154 Industrial Polymers, Specialty Polymers, and Their Applications
1.24.5 Poly(Vinyl Ethers}
‘Commercial uses have developed for several poly(vinyl ethers) in which R is methyl, ethyl, and
isobutyl The vinyl alkyl ether monomers are produced from acetylene and the corresponding alcohols,
and the polymerization is usually conducted by cationic initiation using Friedel-Craft-type catalysts
Poly(vinyl methyl ether) is a water-soluble viscous liquid which has found application in the adhesive
and rubber industries. One particular applications has been as a heat sensitizer in the manufacture of
rubber-latex dipped goods.
Ethyl and butyl derivatives have found uses as adhesives. Presure-sensitive adhesive tapes made from
poly(vinyl ethyl cither) incorporating antioxidants are said to have tovice the shelf life of similar tapes
‘made from natural rubber, Copolymers of vinyl isobutyl ether with vinyl chloride vinyl acetate and ethyl
acrylate are also produce.
1.2.4.6 Poly(Vinyl Pyrrolidone)
-for-pi}
ho dn
on
plasma substitute. Also, about 796 polymer added to whole blood allows it to be frozen, stored at liquid
nitrogen temperatures for years, and thawed out without destroying blood cells.
merization is usually carried out in aqueous solution to produce a solution containing
1.2.4.7 Poly(Vinyl Carbazole)
tet
OO
Poly(vinyl carbazole) is produced by polymerization of vinyl carbazole using free-radial initiation or
gler-Natta catalysis,
Poly(vinyl carbazole) has a high softening point, excellent electrical insulating properties, and good
photoconductivity, which has led to its application in xerography.