Total Pages—6 : SH CHE—02 (Model Syllabus) 1st Semester Examination, 2021 Time : 3 hours Full Marks : 60 Answer from all the Parts as per direction The figures in the right-hand margin indicate marks Candidates are required to answer in their own words as far as practicable (PHYSICAL CHEMISTRY - I) PART—I 1. Answer al! the following questions : 1x8 (a) Viscosity of gases with temperature. (5) The temperature above which a gas can not be liquefied however great the pressure may be is called temperature of that gas. (c) Anexample of moderate electrolyte is___ (Turn Over)SH CHE=02 (Model $3 "\abus) (2) (a) When temperature js increased; the surface tension ofa liquid (e) In a solid crystal the angle between the normals to the two intersecting faces is called angle. ( Whatis the Co-ordination number of Cs* ion in CsCl crystal ? (g) Mixing up of NH,OH with ——— forms a basic buffer solution. (2) pH of 0.001M HCI solution is es PART —1 Answer any eight of the following questions : 4 x8 (a) Define collision frequency. (8) What is compressibility factor ? (e) What is continuity of states 7 How does vapour pressure of liquid depend 9 upon temperature, nature of liquid and surface area ? (Continued )(3) (e) What is degree of j Onisation of weak electrolyte 7 (f) State law of constancy of interfacial angles of solids. (g) Name three symmetry elements. (2) What do you mean by liquid crystal ? () Explain buffer capacity, (7) What is hydrolysis of salt 2 PART =I] 3. Answer any eight of the following questions; yg (a) What do you mean by average, most probable and root mean square velocities of fas molecules ? (6) Derive Charle's law from kinetic gas equation. (c) At what temperature CO will have same velocity as that of CH, ? SH CHE-02 (Model Syllabus) ( Turn Over)(4) (a) Express Pc, Tc and Vc in terms ofaand 5, the notations have their usual meanings. (e) Distinguish between evaporation and boiling ? (f) Mention a property common to solid and liquid and another property common to liquid and gas. (g) Mention a few applications of surface tension. (4) Mention a few applications of buffer solution in analytical chemistry. (i) Distinguish between solubility and solubility product of a sparingly soluble salt. () Why is aqueous solution of Na,CO3 alkaline ? PART —IV Answer all the following questions as directed : 6 x4 4. (a) (i) What are causes of deviation of real gases from ideal behaviour ? 2 (ii) Write the postulates of kinetic molecular theory of gases. 4 SH CHE-02 (Model Syllabus) (Continued )(5) Or (2) (i) Prove that Cp-Cy = R for one more of ideal gas, 3 (ii) Define x, 6 ana $ for reduced equation ofstate and the Teduced equation of state. 3 5. (a) Define Coeffic’ ient of viscosity. Discuss one method of its determination, 1+5 Or () Write notes on: 24+4 @) Ionic Product of water (ii) Cleaning action of ‘soap. 6 (a) (i) Explain powder method for determination of crystal structure of NaCl, 3 (Gi) Calculate the number of plane, axis and centre of symmetry in a cubic crystal. 3 Or : (6) (i) What are schottky and Frenkel] defects in crystals 7 4 SHCHE~p2 (Model Syllabus) (Turn Over )(6) (ii) Calculate Miller indices of the plane for «on wieles fad Yi which weiss indices are 7+ °9 - 2 7. (a) Explain application of solubility product principle and common ion effect in precipi- tation of group - II Sulphides in qualitative analysis. 6 Or (b) Explain following titration curves : 343 (Strong acid with strong base (ii) Weak acid with strong base. SH CHE—02 (Model Syllabus) BA-1,900