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Total Pages—7 SH CHE—O1 | (Model Syllabus) \ Ist Semester Examination, 2021 Time <3 hours Full Marks : 60 Answer from all the Parts as per direction The figures in the right-hand margin indicate marks Candidates are required to answer in their own words as far as practicable (NORGANIC CHEMISTRY - 1) PART—I 1. Answer al! the following questions : 1x8 (a) The number of electrons present in the 3rd orbit of Cr‘? ion is (4) In de-Broglie's relation z » P represents (c) The periodic table has been divided into number of blocks. (Turn Over) (2) (d) In the periodic table electron gain enthalpy on moving from left to right along a period. (e) Fora salt to be soluble in a solvent, lattice energy should be than solvation energy, () Chargex Distance = (g) Oxidation number of sulphur in sodium tetrathionate is i (h) Due to large size of alkali metal cations defect is not found in alkali metal halides. PART — 1 Answer any eight of the following questions : 14x8 (a) What is Aufbau's rule ? Which orbital will be first filled up by electron between 4s and 3d? (6) What is effective nuclear charge ? SH CHE~O1 (Model Syilsens) ( Continued ) C3) {c) Why there are no 2d orbitals ? (@) Explain what do you understand by typical elements in the periodic table. (e) How does hybridisation affect the radius of an atom 7? (f) Define radius ratio. What will be the co- r ——— a . ordination number of cation if radius ratio limiting value is 0.155-0.225 ? ; (g) Define resonance energy and draw the reso- nating structures of CO. (h) Why KHF, exists but not KHC1,? (i) Which point defect gives rise to the formation of F-centres in crystals ? What is the effect of F-centres in solid crystals ? (/) Write the formula to calculate e.m.f. ofa cell if reduction potentials of anode and cathode : are given. SH CHE—01 (Model Syllabus) ( Turn Over (4) PART = I 3. Answer any eight of the following questions : . . 2 (a) Write the Schridinger wave equation far ; < hydrogen atom. (b) What is the meaning of radial probability distribution of electron ? What is obtained by the product of probability density and - volume of the shell ? (c) The terms or designations 5, p, d and f for subshells originate from atomic spectra (series of lines). Write the full forms of these four letters. (d) Give reasons for the following order of radii for an atom and its corresponding cation and anion. radius of cation

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