B V R AJ U IN S T IT U T E O F T E C H N O L O G Y , N AR S A P U R (UGC - AUTONOMOUS) I M.TECH II Semester Regular/Supplementary Examinations, Sep/Oct 2020 ADVANCED REACTION ENGINEERING (Che mical E ng ineer ing) Time: 2 Hours Max Marks: 70 Note: Answer any Five Questions (5x14 = 70 Marks) Bloom Level CO 1 Derive the performance equation of ideal plug flow reactor and L2 1 represent it graphically. 2 Substance A in liquid phase produces R and S by A→ R, rR=k1 CA A→ S, rS=k2 CA. Feed (CAo=1.0, CRo=CSo=0) enters 2 CSTRS in series (τ1=2 L4 1 min,τ2=5 min). Knowing the compositions in the first reactor CA1=0.4, CR1=0.4,CS1=0.2.Find the composition leaving the second reactor, using fractional yield concept. 3 An irreversible isomerization reaction is carried out in liquid phase in mixed reactor. A→R, first order reaction. Rate constant at 165oC=0.7 hr-1. Activation energy =120000 J/mol. heat of reaction=-350kJ/kg. Heat capacity of reactants and L4 2 products=1.95kJ/kg.K. Volumetric flow rate = 0.33 m3/hr. Feed temperature=20oC.Conversion expected=95%. Calculate the reactor size and temperature of the reaction mixture is operated adiabatically. 4 Derive energy balance equation for adiabatic operation and L3 2 graphically represent it. 5 Obtain an expression for the global rate of reaction and conversion Vs. time A(g) + bB(s) E (g) + F (s) considering a L3 3 spherical pellet and SCM when chemical reaction controlling in case of gas-solid non catalytic reaction. 6 A sample of tracer was injected as pulse into a vessel to be used as reactor and the effluent concentration is measured as a function of time. The data collected in given below: CA, 0 1 5 8 10 8 6 4 3 2.2 1.5 0.6 0 g/m3 4 L4 t, 0 1 2 3 4 5 6 7 8 9 10 12 14 min Construct C and E curves. Find the fraction of material leaving the reactor that has spent 3 and 6 min. 7 Discuss about the various aspects of population balance of gas- L2 5 solid reactions in Rotary kiln. 8 Substrate A and enzyme E flow through a mixed flow reactor (V = 6 liter). From the entering and leaving concentrations and flow rate find a rate equation to represent the action of enzyme on substrate. CBO CAO CA V, LPH L4 6 mol/liter mol/liter mol/liter 0.02 0.2 0.04 3 0.01 0.3 0.15 4 0.001 0.69 0.6 1.2