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1. What do you mean by covalent bonding? 17. Draw the possible isomers ofthe compound with
molecular formula C3HgO and also give their
covalent bond using the
2. Explain the nature of the (NCERT) electron dot structures. (NCERT Exemplar)
bond formation in CH,Cl.
What would be the electron
dot structure of carbon 18. What by functional group in carbon
is meant
3. Write in tabular form the structural
dioxide which has molecular
formula CO,? (NCERT) compounds?
calcium chloride with the
formula and the functional group present in the
4. () Explain the formation of following compounds:
help of electron dot structure. ) Ethanol (i) Ethanoic acid
(Atomic numbers of Ca 20; Cl =17)
=
examples of four
(i) H-C-C-OH
i) H-C
f
OH H
different functional groups. H
H
l Science x
CBSE
Tem
09
H HH
any reterence to space, the phenomenon is called
H-C-CHO iv) H-C-C-Br structural isomerism. In other words, structural
isomers are compounds that have the same molecular
H formula but different structural formulas, i.e. they are
HH different in the order in which different atoms are
HH O H
linked or they have different connectivities depending
structural
formula
of pentane C,H,, is
10. (c) The H H HH
H
Objective Questions
in the
form ofcarbon
in H--C C-C-H
the
atmosphere
Carbon
also occurs
exists in also
Carbon
(only 0.03%). c a r b o n a t e s . It H H H H
1. c) in air like
(CO,) minerals
dioxide gas
the form of c o m p o u n d s , wood bonds.
cerust in organic 16 covalent
the earth's form fossil fuels, It contains
it resembles with thesgeter
in the of alkane
because
occurs
to is an
is benzene wtich
and wool,
etc.
valence electrons.
Thus, 11. (a) CH, i.e. C,H2n+2: GgHg
formula of alkane, double bonds in alternate carbon
cotton
six (6) another o x y g e n
atom has bond with
having of alkyne and
Oxygen double
2. (b) forms
octet, it
complete its
cyclic ring the general formula
resembles with
atom to get O
molecule as
CH because
number H-atoms are
of douh
is an alkene
C.H atoms.
carbon
or O=0 that of
carbon atoms
and 'yne' showsDreve
2
has the structural formula
Eth' represents
12. (a) ethyne
g
Shared electrons
of a triple bond. Thus, known as acetylene.
(covalent bond H-C=C-H Itis also have double o r triple bnda
formation) hydrocarbons
have double carbon-carb
Unsaturated
number 7) is . 13. (c) Both (ii) and (iv)
Electronicconfiguration
of N (atomic 2 5 their s t r u c t u r e .
structures.
3. (d) bonds in their alternate single and doube
electrons to complete its Benzene
molecule contains
three more 14. (c)
Therefore, it needs electrons to form
a
layers of
carbon
A graphite crystal consists of various atoms
to three otntom
in which each carbon atom is joined
The various layers carares
6. (b)8 covalent bonds are formed in S molecule. of forc
79.
of the sane
Catenation is the bonding of atoms
Crown shaped (Ss) molecule forms
7. (d) Graphite can not be used for making insulated plates, as Catenation occurs more
to
other C-atoms
it is a good conductor of electricity. strong covalent bond with
8. (d) C Si and Gebelongs to group 14 and their valency is 4. and structures. the
But oxygen has electronic configuration 2, 6. So, its valency Rare true and R is the
correct e S o
or HH Atomic number of O = 8
H H
Electronic configuration =
2'
Single bond showing H, molecule
To attain the stable electronie
2 c) Each
Each atom is covalently bonded
to four other atoms
4
configuration. carbon
electrons, while oxygen needs 2 electrons. needs
atoms. Thus,
bonded to four more So, in CO, each
which in turn, are
similarto that of oxygen atom share two electrons from carbou.
agiant molecule and has a
structure
consists and carbon both Thus, oxygen
lanond Substance X is not a compound as it
complete their octet.
ot only one type of atons Before
held After
carbon atoms are combination
In the structure of diamond, combination Shared elecurons
a covalent bonds a s this is a rigid
ether by single cach 0:Cö:
network structure because
uree-dinensional
2 these
compoundsis
C,H2n+2*
where, n = number of carbon atoms in one molecu
ofa
The
electron dot structure and structural formula
is as follows: hydrocarbon.
of CO2 mongst, the given compounds, only C,Hho and d
qo
to the formula of C,Ie 2.Therefore,
belongs
CH4 are saturated hydrocarbons.
or O=C=0 13. Ceneral formula of cycloalkane - C,}ln
In cyclopentane, n =5
Carbon dioxide (CO) '. Formula of cyclopentane, C1, . so
CBSETem|Science
X 13
Electron dot structure of cyclopentane
The structures of possible isomers of butane (C,H! are
HH HH HH H
H
#- -f-f-H H--¢-C-H
H H H H
Or H
H H H
n-butane H-C-H
()
H H
H Iso-butane
H
(I1)
14 ) Carbon is a versatile element because of its The first three members of alkane series are:
properties.
It shows the property of catenation due to which it ) CH, (methane)
forms a large number of compounds. Carbon is (i) CH, (ethane)
tetravalent. Due to this, it forms covalent compounds (ii) C,Hs (propane)
only. In the above members of alkane series, it is not possible to
() Saturated hydrocarbons contain carbon-carbon single have different arrangements of carbon atoms, because
bonds. e.g. Methane (CH,), ethane (C,H,). Unsaturated branching is not possible from either first or last carbon.
hydrocarbons contain atleast one carbon-carbon double Thus, we cannot have isomers of first three members of
or triple bond. e.g. Propene
(CH,), butyne (C,H) alkane series.
i) Functional group is an atom or group of atoms joined in 17. There are four isomers possible for the molecular formula
a specific manner which is responsible for the CgHO. These are as follows:
characteristies chemical properties of the organic H H HH
compounds. ) CH,CHCHO or CH,CH,-¢»H:C:C:C::0:
Examples are alcohols (-OH), aldehyde group
(-CHO) carboxylie group(-COOH), ketone (-cO) H
etc. H
corTesponding alcohols. By doing so, both the atoms of oxygen get 8 electrons
outermost shell. Thus, a double bond is formed in the
The physical properties ofthe members change gradually, between
oxygen atoms which consists of four electrons.
i.e. show gradation in properties as the number of carbon
atom per molecule increased. Before After
combination combination
20.
Ahomologous series the
is family of compounds
organic
having the same functional group, similar chemical
Shared electrons
properties but the successive (adjacent) members of the
series are differ by a CH2 unit or 14 mass units.
Consecutive members of the homologous series of alcohols
are
(3)- -)9)
Oxygen atoms Oxygen molecule
or O=0
or difterent other
atoms, to form an eight atom molecule.
i.e. it forms covalent
compounds. 24. Covalent compounds are those compounds which are lo
med
HH functional group
CH3
contains halo (bromo) Iso-butane
nis compound
as-Br.
CBSE Ternm I Sclente
property
of carbon, it isomerism
catenation different sizes. carbon-1. 2 and 3
i ) Due to and rings of
branched chains
straight or C(3 artm atm
three structural isomers i.c.
(ii) Pentane (C,H12) has
C H - C H - C H - C H - C H ,
n-pentane Se
CH-CH-CH,-CH C (4cautnnatm
CH
Isv-pentane Y
Isoners
CH3 that bekngs to same
29. (i) Pand Tare the compounds are alkv
Both these conmponds
CH-C-CH, homologous series. molocular fomala
tunit in thein
and differ by --CH, Ollwluh
CH (R) is
cyclic structure.
H H
H H
H
H H
alkane series having general
formula of C,H
H HH is unsatrated
H H H i.e.
(v) Compound (U), H
H
HH contain clouble
bond. ie
hydrocarbon becuase it
CH12 CgH belongs to alkene.
Cyclohexane) (Benzene)