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2. 4, 5. 1 9. 12. 13. The following group does not contain a dative bond (a) -NO, (b) -N,CI (©) -NC (€) all of these Which of the following pairs will form the most stable ionic bond ? (a) Naand Ct (b) Mgand F (©) Liand F (@) Naand F Which of the following conceivable structures for CCL, will havea zero dipole moment ? (@) Imegular tetrahedron (©) Square planar (©) Square pyramid (carbon at apex) (@ None of these Among the following which compound will show the highest Iattice energy ? (@) KF (b) NaF (©) CsF (4) RUF ‘The compound which contains both ionic and covalent bond : @ KQ =) KCN @CH, @H, Which one ofthe following contains co-ordinate covalent and? @ 1,0) HC © BaCl, @) Noll The strength of bonds formed by s-s and p-p, s-p overlap, in theorder of () sp>ss>p-p () p-p>s-s>sp (©) ss>pp>sp (@) ss>s-p>p-p The types of bonus present in CuSO, 51,0 are only (2) electrovatent, covalent and co-ordinate covalent bonds (&) clecirovalent, covalent and hydrogen bond (©) clecirovalent and covalent bonds (@ clectrovalent and co-ordinate covalent bonds, ‘Which ofthe following combination will form an electrovalent, bond ? (@) PandCl (b) NH, and BF, (©) HandCa (@ Hands. Which one of the following will dissolve in water most, readily? @ | (a) Ply (b) BaCO, (©) KF ‘When a metal atom combines with non-metal atom, the ‘non-metal atom will (a) lose electrons and decrease in size (b) lose electrons and increase in size (© gain clectrons and decrease in size (@)_gain electrons and increase in size Indicate the nature of bonding in CCl, and Call, (@) Covalentin CCl, and eleetrovalent in Call, (6) Electrovalentin bot CC, and Cally (©) Covalent in both CCl, and Ca, (d) Electrovalent in CCI, and covalent in CaH. What is the correct mode of hybridisation of the central atom in the following compounds? NO> SF, PES @ sp spt sp ©) sp? spd spe © sp sp? (d) sp’ sp? sp'd? 15, 16, 17, 18, 19. 20, 2. 22, 23. 24, 25. 26. In PO,* ion, the formal charge on each oxygen atom and P_O bond order respectively are (a) -0.75,06 (b) -0.75, 1.0 (©) -0.75, 1.25 (@) -3,125 Which of the following hydrogen bonds are strongest in vapour phase? (a) HE--HF (b) HF—HCI (6) HC-HCI (@) HEH As the scharacter of hybridised orbital inereases, the bond angle (a) increase (b) decrease (©) becomes zero (¢) does not change Among the following the electron deficient compound is @ BC, — &) CCl, © PC (A) BeCl, How many sigma bonds are there in PO). f@) 4 (b) 8 © 2 @ 16 ‘The number of possible resonance structures for CO} is @) 2 (b) 3 (©) 6 @9 The strongest hydrogen bond is : (c) F-H. Which of the following has the highest dipole moment? CH; H i > N lot fa) c=0 () C=C a 1 | cH; y oH cl CH; © § = f (d) ¢ “¢ CH; H CH; Cl In the cyanide ion, the formal negative chargeis on @c () N (© BothCandN (@) Resonate between CandN Ofthe following hydrides which onc has the lowest boiling point ? (a) AsHs (6) SbHy (©) PH; — (@) NH Resonance structures can be written for (a) 05 () NH) CH, @) HO Which one of the following is the correct order of interactions? (a) covalent < hydrogen bonding < van der Waals OH Onn’ (a) dipole moment (b) dipole-dipole interaction (6) H-bonding (@) lattice structure The bond length between C-C bond in sp? hybridised molecule is : f@) 12A (b) 139A (© 133A (@) 158A Which one of the following pairs of molecules will have permanent dipole moments for both members? (a) NO, and CO, (b) NO, and O, (©) SiFyand CO; (@) SiFyand NO, The corrcet sequence of inereasing covalent character is represented by (a) LiCl

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