Total Pages—7 SH CHE—O1 |
(Model Syllabus) \
Ist Semester Examination, 2021
Time <3 hours
Full Marks : 60
Answer from all the Parts as per direction
The figures in the right-hand margin indicate marks
Candidates are required to answer in their own words
as far as practicable
(NORGANIC CHEMISTRY - 1)
PART—I
1. Answer al! the following questions : 1x8
(a) The number of electrons present in the 3rd
orbit of Cr‘? ion is
(4) In de-Broglie's relation z » P represents
(c) The periodic table has been divided into
number of blocks.
(Turn Over)(2)
(d) In the periodic table electron gain enthalpy
on moving from left to right along a
period.
(e) Fora salt to be soluble in a solvent, lattice
energy should be than solvation energy,
() Chargex Distance =
(g) Oxidation number of sulphur in sodium
tetrathionate is i
(h) Due to large size of alkali metal cations
defect is not found in alkali metal
halides.
PART — 1
Answer any eight of the following questions : 14x8
(a) What is Aufbau's rule ? Which orbital will
be first filled up by electron between 4s and
3d?
(6) What is effective nuclear charge ?
SH CHE~O1 (Model Syilsens) ( Continued )C3)
{c) Why there are no 2d orbitals ?
(@) Explain what do you understand by typical
elements in the periodic table.
(e) How does hybridisation affect the radius of
an atom 7?
(f) Define radius ratio. What will be the co-
r ——— a .
ordination number of cation if radius ratio
limiting value is 0.155-0.225 ?
;
(g) Define resonance energy and draw the reso-
nating structures of CO.
(h) Why KHF, exists but not KHC1,?
(i) Which point defect gives rise to the
formation of F-centres in crystals ? What is
the effect of F-centres in solid crystals ?
(/) Write the formula to calculate e.m.f. ofa cell
if reduction potentials of anode and cathode :
are given.
SH CHE—01 (Model Syllabus) ( Turn Over(4)
PART = I
3. Answer any eight of the following questions :
. . 2
(a) Write the Schridinger wave equation far ;
< hydrogen atom.
(b) What is the meaning of radial probability
distribution of electron ? What is obtained
by the product of probability density and -
volume of the shell ?
(c) The terms or designations 5, p, d and f for
subshells originate from atomic spectra (series
of lines). Write the full forms of these four
letters.
(d) Give reasons for the following order of radii
for an atom and its corresponding cation
and anion. radius of cation