Ejercicios de Sistemas Binarios A Punto de Burbuja.

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Acetonitrilo(1)/Nitrometano(2).

Ctes de Antoine.
A B C
Acetonitrilo. 14.2724 2,945.47 224
Nitrometano. 14.2043 2,972.64 209
T 75 °C
P 70 kPa
P1 sat 83.2068575 kPa T1 sat 69.8445717
P2 sat 41.9827049 kPa T2 sat 89.5835974
x1 P(kPa) y1 T(°C) P1 sat(kPa)
0 41.9827049 0 69.8445717 70
0.1 46.1051202 0.18047205 72 75.30058
0.2 50.2275354 0.33131969 74 80.5012316
0.3 54.3499507 0.4592839 76 85.9844673
0.4 58.472366 0.56920466 78 91.761065
0.5 62.5947812 0.66464692 80 97.8420014
0.6 66.7171965 0.74829455 82 104.238448
0.7 70.8396117 0.82220666 84 110.961769
0.8 74.962027 0.88798941 86 118.023513
0.9 79.0844422 0.94691408 89.5835974 131.560406
1 83.2068575 1

Ley de Raoult.
90
1.2
80
1
70
0.8
60

0.6 50

0.4 40

30
0.2
20
0
0 0.2 0.4 0.6 0.8 1 1.2 10

0
0 0.2 0.4 0

Grafica de
92

87

82
Grafica de
92

87

82

77

72

67
0 0.2 0.4 0.6
°C
°C
P2 sat(kPa) x1 y1
34.5959784 1 1
37.5438643 0.85961226 0.92470431
40.4582967 0.7377507 0.84842629
43.5532449 0.62328525 0.76561215
46.8368056 0.51560548 0.67589297
50.3172743 0.41415757 0.5788858
54.0031441 0.31843852 0.47419339
57.9031038 0.22799097 0.36140401
62.0260363 0.14239862 0.24009123
70 0 0

0.2 0.4 0.6 0.8 1 1.2

Grafica del ej. [b)].


Grafica del ej. [b)].

0.2 0.4 0.6 0.8 1 1.2

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