NME-Laporan 2 - Kelompok 25 - CP Monomer

A.
Perhitungan Cp Menggunakan Metode Estimasi
Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

C 10.89
H 7.56
O 13.42
Cl 24.69
Na 26.19
1. Selulosa (C6H10O5)n
4. Na-CMC (C8H11O7Na)n
n= 1000
MR = 162 g/mol 0.162 kg/mol
nE ΣnE ΣΔE
C= 6 6000 65340
H= 10 10000 75600
O= 5 5000 67100
208040
CpSelulosa =_x000D_ 208040 J/mol.K 1284198 J/kg.K CpNa-CMC =_x000D_
2. Hemiselulosa(C5H8O4)n 5. Na-MCA
n= 175
nE ΣnE ΣΔE
C= 5 875 9528.75
H= 8 1400 10584
O= 4 700 9394
29506.75
CpHemiselulosa =_x000D_ 29506.75 J/mol.K 223536 J/kg.K CpNa-MCA =_x000D_
6. Na-Glikolat (OHCH2COON
3. Lignin (C9H10O2)n
)
n= 10
nE ΣnE ΣΔE
C= 9 90 980.1
H= 10 100 756
O= 2 20 268.4
2004.5
Cplignin =_x000D_ 2004.5 J/mol.K 13363.333 J/kg.K CpNa-Glikolat =_x000D_
Na = 1 0 0 0
4. Na-CMC (C8H11O7Na)n 7. Selulosa-Na ( (C6H9O5Na)n)
n= 1000 n=
MR = 242 g/mol 0.242 kg/mol MR =
nE ΣnE ΣΔE
C= 8 8000 87120 C=
H= 11 11000 83160 H=
O= 7 7000 93940 O=
Na = 1 1000 26190 Na =
290410
CpNa-CMC =_x000D_ 290410 J/mol.K 1200041 J/kg.K CpSelulosa =_x000D_
ClCH2COONa_x000D_
nE ΣnE ΣΔE
Cl = 1 1 24.69
C= 2 2 21.78
H= 2 2 15.12
61.59
CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K
6. Na-Glikolat (OHCH2COONa
)
nE ΣnE ΣΔE
C= 2 2 21.78
H= 3 3 22.68
O= 3 3 40.26
Na = 1 1 26.19
110.91
CpNa-Glikolat =_x000D_ 110.91 J/molK 1131.7347 J/kg.K
C6H9O5Na)n)
1000
184 g/mol 0.184 kg/mol
nE ΣnE ΣΔE
6 6000 65340
9 9000 68040
5 5000 67100
1 1000 26190
200480
200480 J/mol.K 1089565 J/kg.K

B. Perhitungan Cp Menggunakan Appendix Yaws
Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

Solid Cp = A+BT+CT 2_x000D_
Liquid Cp = A+BT+CT2+DT3_x000D_
GAS
1. H2O_x000D_
MR = 18 g/mol
T= 298.15 K
A B C D E Cp (J/mol.K)
H2O(g)_x000D_ 33.933 -0.008419 0.000029906 -1.7825E-08 3.6934E-12 9973.677017
SOLID LIQUID
1. NaOH 1. H2O_x000D_
MR = 40 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
NaOH 51.234 0.013088 2.336E-05 16063.501318 H2O(l)_x000D_ 92.053
2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

MR = 94.497 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
MCA -55.75 0.59859 9983.4943871 H2O2_x000D_ -15.248
3. NaCl
MR = 58.5 g/mol
T= 298.15 K
A B C Cp (J/mol.K)
NaCl 41.293 0.033607 -1.393E-05 13682.19015
LIQUID
18 g/mol
298.15 K
B C D Cp (J/mol.K)
-0.039953 -0.000211 5.347E-07 24861.758278
34 g/mol
298.15 K
B C D Cp (J/mol.K)
0.67693 -0.001495 1.202E-06 14709.4417028
Kapasitas Produksi : 6000 ton/tahun
Masa Aktif Produksi : 330 hari
Temperatur Referensi : 25 C_x000D_
o
: 298 K
Basis Perhitungan : kg/jam
Bahan Baku : Bagasse_x000D_
Produk : Carboxymethyl Cellulose (CMC)_x000D_
Kapasitas Perancangan Pabrik CMC

Kapasitas Produksi = 757.5758 kg/jam 757.5757575758
Basis Perancangan = 786.474 kg/jam
26. Rotary Reactor (R-101)

Fungsi : Reaksi karboksimetilasi
Asumsi : 1. Konversi reaksi 80%
2. Basis F36 =_x000D_441.4876
3. Udara keluar F48 membawa 1% produk hasil reaksi_x000D_
4. Rasio Selulosa : MCA adalah 1:1,2
5. Rasio MCA : NaOH adalah 1:1,7
Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Komponen w F (kg/jam) Mr (kg/kmol) N (kmol)
Selulosa 0.95 419.4132 162 2.588970589
H2O_x000D_ 0.05 22.0744 18 1.22635449
3.815325079
0.941394 1.7
Tahap 1 : Alkalisasi Selulosa konversi = 0.8

(C6H10O5)1000 + 1000NaOH → (C6H9O5Na)1000
Mula 2.5889705894 + 4.143309312 →
Reaksi 2.071176471 + 2.071176471 → 2.071176471
Sisa 0.5177941179 + 2.072132840 → 2.071176471
Tahap 2 : Eterifikasi konversi = 0.8

ClCH2COOH + NaOH → ClCH2COONa
Mula 2.437240772 + 2.072132840 →
Reaksi 1.657706272 + 1.657706272 → 1.657706272
Sisa 0.7795344994 + 0.414426568 → 1.657706272
konversi = 0.8
ClCH2COONa + (C6H9O5Na)1000 → (C8H11O7Na)1000
Mula 1.657706272 + 2.071176471 →
Reaksi 1.656941177 + 1.656941177 → 1.656941177
Sisa 0.000765095 + 0.414235294 → 1.656941177
Tahap 3 : Reaksi samping 0.8

ClCH2COONa + 1000NaOH → OHCH2COONa
Mula 0.00076510 + 0.41442657 →
Reaksi 0.00061208 + 0.00061208 → 0.000612076
Sisa 0.00015302 + 0.41381449 → 0.000612076
Komponen Mr (kg/kmol) w F (kg/jam) X N (kmol)

Selulosa 162 0.069 83.88264710 0.016647 0.517794
Selulosa-Na 184 0.063 76.21929415 0.013318 0.414235
MCA 94.497 0.061 73.66367159 0.025062 0.779534
MCA-Na 84 0.000 0.01285360 0.000005 0.000153
NaOH 40 0.014 16.55257968 0.013304 0.413814
CMC 242 0.331 400.97976488 0.053271 1.656941
Na-Glikolat 98 0.000 0.05998346 0.000020 0.000612
NaCl 58.5 0.080 96.96686532 0.053290 1.657553
H2O_x000D_ 18 0.382 461.94274024 0.825083 25.663486
1 1210 1.000000 31.104123
Masuk
Komponen
F 36
N36
F40
N40
F44
Selulosa 419 2.588971
Selulosa-Na
MCA 230.312 2.437
MCA-Na
NaOH 165.73
CMC
Na-Glikolat
NaCl
H2O_x000D_ 22 1.22635449 64.96 3.608876572 307.79
O2
N2
Total 441 4 295 6 474
27. Heater (E-204)

F masuk F keluar N masuk N keluar
Komponen Mr
46 48 46 48
Selulosa 162.0 83.0438 83.0438 0.5126 0.5126
Selulosa-Na 184.0 75.4571 75.4571 0.4101 0.4101
MCA 94.5 72.9270 72.9270 0.7717 0.7717
MCA-Na 84.0 0.0127 0.0127 0.0002 0.0002
NaOH 40.0 16.3871 16.3871 0.4097 0.4097
CMC 242.0 396.9700 396.9700 1.6404 1.6404
Na-Glikolat 98.0 0.0594 0.0594 0.0006 0.0006
NaCl 58.5 95.9972 95.9972 1.6410 1.6410
H2O_x000D_ 18.0 457.3233 457.3233 25.4069 25.4069
Total 981.0 1198.1776 1198.1776 1.2214 1.2214
28. Aging vessel (V-103)

F in F out N in N out
Komponen Mr
Komponen Mr
48 49 N48 N49
Selulosa 162.0 83.0438 83.0438 0.5126 0.5126
Selulosa-Na 184.0 75.4571 75.4571 0.4101 0.4101
MCA 94.5 72.9270 72.9270 0.7717 0.7717
MCA-Na 84.0 0.0127 0.0127 0.0002 0.0002
NaOH 40.0 16.3871 16.3871 0.4097 0.4097
CMC 242.0 396.9700 396.9700 1.6404 1.6404
Na-Glikolat 98.0 0.0594 0.0594 0.0006 0.0006
NaCl 58.5 95.9972 95.9972 1.6410 1.6410
H2O_x000D_ 18.0 457.3233 457.3233 25.4069 25.4069
Total 981.0 1198.1776 1198.1776 1.2214 1.2214
29. Cooler (E-205)

Masuk Keluar Masuk Keluar
Komponen Mr
F49 F50 N49 N50
Selulosa 162.0 83.044 83.044 0.512616177 0.512616176692
Selulosa-Na 184.0 75.457 75.457 0.410092941 0.410092941353
MCA 94.5 72.927 72.927 0.771739154 0.771739154364
MCA-Na 84.0 0.013 0.013 0.000151489 0.00015148885
NaOH 40.0 16.387 16.387 0.409676347 0.409676347016
CMC 242.0 396.970 396.970 1.640371765 1.640371765414
Na-Glikolat 98.0 0.059 0.059 0.000605955 0.0006059554
NaCl 58.5 95.997 95.997 1.640977721 1.640977720814
H2O_x000D_ 18.0 457.323 457.323 25.40685071 25.40685071318
Total 980.997 1198.178 1198.178 30.793 30.793
30. Cyclone (CY-301)

Masuk Keluar Masuk
Komponen Mr
F47 F51 F52 N47
Selulosa 162 0.839 0.0084 0.8304 0.005178
Selulosa-Na 184 0.762 0.0076 0.7546 0.004142
MCA 94.497 0.737 0.0074 0.7293 0.007795
MCA-Na 84 0.000 0.0000 0.0001 0.000002
NaOH 40 0.166 0.0017 0.1639 0.004138
CMC 242 4.010 0.0401 3.9697 0.016569
Na-Glikolat 98 0.001 0.0000 0.0006 0.000006
NaCl 58.5 0.970 0.0097 0.9600 0.016576
H2O_x000D_ 18 4.619 0.0462 4.5732 0.256635
O2 32 67369.734 67369.7345 2105.304203
N2 14 110879.355 110879.3547 7919.953906
Total 1027 178261.19 178249.21 11.982 10025.57
1027 178261.19 178261.19 10025.57
31. Cyclone (CY-302)

Masuk Keluar Masuk
Komponen Mr
F51 F
53
F
54
N51
Selulosa 162 0.0084 0.0001 0.0083 0.0000518
Selulosa-Na 184 0.0076 0.0001 0.0075 0.0000414
MCA 94.5 0.0074 0.0001 0.0073 0.0000780
MCA-Na 84 0.0000 0.0000 0.0000 0.0000000
NaOH 40 0.0017 0.0000 0.0016 0.0000414
CMC 242 0.0401 0.0004 0.0397 0.0001657
Na-Glikolat 98 0.0000 0.0000 0.0000 0.0000001
NaCl 58.5 0.0097 0.0001 0.0096 0.0001658
H2O_x000D_ 18 0.0462 0.0005 0.0457 0.0025663
O2 32 67369.7345 67369.7345 2105.3042029
N2 14 110879.3547 110879.3547 7919.9539062
Total 1026.997 178249.210 178249.090 0.120 10025.261
32. Silo (TK-107)

Masuk Keluar
Komponen Mr
F
50
F52 F
54
F55
Selulosa 162 83.0438 0.8304 0.0083 83.8826
Selulosa-Na 184 75.4571 0.7546 0.0075 76.2192
MCA 94.497 72.9270 0.7293 0.0073 73.6636
MCA-Na 84 0.0127 0.0001 0.0000 0.0129
NaOH 40 16.3871 0.1639 0.0016 16.5526
CMC 242 396.9700 3.9697 0.0397 400.9794
Na-Glikolat 98 0.0594 0.0006 0.0000 0.0600
NaCl 58.5 95.9972 0.9600 0.0096 96.9668
H2O_x000D_ 18 457.3233 4.5732 0.0457 461.9423
Total 1198.1776 11.9818 0.1198 1210.2792
1210.2792 1210.2792
33. Rotary Dryer (RD-301)

Masuk Keluar
Komponen Mr
F55 F57 F58 F59
Selulosa 162 83.88 83.883
Selulosa-Na 184 76.22 76.219
MCA 94.497 73.66 73.664
MCA-Na 84 0.01 0.013
NaOH 40 16.55 16.553
CMC 242 400.98 400.979
Na-Glikolat 98 0.06 0.060
NaCl 58.5 96.97 96.967
H2O_x000D_ 18 461.94 452.703 9.239
O2 32 67487.73 67487.733
N2 14 111073.56 111073.560
Total 1210 178561 179013.997 757.576
179772 179772
34. Heater (E-301)

Komponen Mr F56 F57 N56 N57
Komponen Mr F56 F57 N56 N57
O2 32 67487.733 67487.733 2108.992 2108.992
N2 14 111073.560 111073.560 7933.826 7933.826
Total 46 178561 178561 10043 10043
36. Cooler (E-302)

Komponen Mr
F59 F60 N59 N50
Selulosa 162 83.883 83.883 0.5178 0.517793600076
Selulosa-Na 184 76.219 76.219 0.4142 0.414234880061
MCA 94.497 73.664 73.664 0.7795 0.779533719823
MCA-Na 84 0.013 0.013 0.0002 0.000153018887
NaOH 40 16.553 16.553 0.4138 0.413814078121
CMC 242 400.979 400.979 1.6569 1.656939520244
Na-Glikolat 98 0.060 0.060 0.0006 0.00061207555
NaCl 58.5 96.967 96.967 1.6576 1.6575515957943
H2O_x000D_ 18 9.239 9.239 0.5133 0.513269198108
Total 980.997 757.576 757.576 5.95390 5.95390
33. Ball mill (BM-301)

Komponen Mr
F60 F61 N50 N61
Selulosa 162 83.88 83.88 0.5177936 0.517793600076
Selulosa-Na 184 76.22 76.22 0.41423488 0.414234880061
MCA 94.497 73.66 73.66 0.77953372 0.779533719823
MCA-Na 84 0.01 0.01 0.000153019 0.000153018887
NaOH 40 16.55 16.55 0.413814078 0.413814078121
CMC 242 400.98 400.98 1.65693952 1.656939520244
Na-Glikolat 98 0.06 0.06 0.000612076 0.00061207555
NaCl 58.5 96.97 96.97 1.657551596 1.6575515957943
H2O_x000D_ 18 9.24 9.24 0.513269198 0.513269198108
Total 980.997 758 758 5.953901687 5.953901686664
37. Product Tank (TK-108)

Komponen Mr
F61 F62 N61 N62
Selulosa 162 83.88 83.88 0.51779 0.51779
Selulosa-Na 184 76.22 76.22 0.41423 0.41423
MCA 94.497 73.66 73.66 0.77953 0.77953
MCA-Na 84 0.01 0.01 0.00015 0.00015
NaOH 40 16.55 16.55 0.41381 0.41381
CMC 242 400.98 400.98 1.65694 1.65694
Na-Glikolat 98 0.06 0.06 0.00061 0.00061
NaCl 58.5 96.97 96.97 1.65755 1.65755
H2O_x000D_ 18 9.24 9.24 0.51327 0.51327
Total 980.9970 757.5758 757.5758 5.95390 5.95390
1. Roll crusher (RC-101)
Komponen Mr
F1 F2 N1 N2
Selulosa 162 413.934 413.934 2.555146199 2.55514619883
Hemiselulosa 132 206.967 206.967 1.567930622 1.56793062201
Lignin 150 206.967 206.967 1.379778947 1.379778947368
827.867 827.867 5.502855768 5.5028557682084
2. Vibrating screen (VS-101)

Masuk Keluar Masuk
Komponen Mr
F2 F3 F4 N2
Selulosa 162 413.934 20.697 393.237 2.55514619883
Hemiselulosa 132 206.967 10.348 196.619 1.56793062201
Lignin 150 206.967 10.348 196.619 1.379778947368
827.867 41.393 786.474 5.5028557682084
827.867 827.867 5.5028557682084
3. Silo 1 (TK-101)
Komponen Mr
F4 F5 N4 N5
Selulosa 162 393.237 393.237 2.427388889 2.427388888889
Hemiselulosa 132 196.619 196.619 1.489534091 1.489534090909
Lignin 150 196.619 196.619 1.31079 1.31079
786.474 786.474 5.22771298 5.227712979798
4. Steam Explosion Tank (V-101)

Masuk Keluar Masuk
Komponen Mr
5 6 7 5
Selulosa 162 393.237 393.237 2.427388888889
Hemi 132 196.619 58.986 1.489534090909
Hemi aq 132 137.633
Lignin 150 196.619 196.619 1.31079
H2O g 18 1258.358
H2O l 18 1572.948 314.590
786.474 1572.948 2359.422 5.227712979798
2359.422 2359.422 92.613712979798
5. Flash Tank (V-102)

Masuk Keluar Masuk
Komponen Mr
7 8 9 7
Selulosa 162 393.237 393.237 2.427388888889
Hemi 132 58.986 58.986 0.446860227273
Hemi aq 132 137.633 137.633 1.042673863636
Lignin 150 196.619 196.619 1.31079
H2O g 18 1258.358 1258.358 69.9088
H2O l 18 314.590 314.590 17.4772
2359.422 1101.064 1258.358 92.613712979798
2359.422 2359.422 92.613712979798
6. Heater (E-101)
Komponen Mr
F8 F10 N8 N10
Selulosa 162 393.237 393.237 2.427388889 2.427388888889
Hemi 132 58.986 58.986 0.446860227 0.446860227273
Hemi aq 132 137.633 137.633 1.042673864 1.042673863636
Lignin 150 196.619 196.619 1.31079 1.31079
H2O l 18 314.590 314.590 17.4772 17.4772
1101.064 1101.064 22.70491298 22.704912979798
7. Mixer (M-101)
Masuk Keluar Masuk
Komponen Mr
F12 F13 F14 N12
NaOH 40 1101.064 1101.064 27.52659
H2O 18 1101.064 3303.191 4404.254 61.1702
2202.127 3303.191 5505.318 88.69679
5505.318 5505.318 272.20739
8. Heater (E-102)
Komponen Mr
14 15 14 15
NaOH 40 1101.064 1101.064 27.52659 27.52659
H2O 18 4404.254 4404.254 244.6808 244.6808
5505.318 5505.318 272.20739 272.20739
9. Delignification Tank (DT-101)

Masuk Keluar Masuk
Komponen Mr
F8 F15 F16 N8
Selulosa 162 393.237 393.237 2.427388888889
Hemi 132 58.986 0.446860227273
Hemi aq 132 137.633 196.619 1.042673863636
Lig 150 196.619 9.831 1.31079
Lig aq 150 186.788
H2O l 18 314.590 4404.254 4718.844 17.4772
NaOH 40 1101.064 1101.064
1101.064 5505.318 6606.382 22.704912979798
6606.382 6606.382 294.912302979798
10. Expansion Valve (EV-101)
Komponen Mr
16 17 16 17
Selulosa 162 393.237 393.237 2.427388889 2.427388888889
Hemi aq 132 196.619 196.619 1.489534091 1.489534090909
Lig 150 9.831 9.831 0.0655395 0.0655395
Lig aq 150 186.788 186.788 1.2452505 1.2452505
H2O l 18 4718.844 4718.844 262.158 262.158
NaOH 40 1101.064 1101.064 27.52659 27.52659
6606.382 6606.382 294.912303 294.9123029798
11. Cooler (E-103)

Komponen Mr
17 18 17 18
Selulosa 162 393.237 393.237 2.427388889 2.427388888889
Hemi aq 132 196.619 196.619 1.489534091 1.489534090909
Lig 150 9.831 9.831 0.0655395 0.0655395
Lig aq 150 186.788 186.788 1.2452505 1.2452505
H2O l 18 4718.844 4718.844 262.158 262.158
NaOH 40 1101.064 1101.064 27.52659 27.52659
6606.382 6606.382 294.912303 294.9123029798
12. Heater (E-104)

Komponen Mr
19 20 19 20
H2O 18 13212.763 13212.763 734.0424 734.0424
13212.763 13212.763
13. Rotary Filter (RF-101)

Masuk Keluar
Komponen Mr
18 20 22 21
Selulosa 162 393.237 393.237
Hemi aq 132 196.619 196.619
Lig 150 9.831 9.831
Lig aq 150 186.788 186.788
H2O l 18 4718.844 13212.763 358.632 17572.975
NaOH 40 1101.064 1101.064
6606.382 13212.763 761.700 19057.445
19819.145 19819.145
14. Heater (E-105)

Komponen Mr
23 24 23 24
H2O2 34 228.510 228.510 6.720882962 6.720882961765
228.510 228.510
15. Heater (E-106)

Komponen Mr
25 26 25 26
H2O 18 2466.082 2466.082 137.0045419 137.0045418529
2466.082 2466.082
16. Bleaching Tank (BT-101)

Masuk Keluar
Komponen Mr
21 24 26 27
Selulosa 162 393.237 393.237
Lig 150 9.831
Lig aq 150 9.831
H2O l 18 358.632 2466.082 2824.714
H2O2 34 228.510 228.510
761.700 228.510 2466.082 3456.292
3456.292 3456.292
17. Heater (E-107)

Komponen Mr
28 29 28 29
H2O 18 6912.584 6912.584 384.032427 384.0324270059
6912.584 6912.584
18. Rotary Filter (RF-102)

Masuk Keluar
Komponen Mr
27 29 30 31
Selulosa 162 393.237 393.237
Lig aq 150 9.831 9.831
H2O l 18 2824.714 6912.584 9542.552 194.746
H2O2 34 228.510 228.510
3456.292 6912.584 9780.893 587.983
10368.876 10368.876
19. Rotary RD (RD-101)

Masuk Keluar
Komponen Mr
31 33 34 35
Selulosa 162 419.413 419.413
H2O 18 194.746 172.672 22.074
O2 32 16534.413 16534.413
N2 14 27212.889 27212.889
614.159 43747.302 43919.973 441.488
44361.461 44361.461
20. Heater (E-108)
Komponen Mr
32 33 32 33
O2 32 16534.413 16534.413 516.7004161 516.700416083
N2 14 27212.889 27212.889 1943.777756 1943.777755741
27212.889 27212.889
21. Cooler (E-201)

Komponen Mr
35 36 35 36
Selulosa 162 419.413 419.413 2.588970589 2.588970589352
H2O 18 22.074 22.074 1.22635449 1.226354489693
441.488 441.488 3.815325079 3.815325079046
22. Mixer (M-201)

Masuk Keluar Masuk
Komponen Mr
37 38 39 37
MCA 94.497 230.312 230.312 2.437240771745
H2O 18 2.326383245 62.63339504481 64.960 0.129243513585
232.6383245 62.63339504481 295.272 2.56648428533
295.272 295.272 6.04611734337457
23. Heater (E-202)

Komponen Mr
39 40 39 40
MCA 94.497 230.312 230.312 2.437240772 2.437240771745
H2O 18 64.960 64.960 3.608876572 3.608876571629
295.272 295.272 6.046117343 6.046117343375
24. Mixer (M-202)

Masuk Keluar Masuk
Komponen Mr
41 42 43 41
NaOH 40 165.732 165.732 4.143309311967
H2O 18 165.732 142.06 307.789 9.2073540265933
331.464745 142.0563192674 473.5210642 13.35066333856
473.521 473.521 21.2426810756403
25. Heater (E-203)

Masuk Keluar
Komponen Mr
43 44 43 44
NaOH 40 165.732 165.732 4.143309312 0.241352968052
H2O 18 307.789 307.789 17.09937176 17.09937176367
473.521 473.521 21.24268108 17.34072473173
Data Aliran 40 F40 =_x000D_ 295.271719497 kg/jam
MCA 0.78 230.3119412076 94.497 2.437
H2O_x000D_ 0.22 64.95977828933 18 3.608876572
6.046
+ 1000H2O
+ 21.934602825
+ 2.071176471
+ 24.00577929648
+ H2O
24.00577929648
+ 1.657706272
+ 25.66348556887
+ 1000NaCl
+ 1.656941
+ 1.656941177186
+ 1000NaCl
1.656941177186
+ 0.000612076
+ 1.6575533
F (kg/jam) N (kmol) F (kg/jam) N (kmol)

83.0438206241 0.512616176692 0.83882647095 0.00517794118
75.457101209 0.410092941353 0.762192941505 0.00414235294
72.9270348699 0.771739154364 0.736636715858 0.00779534499
0.01272506341 0.00015148885 0.000128535994 1.5301904E-06
16.3870538806 0.409676347016 0.165525796774 0.00413814492
396.96996723 1.640371765414 4.009797648789 0.01656941177
0.05938362924 0.0006059554 0.000599834639 6.1207616E-06
95.9971966676 1.640977720814 0.969668653208 0.01657553253
457.323312837 25.40685071318 4.619427402396 0.25663485569
1198.177596 30.793082 12.102804 0.311041
k Keluar
N44
F45
N45
F46
N
46
F47
83.043821 0.512616 0.838826
75.457101 0.410093 0.762193
72.927035 0.771739 0.736637
0.012725 0.000151 0.000129
4.143 16.387054 0.409676 0.165526
396.969967 1.640372 4.009798
0.059384 0.000606 0.000600
95.997197 1.640978 0.969669
17.0993717637 457.323313 25.406851 4.619427
67369.73 2105.304202911 67369.734
110879.35 7919.95390619 110879.355
21 178249 10025 1198 30.793 178261
179459.370 10056.362233 179459.370
Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Asumsi : 1. Tidak terjadi perubahan massa
Fungsi : Pematangan produk

Kondisi : T = 55 o
C_x000D_ kg/jam
t= 8 jam
Fungsi : Menurunkan suhu dari aging vessel

Keluar Fungsi : Memisahkan produk dari udara

N51 N52 Asumsi : 1. 1% produk terbawa udara
0.000052 0.005126
0.000041 0.004101
0.000078 0.007717
0.000000 0.000002
0.000041 0.004097
0.000166 0.016404
0.000000 0.000006
0.000166 0.016410
0.002566 0.254069
2105.304203
7919.953906
10025.26 0.308
10025.57
Keluar Fungsi : Memisahkan produk dari udara
N
53
N54
Asumsi : 1. 1% produk terbawa udara
0.0000005 0.0000513
0.0000004 0.0000410
0.0000008 0.0000772
0.0000000 0.0000000
0.0000004 0.0000410
0.0000017 0.0001640
0.0000000 0.0000001
0.0000017 0.0001641
0.0000257 0.0025407
2105.3042029
7919.9539062 0.0000000
10025.258 0.003
N50 N52 N54 N55

0.51261617669 0.005126161767 5.126161767E-05 0.51779360008
0.41009294135 0.004100929414 4.100929414E-05 0.41423488006
0.77173915436 0.007717391544 7.717391544E-05 0.77953371982
0.00015148885 1.5148885E-06 1.514888501E-08 0.00015301889
0.40967634702 0.00409676347 4.09676347E-05 0.41381407812
1.64037176541 0.016403717654 0.000164037177 1.65693952024
0.0006059554 6.059554E-06 6.059554004E-08 0.00061207555
1.64097772081 0.016409777208 0.000164097772 1.65755159579
25.4068507132 0.254068507132 0.002540685071 25.6634599054
30.7930822631 0.307930822631 0.003079308226 31.104092394
31.104092 31.104092394
N Fungsi : Mengurangi kadar air

55 57 58 59 Asumsi : 1. Efisiensi 95%
0.51779360008 0.51779360008
0.41423488006 0.41423488006
0.77953371982 0.77953371982
0.00015301889 0.00015301889
0.41381407812 0.41381407812
1.65693952024 1.65693952024
0.00061207555 0.00061207555
1.65755159579 1.65755159579
25.6634599054 25.15019070727 0.51326919811
2108.99165351 2108.99165351
7933.825744157 7933.825744157
31.1040923939 10042.81739767 10067.96758837 5.95390168666
10073.9214900613 10073.9214900613
Fungsi : Memperkecilkan ukuran prduk
Asumsi : tidak teriadi perubahan massa
52.9292760749
Fungsi : Mencacah Bagasse menjadi 2 mm
Asumsi : 1. Efisiensi Roll crusher 95%
2. Aliran F3 dimasukkan kembali kedalam roll crusher
asumsi F1 = 827.867
Feed = 786.474 kg bagasse
Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

N3 N4 Asumsi : 1. Aliran 3 adalah 5% dari aliran 2
0.12775730994 2.427388888889
0.0783965311 1.489534090909
0.06898894737 1.31079
0.27514278841 5.227712979798
5.5028557682084
Fungsi : Untuk menyimpan bagasse sementara

Asumsi : tidak ada perubahan massa
Masuk Keluar Fungsi : Melunakan serta mengurangi ukuran partikel dan kandungan hemise
6 7 Asumsi : 1. Aliran keluar tangki dalam keadaan saturated pada tekanan atmos
2.427388888889 2. Adiabatic expansion process
0.446860227273 3. 70% hemiselulosa terpisahkan dari bagasse
1.042673863636 4. Rasio saturated steam terhadap bagasse 1:2
1.31079
69.9088 y= 0.8000
87.386 17.4772 x= 0.2000
87.386 92.6137129798
92.613712979798 92.6137129798
Keluar Fungsi : Untuk melepaskan uap air sisa steam explotion tank
8 9 Asumsi : 1. semua uap terlepas ke aliran 9
2.42738888889
0.44686022727
1.04267386364
1.31079
69.9088
17.4772
22.7049129798 69.9088
92.613712979798
Fungsi : Untuk meningkatkan suhu keluaran dari flash tank (V-102) dari 100C menjadi 150C
Asumsi : 1. Menggunakan steam suhu
karena tidak ada perubahan massa masuk dan keluar maka nilai F8 = F10
Masuk Keluar Fungsi : Untuk mengencerkan NaOH 50% menjadi 20%

N13 N14 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 :
27.52659 F11= 1266.796
183.5106 244.6808 1266.796
183.5106 272.20739 2533.592
272.20739 272.20739
Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

karena tidak ada perubahan massa masuk dan keluar maka nilai F14 = F15
Masuk Keluar Fungsi : Untuk memecahkan ikatan lignin

N15 N16 T= 150
2.427388888889 P= 7
Asumsi : 1. rasio bagasse : cairan NaOH adalah 1:5
1.489534090909 2. menghilangkan lignin sebesar 95%
0.0655395 3. melarutkan hemiselulosa yang masih tersisa dari dalam bagasse
1.2452505
244.6808 262.158
27.52659 27.52659
272.20739 294.9123029798
294.912302979798 294.9123029798
Fungsi : Untuk menurunkan tekanan keluaran dari tangki delignifikasi (DT-101)
Asumsi: 1. Tidak ada perubahan masa
2. Tekanan diturunkan dari 7 menjadi 1 bar
Fungsi : Untuk mendinginkan keluaran dari tangki delignifikasi

Asumsi: 1. tidak ada perubahan massa
2. medinginkan dari suhu 150 ke suhu 80
Fungsi : Untuk meningkatkam suhu air pencucian yang akan masuk kedalam rotary filter 1
Asumsi: 1. Tidak ada perubahan massa
2. Meningkatkan suhu air dari 30 menjadi 80
3. Rasio air yang digunakan untuk pencucian 2 : 1
Masuk Keluar Fungsi : Untuk memisahkan selulosa dari sisa b

18 20 22 21 Asumsi : 1. Efisiensi rotary filter 98%
2.42738888889 2.427388888889 2. Rasio Air pencucian dan pulp 2 : 1
1.48953409091 1.48953409091
0.0655395 0.0655395
1.2452505 1.2452505
262.158 734.0424 19.924008 976.276392
27.52659 27.52659
294.91230298 734.0424 22.41693638889 1006.5377666
1028.9547029798 1028.9547029798
Fungsi : Untuk meningkatkan suhu H2O2 yang akan masuk kedalam tangki bleaching
Asumsi : 1. Tidak ada perubahan massa
2. Suhu dinaikkan dari 30 menjadi 80
3. H2O2 yang akan digunakan adalah 30% dari aliran 21
Fungsi : Untuk meningkatkan suhu air yang akan digunakan pada proses bleaching
Asumsi : 1. Tidal terjadi perubahan massa
Masuk Keluar Fungsi : Untuk menghilangkan sisa lignin dan si

21 24 26 27 Asumsi : 1. Melarutkan sisa lignin yang ada
2.42738888889 2.42738888889 2. Air yang digunakan untuk konsistens
0.0655395
0.0655395
19.924008 137.0045418529 156.928549853
6.720882961765 6.72088296176
22.4169363889 6.720882961765 137.0045418529 166.142361204
166.142361203595 166.1423612
Fungsi : Untuk meningkatkan suhu air pencucian yang akan digunakan pada rotary filter 2
Asumsi : 1. Tidal terjadi perubahan massa
3. Rasio air yang digunakan untuk pencucian 2 : 1
Masuk Keluar Fungsi : Untuk memisahkan selulosa dari sisa li

27 29 30 31 Asumsi : 1. Rasio Air pencucian dan pulp 2 : 1
2.42738888889 2.42738888889 355.868141331
0.0655395 0.0655395
156.928549853 384.0324270059 530.1417573216 10.8192195372
6.72088296176 6.720882961765
166.142361204 384.0324270059 536.9281797834 13.246608426
550.174788209477 550.174788209477
Masuk Keluar Fungsi : Untuk mengurangi kadar air

31 33 34 35 Asumsi : 1. Efisiensi rotary dryer 95%
2.58897058935 2.58897058935 2. Rasio Air pencucian dan pulp 2 : 1
10.8192195372 9.592865047483 1.22635448969
516.700416083 516.700416083
1943.777755741 1943.777755741 5714.706602
13.4081901265 2460.478171824 2470.071036871 3.815325079 34560.3685
2473.88636195027 2473.88636195027
Fungsi : Untuk meningkatkan suhu udara pengering
Fungsi : Untuk menurunkan suhu selulosa keluaran rotary dryer (RD-101)

2. Suhu diturunkan dari 90 menjadi 35
Masuk Keluar Fungsi : Untuk mengencerkan MCA 99% menjadi 78%

38 39 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 :
2.437240771745 F40 = 295.271719497
3.47963305804 3.608876571629
3.47963305804 6.046117343375
6.04611734337457 6.046117343375
Fungsi : Untuk meningkatkan suhu MCA

Masuk Keluar Fungsi : Untuk mengencerkan NaOH 50% menjadi 35%

42 43 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 :
4.143309311967 F41 = 473.521064225 kg/jam
7.89201773708 17.09937176367
7.89201773708 21.24268107564
21.2426810756403 21.24268107564
Fungsi : Untuk meningkatkan suhu NaOH

Data Aliran 44 F44 =_x000D_ 473.521064224799 kg
NaOH 0.35 165.732372 40 4.143
H2O_x000D_ 0.65 307.788692 18 17.099371764
21.243
N47
0.005178
0.004142
0.007795
0.000002
0.004138
0.016569
0.000006
0.016576
0.256635
2105.304203
7919.954
10025.569
10056.362233
gurangi kadar air
menuhi ukuran
n partikel dan kandungan hemiselulosa bagasse

an saturated pada tekanan atmosfer
m explotion tank
a delignifikasi : Bagasse adalah 5 : 1
asih tersisa dari dalam bagasse

k memisahkan selulosa dari sisa black liquor
siensi rotary filter 98%
sio Air pencucian dan pulp 2 : 1
k menghilangkan sisa lignin dan sisa blackliquor
elarutkan sisa lignin yang ada
yang digunakan untuk konsistensi pulp 15%
k memisahkan selulosa dari sisa lignin dan bleaching agent

k mengurangi kadar air

siensi rotary dryer 95%

Masuk
Komponen
x 36_x000D_
N36_x000D_
x 40_x000D_
Selulosa 0.68 2.5890
MCA 0.4031084
NaOH
Na-Glikolat
CMC
NaCl
H2O_x000D_ 0.32 1.2264 0.60
Total 1.0000 3.8153 1.0000

304
Masuk Keluar
N
40_x000D_
x44_x000D_ N44_x000D_
x 45_x000D_
N45_x000D_
x
46_x000D_
N46_x000D_
x47 N47
0.0169 0.5126162 0.0000 0.0051779
2.437 0.0254 0.7717392 0.0000 0.0077953
0.0135 0.4096763 0.0000 0.0041381

0.20 4.1433 0.0000 0.000606 0.0000 6.121E-06
0.0540 1.6403718 0.0000 0.0165694
0.0540 1.6409777 0.0000 0.0165755
3.6089 0.80 17.099372 0.8362 25.406851 0.0000 0.2566349
273.38467 0.0273 273.38467

6.0461 1.0000 21.2427 0.0000 273.385 1.0000 30.3828 0.0273 273.69
304 304
0
26. Rotary Reactor (R-101)
Reaksi Alkalisasi (C_6 H_10 O_5 )n+NaOH →(C_6 H_10 O_5 Na)+H_2 O
Reaksi Eterifikasi ClCH_2 COOH+NaOH →ClCH_2 COONa+H_2 O
(C_6 H_10 O_5 Na)+ClCH_2 COONa →C_5 H_7 O_4 CH_2 OCH_2 COONa+NaCl
Reaksi Samping ClCH_2 COONa+NaOH →OHCH_2 COONa+NaCl
Neraca Energi Total : Qumpan + Qreaksi = Qproduk + Qloss
a. Panas Umpan
T36 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
T44 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qumpan = 5408083.255308 + 147.3914273716 N O2
b. Panas Reaksi Standar

Reaksi beroperasi pada 35oC
Data ΔHf0 masing komponen pada 25oC (298 K) :
Komponen ΔHf (kj/mol) ΔHf (kj/kmol)

Selulosa -74.764 -74764
Selulosa-Na -161.075 -161075
MCA -435.2025997143 -435202.5997143
MCA-Na -59.888 -59888
NaOH -147.456 -147456
CMC -198.038 -198038
Na-Glikolat -30.954 -30954
NaCl -250.267 -250267
H2O -285 -285000
Tahap 1 : Alkalisasi Selulosa

(C_6 H_10 O_5 )+NaOH →(C_6 H_9 O_5 Na)+ H_2 O
T = 308.15 Tref = 298.15
Komponen Mr (kg/kmol) N (kmol) F (kg) A
Selulosa 162 3 419.4132354751
Selulosa-Na 94.497 0 0
NaOH 40 4.143309311967 165.7323724787 51.234
H2O 18 21.934602825 394.8228508499 92.053
ΔHR0 = Σ ΔHf produk - Σ ΔHf reaktan ΔHR =

ΔHR0 = -223.855 kJ/mol ΔHR =
ΔHR0 = -223855 kJ/kmol ΔHR =
Tahap 2 : Eterifikasi
ClCH_2 COOH+NaOH →ClCH_2 COONa+ H_2 O
T = 308.15 Tref = 298.15

MCA 94.497 2 230.3119412076 -55.75
MCA-Na 84 0 0
NaOH 40 2.072132840485 82.8853136194 51.234
H2O 18 24.00577929648 432.1040273366 92.053

ΔHR0 = 237770.5997143 kJ/kmol ΔHR =
ΔHR =
ClCH_2 COONa+(C_6 H_9 O_5 Na) →(C_8 H_11 O_7 Na)+ NaCl
T = 308.15 Tref = 298.15
Selulosa-Na 184 2 381.0964707527
MCA-Na 84 1.657706272388 139.2473268806
CMC 242 0 0
NaCl 58.5 0 0 41.293

ΔHR0 = -227342 kJ/kmol ΔHR =
ΔHR =
Tahap 3 : Reaksi samping

ClCH_2 COONa+NaOH →OHCH_2 COONa+NaCl
T = 308.15 Tref = 298.15
Komponen Mr (kg/mol) N (mol) F (kg) A
MCA-Na 84 0.000765095203 0.064267997012
Na-Glikolat 98 0 0
NaOH 40 0.414426568097 16.57706272388 51.234
NaCl 58.5 1.656941177186 96.93105886535 41.293

ΔHR0 = -73877 kj/jam ΔHR =
ΔHR =
c. Q Produk
(ΔH47)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Q produk = 3094827.720212 + 31260.88606275 +
d. Qloss
0,25 dari Qudara di aliran 48
Qloss = 0.25 X ( 147.3914273716
Qloss = 36.84785684289 N O2 + 36.341979849
Qumpan = 5408083.255308 + 147.3914273716 N O2

Qreaksi = -454376.4292635
Qproduk = 3094827.720212 + 31260.88606275 +
Qloss = 36.84785684289 N O2 + 136.715067051
Qumpan + Qreaksi = Qproduk + Qloss

5408083.25530776 + 147.3914273716 N O2 +
5408083.255308 +
6415317.83861796 = 6415317.838618
6415317.83861796 = 6415317.838618
Qloss = 365402.7531434 kJ/jam

Qudara 46 = 1.46E+06 kJ/jam
Qudara 48 = 2923826.479199 kJ/jam
Masuk
Komponen
36 40 44 45
Selulosa 5386094.414089
Selulosa-Na
MCA 3064
MCA-Na
NaOH 2376.126244103
Na-Glikolat
CMC
NaCl
H2O_x000D_ 925.236347386 2723 12900.80511482
O2 310303.7915184
N2 1151307
Total 5387019.650436 5786.673512727 15276.93135892 1461611.012574
Reaksi -454376.429263456
Qloss
6415317.8
Heater (E-204)
(ΔH46)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Aging Vessel (V-103)

T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cooler (E-205)
T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cyclone (CY-101)
Tref = 25 C = 298.15 K
T48 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Cyclone (CY-102)
Tref = 25 C = 298.15 K
T52 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Silo (TK-107)
Tref = 25 C = 298.15 K
T51 = 35 C = 308.15 K
T53 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Rotary Dryer (RD-102)

Tref = 25 C = 298.15 K
T57 = 35 C = 308.15 K
T59 = 150 C = 423.15 K
T60 = 100 C = 373.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865285
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)
Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 150-51
4.48169 = 99
99 = 4.48169
99 = 4.48169
327.56614 = 4.48169
TG1 = 73.1
= 346.2
d. Menentukan panas umpan masuk (Q57)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
e. menentukan panas produk keluar (Q60 dan Q61)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
90990.68043748 + 294.93738 N O2
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x ( 3737.70020
Qloss = 934.4250489227 N O2 + 912.0466488625
Panas masuk = Panas keluar
Q55 + Q57 = Q58 + Q59 + Qloss
3132445.99427 + 3737.70020 N O2 +
3132445.99427 + 3737.70020 N O2 +
3132445.994 +
17461.83072 N O2 -
39959301.2407794 39959301.24078
Q55 = 3132445.99 39959301.24

Q57= 36826855.24651 kj/jam 39959301.24
Q58 = 3019938.25600 kj/jam
Qloss = 9206713.811626 kj/jam
Masuk Keluar
Komponen
55 57 58 59
Selulosa 1077217.80560 3770262.32
Selulosa-Na 830458.08755 2906603.31
MCA 979.97178 3634.05
MCA-Na 0.09424 0.33
NaOH 1201757.46427 4206151.12
CMC 1837.71162 16841713.21
Na-Glikolat 0.67885 2.38
NaCl 832.10674 2930.42
H2O_x000D_ 19362.07361 90990.68044 1352.04
O2 7882778.516 622020.48057
N2 28944076.730 2306927.095
3132445.994 36826855.247 3019938.256 27732649.173
Qloss 9206713.81163
Total 39959301.241 39959301.241
Heater (E-301)
Tref = 25 C = 298.15 K
Komponen A B C D
Komponen A B C D
O2 29.526 -0.0088999 0.000038083 -3.2629E-08

N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Masuk Keluar
Komponen
58 59
Udara 1464171.031 36826855.247
Qsteam 35362684.215
36826855.247 36826855.247
Cooler (E-302)
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Masuk Keluar
Komponen
59 60
Selulosa 3770262.320 1077217.806
Selulosa-Na 2906603.306 25590565.968
MCA 3634.048 979.972
MCA-Na 0.330 2.904
NaOH 835.625 237.316
CMC 16841713.213 148279255.042
Na-Glikolat 2.376 20.919
NaCl 2930.419 832.107
H2O_x000D_ 1352.036 387.241
23527333.673 174949499.274
Qsteam 151422165.601
total 174949499.274 174949499.274
Ball Mill (BM-301)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Roll Crusher (RC-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Komponen Cp (kj/kg) 1 2
N (kmol) NCpdT N (kmol)
Selulosa 1040200 2.55514619883 2657863.076023 2.55514619883
Hemiselulosa 147533.75 1.56793062201 231322.6844049 1.56793062201
Lignin 10022.5 1.379778947368 13828.8345 1.379778947368
2903014.594928
Vibrating Screen (VS-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Selulosa 1040200 2.55514619883 2657863.076023 0.127757309942
Hemiselulosa 147533.75 1.56793062201 231322.6844049 0.0783965311
Lignin 10022.5 1.379778947368 13828.8345 0.068988947368
2903014.594928
2903014.594928
Silo 1 (TK-101)
Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Selulosa 1040200 2.427388888889 2524969.922222 2.427388888889
Hemiselulosa 147533.75 1.489534090909 219756.5501847 1.489534090909
Lignin 10022.5 1.31079 13137.392775 1.31079
2757863.865182
Steam Explosion Tank (V-101)

Data Steam
P= 1002.7 kPa P=
T6 =_x000D_ 453.15 K T7 =_x000D_
Vspecific =_x000D_ 193.8 cm3/g Vspecific =_x000D_
Hvap = 2776.3 kj/kg Hvap =
Hliq = 763.1 kj/kg Hliq =
Q= 0 diasumikan proses adibatik

r= 0 diasumsikan tidak ada panas tergenerasi
T =_x000D_
5
303.15 K
T6=_x000D_ 453.15 K
T7=_x000D_ 373.15 diasumsikan aliran keluar proses dalam keadaan setimbang pada tekanan atmos
T = _x000D_
ref
298.15 K
1. Menghitung Usaha (W)

𝑊=−∫_(𝑣_1^𝑡)^(
𝑣_2^𝑡)▒ 〖𝑃 P1.3 hal 9 van ness et al (2005) introduction of chemical engineering thermody
𝑑𝑉 ^𝑡 〗
Adiabatic expansion process berlaku persamaan 𝑃𝑉^𝛾=𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
γ= 1.32
Vin = 2631.542004 m3/jam
Vout = 304.8373224 m3/jam
K = 3313500.572382 kJ/m3
W= -827438.6720435 kj/jam 37742330.16
2. Menghitung Entalpi Aliran Input
Komponen Cp m m.Cp.dT (kJ/kg)
Selulosa 6420.987654321 393.237 2524969.92

Hemiselulosa 1117.679924242 196.6185 219756.55
Lignin 66.81666666667 196.6185 13137.3928
H2O 4366976
7124839.398
W+ 〖∆ H 〗 _input− 〖∆ H 〗 _output =0
W+ 〖∆ H 〗 _input−( 〖∆ H 〗 _Selulosa+ 〖∆ H 〗 _Hemiselulosa+ 〖∆ H 〗 _Hemiselulosa(aq) +
〖∆ 〖
W+ H〗∆ H_Lignin+ 〖∆〖
〗 _input−( H∆〗H_(H_2 O(g) )+ 〖〖
〗 _Selulosa+ ∆∆HH〗〗_(H_2 O(l))) =0
_Hemiselulosa+
〖∆ H 〗 _(Hemiselulosa(aq))+ 〖∆ H 〗 _Lignin) = 〖∆ H 〗 _(H_2 O)
∆H2O = 2224.6 kj/jam
4. Menghitung fraksi uap dan cair dari steam

y= fraksi uap
P6.73a hal 219 van ness et al (2005) introdu
y= 0.8000
1-y= 0.2000
3367367.0784 kj/jam
131844.50136 kj/jam
Masuk Keluar
Komponen 5 6 7
Q Q Q
Selulosa 2524969.9222 37874548.833
Hemiselulosa 219756.5502 988904.4758
Hemiselulosa (aq) 2307443.7769
Lignin 13137.3928 197060.8916
H2O (g) 4366975.5324 3367367.0784
H2O (l) 131844.50136
2757864 4366975.5 44867170
W 37742330.16
44867169.56 44867169.56
Cp (kj/kg)
Flash Tank (V-102)
Tref = 25 C = 298.15 K
T7 = 100 C = 373.15 K
T8= 100 C = 373.15 K
T9 = 100 C = 373.15 K
7
Komponen Cp
N N.Cp.dT
Selulosa 15603000 2.427388888889 37874548.833
Hemiselulosa 2213006.25 0.446860227273 988904.476
Hemiselulosa (aq) 2213006.25 1.042673863636 2307443.777
Lignin 150337.5 1.31079 197060.892
H2O (g) 3367367.078
H2O (l) 131844.501
44867169.557
44867169.557
Heater (E-101)
Tref = 25 C = 298.15 K
T8 = 100 C = 373.15 K
T10= 150 C = 423.15 K
Masuk Keluar
Komponen 8 10
Cp N N.Cp.dT Cp
Selulosa 15603000 2.427388888889 37874548.83 26005000
Hemiselulosa 2213006.25 0.446860227273 988904.4758 3688343.75
Hemiselulosa (aq) 2213006.25 1.042673863636 2307443.7769 3688343.75
Lignin 150337.5 1.31079 197060.8916 250562.5
H2O 131844.5014
41499802.4791 69078441.1309071
Qsteam 27578638.6518
69078441.131
Mixer (M-101)
Tref = 25 C = 298.15 K T13= 30 C =
T12 = 30 C = 303.15 K T14= 30 C =
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Heater (E-102)
Tref = 25 C = 298.15 K
T14 = 30 C = 303.15 K
T15= 150 C = 423.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Delignification Tank (DT-101)

Tref = 25 C = 298.15 K
T10 = 150 C = 423.15 K
T15= 150 C = 423.15 K
T16= 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Expansion Valve (EV-101)

Tref = 25 C = 298.15 K
T16 = 150 C = 423.15 K
T17 = 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Cooler (E-103)
Tref = 25 C = 298.15 K
T17 = 150 C = 423.15 K
T8 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Qcw
Heater (E-104)
Tref = 25 C = 298.15 K
T19 = 30 C = 303.15 K
T20 = 80 C = 353.15 K
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469

Qsteam
Rotary Filter (RF-101)

Tref = 25 C = 298.15 K
T18 = 80 C = 353.15 K
T20 = 80 C = 353.15 K
T21 = 80 C = 353.15 K
T22 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemiselulosa(aq)
Lgnin
Lignin (aq)
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Heater (E-105)
Tref = 25 C = 298.15 K
T23 = 30 C = 303.15 K
T24 = 80 C = 353.15 K
Komponen A B C D
H2O2 -15.248 0.67693 -0.0014948 0.0000012018

Qsteam
Bleaching Tank (BT-101)

Tref = 25 C = 298.15 K
T21 = 80 C = 353.15 K
T24 = 80 C = 353.15 K
T26 = 80 C = 353.15 K
T27 = 80 C = 353.15 K
Komponen A B C D
Komponen A B C D
Selulosa
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
H2O2 -15.248 0.67693 -0.0014948 0.0000012018
Heater (E-106)
Tref = 25 C = 298.15 K
T25 = 30 C = 303.15 K
T26 = 80 C = 353.15 K
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Heater (E-107)
Tref = 25 C = 298.15 K
T28 = 30 C = 303.15 K
T29 = 80 C = 353.15 K
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Rotary Filter (RF-102)

Tref = 25 C = 298.15 K
T27 = 80 C = 353.15 K
T29 = 80 C = 353.15 K
T30 = 80 C = 353.15 K
T31 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Lignin (aq)
H2O (l) 92.053 -0.039953 -0.00021103 0.00000053469
H2O2 -15.248 0.67693 -0.0014948 0.0000012018
Rotary Dryer (RD-101)
Tref = 25 C = 298.15 K
T31 = 80 C = 353.15 K
T33 = 200 C = 473.15 K
T35 = 90 C = 363.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865285
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)
Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 200-51
4.48169 = 149
149 = 4.48169
149 = 4.48169
377.56614 = 4.48169
TG1 = 84.2
= 357.4
d. Menentukan panas umpan masuk

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qumpan masuk = 29657205.349 + 5612.45127847
e. menentukan panas produk keluar

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qproduk = 31954.3182096 + 1825.70095
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x ( 5612.45127847
Qloss = 1403.112819618 N O2 + 1290.957471715
Panas masuk = Panas keluar

Q31 + Q33 = Q34 + Q35 + Qloss
29657205.34858 + 5612.45128 N O2 +
29657205.34858 + 5612.45128 N O2 +
29657205.349 +
25038.28752 -
Q33= 12937293.57934 kj/jam
Q34= 4346122.107872 kj/jam
Qloss = 3234323.394835 kj/jam
Heater (E-108)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 200 C = 473.15 K
Komponen A B C D
O2 29.526 -0.0088999 0.000038083 -3.2629E-08

N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qsteam
Cooler (E-201)
Tref = 25 C = 298.15 K
T36 = 90 C = 363.15 K
T37 = 35 C = 308.15 K
Komponen A B C D
Selulosa
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
Qcw
Heater (E-202)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 35 C = 308.15 K
Komponen A B C D
MCA -55.75 0.59859

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
heater (E-203)
Tref = 25 C = 298.15 K
T44 = 30 C = 303.15 K
T45 = 35 C = 308.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O l 92.053 -0.039953 -0.00021103 0.00000053469
Qcw
Mixer (M-201)
Tref = 25 C = 298.15 K
T37 = 30 C = 303.15 K
T38= 30 C = 303.15 K
T39= 30 C = 303.15 K
Komponen A B C D
MCA -55.75 0.59859

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Mixer (103)
Tref = 25 C = 298.15 K
T41 = 30 C = 303.15 K
T42= 30 C = 303.15 K
T43= 30 C = 303.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Total steam = 80443.566896 kg/jam

80.44356689617 ton/jam
Total cw = 5026525.324134 kg/jam
5026.525324134 ton/jam
Total udara = 400557.68 kg/jam
400.5576844054 ton/jam
O
_2 OCH_2 COONa+NaCl
T40 =
Tref =
Cp (kJ/kmol ) N (kmol) Q (kj/jam) Komponen
2080400 2.58897 5386094.41408872 MCA
754.460765759055 1 925.236347386016 H2O
5387019.6504361
T45 =
Tref =
Cp (J/mol ) N (kmol) Q (kj/jam) Komponen
573.485121480108 4.143309311967 2376.12624410305 O2
754.460765759055 17.099371763673 12900.8051148197 N2
15276.9313589228
+ 145.36792 N N2
B C D Cp (kJ/kmol) ΔH (kj/jam)
2080400 5386094.4140887
2004800 0
0.013088 0.000023359 573.485121480108 2376.1262441031
-0.039953 -0.00021103 0.00000053469 754.460765759055 16548.797243967
4086527.94588724 5405019.3375768
ΔHR0 + [ΔH produk - ΔH reaktan]

-223855 + -75419.024355721
-299274.02435572 kJ/kmol
0.59859 1257.125585 3063.9177309662
61.59 0
0.013088 0.000023359 573.485121480108 1188.3373537485
-0.039953 -0.00021103 0.00000053469 754.460765759055 18111.418630664
2646.66147223916 22363.673715378

237770.599714255 + -1014.5599407211
236756.039773534 kJ/kmol
200480 4152294.590027
61.59 1020.9812931638
290410 0
0.033607 -0.000013927 502.009557710092 0
491453.59955771 4153315.5713201

-227342 + 90370.4195577101
-136971.58044229
B C D Cp (J/kg) ΔH (kj/jam)
61.59 0.471222135236
110.91 0
0.013088 0.000023359 573.485121480108 237.6674707497
0.033607 -0.000013927 502.009557710092 831.80030751055
1247.9946791902 1069.9390003955

-73877 + -22.155563770017
-73899.15556377
(ΔH48)
T=
Tref =
Cp (J/kg) N (kmol) Q (kj/jam) Komponen
208040 0.512616 1066446.69398957 Selulosa
200480 0.410093 822154.328825334 Selulosa-Na
1257.125585 0.771739 970.173035896816 MCA
61.59 0.000151 0.09330198277673 MCA-Na
290410 0.409676 1189741.07936813 CMC
110.91 1.640372 1819.33632502031 Na-Glikolat
754.460765759055 0.000606 0.45716957540233 H2O
573.485121480108 1.640978 941.076307567213 NaOH
502.009557710092 25.406851 12754.4818893284 NaCl
3094827.7202124 O2
N2
294.937383716924 N O2 + 290.771081870133 N N2
N O2 + 145.36792 N N2 )
N N2
+ 546.86026820407 N O2
294.937383716924 N O2 + 1093.85311751145 N O2
N O2
546.860268204066 N O2 + -454376.429263456 =
694.251695575628 N O2 + -454376.429263456 =
4953706.8260443 + 694.251695575628 N O2 =
694.251695575628 N O2 =
-868.10172954666 N O2 =
N O2 =
F O2 =
F O2 =
N N2 =
F N2 =
F N2 =
Udara =
=
Keluar
46 47
1066446.69398957 10772.188828178
822154.328825334 8304.5891800539
970.173035896816 9.7997276353214
0.09330198277673 0.0009424442705
1189741.07936813 12017.586660284
1819.33632502031 18.377134596165
0.45716957540233 0.004617874499
941.076307567213 9.5058212885577
12754.4818893284 128.83315039726
620932.91353491
2302893.5656645
3094827.7202124 2955087.3652622
365402.753143416
6415317.839
(ΔH48)
T=
Tref =
Cp (J/mol.K) N (kmol) Q (kj/jam) Komponen
2080400 0.51 1066446.69 Selulosa
2004800 0.41 822154.33 Selulosa-Na
1257.13 0.77 970.17 MCA
615.90 0.00 0.09 MCA-Na
2904100 0.41 1189741.08 CMC
1109.10 1.64 1819.34 Na-Glikolat
754.46 0.00 0.46 H2O
573.49 1.64 941.08 NaOH
502.01 25.41 12754.48 NaCl
3094827.72
T=
Tref =
Cp N (kmol) Q (kj/jam) Komponen
6241200 0.5126 3199340.1 Selulosa
6014400 0.4101 2466463.0 Selulosa-Na
3950.9538 0.7717 3049.1 MCA
1847.7000 0.0002 0.3 MCA-Na
1728.7473 0.4097 708.2 NaOH
8712300 1.6404 14291410.9 CMC
3327.3000 0.0006 2.0 Na-Glikolat
1513.5080 1.6410 2483.6 NaCl
2258.6647 25.4069 57385.6 H2O_x000D_
20020842.818
T=
Tref =
Cp (J/kg K) N (kmol) Q (kj/jam) Komponen
6241200 0.5126161766918 3199340.0819687 Selulosa
6014400 0.4100929413534 2466462.986476 Selulosa-Na
3950.9538 0.7717391543637 3049.10570981361 MCA
1847.7 0.0001514888501 0.2799059483302 MCA-Na
1728.7473 0.4096763470156 708.226890227744 NaOH
8712300 1.6403717654137 14291410.9318136 CMC
3327.3 0.0006059554004 2.01619540375403 Na-Glikolat
1513.5080 1.6409777208141 2483.6328362354 NaCl
2258.6647 25.406850713177 57385.5561976736 H2O_x000D_
20020842.8180
T52 = 35 C =
T53 = 35 C =
47 51
E
Cp N (kmol) Q (kj/jam) Cp
2080400 0.0051779411787 10772.1888281774 2080400
2004800 0.00414235294296 8304.58918005388 2004800
1257.125585 0.00779534499357 9.79972763532138 1257.125585
615.9 1.5301904051E-06 0.0009424442704721 615.9
573.48512148011 0.00413814491935 2.37316454177569 573.48512148011
2904100 0.01656941177186 48119.228726645 2904100
1109.1 6.1207616202E-06 0.0067885367129765 1109.1
502.00955771009 0.01657553253348 8.32107575593928 502.00955771009
754.46076575906 0.25663485568866 193.620929743329 754.46076575906
8.8607E-12 294.93738371693 2105.3042029113 620932.913534904 294.93738371693
2.5935E-13 290.77108187013 7919.95390619013 2302893.56566449 290.77108187013
2991236.60856293
2991236.60856293
T54 = 35 C =
T55 = 35 C =
51 53
E
2080400 5.1779411787E-05 107.7218883 2080400.00
2004800 4.142352943E-05 83.0458918 2004800.00
1257.125585 7.7953449936E-05 0.0979973 1257.13
615.9 1.5301904051E-08 0.0000094 615.90
573.48512148011 4.1381449193E-05 0.0237316 573.49
2904100 0.00016569411772 481.1922873 2904100.00
1109.1 6.1207616202E-08 0.0000679 1109.10
502.00955771009 0.00016575532533 0.0832108 502.01
754.46076575906 0.00256634855689 1.9362093 754.46
8.8607E-12 294.93738371693 2105.3042029113 620932.914 294.94
2.5935E-13 290.77108187013 7919.95390619013 2302893.566 290.77
2924500.58
2924500.58
T55 = 35 C = 308.15
T56 = 35 C = 308.15
50 52
Cp N (kmol) Q (kj/jam) Cp N (kmol)
2080400 0.513 1066446.694 2080400.00 0.00513
2004800 0.410 822154.329 2004800.00 0.00410
1257.125585 0.772 970.173 1257.13 0.00772
615.9 0.000 0.093 615.90 0.00000
573.485121480108 0.410 234.943 573.49 0.00410
2904100 1.640 4763803.644 2904100.00 0.01640
1109.1 0.001 0.672 1109.10 0.00001
502.009557710092 1.641 823.786 502.01 0.01641
754.460765759055 25.407 19168.472 754.46 0.25407
6673602.807
oplis 1993:857)
y's 7th ed gambar 12-3 hal 12-6)
C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T57 = 35 C = 308.15 K T59 = 150C =

55 57
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
2080400 0.51779 1077217.81 26005000
2004800 0.41423 830458.09 25060000
1257.12559 0.77953 979.97 20016.43544
615.90 0.00015 0.09 7698.75000
2904100 0.41381 1201757.46 36301250
1109.10 1.65694 1837.71 36301250.00
1109.10000 0.00061 0.68 13863.75000
502.00956 1.65755 832.11 6447.97094
754.46077 25.66346 19362.07 9469.49572
8.8607E-12 3737.70020
2.5935E-13 3648.18660
3132445.99
T60=73,1C = 346.25 K T61 = 60 C =

58 59
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
7281400
7016800
4661.82267
2155.65000
10164350
10164350
3881.85000
1767.92043
3617.89227 25.1501907072726 90990.6804374824 2634.16638
8.8607E-12 294.93738 ? ?
2.5935E-13 290.77108 ? ?
+ 290.77108 N N2
N O2 + 3648.18660 N N2 )
N N2
3648.18660 N N2 = 90990.6804374824 +
13724.13053 N O2 = 90990.6804374824 +
17461.831 N O2 = 5754.248 N O2
5754.248 N O2 = 27823639.854 -
11707.583 N O2 = 24691193.859
N O2 = 2108.992 kmol/jam
F O2 = 67487.733 kg/jam
F O2 = 67.488 ton/jam
N N2 = 7933.826 kmol/jam
F N2 = 111073.560 kg/jam
F N2 = 111.074 ton/jam
Udara = 178561.293 kg/jam

udara = 178.561 ton/jam
T56 = 30 C = 303.15 K T57 = 150C =

56 57
E
E
8.8607E-12 147.39142737156 2108.99165351015 310847.290125571 3737.7001956907
2.5935E-13 145.36791939602 7933.82574415724 1153323.7412787 3648.18659545
1464171.03140
T59 = 60 C = 333.15 K T60 = 35C = 308.15

59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kmol)
7281400 0.51779 3770262.31960 2080400 0.51779
7016800 0.41423 2906603.30641 61777912 0.41423
4661.82267 0.77953 3634.04797 1257.12559 0.77953
2155.65 0.00015 0.32986 18978.96 0.00015
2019.32444 0.41381 835.62488 573.48512 0.41381
10164350 1.65694 16841713.21260 89489842 1.65694
3881.85 0.00061 2.37599 34176.92 0.00061
1767.92043 1.65755 2930.41933 502.00956 1.65755
2634.16638 0.51327 1352.03646 754.46077 0.51327
23527333.67
T60 = 60 C = 308.15 K T61 = 35C = 308.15

59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kg)
2080400 0.51779 1077217.80560 2080400 0.51779
2004800 0.41423 830458.08755 2004800 0.41423
1257.12559 0.77953 979.97178 1257.12559 0.77953
615.90 0.00015 0.09424 615.90 0.00015
573.48512 0.41381 237.31622 573.48512 0.41381
2904100 1.65694 4811918.06074 2904100 1.65694
1109.10 0.00061 0.67885 1109.10 0.00061
502.00956 1.65755 832.10674 502.00956 1.65755
754.46077 0.51327 387.24147 754.46077 0.51327
6722031.36
K
Keluar
2
NCpdT
2657863.07602339
231322.684404904
13828.8345
2903014.5949283
K
Keluar
3 4
NCpdT N (kmol) NCpdT
132893.15380117 2.4273888888889 2524969.92222222
11566.1342202452 1.4895340909091 219756.550184659
691.441725 1.31079 13137.392775
145150.729746415 2757863.86518188
2903014.5949283
K
Keluar
5
NCpdT
2524969.92222222
219756.550184659
13137.392775
2757863.86518188
101.3 kPa
373.15 K
1673 cm3/g
2676 kj/kg
419.1 kj/kg
eadaan setimbang pada tekanan atmosfer
tion of chemical engineering thermodynamic'
P3.29c hal 75 van ness et al (2005) introduction of chemical engineering thermodynamic'
3. Menghitung Entalpi Aliran output
Komponen Cp m N.Cp.dT
Selulosa 96314.814814815 393.237 37874548.8333

Hemiselulosa 16765.198863636 58.98555 988904.4758
Hemiselulosa(aq) 16765.198863636 137.63295 2307443.7769
Lignin 1002.25 196.6185 197060.8916
H2O (g) 1258.3584 3367367.0784
H2O (l) 314.5896 131844.5014
44867169.5575
〗 _Hemiselulosa(aq) +
37742330.1599
a hal 219 van ness et al (2005) introduction of chemical engineering thermodynamic'
8 9
Cp Cp
N N.Cp.dT N
15603000 2.4273888888889 37874548.8333
2213006.25 0.4468602272727 988904.4758
2213006.25 1.0426738636364 2307443.7769
150337.5 1.31079 197060.8916
131844.5014
41499802.4791
T steam = 170
P steam =
Keluar Q (kj/jam) Hv (kJ/kg)
10 27578638.6518 2767.1
N N.Cp.dT
2.42738888888889 63124248.055556
0.44686022727273 1648174.126385
1.04267386363636 3845739.6282315
1.31079 328434.819375
131844.5014
69078441.1309071
69078441.1
303.15 K
303.15 K
Masuk
12 13
Cp N N.Cp.dT Cp N
286.401928718804 27.52659 7883.66846705175 286.401928718804
377.486381588157 61.1702 23090.9174590239 377.486381588157 183.5106
30974.5859260757
Masuk Keluar
14 15
Cp N N.Cp.dT Cp N
286.401928718804 27.52659 7883.66846705175 7377.8588557201 27.52659
377.486381588157 244.6808 92363.6698360956 9469.49571881325 244.6808
2419843.74557193
2520091.08387508
Masuk
10 15
Cp N N.Cp.dT Cp N
26005000 2.4273888888889 63124248.0555556
3688343.75 0.4468602272727 1648174.12638494
3688343.75 1.0426738636364 3845739.62823153
250562.5 1.31079 328434.819375
131844.5014 9469.49571881325 244.6808

7377.8588557201 27.52659
69078441.1309071
Masuk Keluar
16 17
Cp N N.Cp.dT Cp N
26005000 2.4273888888889 63124248.0555556 26005000 2.4273888888889
3688343.75 1.4895340909091 5493913.75461648 3688343.75 1.4895340909091
250562.5 0.0655395 16421.74096875 250562.5 0.0655395
250562.5 1.2452505 312013.07840625 250562.5 1.2452505
2448848.2894358
7377.8588557201 27.52659 203087.295799277 7377.8588557201 27.52659
71598532.2147821
Masuk Keluar
17 18
Cp N N.Cp.dT Cp N
26005000 2.427388888888963124248.0555556 11442200 2.4273888888889
3688343.75 1.48953409090915493913.75461648 1622871.25 1.4895340909091
250562.5 0.0655395 16421.74096875 110247.5 0.0655395
250562.5 1.2452505 312013.07840625 110247.5 1.2452505
2448848.2894358 4136.37124570978 262.158
7377.8588557201 27.52659 203087.295799277 3188.85429699435 27.52659
71598532.2147821 31508663.6148366
40089868.5999455
71598532.2147821
Masuk Keluar
19 20
Cp N N.Cp.dT Cp N
377.486381588157 734.0424 277091.009508287 4136.37124570978 734.0424
2759180.86698351
3036271.87649
Masuk
18 20
Cp N N.Cp.dT Cp N
11442200 2.4273888888889 27774669.1444444
1622871.25 1.4895340909091 2417322.05203125
110247.5 0.0655395 7225.56602625
110247.5 1.2452505 137285.75449875
4136.37124570978 262.158 1084382.81303278 4136.37124570978 734.0424
3188.85429699435 27.52659 87778.2848031016
31508663.6148366
Masuk Keluar
23 24
Cp N N.Cp.dT Cp N
429.072591260699 6.7208829617647 2883.74666796427 4845.31001 6.7208829617647
29681.0148505524
32564.7615185167
Masuk
22 24
Cp N N.Cp.dT Cp N
11442200 2.4273888888889 27774669.1444444
110247.5 0.0655395 7225.56602625
4136.37124570978 19.924008 82413.0937904915

4845.31001414227 6.7208829617647
27864307.8042612
Masuk Keluar
25 26
Cp N N.Cp.dT Cp N
377.486381588157 137.00454185294 51717.3487652101 4136.37124570978 137.00454185294
514984.298686937
566701.6475
Masuk Keluar
28 29
Cp N N.Cp.dT Cp N
377.486381588157 384.03242700588 144967.011282969 4136.37124570978 384.03242700588
1443533.6772043
1588500.68848727
Masuk
27 29
Cp N N.Cp.dT Cp N
11442200 2.4273888888889 27774669.1444444
110247.5 0.0655395 7225.56602625
4136.37124570978 156.92854985294 649114.741242639 4136.37124570978 384.03242700588
4845.31001414227 6.7208829617647 32564.7615185167
28463574.2132319
oplis 1993:857)
y's 7th ed gambar 12-3 hal 12-6)
C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T31 = 80 C = 353.15 K T33 = 200C =

31 33
E
Cp.dT N N.Cp.dT Cp.dT
11442200 2.58897 29623519.27749
3113.53984 10.81922 33686.07109
8.8607E-12 5612.4512784701
2.5935E-13 5163.8298868604
29657205.34858
N O2 + 5163.82989 N N2
T34=84,2C = 357.4 K T35 = 90 C =

34 35
E
13522600
3331.05053 9.59286504748324 31954.318209601 3620.2694043095
8.8607E-12 1825.70095 ? ?
2.5935E-13 1734.16294 ? ?
N O2 + 1734.16294 N N2 +
N O2 + 5163.82988686043 N N2 )
N N2
5163.82989 N N2 = 31954.318209601 +
19425.83624 N O2 = 31954.318 +
25038.28752 N O2 = 35046007.743 +
14609.02865 N O2 = 35046007.743 -
10429.25886 N O2 = 5388802.395
N O2 = 516.700 kmol/jam
F O2 = 16534.413 kg/jam
= 16.534 ton/jam
N N2 = 1943.778 kmol/jam
F N2 = 27212.8885803706 kg/jam
= 27.2128885803706 ton/jam
udara = 43747.302 kg/jam
= 43.7473018950262 ton/jam
Masuk Keluar
E 32 33
8.8607E-12 151.82534 516.700416082986 78448.2178790656 5612.4512784701
2.5935E-13 145.95382 1943.77775574076 283701.783894248 5163.8298868604
9753635.88461437
10037337.6685086
Masuk Keluar
35 36
Cp.dT N N.Cp.dT Cp.dT N
75549427.85 2.5889705893524 195595246.746051 395427.319135802 2.5889705893524
4888.78746034047 1.2263544896932 5995.38645114454 754.460765759055 1.2263544896932
195601242.132502
194576567.196685
195601242.132502
Masuk Keluar
39 40
621.0804175 2.4372407717453 1513.72251606358 1257.125585 2.4372407717453
377.486381588157 3.6088765716293 1362.30175862261 754.460765759055 3.6088765716293
2910.64923804129
5786.67351272749
Masuk Keluar
43 44
286.401928718804 4.143309311967 1186.65177822593 573.485121480108 4.143309311967
377.486381588157 17.099371763673 6454.77997449974 754.460765759055 17.099371763673
7635.49960619709
15276.9313589228
Masuk
37 38
Cp (kJ/kg) N mCpdT Cp (kJ/kg) N
621.0804175 2.4372407717453 1513.72251606358
377.486381588157 0.1292435135845 48.7876662867603 377.486381588157 3.4796330580448
1562.51018235034
Masuk
41 42
Cp (kJ/kg) N mCpdT Cp (kJ/kg) m (kg)
286.401928718804 4.143309311967 1186.65177822593
377.486381588157 9.2073540265933 3475.65075549986 377.486381588157 7.89
4662.30253372578
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/mol.K) N (kmol)
-55.75 5.99E-01 1257.126 2.43724
92.053 -0.039953 -0.00021103 0.00000053469 754.461 3.60888
30 C = 303.15 K
25 C = 298.15 K
A B C D E Cp (kJ/kmol)
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 147.39143
29.342 -0.0035395 0.000010076 -4.3116E-09 2.59E-13 145.36792
292.7593467676
35 C = 308.15 K
25 C = 298.15 K
A B C D E Cp (J/mol)
208040
200480
-55.75 0.59859 1257.125585
61.59
290410
110.91
92.053 -0.039953 -0.00021103 0.00000053469 754.4607657591
51.234 0.013088 0.000023359 573.4851214801
41.293 0.033607 -0.000013927 502.0095577101
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 294.9373837169
29.342 -0.0035395 0.000010076 -4.3116E-09 2.5935E-13 290.7710818701
…...(1)
…...(2)
…...(3)
…...(4)
3094827.7202124 + 31260.8860627515 + 294.9373837169 N O2

3094827.7202124 + 31260.8860627515 + 1562.353425122 N O2
3126088.60627515 + 1562.35342512228 N O2
3126088.606 - 4953706.8260443
-1827618.220
2105.3042 kmol/jam
67369.7345 kg/jam
67.3697 ton/jam
7920.0 kmol/jam
110879.3547 kg/jam
110.9 ton/jam
178249.1 kg/jam
178.2 ton/jam
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp (J/mol K) N (kmol)
62412000 0.51262
60144000 0.41009
-55.75 0.59859 3950.95376 0.77174
18477.00000 0.00015
87123000 0.40968
33273.00000 1.64037
92.053 -0.039953 -0.00021103 0.00000053469 2258.66467 0.00061
51.234 0.013088 0.000023359 1728.74733 1.64098
41.293 0.033607 -0.000013927 1513.50796 25.40685
Qsteam =
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp N (kmol)
6241200 0.512616176692
6014400 0.410092941353
-55.75 0.59859 3950.9538 0.771739154364
1847.7000 0.00015148885
51.234 0.013088 0.000023359 1728.7473 0.409676347016
8712300 1.640371765414
3327.3000 0.0006059554
41.293 0.033607 -0.000013927 1513.5080 1.640977720814
92.053 -0.039953 -0.00021103 0.00000053469 2258.6647 25.40685071318
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/kg K) N (kmol)
2080400 0.512616176692
2004800 0.410092941353
-55.75 0.59859 1257.1256 0.771739154364
615.9000 0.00015148885
51.234 0.013088 0.000023359 573.4851 0.409676347016
2904100 1.640371765414
1109.1000 0.0006059554
41.293 0.033607 -0.000013927 502.0096 1.640977720814
92.053 -0.039953 -0.00021103 0.00000053469 754.4608 25.40685071318
308.15 K
308.15 K
51 52
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
5.1779411787E-05 107.721888 2080400 0.0051261617669 10664.4669399
4.142352943E-05 83.045892 2004800 0.0041009294135 8221.543288253
7.7953449936E-05 0.097997 1257.125585 0.0077173915436 9.701730358968
1.5301904051E-08 0.000009 615.9 1.514888501E-06 0.000933019828
4.1381449193E-05 0.023732 573.485121480108 0.0040967634702 2.349432896358
0.00016569411772 481.192287 2904100 0.0164037176541 47638.03643938
6.1207616202E-08 0.000068 1109.1 6.059554004E-06 0.006720651346
0.00016575532533 0.083211 502.009557710092 0.0164097772081 8.23786499838
0.00256634855689 1.936209 754.460765759055 0.2540685071318 191.6847204459
2105.3042029113 620932.91
7919.95390619013 2302893.57
2924500.58 66736.0281
2991236.6086
308.15 K
308.15 K
53 54
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
0.000001 1.0772189 2080400.000 5.126161767E-05 106.6446694
0.000000 0.8304589 2004800.000 4.100929414E-05 82.2154329
0.000001 0.0009800 1257.126 7.717391544E-05 0.0970173
0.000000 0.0000001 615.900 1.514888501E-08 0.0000093
0.000000 0.0002373 573.485 4.09676347E-05 0.0234943
0.000002 4.8119229 2904100.000 0.0001640371765 476.3803644
0.000000 0.0000007 1109.100 6.059554004E-08 0.0000672
0.000002 0.0008321 502.010 0.0001640977721 0.0823786
0.000026 0.0193621 754.461 0.0025406850713 1.9168472
2105.304203 620932.91
7919.953906 2302893.57
2923833.22 667.3603
2924500.58
K
K
52 54 55
Q (kj/jam) Cp N (kmol) Q (kj/jam) Cp N (kmol)
10664.467 2080400.00 0.0001 106.644669 2080400.00 0.518
8221.543 2004800.00 0.0000 82.215433 2004800.00 0.414
9.702 1257.13 0.0001 0.097017 1257.13 0.780
0.001 615.90 0.0000 0.000009 615.90 0.000
2.349 573.49 0.0000 0.023494 573.49 0.414
47638.036 2904100.00 0.0002 476.380364 2904100.00 1.657
0.007 1109.10 0.0000 0.000067 1109.10 0.001
8.238 502.01 0.0002 0.082379 502.01 1.658
191.685 754.46 0.0025 1.916847 754.46 25.663
66736.028 667.36028
6741006.195
423.15 K
57
N (kmol) Q (kj/jam)
? ?
? ?
333.15 K
59
N (kmol) Q (kj/jam)
0.52 3770262.319596
0.41 2906603.306413
0.78 3634.047969048
0.00 0.32985516481
0.41 4206151.124944
1.66 16841713.2126
0.00 2.375985473554
1.66 2930.419329058
0.51 1352.036463429
Q59 = 27732649.173
294.93738 N O2 + 290.77108 N N2 +
294.937 N O2 + 1093.853 N O2 +
+ 27823639.854
3132445.994
423.15 K T steam = 170 C

57 P steam = kPa
N (kmol) Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
2108.99165351015 7882778.516035 35362684.215 2767.1 719.1
7933.82574415724 28944076.73047
36826855.247
35362684.215
K
60 T CW in = 30 C 303.15
Q (kj/jam) T CW out = 49 C 323.15
1077217.81 Q Cp
25590565.97 151422165.601 1430.3807663792
979.97
2.90 Q = N.Cp.dT
237.32 N = Q/(Cp.dT)
148279255.04 N = 105861.43854865 kmol/jam
20.92 F Cw = 1905505.8938757 kg/jam
832.11 F Cw = 1905.5058938757 ton/jam
387.24
174949499.27
151422165.601
K
60
Q (kj/jam)
1077217.81
830458.09
979.97
0.09
237.32
4811918.06
0.68
832.11
387.24
6722031.36
9
N.Cp.dT
3367367.0784
3367367.0784
44867169.5575
C 443.15 K
kPa
Hl (kJ/kg) λs (Kj/kg) m (kg/jam) m (ton/jam)
719.1 2047.9 13466.790 13.467
Keluar
13 14
N.Cp.dT Cp N N.Cp.dT
286.4019287188 27.52659 7883.6684670518
69272.7523770717 377.4863815882 244.6808 92363.669836096
69272.7523770717 100247.33830315
100247.338303147 100247.33830315
T steam = 170 C 443.15

P steam = kPa
luar Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
15 2419843.7456 2767.1 719.1 2047.9
N.Cp.dT
203087.295799277
2317003.7880758
2520091.08387508
Keluar
15 16
N.Cp.dT Cp N N.Cp.dT
26005000 2.42738888888889 63124248.055556
3688343.75 1.48953409090909 5493913.7546165

250562.5 0.0655395 16421.74096875
250562.5 1.2452505 312013.07840625
2317003.7880758 2448848.2894
203087.295799277 7377.85885572 27.52659 203087.29580
2520091.08387508 71598532.21
71598532.2147821 71598532.21
luar
17
N.Cp.dT
63124248.0555556
5493913.75461648
16421.74096875
312013.07840625
2448848.2894358
203087.295799277
71598532.2147821
T CW in = 30 C 303.15
T CW out = 49 C 322.15
luar Q Cp.dT
18 40089868.5999455 1430.3807663792
N.Cp.dT
27774669.1444444 Q = N.Cp.dT
2417322.05203125 N = Q/(Cp.dT)
7225.56602625 N = 28027.410282808 kmol/jam
137285.75449875 F Cw = 504493.38509054 kg/jam
1084382.81303278 F Cw = 504.49338509054 ton/jam
87778.2848031016
3.6148366
8.5999455
71598532.2147821
T steam = 100 C 373.15
P steam =
20 2759180.8670 2676 419.1 2256.9
N.Cp.dT
3036271.87649179
3036271.87649
Keluar
20 21 22
N.Cp.dT Cp N N.Cp.dT Cp N
11442200 2.427388888889
1622871.25 1.48953409090909 2417322.0520313
110247.5 0.0655395
110247.5 1.2452505 137285.75449875
3036271.87649179 4136.37124571 976.276392 4038241.5957341 4136.37124571 19.924008
3188.854296994 27.52659 87778.284803102
3036271.87649179 6680627.6870672
34544935.4913284
T steam = 100 C 373.15

P steam = kPa
24 29681.0149 2676 419.1 2256.9
N.Cp.dT
32564.7615185167
32564.7615185167
suk Keluar
24 26 27
11442200 2.427388888889
110247.5 0.0655395
4136.37124571 137.004541852941 566701.64745215 4136.37124571 156.9285498529
32564.7615185167 4845.310014142 6.720882961765
32564.7615185167 566701.64745215
28463574.21
T steam = 100 C 373.15

P steam =
26 514984.2987 2676 419.1 2256.9
N.Cp.dT
566701.647452148
566701.6475
T steam = 100 C 373.15

P steam =
29 1443533.6772 2676 419.1 2256.9
N.Cp.dT
1588500.68848727
1588500.69
Keluar
29 30 31
11442200 2.427388888889
110247.5 0.0655395 7225.56602625
1588500.68848727 4136.37124571 530.141757321647 2192863.1211353 4136.37124571 10.81921953718
4845.310014142 6.72088296176471 32564.761518517
1588500.68848727 2232653.4486801
30052074.9
473.15 K
33
N N.Cp.dT
? ?
? ?
363.15 K
35
N N.Cp.dT
2.59 35009613.69158
1.23 4439.733637874
35014053.425
35014053.425
1825.70094952626 N O2 + 1734.1629409247 N N2 +
1825.701 N O2 + 6523.756 N O2 +
14609.029 N O2
29657205.349
T steam = 220 C
P steam =
Keluar Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
33 9753635.8846 2799.9 943.7
N N.Cp.dT
516.700416082986 2899955.910831
1943.77775574076 10037337.66851
10037337.669
T CW in = 30 C 303.15
T CW out = 49 C 323.15
luar Q Cp
36 194576567.196685 1430.3807663792
N.Cp.dT
1023749.69946906 Q = N.Cp.dT
925.236347386016 N = Q/(Cp.dT)
1024674.93581644 N = 136031.30842512 kmol/jam
F Cw = 2448563.5516522 kg/jam
67.196685 F Cw = 2448.5635516522 ton/jam
195601242.132502
T steam = 100 C 373.15

P steam = kpa
40 2910.6492 2676 419.1 2256.9
N.Cp.dT
3063.91773096614
2722.75578176134
5786.67351272749
T steam = 100 C 373.15

P steam = 101.3 kPa 1.013
44 7635.4996 2676 419.1 2256.9
N.Cp.dT
2376.12624410305
12900.8051148197
15276.9313589228
Keluar
38 39
mCpdT Cp (kJ/kg) N mCpdT
621.0804175 2.43724077174529 1513.7225160636
1313.51409233585 377.4863815882 3.60887657162928 1362.3017586226
1313.51409233585 2876.0242746862
2876.0242746862 2876.0242746862
Keluar
42 43
mCpdT Cp (kJ/kg) m (kg) mCpdT
286.4019287188 4.14330931196699 1186.6517782259
2979.12921899988 377.4863815882 17.0993717636733 6454.7799744997
2979.12921899988 7641.4317527257
7641.43175272566 7641.4317527257
Q (kj/jam)
3063.917730966
2722.755781761
5786.673512727
N (kmol) Q (kj/jam)
? ?
? ?
? ?
N (kmol) Q (kj/jam)
0.0052 10772.188828
0.0041 8304.5891801
0.0078 9.7997276353
0.0000 0.0009424443
0.0041 12017.58666
0.0166 18.377134596
0.0000 0.0046178745
0.0166 9.5058212886
0.2566 128.8331504
? ?
? ?
31260.886063
+ 1093.8531175 N O2 + 36.8478568429 N O2
T steam = 100 C 373.15
P steam = 101.3 kPa 1.013
Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
31993400.820 89354359.01 2676 419.1 2256.9
24664629.865
3049.10571
2.79906
35692232.381
54580.08975
1.36865
2836.83585
38453.47069
92449186.7352
89354359.01
Q (kj/jam)
3199340.081969
2466462.986476
3049.105709814
0.27990594833
708.2268902277
14291410.93181
2.016195403754
2483.632836235
57385.55619767
20020842.818
T CW in = 30 C 303.15
T CW out = 49 C 322.15
Q (kj/jam) Q Cp.dT N
1066446.69399 13347240.0110 1430.38076638
822154.3288253
970.1730358968 Q = N.Cp.dT
0.093301982777 N = Q/(Cp.dT)
234.9432896358 N = 9331.24963977 kmol/jam
4763803.643938 F Cw = 167962.493516 kg/jam
0.672065134585 F Cw = 167.962493516 ton/jam
823.786499838
19168.47204459
6673602.8070
13347240.0110
55
Q (kj/jam)
1077217.8056
830458.0875
979.9718
0.0942
237.3162
4811918.0607
0.6789
832.1067
19362.0736
6741006.195
6741006.195
27732649.173 + 934.425048922676 N O2 + 912.046648863
27732649.173 + 934.425 N O2 + 3431.033
443.15 K
atm
λs (Kj/kg) m (kg/jam) m (ton/jam)
2047.9 17267.779 17.268
K
K
K
m (kg/jam) m (ton/jam)
1181.6220 1.1816220253
K
K
K
m (kg/jam) m (ton/jam)
1222.5534 1.2226
22
N.Cp.dT
27774669.14444
7225.56602625
82413.09379049
27864307.80426
34544935.49133
m (kg/jam)
13.151232
Keluar
27
N.Cp.dT
27774669.14444
7225.56602625
649114.7412426
32564.76151852
28463574.21323
28463574.21323
m (kg/jam)
228.182152
m (kg/jam)
639.609055
31
N.Cp.dT
27774669.14444
44752.3085946
27819421.45304
30052074.9
35014053.42521 + 1403.11281961752 N O2 + 1290.95747172
35014053.425 + 1403.113 N O2 + 4856.459
493.15 K
λs (Kj/kg) m (kg/jam) m (ton/jam)

1856.2 5254.626 5.255
K
K
K
bar
m (kg/jam)
1.289667
K
bar
m (kg/jam)
3.383180
+ 136.7150671 N O2
K
bar
m (kg) (ton/jam)
39591.634 39.59163411
K
K
Ball Mill (BM-101)
Tref = 25 C
T56 = 35 C
T57 = 35 C
Komponen A B
Selulosa
MCA
CMC
Na-Glikolat
H2O 51.234 0.013088
NaOH 0 0
NaCl 0 0
N N2
N O2
N N2
N O2
298.15 K
308.15 K
308.15 K
56 57
C D Komponen
Cp (kj/kg) m (kg) Q (kj/jam) Cp (kj/kg) m (kg) Q (kj/jam)
2080.4 0.51779 1077.2178 ### 0.51779 1077.2178 Selulosa
1.2571256 0.77953 0.9799718 1.25713 0.77953 0.9799718 MCA
0.5734851 0.41381 0.2373162 0.57349 0.41381 0.2373162 NaOH
2904.1 1.65694 4811.9181 ### 1.65694 4811.9181 CMC
2.336E-05 1.1091 0.00061 0.0006789 1.10910 0.00061 0.0006789 NaGlikolat
0 0.5020096 1.65755 0.8321067 0.50201 1.65755 0.8321067 NaCl
0.7544608 25.66346 19.362074 0.75446 25.66346 19.362074 H2O_x000D_
5910.548 5910.548
Masuk Keluar
56 57
### ###
0.97997 0.97997
0.83211 0.83211
0.23732 0.23732
### ###
19.36207 19.36207
0.00068 0.00068
5910.548 5910.548
adjusted T
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW) Stream Ts Tt Tadj
Ts Tt
E-103 H1 150 80 40089868.600 11136.0746 70 0.1591 H1 150 80 10 140 70
E-201 H2 90 35 194576567.197 54049.0464 55 0.9827 H2 90 35 10 80 25
E-205 H3 55 35 13347240.011 3707.5667 20 0.1854 H3 55 35 10 45 25
E-302 H4 60 35 151422165.601 42061.7127 25 1.6825 H4 60 30 10 50 20
E-101 C1 100 150 27578638.652 7660.7330 50 0.1532 C1 100 150 100 150
E-102 C2 30 150 2419843.746 672.1788 120 0.0056 C2 30 150 30 150
E-104 C3 30 80 2759180.867 766.4391 50 0.0153 C3 30 80 30 80
E-105 C4 30 80 29681.015 8.2447 50 0.0002 C4 30 80 30 80
E-106 C5 30 80 514984.299 143.0512 50 0.0029 C5 30 80 30 80
E-107 C6 30 80 1443533.677 400.9816 50 0.0080 C6 30 80 30 80
E-108 C7 30 200 9753635.885 2709.3433 170 0.0159 C7 30 200 30 200
E-202 C8 30 35 2910.649 0.8085 5 0.0002 C8 30 35 30 35
E-203 C9 30 35 7635.500 2.1210 5 0.0004 C9 30 35 30 35
E-204 C10 35 55 89354359.015 24820.6553 20 1.2410 C10 35 55 35 55
E-301 C11 30 150 35362684.215 9822.9678 120 0.0819 C11 30 150 30 150
H1 H2 H3 H4 C1 C2 C3 C4 C5 C6 C7 C8
200 50 200-150 0.0159373
150 10 150-140 0.1532147 0.00560149015 0.0159373
140 40 140-100 0.159086780159 0.1532147 0.00560149015 0.0159373
100 20 100-80 0.159086780159 0.00560149015 0.0159373
80 10 80-70 0.159086780159 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
70 15 70-55 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
55 5 55-50 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
50 5 50-45 0.982709935 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
45 10 45-35 0.982709935 0.185378333486 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
35 5 35-30 0.982709935 0.185378333486 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373 0.000162
30 5 30-25 0.982709935 0.185378333486 1.6824685
25 5 25-20 1.6824685
20 20 20-0
T QH initial Pass Final pass

QH=0 Qh min
200 0 7.263970879419
-0.796866
150 -0.796865676848 6.467105202572
-2.566115
140 -3.36298095863 3.900989920789 QH min = 7.264 0.000
-3.90099 Qc min = 79.623 0.000
100 -7.263970879419 0 T pinch hot = 110 C
1.1137982 T pinch cold = 100 C
80 -6.150172656278 1.113798223141
10.120255
70 3.9700824832307 11.23405336265
12.794081
55 16.764163490117 24.02813436954
-1.94047
50 14.823693338593 22.08766421801
6.4718724
45 21.295565720471 28.55953659989
14.797528
35 36.093093819088 43.35706469851
13.600998
30 49.694092203091 56.95806308251
14.252784
25 63.946876080607 71.21084696003
8.4123425
20 72.359218614008 79.62318949343
Qc
C Q
H1 150 110 0.159086780159 6.3634712 6.3634712
H2 90 110 0.982709935337
H3 55 110 0.185378333486
H4 60 110 1.68246850668
1.2972618 kW 6.363471206341 kW
141.5330441652 C
C1 150 100 0.153214659177 7.660733
0.2800745 kW
C2 150 100 0.005601490152 0.2800745
C3 80 100 0.015328782594
7.2639709
C4 80 100 0.000164894527
C5 80 100 0.002861023882
C6 80 100 0.00801963154
1.5937314 kW
C7 200 100 0.015937313537 1.5937314
C8 35 100 0.000161702735
C9 35 100 0.000424194423
C10 55 100 1.241032764097
4.0929033 Kw
C11 150 100 0.081858065313 4.0929033
Beban Heater = 7.263970879

C9 C10 C11 ∑C ΔH
-0.015937 -0.796865676848
0.0818581 -0.256612 -2.566115281782
0.0818581 -0.097525 -3.900989920789
0.0818581 0.0556899 1.113798223141
0.0818581 1.0120255 10.12025513951
0.0818581 0.8529387 12.79408100689
1.2410328 0.0818581 -0.388094 -1.940470151524
1.2410328 0.0818581 1.2943745 6.471872381878
1.2410328 0.0818581 1.4797528 14.79752809862
0.000424 0.0818581 2.7201997 13.600998384
2.8505568 14.25278387752
1.6824685 8.412342533401
Ch > Cc
0.1430512 kW 0.3921043 kW
109.1007977285 C 106.63608
110
H
E
1.1156 kW 0.76643913 kW
88.864760 C 88.084835606 C
110
90
110
55
0.008245 kW 24.8207 kW 5.7300645719 kW
59.9951 C 45.242576661 C 41.836828 C
110
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
Beban Cooler = 79.623189493

0.002121 Kw C Q
C 106.62275 C
80 0.159086780159 4.772603405 0.07722871485
4.2353269 kW
35 0.982709935337 54.04904644 0.94584234905

52.166995 kW
0.4010 kW 0.0008085 kW
52.836956 52.832594116 C
35 0.185378333486 3.70756667 0.18521
3.3057766
30 1.68246850668 50.4740552 0.358992

19.915091 kW
100 0.153214659177
30 0.005601490152 0.392104311
30 0.015328782594 0.76643913
30 0.0001649 0.008245
30 0.002861023882 0.143051194
30 0.00801963154 0.400981577
30 0.015937313537 1.115611948
30 0.000162 0.000808514
30 0.000424 0.002120972
35 1.241032764097 24.82065528
30 0.081858065313 5.730064572
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW)
E-103 H1 150 80 40089868.6 11136.0746 70 159.0868

E-201 H2 90 35 194576567.2 54049.0464 55 982.7099
E-205 H3 55 35 13347240.0 3707.5667 20 185.3783
E-302 H4 60 35 151422165.6 42061.7127 25 1682.4685
E-101 C1 100 150 27578638.7 7660.7330 50 153.2147
E-102 C2 30 150 2419843.7 672.1788 120 5.6015
E-104 C3 30 80 2759180.9 766.4391 50 15.3288
E-105 C4 30 80 29681.0 8.2447 50 0.1649
E-106 C5 30 80 514984.3 143.0512 50 2.8610
E-107 C6 30 80 1443533.7 400.9816 50 8.0196
E-108 C7 30 200 9753635.9 2709.3433 170 15.9373
E-202 C8 30 35 2910.6 0.8085 5 0.1617
E-203 C9 30 35 7635.5 2.1210 5 0.4242
E-204 C10 35 55 89354359.0 24820.6553 20 1241.0328
E-301 C11 30 150 35362684.2 9822.9678 120 81.8581
H1 H2 H3
200 50 200-150
150 10 150-140
140 5 140-135
135 35 135-100 159.086780159
100 20 100-80 159.086780159
80 5 80-70 159.086780159
75 5 75-70 159.086780159 982.7099353
70 5 70-65 159.086780159 982.7099353
65 10 65-55 982.7099353
55 5 55-50 982.7099353
50 5 50-45 982.7099353
45 5 45-40 982.7099353
40 5 40-35 982.7099353 185.378333486
35 5 35-30 982.7099353 185.378333486
30 5 30-25 982.7099353 185.378333486
25 5 25-20 982.7099353 185.378333486
20 5 20-15
15 15 15-0

QH=0 Qh min
200 0 8059.40478021
-796.8657
150 -796.865676848 7262.53910336
-2566.115
140 -3362.98095863 4696.42382158
-1283.058
135 -4646.03859952 3413.36618069
-3413.366
100 -8059.40478021 0
1113.7982
80 -6945.60655707 1113.79822314
146.57789
75 -6799.028664 1260.37611621
5060.1276
70 -1738.90109425 6320.50368597
5060.1276
65 3321.226475509 11380.6312557
8529.3873
55 11850.61381343 19910.0185936
-1940.47
50 9910.143661909 17969.5484421
-1940.47
45 7969.673510386 16029.0782906
6471.8724
40 14441.54589226 22500.9506725
7398.764
35 21840.30994157 29899.7147218
13601
30 35441.30832558 43500.7131058
14252.784
25 49694.09220309 57753.4969833
14252.784
20 63946.87608061 72006.2808608
8412.3425
15 72359.21861401 80418.6233942
Qc
H1 150
H2 90
H3 55
H4 60
2092.6957 kW 5568.03730555
136.341413645
C1 150
280.07451 kW
C2 150
C3 80
8059.4048
C4 80
C5 80
C6 80
1593.7314 kW
C7 200
C8 35
C9 35
C10 55
4092.9033 Kw
C11 150

adjusted T
Stream Ts Tt Tadj
Ts Tt
ceklis H1 150 80 15 135 65
ceklis H2 90 35 15 75 20
ceklis H3 55 35 15 40 20
ceklis H4 60 30 15 45 15
ceklis C1 100 150 100 150
ceklis C2 30 150 30 150
ceklis C3 30 80 30 80
ceklis C4 30 80 30 80
ceklis C5 30 80 30 80
ceklis C6 30 80 30 80
ceklis C7 30 200 30 200
ceklis C8 30 35 30 35
ceklis C9 30 35 30 35
ceklis C10 35 55 35 55
ceklis C11 30 150 30 150
H4 C1 C2 C3 C4 C5 C6 C7
15.937314
153.21466 5.601490152 15.937314
153.21466 5.601490152 15.937314
153.21466 5.601490152 15.937314
5.601490152 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
1682.4685 5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
1682.4685 5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
1682.4685 5.601490152 15.328783 0.16489453 2.8610238815941 8.0196315 15.937314
1682.4685
1682.4685
1682.4685
QH min = 8059.405 0.00
Qc min = 80418.623 0.00
T pinch hot = 115 C

T pinch cold = 100 C
C Q
115 159.0867801585 5568.0373 5568.0373
115 982.7099353368
115 185.3783334862
115 1682.46850668
kW
C
100 153.2146591768 7660.733
100 5.601490151787 280.07451
100 15.32878259435
100 0.164894526948
100 2.8610238815941
100 8.0196315400239
100 15.93731353695 1593.7314
100 0.161702735447
100 0.424194422567
100 1241.032764097
100 81.85806531274 4092.9033
C8 C9 C10 C11 delta H sigma C
-15.93731 -796.8656768476
81.858065 -256.6115 -2566.115281782
81.858065 -256.6115 -1283.057640891
81.858065 -97.52475 -3413.366180691
81.858065 55.689911 1113.798223141
81.858065 29.315579 146.5778930706
81.858065 1012.0255 5060.127569755
81.858065 1012.0255 5060.127569755
81.858065 852.93873 8529.387337924
1241.0328 81.858065 -388.094 -1940.470151524
1241.0328 81.858065 -388.094 -1940.470151524
1241.0328 81.858065 1294.3745 6471.872381878
1241.0328 81.858065 1479.7528 7398.764049308
0.161703 0.424194 81.858065 2720.1997 13600.998384
2850.5568 14252.78387752
2850.5568 14252.78387752
1682.4685 8412.342533401
Ch > Cc
8.244726 kW
114.9481746608 C
115
H
E
766.439 kW
89.220076
115
90
115
55
115
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
2.12 kW
114.93484249 C
400.981577 kW
C 88.812039377 C
1115.612 kW 5730.0645719 kW
59.33692 C 55.931171
392.10431 kW
88.413036 C
0.8085137 kW
54.995638575 C
143.051 kW
C 55.8461465 C
C
80 159.0867801585
5557.6716 kW
35 982.7099353368
52489.521 kW
35 185.3783334862
3706.7582
24820.655 Kw
41.093624 C
30 1682.46850668
18664.672 kW
100 153.2146591768
30 5.601490151787
30 15.32878259435
30 0.1648945
30 2.861023881594
30 8.019631540024
30 15.93731353695
30 0.161703
30 0.424194
35 1241.032764097
30 81.85806531274
Q
5568.037306 113798.71 80418.623
54049.04644
3707.56667
50474.0552
392.1043106 33380.082
766.4391297
8.244726
143.0511941
400.981577
1115.611948
0.808513677
2.120972113
24820.65528
5730.064572
adjusted T
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW) Stream Ts Tt Tadj
Ts Tt
E-103 H1 150 80 40089868.600 11.1361 70 0.15909 H1 150 80 10 140 70
E-201 H2 90 35 194576567.197 54.0490 55 0.98271 H2 90 35 10 80 25
E-205 H3 55 35 13347240.011 3.7076 20 0.18538 H3 55 35 10 45 25
E-302 H4 60 35 151422165.601 42.0617 25 1.68247 H4 60 30 10 50 20
E-101 C1 100 150 27578638.652 7.6607 50 0.15321 C1 100 150 100 150
E-102 C2 30 150 2419843.746 0.6722 120 0.00560 C2 30 150 30 150
E-104 C3 30 80 2759180.867 0.7664 50 0.01533 C3 30 80 30 80
E-105 C4 30 80 29681.015 0.0082 50 0.00016 C4 30 80 30 80
E-106 C5 30 80 514984.299 0.1431 50 0.00286 C5 30 80 30 80
E-107 C6 30 80 1443533.677 0.4010 50 0.00802 C6 30 80 30 80
E-108 C7 30 200 9753635.885 2.7093 170 0.01594 C7 30 200 30 200
E-202 C8 30 35 2910.649 0.0008 5 0.00016 C8 30 35 30 35
E-203 C9 30 35 7635.500 0.0021 5 0.00042 C9 30 35 30 35
E-204 C10 35 55 89354359.015 24.8207 20 1.24103 C10 35 55 35 55
E-301 C11 30 150 35362684.215 9.8230 120 0.08186 C11 30 150 30 150
H1 H2 H3 H4 C1 C2 C3 C4 C5 C6 C7 C8
200 50 200-150 0.0159373
150 10 150-140 0.1532147 0.00560149015 0.0159373
140 40 140-100 0.159086780159 0.1532147 0.00560149015 0.0159373
100 20 100-80 0.159086780159 0.00560149015 0.0159373
80 10 80-70 0.159086780159 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
70 15 70-55 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
55 5 55-50 0.982709935 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
50 5 50-45 0.982709935 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
45 10 45-35 0.982709935 0.185378333486 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373
35 5 35-30 0.982709935 0.185378333486 1.6824685 0.00560149015 0.0153288 0.00016489 0.002861023882 0.0080196 0.0159373 0.000162
30 5 30-25 0.982709935 0.185378333486 1.6824685
25 5 25-20 1.6824685
20 20 20-0

QH=0 Qh min
200 0 7.263970879419
-0.796866
150 -0.796865676848 6.467105202572
-2.566115
140 -3.36298095863 3.900989920789 QH min = 7.264 0.000
-3.90099 Qc min = 79.623 0.000
100 -7.263970879419 0 T pinch hot = 110 C
1.1137982 T pinch cold = 100 C
80 -6.150172656278 1.113798223141
10.120255
70 3.9700824832307 11.23405336265
12.794081
55 16.764163490117 24.02813436954
-1.94047
50 14.823693338593 22.08766421801
6.4718724
45 21.295565720471 28.55953659989
14.797528
35 36.093093819088 43.35706469851
13.600998
30 49.694092203091 56.95806308251
14.252784
25 63.946876080607 71.21084696003
8.4123425
20 72.359218614008 79.62318949343
Qc
C Q
H1 150 110 0.159086780159 6.3634712 6.3634712
H2 90 110 0.982709935337
H3 55 110 0.185378333486
H4 60 110 1.68246850668
1.2972618 kW 6.363471206341 kW
141.5330441652 C
C1 150 100 0.153214659177 7.660733
0.2800745 kW
C2 150 100 0.005601490152 0.2800745
C3 80 100 0.015328782594
7.2639709
C4 80 100 0.000164894527
C5 80 100 0.002861023882
C6 80 100 0.00801963154
1.5937314 kW
C7 200 100 0.015937313537 1.5937314
C8 35 100 0.000161702735
C9 35 100 0.000424194423
C10 55 100 1.241032764097
4.0929033 Kw
C11 150 100 0.081858065313 4.0929033

C9 C10 C11 ΔH ∑C
-0.015937 -0.796865676848
0.0818581 -0.256612 -2.566115281782
0.0818581 -0.097525 -3.900989920789
0.0818581 0.0556899 1.113798223141
0.0818581 1.0120255 10.12025513951
0.0818581 0.8529387 12.79408100689
1.2410328 0.0818581 -0.388094 -1.940470151524
1.2410328 0.0818581 1.2943745 6.471872381878
1.2410328 0.0818581 1.4797528 14.79752809862
0.000424 0.0818581 2.7201997 13.600998384
2.8505568 14.25278387752
1.6824685 8.412342533401
Ch > Cc
0.1430512 kW
109.1007977285 C
110
H
E
1.1156 kW 0.76643913 kW 0.3921043 kW
88.864760 C 88.084835606 C 87.685833
110
90
110
55
0.008245 kW 24.8207 kW 5.7300645719 kW
59.9951 C 45.242576661 C 41.836828 C
110
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100

0.002121 Kw C Q
109.08747 C
80 0.159086780159 4.772603405 0.07722871485
4.6274312 kW
C
35 0.982709935337 54.04904644 0.94584234905
51.774891 kW
0.4010 kW 0.0008085 kW
52.836956 52.832594116 C
35 0.185378333486 3.70756667 0.18521
3.3057766
30 1.68246850668 50.4740552 0.358992

19.915091 kW
100 0.153214659177
30 0.005601490152 0.392104311
30 0.015328782594 0.76643913
30 0.0001649 0.008245
30 0.002861023882 0.143051194
30 0.00801963154 0.400981577
30 0.015937313537 1.115611948
30 0.000162 0.000808514
30 0.000424 0.002120972
35 1.241032764097 24.82065528
30 0.081858065313 5.730064572
Stream Ts Tt ΔH (kj/h) ΔH (kW) ΔT (oC)
E-103 H1 150 80 40089868.600 11136.075 70
E-201 H2 90 35 194576567.197 54049.046 55
E-205 H3 55 35 13347240.011 3707.567 20
E-302 H4 60 35 151422165.601 42061.713 25
E-101 C1 100 150 27578638.652 7660.733 50
E-102 C2 30 150 2419843.746 672.179 120
E-104 C3 30 80 2759180.867 766.439 50
E-105 C4 30 80 29681.015 8.245 50
E-106 C5 30 80 514984.299 143.051 50
E-107 C6 30 80 1443533.677 400.982 50
E-108 C7 30 200 9753635.885 2709.343 170
E-202 C8 30 35 2910.649 0.809 5
E-203 C9 30 35 7635.500 2.121 5
E-204 C10 35 55 89354359.015 24820.655 20
E-301 C11 30 150 35362684.215 9822.968 120
Hot Stream
Interval Tstart Tend ΔT H1 H2 H3
1 150 90 60 0.159
2 90 80 10 0.159 0.983
3 80 60 20 0.983
4 60 55 5 0.983
5 55 35 20 0.983 0.185
Cold Stream
Interval Tstart Tend ΔT C1 C2 C3
1 200 150 50
2 150 100 50 0.1532 0.0056
3 100 80 20 0.0056
4 80 55 25 0.0056 0.0153
5 55 35 20 0.0056 0.0153
6 35 30 5 0.0056 0.0153
Hot Cold
T ΔH T ΔH
250
150 9.545207 200 0.7969
90 19.09041 150 1.5937
80 30.50838 100 14.4243 200
60 50.16258 80 16.4922
55 63.48847 55 19.7365 150
35 120.4996 35 47.1526
30 47.8044 100
50
0
0 20 40
150
100
50
0
0 20 40
Hot Cold 250

T ΔH T ΔH
150 0 200 0 200
90 9.545207 150 0.796866
80 20.96317 100 13.62744
150
60 40.61737 80 15.69538
T (C)
55 53.94326 55 18.93966
100
35 110.9544 35 46.35574
30 47.00752
50
0
0 10 20 30 4
Hot Cold
T ΔH T ΔH T ΔH
150 4.954793 200 0 100 0
200
90 14.5 150 0.796866 100 20
180
80 25.91797 100 13.62744 160
60 45.57217 80 15.69538 T ΔH 140
55 58.89806 55 18.93966 60 13.62744208576 Suhu (C) 120
35 115.9092 35 46.35574 120 13.62744208576 100
30 47.00752 80
60
Tpinch hot = 110 C 40
Tpinch cold = 100 C 20
0
0 10 20 30 40
Hot Cold
T ΔH T ΔH Delta T min ΔH T
150 7.263971 200 0 110 0 200
90 16.80918 150 0.796866 110 0.796865676848 150
80 28.22714 100 13.62744 110 13.62744208576 100
60 47.88134 80 15.69538 110 15.69537946579 80
55 61.20724 55 18.93966 110 18.9396595044 55
35 118.2184 35 46.35574 110 46.35573881723 35
30 47.00752 110 47.00752431074 30
QH min 7.263971 MW T ΔH 79623.1894934275

QC min 71.21085 MW 150 7.263970879419 126.630713804169
Tpinch hot = 110 C 125 7.263970879419
Tpinch cold = 100 C
T ΔH
30 47.00752431074
60 47.00752431074
Hot Cold
T ΔH T ΔH T ΔH T
150 8.15 200 0 115 0 200
90 17.69521 150 0.796866 115 0.796865676848 150
80 29.11317 100 13.62744 115 13.62744208576 100
60 48.76737 80 15.69538 115 15.69537946579 80
55 62.09326 55 18.93966 115 18.9396595044 55
35 119.1044 35 46.35574 115 46.35573881723 35
30 47.00752 115 47.00752431074 30
QC min 8.15 kW T ΔH
QH min 72.09688 kW 150 8.15
Tpinch hot = 115 C 120 8.15
Tpinch cold = 100 C
T ΔH
30 47.00752431074
60 47.00752431074
Cc > Ch
H1 150
H2
H3
H4
1.297262 MW
C1 150
0.280075 MW
C2 150
C3 80
C4 80
C5 80
C6 80
1.593731 MW
C7 200
C8 35
C9 35
C10 55
4.092903 MW
C11 150
Qh min= = 7.2640
0.00000000
C (MW/C)
0.1591
0.9827
0.1854
1.6825
0.1532
0.0056
0.0153
0.0002
0.0029
0.0080
0.0159
0.0002
0.0004
1.2410
0.0819
H4 sum C ΔH (kW)
0.159087 9.5452068
1.141797 11.417967
0.9827099 19.654199
1.682 2.6651784 13.325892
1.682 2.8505568 57.011136
C4 C5 C6 C7 C8 C9 C10
0.0159
0.0159
0.0159
0.0002 0.0029 0.0080 0.0159
0.0002 0.0029 0.0080 0.0159 1.2410
0.0002 0.0029 0.0080 0.0159 0.0002 0.0004
Chart Title
20 40 60 80 100 120 140

20 40 60 80 100 120 140
250
200
150
Hot
100
Cold
50
0
0 10 20 30 40 50 60 70 80 90 100 110 120
Entalpi (ΔH)
Penentuan Pinch
00
80
60
40
Hot
20 Cold
00 Column F
80 Column F
60
40
20
0
0 10 20 30 40 50 60 70 80 90 100 110 120 130
Entalpi (ΔH)
ΔTmin = 10
ΔH
13.62744208576
200
13.62744208576
180
13.62744208576
160
13.62744208576
140
13.62744208576
120
13.62744208576
Suhu (C)
100
80
60
40
20
160
140
120
Suhu (C)
100
13.62744208576
80
60
79.623189493428
40
8.4123425334011
20
0
0 20 40 60 80 100 120
Entalpi (kW)
Hot Linear (Hot) Cold Linear (Co

delta Tmin = 10 pinch Column F Column F
ΔH ΔTmin = 15
13.62744208576
200
13.62744208576 180
13.62744208576 160
13.62744208576 140 f(x) = − 2.84728105252699 x + 150.788171215429
13.62744208576 120
Suhu (C)
100 f(x) = − 0.821164914580766 x + 117.328185798911

13.62744208576
80
13.62744208576 60
40
20
0
0 20 40 60 80 100 120 140
Entalpi (kW)
Hot Linear (Hot) Cold Linear (Cold)

delta T min 15 pinch Column F Column F
7.660733
101.84557 C C Q
110 0.1591 6.363471206
110 0.9827
110 0.1854
110 1.6825
6.3634712063406 MW
141.53304416517 C
100 0.1532 7.660732959
100 0.0056 0.280074508
100 0.0153
100 0.0002
100 0.0029
100 0.0080
100 0.0159 1.593731354
100 0.0002
100 0.0004
100 1.2410
100 0.0819 4.092903266
C11 sum C ΔH (kW)
0.0159 0.7969
0.0819 0.2566 12.8306
0.0819 0.1034 2.0679
0.0819 0.1298 3.2443
0.0819 1.3708 27.4161
0.0819 0.1304 0.6518
10
x pada 100C = 13.62744
y pada pinch 189.1506
80 100 120 140
(kW)
Cold Linear (Cold)

Column F Column F
x pada 100C = 13.62744

y pada pinch 194.1606
100 120 140
d Linear (Cold)
umn F Column F
Ch > Cc
0.392104 kW
107.5353 C
110
H
E
0.0082 kW
89.992 C
110
90
0.143 kW
54.22833
110
55
110
60
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
Beban Cooler
0.766439 kW
102.7175 C
0.0008 kW
89.99079 C 0.002121 kW
89.98863 C
24.8207
1.115612 kW 44.5844
59.33692 C
Qc min = 71.21084696
8.412342533
3.61406
54.03787
0.400982 Kw
52.06528 C
kW 3.163534
C 5.730065 kW
41.17865 C
18.80772
C Q
80 0.1591 4.772603 0.077229 0.1591 0.0056 0.1438 0.13816

kW 0.9827 0.0153 0.0004 0.0003
0.1854 0.0002 0.1825
1.6825 0.0029 0.4414 0.3596
35 0.9827 54.04905 0.945842 3.0096 0.0080
kW 0.0159
0.0002
0.0004
35 0.1854 3.707567 0.18521 1.2410
0.0819
1.3714
30 1.6825 50.47406 0.358992
kW
30 0.0056 0.392104
30 0.0153 0.766439
30 0.0002 0.008245
30 0.0029 0.143051
30 0.0080 0.400982
30 0.0159 1.115612
30 0.0002 0.000809
30 0.0004 0.002121
35 1.2410 24.82066
30 0.0819 5.730065
0.13014 113.0033 79.62319
0.0001
0.3436
33.38008
1 2 3 4 5 6
Selulosa 413.9337 413.93368421 20.69668 393.237 393.237
Hemiselulosa 206.9668 206.96684211 10.34834 196.6185 196.6185
Lignin 206.9668 206.96684211 10.34834 196.6185 196.6185
MCA
NaOH
CMC
Na-Glikolat
NaCl
H2O 1179.711
H2O2
Udara
Total 827.8674 827.86736842 41.39337 786.474 786.474 1179.711
Suhu (K)
Tekanan (bar)
Laju Panas (kj/jam) 2903015 2903014.5949 145150.7 2757864 2757864 4366976
0 #DIV/0!
0 0
0 0 0 0
0 0 0 0
0 0 0
0 0 0 0
0 0 0
F (kg)
0 0.0000
0 0.0000
0 0.0000
0 0.0000
0 0.0000
26.206 0.0000
26.206 0.00
#DIV/0!
0 0 0.35
#DIV/0! #DIV/0!
#DIV/0! 0
#DIV/0! 0 0
#DIV/0! 0
#DIV/0!
#DIV/0!
#DIV/0! 0
#DIV/0! 0
#DIV/0! 0
#DIV/0! 26.206
#DIV/0! 0 26.206
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
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NME-Laporan 2 - Kelompok 25 - CP Monomer

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A.

Perhitungan Cp Menggunakan Metode Estimasi

Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

CpSelulosa =_x000D_ 208040 J/mol.K 1284198 J/kg.K CpNa-CMC =_x000D_

CpHemiselulosa =_x000D_ 29506.75 J/mol.K 223536 J/kg.K CpNa-MCA =_x000D_

CpNa-CMC =_x000D_ 290410 J/mol.K 1200041 J/kg.K CpSelulosa =_x000D_

CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K

200480 J/mol.K 1089565 J/kg.K

Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

Kapasitas Perancangan Pabrik CMC

26. Rotary Reactor (R-101)

Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Tahap 1 : Alkalisasi Selulosa konversi = 0.8

Tahap 2 : Eterifikasi konversi = 0.8

Tahap 3 : Reaksi samping 0.8

Komponen Mr (kg/kmol) w F (kg/jam) X N (kmol)

27. Heater (E-204)

28. Aging vessel (V-103)

29. Cooler (E-205)

30. Cyclone (CY-301)

31. Cyclone (CY-302)

32. Silo (TK-107)

33. Rotary Dryer (RD-301)

34. Heater (E-301)

36. Cooler (E-302)

33. Ball mill (BM-301)

37. Product Tank (TK-108)

2. Vibrating screen (VS-101)

4. Steam Explosion Tank (V-101)

5. Flash Tank (V-102)

9. Delignification Tank (DT-101)

11. Cooler (E-103)

12. Heater (E-104)

13. Rotary Filter (RF-101)

14. Heater (E-105)

15. Heater (E-106)

16. Bleaching Tank (BT-101)

17. Heater (E-107)

18. Rotary Filter (RF-102)

19. Rotary RD (RD-101)

21. Cooler (E-201)

22. Mixer (M-201)

23. Heater (E-202)

24. Mixer (M-202)

25. Heater (E-203)

F (kg/jam) N (kmol) F (kg/jam) N (kmol)

Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Fungsi : Pematangan produk

Fungsi : Menurunkan suhu dari aging vessel

Keluar Fungsi : Memisahkan produk dari udara

N50 N52 N54 N55

N Fungsi : Mengurangi kadar air

Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

Fungsi : Untuk menyimpan bagasse sementara

Masuk Keluar Fungsi : Untuk mengencerkan NaOH 50% menjadi 20%

Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)