DAV Public School Brij Vihar

Class XII
Electrochemistry

1 Amongst the cell given below identify, which will measure the standard Electrode potential
of copper electrode

2 Select the correct statement from the following

a Ecell and ◇G of cell reaction both are extensive properties.
b Ecell and◇G of a cell reaction both are intensive properties.
c Ecell is an intensive property and ◇G of a cell reaction is an extensive property.
d E cell is an extensive while ◇G of a cell reaction is an intensive property.
3 The difference between the electrode potential of the electrodes when no current is drawn
through the cell is called
a cell potential
b cell emf
c potential difference
d cell voltage
4 An electrochemical cell can behave like an electrolytic cell when
a Ecell = 0
b E cell<E ext
c E cell >E ext
d E cell= E ext.
5 Electrode potential of magnesium electrode varies with the equation

6 Given below are two figures of Daniel cell (X) and(Y ).Study the figure and mark the
incorrect statement from the following
a ln figure X electrons flow from zinc rod to Copper rod hence current flows from copper to
zinc b In figure Y electrons flow from copper to Zinc and current flows from zinc to Copper
c In figures X zinc deposits at anode and copper deposits at cathode.
d In figure Y zinc is deposited at Copper and copper is deposited at zinc.

7 The conductivity of a solution decreases with dilution .Give reason.

8 Write the unit of molar conductivity.
9 On dilution the molar conductivity of acetic acid increases drastically while that of sodium
acetate increases gradually. Explain.
10 Write the mathematical formulation for kohlrausch law
11 Define electrochemical series and mention its any three applications.
12 Mention the two function of salt bridge.
Also write its composition.
13 List the factors which effect value of cell potential.
14 Consider the cell reaction given below
Cu l Cu2+ II Cl- I Cl2,Pt
Write the reactions occurring at cathode and anode.
15 Write Nernst equation for the following cell reaction.
2Cr + 3Fe2+ =2 Cr3+ +3Fe
16 Express the relation among cell constant ,resistance of the solution in the cell and
conductivity of the solution.
17 Define conductivity and molar conductivity for the solution of an electrolyte . Discuss the
variation with concentration for a strong and weak electrolyte. Draw the graph also.
18 The conductivity of 0.20 M solution of KCL at 298k is 0.0248 S/cm. Calculate its molar
conductivity .
19 The resistance of a conductivity cell containing 0.01 M KCl solution at 298k is 1500 ohms
.What is the cell constant if conductivity of 0.01 M KCl solution at 298 K is 0.146 × 10 -3
S/cm.
20 Write the cathodic and anodic reactions taking place in following cells.
a. Dry cell
b. Mercury cell
c. Nickel cadmium cell
d. Lead storage battery
21 Fuel cells are better than ordinary cells.Give reason.
Write cathodic and anode reaction taking place in hydrogen oxygen fuel cell
22 Rusting is an electrochemical phenomenon. Explain.