SULIT ‘SC12023/A181/0, USIM FINAL EXAMINATION SEMESTER I, ACADEMIC SESSION 2018/2019 DATE : JANUARY 2019, DURATION : 2 HOURS 30 MINUTES $C12023 INORGANIC CHEMISTRY (KIMIA TAK ORGANIK) INSTRUCTIONS TO CANDIDATES: 1, This paper contains one (1) section, 2, Answer all questions in the answer booklet provided. 3. All answers must be written in English. 4, All answers must be clearly writen and readable. 5. Candidates are not allowed to take the question papers out of the examination hall. 6. Please complete your particulars in Borang H. DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE INSTRUCTED TO DO SO This question paper has six (6) printed pages excluding this cover page e- sot @ = [sels HAKCIPTA TERPELIHARA USIM.SULIT SCI2023/A181/A [60 MARKS] ANSWER ALL QUESTIONS IN THE ANSWER BOOKLET PROVIDED. 1, Based on the VSEPR theory determine the structure of XeF. (10 Marks) 2. The complex [Cr(dipy)s}**, where dipy = 2,2-dipyridyl, is known to possess a distorted octahedral structure and magnetic moment of approximately 5 BM. a) With the aid of the ligand field theory, show the electron distribution of Cr?’ in this complex. (9 Marks) From your answer in 2(a), why the magnetic moment value of complex above is approximately 5 BM. (1 Mark) [Total: 10 Marks] 3. Based on the NHa[Cr(NHs)2(NCS).] complex, determine: a) b) coordination number. (1 Mark) chromium complex charge. (4 Marks) metal oxidation state. (3 Marks) [Total: 8 Marks] HAKCIPTA TERPELIHARA USIM 1SULIT SC12023/A181/A, 4. Compare the definitions of low-spin (L.S.) and high-spin (H.S.) terms. (4 Marks) Figure 1 shows the first ionization energy versus period graph. Relate: Period 2 Period 3 Period 2500 4 i 2000 1500 1000 500 First ionization energy (ki/mol) ° 10 20 30 40 Atomic number Figure 1 a) the trends within elements in each period. (4 Marks) b) the trends between period one (1) to three (3). (2 Marks) [Total: 6 Marks] 6. Draw Lewis-electron-dot structure of SPF. (8 Marks) HAKCIPTA TERPELIHARA USIM 2SULIT ‘SCI2023/A181/4 7. Figure 2 shows a molecular structure of chromium(|lI) complex. b) Figure 2 What is the type of ligand bonded to Cr(lll) centre? (1 Mark) Define your answer in 7(a). (2 Marks) State how the ligands bonded to Cri) centre. (1 Mark) Provide ONE (1) suggestion on how to balance the molecule charge. (2 Marks) [Total: 6 Marks] HAKCIPTA TERPELIHARA USIM 3SULIT SCI2023/A181/A 8. Figure 3 shows bond length values. Relate: Single Bond Lengths 1A 4A 5A GA Ss a Bb oT H 7 110-9884 we 1272161 c 154147143 81176 19120 N 40 136 1% 169 18403 0 132 170 165180199 F 168168178197 Si 21 216 23180 P 24 209 224243 5 20820321827 Figure 3 a) bond length of C-H and C-F. (3 Marks) b) bond length of C-H and C-L (3 Marks) ©) bond strength of C-H and C-I (2 Marks) [Total: 8 Marks] END OF QUESTION HAKCIPTA TERPELIHARA USIM 4SULIT SCI2023/A181/A APPENDIX Zz Symbol 1 H 2 He 3 Li 4 Be 5 B 6 c t N 8 ° 9 F 10 Ne 11 Na 12 Mg 13, Al 14 Si 15, P 16 OS 17 cl 18 Ar 20 Ca 24 Cr 25° Mn 27 Co 28 Ni 29° Gu 35 Br 36 Kr 47 Ag 50 Sn 53 1 54 Xe 7% Pt 79° Au 80 Hg HAKCIPTA TERPELIHARA USIM 5Dicatak oleh Unit Peperiksaan dan Pengijazahan Bahagian Pengurusan Akademik Universiti Sains Istam Malaysia HAKCIPTA TERPELIHARA USIM @