ASSIGNMENT-7

(Carbon and Its compound)

1. Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-

5-ynoic acid is

(a) (b) (c) (d)

2. Which nomenclature is not according to IUPAC system?

(a) (b)

(c) (d)
3. The correct IUPAC name of the compound

(a) 4-Ethyl-3-propyl hex-1-ene (b) 3-Ethyl-4-ethenyl heptane

(c) 3-Ethyl-4-propyl hex-1-ene (d) 3-(1-ethylpropyl) hex-1-ene
4. The IUPAC name of the following compound is

(a) trans-2-chloro-3-iodo-2-pentene (b) cis-3-iodo-4-chloro-3-pentene

(c) trans-3-iodo-4-chloro-3-pentene (d) cis-2-chloro-3-iodo-2-pentene
5. The IUPAC name
 (a) 1- chloro -1-oxo - 2, 3- dimethyl penta (b) 2-ethyl -3- methylbutanoyl chloride
(c) 2, 3-dimethylpentanoyl chloride (d) 3, 4-dimethyl pentanoyl chloride
6. Names of some compounds are given. Which one is not correct in IUPAC

(a) (b)

(c) (d)
7. Name of the compound given below is

(a) 5-ethyl-6-methyloctane (b) 4-ethyl-3-methyloctane

(c) 3-methyl-4-ethyloctane (d) 2, 3-diethylheptane
8. IUPAC name of the following is

(a) 1, 5-hexenyne (b) 1-hexene- 5-yne (c) 1-hexyne- 5-ene (d) 1, 5-hexynene
9. The incorrect IUPAC name is

(a) (b)

(c) (d)
10. The IUPAC name of
 (a) 1, 3-isopropyl-3-methylpropane (b) 2, 3, 6-trimethylheptane
(c) 2, 5, 6-trimethylheptane (d) 2, 6, 3-trimethylheptane
11. The IUPAC name of

(a) 4-Hydroxy-1-methylpentanal (b) 4-Hydroxy-2-methylpent-2-en-1-al

(c) 2-Hydroxy-4-methylpent-3-en-5-al (d) 2-Hydroxy-3-methylpent-2-en-5-al
12. 2-Methyl-2-butene will be represented as

(a) (b)

(c) (d)
13. The IUPAC name for the compound :

(a)4-ethyl-2-pentene (b) 1 - Ethyl - 3 - methyl - 2 - butane

(c) 3 - Methylhex - 4-en-1-yne (d) 4 - Methyl - 2 - hexen - 5 yne
14. Name of the some compounds are given, which one is not true according to IUPAC
system

(a) (b)

(c) (d)
15. Arrange the following compounds in the increasing order of Carbon Carbon bond length :
Ethene, Ethyne, Ethane.
(a) Ethane, Ethyne, Ethene (b) Ethyne, Ethene, Ethane
(c) Ethene, Ethyne, Ethane (d) None of these
16. The percentage by weight of carbon in ethyne is:
(a) 33.3% (b) 92.3% (c) 50% (d) 27.35%
17. Which of the following pairs is an example of chain isomer?
(a) CH3 - CH - OH and CH3OCH3
(b) CH3 - CH2 - CHO and CH3 - COCH3
(c) CH3 - CH2 - CH2 - CH2 - CH3 and CH3 - CH - CH2 - CH3
I
CH3
(d) All of the above
18. A person is suffering from Diabetes, which get confirmed by testing his urine with
Benedict’s reagent. The organic compound and functional group present in the urine of
suffering person is:

(a)Sucrose - COOH (b) (c) (d)

19. Ethoxyethane and 1-methoxy propane are:
(a)Position isomers (b) Metamers (c) Functional isomers (d) Tautomers
20. The number of isomeric ketones with formula C5H10O are:
(a) 6 (b) 3 (c) 5 (d) 4
21. An organic compound gives hydrogen gas on reacting with Sodium metal. It also gives
iodoform test and forms an aldehyde of molecular formula C2H4O on oxidation with
CrO3 in glacial acetic acid. The organic compound is:
(a) CH3OH (b) CH3COOH (c) CH3CHO (d) C2H5OH
22. An organic compound A of molecular formula C2H6O on oxidation gives an acid B with
the same no of carbon atom as in the molecule A. Compound A is often used as tincture
of iodine:
(a) CH3 — O — CH3, CH3 — COOH (b) CH3 — O — CH3, HCOOH
(c) CH3 — CH2 — OH, CH3COOH (d) CH3 — CH2 — OH, HCOOH
23. When 2-Butyne react with one molecule of chlorine then product obtained is:
(a) 1, 2 - Dichlorobutane (b) 2, 3 - Dichlorobutane
(c) 2, 2 - Dichloro - 2- butane (d) 2, 3 - Dichloro - 2- butene
24. How many moles of oxygen are required for the complete combustion of 4.4 gm of
propane:
(a) 10 moles (b) 5 moles (c) 0.5 moles (d) 0.75 moles
25. Which of the following is not the combined form of carbon:
(a) Calamine (b) Marble (c) Diamond (d) Dolomite
26. Steam reacts with red hot charcoal to form:
(a) H2 (b) H2 + O2 (c) H2O2 (d) CO + H2
27. Which is more acidic :
(a) HCOOH (b) CH3COOH

(c) (d) CH3 – CH2 - COOH

28. In esterification, concentrated H2SO4 acts as:
(a) Catalyst (b) Dehydrating agent
(c) Hydrolysis agent (d) Both as catalyst and dehydrating agent
29. Which of the following has maximum boiling point:
(a) CH3COOH (b) HCOOH (c) C2H5COOH (d) C3H7COOH
30. The molecular formula of an ester is HCOOCH3. What will be the molecular formula of
the alcohol and the acid from which it might be prepared?
(a) CH3COOH + CH3OH (b) HCOOH + C2H5OH
(c) HCOOH + CH3OH (d) CH3CH2COOH + CH3OH
31. When a compound (A) reacts with sodium metaL, it forms sodium salt along with a gas
which has highest calorific value. This gas also used along with Pd to convert another
compound (B) into the lower homologue of compound (A). Compound (B) is the first
member of its homologous series. Compound (B) is :
(a) Methanol (b) Methanal (c) Ethanol (d) Ethanal
32. IUPAC name of tertiary butyl alcohol:
(a) 2-Butanol (b) 2-methyl propanol
(c) 2-methyl-2- propanol (d) 2, 2 - dimethyl propanol
33. The product formed when ethene reacts with excess of chlorine is :
(a) 1, 1, 2, 2 -tetrachloroethane (b) 1, 2 - dichloroethane
(c) 1, 1, 2 - trichloroethane (d) None of these
34. Which of the following have a triple bond?
(a) C2H4 (b) C3H4 (c) C3H8 (d) C3H9
35. Number of electrons shared between carbon carbon atoms in ethene is
(a) 2 (b) 4 (c) 6 (d) 8
36. Which of the following does not contain double bond?
(a) CO2 (b) C2H4 (c) HCl (d) O2
37. A phenomenon by which an element occurs in different physical modification in same
physical state is called
(a) Isomerism (b) Allotropy (c) Amorphous (d) Crystalline
 Answer Key
1. (a) 2. (a) 3. (a) 4. (a) 5. (c)
6. (a) 7. (b) 8. (b) 9. (a) 10. (b)
11. (b) 12. (b) 13. (c) 14. (d) 15. (b)
16. (b) 17. (c) 18. (c) 19. (b) 20. (b)
21. (d) 22. (c) 23. (d) 24. (c) 25. (c)
26. (d) 27. (a) 28. (d) 29. (d) 30. (c)
31. (b) 32. (c) 33. (a) 34. (b) 35. (b)
36. (c) 37. (b)