Ecuacion de Antoine

para cada componente

Tb exp (°C) x1 x2 nLiq nVap Tb exp (°K) Tsup (°K) P1 sat (mmHg)
73 0 1 1.37 1.376 346.15 348.97 1167.86825647
74 0.1 0.9 1.37 1.3737 347.15 346.65 1072.06143388
70 0.2 0.8 1.3704 1.3703 343.15 344.5 989.174810899
71 0.3 0.7 1.3671 1.3666 344.15 342.45 915.16142208
67 0.4 0.6 1.35 1.36 340.15 340.56 851.055524739
70 0.5 0.5 1.3536 1.3593 343.15 338.76 793.516459911
64 0.6 0.4 1.3538 1.3502 337.15 337.05 741.889534478
63 0.7 0.3 1.3474 1.3436 336.15 335.45 696.147915239
62 0.8 0.2 1.3436 1.3412 335.15 333.98 656.219691735
60 0.9 0.1 1.3374 1.3334 333.15 332.5 617.969437725
59 1 0 1.3296 1.3278 332.15 331.14 584.48075245

nliq ajust x1
no se reporta 1.372 0
1.38 1.369315 0.1 1.2
1.37 1.36632 0.2 1
f(x) = − 0.015477855477856 x² − 0.0252857808857805 x f(x) =0.8
− 222
1.36 + 1.37196013986014
1.35 R² = 0.928235849254281
1.363015 0.3 R² = 0.9995
0.6
nliq-exp

x1
1.34 1.3594 0.4 0.4
1.33 1.355475 0.5 0.2
1.32
1.31
1.35124 0.6 0
1.32
1.3 1.346695 0.7
0 0.2 0.4 0.6 0.8 1 1.2
1.34184 0.8
x1
1.336675 0.9
1.3312 1

x1 y1 1.2
0 -0.11758336 1
0.1 -0.03863387 0.8
0.2 0.07376959 0.6
y1 exp

0.3 0.19025617 0.4

0.4 0.382944 0.2
0.5 0.40224561
0
0.6 0.63335872 0 0.2 0.4 0.6 0.8 1 1.2
-0.2
0.7 0.77796417
x1
0.8 0.8257504
0.9 0.96338457
1 1.04553171

1.2 x1 y1 calc
1
0 0
0.1 0.18338834345
0.8
0.2 0.33820016662
y1 calc

0.6 0.3 0.46970569231

0.4 0.4 0.58196670204
0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
x1
 0.8

y1 calc
0.6

0.4

0.2 0.5 0.67838371199

0.6 0.76160956023
0
0 0.2 0.4 0.6 0.8 1 1.2 0.7 0.83377090055
x1 0.8 0.89661870387
0.9 0.95165989906
1 1
x1 y1 calc Tsup (°C) 80
0 0 75.82
75
0.1 0.18338834 73.5
0.2 0.33820017 71.35 70

T calc (°C)
0.3 0.46970569 69.3
0.4 0.5819667 67.41 65
0.5 0.67838371 65.61
60
0.6 0.76160956 63.9
0.7 0.8337709 62.3 55
0 0.2 0.4 0.6 0.8 1 1.2
0.8 0.8966187 60.83
x1,y1 calc
0.9 0.9516599 59.35
1 1 57.99
 Ecuacion de Antoine Ecuación de
para cada componente Raoult ideal
P2 sat (mmHg) Pt=x1*P1 sat+x2*P2sat (mmHg) %E y1 calc y2 calc
584.758784466 584.758784465951 -0.04123342 0 1
530.421367623 584.585374249148 -0.0708762 0.1833883434 0.8166116566
483.911444788 584.964118010549 -0.00613367 0.3382001666 0.6617998334
442.804536071 584.511601873631 -0.08348686 0.4697056923 0.5302943077
407.548572235 584.951353236322 -0.00831569 0.581966702 0.418033298
376.199802273 584.858131092111 -0.0242511 0.678383712 0.321616288
348.326849378 584.464460438113 -0.09154522 0.7616095602 0.2383904398
323.846069588 584.457361543359 -0.09275871 0.8337709005 0.1662290995
302.651916504 585.506136688806 0.08651909 0.8966187039 0.1033812961
282.51095299 584.423589251911 -0.09853175 0.9516598991 0.0483401009
265.015312694 584.480752449828 -0.08876026 1 0

y1 y2
no se reporta -0.11758336 1.11758336
1.2 -0.038633866 1.03863387
1 0.0737695901 0.92623041
f(x) =0.8
− 222.112617933659 x² + 576.412142740026 x − 372.723913940173
R² = 0.999536409996016 0.1902561684 0.80974383
0.6
x1

0.4
0.382944 0.617056
0.2 0.4022456061 0.59775439
0 0.6333587156 0.36664128
1.325 1.33 1.335 1.34 1.345 1.35 1.355 1.36 1.365 1.37 1.375
0.7779641744 0.22203583
nliq ajust
0.8257504016 0.1742496
0.9633845684 0.03661543
1.0455317076 -0.04553171

x1 y1 Tb exp (°C) 75
0 -0.117583360000083 73 73
0.1 -0.0386338659000671 74 71
0.2 0.0737695900998574 70 69
67
0.3 0.190256168399912 71
Teb exp

65
0.4 0.382943999999839 67 63
0.5 0.402245606099939 70 61
0.6 0.633358715599911 64 59
0.7 0.77796417439987 63 57
0.8 0.825750401599862 62 55
-0.2 0 0.2 0.4 0.6 0.8 1
0.9 0.963384568399874 60
x1,y1
1 1.04553170759993 59
8 1 1.2
0.4 0.6 0.8 1 1.2
x1,y1
Tb exp (°C) x1 x2 nLiq nVap y1 y2 exp Tb exp (°K)

58 0 1 1.3263 1.328 0.03344576 0.96655424 331.15

55 0.1 0.9 1.3446 1.349 0.04677876 0.95322124 328.15
51 0.2 0.8 1.3719 1.366 0.11039234 0.88960766 324.15
50 0.3 0.7 1.4148 1.4036 0.41895087 0.58104913 323.15
48 0.4 0.6 1.4106 1.3946 0.32404747 0.67595253 321.15
48 0.5 0.5 1.4042 1.3818 0.21188944 0.78811056 321.15
48 0.6 0.4 1.42 1.4167 0.58075984 0.41924016 321.15
48 0.7 0.3 1.4212 1.4273 0.73223024 0.26776976 321.15
48 0.8 0.2 1.4261 1.4322 0.80845962 0.19154038 321.15
48 0.9 0.1 1.4314 1.4397 0.9327414 0.0672586 321.15
48 1 0 1.4454 1.4454 1.03334755 -0.03334755 321.15

no se reporta n liq ajust x1

1.5 1.331 0
1.45 1.352788 0.1
f(x) = − 0.128193473193475 x² + 0.230693473193475 x + 1.33102097902098 1.372012 0.2
1.4
R² = 0.913641482390372 1.388672 0.3
nLiq

1.35 1.402768 0.4

1.3 1.4143 0.5
1.25 1.423268 0.6
0 0.2 0.4 0.6 0.8 1 1.2 1.429672 0.7
x1 1.433512 0.8
1.434788 0.9
1.4335 1

y1 y2 x1 y1 1.2
0.03344576 0.96655424 0 0.03344576
1
0.04677876 0.95322124 0.1 0.04677876
0.11039234 0.88960766 0.2 0.11039234 0.8
0.41895087 0.58104913 0.3 0.41895087
y1 exp

0.6
0.32404747 0.67595253 0.4 0.32404747
0.21188944 0.78811056 0.5 0.21188944 0.4
0.58075984 0.41924016 0.6 0.58075984 0.2
0.73223024 0.26776976 0.7 0.73223024
0.80845962 0.19154038 0.8 0.80845962 0
0 0.2
0.9327414 0.0672586 0.9 0.9327414
1.03334755 -0.03334755 1 1.03334755

x1 y1 Tb exp (°C) 59
0 0.03344576 58 57
0.1 0.04677876 55
55
0.2 0.11039234 51
0.3 0.41895087 53
50
Teb (°C)

0.4 0.32404747 48 51

49

47

45
0 0.2 0.4 0.6 0.8 1
 55

53

Teb (°C)
51
0.5 0.21188944 48 49
0.6 0.58075984 48 47
0.7 0.73223024 48
45
0.8 0.80845962 48 0 0.2 0.4 0.6 0.8 1
0.9 0.9327414 48 x1,y1 exp
1 1.03334755 48

0.6

x1 x2 ln γ1 exp ln γ2 exp 0.4

f(x) = 0.897229327147353 x − 0.529875692
0 1 -0.0335414 R² = 0.375600980680635
0.2
0.1 0.9 -0.79780474 0.18264489
0.2 0.8 -0.49473236 0.40166546 0
0 0.2 0.4
0.3 0.7 0.46853849 0.1525646
-0.2
0.4 0.6 -0.00519699 0.54553471 f(x) = − 0.171265164881085 x + 0.42710448
R² = 0.0369609658027977
0.5 0.5 -0.65316592 0.88137179 -0.4
0.6 0.4 0.17278521 0.47332089
0.7 0.3 0.25039221 0.31268655 -0.6
0.8 0.2 0.21589656 0.38312277
-0.8
0.9 0.1 0.24111078 0.02971623
1 0 0.23818113 -1

Tb exp (°C) x1 x2 nLiq nVap y1 y2 exp Tb exp (°K)

58 0 1 1.3263 1.328 0.03344576 0.96655424 331.15

55 0.1 0.9 1.3446 1.349 0.04677876 0.95322124 328.15
51 0.2 0.8 1.3719 1.366 0.11039234 0.88960766 324.15
50 0.3 0.7 1.4148 1.4036 0.41895087 0.58104913 323.15
48 0.4 0.6 1.4106 1.3946 0.32404747 0.67595253 321.15
48 0.5 0.5 1.4042 1.3818 0.21188944 0.78811056 321.15
48 0.6 0.4 1.42 1.4167 0.58075984 0.41924016 321.15
48 0.7 0.3 1.4212 1.4273 0.73223024 0.26776976 321.15
48 0.8 0.2 1.4261 1.4322 0.80845962 0.19154038 321.15
48 0.9 0.1 1.4314 1.4397 0.9327414 0.0672586 321.15
48 1 0 1.4454 1.4454 1.03334755 -0.03334755 321.15

x1 y1-calc 1.2
0 0.58866383 1
0.1 0.76019143
0.2 0.91015169 0.8
y1 calc

0.3 1.02194431 0.6

0.4 1.08855595
0.4
0.5 1.11268387
0.6 1.10402214 0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
x1
 0.6

y1 ca
0.4

0.2
0.7 1.07561329 0
0 0.2 0.4 0.6 0.8 1 1.2
0.8 1.0408649
0.9 1.01199841 x1
1 1
 Ecuacion de Antoine
P1 sat exp P2 sat exp
γ1 exp γ2 exp ln γ1 exp ln γ2 exp
(mmHg) (mmHg)
672.059529 584.721335 #DIV/0! 0.96701488 #DIV/0! -0.0335414
607.696613 516.161248 0.45031644 1.20038807 -0.797804743217779 0.18264489
529.571182 435.334714 0.60973407 1.49431134 -0.494732360700491 0.40166546
511.345019 416.881589 1.5976575 1.1648177 0.468538494020794 0.1525646
476.388785 381.942602 0.99481649 1.72553079 -0.00519698628620422 0.54553471
476.388785 381.942602 0.52039563 2.41420923 -0.653165924385304 0.88137179
476.388785 381.942602 1.18861078 1.60531643 0.172785212801103 0.47332089
476.388785 381.942602 1.28452913 1.36709295 0.250392212118462 0.31268655
476.388785 381.942602 1.24097401 1.46685811 0.215896560415836 0.38312277
476.388785 381.942602 1.27266201 1.03016216 0.241110778892562 0.02971623
476.388785 381.942602 1.26893901 #DIV/0! 0.238181129716037 #DIV/0!

no se reporta
1.2
1
0.8 f(x) = 81.7647458362541 x² − 218.245077677385 x + 145.671811512777
R² = 0.953557992704552
0.6
x1

0.4
0.2
0
1.32 1.34 1.36 1.38 1.4 1.42 1.44 1.46
nliq ajust

1.2

0.8
y1 exp

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
x1

0.6 0.8 1 1.2

 0.6 0.8 1 1.2
1,y1 exp

1 A12 A21
-0.5299 0.4271

97229327147353 x − 0.529875692593543 0.8

5600980680635

0.6
0.2 0.4 0.6 0.8 1 1.2

171265164881085 x + 0.427104489941105 0.4

69609658027977

0.2

-0.2

Ecuacion de Antoine
P1 sat exp P2 sat exp Modelo de Margules
Tb sup (K) (mmHg) (mmHg) γ1 exp γ2 exp Pt=x1*P1 sat+x2*P2 sat %E
331.15 672.059529 584.721335 0.58866383 1 584.721335215728 -0.04763501
331.75 685.554055 599.308651 0.76019143 0.98712855 584.55044609288 -0.07684682
331.8 686.688166 600.53787 0.91015169 0.95679703 584.67235929887 -0.05600696
331.22 673.623006 586.407735 1.02194431 0.92114023 584.636186985375 -0.06219026
330.23 651.775701 562.931473 1.08855595 0.89100254 584.741750297751 -0.04414525
329.12 627.949423 537.549989 1.11268387 0.87592483 584.781289762264 -0.03738637
328.12 607.078578 515.511283 1.10402214 0.8852723 584.684056730629 -0.0540074
327.35 591.385052 499.061996 1.07561329 0.93045739 584.577910710471 -0.07215202
326.85 581.367625 488.618106 1.0408649 1.02875774 584.634054701134 -0.06255475
326.66 577.596427 484.69779 1.01199841 1.21035899 584.73983173697 -0.04447321
327.01 584.55847 491.940017 1 1.53280593 584.558469741959 -0.07547526

Aqui con tb exp

x1 y1-calc Tb sup (K) 334
Tb exp (°K)
0 0.58866383 331.15 332
331.15 0.1 0.76019143 331.75 330
328.15 0.2 0.91015169 331.8 328
324.15 0.3 1.02194431 331.22 326
323.15 0.4 1.08855595 330.23
324
321.15 0.5 1.11268387 329.12
322
321.15 0.6 1.10402214 328.12
320
318
316
314
0 0.2 0.4 0.6 0.8 1
 326
324
322
320
321.15 0.7 1.07561329 327.35
318
321.15 0.8 1.0408649 326.85
316
321.15 0.9 1.01199841 326.66
314
321.15 1 1 327.01 0 0.2 0.4 0.6 0.8 1
321.15

aqui con t calc

333
332
331
330
329
328
327
326
325
324
0 0.2 0.4 0.6 0.8 1
 y1-calc y2-calcu
0.58866383 1
0.76019143 0.98712855
0.91015169 0.95679703
1.02194431 0.92114023
1.08855595 0.89100254
1.11268387 0.87592483
1.10402214 0.8852723
1.07561329 0.93045739
1.0408649 1.02875774
1.01199841 1.21035899
1 1.53280593

n tb exp

.6 0.8 1 1.2
.6 0.8 1 1.2

n t calc

0.6 0.8 1 1.2