl (1S)-cis-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-dichlorovinyl)-2,2-
CAS: (R)-cyano(3-phenoxyphenyl)methyl (1S,3S)-rel-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 67375-30-8
The name “alphamethrin” has been used in the literature, but it has no official status.
STRUCTURE:
PRONUNCIATION: ǎl-fa sī-per-mēth-rǐn Guide to British pronunciation

GUQZCTLEJXHSIH-RZAVTOELSA-N
InChI=1S/2C22H19Cl2NO3/c2*1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-
INCHI: 4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/t2*17-,18+,20-/m10/s1
Proprietăţile insecticide au fost raportate de Fischer J.P. , 1983

formula brută :C22H19Cl2NO3
denumirea chimică:(S)-α-cyano-3-phenoxybenzyl(1R ,3R )-3-(2,2-dichrovinyl)- 2,2-
dimethylcyclopropanecarboxylate şi (1S,3S)-3-(2,2-dichlorovinyl)-2,2-dimethyl cyclopropanecarboxylate ,
mixare 1:1 , (IUPAC ); [1α(S*),3α]-(±)-cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-
dimethylcyclopropanecarboxylate (9CI)
analiză :produs ~ hplc ;reziduuri ~glc cu ECD .
introdus de Shell Internatonal Chem . sub marca Concord , Fastac –uz agricol , Fendona-igienă publică ;
produs tehnic >90% , tipic > 95% -amestec de 2stereoizomeri , pudră cristalină; punct de topire 80,5 oC ( 99%
puritate enantiomeri pereche );
presiunea de vapori-170 nPa (20oC);
densitate 1,12 g/cm3 ;
solubilitatea 0,005-0,01 mg /l apă , 620 g /l acetonă , 515 g /l cyclohexanonă , 7 g /l hexan , 315 g /l xilen ;
stabil în mediu acid şi neutru , hidrolizeaza rapid în mediu bazic; la 220 oC se descompune ; stabil
în aer şi la lumină ; utilizari:5
-30 g s.a. / ha pentru combaterea lepidopterelor , coleopterelor , hemipterelor la culturi de camp , legume ,
pomi fructiferi , viţa de vie , bumbac , silvicultura , soia , citrice ;
ectoparaziţi – Boophilus microplus -60 mg /l baie , Melophagus ovinus ; igiena publică ( culicide , blatelide ,
purici , Glossina , alte insecte vectoare) ;10-30 mg /m2 , bună persistenţă pe suprafeţe .
DL50 orală acută -79 mg produs tehnic (în ulei de porumb 50 g/l ) /Kg ; 368 mg(200 g/l ulei de porumb)/ Kg ;4000
mg (400 g/l dimetil sulfoxid) /Kg ; DL 50 acută cutanată şobolan -500 mg /produs tehnic ( 250 dimetil sulfoxid
)/Kg; irită minim pielea ;irită mediu ochii ; după 90 de zile de hrănire cu < 60mg/Kg dietă nu au apărut semne
toxicologice sau patologice majore ; toxicitatea pentru albine -efecte nocive inexistente la adulţi în laborator ,
mici la colonii în condiţii de camp; CL50 (96ore) -0,0028 mg / l toxic în laborator pentru păstrăvul curcubeu ;
în practică Nu au fost sesizate semne de toxicitate la peşti … Formulări: WP
( 50 g /Kg); EC( 20 , 30 , 50 , 100 g /l );SC (15 , 100, 250 g /l ) ; UL (15 g /l) ;
Zeta-cypermetrin zeta-cypermethrin
FRENCH: zêta-cyperméthrine (n.f.); RUSSIAN: зета-циперметрин

mixture of the stereoisomers (S)-α-cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate where the ratio of the (S);(1RS,3RS) isomeric pair to the (S);(1RS,3SR)
IUPAC: isomeric pair lies in the ratio range 45-55 to 55-45 respectively
CAS: (S)-cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 52315-07-8
STRUCTURE:
PRONUNCIATION: zē-ta sī-per-mēth-rǐn Guide to British pronunciation

INCHIKEY: KAATUXNTWXVJKI-QPIRBTGLSA-N
InChI=1S/C22H19Cl2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-
INCHI: 5-9-15/h3-12,17-18,20H,1-2H3/t17?,18-,20?/m1/s1
Permetrin permethrin
CHINESE: 氯菊酯; FRENCH: perméthrine (n.f.); RUSSIAN: перметрин

3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
or
IUPAC: 3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate
CAS: (3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 52645-53-1
FORMULA: C21H20Cl2O3
Some subsets of isomers of this substance have their own ISO common names; see biopermethrin and
NOTES: transpermethrin.
STRUCTURE:
PRONUNCIATION: per-mēth-rǐn Guide to British pronunciation

INCHIKEY: RLLPVAHGXHCWKJ-UHFFFAOYSA-N
InChI=1S/C21H20Cl2O3/c1-21(2)17(12-18(22)23)19(21)20(24)25-13-14-7-6-10-16(11-14)26-15-8-4-3-5-9-15/
INCHI: h3-12,17,19H,13H2,1-2H3
proprietăţile insecticide au fost descrise de Eliott M. , 1973

formula brută:C21 H20 Cl2 O3
denumire comună:permethrine (BSI , E-ISO , ESA , BPC , ANSI ); permethrine (F-ISO );
dezvoltat de FMC Co., ICI Plant Protection Div., Mitchell Cotts Chem .,Shell Int. Chem. Sumitomo Chem. ,
Penick ..mărci: Ambushfog , Coopex ,Corsair, Tornade , Perthrine , Pounce , Dragnet , Kafil , Talcord , Peregrin ,
Qamlin . Denumirea chimică: 3-phenoxybenzyl(1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
=dimethylcyclopropanecarboxylate (IUPAC); 3-phenoxybenzyl(RS)-cis-trans -3-(2,2-dichlorovinyl)-2,2-
=dimethylcarboxylate (CA).
produsul tehnic –lichid galben brun ~brun , la 20 oC cristalizare parţială ,uneori presiunea de vapori 0,0013mPa;
densitatea 1,214 ; punctul de topire-34-39oC;
izomerul cis 63-65oC;presiunea de vapori 0,0025mPa; izomerul trans 44-47 oC ; presiunea de vapori 0,0015 mPa;
solubilitatea 0,2 mg /l apă (30oC); >1Kg/ Kg hexan ;258g /Kg metanol ; termostabil >2ani la 50 oC
;stabilitatea mare în mediu acid fata de mediu alcalin; stabilitatea optima la pH=4;
Fotostabilitatea -degradare fotochimică în laborator;
Utilizări: insecticid cu câmp larg de activitate , dăunători la frunze şi fructificaţii (coleoptere , lepidoptere)~100-
150 g /ha bumbac ;fructe -25-50g/ha;viţa de vie 50-200 g/ha;legume 40-70g/ha;ectoparaziţi 60 zile -200 mg s.a.
/m2 perete ; 200mg/Kg lână ;gândaci de bucătărie şi insecte mergătoare -100mg s.a./m 2. DL50 orală cis /trans =
40:60 ;şobolan~430-4000 mg /Kg ;şoarece~540-2690 mg /Kg;pui găină >3000 mg /Kg; prepeliţa japoneză
>13500 mg/Kg ; în anul al doilea an cu dieta 100 mg/Kg fără efect ; CL 50 (96ore) păstrăv curcubeu 0,009 mg /l ;
DZA om = 0,05 mg / Kg .
Formulări:EC(100-500 g s.a. / Kg; WP (100-500 g s.a. /Kg );GR ( 3g /Kg ); UL(50-100); AE ; Amestecuri:
Deltametrin deltamethrin
CHINESE: 溴氰菊酯; FRENCH: deltaméthrine (n.f.); RUSSIAN: дельтаметрин

(S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate
or
IUPAC: (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate
CAS: (S)-cyano(3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate
REG. NO.: 52918-63-5
FORMULA: C22H19Br2NO3
The name “decamethrin” was originally proposed for this compound and was used in the literature, but was
NOTES: rejected because of a conflict with a trade mark.
STRUCTURE:
PRONUNCIATION: děl-ta-mēth-rǐn Guide to British pronunciation

INCHIKEY: OWZREIFADZCYQD-NSHGMRRFSA-N
InChI=1S/C22H19Br2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-
INCHI: 5-9-15/h3-12,17-18,20H,1-2H3/t17-,18+,20-/m0/s1
denumirea comună :deltamethrin (BSI ,E-ISO);delthamethrine (F-ISO ) ; decamethrin , redenumit deltamethrin ,

1998 OMS ; descris de Eliott M. ,1974 , Tessier J. ,1984
formula brută chimică :C22 H19Br 2NO3
denumirea chimică : (S)-α–cyano-3-phenoxybenzyl (1R )-cis-3-(2,2-dibromovinyl)-2,2-
dimethylcyclopropanecarboxylate (C A );
(S)-α-cyano-3-phenoxybenzyl (1R , 3R)-3(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate (IUPAC).
Introdus de Roussel Uclaf ,1984 sub mărcile ‘Decis ‘uz agronomic ;’K-Othrine igienă publică ; Butox , Butoflin uz
veterinar.
analiză:hplc ;i.r.spectroscopie ;reziduuri-glc cu ECD .
în soluţie de hexan cristalizează numai izomerul deltametrin
produsul tehnic >98% deltametrin m/m –pudră cristalină colorată ;
punctul de fierbere -98-101oC ;α D + 61oC (40 g /l benzen ) ;
presiunea de vapori 0,002 mPa (25o C );
solubilitatea (20 oC) 0,002 mg /l apă ;500 g /l acetonă ; 450 g /l benzen , dimetil sulfoxid ;750 g/l
ciclohexanonă ;900 g /l dioxan;15 g /l etanol ;250 g /l xilen . stabil la lumina solară şi în aer;
mai stabil în mediu acid decât în mediu alcalin ;
utilizări:insecticid eficace , de contact , de ingestie , cu câmp larg de activitate insecte dăunătoare ( pomi
fructiferi , culturi de câmp , legume , de depozit) , igienă publică , ectoparaziţi animali ,..
- DL50 :- orală acută -la şobolan = 135 - 5000mg /Kg;
- la câine > 300 mg /Kg;
-cutanee acută –la şobolan>2000mg /Kg;
-inhalare acută- la şobolan=0,6mg /Kg;
-DL50-orală acută pe tip de formulare :EC(150g/l)-1080mg /Kg;
EC(250g/l)-535mg/Kg;
WP(25g/l)-16000mg/Kg;
SC(25g/l)-40000mg/Kg
DZA om =0,01 mg /Kg
Formulări:EC (25g s.a. /Kg , Decis); UL (3-19 g /l);SC (25 g /l );GR (0,5 g /Kg); SC (7,5 ..25 g/l) ;DP (0,1-0,5 g /Kg );
Amestecuri:Decis Best , Decis Quick (25 g deltametrin +400 g heptenofos ) , Thripstick (deltametrin +
polybutena ).
Esfenvalerat esfenvalerate
CHINESE: S-氰戊菊酯; FRENCH: esfenvalérate (n.m.); RUSSIAN: эсфенвалерат

IUPAC: (αS)-α-cyano-3-phenoxybenzyl (2S)-2-(4-chlorophenyl)-3-methylbutyrate
CAS: (S)-cyano(3-phenoxyphenyl)methyl (αS)-4-chloro-α-(1-methylethyl)benzeneacetate
REG. NO.: 66230-04-4
NOTES: The unresolved isomeric mixture of this substance has the common name fenvalerate.
STRUCTURE:
PRONUNCIATION: ěs-fěn-vǎl-er-āt Guide to British pronunciation

INCHIKEY: NYPJDWWKZLNGGM-RPWUZVMVSA-N
InChI=1S/C25H22ClNO3/c1-17(2)24(18-11-13-20(26)14-12-18)25(28)30-23(16-27)19-7-6-10-22(15-19)29-21-
INCHI: 8-4-3-5-9-21/h3-15,17,23-24H,1-2H3/t23-,24+/m1/s1
Fenvalerat . fenvalerate
CHINESE: 氰戊菊酯; FRENCH: fenvalérate (n.m.); RUSSIAN: фенвалерат

IUPAC: (αRS)-α-cyano-3-phenoxybenzyl (2RS)-2-(4-chlorophenyl)-3-methylbutyrate
CAS: cyano(3-phenoxyphenyl)methyl 4-chloro-α-(1-methylethyl)benzeneacetate
REG. NO.: 51630-58-1
NOTES: One subset of isomers of this substance has its own ISO common name; see esfenvalerate.
STRUCTURE:
PRONUNCIATION: fěn-vǎl-er-āt Guide to British pronunciation

INCHIKEY: NYPJDWWKZLNGGM-UHFFFAOYSA-N
InChI=1S/C25H22ClNO3/c1-17(2)24(18-11-13-20(26)14-12-18)25(28)30-23(16-27)19-7-6-10-22(15-19)29-21-
INCHI: 8-4-3-5-9-21/h3-15,17,23-24H,1-2H3
denumirea comună:fenvalerate (E-ISO , BSI , F-ISO , ESA );

formula brută : C25H22ClNO3
analiză:hplc ;reziduu-glc cu ECD
denumirea chimică :(RS)-α–cyano-3-phenoxybenzyl (RS)-2-(4-chlorophenyl)-3-methylbutyrate (IUPAC ) ;
cyano(3-phenoxyphenyl)methyl4-chloro-α-(1-methylethyl )benzeneacetate (9CI);
insecticid descris de Ohno N. 2000; Mowlam M.D., testări în câmp 1977 .
introdus de Shell International Chemical , Sumitomo, sub marca Sumicidin … lichid vâscos galben sau brun ,
porţiune cristalină la to camerei ;
presiunea de vapori 0,037mPa (25oC) ;
densitatea 1,175 ;
solubilitatea (20oC)<1mg /l apă ;1Kg /Kg acetonă , cloroform, ciclohexanonă , etanol , ;xylen ( 23 oC );155 g /Kg
hexan .
fotostabil , termostabil ; stabil
mai mult în mediu acid decât în alcalin , optim la pH=4 .
utilizări :insecticid puternic de contact , combate rase rezistente la insecticide (organoclorurate ,
organofosforice , carbamice ) ;insecte filofage +fructificaţii la legume, pomi fructiferi ,viţa de vie , 25-250 g s.a. /
ha , persistenţă în câmp; igienă publică şi adăposturi de animale 100 mg/m 2 perete , pentru 60 zile;
DL50 acută orală şobolan 451 mg/Kg ; păsări domestice >1600 mg/Kg ; DL 50 acută cutanată şobolan >5000 mg
/Kg; NEL în anul 2 de 250mg/Kg dietă la şobolan ; CL50 (96ore) la păstrăv -0,0036 mg/l ;
DZA temporară om =0,02mg/Kg
Formulări:EC(25-300 gs.a./l ) Sumicidin ; UL(25-75g/l) ;SC (100g/l);
Amestecuri:Sumicombi (fenvalerat+fenitrotion)
Etofenprox etofenprox
CHINESE: 醚菊酯; FRENCH: étofenprox (n.m.); RUSSIAN: этофенпрокс

IUPAC: 2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether
CAS: 1-[[2-(4-ethoxyphenyl)-2-methylpropoxy]methyl]-3-phenoxybenzene
REG. NO.: 80844-07-1
FORMULA: C25H28O3
ACTIVITY: insecticides (pyrethroid ether insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: ět-ō-fěn-prǒks Guide to British pronunciation

INCHIKEY: YREQHYQNNWYQCJ-UHFFFAOYSA-N
InChI=1S/C25H28O3/c1-4-27-22-15-13-21(14-16-22)25(2,3)19-26-18-20-9-8-12-24(17-20)28-23-10-6-5-7-11-
INCHI: 23/h5-17H,4,18-19H2,1-3H3
Fenpropatrin fenpropathrin
CHINESE: 甲氰菊酯; FRENCH: fenpropathrine (n.f.); RUSSIAN: фенпропатрин

IUPAC: (RS)-α-cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate
CAS: cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate
REG. NO.: 39515-41-8
FORMULA: C22H23NO3
NOTES:
STRUCTURE:
PRONUNCIATION: fěn-prō-pa-thrǐn Guide to British pronunciation

INCHIKEY: XQUXKZZNEFRCAW-UHFFFAOYSA-N
INCHI: InChI=1S/C22H23NO3/c1-21(2)19(22(21,3)4)20(24)26-18(14-23)15-9-8-12-17(13-15)25-16-10-6-5-7-11-16/h5-
13,18-19H,1-4H3
Denumirea comună :fenpropathrin (BSI ,E-ISO); fenpropathrine ( F-ISO) formula brută :C 22H23 NO3
denumirea chimică :(RS)-α–cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate (IUPAC);
cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate (CA) ;
analiză: produs –hplc; glc cu FID; reziduu-glc cu ECD .
proprietaţile insecticide descrise de Fujita Y. 1981
introdus de Sumitomo Chemical Co. sub marca Rody , Danitrol , Meothrin . produs tehnic solid galben-brun ;
punct de topire 45-50 oC;
presiunea de vapori 0,730mPa (20oC);
densitate 1,150 ;
solubilitate (25oC): 0,33mg /l apă ;
1Kg /Kg ciclohexanonă , xilen , 337 g/Kg metanol ;
utilizări:acaricid şi insecticid 50-200 g s.a./ha la diverse culturi:pomicultură , legumicultură , viticultură ,
bumbac , cereale ,..
DL50 orală acută şobolan :- mascul 70,6 mg în ulei de porumb /Kg;-femelă 66,7 mg / kg; răţoi -1089 mg /Kg ;
DL50 cutanată acută şobolan:-mascul 1000 mg/Kg ;-femelă 870 mg /Kg . CL 50(48 ore) 0,002mg /l .
Formulări : EC(50 , 100 , 200 , 300s.a./Kg ;SC(100 g /l) Amestecuri:
(fenitrotion +fenvalerat) Danitol , Sumimix ,Sumimik
Fluvalinat fluvalinate
FRENCH: fluvalinate (n.m.); RUSSIAN: флювалинат

IUPAC: (RS)-α-cyano-3-phenoxybenzyl N-(2-chloro-α,α,α-trifluoro-p-tolyl)-DL-valinate
CAS: cyano(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-DL-valinate
REG. NO.: 69409-94-5
NOTES: One subset of isomers of this substance has its own ISO common name; see tau-fluvalinate.
STRUCTURE:
PRONUNCIATION: floo-vǎl-ǐn-āt Guide to British pronunciation

INCHIKEY: INISTDXBRIBGOC-UHFFFAOYSA-N
InChI=1S/C26H22ClF3N2O3/c1-16(2)24(32-22-12-11-18(14-21(22)27)26(28,29)30)25(33)35-23(15-31)17-7-6-
INCHI: 10-20(13-17)34-19-8-4-3-5-9-19/h3-14,16,23-24,32H,1-2H3
activitatea insecticidă şi stereoizomerie raportată de Henrick C. A. 1980, Anderson R.J., 1985;introdus de Zoecon
Corp. sub marca Mavric , Mavric HR ,
denumire comună : fluvalinat (ANSI) pentru DL-valinate
formula brută :C26H22Cl F3N2O3 analiză:produs-
hplc ;reziduuri –glc cu ECD denumire
chimică:(RS)-α-cyano-3-phenoxybenzyl N-(2-chloro-α,α,α-trifluoro-p-tolyl)-D-valinate (IUPAC);
cyano(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate(CA );
D-valinate –ulei galben vâscos ;
punct de fierbere < 450oC ;
presiunea de vapori < 0,013 mPa(25oC) ;
densitatea 1,29 g /cm3 ;
solubilitate < 0,005 mg/ Kg apă ;
solubil în alcool , hidrocarburi aromatice , diclormetan , diethyl eter .
stabilitatea la hidroliză :la 25oC , pH=3 şipH= 6 în 30 zile -50% ;pH=9 – 1-2 ore;
la 42oC la pH=6 -8 zile ;pH=9 1-2 ore ;închis în sticlă >1,5 ani la 42 oC ; fotostabilitatea :produsul ’ filmat’ pe sticlă
sau silicagel are Ti50 -2zile; în emulsie apoasă (1,6 g /l) în sticlă -12 zile în aer -50% într-o zi ;
utilizări:insecticid cu câmp larg , aplicare foliară la doza de 56-168 g s.a. /ha , la combaterea afidelor ,cicadelor ,
lepidopterelor ,tizanopterelor ,+ acaricid acarieni tetranichizi din culturile ( legume , ornamentale , pomi , vie,…)
Toxicitate acută orală –DL50 şobolan 260-280 mg D-valinat /Kg; şoarece 150-220mg /Kg ;prepeliţă > 2510 mg
/Kg ; toxicitatea cutanată acută DL50 >20 000g DL-valinate/Kg ; iritant mediu pentru piele şi ochi ;
LC50 (8 zile) –răţoi , prepeliţă >5620mg/Kg dietă ;neteratogen ; LC50 (96 ore) –bluegill 0,0009 mg/l
(NEL=0,00033mg/l );păstrăv curcubeu-0,0029 mg/l; în câmp doze mici driftul pot afecta mediile acvatice .
Formulări:SC (240g/l ), EW (223g D-valinate /Kg) <>Mavrik Aquaflow , M. HR
Tau-fluvalinat tau-fluvalinate
CHINESE: 氟胺氰菊酯; FRENCH: tau-fluvalinate (n.m.); RUSSIAN: тау-флювалинат

IUPAC: (RS)-α-cyano-3-phenoxybenzyl N-(2-chloro-α,α,α-trifluoro-p-tolyl)-D-valinate
CAS: cyano(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate
REG. NO.: 102851-06-9
NOTES: The unresolved isomeric mixture of this substance has the ISO common name fluvalinate.
STRUCTURE:
PRONUNCIATION: tor floo-vǎl-ǐn-āt Guide to British pronunciation

INCHIKEY: INISTDXBRIBGOC-XMMISQBUSA-N
InChI=1S/C26H22ClF3N2O3/c1-16(2)24(32-22-12-11-18(14-21(22)27)26(28,29)30)25(33)35-23(15-31)17-7-6-
INCHI: 10-20(13-17)34-19-8-4-3-5-9-19/h3-14,16,23-24,32H,1-2H3/t23?,24-/m1/s1
Tefluthrin
introdus de Imperial Chemical Industries Plant Protection ‘Force’,’Forta’ . denumirea comună:tefluthrine (F-ISO),
tefluthrin( BSI , E-ISO )
formula brută : C17H14ClF7O2
analiză:produs - reziduu - .
denumirea chimică :2,3,5,6-tetrafluoro-4-methylbenzyl(Z)-(1RS , 3RS)-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-
=dimethylcyclopropanecarboxylate 2,3,5,6-tetrafluoro-4-methylbenzyl (Z)-(1RS)-cis-3-(2-chloro-3,3,3-
trifluoroprop-1-enyl)-2,2-=dimethylcyclopropanecarboxylate (IUPAC) .
Tefluthrin solid colorat ;
punct de topire 44,6oC ;
presiunea de vapori 80 mPa (20oC)
solubilitatea (20oC) 0,02 mg /l apa ( …apa pH =5,0 , pH=9,2 , apa purificată pH=6,5 );( 21 oC) ;>500 g / l acetonă ,
diclorometan , etil acetic , hexan , toluen ;
stabilitatea >30 zile la pH=5 -7. La pH=9 în 30 zile -7% hidrolizează .
Termostabilitatea > 0,75 ani la t o15-25oC ;
Utilizări: insecte (coleoptere , lepidoptere , unele diptere) hipogeice la culturi prăşitoare( porumb , sfecla de
zahăr ) cu’ L ‘sau ‘GR’ .
DL50 acută orală şobolan 22-35 mg /Kg în ulei porumb ;şoarece 45-56 mg /kg ; raţoi 4190mg/Kg ; raţa 262
mg /Kg ;toxic pentru peşti în câmp adsorbţia în aluviuni şi suspensii este supusă hazardului .
Formulări:EC 100g/Kg ;CS 100 g/Kg ;GR 100 g/Kg .
Tralometrin tefluthrin
CHINESE: 七氟菊酯; FRENCH: téfluthrine (n.f.); RUSSIAN: тефлутрин

2,3,5,6-tetrafluoro-4-methylbenzyl (1RS,3RS)-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-
or
2,3,5,6-tetrafluoro-4-methylbenzyl (1RS)-cis-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-
(2,3,5,6-tetrafluoro-4-methylphenyl)methyl (1R,3R)-rel-3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propen-1-yl]-2,2-
REG. NO.: 79538-32-2
FORMULA: C17H14ClF7O2
NOTES:
STRUCTURE:
PRONUNCIATION: tě-floo-thrǐn Guide to British pronunciation

FIAIQJBJJWXQRC-MLKWDWEKSA-N
INCHIKEY: ZFHGXWPMULPQSE-UHFFFAOYSA-N
InChI=1S/2C17H14ClF7O2/c2*1-6-11(19)13(21)7(14(22)12(6)20)5-27-15(26)10-8(16(10,2)3)4-
INCHI: 9(18)17(23,24)25/h2*4,8,10H,5H2,1-3H3/b2*9-4-/t2*8-,10-/m10/s1
formula brută :C22H19Br4NO3

descoperit şi introdus de Roussel Uclaf
denumirea comună :tralomethtrin (BSI );tralomethrine ( ) ;
denumirea chimică :(S)-α-cyano-3-phenoxybenzyl (1R ,3S)-2,2-dimethyl-3-[(RS)-1,2,2,2-
tetrabromoethyl ]=cyclopropanecarboxylate ( IUPAC ); (S)-α-cyano-3-phenoxybenzyl (1R) –cis-2,2-
dimethyl-3-[(RS)-1,2,2,2-tetrabromoethyl]=cyclopropanecarboxylate ( CA).
analiză:hplc :reziduu-glc cu ECD
tralometrin tehnic >93% - solid răşinos oranj la galben ;
produs pur -2 diastereoizomeri 60:40
densitatea 1,700
presiunea de vapori 17pPa
[ α]D +21o …+27o (50g/l toluen ) ;
solubilitate : 70 mg /l apă ; >1Kg /l acetona, diclormetan , toluen , xylen ; >500 g /l dimetil sulfoxid ;>180 g /l
etanol; în mediu acid stabil , hidrolizare şi reducere prin epimerizare
utilizări :insecticid cu câmp larg (insecte filofage –coleoptere , lepidoptere … ) 16-22 g s.a. /ha soia , cartof (15-
20 g /ha) , legume(11-15g /ha );
DL50 acută orală şobolan 99-3000 mg /Kg ; prepeliţă >2150 mg /Kg ; câine >500 mg capsule / Kg ;DL 50 acută
cutanată : iepure>2000 mg / Kg ; ochi-slab iritant ;piele–slab iritant; CL 50 acută inhalare: -şobolan > 0,286 mg /l
aer ; NEL (90 zile )6mg/Kg zi ;câine -1 mg/Kg zi dietă ; CL 50 (8 zile )prepeliţă -4301mg /Kg dieta ; raţă -7716
mg/Kg dietă ; CL50(96ore)-păstrăv curcubeu 0,0016 mg / l ; bluegill 0,0043 mg /l ; Daphnia -38ng/Kg; în mediu
natural nu este toxic pentru peşti ;
Formulări :EC ( 360 g/l ; ) ; SC (150 g/l ); concentrate ( 300 g/l xi
4. 3.10.. Insecticide cloronicotinilice
Insecticidele cloroniconilice sunt derivaţi ai nitrometilenei , nitroguanidinei . Acţionează prin contact ,ingestie ,
sistemic Toxicitatea este moderată , nu irită ochii şi pielea . Se utilizează pentru tratamentele în vegetaţie , ale
părţilor aeriene ale plantelor , tratarea seminţelor ,a solului …
Mecanismele biochimice de acţiune la nivelul sistemului nervos central determină blocarea postsinaptică a
receptorilor colinergici ai acetilcolinei .
Substanţe
acetamiprid
CHINESE: 啶虫脒; FRENCH: acétamipride (n.m.); RUSSIAN: ацетамиприд

IUPAC: (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine
CAS: (1E)-N-[(6-chloro-3-pyridinyl)methyl]-N′-cyano-N-methylethanimidamide
REG. NO.: 135410-20-7
FORMULA: C10H11ClN4
ACTIVITY: insecticides (pyridylmethylamine nicotinoid insecticides)
NOTES:
STRUCTURE:
ǎ-sǐ-tǎm-ǐ-prǐd
PRONUNCIATION: Guide to British pronunciation
INCHIKEY: WCXDHFDTOYPNIE-RIYZIHGNSA-N
INCHI: InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
imidacloprid
CHINESE: 吡虫啉; FRENCH: imidaclopride (n.m.); RUSSIAN: имидаклоприд

IUPAC: (E)-1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine
CAS: (2E)-1-[(6-chloro-3-pyridinyl)methyl]-N-nitro-2-imidazolidinimine
REG. NO.: 138261-41-3
FORMULA: C9H10ClN5O2
ACTIVITY: insecticides (nitroguanidine nicotinoid insecticides; pyridylmethylamine nicotinoid insecticides)
The name “imidacloprid” was originally approved for a mixture of (E)- and (Z)-isomers, but in 2007 the sponsor
determined that the substance is comprised almost entirely of the (E)-isomer and requested that the definition
NOTES: be changed. It is not possible to specify this isomer in a Standard InChI.
STRUCTURE:
PRONUNCIATION: ǐm-ǐd-a-klō-prǐd Guide to British pronunciation

YWTYJOPNNQFBPC-DLSJENCCNA-N
INCHIKEY: YWTYJOPNNQFBPC-UHFFFAOYSA-N
InChI=1/C9H10ClN5O2/c10-8-2-1-7(5-12-8)6-14-4-3-11-9(14)13-15(16)17/h1-2,5H,3-4,6H2,(H,11,13)/f/h11H/
b13-9+
Standard InChI (no stereo):
INCHI: InChI=1S/C9H10ClN5O2/c10-8-2-1-7(5-12-8)6-14-4-3-11-9(14)13-15(16)17/h1-2,5H,3-4,6H2,(H,11,13)
thiacloprid
CHINESE: 噻虫啉; FRENCH: thiaclopride (n.m.); RUSSIAN: тиаклоприд

IUPAC: (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide
CAS: (Z)-[3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide
REG. NO.: 111988-49-9
FORMULA: C10H9ClN4S
insecticides (pyridylmethylamine nicotinoid insecticides; thiazolidine insecticides)
NOTES:
STRUCTURE:
PRONUNCIATION: thī-a-klō-prǐd Guide to British pronunciation

INCHIKEY: HOKKPVIRMVDYPB-UVTDQMKNSA-N
INCHI: InChI=1S/C10H9ClN4S/c11-9-2-1-8(5-13-9)6-15-3-4-16-10(15)14-7-12/h1-2,5H,3-4,6H2/b14-10-

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FITOFARMACIE

9 pictogrammes de danger (SGH-CLP) : (SGH1 à SGH 9)

L'étiquetage et l'emballage des substances (Directive 67/548/EEC) et des melanges

GHS Pictograms and Hazard Categories

Information on the application procedure.

amorphous silica gel

amorphous silicon dioxide

basic copper carbonate

basic copper chloride

basic copper sulfate

copper carbonate, basic

copper sulfate, basic

copper zinc chromate

ethylmercury 2,3-dihydroxypropyl mercaptide

juvenile hormone III

phenylmercury derivative of pyrocatechol

tribasic copper chloride

tribasic copper sulfate

-Pdeudozyma flocculosa -Susa benigna a virusului mozaicului galben

-Virusul poliedrozei nucleare la Spodoptera exigua

Fitofarmacia trebuie obligatoriu compartimentată astfel :

1) încăpere unde se comercializează produsele pentru care au aprobare.

La sediul (legal) al fitofarmaciei trebuie să existe documentele:

c) documente care atestă efectuarea recepţiei calitative a produselor;

d) registrul unic de control.

Personalul fitofarmaciei se compune din:

CONDIŢII DE ORGANIZARE ŞI FUNCŢIONARE A DEPOZITULUI FITOFARMACEUTIC

-Acibenzolar-S-methyl acibenzolar acibenzolar ацибензолар

STATUS: ISO 1750 (published)

PRONUNCIATION: ǎ-sǐ-běn-zō-lar British pronunciation

Alphametrin(Alphacypermethrin alpha-cypermethrin alpha-cyperméthrine альфа-циперметрин

PRONUNCIATION: ǎl-fa sī-per-mēth-rǐn British pronunciation

- Aminotriazol (Amitrol) amitrole; amitrole ; амитрол

PRONUNCIATION: ǎ-mǐ-trōl British pronunciation

- Azimsulfuron azimsulfuron; azimsulfuron ; азимсульфуро

PRONUNCIATION: ǎz-ǐm-sǔl-fūr-ǒn British pronunciation

- azoxystrobin azoxystrobine азоксистробин

PRONUNCIATION: ǎz-ǒks-ē-strō-bǐn British pronunciation

- Benalaxyl benalaxy bénalaxyl беналаксил

PRONUNCIATION: běn-a-lǎks-ǐl British pronunciation

- Bentazon bentazone bentazone бентазон

PRONUNCIATION: běn-ta-zōn British pronunciation

PRONUNCIATION: bē-ta sī-floo-thrǐn British pronunciation

-Bifenazat bifenazate bifénazate бифеназат

PRONUNCIATION: bī-fěn-a-zāt British pronunciation

-Bromoxynil bromoxynil bromoxynil бромоксинил

-Carfentrazon –ethyl carfentrazone carfentrazone карфентразон

PRONUNCIATION: kar-fěn-tra-zōn British pronunciation

-Chlorothalonil chlorothalonil chlorothalonil хлороталонил

PRONUNCIATION: klor-ō-thǎl-ō-nǐl British pronunciation

-Chlorotoluron (chlortoluron) chlorotoluron chlortoluron хлоротолурон

PRONUNCIATION: klor-ō-tǒl-ūr-ǒn British pronunciation

-Chlorpropham chlorpropham chlorprophame хлорпрофам

PRONUNCIATION: klor-prō-fǎm British pronunciation

–Chlorpyriphos (chlorpyriphos-ethyl) chlorpyriphos* хлорпирифос

PRONUNCIATION: klor-pǐr-ǐ-fǒs British pronunciation

–Chlorpyrifos methyl chlorpyrifos-methyl chlorpyriphos-méthyl хлорпирифос-метнл

PRONUNCIATION: klor-pǐr-ǐ-fǒs mē-thīl British pronunciation