(Oc) Assignment

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atud Date

Poge

tWTIte any one Synthetic evidence foa The clerivcition


o Beniene Stzuetuse Jdp haiw
His tosy, Angalyt ital Synthetie and othed|
evidenceinsderiVatiom of Stuctore of benzene
AHist03y of Benzene sola ted In 1815 by
Mithaelfasadayh o eletemine d C:Hatio to
be11. S ynthe sined tn1134 byEihasd Mitsch
elith dho detemined mole colas fodmula CsH

2 Accodcding to the Hotktt's sule, ho Phenanthgene 1savonatic


-Huckels Rsve state that cyelic.Ptanao moleosle
I'sOnsidered o be Aaomatic f i t has 4n t2 T e

3 ln the nitratibn Teactim, wsite the seacton fo the


Foxnation ofnitsoaiomion

O OH
Nt + 0-S-0H
0
OH
-Ho
0=Nt=o

h y hy Jeattivityf_aniline towards
electaophilie
Substitu tion 1 highe than ben ene
Ctm of ni10ogen haid pos tie Chadje.This
redue
An
the dens ity o benent electons. The electron dens fy_
the A niline 1
pn beniene 3inj tho ot1rmo in anilint.
a30matic Subs titvtio.
mos-t Sensit' v to plectiophilte
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wsde abovt huddlnjnfoil y 9iving suitble exomf
Unsatoratod taigiyc.edsGactIth-hydao
n KesPnce o metalclatalyst to give
atus ated talg lycexide As UMSatusat ed tat
acid tonver t ed Ho satoxtedfqtty acds
s taanjfosmmtdinto Fat is1S catled 4
haodenn3 0f oil,ao

H2C0 HiaCH CH-H2CH3 Ha C-0-C-


HC-0-C-H2-tH=cH-(CH2)4-CH3 HC-0-C-uh
H,C-C-(H1- CHECHCH2)-CH30 C-0-c-th
Match the tolloWn
Acid v aulue Repres ent the amodht of fve
Fatty acid pre sent nfet|0
D lo dine yalue Repre Kent the am out
UnsatuX atjon_ tot Oi
c Reichest MeisSl num
alatile be-RoPTesext The
fatty_aud
am
dunt
shiS bodrO P0sent lh fat o
a Acet mdbex Re se set The numbesL

Fom
66Jis V2x32 2ov)
oioseT

Teachers Signature.
stod Dats
Poge

3
what age polynUcleas Cidomatic hydsocaT bons ive their
Strutore.
x ample with
polynuleax CAOmatic hy
dxuc aobons a/oe Compos ed by
bënl enei10 m DS/
two 03 moe
polynyleas hy dooCabon S

NOY eprenafd
Ben2enoig

Fuse m
3 A 2 d e n e

Anjula
Bipheny

Jux2 Nag
hthal4ne
phen.anthren

ene und es joe electg0 philic Su bs ti ttion


2why naphthgl
a t o n mostly a t a/ha posit ion
1e
Elotioilie atfack-s

YV

b bacbairs Signatura..
glt s'hedouoT
(i)
3
Date
Page

2 What Js The vse 0f ib lv mgnn's test uya


Ch emita seat tion d f t
Thistest ue fos detection 0t Ch0lestesol iHT

NaNO
o Ne
Extesso E
Phengi

eilo calovs

Ndo
Sodiumiqltot
indoph.e mal H
BLue Lalauz)

Hou iHygu synthesinep-n]trahenzyl to


ethex fxbm p- CTeJo
OH 3 1 C H a 8

N00H
- Na gT

N0
CH A0
P-Ceolp a10
benmyl b30md
Date
Page

p-F1gso benuoiC
Coma the acid ity af o m
aid

C-0 0 C

Fs
m)tipyc

Cs boxy 3& i0m m (ieasia audit


c i d th 1so- ftuohenu
orc aud
So 03dex bf p-fioTo b t n r o i a i d
- s0 bemtoia id
6 eoI autd.
13o0m 'el ln base hy daolysis
hich sodct
th Keatio oft
o benlots1 ChloY de 1uwsde
COON
eCl3
NaoH
H H301

Soci Um Benoi
Beo
nthoxde b Pa oufe

m B basichm
3Whyuluhatic am
O Ynne

The basia ty cOmpoun


ot measv3e of
Ubili To a Cept 36Tn
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Date
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In OmmomM, lsne pais of EN a fomls lotal


3to nd hlly avatlbte o fod Irttr acti0ncth Poot

N-H Ht H-NHH
H
amMy10
naliphatiea mime l0m pais of d f N atom ls lo
Sis l l y gvailble Fox 1n 1es t7oy w1dh ) 3ojo7. A|
aliph othe omiea ky 3Du g eleUfdoY
Ves 9 S3oup.makimj lone al of e 0E
N even mosanNgi bt fobasic.ThiS, aliphi
MOTe hasic h an a mndn/14

lkyl
liphahu amiM psatyt e b 0m

S ab0maie a mnefrone pais ofE fNa


cdecolies ins benzene 37 by reonan
Sother« Ls ess a valhle n N fur te

NHL NH2 N Hz NHL

N-H
S+ R essmomce hy b3) d
JNT
A
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Dte

Page

jne eess baic


s baTCthan aliyha
mah amn
am
h y s C O m a n

am m6niC,
0m ine
benmene
b5omo
amu do
(mveKt
ill ud N'H C
4How
NH H H B3 CaBr
NGNO

H
t H w J o -

c 2 H 10

0 SAt 3
bemene Y

6 t
band j ncaSe
w h t do
yaumean
tyclopsopune
o
are_o
ase
3i
i eNTed 22
enTeJ 22

bsid ile oxbi maUlcearhL

n a l l L s p shy maginjln1e

Otrod fJbm
bond
n bond bGn gna
fosn nt
hat
lsend to end ovsla
Sigm 0 bond fh ese de OYelap
-ASn S S i d e to n
pi b 07d
betc
amd med fe n
emtey
ak ea thqenigma
en bsn d

Pxpl qin Th n a e l e d
b e y t b 0 hd
h e e ale
owaYd
yop30 pune

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Date
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1whydaes cycloopue ive P 0ptn)j


Oatio0h easLl Lor paTed to 0the
Cy loalk une
s e s
pesBaeyes s13ain theay there ls Cungle
HS otnpia
Stsn (s Poesene
tuJo ond 1672
TMenos maangle betaeen
khe omy_devah n n g l S h o o fheband
tomeIi

AS Pe he03y the Cylo frop ine agse 1er


aY ge stsa COmpTed to 0ther Cyclo
alk one
Sheyclo p3o pane s g 3eaten nstbi l t
o o ofening f 1 dth qt zlaJn
Cyclo(5o p m asy ih
hefupAnarmeoffollowig struetve
3 itt
Bi
C lo3:1 heptone

2)

spi00 S,4octane
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