11/06/2023, 05:18 Flexible Boron-Doped Laser-Induced Graphene Microsupercapacitors - PubMed

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ACS Nano. 2015 Jun 23;9(6):5868-75. doi: 10.1021/acsnano.5b00436. Epub 2015 May 19.
Flexible Boron-Doped Laser-Induced Graphene
Microsupercapacitors
Zhiwei Peng, Ruquan Ye, Jason A Mann, Dante Zakhidov, Yilun Li, Preston R Smalley 1 , Jian Lin, 
James M Tour
Affiliations
PMID: 25978090 DOI: 10.1021/acsnano.5b00436
Abstract
Heteroatom-doped graphene materials have been intensely studied as active electrodes in energy
storage devices. Here, we demonstrate that boron-doped porous graphene can be prepared in
ambient air using a facile laser induction process from boric acid containing polyimide sheets. At
the same time, active electrodes can be patterned for flexible microsupercapacitors. As a result of
boron doping, the highest areal capacitance of as-prepared devices reaches 16.5 mF/cm(2), 3
times higher than nondoped devices, with concomitant energy density increases of 5-10 times at
various power densities. The superb cyclability and mechanical flexibility of the device are well-
maintained, showing great potential for future microelectronics made from this boron-doped laser-
induced graphene material.
Keywords: boron-doped; energy storage; flexible; graphene; laser induction; microsupercapacitor;
porous graphene.
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https://pubmed.ncbi.nlm.nih.gov/25978090/ 1/1