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NDT Ex
using M-295Leeb hardness tester. A small area of about Results and discussion
2 cm diameter was coarsely polished at every 500 mm
along the height for hardness testing. An average of five Dimensional measurements and visual assessment of
readings taken at close-by locations is reported here. The the pillar
maximum variation in hardness was observed to be 10
Vicker’s Hardness Number. A few locations where hard- The height of the pillar above the ground level is 8.7 m
ness was measured, viz. 1.2, 1.7, 3.3, 3.7, 4.2, 5.2, 6.2 (286), including 1 m in the concrete platform at the
and 8.7 m (top of the pillar), were further polished for in ground level. The concrete platform was built in 1994 to
situ metallography. Polishing on the side surfaces near provide better stability to the pillar. The cross-section of
the top portion of the pillar for in situ metallography was the pillar is rectangular with average dimensions of about
difficult as both the pillar and the scaffolding would 7.75 cm 7 cm (3 2.75). Figure 2 shows the variation
swing with even a small push and also due to the heavy in the thickness of the pillar in two perpendicular direc-
breeze. Hence, in situ metallography was carried out on tions as a function of height of the pillar. Thickness var-
the top face of the pillar and then the next location was at ies in the range 6.4–7.7 cm and 6.8–8.6 cm throughout
2.5 m below the top surface. In order to get the micro- the pillar in the two perpendicular directions, except in
structure of the pillar in the top portion, a small piece the top 0.20 m where it was found to be 89 and 92 mm
(~ 50 mg) of iron was taken out from a sharp protruding respectively. As the surfaces are not exactly parallel, the
point at 0.25 m below the top. A detailed scanning elec- variation in perimeter is also plotted in Figure 2. The
tron microscopy (SEM) study was carried out on this perimeter of the pillar is essentially uniform in the 24.2–
sample. XRF studies were also carried out on the pillar at 30.1 m range throughout its height, with an average of
a few of the in situ metallography locations using port- 27.4 m.
able XRF system (M/s Bruker, Germany). Ultrasonic The general appearance of the pillar is rough and red-
measurements were carried out in transmission mode dish-brown in colour. In general, the pillar exhibits more
using a pair of 500 kHz transducers, a broadband pulser- corrosion compared to the other two pillars at Delhi and
reciever and a 100 MS/s digitizer card. Dhar. The roughness (corrosion) of the pillar increases
with increasing height, as shown in Figure 3. The top
1.25 m (4) of the pillar exhibits extensive erosion/
corrosion (Figure 4). The top portion of the pillar from
north, east, south, west and top is shown in Figure 5. It is
seen that the corrosion of the pillar is high on the west
side (Figure 5 d), which is exposed to direct breeze from
the Arabian Sea that is about 30 km away.
The top of the pillar exhibits signs of hammer forging
(Figure 5 e). Unlike the iron pillars at Delhi and Dhar, the
top of this pillar does not have any groove for further
attachment. The top seems like the end of the pillar, with
heavy forging leading to flattened end and increased
thickness in the top 0.20 m of the pillar (Figure 2). This is
Figure 1. Scaffolding around the Kodachadri iron pillar to have Figure 2. Variation in thickness and perimeter as the function of the
access to different elevations of the pillar. height of the iron pillar.
Figure 3. Appearance of the pillar at different elevations: (a) 4 m (low corrosion), (b) 6 m (medium corrosion) and (c) 8 m (heavy
corrosion).
Hardness
Figure 4. Photograph of the pillar showing high corrosion in about
1.25 m of the top 1.4 m. Hardness was found to be in the range 120–195 VHN at
different elevations of the pillar (Figure 8). The variation
in the hardness is attributed to the difference in the car-
in line with the local tradition which indicates that the bon content, grain size and extent of deformation at dif-
‘flag staff’ is the top portion of the trishul. Contrary to ferent elevations. For 0.15% carbon (estimated based on
the view expressed by Anantharaman6 , the top portion of the maximum volume fraction of pearlite) with ferritic–
the pillar does not show any signs of melting or flow of pearlitic structure, the hardness in the annealed condition
material. is estimated to be ~ 120 VHN (ref. 7). The higher hard-
ness is attributed to the considerable extent of deforma-
In situ XRF and metallography studies on the pillar tion/forging of the pillar.
Figure 6. Low magnification optical microstructure obtained on the replica taken at different elevations of the pillar: (a) 8.7 m
(top of the pillar), (b) 6.2 m, (c) 5.2 m, (d) 4.2 m, (e) 3.7 m, ( f ) 3.3 m, (g) 1.7 m and (h) 1.2 m.
locate any clear interface. As velocity of the ultrasonic reported to be 6000 m/s (ref. 8) and the velocity of vari-
wave can provide the quality of the iron in terms of the ous silicate glasses and ceramics is reported to be in the
presence of distributed voids/cracks, ultrasonic velocity range 5900–6500 m/s (ref. 9). Lower ultrasonic velocity
measurements were carried out at the locations polished in the pillar material compared to the steels and slag
for hardness measurements. Figure 8 also shows the (silicates) indicates presence of defects/discontinuities in
variation in ultrasonic longitudinal wave velocity in the the pillar.
pillar at different elevations. The ultrasonic velocity is
found to be in the range 5500–5900 m/s. As shown in the
next section, the microstructure of the iron pillar consists Scanning electron microscopy
of ferritic–pearlitic structure with varying volume frac-
tion of slag. The longitudinal wave velocity in wrought Figure 9 shows typical SEM backscattered electron images
iron and carbon steels with ferritic–pearlitic structure is (BEI) obtained from the small piece (~ 50 mg) of the
Figure 7. High magnification optical microstructures obtained on the replica taken at different elevations of the pillar: (a) 8.7 m
(top of the pillar), (b) 6.2 m, (c) 5.2 m, (d) 4.2 m, (e) 3.7 m, ( f ) 3.3 m, (g) 1.7 m and (h) 1.2 m.
Figure 8. Variation in perimeter, hardness and ultrasonic longitudinal wave velocity at different elevations of
the pillar.
sample removed from a sharp, protruding point at 0.25 m ited presence of O, Al, Si, Ca and P in the regions of slag,
below the top of the pillar. Ferrite matrix with pearlite, and O and Fe in oxides. A typical EDS spectrum and
iron oxides and slag (confirmed by energy-dispersive composition of a slag particle are shown in Figure 11 a
X-ray spectroscopy (EDS)) is indicated in Figure 9. The and Table 1 respectively. The EDS spectrum for the
constituent phases are typical for iron produced by matrix away from slag regions is shown in Figure 11 b. The
ancient iron-making route in India1. Figure 10 shows a composition of the slag in the iron pillar is similar to that
SEM BEI image and X-ray energy mapping for Fe, C, P, reported by Prakash and Igaki10 for slag obtained in the
O, Si, Al and Ca in the sample. The EDS mapping exhib- iron produced by ancient iron-making route. The above
1708 CURRENT SCIENCE, VOL. 105, NO. 12, 25 DECEMBER 2013
RESEARCH ARTICLES
Figure 9. Typical scanning electron microscopy backscattered electron images showing various constituent phases present in the iron pillar.
Figure 10. Scanning electron microscopy backscattered electron image and X-ray energy mapping for
Fe, C, P, O, Si, Al and Ca on the sample taken at 0.25 m from the top of the pillar.
results clearly demonstrate that the iron pillar at Koda- one of the major factors for high corrosion resistance
chadri is produced by the ancient iron-making route by of the iron pillars at Delhi and MP4,11,12 . The amount of
solid state reduction process. phosphorus obtained in the slag in Kodachadri iron pillar
One major difference in the composition of the matrix is about 1% (Table 1), whereas it is reported to be in the
and slag of the iron pillar at Kodachadri and other ancient range 6–11% in the slag in ancient Indian iron objects ob-
Indian iron objects reported earlier11 , is the amount of tained at other locations11. Further, the amount of P in the
phosphorus. Presence of phosphorus is considered to be matrix is estimated to be about 0.02 wt% by in situ XRF
CURRENT SCIENCE, VOL. 105, NO. 12, 25 DECEMBER 2013 1709
RESEARCH ARTICLES