AITS 2223 CRT I JEEA LD Paper 1 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
CONCEPT RECAPITULATION TEST – I
PAPER –1
TEST DATE: 26-04-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. A, D
Sol. Let r1 be radius of conical conductor at left end, then radius at distance “a” from left end
r2  r1  ba [b = constant]
i i
j  E  E 
A A
1 1 
E  
A  (r1  ab) 
2
 Thus, E – a curve is wrong.

2
I
H
A
I  1 
H  
A  (r1  ab)2 
Thus, (H – a) curve is correct.
H i2  A 
  i  cons tan t
E A  i 
Thus, (H – E) curve is a straight line passing through origin.
a
  idx
dv  E.dx  
0

(r1  ab)2
i  ab 
v
b  r1  ab 
Thus (V – a) is wrong.
2. A, C
d a2  a
Sol. eind   a2 ; i  
dt 
 2a  2
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AITS-CRT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2
3. A, D
1 1 1 1
Sol.   
feff f1 f2 30
1 1 1
 
feff v u
 1/v = 0
 v=
R
f
2(  1)
 R = 20 cm
For surrounding = 9/8
20 10
f 
3  8   4 
2  1   1
29   3 
f = 30 cm
1 1 1
 
f v u
1 1 1
 
30 v 30
v=
4. A, D
Sol. Some field lines must go to infinity also from Q, and some on conductor. Hence total flux leaving
Q is greater than that entering conductor.
Hence A
Also, since potential of conductor is zero, hence it can’t have positive charge anywhere on
surface else it will emit some field lines to infinity making its potential non-zero.
Hence D
5. B, D
Sol. By gas equation
PV = nRT
4.155  105  70  103  n  8.31 350
So, n = 10
Now by first law of thermodynamics
Q = U + W
U = Power  Time – (8077.5) = 6000 – 8077.5 = - 2077.5 Joule
nCVT = – 2077.5
2077.5
So, C V   CV  20.775
10  ( 10)
f
R  20.775
2
2  20.775
f 5
8.31
6. A, B, C
Sol. V1  1R1  2R2
 V1  1R1  2R2
Differentiating, we get
a1  1R1   2R 2
V1,a1 : Speed and tangential acceleration of ‘P’
3 AITS-CRT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
7. A
   
Sol. dF  i d  B 
 
  
 iAB
8. A
Sol. By using (-1)t = n, we can find value of n, that is order of the fringe 5D
produced at P, if that particular strip has been placed over any of the slit. If two 4B
4D
strips are used in conjunction (over each other), path difference due to each is 3B
3D
added to get net path difference created. If two strips are used over different 2B
2D
slits, their path differences are subtracted to get net path difference. 1B
1D
 1  1 t1 1D
CB
Now, n1 = 5 1B
 2D
n2 = 4.5 2B
and n3= 0.5 3D
3B
For (I), order of the fringe is 4.5 i.e. 5th dark
For (II), net order is 5 – 0.5 = 4.5
i.e. fifth dark
For (III) net order is 5 – (0.5 + 4.5) = 0
i.e. it is central bright again at P.
For (IV) net order is (5+0.5) – (4.5) = 1
i.e. first bright
9. A
    
Sol. 
u  40cos37 o i  40 sin37o j, v  40 cos 37o i  40 sin37o  gt j 
 
(I) u.v  0 (32)2 + 24 (24 10t)
(II) 0 = 20 10 t, t = 2 sec (at highest point)
(III) 36 = 24t 5t2  5t2 24t 36 = 0, t = 6 sec
(IV)   40 sin 37o  gt   40 cos 37o
56
(24 10t, = 32 t = = 5.6 sec)
10
10. B
 1
Sol. qB  q  1  
 K
qA   q
 1
qC   q  1  
 K
qD   q
Section – B
11. 1.05
1240
Sol. Energy incident on cesium metal   3.1eV
400
K mx  3.1  1.9  1.2 eV
(kmx  maximum kinetic energy of photoelectron from the metal cesium)
So kinetic energy of photoelectron

0  k  k mx .
e
   k mx
2 0 23.8 eV
So, k    1.053
e 22.6 eV

2 0
12. 2.39
C1C3 CC
Sol. E  C1C2 cos 0t  cos(0  )t  1 3 cos(0  )t
2 2
Of the three components, the highest frequency component will liberate the electrons with
maximum kinetic energy
h
( K .E ) max    (0  )   = 2.39 eV.
2
13. 3.00
(2r  1)(2r 2  2r  1) (2r  1)(2r 2  2r  1)
Sol. Tr   2
(r 2  1)2 (r 2  2r)2 (r  1)2 ((r  1)2  1)2
 1 1 
 Tr   2 2
 2 2
 (r  1) ((r  1)  1) 
 1 1   1 1   1 1 
 K  lim    2 2
 2  2  2   ....   2  2 
n
  (2  1) (3  1)2   (3  1)
2
(4  1)2   (n  1)
2 2
((n  1)  1)  
1
k 
9
14. 0.15
Sol. Energy of incident photons in eV is given as
12431
E eV
1800
As work function of metal is 2eV, the maximum kinetic energy of ejected electrons is
KEmax  E  
 KEmax  6.9  2eV
 KEmax  4.9eV
If max be the speed of fastest electrons then we have
1 2
m max  4.9  1.6  1019 joule
2
2  4.9  1.6  10 19
  max 
9.1 10 31
  max  1.31 10 6 m/s
When an electron with this speed enters a uniform magnetic field normally it follows a circular
path whose radius can be given by
mv mv 2
r [As qvB  ]
qB r
9.1 10 31  1.31 106
 r
1.6  10 19  5  105
 r  0.149 m
15. 1.66
Sol. If central maxima is formed at point P on the screen, then Screen
P
Path difference = S2P + (g–1)t – S1P – wd sin 30° = 0
water x
 w = 4/3 S1
xd d t =30°
S 2 P  S1 P    w d sin 30  ( g  1)  t
D g
s
 S2
x  1.66 cm D
16. 654.00
Sol. 1 2 MR 2 a
Mg  T  Ma and TR   MR   
2  2 R
a
 Mg  M  Ma
2
2
a  g = 654 cm/s2
3
17. 8.00
Sol.  Elements of determinant can be 1 or -1
 First two places of first row can be filled in 2  2 =4 ways and last place can be filled in only
one way to product be 1
 First row can be made in 4 ways
Similarly second row can be made in 4 ways and third row can be made in 1 ways only
 m = 16
3 2 3
 P  2 2 3  1
0 1 1
n2
 adj(adjP)  P P  P  tr(adj(adjP))  tr(P)  2  n.
m 16
  8
n 2
18. 100.00
P V
Sol. B or P   B.
V / V V
 0. 1 
 P  9.8  108   
 100 
 0. 1 
or hg  9.8  108   
 100 
9.8  10 8 0.1
 h  m = 100 m
1000  9.8 100
Chemistry PART – II
Section – A
19. C, D
Sol. (A) (B)
(C) (D)
20. B, C, D
K b  Wsolute  1000 1.70  1.22  1000
Sol. Molecular weight of C6H5 COOH in CH3 COCH3    122
Tb  Wsolvent 0.17  100
2.6  1.22  1000
Molecular weight of C6H5 COOH in C6H6   244
0.13  100
Hence, molecular weight of C6H5 COOH in both the solvent is not equal. C6H5 COOH dimerise in
C6H6 and remains in monomeric form in acetone.
21. B, C, D
Sol. CS2
P4 is soluble in CS2 but it does not react with CS2
HOT NaOH
solution PH3 (g)  NaH2PO2
P4
Cl2 (g)
PCl3
Molten
Na2P
Na metal
22. A, D
Sol. According to Bohr model angular momentum = nh/2, n = 3 thus A is incorrect
Number of electrons is nucleus = 0, thus D is incorrect
23. A, B, C, D
Sol. (A) End othermic raction temperature  equilibrium shift in forward direction so degree of
dissociation 
D
(B) 1    T d
d
(C) PN2 O4  PNO2  when helium gas added under constant pressure.
(D) PN2 O4  when N2 O4 added
24. A, C, D
Sol. Complex compounds Type of structural iso.
A Ir  ONO 3 H2 O 3  linkageisomerism
2
B  Ir NO3 H2O 5  None
 C  Co  ox H2O 3 Br  .H2O Hydrate isomerism
D  PdBr NH3 4  SO4   Cl Ionizationisomerism
25. B
Sol. NO2  H2 O  HNO3  NO  g

XeF2  HF   XeF F  .......H  F 
OCl2  H2 O  2HClO

BF3  HF  H BF4 
26. B
Sol. (I)
(II)
(III)
(IV)
27. D
Sol. (I) Tf  0.1 2  0  Tf  273  0.2  272.8K
(II)   0.1 2   0.0821 298  4.98atm
  1  0.25
(III) Tb  2.5 1    1  0.1   0.125
  2  2
Pº P in 0.1
(IV) RLVP     18  104
Pº N 1000
18
Pº P
% RLVP  100   18  102 or 0.18
Pº

C6H2 OH  H2 O  
 C6H5 O  aq  H3 O aq
 
0.1 0.1 0.1 0.1
10
C6H5 O  H3 O  
K a  10   0.1 2
C6H5OH
0.1  0.1
  10 3 , i     1  1  10 3  1
0.1
28. A
Sol. Ionic Compound voids Occupied
NaCl Octahedral voids occupied
ZnS 50% tetrahedral voids occupied
CsCl Cubic void occupied
CaF2 100% tetrahedral voids occupied
Section – B
29. 4.00
Sol.
30. 3.00
Sol.
31. 6160.00
50
Sol. Litres of gasoline used =  2.5L
20
Mass of gasoline used = 2.5  1000  0.8 g = 2000 g
Mass of carbon consumed = 0.84  2000 g = 1680.
1680
Moles of carbon consumed =
12
1680
Moles of CO2 formed =
12
1680
Mass of CO2 produced =  44
12
= 6160
32. 2.38
Sol. 2Mn + 4 HCl + O2  2 MnCl2 + 2 H2O
2
E = Eº 
RT
n
MnCl2 
4F PO2  HCl 4
0.06  10 6 
= 1.229 + 1.185  log  8 
4  0.25  10 
= 2.375
33. 6.00
Sol. (ii, iii, iv, v, vii, viii) are more basic than aniline
34. 30.00
Sol. Let initial no. of tritium atoms = x
Mass of T2O + mass of H2O = 0.0009
x  18 
  22   0.0009
NA  8  10 18 
0.0009
x=  8  1018  6  1023  240
18
240
Atoms of tritium left after 3 half lives =  30
8
35. 66.00
Sol. No. of Si per unit cell = 8
Let radius of Si atom = R
3a 8R
2R = a
4 3
4 3
8 R
% of vacant space = 100 – 3
3
a
8 43 3
= 100 
3  83
= 66%
36. 72.00
3
Sol. O3  O2
2
K = 5  10–4
d  O3  2
  5  104  2  108  mol L1s 1
dt
2 1
 
= 5  104  2  10 8  6  10 23 
1000
 60
= 7200 molecules mL–1 min–1
Mathematics PART – III
Section – A
37. B, C
Sol. z  r  cos   isin  
cos  isin 
5r cos   i5r sin    3
r r
2 2
 cos    sin  
 5r cos      5r sin    9
 r   r 
1

25r 2  2  10 cos 2   sin2   9
r

 1
9   25r 2  2 
 r 
cos2  
10
1
2cos 2   1  
10
2 9
cos  
20
38. A, B, C
Sol. In right triangle
1
Inradius =  ba se  height  hypo taneous 
2
hypo tanens
Circum radius =
2
In isosceles right angled , sides are is ratio 1 : 1 : 2, So required ratio is 2 + 1
In right triangle having angles is AP is 3 +1
In regular hexogen required ratio is 2 :3
In equalled , radii of incircle, circumcircle and ex circle are in ratio 1 : 2: 3
39. A, B, C
Sol. 2x  2y  2x  y  2 x  2 y  1
dy dy 2y
2 y.ln 2  21 ln 2  1  0   x
dx dx 2
2y  2 y
1  x  2y  1  2y  x
2 2
dy
 1  2y
dx
2x 2y 1
Also  1  2x  
2y 2x 1  2x
dy 1

dx 1  2x
40. A
Sol. Let Q be the centre of the given circle and R be the centre of the smallest circle touching the
given circle externally than
AQ  3  2
PQ  3 2  4
 
 3 2  4  32 2 r r 2  APQ  
 4 
 ( 2  1)  r( 2  1)  r  1.
41. C, D
5  
Sol. Let A     A , 
18 6 4
 
f(A)  tan A  cos A  cot A  A   , 
6 4
11 2 2 1
Hence l1  ,l2 
2 3 2
42. A, B
Sol. Let P (2, -1) goes 2 units along x + y = 1 upto A and 5 units along x – 2y = 4 up to B
1
Slope of PA = -1= tan135°, slope of PB = = tan
2
1 2
 sin = , cos =
5 5
1 1
 A  (x1 + rcos135°, y1 = rsin135°) = (2 + 2x  , -1 + 2  )
2 2
= (2 - 2, 2 – 1)
2 5
B  (x1 + rcos, y1 + rsin) = (2 + 5  , -1 + ) = (25 + 2, 5 – 1)
5 5
43. B
z  z 
Sol. (I) We have,    
16  z 16  z 
But z z    16
16 16

So,   z   
 16  16 
16    
 z   
   0  Re     0
x 3  2  11i   3  4i  
(II) x     2 i
x 2  3  4i   3  4i 
 p  2, q  1
 p  q  2 1 3
(III) We have, z  iz 2 ; Put z = x + iy
 x  iy  i  x 2  y 2  2ixy 
 On solving, we get
3 i  3 i
z  0  i 0, i ,  , 
2 2 2 2
 4 solutions.
(IV) | 3z  9  7i |  3z  6  3i   3  4i 
 3z  6  3i  3  4i
3 z2i 5
 20
44. A
Sol. (I) Equally like mutually exclusive and exhaustive cases to have exactly 2H in first three and
exactly 2H in last three, when the coin is thrown 5 times, are
 n(S) = 5
H H T H H 
H T H H T 
 
H T H T H 
 
T H H H T 
 T H H T H
Out of these five, 4 cases favours the event, that 3rd flip is H.
4
Hence P(E) =
5
2D
(II) E : atmost 3 are drawn 10

8G
P(E)  P(G or DG or DDG)
8  2  8   2  1 
         1
10  10  9   10  9 
8 16 2 72  16  2
    1
10 90 90 90
(III) new 1/3 W
B 2B / 1W
1/2 content 2/3 B
1B
new 2/3 W
1W
1/2
W 2W / 1B
content 1/3 B
st
A : 1 drawn is white
B = at least one of the two balls drawn was white
1 2 1 1 1 1 1
.  . 
P  A  B 2 3 2 3 1 6 3
P  A / B    3 6  2  . 

P B  1 1 1 2 1 1 1 1 1 4 2 4 4
.  .  .  
2 3 2 3 2 3 6 3 6 6
(IV) A B
P  A  Bc   P  A   P  A  B 
c
P  A  Bc  will be minimum if P  A  B  is maximum AB AB BAc
But P  A  B max  0.3  think 
  A  B c min  0.7  0.3
4 2
 0.4  
10 5
45. C
x 1
Sol. (I)  t.f  2x  t  dt  tan1  x 2 
0 2
Put 2x – t = y
 dt = –dy
2x 2x 2x
Hence   2x  y  f  y dy  2x  f  y  dy  
x x x
yf  y  dy
2x 2x 1
 2x  f  y  dy   yf  y  dy  tan1  x 2 
x x 2
Differentiating both sides
2x 2x
2  x  2f  2x   f  x     f  y  dy    2.2x.f  2x   xf  x  
 x  2 1  x 4 
2x x
4xf  2x   2xf  x   2 f  y  dy  4xf  2x   xf  x  
x 1 x4
2x x
2 f  y  dy  xf  x  
x 1 x4
2 1 3
Put x = 1, 2 f  y  dy  f 1  
1 2 2
2 3
1 f  x  dx  4
2
 4 f  x  dx  3   S 
1
2009
(II) Let I   
 x  1 x  2 ...  x  1004  ...  x  2007   x  2008   x  2009  dx

1
2009 terms  f (x )say
Using King
2009
I  2009  x  2008  x  2007  x  ...  2004  x  2003  x ... 1  x  dx
1
2009 2009
  1  f  x  dx  I
1
 2I = 0
 I = 0  (P)
ex ex  1
ln10
(III) I   dx
0 ex  8
Let e x  1  t 2
 e x dx  2t dt
3 t 2 dt  3 3 dt 
I    dt  9  2
0 2
t 9  0 0 t  9 
3
 9 1 t
  3
 2 3  tan   6  6   6 
 3 3 0 4 2
3
 a  6 and b 
2
 a/b = 4  (T)
g'  x 
(IV) G'  x   2
g  x
g'  2  g'  2 
G'  2    2

g 2 16
Now  fog  x   x
f '  g  x   .g'  x   1
 f '  g  2   .g'  2   1
 f '  4  .g'  2   1
 g'  2   16
16
From (ii), G'  2     1
16
  G'  2  2  1
46. D
Sol. (I) A, B, C are the 3 critical points of y = f(x). A
f’’(x) = 0 for x = 2 and fails to exists at x = 0. y
B c
x
0 1
2
(II) x = ¼ and 2. Make a quadratic in log2x and interpret the result.
dy 3 1
(III)  1  2x13    x1 
dx 4 2
1 1 15 3
   y1 or y1   c
32 2 32 8
3
 
(IV) f ' x  2x  3x  1 this is always positive in (1, 2). 3x + 4y = c
 Increasing in [1, 2]
 f(2) will be the greatest value. x1, y1
Section – B
47. 12.00
ai
Sol. a j
, i, j  { 1, 2, 3, 4} , i  j has a total of 4  4 – 4 = 12 terms i.e. 6 pairs, each pair of the
 ai a j 
type   .
 a j ai 
 
a aj  ai
Now  i   2 (as  0)
 a j ai  aj
 
ai ai
  aj
 26 a j
 12 .
48. 32.00
Sol. x 3  px2  qx  8  0
abc = 8 ( a, b, c are roots of the equation)
  n  0  a, b, and c are even numbers.
3
 N  32.22.52 and f  x    x  2 
44 

A
4
8   x  2 3  dx  8x 04    x  2    32
0  4 0
49. 25.00
Sol.  30 Cr .20 C0  30 Cr 1.20 C1  .... 30 C0 .20 Cr
r 30 20
= coefficient of x in (1 + x) (1 + x)
50
= coefficient of x r in 1  x   50 Cr
 50 Cr is maximum
50
 r  25
2
50. 47.00
Sol. S(2, 3) is circumcentre  SA = SB = SC
13  13 26 
    ,   7  B is   ,  , C is (7, 4)  BC is x + 8y = 39, p + q = 47
5  5 5 
51. 100.00
 x3
Sol. Given, f  x    log2 sin1  
  5 
2 x3
 log2 sin1   0
  5 
2 1  x  3 
0 sin    1 Double  inequality 
  5 
2 1  x  3 
 1  sin   1
  5 
 x3 
  sin1  
2  5  2
x3
 1   1  5  x  3  5
5
 8  x  2 ...(1)
2 1  x  3 
Also, sin   0
  5 
 x  3 ...(2)
 1   2 
 Domain of f(x) = x  [–8, 2] – {–3}
(i) As, a, b  I and a, b  domain f(x), so, a & b (–8, –7, –6, –5, –4, –2, –1, 0, 1, 2}
Hence, the number ordered pairs (a, b) is = 10  10 = 100 Ans.
52. 11.00
Sol. Given f  x  f '   x   f   x  f '  x 
f ' x f '  x 
 
f  x f  x 
Integrating both sides
ln  f  x     ln  f(  x )  c
ln  f  x  f   x    c  f  x  f   x   ec  c1
but f  0   3
2
f 0   c c  9
f  x f ' x  9
53. 16.00
  
Sol. 3 cos x  sin x  2  cos  x    1 or  1
 16 
11 23 5 17
x , , ,
6 6 6 6
Hence four values
54. 30.00
3 1

A  10 3 1
Sol. P 3   
 E2  2 1 3 1 4 1 3
    
10 2 10 3 10 4

AITS 2223 CRT I JEEA LD Paper 1 Sol

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

 Thus, E – a curve is wrong.

So kinetic energy of photoelectron

 C  Co  ox H2O 3 Br  .H2O Hydrate isomerism

D  PdBr NH3 4  SO4   Cl Ionizationisomerism

0.1 0.1 0.1 0.1

= 7200 molecules mL–1 min–1

Mathematics PART – III

(II) E : atmost 3 are drawn 10

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