AJ50015P2 Solution

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Online

06/10/2013 AIATS
P-II

Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456 Fax : 011-47623472

TEST-1 (PAPER-II) : ANSWERS


PHYSICS CHEMISTRY MATHEMATICS

1. (D) 21. (A) 41. (A)

2. (C) 22. (C) 42. (C)

3. (C) 23. (A) 43. (A)

4. (B) 24. (B) 44. (B)

5. (B) 25. (D) 45. (A)

6. (C) 26. (A) 46. (C)

7. (B, C, D) 27. (B, C) 47. (B, D)

8. (B, C) 28. (B, C) 48. (B, C)

9. (A, C) 29. (A, C, D) 49. (A, B, C)

10. (A, B, C, D) 30. (C, D) 50. (B, C, D)

11. (A, C) 31. (C, D) 51. (B, D)

12. (B) 32. (C) 52. (A)

13. (B) 33. (B) 53. (A)

14. (B) 34. (D) 54. (B)

15. (C) 35. (B) 55. (D)

16. (A) 36. (B) 56. (A)

17. (A) 37. (C) 57. (D)

18. (9) 38. (4) 58. (4)

19. (1) 39. (1) 59. (5)

20. (5) 40. (1) 60. (7)

–1–
Online
06/10/2013 AIATS
P-II

Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456 Fax : 011-47623472

ALL INDIA AAKASH TEST SERIES for IIT-JEE (Advanced)-2015


Test- 1 (Paper-II)

PART - I : PHYSICS
1. Answer (D)
2. Answer (C)

1 2
y = αx 2 = αt
2

t
x=
2

dx 1
=
dt 2
3. Answer (C)

VS2S1
VS2

30°
30°
60° 60°

G G
| VS1 | = | VS2 | = 10 m/s

4. Answer (B)

2g1h − 2g2 h = S

2h 2h
− =T
g2 g1

2g1h − 2g 2 h S
T = =
g1g2 g1g 2

S2
g1g2 =
T2

–2–
5. Answer (B)

v2 v2
ac = = = constant
4R 4
v 2 = v ⎛1 + vt ⎞
speed V ' = v + ⎜ 4 ⎟⎠
t
4 ⎝
2
V2 ⎛ vt ⎞
ac = = v 2 ⎜1 + ⎟
R ⎝ 4⎠
6. Answer (C)

V
v

t
T T 2T
Δt1 = Δt2 = (n − 3) Δt3 =
n n n

Average speed = Distance = Area of V − T curve


Time T

1⎡ T⎤
⎢T + (n + 3) ⎥ v
= ⎣
2 n⎦ v
= (2n − 3)
T 2n

7. Answer (B, C, D)

2uv v2
R= ,h =
g 2g

4h v R 2g 2uv
= ,h= 2
,R =
R u 8u g
8. Answer (B, C)
1 1
u(T + t ) − g (T + t )2 = uT − gT 2
2 2
T is the time taken by second particle
u t
T = −
g 2
9. Answer (A, C)
10. Answer (A, B, C, D)
11. Answer (A, C)
α + β = 90

u2
h1 = sin2 α
2g

u2
h2 = sin2 β
2g

–3–
12. Answer (B)
13. Answer (B)
Solution of Qs. 12 & 13

8H W3
T2 = W4 10 m
g C D
A B
8
× 10 = T 2 − (2 2)2
10
T=4s W1 W2

Δx1 4 ×vx
= = 2
Δx 2 2 2 × v x

14. Answer (B)


15. Answer (C)
z(m)
Solution for Qs. 14 & 15
JJJJG JJJJG JJJJG
Down the rope displacement = P1P2 = OP2 − OP1 (50, 0, 50)
P1
(0, 50, 25)
= (50 ˆj + 25kˆ ) − (50iˆ + 50kˆ ) P2

y(m)
= −50iˆ + 50 jˆ − 25kˆ O

JJJJG
| P1P2 | = 75 m (Length of the rope)

16. Answer (A) x(m)


17. Answer (A)
18. Answer (9)

North | VAG | = V 3
| VWG | = v
°
30

30°
| VAW | = v
East

540 u 3
Δt = = 540 s
u 3
= 9 minutes.
19. Answer (1)

I
= pressure = [ML–1T–2]
v
|a| = 1 |b| = 1 |c| = 2

|a|+|b|
=1
|c |

–4–
20. Answer (5)
y

10 m/s
Δx
30°

h h
2 2
x
5 m/s
Δx = 5 × t
Δx
= 5 m/s
t

PART - II : CHEMISTRY
21. Answer (A)

N 1000
M= ×
NA v(ml)

22. Answer (C)

ω2 × 1000 150 × 1000


m= = = 1.6 mol/kg
M2 × ω1 98 × 950

23. Answer (A)

X 5
= ...(i)
Y 4
(250) X + (500) XY = 2000 × 1.6 ...(ii)
Solving (i) & (ii)
X + Y = 8.86
24. Answer (B)

Orbital angular momentum = l(l + 1) h


Radial nodes = n – l – 1
Angular nodes = l
25. Answer (D)
ψ represents electron wave. It is a dimensionless quantity.
26. Answer (A)
Mn outermost electronic configuration is 3d 54s 2
and it has 5 unpaired electrons.
Mn+5 has 2 unpaired electrons
Mn+3 has 4 unpaired electrons
Mn+4 has 3 unpaired electrons
27. Answer (B, C)
1 g-atom of nitrogen (N) = 1 mole of N-atoms = 0.5 mole of N2 molecules

–5–
28. Answer (B, C)

xM + y(M + 1) + z(M + 2)
Mean mass = = M + 0.5
x+y+z

Where x : y : z = 4 : 1 : 1 or 9 : 6 : 1
29. Answer (A, C, D)

(A) No. of atoms = 6 × NA × 3


18

(C) No. of atoms = 7.5 × NA × 24


180

4.25 × NA × 4
(D) No. of atoms =
17
30. Answer (C, D)
In Bohr's theory particle character of electron is considered.
31. Answer (C, D)

μ = n(n + 2).BM

where n is number of unpaired electron(s).


V has 3 unpaired electrons (x)
Mn has 5 unpaired electrons (z)
Cr has 6 unpaired electrons (y)
32. Answer (C)

0.32 RT
V= ...(1)
32 P

0.26 RT
V= ...(2)
M P
From equation (1) & (2)

0.32 0.26
=
32 M
M = 26
33. Answer (B)
C2H2 has molecular mass 26 g/mol.
34. Answer (D)

2.179 × 10−18 × 6.023 × 1023 22


E= × 2 kJ / mol.
1000 1
35. Answer (B)

⎛1 1 ⎞
E = 2.179 × 10 −18 × 42 ⎜ 2 − 2 ⎟ J
⎝1 ∞ ⎠
36. Answer (B)
Applying the concept of limiting reagent.
–6–
37. Answer (C)
Radial nodes = n – l – 1,
No. of radial nodes 3s is 2
4s is 3
2p is 0
3p is 1
38. Answer (4)

G ⎛ 1 1⎞
v = RZ2 ⎜ 2 − 2 ⎟
⎝ x1 x 2 ⎠

In Lyman series n1 = 1 and n2 = ∞ for highest energy transition


In Balmer transition for higher energy n1 = 2 and n2 = ∞
39. Answer (1)

z
v = 2.18 × 106
n
40. Answer (1)

1
12 × 1U
12

PART - III : MATHEMATICS


41. Answer (A)

⎛ 1 ⎞ 2 1
f ⎜ 3 x + 3 ⎟ = 2x + 3 x + + 3
⎝ x⎠ x x
1
Put 3
x + 3
=t
x
1 ⎛ 1 ⎞
x+ + 3⎜ 3 x + 3 ⎟ = t3
x ⎝ x⎠
1
x+ = t 3 − 3t
x

(
∴ f (t ) = 2 t 3 − 3t + t )
f (t ) = 2t 3 − 5t

f(1) = 2 – 5 = –3
42. Answer (C)

log 3 ( )
( x − 4) + log3 (10 − x ) − log9 [( x + 2)2 ( x − 1)] + log3 ( )
x −1 < 0

Domain is (4, 10)

⎛ ( x − 4)(10 − x ) x − 1 ⎞ + – +
log3 ⎜ ⎟<0
⎜ + 2
− ⎟ 6
⎝ ( x 2) ( x 1) ⎠ 7

–7–
⎛ ( x − 4)(10 − x ) ⎞ − x 2 + 14 x − 40
log3 ⎜ ⎟ < 0 ⇒ <1
⎝ x+2 ⎠ x +2

⇒ x 2 − 13 x + 42 > 0

(x – 6) (x – 7) > 0
∴ x ∈ (4, 6) ∪ (7, 10)
43. Answer (A)
n((A – B)') = 16
⇒ a + c + d = 16 ...(1)
A
n(A ∪ B) = 12 B
b
c
⇒ n(A ∪ B) = 12 ...(2) d
a
⇒ b + c + d = 12
⇒ a + b + c + d = 20 ...(3)
⇒ n(A) = 10
b + c = 10
a=8 ⇒ n(A Δ b) =b+d
b=4
c=6 =4+2
d=2 =6
44. Answer (B)
Domain is x > 0

2 2 2
⎡ ⎛ x + 4 ⎞⎤ ⎡ ⎛ x ⎞⎤ ⎡ ⎛ 1 ⎞⎤
⎢log ⎜ ⎟ ⎥ + ⎢log ⎜ ⎟ ⎥ = 2 ⎢log ⎜ ⎟⎥
⎣ ⎝ x ⎠⎦ ⎣ ⎝ x + 4 ⎠⎦ ⎣ ⎝ x + 1⎠⎦

⎛ x + 4⎞ 2⎛ 1 ⎞
2log2 ⎜ ⎟ = 2log ⎜ x + 1 ⎟
⎝ x ⎠ ⎝ ⎠

⎡ ⎛x +4⎞ ⎛ 1 ⎞⎤ ⎡ ⎛ x + 4 ⎞ ⎛ 1 ⎞⎤
⇒ ⎢log ⎜ x ⎟ − log ⎜ x + 1 ⎟ ⎥ ⎢log ⎜ x ⎟ + log ⎜ x + 1 ⎟ ⎥ = 0
⎣ ⎝ ⎠ ⎝ ⎠⎦ ⎣ ⎝ ⎠ ⎝ ⎠⎦

x+4 1 ⎛ x + 4 ⎞⎛ 1 ⎞
⇒ = or ⎜ ⎟⎜ ⎟ =1
x x +1 ⎝ x ⎠⎝ x + 1 ⎠
x2 + 5x + 4 = x
x2 + 4x + 4 = 0

x = −2

x + 4 = x2 + x

x2 = 4

x = ±2

x = 2 is the only solution.

–8–
45. Answer (A)
Remainder must be linear so remainder is ax + b
Put x = 1 0=0+a+b ...(1)
Put x = –1 1 + 1 = 0 + (–a + b) ...(2)
a=–b
b–a=2
b=1
a = –1
46. Answer (C)
Proper subsets = 27 – 1
Subset containing either 3 or 4 elements = 7C3 + 7C4 = 70
Subset containing at most 5 elements are = 27 – 7C6 – 7C1
= 128 – 7 – 1
= 120
47. Answer (B, D)

⎛ 1 ⎞ 1
x 6 ⎜ x6 − 6 ⎟ x 6 −
⎛ 2 1 ⎞ ⎝ x ⎠ x 6
f ⎜x − 2 ⎟ = =
⎝ x ⎠ x6 ⎛ x 4 − 1 ⎞ x 4 + 1
⎜ ⎟
⎝ x4 ⎠ x4

1
Put x − =t
2
...(1)
x2
⇒ Squaring both sides in equation (1)

1 1
x4 + 4
− 2 = t 2 ⇒ x4 + 4
= t2 + 2
x x

⇒ Cubing both sides in equation (1)

1 ⎛ 1 ⎞
x6 − − 3⎜ x2 − 2 ⎟ = t 3
x6 ⎝ x ⎠

1
x6 − = t 3 + 3t
x6

t 3 + 3t t (t 2 + 3)
∴ f (t ) = =
t +2
2
t2 + 2

∴ 1× 4 4 7
f (1) = = f (2) =
3 3 3

4 7
f ( −1) = − f ( −2) = −
3 3

f (t ) + f ( − t ) = 0 ∀ t ∈ R

–9–
48. Answer (B, C)
Number of elements divisible by 3 from 1 to 150 = 50
Number of elements divisible by 5 from 1 to 150 = 30
Number of elements divisible by 15 from 1 to 150 = 10
n(A) = 50 + 30 – 10 = 70
n(B) = 76
1 to 9 → 5
10 to 99 → 90 – 20 = 70
100 → 1

1 to 100 are → 76
49. Answer (A, B, C)

⎡ 1⎤ ⎡ 2⎤
[a ] = 3 + ⎢3 + ⎥ + ⎢3 + ⎥ + ...... + [6]
⎣ 5⎦ ⎣ 5⎦

r r r
3≤3+ <4 4≤3+ < 5 5 ≤ 3+ < 6
5 5 5
0≤r <5 5 ≤ r < 10 10 ≤ r < 15
⎡ r⎤ ⎡ r⎤ ⎡ r⎤
⎢3 + 5 ⎥ = 3 ⎢3 + 5 ⎥ = 4 ⎢ 3 + 5 ⎥ = 5
⎣ ⎦ ⎣ ⎦ ⎣ ⎦

15
⎡ r⎤ 4
⎡ r⎤ 9
⎡ r⎤ 14
⎡ r ⎤
a= ∑ ⎢⎣3 + 5 ⎥⎦ = ∑ ⎢⎣3 + 5 ⎥⎦ + ∑ ⎢⎣3 + 5 ⎥⎦ + ∑ ⎢⎣3 + 15 ⎥⎦ + 6
r =0 r =0 r= 5 r = 10

=3×5+4×5+5×5+6

a = 66
[[x + 3] – 2] = 0, 1, 2, 3
⇒ 0 ≤ |x + 3| –2 < 4

0 ≤| x +3|< 6 or –6 < x + 3 ≤ –2
2≤x<3 –9 < x ≤ –5
–≤x<3
Integral solution are : –1, 0, 1, 2, –5, –6, –7, –8

b=8
50. Answer (B, C, D)

U
B b A
c a
C
e
d

According to first two statements, this is the possible Venn diagram.


Now,

n(C '∩ A) = 7 ⇒ b + c = 7 ...(1)

– 10 –
n(B ΔC ) = 5 ⇒ c + d = 5 ...(2)

n( A − (B − C )) = 6 ⇒ b + d + e = 6 ...(3)

n( A − (C − B )) = 9 ⇒ b + c + e = 9 ...(4)

n((B ∪ C )') = 5 ⇒ a + b = 5 ...(5)

Solving
a = 2, b = 3, c = 4, d = 1, e=2
∴ n(A) = b + c + d + e = 10
n(B) = c + e = 6
n(C) = e + d = 3
n(U) = a + b + c + d + e = 12
51. Answer (B, D)

3 3 3(3)2 x
f (x) = , f (1 − x ) = =
32 x + 3 32 −2 x + 3 32 + 3(32 x )

32 x
f (1 − x ) =
3 + 32 x

3 + 32 x
f ( x ) = f (1 − x ) = =1
3 + 32 x

2013
⎛ r ⎞ ⎛ 1 ⎞ ⎛ 2 ⎞ ⎛ 2011⎞ ⎛ 2012 ⎞ ⎛ 2013 ⎞
∑ f ⎜⎝ 2013 ⎟⎠ = f ⎜⎝ 2013 ⎟⎠ + f ⎜⎝ 2013 ⎟⎠ + ..... + f ⎜⎝ 2013 ⎟⎠ + f ⎜⎝ 2013 ⎟⎠ + f ⎜⎝ 2013 ⎟⎠
r =1 

= 1006 + f(1)

1 4025
= 1006 + =
4 4
52. Answer (A)
53. Answer (A)
Solution for Qs. 52-53

A B
b e c

a h
f g

d
C

|C ∪ B'| = 0 ⇒ d+f=0
|(B – C) ∩ A| = 0 ⇒ e=0
|A Δ B| = 6 ⇒ b+c+f+g=6
|(A ∩ C)'| = 10 ⇒ a + b + c + d + e + g = 10

– 11 –
|(A ∩ C)Δ(A ∪ C)'| = 7 ⇒ a+c+f+h=7
|(A – (B – C)| = 4 ⇒ b+f+h=4
|C' ∩ B| = 2 ⇒ c+e=2
|(B ∪ C)'| = 7 ⇒ a+b=7
Solves all these
a = 4, b = 3, c = 2, d = e = f = 0, g = 3, h = 1
|A| = b + e + f + h = 4
|C| = d + f + g + h = 4
54. Answer (B)
55. Answer (D)
Solution for Qs. 54-55

(
f ( x ) = log10 sin3 x + sin6 x + 1 )
(
f ( − x ) = log10 − sin3 x + sin6 x + 1 )
⎛ ⎞
⎜ ( − sin3 x + sin6 x + 1)(sin3 x + sin6 x + 1) ⎟
= log10 ⎜
( )

⎜ sin3 x + sin6 x + 1 ⎟
⎝ ⎠
⎛ 1 ⎞
= log10 ⎜ ⎟
⎜ ⎟
⎝ 1 + sin x + 1 ⎠
6

= − log10 (sin3 x + sin6 x + 1)


f ( − x ) = −f ( x )
Hence odd function.
f ( x ) = [ g ( x ) + g (− x )][ g ( x ) − g (− x )]
f (− x ) = [g(− x ) + g( x )][g(− x ) − g( x )]

= −[g ( − x ) + g ( x )][g ( x ) − g (− x )]

f ( − x ) = −f ( x )

f(x) is odd function.


56. Answer (A)

⎡ln( xy ) = ln x → ln y ⎤
⎢ ⎥ Q→1
⎣ f ( xy ) = f ( x ) − f ( y ) ⎦
⎡ f ( x + y ) = f ( x )f ( y ) ⎤
⎢ ⎥ P→2
⎢⎣ e x + y = e x − e y ⎥⎦

ex e− x
f ( x ) + f (−x ) = 1 ⇒ + =1 R→4
1+ e x 1 + e−x
f ( x + y ) = f ( x ) + f ( y )⎤
x+y =x+y ⎥ S→3

– 12 –
57. Answer (D)

n(BΔC ) = 1 n(P (BΔC ) = 21 = 2

n(B ∩ C ) = 3 n(P(B ∩ C )) = 23 = 8

[ A ∩ (B ∪ C )] = 2 n(P ( A ∩ (B ∪ C ) = 22 = 4

n [ A − (B − C )] = 4 n(P ( A − (B − C ))) = 24 = 16

58. Answer (4)


Domain is x > 0, x ≠ 1

⎡1 1 ⎤ ⎛⎡1 1 ⎤ ⎞
⎢ 5 ( log5 5 + log5 x ) + 5 ( logx 5 + logx x ) ⎥ ( 5log5 x ) + ⎜ ⎢ 5 ( log5 x − log5 5 ) + 5 (log x 5 − log x x ) ⎥ 5log5 x ⎟ = 2
⎣ ⎦ ⎝⎣ ⎦ ⎠

(1 + log5 x + logx 5 + 1) log5 x + ⎡⎣(log5 x − 1) + (logx 5 − 1) ⎤⎦ (log5 x ) = 2

Put log5 x = t

⎛ 1⎞ ⎛ 1 ⎞
⎜⎝ 2 + t + ⎟⎠ t + ⎜⎝ t + − 2⎟⎠ t = 2
t t

(t + 1)2 + (t − 1)2 = 2

| t + 1| + | t − 1| = 2

It is true for |t| ≤ 1


i.e., |log5x| ≤ 1

1
–1 ≤ log5x ≤ 1 ⇒ ≤x≤5
5

⎡1 ⎤
∴ x ∈ ⎢ , 5⎥
⎣5 ⎦
So, integral solutions are 2, 3, 4, 5 (x ≠ 1)

59. Answer (5)

a = 7C0 + 7C1 = 8

7! 7×6×5
b = 7C3 = = = 35
3!4! 3!

c = 7C7 = 1

b 35
= =5
a−c 8 −1

– 13 –
60. Answer (7)
x2 – y = t 1
y2 – x = t 2
x2 + y2 – [y + x] = t1 + t2
x(x – 1) + y(y – 1) = t1 + t2

( x 2 − y ) − ( y 2 − x ) = t1 − t2

(x 2 − y 2 + x − y = t1 − t2

( x − y )[ x + y + 1] = t1 − t 2

f ( x 2 − y, y 2 − x ) = [( x − y )( x + y + 1)][ x( x − 1) + y ( y − 1)]

f (t1, t2 ) = (t1 − t2 ) ( t1 + t2 )

f (t1, t2 ) = t12 − t22

f (4, 3) = 16 − 9 = 7

– 14 –
Online
06/10/2013 AIATS
P-II

Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456 Fax : 011-47623472

ALL INDIA AAKASH TEST SERIES for IIT-JEE (Advanced)-2015


Test- 1 (Paper-II)
Time : 3 hrs. Max. Marks: 186

Topics covered:

Physics : Units and Measurement, Motion in a Straight Line, Motion in a Plane

Chemistry : Some basic Concepts of Chemistry, Structure of Atom

Mathematics : Sets, Relations and Functions (XI syllabus)

INSTRUCTIONS
Pattern of the questions are as under:

(i) The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has 5 sections.

(ii) Section 1 contains 6 multiple choice questions which have only one correct answer. Each question carries
+2 marks each for correct answer(s). There are no negative marks in this section.

(iii) Section 2 contains 5 multiple choice questions which have one or more answers are correct. Each question
carries +4 marks each for correct answer and –1 mark for each wrong answer.

(iv) Section 3 contains 2 paragraphs. Based upon each paragraph 2 multiple choice questions have to be
answered. Each question has only one correct answer and carries +3 marks for correct answer and –1
mark for wrong answer.

(v) Section 4 contains 2 matching column type questions which have only one correct answer. Each question
carries +3 marks each for correct answer and –1 mark for each wrong answer.

(vi) Section 5 contains 3 integer value correct type questions which have only one correct answer. Each
question carries +4 marks each for correct answer and –1 mark for each wrong answer.

–1–
PART - I : PHYSICS
SECTION - 1
Only One Option Correct Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. A rectangular cookie of the given dimensions, length (l) = 15.00 cm ± 0.05 cm, breath (b) = 5.00 cm ± 0.01
cm and thickness t = 1.00 cm ± 0.01 cm. Twenty cookies are to be packed in a box by placing them along
their thickness. Correct dimensions of the box is
(A) 15.05 × 5.01 × 20.00 cm3 (B) 15.00 × 5.01 × 20.20 cm3
(C) 20.20 cm × 15.00 cm × 5.01 cm (D) 20.20 cm × 15.05 cm × 5.01 cm
2. A particle has constant acceleration α(m/s2) along y-axis. It follows y = αx2. x-component of velocity is

(A) 1 m/s (B) 2 m/s

1
(C) m/s (D) 2 m/s
2
3. A ship S1 is moving eastward with 10 m/s observes another ship S2 which is moving 30° east of north. Ship
S2 is observed moving 30° west of north from S1. Speed of S2 is

(A) 10 3 m/s (B) 10 2 m/s

(C) 10 m/s (D) 20 m/s


4. A particle takes T seconds more and acquires velocity of S m/s less at one place than the other in falling
from rest through the same distance. Accelerations due to gravity are g1 and g2 at the two places. Value of
g1g2 is

S2 S2
(A) (B)
T T2

2S 2 S2
(C) (D)
T2 2T 2

5. A particle starts with speed v on the circular path of radius one meter. It has constant tangential acceleration
v2
of . Centripetal acceleration of the particle is
4R
2 2
⎛ vt ⎞ 2⎛ vt ⎞
(A) ⎜ 1 + ⎟ (B) v ⎜ 1 + ⎟
⎝ 4⎠ ⎝ 4⎠

2 2
⎛ vt ⎞ ⎛ vt ⎞
(C) v ⎜ 1 + ⎟ (D) v ⎜ 1 + ⎟
⎝ 2⎠ ⎝ 4⎠

T
6. A train takes time T second to perform a journey. It travels second with uniform acceleration, then for
n
T 2T
(n − 3) second with uniform speed V and finally for second with constant retardation. Average speed
n n
of the train is

v v
(A) ( 2n − 1) (B) 2 ( n − 1)
2n n
v v
(C) ( 2n − 3 ) (D) ( 2n − 1)
2n 3n

–2–
SECTION - 2
One or More Option Correct Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONE

7. A particle is projected in the vertical plane under gravity. Its horizontal and vertical components are u and v
respectively. If R is the horizontal range and h the greatest height. Evaluate the correct statement

h u 4h v
(A) = (B) =
R v R u

R2g 2uv
(C) h = 2 (D) R =
8u g

8. A particle is projected upward with a velocity u m/s and t second after another particle is projected upward
from the same point with same velocity. If particles meet at same height, evaluate the correct statements

⎛ 2u t ⎞
(A) Time of motion of first particle is ⎜ + ⎟
⎝ 3 2⎠

⎛u t ⎞
(B) Time of motion of first particle is ⎜ + ⎟
⎝g 2⎠

⎛u t ⎞
(C) Time of motion of the second particle is ⎜ − ⎟
⎝ g 2⎠

⎛ 2u t ⎞
(D) Time of motion of the second particle is ⎜ − ⎟
⎝ g 2⎠

9. Two particles are projected simultaneously from the same point with different vertical velocities. Evaluate the
correct statement
(A) Distance between them is increasing at the constant rate when moving upward
(B) Distance between them is increasing at variable rate when moving upward
(C) Distance between them is increasing at constant rate when moving downward
(D) Distance between them is increasing at non-uniform rate when moving downward
10. Which of the following physical quantities are dimensionless?
(A) Solid angle (B) Refractive index
(C) Longitudinal strain (D) Specific gravity

11. α and β (α ≠ β) be the two angles of projection to reach a point at distance R on the horizontal from the
point of projection. v is the speed of projection. If the maximum heights are h1 and h2 respectively then which
is correct relation?

u2 u2
(A) h1 + h2 = (sin2 α + sin2 β ) (B) h1 + h2 = (cos2 α + cos2 β )
2g 2g

u2 u2
(C) h1 + h2 = (D) h1 + h2 =
2g g

–3–
SECTION - 3
Paragraph Type
This section contains 2 paragraphs. Each describing theory, experiment, data etc. Four questions relate to
two paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph for Question Nos. 12 to 13


A particle during its trajectory (vertical X-Y plane) crosses two walls (W1, W2) of same height H at distance Δx1 in time
t and takes 2 2 s to cross another two walls (W3, W4) of the height (H + 10) m separated by Δx2 distance

12. Find the value of t


(A) 3 s (B) 4 s

(C) 3 2 s (D) 4 2 s

Δx1
13. Find
Δx2

(A) 2 2 (B) 2

1 1
(C) (D)
2 2

Paragraph for Question Nos. 14 to 15


X-Y is the horizontal plane. Two poles P1, P2 of 50 m and 25 m height are raised on the x-axis and y-axis at a distance
50 m on both the axes. A rope way trolly move between the top of the poles.
14. Displacement vector of the trolly down the rope is

(A) 50iˆ + 50 jˆ − 25kˆ (B) −50iˆ + 50 jˆ − 25kˆ

(C) −50iˆ − 25 jˆ − 25kˆ (D) 25iˆ + 50 jˆ − 25kˆ

15. Length of the rope between the top of the poles

(A) 60 m (B) 3125 m

1
(C) 75 m (D) 3760 m
2

SECTION - 4
Matching Column Type
This section contains 2 multiple choice questions. Each question has matching Columns. The codes for the Columns
have choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
16. Two particles are projected with same speed follow the trajectories shown as (1), (2) respectively in column-I.
Corresponding statements about time of flight are given in the column-II. Match them correctly
Column-I Column-II

(1) (2)
(P) (1) t1 > t2
x

–4–
y
(1)

(2)
(Q) (2) t1 = t2
x
y

(2)

(R) (1) (3) t1 = 2t2


x

(1)
(2)
(S) (4) t2 > t1
x

Codes :
P Q R S
(A) 2 1 4 3
(B) 4 3 1 2
(C) 1 3 4 2
(D) 2 4 1 3

37°

17.
37°

A canon (Gun) moving with 24 m/s uniformly on the inclined plane fires bullet with the muzzle speed of
120 m/s from the barrel inclined at 37° from the inclined plane. Quantities corresponding to the statements
in column-I are given in column-II in SI units. Match them correctly
Column-I Column-II
(P) The distance where bullet strikes (1) 756
(Q) The farthest distance of bullet from (2) 432
the inclined plane
(R) Distance moved by the cannon when (3) 1188
bullet strikes the incline
(S) How far the bullets are striking (4) 324
from cannon
Codes :
P Q R S
(A) 3 4 2 1
(B) 2 4 3 1
(C) 1 4 2 3
(D) 2 4 1 3

–5–
SECTION - 5
Integer Value Correct Type
This section contains 3 questions. The answer to each of the question is a single digit integer, ranging from 0 to 9. The
appropriate bubbles corresponding to the respective question numbers in the ORS have to be darkened. For example,
if the correct answers to question numbers X, Y and Z (say) are 6, 0 and 9, respectively, then the correct darkening of
bubbles will look like the following :

X 0 1 2 3 4 5 6 7 8 9
Y 0 1 2 3 4 5 6 7 8 9
Z 0 1 2 3 4 5 6 7 8 9

18. An aeroplane has to go from point O to P 540 × v 3m away. Wind is blowing north ward with the same
speed v(m/s) as the aeroplane maintain with respect to wind. Time taken by the plane in minutes is

North
P

30°

O East

19. Intensity, is the energy per unit time per unit area and speed of light is (v). a, b and c are the dimensions of
I |a|+|b|
. Find
v |c |

20. A particle is projected with 10 m/s at an angle 30° from vertical. It attains maximum height h. Find the average
h
velocity between the top of the walls of height .
2

PART - II : CHEMISTRY
SECTION - 1
Only One Option Correct Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

21. 50 ml of an aqueous solution of glucose contains 6.02 × 1022 molecules. The concentration of solution is
(A) 2 M (B) 0.2 M
(C) 20 M (D) 0.02 M
22. The molality of 15% (mass/vol) solution of H2SO4 of density 1.1 g/ml is approximately
(A) 2.6 (B) 3.6
(C) 1.6 (D) 4.6
23. 280 ml of XM solution and 500 ml of YM solution of a solute are mixed and diluted to 2 litre to produce a
solution having concentration 1.6 M. If X : Y = 5 : 4, then X + Y is
(A) 8.86 (B) 7.86
(C) 6.86 (D) 5.86

–6–
24. In ψ321 the sum of 'orbital angular momentum', radial nodes and angular node is

3h + 2π 6h + 4π
(A) (B)
2 2π

6h + 2 2π
(C) (D)
2π 6h + 2

25. The unit of wave function ψ of a hydrogen atom is

(A) m3 (B) m–3


(C) litre3 (D) Dimensionless

26. Which has the highest number of unpaired electrons?

(A) Mn (B) Mn+5


(C) Mn+3 (D) Mn+4

SECTION - 2
One or More Option Correct Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONE

27. 1 g atom of nitrogen(N) represents


(A) 6.023 × 1023 molecules
(B) 14 g of nitrogen
(C) 11.2 L of nitrogen gas at 1 atm and 273 K
(D) 1 g of nitrogen

28. Three isotopes of an element have mass numbers, M, (M + 1) and (M + 2). If the mean mass number is
(M + 0.5), then which of the following ratio(s) may be accepted for M, (M + 1) and (M + 2) in the order

(A) 1 : 1 : 1 (B) 4 : 1 : 1
(C) 9 : 6 : 1 (D) 2 : 1 : 1
29. Which of the following contains Avogardro's number of atoms?
(A) 6.00 g of H2O (B) 4.00 g of CH4
(C) 7.5 g of C6H12O6 (D) 4.25 g of NH3

30. Which of the following were not taken into account in Bohr's model of an atom?

(A) Planck's quantum theory


(B) Stability of an atom
(C) Dual nature of electrons as wave and particle
(D) Results of Zeeman and Stark effects

31. The spin only magnetic moment of V(Z = 23), Cr(Z = 24) and Mn(Z = 25) are x, y and z respectively. Which
of the following is/are correct relationship?

(A) x > y (B) x > z


(C) y > z (D) x < z

–7–
SECTION - 3
Paragraph Type
This section contains 2 paragraphs. Each describing theory, experiment, data etc. Four questions relate to
two paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph for Question Nos. 32 to 33

A cylinder contains 0.32 g of oxygen. The same volume of an unknown gas X under similar conditions of temperature
and pressure weighs 0.26 g. The gas X is known to contain only hydrogen and carbon atoms in the ratio of 1 : 1.
32. The approximate molecular weight of the gas is
(A) 52 (B) 39
(C) 26 (D) 73
33. The molecular formula of the compound X is
(A) CH (B) C2H2
(C) C3H3 (D) C4H4

Paragraph for Question Nos. 34 to 35

According to Bohr's theory the energy of an electron is


− z 2 e4me kz 2
En = or En = − 2
8ε 0 h n
2 2 2
n
where K = 2.179 × 10–18 J
34. The amount of energy required for the transition of electron from n = 1 to n = ∞ of He+ ion is
(A) 2427 kJ/mol (B) 3427 kJ/mol
(C) 4427 kJ/mol (D) 5248 kJ/mol
35. What minimum amount of energy is required to bring an electron from ground state of Be+3 to infinity?
(A) 3.9 × 10–7 J (B) 3.49 × 10–17 J
(C) 3.9 × 10–27 J (D) 3.49 × 10–10 J

SECTION - 4
Matching Column Type
This section contains 2 multiple choice questions. Each question has matching Columns. The codes for the Columns
have choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

36. Match the reaction in (Column-I) with the maximum yield of the product in (Column-II)

Column I Column II

(P) 2H2 + O2 → 2H2 O (1) 1.028 g


1g 1g

(Q) 3H2 + N2 → 2NH3 (2) 1.333 g


1g 1g

(R) H2 + Cl2 → 2HCl (3) 1.125 g


1g 1g

(S) 2H2 + C → CH4 (4) 1.214 g


1g 1g

–8–
Codes :
P Q R S
(A) 4 3 1 2
(B) 3 4 1 2
(C) 3 4 2 1
(D) 3 1 4 2
37. Match the column-I with column-II
Column I Column II
(Orbital) (Probability density (R) vs Distance (r) graph)

R
(P) 3s (1)

R
(Q) 4s (2)

R
(R) 2p (3)

(S) 3p (4)

Codes :
P Q R S
(A) 4 1 2 3
(B) 1 4 3 2
(C) 1 4 2 3
(D) 1 2 4 3

–9–
SECTION - 5
Integer Value Correct Type
This section contains 3 questions. The answer to each of the question is a single digit integer, ranging from 0 to 9. The
appropriate bubbles corresponding to the respective question numbers in the ORS have to be darkened. For example,
if the correct answers to question numbers X, Y and Z (say) are 6, 0 and 9, respectively, then the correct darkening of
bubbles will look like the following :

X 0 1 2 3 4 5 6 7 8 9
Y 0 1 2 3 4 5 6 7 8 9
Z 0 1 2 3 4 5 6 7 8 9

38. The ratio of the wave number for the highest energy transition of electron in Lyman and Balmer series of
hydrogen atom is

39. The velocity of electron related with n as v ∝ n–x, the value of x is

th
⎛ 1⎞
40. In U unit the value of ⎜ ⎟ mass of C – 12 is
⎝ 12 ⎠

PART - III : MATHEMATICS


SECTION - 1
Only One Option Correct Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

⎛ 1 ⎞ 2 1
41. If f ⎜ 3 x + 3 ⎟ = 2 x + 3 x + + 3 , ( x ≠ 0) then f(1) is equal to
⎝ x⎠ x x

(A) –3 (B) 3
(C) 2 (D) 6

42. Number of integral values of x satisfying the equation log


3 (
( x − 4) + log3 (10 − x ) − log9 x 3 + 3 x 2 − 4 )
+ log3 ( )
x − 1 < 0 is/are

(A) 1 (B) 2
(C) 3 (D) 5
43. If A and B are two subsets of the universal set U such that n((A – B)') = 16, n(A ∪ B) = 12, n(U) = 20,
n(A) = 10 then n (AΔB) is equal to
(A) 6 (B) 14
(C) 8 (D) 10

2 2 2
⎡ ⎛ 4 ⎞⎤ ⎡ ⎛ 4 ⎞⎤ ⎡ ⎛ x ⎞⎤
44. The number of values of x satisfying the equation ⎢log ⎜ 1 + ⎟ ⎥ + ⎢log ⎜ 1 − ⎟ ⎥ = 2 ⎢log ⎜ 1 − ⎟ is/are
⎣ ⎝ x ⎠⎦ ⎣ ⎝ x + 4 ⎠⎦ ⎣ ⎝ x + 1 ⎠ ⎥⎦

(A) 0 (B) 1
(C) 2 (D) Infinitely many

– 10 –
45. The remainder when the polynomial (x50 – x49) is divided by x2 – 1 is
(A) –x + 1 (B) (250 – 249)x + 1
(C) 250x + 1 (D) x + 1
46. Let A = {1, 2, 3, a, b, c, d}
Statement-1: Total number of proper subsets of A are 26.
Statement-2: Number of subsets of A contains either three or four elements are 70.
Statement-3: Number of subsets of A containing at most 5 elements are 120.
Identify the correct combination of True (T) and False (F) of the given three statements.
(A) T T F (B) F T F
(C) F T T (D) F F T

SECTION - 2
One or More Option Correct Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONE

⎛ 1 ⎞ x12 − 1
47. If f ⎜ x 2 − 2 ⎟ = 2 8 , then which of the following is true?
⎝ x ⎠ x ( x + 1)
4 4
(A) f (2) = (B) f (1) =
3 3
(C) f(–1) = f(1) (D) f(2) + f(–2) = 0

48. Let A = {x : x is divisible by either 3 or 5, 1 ≤ x ≤ 150, x ∈ N}

B = {x : x contains at least one odd digit, 1≤ x ≤ 100, x ∈ N}

Which of the following are correct?

(A) n(A) = 80 (B) n(A) = 70


(C) n(B) = 76 (D) n(B) = 75

⎡ 1⎤ ⎡ 2⎤ ⎡ 3⎤
49. a = [3] + ⎢3 + ⎥ + ⎢3 + ⎥ + ⎢3 + ⎥ + ..... + [6]
⎣ 5⎦ ⎣ 5⎦ ⎣ 5⎦

b = number of integral solutions satisfying the equation 0 ≤ [| x + 3 | −2] ≤ 3 .

Where [⋅] represents greatest integer function, then which of the following is true?
(A) b is divisible by 4 (B) a = 8b + 2
(C) a is divisible by 3 (D) a = 8b
50. For three sets, A, B, C ⊆ U, following conditions are known

B⊆ A C' ∪ A = U

n(C' ∪ A) = 7 n(B Δ C) = 5

n(A – (B – C)) = 6 n(A – (C – B)) = 9

n[(B ∪ C)'] = 5, then


(A) n(A) = 11 (B) n(B) = 6
(C) n(C) = 3 (D) n(∪) = 12

– 11 –
3
51. If f(x) = , then which of the following statement is true?
32 x + 3

(A) f(x) + f(–x) = 1, ∀x ∈ R (B) f(x) + f(1 – x) = 1, ∀x ∈ R


2013
⎛ r ⎞ 2013
⎛ r ⎞ 4025
(C) ∑ f ⎜⎝ 2013 ⎟⎠ = 1006 (D) ∑ f ⎜⎝ 2013 ⎟⎠ = 4
r =1 r =1

SECTION - 3
Paragraph Type
This section contains 2 paragraphs. Each describing theory, experiment, data etc. Four questions relate to
two paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph for Question Nos. 52 to 53


|x| represent cardinality of the set X i.e., the number of element present in set X.
There are three subsets A, B, C of universal set U. Following cardinalities are known
|C ∩ B'| = 0 |(B – C) ∩ A| = 0
|A Δ B| = 6 |(A ∩ C)'| = 10
|(A ∩ C)Δ (A ∪ C)'| = 7 |A – (B – C)| = 4
|C' ∩ B| = 2 |(B ∪ C)'| = 7
Using these answer the following questions.
52. Cardinality of set A is
(A) 4 (B) 5
(C) 6 (D) 7
53. Cardinality of set C is
(A) 4 (B) 5
(C) 6 (D) 7

Paragraph for Question Nos. 54 to 55


If f(–x) = f(x) ∀x ∈ R, then f(x) is said to be even function. If f(–x) = –f(x) ∀x ∈ R then f(x) is said to be odd function. If
function does not hold only of the two above properties it is known as neither even nor odd function. Based on these
classifications, answer the following questions.

54. (
f ( x ) = log10 sin3 x + sin6 x + 1 is )
(A) Even
(B) Odd
(C) Neither even nor odd
(D) Domain of f(x) is R+
55. f(x) = [g(x) + g(–x)][g(x) – g(–x)] is
(A) Even only and only if g(x) is even
(B) Odd only and only if g(x) is even
(C) Even
(D) Odd

– 12 –
SECTION - 4
Matching Column Type
This section contains 2 multiple choice questions. Each question has matching Columns. The codes for the Columns
have choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

56. Match the functions satisfying the following properties


Column-I Column-II
(P) f(x + y) = f(x)f(y) ∀x, y ∈ R (1) f(x) = loge x
(Q) f(xy) = f(x) + f(y), ∀xy ∈ R+ (2) f(x) = ex
(R) f(x) + f(–x) = 1, ∀x, ∈ R (3) f(x) = x
x
(S) f(x + y) = f(x) + f(y) ∀x, y ∈ R (4) f ( x ) = e
1+ ex
Codes :
P Q R S
(A) 2 1 4 3
(B) 1 2 3 4
(C) 3 4 1 2
(D) 4 3 2 1
57. Match A = {a, e, i, o, u}, B = {a, e, 1, 2}, C = {1, 2, a}. P(X) means power set of set X
Column-I Column-II
(P) n[P(B Δ C)] (1) 2
(Q) n[P(B ∩ C)] (2) 4
(R) n[P(A ∩ (B ∪ C))] (3) 8
(S) n[P(A –(B – C))] (4) 16
Codes :
P Q R S
(A) 2 1 4 3
(B) 1 2 3 4
(C) 2 3 4 1
(D) 1 3 2 4

SECTION - 5
Integer Value Correct Type
This section contains 3 questions. The answer to each of the question is a single digit integer, ranging from 0 to 9. The
appropriate bubbles corresponding to the respective question numbers in the ORS have to be darkened. For example,
if the correct answers to question numbers X, Y and Z (say) are 6, 0 and 9, respectively, then the correct darkening of
bubbles will look like the following :

X 0 1 2 3 4 5 6 7 8 9
Y 0 1 2 3 4 5 6 7 8 9
Z 0 1 2 3 4 5 6 7 8 9

58. Integral values of x satisfying the equation

⎛ ⎛ 5⎞ ⎞
(log5 5 5 x + logx 5
5 x )(log5 x 5 ) +

⎛ x⎞
5 x ⎠
( 5
)
⎜ log5 5 ⎜⎝ ⎟⎠ + logx 5 ⎜⎝ ⎟⎠ ⎟ log5 x = 2 is/are______.

– 13 –
59. A = {1, 2, 3, 4, a, b, c}

Let a be the number of subsets of A containing at most 1 elements

Let b be the number of subsets of A containing exactly 3 elements.

b
Let c be the number of subsets of A containing exactly 7 elements, then is equal to______.
a−c

60. If f(x2 – y, y2 – x) = [(x – y)(x + y + 1)][x (x – 1) + y(y – 1)] ∀ x, y ∈ R, then f(4, 3) is equal to_______.

– 14 –

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